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WO1996000564A1 - Composition quaternaire pour aerosol - Google Patents

Composition quaternaire pour aerosol Download PDF

Info

Publication number
WO1996000564A1
WO1996000564A1 PCT/US1994/007426 US9407426W WO9600564A1 WO 1996000564 A1 WO1996000564 A1 WO 1996000564A1 US 9407426 W US9407426 W US 9407426W WO 9600564 A1 WO9600564 A1 WO 9600564A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
composition
dimethyl ether
alcohol
homogeneous composition
Prior art date
Application number
PCT/US1994/007426
Other languages
English (en)
Inventor
Fred Presant
Agnes Terraforte
Original Assignee
Precision Valve Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Precision Valve Corporation filed Critical Precision Valve Corporation
Priority to PCT/US1994/007426 priority Critical patent/WO1996000564A1/fr
Priority to AU73206/94A priority patent/AU7320694A/en
Publication of WO1996000564A1 publication Critical patent/WO1996000564A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06—Aerosols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/22—Phase substances, e.g. smokes, aerosols or sprayed or atomised substances
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols

Definitions

  • the present invention relates to compositions useful in aerosol, i.e. pressurized, dispensing systems. 5
  • the invention relates in particular to the field of aerosol compositions which exhibit environmental responsibility while retaining desirable properties associated with aerosol dispensing systems.
  • Aerosol products are generally preferred over products dispensed by pumps or other systems. Many advantages of aerosols stem from the fact that air is not drawn into the aerosol container to replace ingredients dispensed. Thus the product is not exposed
  • the product maintains its sterility, and preservatives need not be included in the product composition. Consumers prefer aerosols for their convenience, ease of use and cleanliness. Broadly speaking, the characteristics of
  • Pump-type dispensers tend to over-concentrate the product in one spot because of inability to maintain uniformity of product dispersal throughout the target area. This is important, for ⁇ ⁇ example, in a hairspray product where it is desirable that the spray retain manageability and hold of the hair style yet not weigh the hair down, give an unnatural hold or feel sticky to touch.
  • a further object of the invention is to provide a sealed container with an aerosol dispensing system and a composition which attains the objectives
  • composition may be formulated with active ingredient from about 1-15% by weight, or more.
  • Total propellant may vary from 15-95%.
  • the invention also contemplates an aerosol
  • -'dispensing system comprising a sealed container equipped with an aerosol dispensing valve and containing therein the composition and active ingredient as above.
  • the present invention encompasses non-toxic compositions useful in an aerosol dispensing system.
  • compositions comprise four-component systems made by mixing alcohol, dimethyl ether, non-chlorinated fluorocarbon and water in the proportions indicated.
  • the total of the alcohol and the ether does not exceed
  • composition ⁇ the composition.
  • Optional active ingredients and additives may be included in the formulation in order to prepare different forms of end products by numerous methods known to those skilled in the art. Methods for
  • compositions useful in an aerosol dispensing system which achieves these objectives is obtained by mixing alcohol, 5dimethyl ether ("DME”) , difluoroethane or 1,1,1,2- tetrafluoroethane, and water, in a particular range of percentages by weight.
  • DME 5dimethyl ether
  • the percentage range of compositions contemplated is as follows: a) alcohol selected from the group consisting of alcohols
  • - 1 - 0 containing 2 or 3 carbon atoms and mixtures thereof from about 5-50%, preferably 10-50% and most preferably 15-50% by weight, and dimethyl ether from about 5-50%, preferably 5-45% and most preferably 5-40% by weight wherein said alcohol and dimethyl ether together
  • the total propellant which includes DME and the fluorocarbon ranges from 15-95%, preferably 15-85% and most preferably 25-75% of the composition provided the
  • the preferred alcohol of the present invention is ethanol, which is effective with the range of constituent ingredients listed above in contributing to
  • Isopropanol may also be used, but with a narrower range • ⁇ of the other constituent ingredients.
  • FC-152a available from DuPont but others such as FC-134a and equivalents may be used. 5 it has further been discovered that an active ingredient or mixture of active ingredients may be added up to about 15%, preferably 1-10% by weight. Active ingredient may be added in order to render the composition useful in various applications including
  • Such applications include the dispensing of hairspray, air freshener, anti-perspirant and/or deodorant, disinfectant/deodorant, perfume, paint, insecticide, wax cleaner, solid lubricant, industrial cleaner/lubricant, surface cleaner,
  • the present invention is effective in dispensing a hairspray when formulated with hair fixative resin as active ingredient.
  • Other active ingredients known by those skilled in the art to be useful in the formulation of a hair fixative resin as active ingredient.
  • hairspray to impart hair-holding or style retention properties to hair are also contemplated, such as film forming polymeric substances, or substances which make the hair hydrophobic.
  • active ingredients of hairspray include any one of or a mixture thereof of
  • composition of the present invention is inert to a variety of active ingredients and acts as a solubilizing agent for all manner of hydrophobic and
  • composition of the present invention provides a
  • the novel four component system of the present invention is formulated such that a soluble composition is achieved which provides quick 5drying time and a non-heavy feel to the hair when applied. These characteristics are desirable in many applications, including as a hairspray.
  • the present invention provides these advantages in an aerosol dispensing system with a low content of alcohol and
  • a preferred homogeneous, non-toxic composition of the present invention is produced by the components mixed in the following range by weight percent: a) alcohol selected from the group consisting of alcohols containing 2 or 3 carbon atoms and mixtures thereof from about 10-50%, and dimethyl ether from about 5-45% wherein said alcohol and dimethyl ether together comprise no greater than about 55% by weight of the composition; b) about 10-40% by weight of a material selected from the group consisting of difluoroethane and 1,1,1,2-tetrafluoroethane; and c) water from about 1-30% by weight.
