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WO1993017661A1 - Compositions cosmetiques sans mauvaises odeurs - Google Patents

Compositions cosmetiques sans mauvaises odeurs Download PDF

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Publication number
WO1993017661A1
WO1993017661A1 PCT/US1993/001791 US9301791W WO9317661A1 WO 1993017661 A1 WO1993017661 A1 WO 1993017661A1 US 9301791 W US9301791 W US 9301791W WO 9317661 A1 WO9317661 A1 WO 9317661A1
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WO
WIPO (PCT)
Prior art keywords
zeolites
cosmetic
materials
zeolite
odoriferous
Prior art date
Application number
PCT/US1993/001791
Other languages
English (en)
Inventor
Diane Lynn Furio
Paul Robert Tanner
John Paul Luebbe
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to AU37358/93A priority Critical patent/AU3735893A/en
Publication of WO1993017661A1 publication Critical patent/WO1993017661A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks

Definitions

  • the present invention relates to cosmetic compositions essentially free of the malodors associated with the raw materials comprising an odoriferous cosmetic base.
  • Cosmetic compositions are made from a variety of cosmetic raw materials. These materials include fatty materials, waxes, emollients, humectants, moisturizers, e ulsifiers, colorants, perfumes, and other ingredients typically described in standard references.
  • Typical cosmetic compositions are expected to deliver cosmetic benefits with acceptable odor.
  • many of the materials used in a cosmetic base either have an inherient odor, acquire malodors during processing and storage due to degradation, or have impurities contained in them which are malodorous.
  • zeolitic materials are known for use in sorbent articles, such as disposable diapers and cata enials, to effectively reduce many odors associated with body fluids.
  • zeolitic materials are effective in controlling the malodors associated with cosmetic raw materials comprising the cosmetic base of the present invention.
  • the odor-reducing zeolitic materials useful in the present invention are selected from the group consisting of "intermediate ratio" (Si0 2 /Al 2 0 3 ) Y zeolites, ordenites, large-pore beta zeolites, and mixtures thereof. These zeolitic materials are compatible with various cosmetic raw materials used in the cosmetic arts.
  • the present invention is, therefore, particularly useful in unscented cosmetics, but is also useful for improving the fragrance quality of scented cosmetics.
  • Japanese J63242261-A (88.10.07) 87JP-076111 J63242261 ASK KK relates to an odor-sorbing mat with sepiolite powder, a nonwoven fabric layer, and what appears to be a sheet to which the sepiolite is attached by adhesive.
  • J87019865 teaches the manufacture of powder (including zeolites) sheets by laminating the powder between a first and second sheet. Powders include activated carbon, zeolite, etc. The abstract indicates use in catamenials or deodorizing materials.
  • ABSCENTS odor-reducing molecular sieve from Union Carbide
  • U.S. Pat. 4,826,497, Marcus et al . (issued 5/2/92) relate to ABSCENTS used as an odor-reducing agent, generally, and in sanitary products, in particular.
  • the present invention relates to cosmetic compositions essentially free of raw material malodors.
  • cosmetic compositions the Applicants mean any preparation of a liquid, semi-liquid, paste, powder, solid or other compositional form which when applied to the body protects the skin, improves the appearance and/or condition of the skin, and/or promotes other aesthetic or therapeutic conditions without specific medicinal effects.
  • Such cosmetics are well-known in the art and are disclosed in various formularies, such as Harry's Cosmeticolocy,
  • the cosmetic compositions of the present invention comprise a odoriferous cosmetic base, and greater than about 0.05%, preferably from about 0.05% to -.bout 10% by weight of the cosmetic composition, of an odor-reducing zeolitic material selected from the group consisting of intermediate ratio Si0 2 /A 2 0 3 Y zeolites, ordenites, beta zeolites, and mixtures thereof.
  • the zeolitic material be substantially free of particles greater than about 30 microns, preferably greater than about 15 microns.
  • substantially free means that larger particles are less than than about 5%, preferably 4%, and most preferably 3% as measured by laser light scattering. All percentages, ranges and ratios herein are by weight, except for the alumino/silica ratios which are expressed as molar ratios.
