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WO1996002620A1 - Melanges detergents a pouvoir ameliore de lavage - Google Patents

Melanges detergents a pouvoir ameliore de lavage Download PDF

Info

Publication number
WO1996002620A1
WO1996002620A1 PCT/EP1995/002677 EP9502677W WO9602620A1 WO 1996002620 A1 WO1996002620 A1 WO 1996002620A1 EP 9502677 W EP9502677 W EP 9502677W WO 9602620 A1 WO9602620 A1 WO 9602620A1
Authority
WO
WIPO (PCT)
Prior art keywords
detergent mixtures
fatty acid
mixtures according
weight
acid
Prior art date
Application number
PCT/EP1995/002677
Other languages
German (de)
English (en)
Inventor
Bernd Fabry
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to EP95943495A priority Critical patent/EP0771346B1/fr
Priority to DE59507095T priority patent/DE59507095D1/de
Publication of WO1996002620A1 publication Critical patent/WO1996002620A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest

Definitions

  • the invention relates to detergent mixtures with synergistic enhancement of the cleaning and foaming power, containing fatty acid N-alkylpolyhydroxyalkylamides and sulfosuccinates and their use for the preparation of surface-active agents.
  • Fatty acid-N-alkylpolyhydroxyalkylamides and in particular fatty acid-N-methylglucamides are nonionic surfactants which are used, for example, for the production of hand dishwashing detergents because of their good application profile.
  • the object of the invention was therefore to provide detergent mixtures based on fatty acid-N-alkylpolyhydroxyalkyl aids, which have improved cleaning and foaming power, without this advantage due to performance losses in other applications-relevant Properties must be paid for.
  • the invention relates to detergent mixtures with improved cleaning performance, containing
  • the fatty acid N-alkylpolyhydroxyalkylamides are known substances which are usually obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or one Fatty acid chloride can be obtained.
  • a reducing sugar with ammonia an alkylamine or an alkanolamine
  • subsequent acylation with a fatty acid, a fatty acid alkyl ester or one Fatty acid chloride can be obtained.
  • US Pat. Nos. US 1985424, US 2016962 and US 2703798 and international patent application WO 92/0698 An overview of this topic by H. Kelkenberg can be found in Tens. Surf.Det. 25, 8 (1988).
  • the fatty acid N-alkylpolyhydroxyalkylamides are preferably derived from reducing sugars with 5 or 6 carbon atoms, in particular from glucose.
  • the preferred fatty acid N-alkylpolyhydroxyalkylamides are therefore fatty acid N-alkylglucamides as represented by the formula (II):
  • Glucamides of the formula (II) are preferably used as the fatty acid N-alkylpolyhydroxyalkylamides in which R 2 is hydrogen or an amine group and R 1 -C 4 is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid , Palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroseline acid, linoleic acid, linolenic acid, arachidic acid, gadoleic acid, behenic acid or erucic acid or their technical mixtures.
  • Fatty acid N-alkylglucamides of the formula (II) which are obtained by reductive amination of glucose with methylamine and subsequent acylation with are particularly preferred Lauric acid or Ci2 / i4 coconut fatty acid or a corresponding derivative can be obtained.
  • the polyhydroxyalkylamides can also be derived from maltose and palatinose.
  • Sulfosuccinates which are also referred to as sulfosuccinic acid esters, are known anionic surfactants which can be obtained by the relevant methods of preparative organic chemistry. They follow formula (III)
  • R-3 stands for an alkyl and / or alkenyl radical with 6 to 22 carbon atoms
  • R * for R 3 or X
  • m and n independently of one another for 0 or numbers from 1 to 10 and X for an alkali or alkaline earth metal , Ammonium, alkylammonium, alkanolamonium or glucamonium.
  • Typical examples are sulfosuccinic acid monoesters and / or diesters in the form of their sodium salts which are derived from fatty alcohols having 8 to 18, preferably 8 to 10 or 12 to 14, carbon atoms; the fatty alcohols can be etherified with an average of 1 to 10 and preferably 1 to 5 moles of ethylene oxide and can have both a conventional and preferably a narrow hologmological distribution.
  • Examples include di-n-octyl sulfosuccinate and monolauryl 3EO sulfosuccinate in the form of their sodium salts.
  • the mixtures which are preferably aqueous and then have a solids content of 5 to 70, preferably 25 to 50% by weight, are generally prepared by stirring aqueous solutions, pastes or concentrates of the starting materials, if necessary at a slightly elevated temperature.
  • aqueous solutions, pastes or concentrates of the starting materials if necessary at a slightly elevated temperature.
  • spray-dried powders of the two components it is also possible to paste them on or to subject solutions of both ingredients to spray drying and / or granulation together. All of these cases are purely mechanical processes and there is no chemical reaction.
  • the detergent mixtures according to the invention have a synergistic enhancement of the cleaning and foaming power.
  • Another object of the invention therefore relates to their use for the production of surface-active agents, as there are:
  • Powder-form universal detergents containing 10 to 30% by weight, based on the detergent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • Liquid universal detergents containing 10 to 70% by weight, based on the detergent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • Liquid mild detergent containing 10 to 50% by weight, based on the detergent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Hand dishwashing detergent containing 10 to 50% by weight, based on the detergent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o rinse aid containing 10 to 50% by weight, based on the detergent, of the detergent mixtures according to the invention, and also conventional auxiliaries and additives.
