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WO1994011473A1 - Compositions detergentes liquides stables empechant le transfert des couleurs - Google Patents

Compositions detergentes liquides stables empechant le transfert des couleurs Download PDF

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Publication number
WO1994011473A1
WO1994011473A1 PCT/US1993/010542 US9310542W WO9411473A1 WO 1994011473 A1 WO1994011473 A1 WO 1994011473A1 US 9310542 W US9310542 W US 9310542W WO 9411473 A1 WO9411473 A1 WO 9411473A1
Authority
WO
WIPO (PCT)
Prior art keywords
dye transfer
polyamine
brightener
oxide
group
Prior art date
Application number
PCT/US1993/010542
Other languages
English (en)
Inventor
Abdennaceur Fredj
Patrick Willy M. Goethals
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to PL93308760A priority Critical patent/PL175677B1/pl
Priority to JP6512172A priority patent/JPH08503246A/ja
Priority to CA002148808A priority patent/CA2148808C/fr
Priority to AU55904/94A priority patent/AU670851B2/en
Priority to KR1019950701775A priority patent/KR950704458A/ko
Publication of WO1994011473A1 publication Critical patent/WO1994011473A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest

Definitions

  • the present invention relates to stable liquid detergent compositions inhibiting dye transfer
  • Brighteners also known as fluorescent whitening agents, are commonly used in laundry detergents. Brighteners deposit onto fabrics where they absorb ultraviolet radiant energy and reemit it as blue light.
  • Copending EP Patent Application 92202168.8 describes dye transfer inhibiting compostions comprising polyamine N-oxides containing polymers.
  • a dye transfer inhibiting composition comprising a brightener is provided which has improved stability upon storage.
  • the present invention relates to inhibiting dye transfer compositions comprising
  • compositions of the present invention comprise as essential elements
  • the polyamine N-oxide polymers contain units having the following structure formula : P
  • P is a polymerisable unit, whereto the N-O group can be attached to or wherein the N-O group forms part of the polymerisable unit or a combination of both.
  • A is NC, CO, C, -0-,-S-, -N- x is or 0 or 1;
  • R are aliphatic, ethoxylated aliphatics, aromatic, heterocyclic or alicyclic groups or any combination thereof whereto the nitrogen of the N-O group can be attached or wherein the nitrogen of the N-O group is part of these groups.
  • the N-O group can be represented by the following general structures :
  • Rl, R2, R3 are aliphatic groups, aromatic, heterorocyclic or alicyclic groups or combinations thereof, x or/and y or/and z is 0 or 1 and wherein the nitrogen of the» N-O group can be attached or wherein the nitrogen of the N-O group forms part of these groups.
  • the N-O group can be part of the polymerisable unit (P) or can be attached to the polymeric backbone or a combination of both.
  • Suitable polyamine N-oxides wherein the N-O group forms part of the polymerisable unit comprise polyamine N-oxides wherein R is selected from aliphatic, aromatic, alicyclic or heterocyclic groups.
  • polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group forms part of the R-group.
  • Preferred polyamine N-oxides are those wherein R is a heterocyclic group such as pyrridine, pyrrole, imidazole, pyrrolidine, piperidine and derivatives thereof.
  • Another class of said polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group is attached to the R-group.
  • polyamine N-oxides are the polyamine oxides whereto the N-O group is attached to the polymerisable unit.
  • Preferred class of these polyamine N-oxides are the polyamine N-oxides having the general formula (I) wherein R is an aromatic, heterocyclic or alicyclic groups wherein the nitrogen of the N-O functional group is part of said R group.
  • polyamine N-oxides are the polyamine oxides having the general formula (I) wherein R are aromatic, heterocyclic or alicyclic groups wherein the nitrogen of the N-O functional group is attached to said R groups.
  • polyamine oxides wherein R groups can be aromatic such as phenyl.
  • Any polymer backbone can be *used as long as the amine oxide polymer formed is water-soluble and has dye transfer inhibiting properties.
  • suitable polymeric backbones are polyvinyls, polyalkylenes, polyesters, polyethers, polyamide, polyimides, polyacrylates and mixtures thereof.
  • the a ine N-oxide polymers of the present invention typically have a ratio of amine to the amine N-oxide of 10 : 1 to 1: 1000000.
  • the amount of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerization or by appropriate degree of N- oxidation .
  • the ratio of amine to amine N-oxide is from 3:1 to 1:1000000.
  • the polymers of the present invention actually encompass random or block copolymers where one monomer type is an amine N-oxide and the other monomer type is an N-oxide or not.
  • the amine oxide unit of the polyamine N-oxides has a pKa ⁇ 10, preferably pKa ⁇ 1 , more preferred PKa ⁇ 6.
  • the polyamine oxides can be obtained in almost any degree of polymerisation. The degree of polymerisation is not critical provided the material has the desired water-solubility and dye-suspending power.
  • the average molecular weight is within the range of 500 to 1000,000 ; more preferred 1000 to 500,000 ; most preferred 5000 to 100,000.