  • the process for making cosmetic compositions essentially free of raw material malodors is also disclosed herein.
  • the process comprises the addition of the above disclosed zeolitic material to the liquified odoriferous cosmetic base, wherein the mixture is adequately mixed to uniformly distribute said zeolite throughout the liquified odoriferous cosmetic base.
  • the cosmetic compositions of the present invention have no perceptible malodors. This is accomplished by including specific zeolitic materials, as described more fully hereinafter. In addition to its ability to sorb malodorous materials, it has been discovered that the above mentioned zeolitic materials can also reduce residual skin irritants found in cosmetic compositions.
  • the cosmetic compositions of the present invention comprise an odor-reducing amount, preferably greater than about 0.05%, more preferably from about 0.05% to about 10% by weight of a zeolitic material, selected from the group consisting of intermediate ratio Si0 2 /Al 2 0 3 Y zeolites (herein referred to as intermediate zeolites), mordenites, beta zeolites, and mixtures thereof.
  • a zeolitic material selected from the group consisting of intermediate ratio Si0 2 /Al 2 0 3 Y zeolites (herein referred to as intermediate zeolites), mordenites, beta zeolites, and mixtures thereof.
  • traditional zeolites comprise an alumino/silicate framework, with associated cations, M, providing overall electrical neutrality.
  • the zeolite framework can be represented as x A10 2 . y Si0 2 and the electrical neutral zeolite as x/n M . x A10 2 . y Si0 2 . z H 2 0 wherein: x and y are each integers, M is a cation and n is the charge on the cation.
  • zeolites may also comprise water of hydration (z H 2 0).
  • M can be a wide variety of cations, e.g., Na + , K + , NH 4 + , alkylammonium, heavy metals and the like.
  • the practice of the present invention does not require any particular selection of cation; accordingly, sodium ion is con ⁇ venient and preferred.
  • the intermediate zeolites particularly useful in this invention are characterized by Si0 2 /Al 2 0 3 molar ratios of from about about 2:1 to about 50:1, preferably from about 2:1 to about 20:1, more preferably from 2:1 to about 10:1, and most preferably from about 4:1 to about 7:1.
  • ultrastable intermediate zeolites By ultrastable, it is meant that the counter ion level, and the water of hydration value of the intermediate zeolites are lower than typical zeolites known in the art.
  • counter ion values for ultrastable zeolites in the present invention are from about 0 about 5.
  • Mordenites are also useable in the present invention.
  • mordenites are to be considered zeolitic materials having a needle-like structure, naturally found or a synthetic analog.
  • the mordenites are of the formula Si0 2 /Al : 0 3 wherein the ratio of Si0 2 /Al 2 0 3 is from about 12:1 to about 35:1, preferably from about 12:1 to about 20:1. Its surface area is from about 400 m ⁇ / to about 550 m ⁇ /g.
  • Examples of mordenites useful herein include CP500-11, CP511-13,CP504-20, CBV10A, CBV20A, CBV30A, and mixtures thereof.
  • the beta zeolites disclosed for use in the present invention have a Si0 2 /Al 2 0 3 ratios from about 10:1 to about 75:1, preferably from about 10:1 to about 50:1.
  • the surface area of said particles are from about 700 m 2 /g to about 800 m 2 /g.
  • They are also distinguished from the intermediate zeolites previously discussed by their larger pore size.
  • the pore size of the beta zeolites are known to be greater than the intermediate zeolites since its aluminosilicate rings typically have 12 members whereas the rings in the intermediate zeolites typically have no more than 10.
  • a wide variety of intermediate, and higher ratio ultrastable Y zeolites, suitable for use herein, are commercially available from commercial suppliers such as PQ Corporation, Mobil Corporation, and UOP. Such materials are sold under various commercial and trade names such as VALFOR CP301-68, VALFOR 300-63, VALFOR CP300-35, VALFOR CP300-51, VALFOR CP300-56, CP800 series, CBV10A-30A series, and the CBV300 to CBV780 series all from PQ Corporation.
  • zeolites While not intending to be limited by theory, it appears that the alumino/silicate ratios of the zeolitic materials for use in the present invention result in several advantages over the "high" zeolites.
