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WO1993015135A3 - Revetements de sol decoratifs ayant l'apparence de carreaux en ceramique et compositions et procedes pour leur production - Google Patents

Revetements de sol decoratifs ayant l'apparence de carreaux en ceramique et compositions et procedes pour leur production Download PDF

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Publication number
WO1993015135A3
WO1993015135A3 PCT/US1993/000947 US9300947W WO9315135A3 WO 1993015135 A3 WO1993015135 A3 WO 1993015135A3 US 9300947 W US9300947 W US 9300947W WO 9315135 A3 WO9315135 A3 WO 9315135A3
Authority
WO
WIPO (PCT)
Prior art keywords
layer
polymeric material
compositions
carrier
appearance
Prior art date
Application number
PCT/US1993/000947
Other languages
English (en)
Other versions
WO1993015135A2 (fr
Inventor
Allen A Shalov
Eugene Morselander
Ronald Dixon
Original Assignee
Congoleum Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Congoleum Corp filed Critical Congoleum Corp
Priority to JP5513500A priority Critical patent/JPH08503493A/ja
Priority to EP93904852A priority patent/EP0625170A4/en
Publication of WO1993015135A2 publication Critical patent/WO1993015135A2/fr
Publication of WO1993015135A3 publication Critical patent/WO1993015135A3/fr
Priority to KR1019940702632A priority patent/KR950700353A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
    • D06N7/0039—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
    • D06N7/0052—Compounding ingredients, e.g. rigid elements
    • D06N7/0055—Particulate material such as cork, rubber particles, reclaimed resin particles, magnetic particles, metal particles, glass beads
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/58—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
    • B29C70/60—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres comprising a combination of distinct filler types incorporated in matrix material, forming one or more layers, and with or without non-filled layers
    • B29C70/603—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres comprising a combination of distinct filler types incorporated in matrix material, forming one or more layers, and with or without non-filled layers and with one or more layers of pure plastics material, e.g. foam layers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D06N3/08—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products with a finishing layer consisting of polyacrylates, polyamides or polyurethanes or polyester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/722—Decorative or ornamental articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/732—Floor coverings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Floor Finish (AREA)

Abstract

Compositions comprenant un support, un premier matériau polymère organique fusionné ou fusible dans ledit support ainsi qu'un second matériau polymère non fusible dans ledit support, ledit second matériau polymère présentant une température de ramollissement inférieure à environ la température de fusion dudit premier matériau polymère dans le plastifiant. Il est préférable que le premier matériau polymère comprenne une résine vinylique, et que le second matériau polymère comprenne des particules polymères. La figure (2) reproduit une feuille en polymère résineux (10) comprenant une couche de base (11) avec un support (12) relativement plat. Eventuellement, mais de préférence, une couche résineuse intermédiaire (13) recouvre le support (12). Une composition d'encre (18) est déposée sur la surface de la couche résineuse intermédiaire (13). Une couche (19) de composition est appliquée sur la couche (18) d'encre d'impression. Une couche supplémentaire (20) de matière organique synthétique, comme des polymères de vinyle et d'uréthane, est appliquée sur la couche décorative (19).
PCT/US1993/000947 1992-02-04 1993-02-04 Revetements de sol decoratifs ayant l'apparence de carreaux en ceramique et compositions et procedes pour leur production WO1993015135A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP5513500A JPH08503493A (ja) 1992-02-04 1993-02-04 セラミックタイルの外観を有する装飾フロアカバーおよび該フロアカバーを作成するための組成物並びに方法
EP93904852A EP0625170A4 (en) 1992-02-04 1993-02-04 Decorative floor coverings having the appearance of ceramic tile and compositions and methods for making same.
KR1019940702632A KR950700353A (ko) 1992-02-04 1994-07-30 세라믹 타일의 외관을 갖는 바닥장식재, 그것을 제조하기 위한 조성물 및 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US83072792A 1992-02-04 1992-02-04
US07/830,727 1992-02-04

Publications (2)

Publication Number Publication Date
WO1993015135A2 WO1993015135A2 (fr) 1993-08-05
WO1993015135A3 true WO1993015135A3 (fr) 1993-09-30

Family

ID=25257580

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/000947 WO1993015135A2 (fr) 1992-02-04 1993-02-04 Revetements de sol decoratifs ayant l'apparence de carreaux en ceramique et compositions et procedes pour leur production

Country Status (8)

Country Link
US (1) US5627231A (fr)
EP (1) EP0625170A4 (fr)
JP (1) JPH08503493A (fr)
KR (1) KR950700353A (fr)
CN (1) CN1085233A (fr)
CA (1) CA2129025A1 (fr)
MX (1) MX9300647A (fr)
WO (1) WO1993015135A2 (fr)

