WO1996000565A1 - Agent de fixation capillaire - Google Patents
Agent de fixation capillaire Download PDFInfo
- Publication number
- WO1996000565A1 WO1996000565A1 PCT/EP1995/001728 EP9501728W WO9600565A1 WO 1996000565 A1 WO1996000565 A1 WO 1996000565A1 EP 9501728 W EP9501728 W EP 9501728W WO 9600565 A1 WO9600565 A1 WO 9600565A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hair
- degree
- composition according
- percent
- agent
- Prior art date
Links
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 229920001800 Shellac Polymers 0.000 claims abstract description 21
- 239000004208 shellac Substances 0.000 claims abstract description 21
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims abstract description 21
- 235000013874 shellac Nutrition 0.000 claims abstract description 21
- 229940113147 shellac Drugs 0.000 claims abstract description 21
- -1 hydroxypropyl Chemical group 0.000 claims abstract description 15
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims abstract description 13
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims abstract description 13
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims abstract description 12
- 229920002678 cellulose Polymers 0.000 claims abstract description 9
- 239000001913 cellulose Substances 0.000 claims abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 229940054190 hydroxypropyl chitosan Drugs 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 10
- 238000006467 substitution reaction Methods 0.000 claims description 6
- 230000001476 alcoholic effect Effects 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 150000001414 amino alcohols Chemical class 0.000 claims description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 2
- 150000003141 primary amines Chemical class 0.000 claims description 2
- 150000003335 secondary amines Chemical class 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 19
- 238000001035 drying Methods 0.000 abstract description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- 239000000443 aerosol Substances 0.000 description 12
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000002304 perfume Substances 0.000 description 8
- 239000008266 hair spray Substances 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 239000000834 fixative Substances 0.000 description 5
- 229920001059 synthetic polymer Polymers 0.000 description 5
- 239000004604 Blowing Agent Substances 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000004676 glycans Chemical class 0.000 description 4
- 229920001282 polysaccharide Polymers 0.000 description 4
- 239000005017 polysaccharide Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000003380 propellant Substances 0.000 description 4
- 238000005728 strengthening Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 235000018185 Betula X alpestris Nutrition 0.000 description 3
- 235000018212 Betula X uliginosa Nutrition 0.000 description 3
- 229920001661 Chitosan Polymers 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000000973 cosmetic coloring agent Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- QBYIENPQHBMVBV-HFEGYEGKSA-N (2R)-2-hydroxy-2-phenylacetic acid Chemical compound O[C@@H](C(O)=O)c1ccccc1.O[C@@H](C(O)=O)c1ccccc1 QBYIENPQHBMVBV-HFEGYEGKSA-N 0.000 description 1
- ICVRBKCRXNVOJC-UHFFFAOYSA-N 1-amino-4-(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2NC ICVRBKCRXNVOJC-UHFFFAOYSA-N 0.000 description 1
- NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 description 1
- ARNOCIJYIDDUMQ-UHFFFAOYSA-N 2-[2-chloro-4-(2-hydroxyethylamino)-5-nitroanilino]ethanol Chemical compound OCCNC1=CC([N+]([O-])=O)=C(NCCO)C=C1Cl ARNOCIJYIDDUMQ-UHFFFAOYSA-N 0.000 description 1
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 1
- HVHNMNGARPCGGD-UHFFFAOYSA-N 2-nitro-p-phenylenediamine Chemical compound NC1=CC=C(N)C([N+]([O-])=O)=C1 HVHNMNGARPCGGD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- GHOKWGTUZJEAQD-UHFFFAOYSA-N Chick antidermatitis factor Natural products OCC(C)(C)C(O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-UHFFFAOYSA-N 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 101100396356 Mycoplasma hyopneumoniae (strain 232) infA gene Proteins 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- IWYDHOAUDWTVEP-UHFFFAOYSA-N R-2-phenyl-2-hydroxyacetic acid Natural products OC(=O)C(O)C1=CC=CC=C1 IWYDHOAUDWTVEP-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000000490 cosmetic additive Substances 0.000 description 1