  • the presently disclosed zeolites have a larger surface area (700-800 m z /g) than the high zeolites (ca. 400 m 2 /g). This results in more efficient odor sorption, on a wt./wt. basis; or, in the alternative, allows less zeolite to be used to reduce a given amount of odor.
  • These zeolites have a relatively low affinity for moisture, thereby, retaining more of their odor-sorbing capacity in the presence of water.
  • these zeolites act to sorb product odors even in liquid or solid cosmetic matrices which completely encompass the zeolite molecule sieve structures.
  • the zeolites disclosed for use in the present invention can be used in combination with other zeolites known in the art, such as high zeolites, to impart desirable characteristics to the cosmetic composition.
  • U.S. Pat. 4,362,715 as disclosed above, utilizes high zeolites to impart desirable rheology to the cream composition disclosed therein.
  • high ratio zeolites useful for such secondary benefits include, for example, the well-known "molecular sieve" zeolites of the ZSM, pentasil, silicate type (generally in the 1-10 micron particle size range) available from PQ Corporation as the VALFOR 600 series, and their CBV MFI-Type zeolites and and the zeolite materials marketed under the trade name ABSCENTS by UOP, and which are typically available as a white powder in the 3-5 micron particle size range (see: ABSCENTS, A New Approach for Odor Control by A. J. Gioffre, copyright 1988 by the Union Carbide Corporation) .
  • the odor-reducing agent described above can be optionally combined with the other odor sorbing materials, such as "high ratio" zeolites.
  • Such materials include, for example, The use of zeolites of the ABSCENTS type to reduce odors is fully described in U.S. Patent 4,795,482, January 3, 1989, to Gioffre and Marcus. These agents are reported by Gioffre and Marcus to be crystalline siliceous molecular sieves in which at least about 90, and preferably at least about 95, percent of the framework tetra- hedral oxide units are Si0 2 tetrahedra and which have a sorptive capacity for water at 25 * C and 4.6 of less than 10 weight percent.
  • those "high ratio" zeolite odor-reducing agents have a framework Si0 2 /Al 2 0 3 molar ratio of from about 35 to infinity, and preferably from 200 to 500.
  • Such siliceous molecular sieves have a pore diameter of at least 5.5 Angstroms, preferably at least 6.2 Angstroms.
  • zeolites are synthesized by hydrother al crystallization of alkaline (pH >8 and preferably higher) reactant mixtures. The synthesis can be viewed as 3 major stages with each having sub-steps: (1) combining and gelation of reactants; (2) crystallization; and (3) post-treatment. The resulting zeolite is not only a function of the reactant mixture but also is equally a function of the synthetic conditions. External factors such as temperature, pressure, time, etc. highly influence the crystalline structure.
  • silica source + alumina source + base + water A host of starting reactants are available; some typical silica and alumina sources are noted as follows.
  • Silica sources include: silicates; silica sol; silicic acid; silica gels; silica glass; minerals; and other zeolites.
  • Alumina sources include: aluminum hydroxide; aluminum salts; metal aluminates; aluminum nitrate; aluminum sulfate; pseudoboehmite; and various minerals. While different starting materials can yield different zeolites, the same zeolite can be made from different reactants.
  • Some reactant variables influencing the structure and composition of the final zeolite are:
  • the gel is transferred to a teflon or stainless steel container and placed in an autoclave.
  • Crystal formation begins as the gel is subjected to constant or variable temperature at autogeneous pressure for an indefinite time.
  • the phases are (1) induction or nucleation (first crystal appears); (2) crystal growth; and (3) phase transformation.
  • Some factors influencing the rate at which crystals form and grow are the temperature, pH, addition of seed crystals or tempiating materials for structure directing, stirring and centrifugation.
  • the slurry is removed from the autoclave and filtered. The crystals are washed and dried at ca.
  • counter ions can be exchanged such as: Na-zeolite + NH 4 C1 - NH 4 -zeolite or
  • Na-zeolite + HC1 - H-zeolite imparting unique adsorptive forces and modifying the pore size of, for example, an A, X or Y zeolite.
  • stabilization of traditional zeolites is possible.
