[go: up one dir, main page]

WO1993018545A1 - Method of laser etching of silicon dioxide - Google Patents

Method of laser etching of silicon dioxide Download PDF

Info

Publication number
WO1993018545A1
WO1993018545A1 PCT/US1992/003670 US9203670W WO9318545A1 WO 1993018545 A1 WO1993018545 A1 WO 1993018545A1 US 9203670 W US9203670 W US 9203670W WO 9318545 A1 WO9318545 A1 WO 9318545A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
amorphous silicon
silicon dioxide
integrated circuit
etching
Prior art date
Application number
PCT/US1992/003670
Other languages
French (fr)
Inventor
Arthur R. Elsea, Jr.
Daniel J. Dooley
Original Assignee
Lasa Industries Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lasa Industries Inc. filed Critical Lasa Industries Inc.
Publication of WO1993018545A1 publication Critical patent/WO1993018545A1/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3205Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
    • H01L21/321After treatment
    • H01L21/3213Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
    • H01L21/32139Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer using masks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/3065Plasma etching; Reactive-ion etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31144Etching the insulating layers by chemical or physical means using masks

Definitions

  • This invention relates to a method of patterning oxide for the fabrication of integrated circuits using laser pantography.
  • the patterning of oxide is one of the most basic and repeated steps in the fabrication of integrated circuit devices particularly in silicon microelectronics.
  • Silicon dioxide (Si0 2 ) is often used as a mask against ion implantation or diffusion. It is also used as an isolation layer to define transistor geometries.
  • this oxide patterning is done using photolithography techniques.
  • Photolithography employs wet chemical processes for coating and developing a photoresist layer. The photolithography process required for each oxide delineation comprises a series of several steps. The photolithography process is a source of contamination and defect generation and often produces a loss of circuit yields.
  • the present invention relates to a method of using a laser to provide a method of etching openings in a silicon dioxide (Si0 2 ) pattern on an integrated circuit or other semiconductor element.
  • a thin layer, for example, 2,000 A, of amorphous silicon is blanket deposited over the surface area of an integrated circuit or other semiconductor element upon which an oxide pattern is to be delineated.
  • a focused laser beam with sufficient power having a wavelength of, for example, 5,145 A as a point heat source and placing the integrated circuit
  • the desired pattern is etched in the amorphous silicon.
  • the semiconductor substrate is then placed in a plasma etcher or reactive ion etcher (RIE) .
  • RIE reactive ion etcher
  • a plasma etcher using a gas, such as CHF 3 which has a selectivity ratio of Si0 2 :Si equal to 10:1
  • the laser etched pattern in the amorphous silicon can be transferred to the silicon dioxide.
  • the amorphous silicon layer can be removed, if desired.
  • One advantage of the present invention is that all wet chemical steps may be eliminated during etching of the oxide when fabricating integrated circuits.
  • the use of the present invention is easily adapted to automation where standard machine interface ("SMIF") boxes for transferring substrates between machines are used. Therefore, clean room requirements are reduced or eliminated, providing for a truly all dry process for the fabrication of integrated circuits.
  • SMIF standard machine interface
  • Figure 1 illustrates a first step in accordance with a preferred embodiment of the present invention
  • Figure 2 shows the second step in accordance with a preferred embodiment of the present invention
  • Figure 3 illustrates the third step in accordance with a preferred embodiment
  • Figure 4 shows the resulting step in accordance with a preferred embodiment of the present invention.
  • Figures 5, 6, 7 and 8 show various steps of etching using the invention to etch a metallic layer with an amorphous silicon mask.
  • Figures 9, 10, 11, 12 and 13 show an alternative preferred embodiment of the invention which etches a metallic layer using both an amorphous silicon mask and a silicon dioxide etched hard mask in a double masking technique.
  • DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT The Figures, by way of example, illustrate a preferred embodiment of the present invention. It should be appreciated that the oxide patterning process of the present invention may be used in connection with any type of patterning of silicon dioxide on an integrated circuit or other semiconductor element. By way of example, the invention may be used in forming the implant mask openings on an integrated circuit.
  • the semiconductor substrate 10 has a thin film of Si0 2 12 which has been either grown or deposited on the substrate.
  • a blanket deposition of amorphous silicon 14 is made over the thin film of Si0 2 12. It is preferable that the amorphous silicon layer 14 be less than about 2,000 A in thickness.
  • a focused laser beam illustrated by the arrows 16 in Figure 2 and having a wavelength of, for example, 5,145 A, is used as a point heat source.
  • the semiconductor substrate 10 having the thin film layer of Si0 2 12 and amorphous silicon layer 14 is placed in a chamber having a gaseous environment of CLj or HCl or other halogen containing gas.
  • the laser beam 16 is focused on the amorphous silicon 14 and traversed along the surface of the amorphous silicon 14 in the form of the desired Si0 2 pattern openings, and by doing so, the thin amorphous silicon layer 14 is etched away.
  • the laser's light and heat interact with the halogen gas environment to loosen the gas's ionic covalent bond.
  • the resulting etchant gas turns the amorphous silicon layer 14 into a gas at the point of contact of the laser beam on the amorphous silicon.
  • the gaseous compounds are then pumped out of the pantography chamber. Because the reaction chamber remains at room temperature, process-gas contamination of the chamber or the workplace is virtually eliminated.
  • the integrated circuit device After laser etching the amorphous silicon, the integrated circuit device is then placed in plasma etcher or reactive ion etcher (RIE) to transfer (by conventional integrated circuit fabrication means) the pattern existing on the amorphous silicon to the Si0 2 layer.
  • plasma etcher using a gas such as CHF 3/ a selectivity ratio of silicon
  • the amorphous silicon 14 can be plasma stripped to remove the amorphous silicon layer
  • the invention as described eliminates the need for wet chemistry in all processes and particularly in the use of photolithography.
  • the yield loss during photolithography due to particles, contamination, over and under cutting, and bad exposure are all eliminated.
  • the process can be used to pattern oxides even over metal regions and is not subject to topology or reflectivity variations existing on the integrated circuit substrate.
  • Figure 5 shows this embodiment of the invention.
  • the amorphous silicon layer 14 is deposited over the metallic layer 21 on the substrate 10.
  • the laser 16 etches the amorphous silicon 14 in the manner of the previous embodiments.
  • the etched amorphous silicon 14 is then used as a mask to etch the metallic layer 21 by placing it in a blank environment.
  • the amorphous silicon layer may be removed if required or it may be left in place as shown in
  • the heat flow into the metal layer 21 of this embodiment may cause a loss of the subsequent lasography effect required. This might be avoided by the use of excimer lasers to etch, or other means.
  • the preferred embodiment is to
  • SUBSTITUTE SHEET deposit a layer of silicon dioxide between the metal layer 21 and the amorphous silicon 14, as shown in Figure 9.
  • laser 16 then will etch a mask in the amorphous silicon 14.
  • the silicon dioxide layer 12 will then be etched through the amorphous silicon mask 14, as shown in Figure 11.
  • the metal layer 21 may be etched through the hard mask provided by the silicon dioxide 12. This is a double masking technique.
  • the etching of the silicon 12 and the metal layer 21 might, in theory, be done in the same chamber with a two-step process, however, it is preferable to etch the Si0 2 in a separate step from the metal in order to split the etch chemistry and for cleanliness reasons.
  • the amorphous silicon layer 14 may be plasma stripped if required, as shown in Figure 13. Also, the silicon dioxide layer 12 may be removed as shown in Figure 14, if required.
  • the laser can be accurately controlled during the etching of the amorphous silicon, undercutting can be minimized or can be controllably reproduced.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Plasma & Fusion (AREA)
  • Drying Of Semiconductors (AREA)