- 230000036758 dandruff formation Effects 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical class O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229960002510 mandelic acid Drugs 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Substances [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 229940055726 pantothenic acid Drugs 0.000 description 1
- 235000019161 pantothenic acid Nutrition 0.000 description 1
- 239000011713 pantothenic acid Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- QXYMVUZOGFVPGH-UHFFFAOYSA-N picramic acid Chemical compound NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O QXYMVUZOGFVPGH-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- AFJYYKSVHJGXSN-KAJWKRCWSA-N selamectin Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1C(/C)=C/C[C@@H](O[C@]2(O[C@@H]([C@@H](C)CC2)C2CCCCC2)C2)C[C@@H]2OC(=O)[C@@H]([C@]23O)C=C(C)C(=N\O)/[C@H]3OC\C2=C/C=C/[C@@H]1C AFJYYKSVHJGXSN-KAJWKRCWSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/736—Chitin; Chitosan; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Definitions
- the invention relates to an agent for setting the hair on an aqueous, alcoholic or aqueous-alcoholic basis, which contains 50 to 100 percent neutralized shellac in combination with hydroxypropylchitosan, hydroxybutylchitosan, hydroxypropylcellulose and / or hydroxybutylcellulose.
- the temporary reshaping of the hair is generally based on the use of hair-setting agents, the essential component of which are solutions of film-forming natural or synthetic polymers.
- synthetic polymers are anionic polymers such as acrylic acid or methacrylic acid homopolymers or copolymers, copolymers of acrylic acid and acrylamides and copolymers based on alkyl vinyl ethers and maleic acid monoalkyl esters, amphoteric polymers such as copolymers of octylacrylamide, acrylate and butylaminoethyl methacrylate and nonionic polymers such as vinylpyrrolidone homopolymers, vinylpyrrolidone-vinyl acetate copolymers and copolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate.
- Synthetic hair-fixing polymers are preferred by radical polymerization of monomeric petro- chemical products, i.e. from non-renewable raw materials.
- synthetic polymers can contain contaminants from monomers, polymerization stoppers and polymerization regulators, which can be toxicologically unsafe.
- Natural polymers do not have the disadvantages of synthetic polymers described above.
- the most suitable natural hair-setting polymers are Schel varnish, polysaccharides or derivatives of polysaccharides, in particular cellulose derivatives, chitosan or chitosan derivatives.
- Hair fixatives the hair-setting effect of which is based on shellac as a film-forming agent, generally adhere strongly to the hair, making the hair difficult to style. In addition, such hair fixatives leave residues on the hair which are difficult to remove.
- Hair-setting agents containing polysaccharides are generally difficult to spray due to the thickening effect of polysaccharides. Furthermore, these agents have the disadvantage that when combing out the hair, dandruff formation and the formation of a gray coating on the hair can occur.
- Polymers suitable for use in hair setting agents must have a multitude of properties. For example, they have to Dissolve alcohols and alcohol-water mixtures well and be contracted with the commonly used aerosol propellants.
- a general problem with setting products is the durability of the hairstyles created with them. For example, washing the hair loses the setting effect of the products.
- the object was therefore to provide a means for setting the hair that does not have the disadvantages of the previously known means.
- the middle is said to make the hair easy to style, to give the hair shine and to ensure good hair strengthening beyond washing. Furthermore, with good sprayability and resistance to atmospheric humidity, it should dry quickly and act less stressfully on the hair.
- the present invention therefore relates to an agent for setting the hair on an aqueous, alcoholic or aqueous-alcoholic basis, which is characterized in that it
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- the hair fixative preferably contains.
- shellac component (A) can handels ⁇ conventional shellac, such as the commercial product shellac MHP210 ® from Pennig, Hamburg / Germany, are used.
- the organic or inorganic bases customary in cosmetics such as primary, secondary or tertiary amines, amino alcohols, alkali metal hydroxides or ammonia in the form of aqueous ammonia solutions, can be used.