  • a typical method of synthesizing an ultrastable zeolite Y (USY) such as "VALFOR CP300-56" is as follows: NaY + NH 4 + or NH+ exchange - NH 4 NaY + calcine (650-800'C) ⁇ USY Synthesis of Stabilized Zeolites
  • the methods include (1) pore modification; (2) surface modification; and (3) structural change.
  • the first two methods consist of adsorbing species by chemical vapor deposition inside or on the zeolite. Pore modifiers such as SiH 4 and BH 3 and surface modifiers such as Si(0CH 4 ) 4 , SiCl 4 , TiCl 4 and SeCl 4 have been used to impart new unique properties to the zeolite.
  • the most frequently used structural change method is to remove alumina from the main framework (i.e., de-alu inate) .
  • De-alumination can be performed by one of several routes such as (1) acid leaching; 2) steam (700-900'C); or (3) treatment with SiCl 4 at cold temperatures.
  • An example of de-alumination is: Zeolite Y + H 4 EDTA - de-alu inated Zeolite Y
  • the following references, incorporated by reference herein, further illustrate the synthesis of intermediate zeolites of the type employed herein: Lok, B. M., Cannan, T. R., and Messina, C. A., "The Role of Organic Molecules in Molecular Sieve Synthesis" Zeolites 3, 282-291 (1983); Barrer, R. M.
  • the sorption capacity for water vapor at 25'C and a water vapor pressure (p/p 0 ) of 4.6 is less than 6 Weight percent.
  • the efficacy of these molecular sieves is not dependent on the presence of the water of hydration in the internal cavities of the microporous structure as a result of their hydrothermal formation. In fact, at least a major proportion, usually substantially all, of this original water of hydration is removed in the process of removing any pore-blocking te plating agent which may be present in the adsorbent. Calcina- tion effectively removes any organic moieties.
  • water washing, leaching or washing with a caustic or dilute mineral acid solution is advantageously utilized to remove extraneous synthesis reactants from the pore system.
  • Lowering of the alkali metal content, particularly the nonzeolitic, i.e., occluded alkali metal compounds can also be beneficial. These procedures also serve to remove the original water of hydration.
  • siliceous molecular sieves include the microporous crystalline aluminosili- cates, i.e., the zeolitic molecular sieves as well as the so- called silica poly orphs. With respect to the latter composi ⁇ tions, their crystal lattices are ideally formed entirely of Si0 2 tetrahedral units, but the as-synthesized forms commonly ' contain at least trace amounts of aluminum derived from aluminum impuri ⁇ ties in the synthesis reagents.
  • the aluminosil icate molecular sieves comprise the large class of well-known crystalline zeolites.
  • the cosmetic compositions of the present invention can also contain an effective, i.e., odor-reducing, amount of various additional non-zeolitic odor-reducing materials to further expand their capacity for reducing odors, as well as the range of odor types being controlled.
  • Other sorbents include, for example, cetyl pyrdinium chloride, zinc chloride, EDTA, etidronate, BHT, and the like.
  • the odoriferous cosmetic base makes up the bulk of the compositions disclosed herein; the level being the difference between 100% and the level of zeolitic material being used.
  • the odoriferous cosmetic base disclosed herein utilizes cosmetic raw materials that are well-known in the cosmetic arts, and reference can be made to the various patents mentioned herein and to the general cosmetic products patent literature and trade catalogues for a description of these raw materials. While the cosmetic raw materials comprising the odoriferous cosmetic base are well-known, the present invention resides in the novel use of specific zeolitic materials to suppress the cosmetic raw material's malodors.
  • the odoriferous cosmetic base disclosed herein typically comprises cosmetic raw materials such as emollients, emulsifiers, cosmetic powders, waxes, colorants, humectants, moisturizers, suspending agents, oily materials, water, alcohol, viscosity modifiers, antimicrobials, preservatives, astringent materials, antiperspirant actives, and other conventional cosmetic materials.
  • cosmetic raw materials such as emollients, emulsifiers, cosmetic powders, waxes, colorants, humectants, moisturizers, suspending agents, oily materials, water, alcohol, viscosity modifiers, antimicrobials, preservatives, astringent materials, antiperspirant actives, and other conventional cosmetic materials.