  • the preferred alcohol of the composition is ethanol. Active ingredient may be present from about 1-15% by weight, or more. Total propellents consisting of dimethyl ether and fluorocarbon are 15-95% by weight.
  • the most preferred homogeneous, non-toxic composition of the present invention comprises the following percentages of components measured by weight: a) ethanol, n-propanol or isopropanol at about 15-50% or even 40-50%, dimethyl ether at about 5-40% or even 5-15%; b) difluoroethane or 1,1,1,2-tetrafluoroethane at about 20-35% or even 25-30%; and c) water at about 1-25% or even 5-15%.
  • the preferred amount of active ingredient is about 5%.
  • the preferred amount of propellant is about 25-65%.
  • a total aerosol dispensing system consisting of container, valve and formula has also been discovered in accordance with the present invention.
  • the system comprises a conventional sealed container which contains the novel composition according to the present invention, and which is provided with a conventional aerosol dispensing valve and actuator.
  • the system is useful in storing and then dispensing active ingredient contained therein whenever desired.
  • the composition includes the homogeneous 4-component system of the present invention in addition to active ingredient. J
  • Each of the components of this composition is commercially available from chemical supply houses.
  • composition A formulated as shown in Table 1.
  • 25composition A contained alcohol at about 24%, dimethyl ether at about 30%, difluoroethane at about 34% and water at about 6% as well as active ingredient and other additives as indicated. Upon mixing these ingredients, the composition immediately became cloudy and separated
  • composition of the present invention when the composition of the present invention is formulated with active ingredient, for instance in the amounts of 1-10 wt. % and more preferably about 5 wt.%, the resulting composition is a homogeneous composition useful in 5dispensing the active ingredient from an aerosol dispensing system.
  • the components of the composition useful as a propellant are non-toxic and useful in formulations for personal care products.
  • a further advantage of the present invention is that given higher propellant content allowing for easier atomization, the valve and actuator selections and dimensions are less critical.
  • composition of the present invention can be formulated following normal commercial practice, in
  • composition B * Octyl acrylamide/acrylates/butyl aminoethyl methacrylate polymer available from National Starch and Chemical Corp.
  • EXAMPLE 2 Studies were performed whereby the composition of the present invention was tested in dispensing a hairspray from an aerosol dispensing system. Homogeneous compositions B and C were made with about 5% active ingredient and additives. The particular formulation of each composition is disclosed in Table 1. Study participants tested the homogeneous hair spray compositions B and C dispensed from a sealed container having an aerosol dispensing system equipped with an aerosol dispensing valve. Whole-head evaluations were performed on study participants, 2 or 3 per formulation, in order to observe overall performance of the hair sprays with compositions B and C. The results obtained are as follows: Composition B
  • Drying time for composition B was determined to be about 20 seconds and no stickiness or tackiness was present. The hold was rated as excellent, and the curl retention and manageability was rated as very good. The participant rated overall performance as very good.
  • composition C Drying time for composition C was determined to be about 40 seconds.
  • the product displayed a good hold when sprayed for 10-15 seconds, which was slightly longer than the participant usually sprays her hair.
  • Manageability and curl retention was rated as very good as was overall performance.
  • composition When the composition is formulated in the amounts indicated, a homogeneous, one-phase composition of matter is achieved which is useful in an aerosol dispensing system and which has been shown to be effective.
  • compositions of the present invention were tested by dispensing from an aerosol container.
  • Half-head tests were carried out comparing two of the compositions set forth in the table in Example 3 to a conventional aerosol hairspray formula ⁇ tion.
  • Compositions A and B each exhibited longer drying times compared to the conventional product.
  • Composition A exhibited little or no stickiness/tackiness, and exhibited superior hold and crust, manageability, and l°curl retention.
  • Composition B displayed slight stickiness/tackiness and superior hold and crust.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical & Material Sciences (AREA)
  • Epidemiology (AREA)
  • Dispersion Chemistry (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Toxicology (AREA)
  • Plant Pathology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition quaternaire homogène utilisable dans un système de distribution aérosol. Cette composition comprend: a) un alcool appartenant au groupe constitué d'alcools contenant 2 ou 3 atomes de carbone et leurs mélanges pour une part pondérale approximative de 5 à 55 % avec du diméthyle-éther pour une part pondérale approximative de 5 à 55 %, lesdits alcool et diméthyle-éther ne formant ensemble pas plus d'environ 55 % en poids de la composition; b) une part pondérale d'environ 10 à 45 % d'une substance fluorocarbonée telle que le difluoroéthane et le 1,1,1,2-tétrafluoroéthane; et c) de l'eau pour une part pondérale approximative de 1 à 50 %. Le propulseur total représente 15 à 95 % de la part pondérale. Cette composition permet, une atomisation facile et fine grâce à des niveaux élevés de propulseur, et en cas de besoin, des temps de séchage rapide. La composition solubilise tous les types d'ingrédients actifs pouvant être présents pour une part pondérale au moins égale à environ 15 %, suivant le type de produit désiré. Cette composition s'utilise pour des laques coiffantes, des désinfectants, des désodorisants corporels et des désodorisants d'ambiance.
PCT/US1994/007426 1994-06-30 1994-06-30 Composition quaternaire pour aerosol WO1996000564A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/US1994/007426 WO1996000564A1 (fr) 1994-06-30 1994-06-30 Composition quaternaire pour aerosol
AU73206/94A AU7320694A (en) 1994-06-30 1994-06-30 Four-component aerosol composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1994/007426 WO1996000564A1 (fr) 1994-06-30 1994-06-30 Composition quaternaire pour aerosol