- Preferred neutralizing agents are 2-amino-2-methylpropanol, triisopropanolamine, sodium hydroxide or ammonia as an aqueous ammonia solution.
- partial neutralization of the shellac is possible by means of the hydroxypropylchitosan and / or hydroxybutylchitosan used in the agent.
- the agent according to the invention preferably contains hydroxypropylchitosan or hydroxybutylchitosan with a degree of propoxylation or butoxylation of 1.0 to 5.0 with a ratio of N / O substitution of 99: 1 to 1:99 and an intrinsic viscosity ( ⁇ ) of 10 up to 150 ml per gram (1 percent solution in 0.2 mol acetic acid and 0.1 mol sodium chloride at 20 degrees Celsius).
- Suitable hydroxypropylchitosans are listed for example in EP-PS 0 224 045; Suitable Hydroxy ⁇ butylchitosane are described for example in EP-PS 0 243 822.
- the agent according to the invention preferably contains hydroxypropyl cellulose or hydroxybutyl cellulose with a degree of propoxylation or butoxylation of 2.0 to 4.0 and a kinematic viscosity of 0.1 to 25 mm 2 per second, measured with an Ubbelohde viscometer type 501 103 (capillary 2) at 20 degrees Celsius, 3 percent solution in 96 percent ethanol.
- a hydroxypropyl cellulose or hydroxybutyl cellulose with a degree of propoxylation or degree of butoxylation of 2.3 to 3.8 and a kinematic viscosity of 0.2 to 12 mm 2 per second is particularly preferred.
- Suitable hydroxypropyl include the commercial products Nisso HPC ® Nippon Soda, Tokyo, Japan or Klucel ® EF Aqualon, Dusseldorf, Germany.
- the agent for setting the hair preferably contains component (B) in an amount of 0.5 to 10 percent by weight.
- the agent according to the invention can be in the form of an aqueous, alcoholic or aqueous-alcoholic solution.
- Suitable alcohols are, in particular, the lower alcohols with 1 to 5 carbon atoms usually used for cosmetic purposes, the boiling point of which is below 300 ° Celsius; alcohols with 1 to 3 carbon atoms are particularly preferred.
- the agent according to the invention for setting the hair can be filled with a propellant in a pressure vessel and sprayed as an aerosol or foam. It can also be in the form of a non-aerosol hairspray, non-aerosol foam or non-aerosol hair lacquer that can be sprayed with the aid of a suitable mechanically operated spraying device.
- Mechanical spraying devices are to be understood as devices which enable the spraying of a liquid without using a liquefied propellant.
- a suitable mechanical spray device can be, for example, a spray pump or an elastic container provided with a spray valve, into which the above-described cosmetic agent is filled under pressure, the elastic container expanding and from which the agent expands as a result of the contraction of the elastic one Can be removed continuously when opening the spray valve.
- the agent according to the invention is in the form of an aerosol hairspray, aerosol foam or aerosol hair lacquer, then it additionally contains 2 to 80 percent by weight of a propellant and is filled into a pressure container.
- blowing agents such as N 2 , N 2 0 and C0 2 , and mixtures of the above-mentioned compounds are suitable.
- blowing agents mentioned above dimethyl ether and mixtures of lower alkanes with dimethyl ether are preferred, the use of dimethyl ether as blowing agent being particularly preferred.
- composition according to the invention for hair fixatives can furthermore contain customary cosmetic additives, such as, for example, anionic, cationic, amphoteric or non-anionic wetting agents and emulsifiers, such as, for example, d 2 - to C -.
- customary cosmetic additives such as, for example, anionic, cationic, amphoteric or non-anionic wetting agents and emulsifiers, such as, for example, d 2 - to C -.
- the agent for strengthening the hair according to the invention can optionally dye or tone the hair at the same time through a content of cosmetic dyes.