  • Liquid detergents and disinfectants containing 10 to 30% by weight, based on the agent, of the detergent mixtures according to the invention, as well as customary auxiliaries and additives.
  • o Haa rinses containing 10 to 30 wt .-% - based on the agent - of the detergent mixtures according to the invention and conventional auxiliaries and additives.
  • o Hair waving compositions containing 10 to 30% by weight, based on the composition, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Bubble baths containing 10 to 30% by weight, based on the agent, of the detergent mixtures according to the invention, and also conventional auxiliaries and additives.
  • o Textile and fiber auxiliaries containing 1 to 30% by weight, based on the composition, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Flotation auxiliaries containing 1 to 30% by weight, based on the composition, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Aids for dewatering of solids containing 1 to 30% by weight, based on the agent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • the use of the detergent mixtures according to the invention for the production of manual dishwashing detergents and hair shampoos is particularly preferred.
  • the above-mentioned agents can contain, as auxiliaries and additives, primarily other anionic, nonionic, cationic, amphoteric and / or zwitterionic surfactants.
  • anionic surfactants are alkylbenzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, o-methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerin ether sulfates, hydroxy acid ether sulfate sulfates, mono-ether ether sulfate sulfates, mono-ether ether sulfate sulfates, mono-ether ether sulfate sulfates, mono-ether ether sulfate sulfates,
  • nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, alk (en) yl oligoglycosides, fatty acid N-alkyl glucamides, protein hydrolysate products (insol. Protein hydrolysate products) - acid esters, sugar esters, sorbitan esters and polysorbates. If the nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • cationic surfactants are quaternary ammonium compounds and ester quats, in particular quaternized fatty acid trialkanolamine ester salts.
  • amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, amino glycinates, imidazolinium betaines and sulfobetaines.
  • Washing, rinsing, cleaning and conditioning agents based on the detergent mixtures according to the invention can contain, for example, builders, salts, bleaching agents, bleach activators, optical brighteners, graying inhibitors, solubilizers and enzymes as auxiliaries and additives.
  • Common builders are sodium aluminum silicates (zeolites), phosphates, phosphonates, ethylenediaminetetraacetic acid, nitrilotriacetate, citric acid and / or polycarboxylates.
  • Suitable salts or adjusting agents are, for example, sodium sulfate, sodium carbonate or sodium silicate (water glass).
  • Typical individual examples of further additives are sodium borate, starch, sucrose, polydextrose, TAED, stilbene compounds, methyl cellulose, toluenesulfonate, cumene sulfonate, long-chain soaps, silicones, mixed ethers, lipases and proteases.
  • Hair shampoos, hair lotions or foam baths can contain, as auxiliaries and additives, bmulsifiers such as alkoxylated fatty alcohols or sorbitan esters.
  • bmulsifiers such as alkoxylated fatty alcohols or sorbitan esters.
  • Substances such as, for example, polyethoxylated lanolin derivatives, lecithin derivatives and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
  • Suitable thickeners are, for example, polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinylpyrrolidone and also and ammonium chloride.
  • Biogenic active substances are understood to mean, for example, plant extracts, protein hydrolyzates and vitamin complexes.
  • Common film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives and similar compounds.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentadiol or sorbic acid.
  • Suitable pearlizing agents are, for example, glycol distearic acid esters such as ethylene glycol distearate, but also fatty acid mono-glycol esters.
  • the dyes which can be used are those which are suitable and approved for cosmetic purposes, such as, for example, in the publication "Cosmetic Dyes” of the dye emission of the German Research Foundation, published by the Chemie publishing house, Weinheim, 1984, p. 81-106 are compiled. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole. The.
  • the total proportion of auxiliaries and additives can be 1 to 50, preferably 5 to 40% by weight, based on the composition.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

Des mélanges détergents qui contiennent (a) des alkylpolyhydroxyalkylamides-N d'acides gras et (b) des sulfosuccinates dans un rapport en poids compris entre 80: 20 et 20: 80 se caractérisent par un fort pouvoir synergique détergent et moussant et sont utiles pour préparer des agents tensioactifs.
PCT/EP1995/002677 1994-07-19 1995-07-10 Melanges detergents a pouvoir ameliore de lavage WO1996002620A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP95943495A EP0771346B1 (fr) 1994-07-19 1995-07-10 Utilisation de compositions detergents
DE59507095T DE59507095D1 (de) 1994-07-19 1995-07-10 Verwendung von detergensgemischen

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4425449.0 1994-07-19
DE4425449A DE4425449A1 (de) 1994-07-19 1994-07-19 Detergensgemische mit verbesserter Reinigungsleistung

Publications (1)