Abstract

A method of using a laser (16) to etch patterns in a thin layer of amorphous silicon (14) which is used as a mask for the etching of a layer of silicon dioxide (12) in integrated circuit fabrication. The laser is used to etch the amorphous silicon in the presence of halogen ions. Subsequently, the amorphous silicon is used as a mask to plasma etch the silicon dioxide. Alternate embodiments of the method etch a metal region on a substrate, or a silicon dioxide layer on a metal region, both using an etched amorphous silicon mask. An alternate embodiment uses a double masking technique to etch an amorphous silicon mask, which is used to etch a silicon dioxide hard mask, which is used to etch a metal region.

Description

METHOD OF LASER ETCHING OF SILICON DIOXIDE
This invention relates to a method of patterning oxide for the fabrication of integrated circuits using laser pantography. The patterning of oxide is one of the most basic and repeated steps in the fabrication of integrated circuit devices particularly in silicon microelectronics. Silicon dioxide (Si02) is often used as a mask against ion implantation or diffusion. It is also used as an isolation layer to define transistor geometries. Conventionally, this oxide patterning is done using photolithography techniques. Photolithography employs wet chemical processes for coating and developing a photoresist layer. The photolithography process required for each oxide delineation comprises a series of several steps. The photolithography process is a source of contamination and defect generation and often produces a loss of circuit yields. Also inherent in the photolithography process is the need to have proper exposure and focus on a photoresist layer on the surface of the semiconductor element to be patterned. Focusing and exposure becomes difficult as the topology of the integrated circuit varies and is particularly difficult over reflective metal regions of the integrated circuit device.
Accordingly, there is a need in the art for an improved method for etching silicon dioxide layers on an integrated circuit or other semiconductor element.
SHORT STATEMENT OF THE INVENTION
The present invention relates to a method of using a laser to provide a method of etching openings in a silicon dioxide (Si02) pattern on an integrated circuit or other semiconductor element. In accordance with the invention, a thin layer, for example, 2,000 A, of amorphous silicon is blanket deposited over the surface area of an integrated circuit or other semiconductor element upon which an oxide pattern is to be delineated. Using a focused laser beam with sufficient power having a wavelength of, for example, 5,145 A as a point heat source and placing the integrated circuit
SUBSTITUTESHEET or semiconductor element in a gaseous environment such as Cl2 or HC1 or other halogen ion, the desired pattern is etched in the amorphous silicon. After laser etching the amorphous silicon, the semiconductor substrate is then placed in a plasma etcher or reactive ion etcher (RIE) . In a plasma etcher using a gas, such as CHF3, which has a selectivity ratio of Si02:Si equal to 10:1, the laser etched pattern in the amorphous silicon can be transferred to the silicon dioxide. After the etching of the Si02, the amorphous silicon layer can be removed, if desired.
One advantage of the present invention is that all wet chemical steps may be eliminated during etching of the oxide when fabricating integrated circuits. The use of the present invention is easily adapted to automation where standard machine interface ("SMIF") boxes for transferring substrates between machines are used. Therefore, clean room requirements are reduced or eliminated, providing for a truly all dry process for the fabrication of integrated circuits.
BRIEF DESCRIPTION OF THE DRAWINGS Other improvements, advantages and features of the present invention will become more fully apparent from the following detailed description of the preferred embodiments, the appended claims and the accompanying drawings in which:
Figure 1 illustrates a first step in accordance with a preferred embodiment of the present invention;
Figure 2 shows the second step in accordance with a preferred embodiment of the present invention;
Figure 3 illustrates the third step in accordance with a preferred embodiment; Figure 4 shows the resulting step in accordance with a preferred embodiment of the present invention.