- Such preparations are known in the trade, inter alia, as color fixers or tinting fixers. They additionally contain customary cosmetic dyes known for hair fixatives, for example aromatic nitro dyes such as 1,4-diamino-2-nitrobenzene, picramic acid, 1-hydroxy-2-amino-4, which are known to be hair-absorbing -nitrobenzene and 1,4-bis - [(2-hydroxyethyl) amino] -2-nitro-5-chlorobenzene, azo dyes, such as for example Acid Brown 4 (CI 14 805), anthraquinone dyes, such as, for example, Disperse Violet 4 (CI 61 105) or triphenylmethane dyes, such as, for example, Basic Violet I (CI 42 535), the dyes of these classes depending on the nature of their substituents, they can have an acidic, nonionic or basic character
- the agent according to the invention has a low residue on the hair and does not give the hair a high shine. In addition to good hairdosability, the agent brings about lasting strengthening beyond washing the hair.
- the agent is easy to spray and resistant to atmospheric moisture.
- the agent is also characterized by comparatively shorter drying times.
- hydroxypropyl cellulose e.g. Klucel EF ® der
- Example 5 Aerosol hairspray for normal hold
- Example 6 Spray fixer with birch extract
- birch extract for example Extrapon® birch from Dragoco, Holzminden, Germany 15.00 g ethanol 80.45 g water 100.00 g
- Example 7 Firming mousse for a strong hold
- hydroxypropyl cellulose e.g. Klucel EE * der
- hydroxypropyl cellulose e.g. Klucel EF ® der
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- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Cosmetics (AREA)
- Paints Or Removers (AREA)
Abstract
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR9506005A BR9506005A (pt) | 1994-06-28 | 1995-05-06 | Agente para fixaçao dos cabelos |
JP8502736A JPH09502456A (ja) | 1994-06-28 | 1995-05-06 | 毛髪固化剤 |
EP95919419A EP0715513A1 (fr) | 1994-06-28 | 1995-05-06 | Agent de fixation capillaire |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19944422593 DE4422593A1 (de) | 1994-06-28 | 1994-06-28 | Mittel zur Festigung der Haare |
DEP4422593.8 | 1994-06-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996000565A1 true WO1996000565A1 (fr) | 1996-01-11 |
Family
ID=6521706
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1995/001728 WO1996000565A1 (fr) | 1994-06-28 | 1995-05-06 | Agent de fixation capillaire |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0715513A1 (fr) |
JP (1) | JPH09502456A (fr) |
BR (1) | BR9506005A (fr) |
DE (1) | DE4422593A1 (fr) |
ES (1) | ES2087054T1 (fr) |
WO (1) | WO1996000565A1 (fr) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2326889A (en) * | 1997-06-30 | 1999-01-06 | Procter & Gamble | Hair styling composition |
EP0841060A3 (fr) * | 1996-11-07 | 2000-08-09 | Wella Aktiengesellschaft | Produit de soins capillaires pour la fixation des cheveux |
US6475475B2 (en) | 1999-12-02 | 2002-11-05 | Wella Aktiengesellschaft | Polymer ingredient combinations for hair treatment compositions |
KR100416929B1 (ko) * | 1996-11-25 | 2004-06-04 | 주식회사 엘지생활건강 | 에어졸 헤어 스프레이 조성물 |
DE102004009158A1 (de) * | 2004-02-26 | 2005-09-15 | Beiersdorf Ag | Polymerkombination für Stylingmittel |
US7597898B2 (en) | 2002-05-15 | 2009-10-06 | Wella Ag | Aerosol foam or pump foam product for hair treatment |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0832639B1 (fr) * | 1996-09-12 | 2004-01-28 | KPSS-Kao Professional Salon Services GmbH | Utilisation de composition aérosol contenant une amine |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0224045A2 (fr) * | 1985-11-22 | 1987-06-03 | Wella Aktiengesellschaft | Compositions cosmétiques à base de chitosanes N-hydroxypropylés, chitosanes N-hydroxypropylés modifiés et leur méthode de préparation |