  • the polyamine N-oxides of the present invention are typically present from 0.01 to 10% , more preferably from 0.05 to 1%, most preferred from 0.05 to 0.5 % by weight of the dye transfer inhibiting composition.
  • Preferred brighteners according to the present invention are hydrophobic brighteners which have the general formula:
  • R ] _, R2 R3 and R represent, selected independently, anilino, cyclohexylamino, piperazino, phenylenediamino, toluenediamino, morpholino, aminophenol, N-2-hydroxyethyl-N- methyla ino, N-2-Bis-hydroxyethyl.
  • Suitable brightener species include any combination of the possible R3 . -4 moieties.
  • Examples of preferred brightener species are the tetra-anilino, tetra-piperazino, tetra- cyclohexylamino and combinations thereof such as for example the di-anilinodipiperazino; and the dianilino- dicyclohexylamino species.
  • a preferred brightener system in the context of this invention contains at least 40% (by reference to the total amount of the detergent brightener) of the specific hydrophobic brightener referred to hereinbefore in combination with a conventional detergent brightener, e.g., a di-sulfonated dianilino, dimorpholino stilbene brightener.
  • Non-aromatic anionic surfactants suitable for the present invention are generally disclosed in US-A-3, 929, 678.
  • Classes of non-aromatic anionic surfactants include the classes are :
  • Ordinary alkali metal soaps such as the sodium, potassium, ammonium and alkylolammonium salts of higher fatty acids containing from 8 to 24 carbon atoms, preferably from 10 to 20 carbon atoms.
  • Water-soluble salts preferably the alkali metal, ammonium and alkylolammonium salts, of organic sulfuric reaction products having in their molecular structure an alkyl group containing from 10 to 20 carbon atoms and a sulfonic acid or sulfuric acid ester group.
  • anionic surfactants are the sodium and potassium alkylsulfates, especially those obtained by sulfating the higher alcohols (C8-C18 carbon atoms) such as those produced by reducing the glycerides of tallow or coconut oil; in straight chain or branched configuration.
  • anionic surfactants suitable for the present invention are the alkyl polyethoxylate sulfates, particulary those in which the alkyl group contains from 10 to 22, preferably from 12 to 18 carbon atoms, and wherein the polyethoxylate chain contains from 1 to 15 ethoxylate moieties.
  • anionic surfactants suitable for the present invention include sodium alkyl glyceryl ether sulfonates, especially those ethers of higher alcohols derived from tallow and coconut oil; sodium coconut oil fatty acid monoglyceride sulfonates and sulfates; sodium or potassium salts of alkyl ethylene oxide ether sulfates containing 1 to 10 units of ethylene oxide per molecule and wherein the alkyl group contains from 10 to 20 carbon atoms.
  • Mixtures of anionic surfactants are particularly suitable herein, especially mixtures of sulphonate and sulphate surfactants in a weight ratio of from 5:1 to 1:2, preferably from 3:1 to 2:3, more preferably from 3:1 to 1:1.
  • Preferred sulphonates include alpha-sulphonated methyl fatty acid esters in which the fatty acid is derived from a Ci2 ⁇ c 18 fa ty source preferably from a C ⁇ g-C_g fatty source. In each instance the cation is an alkali metal, preferably sodium.
  • Preferred sulphate surfactants are alkyl sulphates having from 12 to 18 carbon atoms in the alkyl radical, optionally in admixture with ethoxy sulphates having from 10 to 20, preferably 10 to 16 carbon atoms in the alkyl radical and an average degree of ethoxylation of 1 to 6.
  • alkyl sulphates examples are tallow alkyl sulphate, coconut alkyl sulphate, and c 14-15 alkyl sulphates.
  • the cation in each instance is again an alkali metal cation, preferably sodium.
  • a liquid detergent composition comprising the dye transfer inhibiting composition mixed with detergent ingredients.
  • a wide range of surfactants can be used in the detergent composition of the present invention.
  • One class of nonionic surfactants useful in the present invention are condensates of ethylene oxide with a hydrophobic moiety to provide a surfactant having an average hydrophilic- lipophilic balance (HLB) in the range from 8 to 17, preferably from 9.5 to 13.5, more preferably from 10 to 12.5.
  • HLB hydrophilic- lipophilic balance
  • the hydrophobic (lipophilic) moiety may be aliphatic or aromatic in nature and the length of the polyoxyethylene group which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
  • Especially preferred nonionic surfactants of this type are the C9-C15 primary alcohol ethoxylates containing 3-8 moles of ethylene oxide per mole of alcohol, particularly the C1 -C15 primary alcohols containing 6-8 moles of ethylene oxide per mole of alcohol and the C]_2" c 14 primary alcohols containing 3- 5 moles of ethylene oxide per mole of alcohol.
  • Another class of nonionic surfactants comprises alkyl polyglucoside compounds of general formula
  • Z is a moiety derived from glucose; R is a saturated hydrophobic alkyl group that contains from 12 to 18 carbon atoms; t is from 0 to 10 and n is 2 or 3; x is from 1.3 to 4, the compounds including less than 10% unreacted fatty alcohol and less than 50% short chain alkyl polyglucosides.
  • Compounds of this type and their use in detergent are disclosed in EP-B 0 070 077, 0 075 996 and 0 094 118.
  • nonionic surfactants are poly hydroxy fatty acid amide surfactants of the formula
  • R-- is H, or R ⁇ is C ⁇ - hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl or a mixture thereof
