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WO1994021690A3 - Method for the oxidation of vicinal diols, including carbohydrates - Google Patents

Method for the oxidation of vicinal diols, including carbohydrates Download PDF

Info

Publication number
WO1994021690A3
WO1994021690A3 PCT/NL1994/000065 NL9400065W WO9421690A3 WO 1994021690 A3 WO1994021690 A3 WO 1994021690A3 NL 9400065 W NL9400065 W NL 9400065W WO 9421690 A3 WO9421690 A3 WO 9421690A3
Authority
WO
WIPO (PCT)
Prior art keywords
oxidation
vicinal diols
including carbohydrates
hydrogen peroxide
catalytic amount
Prior art date
Application number
PCT/NL1994/000065
Other languages
French (fr)
Other versions
WO1994021690A2 (en
Inventor
WIT Dirk DE
Sarah Veelaert
Hubert Tournois
Original Assignee
Inst Voor Agrotech Onderzoek
Wit Dirk De
Sarah Veelaert
Hubert Tournois
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Voor Agrotech Onderzoek, Wit Dirk De, Sarah Veelaert, Hubert Tournois filed Critical Inst Voor Agrotech Onderzoek
Priority to EP94912096A priority Critical patent/EP0690877A1/en
Priority to AU64381/94A priority patent/AU6438194A/en
Publication of WO1994021690A2 publication Critical patent/WO1994021690A2/en
Publication of WO1994021690A3 publication Critical patent/WO1994021690A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
    • C08B37/0051—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Fructofuranans, e.g. beta-2,6-D-fructofuranan, i.e. levan; Derivatives thereof
    • C08B37/0054—Inulin, i.e. beta-2,1-D-fructofuranan; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/02—Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B31/00—Preparation of derivatives of starch
    • C08B31/18—Oxidised starch

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A method is described for the oxidation of vicinal diols, including carbohydrates, to dicarboxy compounds by reaction of the diol in an aqueous medium with hydrogen peroxide or via an electrochemical route, in the presence of a catalytic amount of a transition metal salt. Oxidation with hydrogen peroxide in the presence of a catalytic amount of an alkali metal halide, alkaline earth metal halide or ammonium halide is also described.
PCT/NL1994/000065 1993-03-25 1994-03-25 Method for the oxidation of vicinal diols, including carbohydrates WO1994021690A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP94912096A EP0690877A1 (en) 1993-03-25 1994-03-25 Method for the oxidation of vicinal diols, including carbohydrates
AU64381/94A AU6438194A (en) 1993-03-25 1994-03-25 Method for the oxidation of vicinal diols, including carbohydrates

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9300540A NL9300540A (en) 1993-03-25 1993-03-25 Method for oxidizing carbohydrates.
NL9300540 1993-03-25

Publications (2)

Publication Number Publication Date
WO1994021690A2 WO1994021690A2 (en) 1994-09-29
WO1994021690A3 true WO1994021690A3 (en) 1994-11-24

Family

ID=19862222

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NL1994/000065 WO1994021690A2 (en) 1993-03-25 1994-03-25 Method for the oxidation of vicinal diols, including carbohydrates

Country Status (4)

Country Link
EP (1) EP0690877A1 (en)
AU (1) AU6438194A (en)
NL (1) NL9300540A (en)
WO (1) WO1994021690A2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9512563B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Surface treated modified cellulose from chemical kraft fiber and methods of making and using same
US9511167B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
US9512561B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
US9512237B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Method for inhibiting the growth of microbes with a modified cellulose fiber

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2767271B1 (en) * 1997-08-13 2001-05-25 Roquette Freres OZONATION CATALYST AND METHOD FOR OZONATION OF CARBON HYDRATES USING SUCH A CATALYST
US8785683B2 (en) 2009-06-13 2014-07-22 Rennovia, Inc. Production of glutaric acid and derivatives from carbohydrate-containing materials
US8501989B2 (en) 2009-06-13 2013-08-06 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
BR112013030060A2 (en) 2011-05-23 2018-01-16 Gp Cellulose Gmbh kraft resin wood fibers and board and their method for making kraft fiber
MX366988B (en) 2012-01-12 2019-08-01 Gp Cellulose Gmbh A low viscosity kraft fiber having reduced yellowing properties and methods of making and using the same.
MX364847B (en) 2012-04-18 2019-05-08 Gp Cellulose Gmbh The use of surfactant to treat pulp and improve the incorporation of kraft pulp into fiber for the production of viscose and other secondary fiber products.
US10151064B2 (en) 2013-02-08 2018-12-11 Gp Cellulose Gmbh Softwood kraft fiber having an improved α-cellulose content and its use in the production of chemical cellulose products
JP6379116B2 (en) 2013-03-14 2018-08-22 ゲーペー ツェルローゼ ゲーエムベーハー Method for making high performance, low viscosity kraft fiber using acid bleaching sequence and fiber made by the process
KR102180665B1 (en) 2013-03-15 2020-11-23 게페 첼루로제 게엠베하 A low viscosity kraft fiber having an enhanced carboxyl content and methods of making and using the same
EP3541849B1 (en) 2016-11-16 2023-11-15 GP Cellulose GmbH Modified cellulose from chemical fiber and methods of making and using the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE544693C (en) * 1929-03-23 1932-02-20 Chem Fab Gedeon Richter A G Process for the preparation of mixtures of organic acids from carbohydrates and materials containing carbohydrates
JPS55102528A (en) * 1979-02-01 1980-08-05 Mitsui Petrochem Ind Ltd Preparation of carbonyl compound

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE544693C (en) * 1929-03-23 1932-02-20 Chem Fab Gedeon Richter A G Process for the preparation of mixtures of organic acids from carbohydrates and materials containing carbohydrates
JPS55102528A (en) * 1979-02-01 1980-08-05 Mitsui Petrochem Ind Ltd Preparation of carbonyl compound

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 8038, Derwent World Patents Index; AN 66701C *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9512563B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Surface treated modified cellulose from chemical kraft fiber and methods of making and using same
US9511167B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
US9512561B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
US9512562B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
US9512237B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Method for inhibiting the growth of microbes with a modified cellulose fiber

Also Published As

Publication number Publication date
WO1994021690A2 (en) 1994-09-29
EP0690877A1 (en) 1996-01-10
AU6438194A (en) 1994-10-11
NL9300540A (en) 1994-10-17

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