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US6145242A (en) * 1996-06-05 2000-11-14 Integrated Pest Management Technologies, Inc. Pest management system
GB9900577D0 (en) 1999-01-13 1999-03-03 Altro Ltd Non stain flooring
US6607818B1 (en) 1999-03-26 2003-08-19 Ronald Mark Associates, Inc. Composite materials with bulk decorative features and process for producing same
US6649257B1 (en) * 1999-03-26 2003-11-18 Ronald Mark Associates, Inc. Composite materials with bulk decorative features and process for producing same
US7763345B2 (en) 1999-12-14 2010-07-27 Mannington Mills, Inc. Thermoplastic planks and methods for making the same
US6399670B1 (en) 2000-01-21 2002-06-04 Congoleum Corporation Coating having macroscopic texture and process for making same
AU2001263242A1 (en) * 2000-05-19 2001-12-03 Ppg Industries Ohio, Inc. Coating compositions having a geometrically ordered array of polymeric particlesand substrates coated therewith
US6641696B1 (en) 2000-07-11 2003-11-04 David A. Edgerton Method and apparatus for laminating ceramic tile
US6395116B1 (en) 2000-08-04 2002-05-28 Kenneth E. Mathis, Sr. Method for manufacturing counter top edging from floor tile
US6875504B2 (en) 2001-07-24 2005-04-05 Congoleum Corporation Backing sheet for surface covering
US8028486B2 (en) 2001-07-27 2011-10-04 Valinge Innovation Ab Floor panel with sealing means
GB0118567D0 (en) * 2001-07-31 2001-09-19 Autoglym Improvements in or relating to organic material
US6759096B2 (en) 2001-09-24 2004-07-06 Congoleum Corporation Method for making differential gloss coverings
FR2845714B1 (fr) * 2002-10-14 2005-03-18 Gerflor Module d'assemblage pour revetements de sols ou murs
US7550192B2 (en) * 2003-04-30 2009-06-23 Congoleum Corporation Resilient floor tile
EP1648691A4 (fr) * 2003-05-30 2008-04-23 Felisa Blazek Article de revetement de surface et procedes d'installation associes
US8056292B2 (en) 2004-10-28 2011-11-15 Diversified Foam Products, Inc. Low relflected-sound-pressure-level, low moisture-vapor-transmission-rate flooring system
SE530653C2 (sv) 2006-01-12 2008-07-29 Vaelinge Innovation Ab Fuktsäker golvskiva samt golv med ett elastiskt ytskikt omfattande ett dekorativt spår
US20090288359A1 (en) * 2007-06-07 2009-11-26 Martin Jr Joel E Polyvinyl Chloride (PVC) Compositions and Reinforced Flexible PVC Flooring With Improved Performance Formed of the Same
CN101532331A (zh) * 2007-07-30 2009-09-16 诺瓦利斯股份有限公司 具有互锁设计的地板覆盖物
US7741395B2 (en) * 2007-08-21 2010-06-22 Eastman Chemical Company Low volatile organic content viscosity reducer
US20090124737A1 (en) * 2007-11-12 2009-05-14 Eastman Chemical Company Acrylic plastisol viscosity reducers
EP2221165A1 (fr) * 2009-02-20 2010-08-25 Tarkett GDL Tige de soudure décorative pour revêtements de surface
NL2003019C2 (nl) 2009-06-12 2010-12-15 4Sight Innovation Bv Vloerpaneel en vloerbedekking bestaande uit meerdere van dergelijke vloerpanelen.
ES2745641T3 (es) * 2011-05-16 2020-03-03 Diversified Foam Products Inc Sistema de entarimado con losetas de vinilo de lujo
WO2013049927A1 (fr) * 2011-10-05 2013-04-11 Maax Bath, Inc. Panneau décoratif et son procédé de fabrication
US10119280B2 (en) * 2014-07-11 2018-11-06 Advanced Formliners, Llc Form liner for visually enhanced concrete
JP6525316B2 (ja) * 2015-07-29 2019-06-05 東リ株式会社 床材
NL2018781B1 (en) 2017-04-26 2018-11-05 Innovations4Flooring Holding N V Panel and covering
BE1026355B1 (nl) 2018-06-06 2020-01-17 Ivc Bvba Vloerpanelen

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US4501783A (en) * 1982-07-06 1985-02-26 Toyo Linoleum Company, Limited Non-slip floor material

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US4210567A (en) * 1974-11-15 1980-07-01 Teroson G.M.B.H. Plastisol of an acrylate polymer and a plasticizer
US4126727A (en) * 1976-06-16 1978-11-21 Congoleum Corporation Resinous polymer sheet materials having selective, decorative effects
US4196243A (en) * 1978-09-29 1980-04-01 Gaf Corporation Non-skid floor covering
US4423178A (en) * 1980-05-19 1983-12-27 Monsanto Company Plasticizers for vinyl chloride polymers
US4501783A (en) * 1982-07-06 1985-02-26 Toyo Linoleum Company, Limited Non-slip floor material

Also Published As

Publication number Publication date
KR950700353A (ko) 1995-01-16
JPH08503493A (ja) 1996-04-16
WO1993015135A2 (fr) 1993-08-05
MX9300647A (es) 1994-07-29
CN1085233A (zh) 1994-04-13
EP0625170A1 (fr) 1994-11-23
CA2129025A1 (fr) 1993-08-05
US5627231A (en) 1997-05-06
EP0625170A4 (en) 1996-06-05

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