  • R 2 is C5-.31 hydrocarbyl
  • Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative thereof.
  • R 1 is methyl
  • R 2 is a straight C ⁇ _ ⁇ __ ⁇ _5 alkyl or alkenyl chain such as coconut alkyl or mixtures thereof
  • Z is derived from a reducing sugar such as glucose, fructose, maltose, lactose, in a reductive amination reaction.
  • compositions according to the present invention may further comprise a builder system.
  • a builder system Any conventional builder system is suitable for use herein including aluminosilicate materials, silicates, polycarboxylates and fatty acids, materials such as ethylenediamine tetraacetate, metal ion sequestrants such as aminopolyphosphonates, particularly ethylenediamine tetramethylene phosphonic acid and diethylene triamine pentamethylenephosphonic acid.
  • phosphate builders can also be used herein.
  • Suitable builders can be an inorganic ion exchange material, commonly an inorganic hydrated aluminosilicate material, more particularly a hydrated synthetic zeolite such as hydrated zeolite A, X, B or HS.
  • SKS-6 is a crystalline layered silicate consisting of sodium silicate (Na2Si2 ⁇ 5) .
  • Suitable polycarboxylates builders for use herein include citric acid, preferably in the form of a water-soluble salt, derivatives of succinic acid of the formula R- CH(COOH)CH2 (COOH) wherein R is C10-20 alkyl or alkenyl, preferably C12-16, or wherein R can be substituted with hydroxyl, sulfo sulfoxyl or sulfone substituents.
  • lauryl succinate examples include lauryl succinate , myristyl succinate, palmityl succinate2-dodecenylsuccinate, 2-tetradecenyl succinate.
  • Succinate builders are preferably used in the form of their water-soluble salts, including sodium, potassium, ammonium and alkanolammonium salts.
  • polycarboxylates are oxodisuccinates and mixtures of tartrate monosuccinic and tartrate disuccinic acid such as described in US 4,663,071.
  • suitable 'fatty acid builders for use herein are saturated or unsaturated C10- 18 fatty acids, as well as the corresponding soaps.
  • Preferred saturated species have from 12 to 16 carbon atoms in the alkyl chain.
  • the preferred unsaturated fatty acid is oleic acid.
  • Another preferred builder system for liquid compositions is based on dodecenyl succinic acid.
  • Suitable water-soluble organic salts are the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms.
  • Polymers of this type are disclosed in GB-A-1, 596, 756.
  • Examples of such salts are polyacrylates of MW 2000-5000 and their copolymers with aleic anhydride, such copolymers having a molecular weight of from 20,000 to 70,000, especially about 40,000.
  • Detergency builder salts are normally included in amounts of from 10% to 80% by weight of the composition preferably from 20% to 70% and most usually from 30% to 60% by weight.
  • detergent compositions may be employed, such as enzymes and stabilizers or activators therefore, soil-suspending agents soil-release agents, optical brighteners, abrasives, bactericides, tarnish inhibitors, coloring agents, and perfumes.
  • enzymes and stabilizers or activators therefore, soil-suspending agents soil-release agents, optical brighteners, abrasives, bactericides, tarnish inhibitors, coloring agents, and perfumes.
  • enzymes and stabilizers or activators therefore, soil-suspending agents soil-release agents, optical brighteners, abrasives, bactericides, tarnish inhibitors, coloring agents, and perfumes.
  • enzyme technologies which also provide a type of color care benefit. Examples are cellulase for color maintenance/ rejuvenation.
  • Other examples are the polymers disclosed in EP 92870017.8 filed January 31,1992 and enzyme oxidation scavengers disclosed in EP 92870018.6 filed January 31, 1992.
  • These components should preferably be chosen such that they are compatible with the bleach component of the composition.
  • liquid compositions according to the present invention can also be in "concentrated form"; in such case, the liquid detergent compositions according to the present invention will contain a lower amount of water, compared to conventional liquid detergents.
  • the stability of the brightener and polyamine N- oxide containing polymer incorporated in liquid detergent compositions were compared in the absence and presence of non- aromatic anionic surfactants. More in particular, the stability of polyamine N-oxide polymer/brightener was determined in the absence of ethoxylated surfactant and in the presence of ethoxylated surfactant.
  • DC 3421 is a silicone oil commercially available from Dow Corning.
  • (2) is a silicone glycol emulsifier available from Dow Corning.
  • Liquid detergent compositions according to the present invention containing the brightener/polyamine N-oxide/non- aromatic anionic surfactant system have a translucent appearance.
  • the brightener starts to bind with the polyamine N-oxide containing polymer resulting in a complex, which in turn flocculates and changes the visual appearance of the bulk solution from translucent to transparent.
  • the brightener remains homogeneously dispersed in the liquid, resulting in a translucent liquid even after long periods of storage.
  • Liquid detergent compositions containing the brightener/polyvinylpyrrolidone/non-aromatic anionic surfactant system have a transparent appearance both in the presence or abscense of non-aromatic anionic surfactant.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