  • cosmetics compositions often contain oily materials such as branched chain organic compounds. These materials closely resemble the naturally occurring oils or lipids found on the skin.
  • branched compounds typically contain more than about 6 carbon atoms and include aliphatic compounds such as 2- ethylhexyl palmitate.
  • Cosmetic compositions containing such materials include lipsticks, eye products, and various barrier creams and lotions.
  • Emollients are considered any material which is applied to the skin to relieve dryness. deNavarre, The Chemistry and Manufacture of Cosmetics. Vol. Ill 2d. Ed. 1975. For many years, emollients were oily materials which served to replace the natural surface lipids of the skin. Id. The best known of the typical emollients used in the art is glycerine. Other emollients which are often used by the artisan to formulate cosmetic compositions include those disclosed in Fox, Antiperspirant & Deodorant Review and Update, 100 Cosmetics & Toiletries, 1985; incorporated herein by reference. Among these are silicones, fatty esters, propoxylated alcohols, and hydrocarbon oils.
  • a necessary component found in most cosmetic compositions is an emulsifier, or coupling agent. These materials function to create an interface between immiscible components, for example aqueous based materials and oil based materials, typically used in cosmetic composition. Absent said emulsifiers, the cosmetics would not exist in a single homogeneous phase for any length of time.
  • Emulsifiers can be finely divided powders, or molecular species containing both hydrophilic and hydrophobic entities. Of the later emulsifier, literally thousands of these are available, and are selected on the basis of, for example color, odor, taste, price, and toxicity.
  • Said emulsifiers, known as surfactants include those shown in the above mentioned article by Fox.
  • compositions of the present invention can take and disclose therein the typical components used therein.
  • components incorporated within the present invention include antiperspirant and deodorant solids, antiperspirant and deodorant liquids, lotions, creams, and sprays, cosmetic solids, lotions, creams, and liquids.
  • Preferred compositions are deodorant or antiperspirant compositions in solid form.
  • solid cosmetic sticks are compressed powder sticks, gel sticks, and wax sticks. The differences between these sticks is within the skill of an artisan and is well known in the art. Cosmetic sticks are disclosed in detail in U.S. Pat. 4,944,937 issued July 31, 1990; U.S. Pat. 4,919,934, issued April 24, 1990; and U.S. Pat. 4,822,602 issued April 18, 1989; all herein incorporated by reference.
  • the solid stick cosmetic compositions are preferably gel and wax sticks, most preferably wax sticks.
  • Compressed powder or suspensoid sticks are made by isostatic compaction of selected powders and granulation containing binders such as microcrystall ine cellulose.
  • binders such as microcrystall ine cellulose.
  • Various other ingredients, such as selected emollients can be introduced to facilitate good skin glide.
  • Gel based sticks of the present invention comprise a liquid material selected for the desirable properties they impart.
  • the liquid material is from about 60% to about 99% by weight of the composition.
  • the liquid material useful herein includes those known in the art for making gel sticks. These include, for example, water, lower monohydric alcohols, polyhydric alcohols, and mixtures.
  • the present gel stick uses solidifying agents to impart a stable physical structure to the gel stick.
  • the solidifying agents are selected on the basis of the desired hardness of the final composition, the liquid base materials, and additional components which may be used.
  • the solidifying agent of the present invention is from about 1% to about 30% by weight of the composition.
  • Solidifying agents useful herein includes those known in the art for making gel sticks. These include, for example, fatty acid soaps; amides of higher fatty acids; higher fatty acid amides of alkylolamides; dibenzaldehyde- onosorbitol acetals; alkali metal and alkaline earth metal salts of the acetates, propionates, and lactates, waxes, and mixtures thereof.
  • Wax based sticks of the present invention comprise a liquid material selected for the desirable properties they impart.
  • the liquid material is about 30% to about 90% by weight of the composition.
  • Liquid materials useful herein include those known in the art for making wax sticks. These include, for example, silicones, hydrocarbon oils, esters, propoxylated and/or ethoxylated alcohols, and mixtures thereof.
