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WO1996004887A1 - Melanges detergents moussants - Google Patents

Melanges detergents moussants Download PDF

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Publication number
WO1996004887A1
WO1996004887A1 PCT/EP1995/003123 EP9503123W WO9604887A1 WO 1996004887 A1 WO1996004887 A1 WO 1996004887A1 EP 9503123 W EP9503123 W EP 9503123W WO 9604887 A1 WO9604887 A1 WO 9604887A1
Authority
WO
WIPO (PCT)
Prior art keywords
mixtures according
weight
additives
detergent
detergent mixtures
Prior art date
Application number
PCT/EP1995/003123
Other languages
German (de)
English (en)
Inventor
Jörg KAHRE
Hermann Hensen
Reinhard Müller
Holger Tesmann
Claudia Panzer
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Publication of WO1996004887A1 publication Critical patent/WO1996004887A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/04—Preparations for permanent waving or straightening the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017—Mixtures of compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

Definitions

  • the invention relates to detergent mixtures with improved foaming power, containing alkyl glycosides and acylglutamates, surface-active agents which contain these mixtures and the use of the mixtures for the preparation of surface-active agents.
  • Alkyl oligoglycosides in particular alkyl oligoglucosides, are nonionic surfactants which are becoming increasingly important due to their excellent detergent properties and high ecotoxicological compatibility.
  • the production and use of these substances have recently been described in a number of review articles, of which the publications by H.Hensen in Skin Care Forum, 1, (Oct. 1992), D.Balzer and N.Ripke in Seifen ⁇ le- Fette waxes 118, 894 (1992) and B.Brancg in soap oils Fette waxes 118, 905 (1992) should be mentioned.
  • Alkyl oligoglucosides are characterized by a foam strength that is otherwise only typical of anionic surfactants.
  • liquid personal cleansing agents are also known which also contain alkyl polyglucosides and protein fatty acid condensates.
  • European patent application EP-A1 0531650 finally discloses hair shampoos based on anionic surfactants, cation polymers, polysiloxanes and vegetable protein fatty acid condensates, which may contain alkyl glucosides as an optional component. Combinations of alkyl glucosides with protein fatty acid condensates are distinguished by a particularly advantageous dermatological compatibility, but are unsatisfactory in terms of their foaming power. Accordingly, the object of the invention was to provide new detergent mixtures which are characterized by improved foaming power and at least equally good skin tolerance.
  • the invention relates to foaming detergent mixtures comprising a) alkyl and alkenyl oligoglycosides of the general formula (I),
  • R 2 CO represents a linear or branched acyl radical having 6 to 22 carbon atoms and 0 and / or 1, 2 or 3 double bonds and X represents hydrogen, an alkali metal and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
  • Alkyl and alkenyl oligoglycosides are known substances that can be obtained by the relevant methods of preparative organic chemistry.
  • the alkyl and / or alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably glucose.
  • the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
  • the index number p in the general formula (I) indicates the degree of oligomerization (DP degree), ie the distribution of mono and oligoglycosides, and stands for a number between 1 and 10. While p must always be an integer in a given compound, the value p for a certain alkyl oligoglycoside is an analytically determined arithmetic parameter, which usually represents a fractional number. Alkyl and / or alkenyl oligoglycosides with an average degree of oligomerization p of 1.1 to 3 are preferably used. From an application point of view, those alkyl and / or alkenyl oligoglycosides are preferred whose degree of oligomerization is less than 1.6 and in particular between 1.2 and 1.5.
  • the alkyl or alkenyl radical R * can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms. Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, and their technical mixtures, which can be obtained as described above. Alkyl oligoglucosides based on hardened C 12/14 coconut alcohol with a DP of 1.1 to 1.6 are preferred.
  • Acyl glutamates are known anionic surfactants which can be obtained, for example, by Schotten-Baumann acylation of glutamic acid with fatty acids, fatty acid esters or chlorides. Sales products are available, for example, from Hoechst AG, Frankfurt / DE or Ajinomoto Co. Inc., Tokyo / JP. An overview of the production and properties of the acylglutamates is given by M.Takehara et al. in J.Am.Oil.Chem.Soc., 49, 143 (1972).
  • glutamic acid is one of the products that would be obtained by total hydrolysis of proteins.
  • the hydrolysis of proteins leads to mixtures of oligopeptides which still have an average of 5 to 20 amino acid units.
  • conventional protein fatty acid condensates represent acylation products of oligopeptides.
  • Acylglutamates differ from these substances in that they represent "monomers" to a certain extent.
  • acylglutamates which are considered as component (b) in the context of the invention are anionic surfactants which are derived from fatty acids having 6 to 22, preferably 12 to 18, carbon atoms, such as, for example, C12 / 14- or C12 / 18 -coconut fatty acid, lauric acid, myristine acid, palmitic acid and / or stearic acid.
  • anionic surfactants which are derived from fatty acids having 6 to 22, preferably 12 to 18, carbon atoms, such as, for example, C12 / 14- or C12 / 18 -coconut fatty acid, lauric acid, myristine acid, palmitic acid and / or stearic acid.
  • Sodium N-cocoyl and sodium N-stearoyl-L-glutamate are particularly preferred
  • the detergent mixtures according to the invention can contain the alkyl and / or alkenyl oligoglucosides and the acyl glutamates in a weight ratio of 1:99 to 99: 1, preferably 10:90 to 90:10 and in particular 80:20 to 50:50.
  • the surfactant mixtures according to the invention can be combined with further anionic, nonionic, cationic, amphoteric and / or zwitterionic surfactants.
  • anionic surfactants are alkylbenzenesulfonates, alkanesulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether, ⁇ -methyl ester sulfonates, sulfofatty acids, alkyl sulfates, fatty alcohol ether sulfates, Glycerol ether, Hydroxymischethersulfate, monoglyceride (ether) sulfates, fatty acid amide (ether) sulfates, mono- and dialkyl sulfosuccinates, mono- and Dialkyl sulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, acyl lactylates, alkyl oligogluco
  • anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, fatty acid N-alkylglucamides, polyol fatty acid esters, sugar esters, sorbitan esters and polysorbates.
  • the nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • cationic surfactants are quaternary ammonium compounds and ester gates, in particular guatemated fatty acid trialkanolamine ester salts.
  • amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
  • the surfactants mentioned are exclusively known compounds. With regard to the structure and manufacture of these substances, reference is made to relevant reviews, for example, J.Falbe (ed.), “Surfactants in Consumer Products”, Springer Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), “Catalysts, Tenside und Mineralöladditive ", Thieme Verlag, Stuttgart, 1978, pp. 123-217.
  • the detergent mixtures according to the invention can have a proportion of the above-mentioned further surfactants from 0 to 90, preferably 5 to 15 and in particular 10 to 25% by weight, based on the solids content of the mixtures.
  • the detergent mixtures according to the invention are notable for improved foaming power, a property which is important in the development of a large number of surface-active agents:
  • Further objects of the invention therefore relate to surface-active agents which have a content of these detergent mixtures and which are defined in more detail below: o Powdery universal detergents containing 10 to 30% by weight, based on the agent, of the detergent mixtures according to the invention and customary auxiliaries and additives . Liquid universal detergents containing 10 to 70% by weight, based on the detergent, of the detergent mixtures according to the invention and customary auxiliaries and additives. o Liquid mild detergent, containing 10 to 50% by weight, based on the detergent, of the detergent mixtures according to the invention and customary auxiliaries and additives. o softening agents containing 10 to 50% by weight, based on the agent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Hand dishwashing detergent containing 10 to 50% by weight, based on the detergent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o rinse aid containing 10 to 50% by weight, based on the detergent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Liquid cleaning agents and disinfectants containing 10 to 30% by weight, based on the agent, of the detergent mixtures according to the invention, as well as customary auxiliaries and additives.
  • o Bar soaps of the K ⁇ mbibar type containing 1 to 2% by weight, based on the agent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Hair waving compositions containing 10 to 30% by weight, based on the composition, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Bubble baths containing 10 to 30% by weight, based on the agent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Facial cleansing agent containing 10 to 30% by weight, based on the agent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Textile and fiber auxiliaries containing 1 to 30% by weight, based on the composition, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Leather greasing agent containing 1 to 30% by weight, based on the agent, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Flotation auxiliaries containing 1 to 30% by weight, based on the composition, of the detergent mixtures according to the invention and customary auxiliaries and additives.
  • o Aids for dewatering of solids containing 1 to 30% by weight, based on the agent, of the detergent mixtures according to the invention, and customary auxiliaries and additives.
  • Washing, rinsing, cleaning and conditioning agents based on the detergent mixtures according to the invention can contain - in addition to the surfactants already mentioned - other auxiliaries and additives, for example, builders, salts, bleaching agents, bleach activators, optical brighteners, graying inhibitors, solubilizers and enzymes.
  • auxiliaries and additives for example, builders, salts, bleaching agents, bleach activators, optical brighteners, graying inhibitors, solubilizers and enzymes.
  • Common builders are sodium aluminum silicates (zeolites), phosphates, phosphonates, ethylenediaminetetraacetic acid, nitrilotriacetate, citric acid and / or polycarboxylates.
  • Suitable salts or adjusting agents are, for example, sodium sulfate, sodium carbonate or sodium silicate (water glass).
  • Typical individual examples for further additives are sodium borate, starch, sucrose, polydextrose, TAED, stilbene compounds, methyl cellulose, toluenesulfonate, cumene sulfonate, long-chain soaps, silicones, misethers, lipases and proteases.
  • Hair shampoos, hair lotions or bubble baths can contain emulsifiers such as alkoxylated fatty alcohols or sorbitan esters as further auxiliaries and additives, in addition to the surfactants already mentioned.
  • emulsifiers such as alkoxylated fatty alcohols or sorbitan esters as further auxiliaries and additives, in addition to the surfactants already mentioned.
  • Substances such as polyethoxylated lanolin derivatives, lecithin derivatives and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
  • Suitable thickeners are, for example, polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol colmono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinylpyrrolidone as well as electrolytes such as table salt and ammonium chloride.
  • Biogenic active substances are understood to mean, for example, plant extracts and vitamin complexes.
  • Common film formers are, for example, chitosan, microcrystalline chitosan, guaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, guaternary cellulose derivatives and similar compounds.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentadiol or sorbic acid.
  • Suitable pearlizing agents are, for example, glycol distearic acid esters such as ethylene glycol distearate, but also fatty acid monoglycol esters.
  • the dyes which can be used are the substances which are suitable and approved for cosmetic purposes, as compiled, for example, in the publication "Cosmetic Dyes” by the Dye Commission of the German Research Foundation, published by Verlag Chemie, Weinheim, 1984, pp. 81-106. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
  • the total proportion of auxiliaries and additives can be 1 to 50, preferably 5 to 40% by weight, based on the composition.
  • a last subject of the invention finally relates to the use of the detergent mixtures according to the invention for the production of liquid or solid surface-active agents, in which they are present in amounts of 1 to 99 and preferably 10 up to 90 wt .-% - based on the solids content of the agent - may be included.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Materials Engineering (AREA)
  • Detergent Compositions (AREA)

