WO1993018545A1 - Method of laser etching of silicon dioxide - Google Patents
Method of laser etching of silicon dioxide Download PDFInfo
- Publication number
- WO1993018545A1 WO1993018545A1 PCT/US1992/003670 US9203670W WO9318545A1 WO 1993018545 A1 WO1993018545 A1 WO 1993018545A1 US 9203670 W US9203670 W US 9203670W WO 9318545 A1 WO9318545 A1 WO 9318545A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- amorphous silicon
- silicon dioxide
- integrated circuit
- etching
- Prior art date
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 29
- 235000012239 silicon dioxide Nutrition 0.000 title claims abstract description 27
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 27
- 238000010329 laser etching Methods 0.000 title claims description 8
- 229910021417 amorphous silicon Inorganic materials 0.000 claims abstract description 54
- 238000005530 etching Methods 0.000 claims abstract description 17
- 239000000758 substrate Substances 0.000 claims abstract description 12
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 5
- -1 halogen ions Chemical class 0.000 claims abstract 3
- 238000000151 deposition Methods 0.000 claims description 6
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 claims description 3
- 150000004767 nitrides Chemical class 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims 11
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 230000000873 masking effect Effects 0.000 abstract description 3
- 239000004065 semiconductor Substances 0.000 description 9
- 238000000206 photolithography Methods 0.000 description 7
- 238000000059 patterning Methods 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000011109 contamination Methods 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 2
- 229920002120 photoresistant polymer Polymers 0.000 description 2
- 238000007704 wet chemistry method Methods 0.000 description 2
- 101000873785 Homo sapiens mRNA-decapping enzyme 1A Proteins 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 102100035856 mRNA-decapping enzyme 1A Human genes 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/3213—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
- H01L21/32139—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer using masks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/3065—Plasma etching; Reactive-ion etching
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31144—Etching the insulating layers by chemical or physical means using masks
Definitions
- This invention relates to a method of patterning oxide for the fabrication of integrated circuits using laser pantography.
- the patterning of oxide is one of the most basic and repeated steps in the fabrication of integrated circuit devices particularly in silicon microelectronics.
- Silicon dioxide (Si0 2 ) is often used as a mask against ion implantation or diffusion. It is also used as an isolation layer to define transistor geometries.
- this oxide patterning is done using photolithography techniques.
- Photolithography employs wet chemical processes for coating and developing a photoresist layer. The photolithography process required for each oxide delineation comprises a series of several steps. The photolithography process is a source of contamination and defect generation and often produces a loss of circuit yields.
- the present invention relates to a method of using a laser to provide a method of etching openings in a silicon dioxide (Si0 2 ) pattern on an integrated circuit or other semiconductor element.
- a thin layer, for example, 2,000 A, of amorphous silicon is blanket deposited over the surface area of an integrated circuit or other semiconductor element upon which an oxide pattern is to be delineated.
- a focused laser beam with sufficient power having a wavelength of, for example, 5,145 A as a point heat source and placing the integrated circuit
- the desired pattern is etched in the amorphous silicon.
- the semiconductor substrate is then placed in a plasma etcher or reactive ion etcher (RIE) .
- RIE reactive ion etcher
- a plasma etcher using a gas, such as CHF 3 which has a selectivity ratio of Si0 2 :Si equal to 10:1
- the laser etched pattern in the amorphous silicon can be transferred to the silicon dioxide.
- the amorphous silicon layer can be removed, if desired.
- One advantage of the present invention is that all wet chemical steps may be eliminated during etching of the oxide when fabricating integrated circuits.
- the use of the present invention is easily adapted to automation where standard machine interface ("SMIF") boxes for transferring substrates between machines are used. Therefore, clean room requirements are reduced or eliminated, providing for a truly all dry process for the fabrication of integrated circuits.
- SMIF standard machine interface
- Figure 1 illustrates a first step in accordance with a preferred embodiment of the present invention
- Figure 2 shows the second step in accordance with a preferred embodiment of the present invention
- Figure 3 illustrates the third step in accordance with a preferred embodiment
- Figure 4 shows the resulting step in accordance with a preferred embodiment of the present invention.
- Figures 5, 6, 7 and 8 show various steps of etching using the invention to etch a metallic layer with an amorphous silicon mask.
- Figures 9, 10, 11, 12 and 13 show an alternative preferred embodiment of the invention which etches a metallic layer using both an amorphous silicon mask and a silicon dioxide etched hard mask in a double masking technique.
- DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT The Figures, by way of example, illustrate a preferred embodiment of the present invention. It should be appreciated that the oxide patterning process of the present invention may be used in connection with any type of patterning of silicon dioxide on an integrated circuit or other semiconductor element. By way of example, the invention may be used in forming the implant mask openings on an integrated circuit.
- the semiconductor substrate 10 has a thin film of Si0 2 12 which has been either grown or deposited on the substrate.
- a blanket deposition of amorphous silicon 14 is made over the thin film of Si0 2 12. It is preferable that the amorphous silicon layer 14 be less than about 2,000 A in thickness.
- a focused laser beam illustrated by the arrows 16 in Figure 2 and having a wavelength of, for example, 5,145 A, is used as a point heat source.
- the semiconductor substrate 10 having the thin film layer of Si0 2 12 and amorphous silicon layer 14 is placed in a chamber having a gaseous environment of CLj or HCl or other halogen containing gas.
- the laser beam 16 is focused on the amorphous silicon 14 and traversed along the surface of the amorphous silicon 14 in the form of the desired Si0 2 pattern openings, and by doing so, the thin amorphous silicon layer 14 is etched away.
- the laser's light and heat interact with the halogen gas environment to loosen the gas's ionic covalent bond.
- the resulting etchant gas turns the amorphous silicon layer 14 into a gas at the point of contact of the laser beam on the amorphous silicon.
- the gaseous compounds are then pumped out of the pantography chamber. Because the reaction chamber remains at room temperature, process-gas contamination of the chamber or the workplace is virtually eliminated.
- the integrated circuit device After laser etching the amorphous silicon, the integrated circuit device is then placed in plasma etcher or reactive ion etcher (RIE) to transfer (by conventional integrated circuit fabrication means) the pattern existing on the amorphous silicon to the Si0 2 layer.
- plasma etcher using a gas such as CHF 3/ a selectivity ratio of silicon
- the amorphous silicon 14 can be plasma stripped to remove the amorphous silicon layer
- the invention as described eliminates the need for wet chemistry in all processes and particularly in the use of photolithography.
- the yield loss during photolithography due to particles, contamination, over and under cutting, and bad exposure are all eliminated.
- the process can be used to pattern oxides even over metal regions and is not subject to topology or reflectivity variations existing on the integrated circuit substrate.
- Figure 5 shows this embodiment of the invention.
- the amorphous silicon layer 14 is deposited over the metallic layer 21 on the substrate 10.
- the laser 16 etches the amorphous silicon 14 in the manner of the previous embodiments.
- the etched amorphous silicon 14 is then used as a mask to etch the metallic layer 21 by placing it in a blank environment.
- the amorphous silicon layer may be removed if required or it may be left in place as shown in
- the heat flow into the metal layer 21 of this embodiment may cause a loss of the subsequent lasography effect required. This might be avoided by the use of excimer lasers to etch, or other means.
- the preferred embodiment is to
- SUBSTITUTE SHEET deposit a layer of silicon dioxide between the metal layer 21 and the amorphous silicon 14, as shown in Figure 9.
- laser 16 then will etch a mask in the amorphous silicon 14.
- the silicon dioxide layer 12 will then be etched through the amorphous silicon mask 14, as shown in Figure 11.
- the metal layer 21 may be etched through the hard mask provided by the silicon dioxide 12. This is a double masking technique.
- the etching of the silicon 12 and the metal layer 21 might, in theory, be done in the same chamber with a two-step process, however, it is preferable to etch the Si0 2 in a separate step from the metal in order to split the etch chemistry and for cleanliness reasons.
- the amorphous silicon layer 14 may be plasma stripped if required, as shown in Figure 13. Also, the silicon dioxide layer 12 may be removed as shown in Figure 14, if required.
- the laser can be accurately controlled during the etching of the amorphous silicon, undercutting can be minimized or can be controllably reproduced.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Plasma & Fusion (AREA)
- Drying Of Semiconductors (AREA)
Abstract
A method of using a laser (16) to etch patterns in a thin layer of amorphous silicon (14) which is used as a mask for the etching of a layer of silicon dioxide (12) in integrated circuit fabrication. The laser is used to etch the amorphous silicon in the presence of halogen ions. Subsequently, the amorphous silicon is used as a mask to plasma etch the silicon dioxide. Alternate embodiments of the method etch a metal region on a substrate, or a silicon dioxide layer on a metal region, both using an etched amorphous silicon mask. An alternate embodiment uses a double masking technique to etch an amorphous silicon mask, which is used to etch a silicon dioxide hard mask, which is used to etch a metal region.