  • the present wax sticks uses solidifying agents to impart a stable physical structure to the said stick.
  • the solidifying agents are selected on the basis of the desired hardness of the final composition, the liquid base materials, and additional components which may be used.
  • the solidifying agent of the present invention is from about 1% to about 30% by weight of the composition.
  • Solidifying agents useful herein includes those known in the art for making wax sticks. These include, for example, fatty alcohols, fatty acids, fatty ester, triglycerides, and waxes having melting points from about 65'C to about llO'-C.
  • Said waxes are selected from the group consisting of beeswax, spermaceti, carnauba, baysberry, candelilla, montan, ozokerite, ceresin, paraffin, castor waxes, synthetic waxes such as Fisher-Tropsch waxes, microcrystall ine wax, and mixtures thereof.
  • both wax and gel sticks can contain a variety of other cosmetic ingredients as previously discussed above.
  • antiperspirants and deodorants are two of the more common cosmetic sticks made.
  • Antiperspirants are typically produced as wax type sticks since the astringent metal actives such as aluminum chlorohydrate are more pH compatible in these waxy matrices.
  • deodorant actives such as antimicrobial compounds like triclosan, form stable solid compositions in gel matrices. Antiperspirant and deodorant sticks of these types are described in U.S. Patents 4,725,432;
  • compositions of the present invention is a cosmetic antiperspirant wax stick, particularly one comprising: a. from about 0.05% to about 10% intermediate ratio Si0 2 /Al 2 0 3 ultrastable Y zeolite; b. from about 30% to about 90% of a liquid material; c. from about 10% to about 30% of a solidifying agent; and d. from about 5% to about 50% of an antiperspirant active.
  • a cosmetic antiperspirant wax stick particularly one comprising: a. from about 0.05% to about 10% intermediate ratio Si0 2 /Al 2 0 3 ultrastable Y zeolite; b. from about 30% to about 90% of a liquid material; c. from about 10% to about 30% of a solidifying agent; and d. from about 5% to about 50% of an antiperspirant active.
  • Examples of antiperspirant and deodorant cosmetic stick compositions follow below:
  • Phenyl Trimethicone 3 5.00 Stearyl Alcohol 14.50
  • Zeolite* 1.0 100.00 I CBV10A, a ordenite available from PQ Corporation
  • Cosmetic creams typically signify a solid or semi-solid emulsion.
  • Said emulsions typically are either oil-in-water or water-in-oil emulsions.
  • the selection of cosmetic raw materials useful in such creams is extensive, with the selection based in part upon the desired purposes for said cream, for example, moisturizing and conditioning skin, imparting color or shades, delivering protectants such as sunscreens, deodorants, and antiperspirants, and numerous other functions. Regardless of their function, most creams contain a fair amount of lipid materials.
  • Orr et al . discloses skin conditioning cream compositions comprising from about 1% to about 60% propoxylated glycerol derivatives, 5% to 10% emollients, a suitable emulsifier, and the balance water.
  • Example 3 Skin Cream
  • Cosmetic lotions typically signify liquids which can be readily spread over the surface of the skin. Viscosities are significantly lower than creams disclosed above. Lotions can be comprised of all miscible components, like alcohol and water after shave lotions, or at least in part a non-solubilized component which is suspended in the liquid carrier of said lotion.
  • Lotions can be comprised of all miscible components, like alcohol and water after shave lotions, or at least in part a non-solubilized component which is suspended in the liquid carrier of said lotion.
  • U.S. Patent 4,976,953, cited above discloses skin conditioning lotions comprising from about 1% to about 60% propoxylated glycerol derivatives, 5% to 10% emollients, and the balance water.
  • a suspension type antiperspirant lotion of the present invention is an example of a suspension type antiperspirant lotion of the present invention.
  • Lipsticks are cosmetics that are molded into sticks, and are essentially dispersions of coloring matter in a base comprising a blend of oils, fats, and waxes.
  • a greasy base is used to provide a desirable moist appearance on the lip surface. This base also provides excellent e olliency.
  • Harry's Cosmeticology Edited by Wilkinson and Moore, 7th Ed., 1982.