Abstract

Des mélanges détergents à pouvoir moussant amélioré contiennent (a) des oligoglycosides d'alkyle et d'alcényle répondant à la formule générale (I) R1O-[G]p, dans laquelle: R1 désigne un reste alkyle et/ou alcényle avec 4 à 22 atomes de carbone, G désigne un reste de sucre avec 5 ou 6 atomes de carbone et p vaut 1 à 10; et (b) des glutamates d'acyle répondant à la formule (II), dans laquelle R2CO désigne un reste acyle linéaire ou ramifié avec 6 à 22 atomes de carbone et 0, 1, 2 et/ou 3 liaisons doubles et X désigne hydrogène, un métal alcalin et/ou alcalino-terreux, ammonium, alkylammonium, alcanolammonium ou glucammonium.
PCT/EP1995/003123 1994-08-16 1995-08-07 Melanges detergents moussants WO1996004887A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4428823.9 1994-08-16
DE4428823A DE4428823A1 (de) 1994-08-16 1994-08-16 Schäumende Detergensgemische

Publications (1)

Publication Number Publication Date
WO1996004887A1 true WO1996004887A1 (fr) 1996-02-22

Family

ID=6525684

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1995/003123 WO1996004887A1 (fr) 1994-08-16 1995-08-07 Melanges detergents moussants

Country Status (2)

Country Link
DE (1) DE4428823A1 (fr)
WO (1) WO1996004887A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0773017A1 (fr) * 1995-11-09 1997-05-14 Henkel Kommanditgesellschaft auf Aktien Emulsions cosmétiques et/ou pharmaceutiques
US6315040B1 (en) 1998-05-01 2001-11-13 Shell Oil Company Expandable well screen
US6391325B1 (en) 1996-05-22 2002-05-21 Ciba Specialty Chemicals Corporation Use of nitrogen-containing complexing agents for deodorization and antimicrobial treatment of the skin and textile fibre materials
EP3275982A1 (fr) * 2016-07-25 2018-01-31 Henkel AG & Co. KGaA Acylglutamate comme ingrédient de nettoyage de tissu