Description
METHOD OF LASER ETCHING OF SILICON DIOXIDE
This invention relates to a method of patterning oxide for the fabrication of integrated circuits using laser pantography. The patterning of oxide is one of the most basic and repeated steps in the fabrication of integrated circuit devices particularly in silicon microelectronics. Silicon dioxide (Si02) is often used as a mask against ion implantation or diffusion. It is also used as an isolation layer to define transistor geometries. Conventionally, this oxide patterning is done using photolithography techniques. Photolithography employs wet chemical processes for coating and developing a photoresist layer. The photolithography process required for each oxide delineation comprises a series of several steps. The photolithography process is a source of contamination and defect generation and often produces a loss of circuit yields. Also inherent in the photolithography process is the need to have proper exposure and focus on a photoresist layer on the surface of the semiconductor element to be patterned. Focusing and exposure becomes difficult as the topology of the integrated circuit varies and is particularly difficult over reflective metal regions of the integrated circuit device.
Accordingly, there is a need in the art for an improved method for etching silicon dioxide layers on an integrated circuit or other semiconductor element.
SHORT STATEMENT OF THE INVENTION
The present invention relates to a method of using a laser to provide a method of etching openings in a silicon dioxide (Si02) pattern on an integrated circuit or other semiconductor element. In accordance with the invention, a thin layer, for example, 2,000 A, of amorphous silicon is blanket deposited over the surface area of an integrated circuit or other semiconductor element upon which an oxide pattern is to be delineated. Using a focused laser beam with sufficient power having a wavelength of, for example, 5,145 A as a point heat source and placing the integrated circuit
SUBSTITUTESHEET
or semiconductor element in a gaseous environment such as Cl2 or HC1 or other halogen ion, the desired pattern is etched in the amorphous silicon. After laser etching the amorphous silicon, the semiconductor substrate is then placed in a plasma etcher or reactive ion etcher (RIE) . In a plasma etcher using a gas, such as CHF3, which has a selectivity ratio of Si02:Si equal to 10:1, the laser etched pattern in the amorphous silicon can be transferred to the silicon dioxide. After the etching of the Si02, the amorphous silicon layer can be removed, if desired.
One advantage of the present invention is that all wet chemical steps may be eliminated during etching of the oxide when fabricating integrated circuits. The use of the present invention is easily adapted to automation where standard machine interface ("SMIF") boxes for transferring substrates between machines are used. Therefore, clean room requirements are reduced or eliminated, providing for a truly all dry process for the fabrication of integrated circuits.
BRIEF DESCRIPTION OF THE DRAWINGS Other improvements, advantages and features of the present invention will become more fully apparent from the following detailed description of the preferred embodiments, the appended claims and the accompanying drawings in which:
Figure 1 illustrates a first step in accordance with a preferred embodiment of the present invention;
Figure 2 shows the second step in accordance with a preferred embodiment of the present invention;
Figure 3 illustrates the third step in accordance with a preferred embodiment; Figure 4 shows the resulting step in accordance with a preferred embodiment of the present invention.
Figures 5, 6, 7 and 8 show various steps of etching using the invention to etch a metallic layer with an amorphous silicon mask. Figures 9, 10, 11, 12 and 13 show an alternative preferred embodiment of the invention which etches a metallic layer using both an amorphous silicon mask and a silicon dioxide etched hard mask in a double masking technique.
DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT The Figures, by way of example, illustrate a preferred embodiment of the present invention. It should be appreciated that the oxide patterning process of the present invention may be used in connection with any type of patterning of silicon dioxide on an integrated circuit or other semiconductor element. By way of example, the invention may be used in forming the implant mask openings on an integrated circuit. The semiconductor substrate 10 has a thin film of Si02 12 which has been either grown or deposited on the substrate. A blanket deposition of amorphous silicon 14 is made over the thin film of Si02 12. It is preferable that the amorphous silicon layer 14 be less than about 2,000 A in thickness. A focused laser beam illustrated by the arrows 16 in Figure 2 and having a wavelength of, for example, 5,145 A, is used as a point heat source. The semiconductor substrate 10 having the thin film layer of Si02 12 and amorphous silicon layer 14 is placed in a chamber having a gaseous environment of CLj or HCl or other halogen containing gas. The laser beam 16 is focused on the amorphous silicon 14 and traversed along the surface of the amorphous silicon 14 in the form of the desired Si02 pattern openings, and by doing so, the thin amorphous silicon layer 14 is etched away. The laser's light and heat interact with the halogen gas environment to loosen the gas's ionic covalent bond. The resulting etchant gas turns the amorphous silicon layer 14 into a gas at the point of contact of the laser beam on the amorphous silicon. The gaseous compounds are then pumped out of the pantography chamber. Because the reaction chamber remains at room temperature, process-gas contamination of the chamber or the workplace is virtually eliminated.