Publications (1)

Publication Number Publication Date
WO1996000564A1 true WO1996000564A1 (fr) 1996-01-11

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1994/007426 WO1996000564A1 (fr) 1994-06-30 1994-06-30 Composition quaternaire pour aerosol

Country Status (2)

Country Link
AU (1) AU7320694A (fr)
WO (1) WO1996000564A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997029790A1 (fr) * 1996-02-19 1997-08-21 Marcel Jean Bombe aerosol a propulseur liquefie pour le parfumage d'ambiance
WO1998037858A1 (fr) * 1997-02-28 1998-09-03 Peter Kwasny Gmbh Composition pour application aerosol ininflammable
DE19708157A1 (de) * 1997-02-28 1998-09-03 Peter Kwasny Gmbh Unbrennbare Aerosolzubereitung
WO1999007220A1 (fr) * 1997-08-06 1999-02-18 Reckitt & Colman Inc. Compositions permettant de lutter contre les acariens detriticoles et leurs allergenes
US6342471B1 (en) * 2000-01-25 2002-01-29 Toney M. Jackson Electrical contact cleaner
EP1161934A3 (fr) * 2000-06-08 2003-05-07 KPSS-Kao Professional Salon Services GmbH Laque capillaire en aérosol
AU2009100883B4 (en) * 2009-09-04 2010-02-18 Riplog (Proprietary) Limited Blast hole plug and propellant therefor
US7754096B2 (en) * 2007-02-01 2010-07-13 E.I. Du Pont De Nemours And Company Liquefied-gas aerosol dusting composition containing denatonium benzoate
WO2023159278A1 (fr) * 2022-02-28 2023-08-31 Squire Kent Pty Limited Compositions d'aérosol anti-pathogène