Compositions empêchant le transfert des couleurs, renfermant: (a) de 0,01 % à 5 % d'un polymère de N-oxyde de polyamine; (b) de 0,01 % à 1 % d'agent azurant; (c) de 5 % à 30 % d'un tensioactif anionique non aromatique.
PCT/US1993/010542 1992-11-06 1993-11-03 Compositions detergentes liquides stables empechant le transfert des couleurs WO1994011473A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
PL93308760A PL175677B1 (pl) 1992-11-06 1993-11-03 Ciekła kompozycja inhibitująca przenoszenie barwnika
JP6512172A JPH08503246A (ja) 1992-11-06 1993-11-03 染料移りを防止する安定な液体洗剤組成物
CA002148808A CA2148808C (fr) 1992-11-06 1993-11-03 Compositions liquides detergentes stables, empechant le transfert de colorant
AU55904/94A AU670851B2 (en) 1992-11-06 1993-11-03 Stable liquid detergent compositions inhibiting dye transfer
KR1019950701775A KR950704458A (ko) 1992-11-06 1993-11-03 이염을 억제하는 안정한 액체 세제 조성물(Stable liquid detergent compositions inhibiting dye transfer)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP92870182A EP0596185A1 (fr) 1992-11-06 1992-11-06 Détergents liquides stables inhibant le transfert de couleur
EP92870182.0 1992-11-06