After laser etching the amorphous silicon, the integrated circuit device is then placed in plasma etcher or reactive ion etcher (RIE) to transfer (by conventional integrated circuit fabrication means) the pattern existing on the amorphous silicon to the Si02 layer. In a plasma etcher using a gas such as CHF3/ a selectivity ratio of silicon
SUBSTITUTESHEET
dioxide to silicon equal to 10:1 can be achieved. After suitable etch time, the pattern delineated in the amorphous silicon is transferred into the Si02 layer 10 as shown in
Figure 3. The use of a plasma etcher or RIE allows for the bulk etching of the Si02 rather than an area-by-area etch limited by the area of a laser scan.
After the etching of the Si02, the amorphous silicon 14 can be plasma stripped to remove the amorphous silicon layer
14. This is shown in Figure 4. Alternatively, it may not be necessary to remove the amorphous silicon layer 14 and it may, in fact, be desirable to have it remain for use in later integrated circuit processing.
The invention as described eliminates the need for wet chemistry in all processes and particularly in the use of photolithography. The yield loss during photolithography due to particles, contamination, over and under cutting, and bad exposure are all eliminated.
The process can be used to pattern oxides even over metal regions and is not subject to topology or reflectivity variations existing on the integrated circuit substrate.
This also permits etching metal layers or regions on integrated circuit substrates.
Figure 5 shows this embodiment of the invention. The amorphous silicon layer 14 is deposited over the metallic layer 21 on the substrate 10. In Figure 6 the laser 16 etches the amorphous silicon 14 in the manner of the previous embodiments. In Figure 7 the etched amorphous silicon 14 is then used as a mask to etch the metallic layer 21 by placing it in a blank environment. Then in Figure 8 the amorphous silicon layer may be removed if required or it may be left in place as shown in
Figure 7.
The heat flow into the metal layer 21 of this embodiment, arising from the laser etch of the amorphous silicon layer 14, may cause a loss of the subsequent lasography effect required. This might be avoided by the use of excimer lasers to etch, or other means. Currently, to prevent this heat flow, the preferred embodiment is to
SUBSTITUTE SHEET
deposit a layer of silicon dioxide between the metal layer 21 and the amorphous silicon 14, as shown in Figure 9. As shown in Figure 10, laser 16 then will etch a mask in the amorphous silicon 14. The silicon dioxide layer 12 will then be etched through the amorphous silicon mask 14, as shown in Figure 11. Then as shown in Figure 12, the metal layer 21 may be etched through the hard mask provided by the silicon dioxide 12. This is a double masking technique. The etching of the silicon 12 and the metal layer 21 might, in theory, be done in the same chamber with a two-step process, however, it is preferable to etch the Si02 in a separate step from the metal in order to split the etch chemistry and for cleanliness reasons.
After the etching, the amorphous silicon layer 14 may be plasma stripped if required, as shown in Figure 13. Also, the silicon dioxide layer 12 may be removed as shown in Figure 14, if required.
Because the laser can be accurately controlled during the etching of the amorphous silicon, undercutting can be minimized or can be controllably reproduced.
While the present invention has been disclosed in connection with the preferred embodiment thereof, it should be appreciated that other embodiments may be used in keeping with the spirit and scope of the present invention as defined by the appended claims. Examples of variations include the use of the invention to etch various materials and their oxides or nitrides.
SUBSTITUTESHEET
Claims
1. A method of laser etching an oxide or nitride coated substrate comprising the steps of:
(a) depositing an amorphous silicon layer on the substrate;
(b) forming a pattern in the amorphous silicon layer by exposing selected regions of the amorphous silicon layer to laser light in the presence of reactive ions; and (c) etching the substrate in a plasma environment or reactive ion environment using the amorphous silicon as a mask over the oxide or nitride.