Figures 5, 6, 7 and 8 show various steps of etching using the invention to etch a metallic layer with an amorphous silicon mask. Figures 9, 10, 11, 12 and 13 show an alternative preferred embodiment of the invention which etches a metallic layer using both an amorphous silicon mask and a silicon dioxide etched hard mask in a double masking technique. DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT The Figures, by way of example, illustrate a preferred embodiment of the present invention. It should be appreciated that the oxide patterning process of the present invention may be used in connection with any type of patterning of silicon dioxide on an integrated circuit or other semiconductor element. By way of example, the invention may be used in forming the implant mask openings on an integrated circuit. The semiconductor substrate 10 has a thin film of Si02 12 which has been either grown or deposited on the substrate. A blanket deposition of amorphous silicon 14 is made over the thin film of Si02 12. It is preferable that the amorphous silicon layer 14 be less than about 2,000 A in thickness. A focused laser beam illustrated by the arrows 16 in Figure 2 and having a wavelength of, for example, 5,145 A, is used as a point heat source. The semiconductor substrate 10 having the thin film layer of Si02 12 and amorphous silicon layer 14 is placed in a chamber having a gaseous environment of CLj or HCl or other halogen containing gas. The laser beam 16 is focused on the amorphous silicon 14 and traversed along the surface of the amorphous silicon 14 in the form of the desired Si02 pattern openings, and by doing so, the thin amorphous silicon layer 14 is etched away. The laser's light and heat interact with the halogen gas environment to loosen the gas's ionic covalent bond. The resulting etchant gas turns the amorphous silicon layer 14 into a gas at the point of contact of the laser beam on the amorphous silicon. The gaseous compounds are then pumped out of the pantography chamber. Because the reaction chamber remains at room temperature, process-gas contamination of the chamber or the workplace is virtually eliminated.
After laser etching the amorphous silicon, the integrated circuit device is then placed in plasma etcher or reactive ion etcher (RIE) to transfer (by conventional integrated circuit fabrication means) the pattern existing on the amorphous silicon to the Si02 layer. In a plasma etcher using a gas such as CHF3/ a selectivity ratio of silicon
SUBSTITUTESHEET dioxide to silicon equal to 10:1 can be achieved. After suitable etch time, the pattern delineated in the amorphous silicon is transferred into the Si02 layer 10 as shown in
Figure 3. The use of a plasma etcher or RIE allows for the bulk etching of the Si02 rather than an area-by-area etch limited by the area of a laser scan.
After the etching of the Si02, the amorphous silicon 14 can be plasma stripped to remove the amorphous silicon layer
14. This is shown in Figure 4. Alternatively, it may not be necessary to remove the amorphous silicon layer 14 and it may, in fact, be desirable to have it remain for use in later integrated circuit processing.
The invention as described eliminates the need for wet chemistry in all processes and particularly in the use of photolithography. The yield loss during photolithography due to particles, contamination, over and under cutting, and bad exposure are all eliminated.
The process can be used to pattern oxides even over metal regions and is not subject to topology or reflectivity variations existing on the integrated circuit substrate.
This also permits etching metal layers or regions on integrated circuit substrates.
Figure 5 shows this embodiment of the invention. The amorphous silicon layer 14 is deposited over the metallic layer 21 on the substrate 10. In Figure 6 the laser 16 etches the amorphous silicon 14 in the manner of the previous embodiments. In Figure 7 the etched amorphous silicon 14 is then used as a mask to etch the metallic layer 21 by placing it in a blank environment. Then in Figure 8 the amorphous silicon layer may be removed if required or it may be left in place as shown in
Figure 7.
The heat flow into the metal layer 21 of this embodiment, arising from the laser etch of the amorphous silicon layer 14, may cause a loss of the subsequent lasography effect required. This might be avoided by the use of excimer lasers to etch, or other means. Currently, to prevent this heat flow, the preferred embodiment is to
SUBSTITUTE SHEET deposit a layer of silicon dioxide between the metal layer 21 and the amorphous silicon 14, as shown in Figure 9. As shown in Figure 10, laser 16 then will etch a mask in the amorphous silicon 14. The silicon dioxide layer 12 will then be etched through the amorphous silicon mask 14, as shown in Figure 11. Then as shown in Figure 12, the metal layer 21 may be etched through the hard mask provided by the silicon dioxide 12. This is a double masking technique. The etching of the silicon 12 and the metal layer 21 might, in theory, be done in the same chamber with a two-step process, however, it is preferable to etch the Si02 in a separate step from the metal in order to split the etch chemistry and for cleanliness reasons.
After the etching, the amorphous silicon layer 14 may be plasma stripped if required, as shown in Figure 13. Also, the silicon dioxide layer 12 may be removed as shown in Figure 14, if required.
Because the laser can be accurately controlled during the etching of the amorphous silicon, undercutting can be minimized or can be controllably reproduced.
While the present invention has been disclosed in connection with the preferred embodiment thereof, it should be appreciated that other embodiments may be used in keeping with the spirit and scope of the present invention as defined by the appended claims. Examples of variations include the use of the invention to etch various materials and their oxides or nitrides.
SUBSTITUTESHEET