Publication Number Publication Date
WO1996002620A1 true WO1996002620A1 (fr) 1996-02-01

Family

ID=6523534

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1995/002677 WO1996002620A1 (fr) 1994-07-19 1995-07-10 Melanges detergents a pouvoir ameliore de lavage

Country Status (4)

Country Link
EP (1) EP0771346B1 (fr)
DE (2) DE4425449A1 (fr)
ES (1) ES2138762T3 (fr)
WO (1) WO1996002620A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1047815B1 (fr) * 1998-01-15 2003-06-18 Acordis Kelheim GmbH Procedes de fabrication et de recuperation de particules cellulosiques

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0509810D0 (en) * 2005-05-16 2005-06-22 Reckitt Benckiser Nv Aqueous cleaning compositions

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0112046A1 (fr) * 1982-11-16 1984-06-27 Unilever N.V. Compositions détergentes
WO1992006162A1 (fr) * 1990-09-28 1992-04-16 The Procter & Gamble Company Detergent contenant des tensioactifs de sulfate d'alkyle et d'amide de l'acide gras de polyhydroxy
DE4301358A1 (en) * 1992-01-30 1993-08-05 Hermann Scheler Packaging-free detergent prods. - comprising detergent paste in gelatin capsules, avoids environmental problems associated with disposal of packaging
WO1993021293A1 (fr) * 1992-04-09 1993-10-28 The Procter & Gamble Company Compositions aqueuses detergentes a usage personnel ou cosmetique comprenant des apports en huile vegetale
EP0572723A1 (fr) * 1992-06-02 1993-12-08 The Procter & Gamble Company Compositions détergentes liquides structurées
DE4238211C1 (de) * 1992-11-12 1994-01-13 Henkel Kgaa Detergensgemische enthaltend kationische Zuckertenside
DE4224714A1 (de) * 1992-07-27 1994-02-03 Henkel Kgaa Schäumende Detergensgemische
WO1994005755A1 (fr) * 1992-09-01 1994-03-17 The Procter & Gamble Company Liquide ou gel detergent pour la vaisselle contenant un amide d'acide gras polyhydroxy, des ions de calcium et un alkylpolyethoxypolycarboxylate
WO1994009100A1 (fr) * 1992-10-13 1994-04-28 The Procter & Gamble Company Composition detergente sous forme liquide ou de gel pour lave-vaisselle contenant une amide d'acide gras polyhydroxy et certains elements
DE4315810A1 (de) * 1993-05-12 1994-11-17 Henkel Kgaa Wäßrige Detergensgemische
WO1995003782A1 (fr) * 1993-07-28 1995-02-09 Ici Australia Operations Proprietary Limited Concentre formant une surface perlee pour produits de soins

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0112046A1 (fr) * 1982-11-16 1984-06-27 Unilever N.V. Compositions détergentes
WO1992006162A1 (fr) * 1990-09-28 1992-04-16 The Procter & Gamble Company Detergent contenant des tensioactifs de sulfate d'alkyle et d'amide de l'acide gras de polyhydroxy
DE4301358A1 (en) * 1992-01-30 1993-08-05 Hermann Scheler Packaging-free detergent prods. - comprising detergent paste in gelatin capsules, avoids environmental problems associated with disposal of packaging
WO1993021293A1 (fr) * 1992-04-09 1993-10-28 The Procter & Gamble Company Compositions aqueuses detergentes a usage personnel ou cosmetique comprenant des apports en huile vegetale
EP0572723A1 (fr) * 1992-06-02 1993-12-08 The Procter & Gamble Company Compositions détergentes liquides structurées
DE4224714A1 (de) * 1992-07-27 1994-02-03 Henkel Kgaa Schäumende Detergensgemische
WO1994005755A1 (fr) * 1992-09-01 1994-03-17 The Procter & Gamble Company Liquide ou gel detergent pour la vaisselle contenant un amide d'acide gras polyhydroxy, des ions de calcium et un alkylpolyethoxypolycarboxylate
WO1994009100A1 (fr) * 1992-10-13 1994-04-28 The Procter & Gamble Company Composition detergente sous forme liquide ou de gel pour lave-vaisselle contenant une amide d'acide gras polyhydroxy et certains elements
DE4238211C1 (de) * 1992-11-12 1994-01-13 Henkel Kgaa Detergensgemische enthaltend kationische Zuckertenside
DE4315810A1 (de) * 1993-05-12 1994-11-17 Henkel Kgaa Wäßrige Detergensgemische
WO1995003782A1 (fr) * 1993-07-28 1995-02-09 Ici Australia Operations Proprietary Limited Concentre formant une surface perlee pour produits de soins

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1047815B1 (fr) * 1998-01-15 2003-06-18 Acordis Kelheim GmbH Procedes de fabrication et de recuperation de particules cellulosiques

Also Published As

Publication number Publication date
EP0771346A1 (fr) 1997-05-07
DE59507095D1 (de) 1999-11-25
DE4425449A1 (de) 1996-01-25
ES2138762T3 (es) 2000-01-16
EP0771346B1 (fr) 1999-10-20

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