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3207386A (en) * 1962-06-01 1965-09-21 Aerosol Tech Inc Aerosol dispenser producing non-flammable spray with fluid system having a flammable propellant
US4134968A (en) * 1976-02-18 1979-01-16 Lever Brothers Company Single phase water containing aerosol compositions
US4243548A (en) * 1977-11-25 1981-01-06 Hans Schwarzkopf Gmbh Pressurized aerosol formulation and process for the manufacture thereof
US4536323A (en) * 1983-06-28 1985-08-20 The Drackett Company Non-flammable aerosol propellant microemulsion system
US5188748A (en) * 1990-02-20 1993-02-23 Societe Atochem Azeotropic mixtures of dimethyl ether and of 1,1,1,2-tetrafluoroethane and their use
US5190029A (en) * 1991-02-14 1993-03-02 Virginia Commonwealth University Formulation for delivery of drugs by metered dose inhalers with reduced or no chlorofluorocarbon content
US5225183A (en) * 1988-12-06 1993-07-06 Riker Laboratories, Inc. Medicinal aerosol formulations
US5269958A (en) * 1993-01-13 1993-12-14 S. C. Johnson & Son, Inc. Self-pressurized aerosol spot dry cleaning compositions
US5286477A (en) * 1991-06-18 1994-02-15 Helene Curtis, Inc. Aerosol hair styling aid

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3207386A (en) * 1962-06-01 1965-09-21 Aerosol Tech Inc Aerosol dispenser producing non-flammable spray with fluid system having a flammable propellant
US4134968A (en) * 1976-02-18 1979-01-16 Lever Brothers Company Single phase water containing aerosol compositions
US4243548A (en) * 1977-11-25 1981-01-06 Hans Schwarzkopf Gmbh Pressurized aerosol formulation and process for the manufacture thereof
US4536323A (en) * 1983-06-28 1985-08-20 The Drackett Company Non-flammable aerosol propellant microemulsion system
US5225183A (en) * 1988-12-06 1993-07-06 Riker Laboratories, Inc. Medicinal aerosol formulations
US5188748A (en) * 1990-02-20 1993-02-23 Societe Atochem Azeotropic mixtures of dimethyl ether and of 1,1,1,2-tetrafluoroethane and their use
US5190029A (en) * 1991-02-14 1993-03-02 Virginia Commonwealth University Formulation for delivery of drugs by metered dose inhalers with reduced or no chlorofluorocarbon content
US5286477A (en) * 1991-06-18 1994-02-15 Helene Curtis, Inc. Aerosol hair styling aid
US5269958A (en) * 1993-01-13 1993-12-14 S. C. Johnson & Son, Inc. Self-pressurized aerosol spot dry cleaning compositions

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997029790A1 (fr) * 1996-02-19 1997-08-21 Marcel Jean Bombe aerosol a propulseur liquefie pour le parfumage d'ambiance
FR2744992A1 (fr) * 1996-02-19 1997-08-22 Jean Marcel Bombe aerosol a propulseur liquefie pour le parfumage d'ambiance
WO1998037858A1 (fr) * 1997-02-28 1998-09-03 Peter Kwasny Gmbh Composition pour application aerosol ininflammable
DE19708157A1 (de) * 1997-02-28 1998-09-03 Peter Kwasny Gmbh Unbrennbare Aerosolzubereitung
AU735016B2 (en) * 1997-08-06 2001-06-28 Reckitt Benckiser Inc. Compositions for controlling dust mites and their allergens
US6117440A (en) * 1997-08-06 2000-09-12 Reckitt Benckiser Inc. Compositions effective for controlling dust mites and the allergens produced by dust mites
WO1999007220A1 (fr) * 1997-08-06 1999-02-18 Reckitt & Colman Inc. Compositions permettant de lutter contre les acariens detriticoles et leurs allergenes
US6428801B1 (en) 1997-08-06 2002-08-06 Reckitt Benckiser Inc. Methods for controlling dust mites and the allergens produced by dust mites
US6342471B1 (en) * 2000-01-25 2002-01-29 Toney M. Jackson Electrical contact cleaner
EP1161934A3 (fr) * 2000-06-08 2003-05-07 KPSS-Kao Professional Salon Services GmbH Laque capillaire en aérosol
US7754096B2 (en) * 2007-02-01 2010-07-13 E.I. Du Pont De Nemours And Company Liquefied-gas aerosol dusting composition containing denatonium benzoate
AU2009100883B4 (en) * 2009-09-04 2010-02-18 Riplog (Proprietary) Limited Blast hole plug and propellant therefor
WO2023159278A1 (fr) * 2022-02-28 2023-08-31 Squire Kent Pty Limited Compositions d'aérosol anti-pathogène

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Publication number Publication date
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