2. A method of laser etching a silicon dioxide layer on an integrated circuit device comprising the steps of:
(a) depositing an amorphous silicon layer over the silicon dioxide layer on the integrated circuit device;
(b) forming a pattern in the amorphous silicon layer by exposing selected regions of the amorphous silicon layer to laser light in the presence of reactive ions; and
(c) etching the silicon dioxide layer on the integrated circuit device in a plasma environment or reactive ion environment using the amorphous silicon as a mask over the silicon dioxide.
3. The method of claim 2 wherein the amorphous silicon layer is less than about 2,000 A in thickness.
4. The method of claim 2 wherein the laser used to expose selective regions of the amorphous silicon has a wavelength of 5,145 A.
5. The method of claim 2 wherein the reactive ions are halogen ions.
6. The method of claim 5 wherein the reactive ions are chlorine ions.
7. The method of claim 2 wherein the silicon dioxide is etched in a plasma etchant containing CHF3.
8. A method of laser etching a metallic layer region in an integrated circuit device comprising the steps of:
(a) depositing an amorphous silicon layer over the metallic layer region on the integrated circuit device;
(b) forming a pattern in the amorphous silicon layer by exposing selected regions of the amorphous silicon layer to laser light in the presence of reactive ions, and (c) etching the metallic layer region on the integrated circuit device in a plasma environment or a reactive ion environment using the amorphous silicon as a mask over the metallic layer.
9. A method of laser etching a silicon dioxide layer over a metallic layer region in an integrated circuit device comprising the steps of:
(a) depositing a layer of silicon dioxide over the metallic layer region on the integrated circuit device;
(b) depositing a layer of amorphous silicon over the layer of silicon dioxide that was deposited over the metallic layer region.
(c) forming a pattern in the amorphous silicon layer by exposing selected regions of the amorphous silicon layer to laser light in the presence of reactive ions, and
(d) etching the layer of silicon dioxide that was deposited over the metallic layer region, in a plasma environment or a reactive ion environment using the amorphous silicon as a mask to the layer of silicon dioxide.
10. The method in claim 9, further comprising the step of: (a) etching the metallic layer region on the integrated circuit device in a plasma environment or a reactive ion environment using the etched layer of silicon dioxide as a hard mask over the metallic layer region.
SUBSTITUTESHEET
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US84923792A | 1992-03-10 | 1992-03-10 | |
US849,237 | 1992-03-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1993018545A1 true WO1993018545A1 (en) | 1993-09-16 |
Family
ID=25305375
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1992/003670 WO1993018545A1 (en) | 1992-03-10 | 1992-04-27 | Method of laser etching of silicon dioxide |
Country Status (2)
Country | Link |
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TW (1) | TW217465B (en) |
WO (1) | WO1993018545A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2329529A4 (en) * | 2008-09-19 | 2017-10-11 | Sunpower Corporation | Method for fabricating a solar cell using a direct-pattern pin-hole-free masking layer |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60173502A (en) * | 1984-02-17 | 1985-09-06 | Nippon Telegr & Teleph Corp <Ntt> | Waveguide type optical branching circuit |
JPS6153731A (en) * | 1984-08-24 | 1986-03-17 | Anritsu Corp | Etching method by ultraviolet ray and apparatus for the same |
EP0272799A1 (en) * | 1986-11-26 | 1988-06-29 | Quick Technologies Ltd. | Ablative etch resistant coating for laser personalization of integrated circuits |
-
1992
- 1992-04-27 WO PCT/US1992/003670 patent/WO1993018545A1/en active Application Filing
-
1993
- 1993-03-25 TW TW82102266A patent/TW217465B/zh active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60173502A (en) * | 1984-02-17 | 1985-09-06 | Nippon Telegr & Teleph Corp <Ntt> | Waveguide type optical branching circuit |
JPS6153731A (en) * | 1984-08-24 | 1986-03-17 | Anritsu Corp | Etching method by ultraviolet ray and apparatus for the same |
EP0272799A1 (en) * | 1986-11-26 | 1988-06-29 | Quick Technologies Ltd. | Ablative etch resistant coating for laser personalization of integrated circuits |
Non-Patent Citations (1)
Title |
---|
PLASMA CHEMISTRY AND PLASMA PROCESSING, Volume 2, No. 1, 1982, COBURN, J., "Plasma Etching", pp. 1-5. * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2329529A4 (en) * | 2008-09-19 | 2017-10-11 | Sunpower Corporation | Method for fabricating a solar cell using a direct-pattern pin-hole-free masking layer |
Also Published As
Publication number | Publication date |
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TW217465B (en) | 1993-12-11 |
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