US5053218A (en) * | 1989-07-17 | 1991-10-01 | Cosmosol, Ltd. | Pressurized hair spray composition |
EP0469232A1 (fr) * | 1990-08-03 | 1992-02-05 | Kabushiki Kaisha Japan Happy | Matériaux pour produits cosmétiques capillaires et produits cosmétiques capillaires |
EP0580514A1 (fr) * | 1992-07-24 | 1994-01-26 | L'oreal | Laque aérosol capillaire à base de N-carboxybutyl chitosane |
US5304368A (en) * | 1993-02-19 | 1994-04-19 | American Telecast Corporation | Non-foaming, non-viscous, alcohol-free, water-based, pressurized hair spray product |
DE4234743A1 (de) * | 1992-10-15 | 1994-04-21 | Wella Ag | Mittel zur Festigung der Haare |
-
1994
- 1994-06-28 DE DE19944422593 patent/DE4422593A1/de not_active Withdrawn
-
1995
- 1995-05-06 ES ES95919419T patent/ES2087054T1/es active Pending
- 1995-05-06 EP EP95919419A patent/EP0715513A1/fr not_active Withdrawn
- 1995-05-06 JP JP8502736A patent/JPH09502456A/ja active Pending
- 1995-05-06 WO PCT/EP1995/001728 patent/WO1996000565A1/fr not_active Application Discontinuation
- 1995-05-06 BR BR9506005A patent/BR9506005A/pt active Search and Examination
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0224045A2 (fr) * | 1985-11-22 | 1987-06-03 | Wella Aktiengesellschaft | Compositions cosmétiques à base de chitosanes N-hydroxypropylés, chitosanes N-hydroxypropylés modifiés et leur méthode de préparation |
US5053218A (en) * | 1989-07-17 | 1991-10-01 | Cosmosol, Ltd. | Pressurized hair spray composition |
EP0469232A1 (fr) * | 1990-08-03 | 1992-02-05 | Kabushiki Kaisha Japan Happy | Matériaux pour produits cosmétiques capillaires et produits cosmétiques capillaires |
EP0580514A1 (fr) * | 1992-07-24 | 1994-01-26 | L'oreal | Laque aérosol capillaire à base de N-carboxybutyl chitosane |
DE4234743A1 (de) * | 1992-10-15 | 1994-04-21 | Wella Ag | Mittel zur Festigung der Haare |
US5304368A (en) * | 1993-02-19 | 1994-04-19 | American Telecast Corporation | Non-foaming, non-viscous, alcohol-free, water-based, pressurized hair spray product |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0841060A3 (fr) * | 1996-11-07 | 2000-08-09 | Wella Aktiengesellschaft | Produit de soins capillaires pour la fixation des cheveux |
US6214319B1 (en) | 1996-11-07 | 2001-04-10 | Wella Aktiengesellschaft | Aqueous-alcoholic hair fixing composition containing a combination of shellac and synthetic hair fixing polymer |
KR100416929B1 (ko) * | 1996-11-25 | 2004-06-04 | 주식회사 엘지생활건강 | 에어졸 헤어 스프레이 조성물 |
GB2326889A (en) * | 1997-06-30 | 1999-01-06 | Procter & Gamble | Hair styling composition |
US6475475B2 (en) | 1999-12-02 | 2002-11-05 | Wella Aktiengesellschaft | Polymer ingredient combinations for hair treatment compositions |
US7597898B2 (en) | 2002-05-15 | 2009-10-06 | Wella Ag | Aerosol foam or pump foam product for hair treatment |
DE102004009158A1 (de) * | 2004-02-26 | 2005-09-15 | Beiersdorf Ag | Polymerkombination für Stylingmittel |
Also Published As
Publication number | Publication date |
---|---|
EP0715513A1 (fr) | 1996-06-12 |
ES2087054T1 (es) | 1996-07-16 |
BR9506005A (pt) | 1997-08-19 |
DE4422593A1 (de) | 1996-01-04 |
JPH09502456A (ja) | 1997-03-11 |
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