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WO1996014882A1 - Procede de traitement antimicrobien pour systeme d'air conditionne des vehicules automobiles - Google Patents

Procede de traitement antimicrobien pour systeme d'air conditionne des vehicules automobiles Download PDF

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Publication number
WO1996014882A1
WO1996014882A1 PCT/KR1994/000162 KR9400162W WO9614882A1 WO 1996014882 A1 WO1996014882 A1 WO 1996014882A1 KR 9400162 W KR9400162 W KR 9400162W WO 9614882 A1 WO9614882 A1 WO 9614882A1
Authority
WO
WIPO (PCT)
Prior art keywords
antimicrobial
air
conditioning system
conditioning
treatment method
Prior art date
Application number
PCT/KR1994/000162
Other languages
English (en)
Inventor
John Hee Hong
Mal Sik Park
Original Assignee
Hyundai Motor Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hyundai Motor Company filed Critical Hyundai Motor Company
Priority to PCT/KR1994/000162 priority Critical patent/WO1996014882A1/fr
Priority to EP95900318A priority patent/EP0790838A1/fr
Priority to AU81176/94A priority patent/AU8117694A/en
Priority to JP8515933A priority patent/JPH09511941A/ja
Publication of WO1996014882A1 publication Critical patent/WO1996014882A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
    • B60H3/00—Other air-treating devices
    • B60H3/0085—Smell or pollution preventing arrangements
    • B60H3/0092—Smell or pollution preventing arrangements in the interior of the HVAC unit, e.g. by spraying substances inside the unit
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/20—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation

Definitions

  • This invention relates to a method of antimicrobial treatment for automative air-conditioning system and more particularly, the method of antimicrobial treatment for automative air-conditioning system wherein ; while manufacturing air-conditioning evaporator, heater, blower and duct, which are main components of the existing automative air-conditioning system, the mixture of some antimicrobial agents is applied ⁇ c to the said automative air-conditioning system for its antimicrobial treatment in an attempt to prevent the proliferation of several fungi present in the system, thus keeping the indoor air, flowing from the said air-conditioning system, fresh and clean during the operation of cooling or heating.
  • the automative air- conditioning system consists of 4 components such as air-conditioning evaporator, heater, blower and duct, installed at the engine room in the indoor of automobile; each component of the automobile air-conditioning system is made from plastic moldings : c such as housing or pad, while metallic materials in some components.
  • the difference in temperature between atmosphere and the air-conditioning system causes to bring about the local blockade in each component.
  • the indoor air flowing from the outside to the said air-conditioning system serves to make various species of bacteria or fungi fit for their living. Actually, one can easily detect the proliferation of several species of bacteria or fungi present in the automative air-conditioning system which is now under market.
  • fungi e.g., Aspergillus sp. ATCC 6275, Cladosporium sp., 5 Penicillum sp., Aspergillus sp., Trichoderma sp., Saccharomyces sp., Fusarium sp.,
  • Alternaria sp., etc. are propagated in each component consisting of the automative air-conditioning system, as shown in Fig. 1.
  • Fig. 1 demonstrates several species of fungi propagated in each component consisting of the automative air-conditioning system ; the door pad of i heater has five species of fungi [e.g., Aspergillus sp. ATCC 6275(1), Cladosporium sp.
  • the core of air-conditioning evaporator has five species of fungi[e.g.,
  • the main object of this invention to comply with those matters associated with the proliferation of several fungi present in the existing automative air-conditioning system, is to provide a new method of antimicrobial treatment designed to prevent the proliferation of several fungi present in the automative air-conditioning system and to keep the indoor atmosphere of automobile fresh and clean.
  • the characteristics of this invention relates to an automative air-conditioning system comprising air-conditioning evaporator, heater, blower and duct characterized in which plastic material of housing, well-closed pad and lining pad of air-conditioning evaporator, door pad of heater housing, blowing - fan and lining pad of blower and 5 duct are molded by mixing the antimicrobial compound selected from isothiazolines and oxybisphenoxarsines, and aluminum material of core of the said air-conditioning evaporator core is antimicrobially treated by coating hydrophilic coloring agent mixed with the antimicrobial composition of parachlorometa xylenol.
  • Fig. 1 is a photograph demonstrating the cultured fungi collected and separated from the existing general automative air-conditioning system ; the photograph of No. (1) through No. (5) shows five species of cultured fungi collected from a door pad of heaterfe.g., Aspergillus sp. ATCC 6275(1 ), Cladosporium sp. IAM.F 517(2),
  • (16) shows five species of fungi [e.g., Penicillum sp. ATCC 9849(12), Rhodotorula sp.(13), Cladosporium sp.(14) and Cladosporium sp. IAM.F 517(15), Fusarium sp. USDA 1004.1 (16)] collected from a housing of air- conditioning evaporator.
  • fungi e.g., Penicillum sp. ATCC 9849(12), Rhodotorula sp.(13), Cladosporium sp.(14) and Cladosporium sp. IAM.F 517(15), Fusarium sp. USDA 1004.1 (16)
  • Fig. 2 represents test results of the antimicrobial activities concerning the
  • Fig. 3 represents test results of the antimicrobial activities related to Candida albicans and Cladosporium after the aging test concerning the antimicrobially-treated polypropylene housing in the automative air-conditioning system, according to this i c invention ; the photographs of No. (40) and No. (41 ) show the antimicrobial test after environment aging ; the photographs of No. (42) and No. (43) show the antimicrobial test after waterproofing aging ; the photographs of No. (44) and No. (45) show the antimicrobial test after heat aging ; the photographs of No. (46) and No. (47) show the antimicrobial test after shock aging.
  • FIG. 4 represents test results of the antimicrobial activities after the aging test concerning the antimicrobially-treated pad of the automative air-conditioning system, according to this invention ;
  • the photographs of No. (48) and No. (49) show the antimicrobial test of well-closed polyethylene pad after the aging test ;
  • the photographs of No. (50) and No. (51) show the antimicrobial test of polyurethane door pad after the C aging test ;
  • the photographs of No. (52) and No. (53) show the antimicrobial test of polyurethane lining pad after the aging test.
  • Fig. 5 represents test results of the antimicrobial activities after the aging test concerning the antimicrobially-treated core of air-conditioning evaporator of the automative air-conditioning system, according to this invention ; the photographs of 5 No. (54) and No. (55) show the 28-day culture after microbial untreatment ; the photographs of No. (56) and No. (57) show the antimicrobial test after 28-day culture of fungi's spores. DETAILED DESCRIPTION OF THE INVENTION
  • This invention relates to the a method of antimicrobial treatment for automative air-conditioning system designed to entirely inhibit the generation and proliferation of several species of fungi by manufacturing, through the use of antimicrobial agents, each of components consisting of the existing air-conditioning system.
  • sub-components in plastic material such as housing, pad, etc. are molded by mixing the antimicrobial compounds such as isothiazolines or oxybisphenoxarsines.
  • a core of air-conditioning evaporator in aluminium material is antimicrobially treated by coating hydrophilic coloring agent containing parachlorometa xylenol, antimicrobial composition.
  • isothiazolines having the following chemical formula(I) of 2-n-octyl-4-isothiazoline-3-one is used as an antimicrobial agent
  • oxybisphenoxarsine having the following chemical formula(II) of 10,10'- oxybisphenoxarsine is used as an antimicrobial agent:
  • the said air-conditioning system composes of four components such as air-conditioning evaporator, heater, blower and duct ; among them, the fabrication of air-conditioning evaporator contains the housing and core in its inside, well-closed pad designed to ensure the tightness in the inside of housing, and 7 oscillation-absorbing lining pad.
  • the fabrication of housing in the said air-conditioning evaporator is made from the following process : polypropylene resin added with talc of 20wt. % is mixed with appropriate antimicrobial agents such as isothiazolines or oxybisphenoxarsines to manufacture a master batch and then, the batch is under the process of injection molding to manufacture the air-conditioning evaporator housing, having durability and antimicrobial activity.
  • the compound having 2-n-octyl-4-isothiazoline-3-one as isothiazolines may be used as an antimicrobial agent
  • the compound having 10,10'- oxybisphenoxarsine as oxybisphenoxarsines may be used as an antimicrobial agent.
  • the antimicrobial effect may not be achieved and in case of its excessive use, the injected molding become poor and thus, a variety of physical properties proves to be also poor.
  • the core of air-conditioning evaporator comprises a refrigerant evaporator, the antimicrobial treatment should require special consideration.
  • the core of air-conditioning evaporator is made from aluminum material, its radiation of heat is of much significance and during the antimicrobial treatment, every care should be made not to reduce the radiation of heat.
  • the core of air-conditioning evaporator is coated by the antimicrobial coloring agent producing from mixing silicate-family hydrophilic coloring agent with parachlorometa xylenol in 0.1 ⁇ 1.5wt. %.
  • the core is dipped into coloring agent mixed with the said antimicrobial coloring agent and then, picked it up to continue the application by making its dried thickness 4 - 7 ⁇ m.
  • the applied thickness of antimicrobial coloring agent is less than 4 ⁇ m, the stability of applied membrane is not secured under the operation of air-conditioning evaporator where the change in temperature or humidity is very high ; the applied membrane is detached or the antimicrobial activity may not be expected due to insufficiency of antimicrobial agent. If the thickness is over lim, however, the radiation of heat in the core of air-conditioning evaporator become decreased so that a centrifuge should be desirably used so as to assure the homogeneous applied membrane 5 and to prevent the cloggedness due to the antimicrobial agents at the core of air- conditioning evaporator.
  • parachlorometha xylenol may be added as an antimicrobial agent; if the content of parachlorometha xylenol is less than 0.5 wt. % of the colouring agent, the antimicrobial effect may not be achieved and if the content is i C more than 1.5 wt. %, the antimicrobial effect is quite remarkable, but the application characteristics of colouring agents becomes poor and the reducement of viscosity may lead to easy detachment of the antimicrobial membrane.
  • the content of isothiazolines or oxybisphenoxarsine is used in 0.2 ⁇ 1.0 wt. % and with the mixture of foaming agent and cross-linking agent, a master batch dissolved is pressured and molded to manufacture an foaming-type pad.
  • the content of the said antimicrobial agent is used in 0.2 ⁇ 1.0 wt. % in proportion to the whole composition; if the content is less than 0.2wt. %, the C antimicrobial effect of well-closed polyethylene pad and in case of the excessive use, the pressured molding is very poor so that the quality of pad product is deteriorated with the difficulty of molding.
  • the lining pad of the said air-conditioning evaporator made from a foaming urethanee material, is intended to be used for absorbing noise and oscillation 5 incurred out of the operation of air-conditioning evaporator.
  • the antimicrobial treatment of the lining pad is made in the following manner; prior to the molding, main ingredients such as polyol and isocyanate are mixed with, water, foaming agent, surfactant and amine compound, catalyst such as organic metal, etc.
  • the antimicrobial agent such as oxybisphenoxarsines is added in 0.2 ⁇ 1.0 wt. % to produce a foamed molding pad.
  • the antimicrobially treated housing, core, well- closed pad and lining pad of air-conditioning evaporator are manufactured. Based upon the existing structure, these components are fabricated from the well-known method to 5 comprise the air-conditioning evaporator as part of the air-conditioning system according to this invention.
  • the antimicrobial treatment is to be made to the heater, another main component of automative air-conditioning system for the purpose of proliferation of several fungi; a high temperature of dried air generated by i o the heater makes the fungi difficult to proliferate, but when the heater is not operated, some fungi coming from the outside is proliferated on the door pad of heater. Therefore, the antimicrobial treatment for the door pad of heater in carried out in the same method as the case of lining pad of said air-conditioning evaporator, the treated door pad is assembled in heater. 15
  • the blower which is fan-flowing the cooled or heated air through the air- conditioning evaporator or heater manufactured in accordance with the present invention into the inside of automobile, should be antimicrobially treated.
  • the blower consists of housing, fan and lining pad, but dusts from the outside are liable to be piled on these components. Since the piled dusts are placed on the spot where outer 0 air and cooled (or heated) air are met, the great difference in temperature and humidity akes the fungi fit for their living.
  • the antimicrobial treatment of housing and blowing-fan of blower is made in the same manner as do in the above; as a basic material, the housing of blower uses polypropylene adding a talc in 20wt. %, whilst the 5 blowing-fan uses polypropylene adding a talc in 15wt. %. Then, by mixing the said isothiazoline or oxybisphenoxarsine in 0.5 ⁇ 1.5wt. %, a master batch is manufactured and through the common method, the injected molding is performed to obtain a final object.
  • the reason on limited use of antimicrobial agent in case of the housing of the said air-conditioning evaporator is applicable to the components of blower.
  • the lining pad of blower comprises a foaming urethane item, manufactured from a foaming process after the antimicrobial treatment as in the same manner as do in the lining pad of the said air-conditioning evaporator.
  • the duct, air tunnel of the antimicrobially treated automative air- conditioning system comprises a blow-molding product of polyethylene material; the piled dusts make the fungi to proliferate in duct due to difference in temperature, the antimicrobial treatment must be taken; as a basic material, polypropylene is added with the said isothiazoline or oxybisphenoxarsine in 0.5 - 1.5 t. %, a master batch is i o manufactured and through the common method, the blow molding is performed to obtain the antimicrobially treated duct.
  • the air-conditioning system consisting of each of antimicrobially treated component under a common fabrication method may inhibit the proliferation of fungi.
  • the manufactured air-conditioning evaporator, heater, blower and duct which are main components of the existing automative air- conditioning system, is under antimicrobial treatment by mixing a certain amount of antimicrobial agents to the existing molding materials.
  • the system can demonstrate their antimicrobial activities without change in physical properties C compared with the existing components.
  • any contamination of fungi may be prevented in the automative air-conditioning system, thus flowing fresh and clean air into the inside of automobile and maintaining the comfortable environment of inside without any bad odor.
  • the present invention is described in more detail based upon the following examples but the invention is not limited to the examples.
  • EXAMPLE 1 Antimicrobial treatment for air-conditioning evaporator 5
  • polypylene in 100 wt. part was prepared and then, the mixture was mixed with 2-n-octyl-4-isothiazoline-3-one in 0.1 wt. part for its pelletization in the compressor heated at 230"C .
  • a master batch is manufactured and at the temperature of 230 , , the housing of air-conditioning evaporator was manufactured by injection molding.
  • a foaming polyurethane resin (Manufacturer: Cheil urethanee Co., Korea) in 10 wt. part added with 10, lO'-oxybisphenoxarsine in 0.5 wt. pan was mixed homogeneously and a lining pad was manufactured following the foaming and molding process. 9 /1
  • a foaming polyurethane resin (Manufacturer: Cheil urethanee Co., Korea) in 10 wt. part, added with 10, 10' -oxybisphenoxarsine in 0.5 wt. part, was mixed homogeneously and a door pad of heater was manufactured following; the foaming and 5 molding process at the temperature of 20 ⁇ 301-: .
  • a heater was manufactured using the existing heater (Manufacturer: Halla Co., Korea) whose door pad was antimicrobially treated.
  • EXAMPLE 6 and heaters were manufactured in parallel with the composition of antimicrobial agent as shown in Table 2.
  • Blowing-fan 10 10' -oxybisphenoxarsine 0.3 0.5 1.0 1.5 2.0
  • the housing manufactured from the EXAMPLE 1 was denominated as specimen A and B by adding 2-n-octyl-4-isothiazoline-3-on in the EXAMPLE 1, 2; the housing was denominated as specimen D, E by adding 10, lO'-oxybispenoxarsine; in order to compare the effect of two antimicrobial agents as above, another specimen was denominated as specimen C by adding another sample of antimicrobial agent. The size of each specimen was made by 1 x 1cm and the antimicrobial test was made on agar plate medium.
  • Test strains were prepared in the following method; the strains were inoculated into a medium of American Association of Textile Chemists and Colorists(AATCC) by using Ami platinum loop under the medium condition of pH 7.0 - 7.2 and then, cultured at the temperature of 37 Xl for 24 hours.
  • AATCC American Association of Textile Chemists and Colorists
  • a ATCC agar While sterilized samples of strain were placed on a plate of agar medium, a necessary amount of A ATCC agar was dissoluted in a test tube or flask, cooled at 45 "C , and cultured for 24 hours. In proportion to 150ml of AATCC agar, 1 ml of the cultured strains are injected and after 15 minutes, the mixture was used as a medium. After placing the test strains on the medium, the plate medium was cultured at the temperature of 37 * C for 24 hours.
  • the above photo shows the design illustrated in Fig. 2.
  • the above Table demonstrates antimicrobial acivities by calculating the formation scope of lower region in accordance with Paragraph 2, Article 8 of Korean Standard K 0692-1991.
  • +++ Excellent (more than 3mm in the formation scope of lower region), 5 ++ : Good (more than l ⁇ 3mm in the formation scope of lower region), + : Fair (less than 1mm in the formation scope of lower region), : Poor (no formation of lower region).
  • TEST 2 i c Among the antimicrobially-treated components, the antimicrobial activity test on a housing product in polypropylene resin was made after aging test. The test conditions of antimicrobial activity were established in the same manner as did in the above Test 1 and the microbial activity on Candida albicans and Cladosporium cucumerinum were made. About five kinds of housing specimen A, B, C, D, and E,
  • a specimen was left in a flowing water at 3012 - 3512 for 10 - 15 days and then, the aging specimen was prepared.
  • shock aging A specimen was left at -3012 - 4512 for 15 - 20 hours and immediately, it was dipped into a warm water at 7012 - 9012 for 5 minutes. Then, the aging specimen was prepared.
  • the antimicrobial activity tests on polyethylene pad, polyurethane pad, and polyurethane lining pad were made after aging test respectively.
  • the test conditions of antimicrobial activity were established in the same manner as did in the above Test 1 and the microbial activity on Candida albicans and Cladosporium cucumerinum were made.
  • About well-closed polyethylene pad of air-conditioning evaporator, polyurethane door pad, and polyurethane lining pad of blower manufactured from the above EXAMPLES 3 several aging tests such as environment aging , water-proof aging, heat aging and shock aging were made so as to determine the antimicrobial activity under the following conditions and the results were as shown in Table 10 -11.
  • the aging conditions are the same as did in the above Test 2.
  • Table 10 - 1 the control was not provided with the aging condition.
  • Table 10 Well-closed pad of polyethylene
  • the antimicrobial test on the core of air-conditioning evaporator was performed based on a method of JIS Z2911; according to this method, spore solution was dipped into a test specimen, cultured at 28 ⁇ 2 "C for 28 days and at 7-day intervals, the growth of molds were observed.
  • used was the test specimen where the antimicrobial colouring agent was applied to the core manufactured from the above EXAMPLE 1. The results were as shown in the following Table 13.
  • the mold spores used in the Test 4 were as follows:
  • the IZOD impact strength was measured at room temperature.
  • the antimicrobially treated components demostrated the excellent antimicrobial activity and various kinds of physical properties proved good in comparison with the control group in non-treatment.

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  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
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Abstract

L'invention concerne un système d'air conditionné de véhicules automobiles comprenant un évaporateur d'air conditionné, un dispositif de chauffage, une soufflante et un conduit, caractérisé en ce que de la matière plastique de l'enceinte, ou du rembourrage bien renfermé et du rembourrage de garniture de l'évaporateur d'air conditionné, du rembourrage de la porte de l'enceinte du dispositif chauffant, de la soufflante et du rembourrage de garnissage de la soufflante et du conduit sont moulés en mélangeant le composé antimicrobien sélectionné parmi les isothiazolines et les oxybisphénoxarsines, et du matériau à base d'aluminium du noyau de l'évaporateur d'air conditionné subit un traitement antimicrobien sous la forme d'un revêtement à base d'un agent de coloration hydrophile mélangé avec la composition antimicrobienne de parachlorométa xylénol.
PCT/KR1994/000162 1994-11-11 1994-11-11 Procede de traitement antimicrobien pour systeme d'air conditionne des vehicules automobiles WO1996014882A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PCT/KR1994/000162 WO1996014882A1 (fr) 1994-11-11 1994-11-11 Procede de traitement antimicrobien pour systeme d'air conditionne des vehicules automobiles
EP95900318A EP0790838A1 (fr) 1994-11-11 1994-11-11 Procede de traitement antimicrobien pour systeme d'air conditionne des vehicules automobiles
AU81176/94A AU8117694A (en) 1994-11-11 1994-11-11 Antimicrobial treatment method for automative air-conditioning system
JP8515933A JPH09511941A (ja) 1994-11-11 1994-11-11 自動車用共助システムの抗菌処理方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/KR1994/000162 WO1996014882A1 (fr) 1994-11-11 1994-11-11 Procede de traitement antimicrobien pour systeme d'air conditionne des vehicules automobiles

Publications (1)

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WO1996014882A1 true WO1996014882A1 (fr) 1996-05-23

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PCT/KR1994/000162 WO1996014882A1 (fr) 1994-11-11 1994-11-11 Procede de traitement antimicrobien pour systeme d'air conditionne des vehicules automobiles

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EP (1) EP0790838A1 (fr)
JP (1) JPH09511941A (fr)
AU (1) AU8117694A (fr)
WO (1) WO1996014882A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004099308A1 (fr) * 2003-05-12 2004-11-18 Lg Electronics Inc. Composition en plastique antimicrobienne et machine a laver comprenant des elements fabriques a partir de cette composition
EP1612317A3 (fr) * 2004-06-30 2006-03-29 Schott AG Elément de construction dopé par un bactériozide pour un lave-linge ou un sèche-linge
CN105264063A (zh) * 2012-12-21 2016-01-20 现代自动车株式会社 包含无气味微生物的用于防止气味的组合物
EP3081650A4 (fr) * 2013-12-10 2017-08-02 Hyundai Motor Company Procédé de criblage d'un agent antimicrobien
US10047663B2 (en) 2014-04-29 2018-08-14 Dana Canada Corporation Charge air cooler with multi-piece plastic housing

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2013792A1 (de) * 1969-04-03 1970-10-15 Mobay Chemical Company, Pittsburgh Pa. (V.St.A.) Gegen mikrobiologischen Abbau stabilisierte Polyurethane
JPS62182298A (ja) * 1986-01-17 1987-08-10 Nippon Alum Mfg Co Ltd:The 抗菌・防黴性複合皮膜付アルミニウム製品
JPS62276396A (ja) * 1986-05-22 1987-12-01 Toshiba Corp 熱交換器
JPS63301251A (ja) * 1987-06-02 1988-12-08 Dai Ichi Kogyo Seiyaku Co Ltd 塗料組成物
WO1992010530A1 (fr) * 1990-12-13 1992-06-25 Akzo N.V. Concentre essentiellement solide comprenant un agent biocide
JPH0525319A (ja) * 1991-07-17 1993-02-02 Daiwa Kagaku Kogyo Kk プラスチツク用防黴剤組成物
US5314719A (en) * 1993-03-18 1994-05-24 Foster Products Corporation Fungicidal protective coating for air handling equipment

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2013792A1 (de) * 1969-04-03 1970-10-15 Mobay Chemical Company, Pittsburgh Pa. (V.St.A.) Gegen mikrobiologischen Abbau stabilisierte Polyurethane
JPS62182298A (ja) * 1986-01-17 1987-08-10 Nippon Alum Mfg Co Ltd:The 抗菌・防黴性複合皮膜付アルミニウム製品
JPS62276396A (ja) * 1986-05-22 1987-12-01 Toshiba Corp 熱交換器
JPS63301251A (ja) * 1987-06-02 1988-12-08 Dai Ichi Kogyo Seiyaku Co Ltd 塗料組成物
WO1992010530A1 (fr) * 1990-12-13 1992-06-25 Akzo N.V. Concentre essentiellement solide comprenant un agent biocide
JPH0525319A (ja) * 1991-07-17 1993-02-02 Daiwa Kagaku Kogyo Kk プラスチツク用防黴剤組成物
US5314719A (en) * 1993-03-18 1994-05-24 Foster Products Corporation Fungicidal protective coating for air handling equipment

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, Vol. 109, No. 2, 11 July 1988, (Columbus, Ohio, USA), EGUCHI H., "Heat Exchangers for Air Conditioning", page 291, Abstract No. 11091a; & JP,A,62 276 396. *
CHEMICAL ABSTRACTS, Vol. 111, No. 6, 07 August 1989, (Columbus, Ohio, USA), WADA S. et al., "Bacteria- and Mildew- Resistant Polyurethane Coating Compositions", page 123, Abstract No. 41492r; & JP,A,63 301 251. *
CHEMICAL ABSTRACTS, Vol. 119, No. 6, 09 August 1993, (Columbus, Ohio, USA), FUJITA R., "Antifungal Compositions for Plastics", page 58, Abstract No. 50655p; & JP,A,05 025 319. *
CHEMICAL ABSTRACTS, Vol. 74, No. 4, 25 January 1971, (Columbus, Ohio, USA), KEMP H.T. et al., "10,10'-Oxydiphenoxarsine to Inhibit Decomposition of Polyrethanes by Fungi", page 29, Abstract No. 13842d; & DE,A,2 013 792. *
PATENT ABSTRACTS OF JAPAN, Section C, Vol. 12, No. 33, 1988; & JP,A,62 182 298 (NIPPON ALUM MFG CO LTD) THE(1). *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004099308A1 (fr) * 2003-05-12 2004-11-18 Lg Electronics Inc. Composition en plastique antimicrobienne et machine a laver comprenant des elements fabriques a partir de cette composition
US7371789B2 (en) 2003-05-12 2008-05-13 Lg Electronics Inc. Anti-microbial plastic composition and washing machine comprising the parts manufactured by using the same
AU2004236557B2 (en) * 2003-05-12 2009-08-06 Lg Electronics Inc. Anti-microbial plastic composition and washing machine comprising the parts manufactured by using the same
EP1612317A3 (fr) * 2004-06-30 2006-03-29 Schott AG Elément de construction dopé par un bactériozide pour un lave-linge ou un sèche-linge
CN105264063A (zh) * 2012-12-21 2016-01-20 现代自动车株式会社 包含无气味微生物的用于防止气味的组合物
EP2937414A4 (fr) * 2012-12-21 2016-06-15 Hyundai Motor Co Ltd Composition pour la prévention des odeurs comprenant des microorganismes inodores
CN105264063B (zh) * 2012-12-21 2018-12-11 现代自动车株式会社 包含无气味微生物的用于防止气味的组合物
US10716872B2 (en) 2012-12-21 2020-07-21 Hyundai Motor Company Composition for preventing odors containing odorless microorganism
EP3081650A4 (fr) * 2013-12-10 2017-08-02 Hyundai Motor Company Procédé de criblage d'un agent antimicrobien
RU2696200C1 (ru) * 2013-12-10 2019-07-31 Хендэ Мотор Компани Способ скрининга противомикробного реагента
US10047663B2 (en) 2014-04-29 2018-08-14 Dana Canada Corporation Charge air cooler with multi-piece plastic housing

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