Publications (1)

Publication Number Publication Date
WO1994011473A1 true WO1994011473A1 (fr) 1994-05-26

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Application Number Title Priority Date Filing Date
PCT/US1993/010542 WO1994011473A1 (fr) 1992-11-06 1993-11-03 Compositions detergentes liquides stables empechant le transfert des couleurs

Country Status (11)

Country Link
EP (1) EP0596185A1 (fr)
JP (1) JPH08503246A (fr)
KR (1) KR950704458A (fr)
CN (1) CN1041840C (fr)
AU (1) AU670851B2 (fr)
CA (1) CA2148808C (fr)
CZ (1) CZ116595A3 (fr)
HU (1) HUT71963A (fr)
MX (1) MX9306971A (fr)
PL (1) PL175677B1 (fr)
WO (1) WO1994011473A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995027038A1 (fr) * 1994-03-30 1995-10-12 The Procter & Gamble Company Pains de detergent a lessive a blanchiment ameliore et inhibition du transfert des colorants
US5597795A (en) * 1992-10-27 1997-01-28 The Procter & Gamble Company Detergent compositions inhibiting dye transfer
EP0786517A1 (fr) 1996-01-25 1997-07-30 Unilever N.V. Composition détergente
US5804543A (en) * 1994-10-11 1998-09-08 The Procter & Gamble Company Detergent compositions with optimized surfactant systems to provide dye transfer inhibition benefits

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10353310A1 (de) * 2003-11-10 2005-06-09 Maier, Ursula, Dipl.-Ing. Verwendung einer Lösung mit mindestens einem nichtionischen Tensid
DE102007037430A1 (de) * 2007-08-08 2009-02-12 Henkel Ag & Co. Kgaa Farbschützendes Wasch- oder Reinigungsmittel mit optischem Aufheller
JP5396707B2 (ja) * 2007-11-07 2014-01-22 ライオンハイジーン株式会社 洗浄剤組成物
EP2964740B1 (fr) * 2013-03-05 2017-10-04 The Procter and Gamble Company Compositions comprenat des combinaisons de tensio-actifs dérivés d'amides de sucres
DE102013205079A1 (de) 2013-03-22 2014-09-25 Henkel Ag & Co. Kgaa Farbschützendes Wasch- oder Reinigungsmittel mit optischem Aufheller
MX2016009402A (es) 2014-01-20 2016-09-16 Procter & Gamble Premezcla de abrillantador fluorescente.
CN105907490A (zh) * 2016-05-17 2016-08-31 河南工程学院 一种酸性护色洗涤剂组合物