Claims

We Claim:
1. A method of laser etching an oxide or nitride coated substrate comprising the steps of:
(a) depositing an amorphous silicon layer on the substrate;
(b) forming a pattern in the amorphous silicon layer by exposing selected regions of the amorphous silicon layer to laser light in the presence of reactive ions; and (c) etching the substrate in a plasma environment or reactive ion environment using the amorphous silicon as a mask over the oxide or nitride.
2. A method of laser etching a silicon dioxide layer on an integrated circuit device comprising the steps of:
(a) depositing an amorphous silicon layer over the silicon dioxide layer on the integrated circuit device;
(b) forming a pattern in the amorphous silicon layer by exposing selected regions of the amorphous silicon layer to laser light in the presence of reactive ions; and
(c) etching the silicon dioxide layer on the integrated circuit device in a plasma environment or reactive ion environment using the amorphous silicon as a mask over the silicon dioxide.
3. The method of claim 2 wherein the amorphous silicon layer is less than about 2,000 A in thickness.
4. The method of claim 2 wherein the laser used to expose selective regions of the amorphous silicon has a wavelength of 5,145 A.
5. The method of claim 2 wherein the reactive ions are halogen ions.
6. The method of claim 5 wherein the reactive ions are chlorine ions.
7. The method of claim 2 wherein the silicon dioxide is etched in a plasma etchant containing CHF3.
8. A method of laser etching a metallic layer region in an integrated circuit device comprising the steps of:
(a) depositing an amorphous silicon layer over the metallic layer region on the integrated circuit device;
(b) forming a pattern in the amorphous silicon layer by exposing selected regions of the amorphous silicon layer to laser light in the presence of reactive ions, and (c) etching the metallic layer region on the integrated circuit device in a plasma environment or a reactive ion environment using the amorphous silicon as a mask over the metallic layer.
9. A method of laser etching a silicon dioxide layer over a metallic layer region in an integrated circuit device comprising the steps of:
(a) depositing a layer of silicon dioxide over the metallic layer region on the integrated circuit device;
(b) depositing a layer of amorphous silicon over the layer of silicon dioxide that was deposited over the metallic layer region.
(c) forming a pattern in the amorphous silicon layer by exposing selected regions of the amorphous silicon layer to laser light in the presence of reactive ions, and
(d) etching the layer of silicon dioxide that was deposited over the metallic layer region, in a plasma environment or a reactive ion environment using the amorphous silicon as a mask to the layer of silicon dioxide.
10. The method in claim 9, further comprising the step of: (a) etching the metallic layer region on the integrated circuit device in a plasma environment or a reactive ion environment using the etched layer of silicon dioxide as a hard mask over the metallic layer region.
SUBSTITUTESHEET
PCT/US1992/003670 1992-03-10 1992-04-27 Method of laser etching of silicon dioxide WO1993018545A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US84923792A 1992-03-10 1992-03-10
US849,237 1992-03-10