  • Example 5 Component Weight %
  • ALFOR CP300-51 an intermediate zeolite available from PQ Corporation Dissolve the bromoacid in the HD-Eutanol and heat to about 80°C. Melt the remaining fatty materials, add the pigments to this solution, and add the mixture into the bromoacid/Eutanol solution above. Lower the temperature of this mixture to about 60°C, and add antioxidant and perfume. Pass the mixture through a roller mill two or three times, and remelt the solidified material. Pour the molten mixture into lipstick molds, and add color blends.

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Abstract

L'invention se rapporte à des compositions cosmétiques contenant des matières zéolitiques afin de réduire les mauvaises odeurs provenant des matières de la base cosmétique de la composition. Les matières zéolitiques comprennent des zéolites, des mordénites, des zéolites bêta et des combinaisons de celles-ci. L'invention se rapporte également au procédé de fabrication des compositions cosmétiques.
PCT/US1993/001791 1992-03-11 1993-03-01 Compositions cosmetiques sans mauvaises odeurs WO1993017661A1 (fr)

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AU37358/93A AU3735893A (en) 1992-03-11 1993-03-01 Cosmetic compositions free of malodors

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US85017692A 1992-03-11 1992-03-11
US07/850,176 1992-03-11

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4309748A1 (de) * 1993-03-28 1994-12-01 Heike Pfeiffer Mittel zur Bekämpfung von Schweißgerüchen
EP0697212A3 (fr) * 1994-07-19 1996-11-13 Shinagawa Fuel Co Ltd Composition cosmétique déodorante à résistance supérieure à la décoloration et dispersion
US6048549A (en) * 1997-12-19 2000-04-11 Johnson & Johnson Consumer Companies, Inc. Powder compositions
WO2000074643A1 (fr) * 1999-06-04 2000-12-14 The Procter & Gamble Company Batons de soins de la peau
WO2002061027A1 (fr) * 2001-01-30 2002-08-08 The Procter & Gamble Company Nanozeolites pour la suppression des mauvaises odeurs
FR2992553A1 (fr) * 2012-06-29 2014-01-03 Oreal Composition cosmetique anhydre deodorante comprenant au moins une zeolite particuliere et procede de traitement des odeurs corporelles
US11154483B1 (en) 2018-05-17 2021-10-26 American Spraytech, L.L.C. Composition to shorten drying time for hair

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Cited By (11)

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Publication number Priority date Publication date Assignee Title
DE4309748A1 (de) * 1993-03-28 1994-12-01 Heike Pfeiffer Mittel zur Bekämpfung von Schweißgerüchen
EP0697212A3 (fr) * 1994-07-19 1996-11-13 Shinagawa Fuel Co Ltd Composition cosmétique déodorante à résistance supérieure à la décoloration et dispersion
US5723110A (en) * 1994-07-19 1998-03-03 Shinagawa Fuel Co., Ltd. Deodorant cosmetic composition superior in resistance to discoloration and dispersion
US6048549A (en) * 1997-12-19 2000-04-11 Johnson & Johnson Consumer Companies, Inc. Powder compositions
US6426092B1 (en) * 1997-12-19 2002-07-30 Johnson & Johnson Consumer Companies, Inc. Powder compositions comprising a skin irritation reducing agent
US6660304B2 (en) 1997-12-19 2003-12-09 Johnson & Johnson Consumer Companies, Inc Method of treating prickly heat
WO2000074643A1 (fr) * 1999-06-04 2000-12-14 The Procter & Gamble Company Batons de soins de la peau
WO2002061027A1 (fr) * 2001-01-30 2002-08-08 The Procter & Gamble Company Nanozeolites pour la suppression des mauvaises odeurs
US6660713B2 (en) 2001-01-30 2003-12-09 The Procter & Gamble Company Hydrophobic nanozeolites for malodor control
FR2992553A1 (fr) * 2012-06-29 2014-01-03 Oreal Composition cosmetique anhydre deodorante comprenant au moins une zeolite particuliere et procede de traitement des odeurs corporelles
US11154483B1 (en) 2018-05-17 2021-10-26 American Spraytech, L.L.C. Composition to shorten drying time for hair

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