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US3929678A (en) * 1974-08-01 1975-12-30 Procter & Gamble Detergent composition having enhanced particulate soil removal performance
US4123376A (en) * 1973-08-24 1978-10-31 Colgate-Palmolive Company Peroxymonosulfate-base bleaching and bleaching detergent compositions
US4146496A (en) * 1977-05-18 1979-03-27 Colgate-Palmolive Company Peroxy bleach system suitable for colored laundry
DE2814329A1 (de) * 1978-04-03 1979-10-11 Henkel Kgaa Waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen
US4300897A (en) * 1973-08-24 1981-11-17 Colgate-Palmolive Company Method for bleaching with peroxymonosulfate-based compositions
US4545919A (en) * 1982-08-31 1985-10-08 Ciba-Geigy Corporation Detergent composition for washing off dyeings obtained with fibre-reactive dyes and washing process comprising the use thereof

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US4548744A (en) * 1983-07-22 1985-10-22 Connor Daniel S Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions
DE3585512D1 (de) * 1984-12-28 1992-04-09 Procter & Gamble Fluessiges hypochlorit-bleichmittel, enthaltend optische aufheller, geloest in aminoxid.
EP0314630A3 (fr) * 1987-10-30 1989-10-25 Sandoz Ag Compositions détergentes
EP0350449A3 (fr) * 1988-07-08 1990-10-24 Ciba-Geigy Ag Composition détergente liquide contenant des azurants optiques

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3714050A (en) * 1968-03-07 1973-01-30 Colgate Palmolive Co Stain removal
GB1348212A (en) * 1971-07-02 1974-03-13 Procter & Gamble Detergent composition with dye-transfer control characteristics
US4123376A (en) * 1973-08-24 1978-10-31 Colgate-Palmolive Company Peroxymonosulfate-base bleaching and bleaching detergent compositions
US4300897A (en) * 1973-08-24 1981-11-17 Colgate-Palmolive Company Method for bleaching with peroxymonosulfate-based compositions
US3929678A (en) * 1974-08-01 1975-12-30 Procter & Gamble Detergent composition having enhanced particulate soil removal performance
US4146496A (en) * 1977-05-18 1979-03-27 Colgate-Palmolive Company Peroxy bleach system suitable for colored laundry
DE2814329A1 (de) * 1978-04-03 1979-10-11 Henkel Kgaa Waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen
US4545919A (en) * 1982-08-31 1985-10-08 Ciba-Geigy Corporation Detergent composition for washing off dyeings obtained with fibre-reactive dyes and washing process comprising the use thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5597795A (en) * 1992-10-27 1997-01-28 The Procter & Gamble Company Detergent compositions inhibiting dye transfer
WO1995027038A1 (fr) * 1994-03-30 1995-10-12 The Procter & Gamble Company Pains de detergent a lessive a blanchiment ameliore et inhibition du transfert des colorants
US5804543A (en) * 1994-10-11 1998-09-08 The Procter & Gamble Company Detergent compositions with optimized surfactant systems to provide dye transfer inhibition benefits
EP0786517A1 (fr) 1996-01-25 1997-07-30 Unilever N.V. Composition détergente

Also Published As

Publication number Publication date
EP0596185A1 (fr) 1994-05-11
PL308760A1 (en) 1995-08-21
JPH08503246A (ja) 1996-04-09
PL175677B1 (pl) 1999-01-29
HU9501296D0 (en) 1995-06-28
AU5590494A (en) 1994-06-08
CA2148808C (fr) 1999-05-18
CA2148808A1 (fr) 1994-05-26
CZ116595A3 (en) 1995-12-13
HUT71963A (en) 1996-02-28
MX9306971A (es) 1995-01-31
CN1088610A (zh) 1994-06-29
KR950704458A (ko) 1995-11-20
AU670851B2 (en) 1996-08-01
CN1041840C (zh) 1999-01-27

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