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19609056C2 (de) * 1996-03-08 1999-02-11 Henkel Kgaa Verwendung von Alkyl- und/oder Alkenyloligoglykosiden und/oder Fettsäure-N-alkylpolyhydroxyalkylamiden zur Entfettung von Ledern oder Pelzen
EP0864638B1 (fr) * 1997-03-12 2001-12-05 Showa Denko Kabushiki Kaisha Composition détergente
DE19856555A1 (de) * 1998-12-08 2000-06-15 Cognis Deutschland Gmbh Ölbäder
DE19926527A1 (de) * 1999-06-10 2000-12-14 Goldwell Gmbh Flüssiges Detergensgemisch
DE19950497B4 (de) * 1999-10-20 2004-12-02 Cognis Deutschland Gmbh & Co. Kg Kosmetische und/oder pharmazeutische Zubereitungen und deren Verwendung
DE10102007A1 (de) * 2001-01-18 2002-10-10 Cognis Deutschland Gmbh Tensidgemisch
DE10154628A1 (de) * 2001-09-25 2003-04-10 Beiersdorf Ag Verwendung von Alkylglucosiden zum Erzielen oder Erhöhen der Selektivität von Reinigungszubereitungen
DE10221813A1 (de) * 2002-05-16 2003-11-27 Beiersdorf Ag Stark schäumendes Reinigungsgel
DE10342127A1 (de) * 2003-09-12 2005-04-07 Beiersdorf Ag Kosmetisches Reinigungsprodukt
DE10342418A1 (de) * 2003-09-13 2005-04-07 Beiersdorf Ag Verwendung von waschaktiven Substanzen, gewählt aus der Gruppe der N-Acylaminosäuren und der Salze von N-Acylaminosäuren zur Steigerung der Verträglichkeit kosmetischer oder dermatologischer Reinigungszubereitungen
DE102010001193A1 (de) * 2010-01-25 2011-07-28 Dahms, Gerd, 47138 Neue Tensidzusammensetzungen
BR112014014976A2 (pt) * 2011-12-19 2017-06-13 Firmenich & Cie composição de limpeza corporal sem sulfato e sem peg
WO2015028344A1 (fr) * 2013-08-29 2015-03-05 Basf Se Produits cosmétiques
WO2022241143A1 (fr) * 2021-05-14 2022-11-17 Colgate-Palmolive Company Compositions de soins personnels

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2025629A1 (en) * 1970-05-26 1971-12-09 Manzke, Oswald, Dipl.-Chem. Dr., 5650 Solingen Surface-active glutamic acid derivs - for cosmetic prepns
EP0409005A2 (fr) * 1989-07-19 1991-01-23 Kao Corporation Composition détergente
EP0453238A1 (fr) * 1990-04-20 1991-10-23 Unilever Plc Composition de nettoyage
WO1995017163A1 (fr) * 1993-12-20 1995-06-29 Colgate-Palmolive Company Composition de nettoyage de la peau

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2526105B2 (ja) * 1988-09-20 1996-08-21 花王株式会社 洗浄剤組成物
DE4009616A1 (de) * 1990-03-26 1991-10-02 Henkel Kgaa Fluessige koerperreinigungsmittel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2025629A1 (en) * 1970-05-26 1971-12-09 Manzke, Oswald, Dipl.-Chem. Dr., 5650 Solingen Surface-active glutamic acid derivs - for cosmetic prepns
EP0409005A2 (fr) * 1989-07-19 1991-01-23 Kao Corporation Composition détergente
EP0453238A1 (fr) * 1990-04-20 1991-10-23 Unilever Plc Composition de nettoyage
WO1995017163A1 (fr) * 1993-12-20 1995-06-29 Colgate-Palmolive Company Composition de nettoyage de la peau

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0773017A1 (fr) * 1995-11-09 1997-05-14 Henkel Kommanditgesellschaft auf Aktien Emulsions cosmétiques et/ou pharmaceutiques
US6391325B1 (en) 1996-05-22 2002-05-21 Ciba Specialty Chemicals Corporation Use of nitrogen-containing complexing agents for deodorization and antimicrobial treatment of the skin and textile fibre materials
US6315040B1 (en) 1998-05-01 2001-11-13 Shell Oil Company Expandable well screen
EP3275982A1 (fr) * 2016-07-25 2018-01-31 Henkel AG & Co. KGaA Acylglutamate comme ingrédient de nettoyage de tissu

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Publication number Publication date
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