Publications (1)

Publication Number Publication Date
WO1993018545A1 true WO1993018545A1 (en) 1993-09-16

Family

ID=25305375

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1992/003670 WO1993018545A1 (en) 1992-03-10 1992-04-27 Method of laser etching of silicon dioxide

Country Status (2)

Country Link
TW (1) TW217465B (en)
WO (1) WO1993018545A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2329529A4 (en) * 2008-09-19 2017-10-11 Sunpower Corporation Method for fabricating a solar cell using a direct-pattern pin-hole-free masking layer

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60173502A (en) * 1984-02-17 1985-09-06 Nippon Telegr & Teleph Corp <Ntt> Waveguide type optical branching circuit
JPS6153731A (en) * 1984-08-24 1986-03-17 Anritsu Corp Etching method by ultraviolet ray and apparatus for the same
EP0272799A1 (en) * 1986-11-26 1988-06-29 Quick Technologies Ltd. Ablative etch resistant coating for laser personalization of integrated circuits

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60173502A (en) * 1984-02-17 1985-09-06 Nippon Telegr & Teleph Corp <Ntt> Waveguide type optical branching circuit
JPS6153731A (en) * 1984-08-24 1986-03-17 Anritsu Corp Etching method by ultraviolet ray and apparatus for the same
EP0272799A1 (en) * 1986-11-26 1988-06-29 Quick Technologies Ltd. Ablative etch resistant coating for laser personalization of integrated circuits

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PLASMA CHEMISTRY AND PLASMA PROCESSING, Volume 2, No. 1, 1982, COBURN, J., "Plasma Etching", pp. 1-5. *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2329529A4 (en) * 2008-09-19 2017-10-11 Sunpower Corporation Method for fabricating a solar cell using a direct-pattern pin-hole-free masking layer

Also Published As

Publication number Publication date
TW217465B (en) 1993-12-11

Similar Documents

Publication Publication Date Title
US5861233A (en) Pattern forming method by imparting hydrogen atoms and selectively depositing metal film
US5895740A (en) Method of forming contact holes of reduced dimensions by using in-situ formed polymeric sidewall spacers
US4919749A (en) Method for making high resolution silicon shadow masks
JPS63116430A (en) Method of forming mask
TW477007B (en) Method and apparatus for high-resolution in-situ plasma etching of inorganic and metal films
US6074946A (en) Integrated processing for an etch module using a hard mask technique
JPH1041248A (en) Semiconductor device manufacturing method by pattern formation of wafer having non-planar surface
KR100415088B1 (en) method for fabricating semiconductor device
US6027959A (en) Methods for in-situ removal of an anti-reflective coating during a nitride resistor protect etching process
US6066567A (en) Methods for in-situ removal of an anti-reflective coating during an oxide resistor protect etching process
JP2003173951A (en) Method for manufacturing electron beam lithography mask and mask blanks for electron beam lithography
KR100425856B1 (en) Method for etching layer to be etched
US6100157A (en) Formation of alignment mark and structure covering the same
WO1993018545A1 (en) Method of laser etching of silicon dioxide
KR20010003465A (en) method of forming fine pattern of semiconductor device
JP3585039B2 (en) Hole forming method
KR100632422B1 (en) Method of forming a structure in a semiconductor substrate
JPH1145863A (en) Method for implanting ions into substrate
US6037670A (en) Alignment mark and structure covering the same
JPH11186230A (en) Method for manufacturing semiconductor device
JPH08236506A (en) Manufacture of semiconductor device
US6511777B1 (en) Method for manufacturing a phase shift photomask
KR100318272B1 (en) Method for forming fine pattern of semiconductor device
KR100227634B1 (en) Method of fabricating semiconductor device
JP3271185B2 (en) Manufacturing method of antireflection film

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CA JP KR

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LU MC NL SE

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA