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WO1996026990A1 - Liquides de refroidissement resistants au gel et exempts de glycol - Google Patents

Liquides de refroidissement resistants au gel et exempts de glycol Download PDF

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Publication number
WO1996026990A1
WO1996026990A1 PCT/HU1996/000011 HU9600011W WO9626990A1 WO 1996026990 A1 WO1996026990 A1 WO 1996026990A1 HU 9600011 W HU9600011 W HU 9600011W WO 9626990 A1 WO9626990 A1 WO 9626990A1
Authority
WO
WIPO (PCT)
Prior art keywords
liquid
mass
corrosion
glycol
heat
Prior art date
Application number
PCT/HU1996/000011
Other languages
English (en)
Inventor
József KERTI
Józsefné KERTI
Péter Kardos
Tibor Kálmán
Original Assignee
Kerti Jozsef
Kerti Jozsefne
Kardos Peter
Kalman Tibor
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kerti Jozsef, Kerti Jozsefne, Kardos Peter, Kalman Tibor filed Critical Kerti Jozsef
Priority to AU48886/96A priority Critical patent/AU4888696A/en
Priority to SK1183-97A priority patent/SK282138B6/sk
Publication of WO1996026990A1 publication Critical patent/WO1996026990A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08—Materials not undergoing a change of physical state when used
    • C09K5/10—Liquid materials
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids

Definitions

  • the invention relates to glycol-free, frost resistant cooling and heat transference liquids on potassium-acetate - potassium formate basis, as im ⁇ provement to the solution of Hungarian patent No. 203 776, having the same subject matter.
  • Said patent gives detailed discussion and summary of the state of the prior art and indicates the task aiming at a more advantagous satisfaction of need compared to it.
  • the goal to be achieved by the present patent application lies in an improvement by modificating of the liquid's com ⁇ position ensuring an efficacious protection against corrosion even if having been mixed with usually applied cooling liquids on glycol basis and meeting the more exacting hygienic requirements in heat exchangers of water for consumption as well as in heating systems, such as in radiators.
  • the achievement of the aim set recently could be based on the obser ⁇ vation that, if a water-soluble lubricant, preferably glycerine is added to the heattransferene liquid in a ratio of about 4 to 6 mass%, this lubricant, be ⁇ sides protecting the mobile metallic surfaces against friction, can impede the formation of the local concentration ceils and, in this way, so can the possi ⁇ bility of the pitting and crevice corrosion even at identic inhibitor composition by ensuring the uniform distribution of the inhibitors in the adhering liquid film.
  • a water-soluble lubricant preferably glycerine
  • the liquid may contain in a given case besides the glycerine and the usual quantity of the other inhibitors listed, benzo-and tolyl-triazoie respectively.
  • the present invention is characterized in that the frost resistant cooling and heat-transference liquids contain as erosion-and corrosion hin ⁇ dering components 4-6 mass% glycerine, 0,8-0,9 mass% alkali-benzoate, 0,08-0,12 mass% alkali-polymetaphosphate and 0,02-0,04 mass% borax, and in a given case 0,15-0,20 mass% benzo-or tolyl-triazoie.
  • Example 1 Moderately frost resistant cooling liquid variety One ton liquid is produced by blending of 649,3 kg water, 189,4 kg caustic potash solution of 50 w%, 84 kg acetic acid solution of 96 w%, 16 kg formic acid solution of 99 w%, 50 kg glycerine of technical quality, 8,3 kg sodium-benzoate, 1 ,7 kg tolyl-triazoie, 0,5 kg sodium-trimeta-phosphate, 0,5 kg sodium-hexametaphosphate and 0.3 kg borax (dissolving under stirring and cooling).
  • the concentration of the acids and that of the alkali may obvi- sously be different from that as it is given above. If so, the proportions are to be varied according to the sense.
  • the crystal point of the liquid produced in this way (in other words: its theoretic, i.e. thermodynamic freezing point) is - 10°C but the separated, loose crystals containing liquid can be used even at -16°C (lower temperature
  • Example 3 Cooling liquid variety frost resistant in an increased degree To one ton of the make 216,1 kg water is blended with 472,6 kg caus ⁇ tic potash of 50 w%, 210 kg acetic acid of 96% and 40 kg formic acid of 99 w%, the further components are unchanged.
  • the crystal point of the liquid produced in this way is -45°C, its lower temperature limit, however, is -70°C.
  • optional other varieties can also be manufactured by interpolation, according to the prescribed frost resis ⁇ tance.
  • the given freezing points do not practically change if the liquids are blended with ones on glycol basis of identic freezing point.
  • the mixing of liquids of different freezing point results in freezing point that can be esti ⁇ mated by proportionate interpolation.
  • Another important advantage of the inhibotor composition elaborated is inherent in its compatibility with the in ⁇ hibitors generally used in antifreeze makes on glycol basis. All these enables to keep the inhibitors' concentration constant, independently of that of the freezing point depressants, as shown in the examples. In this way it can be attained, that the liquid is not diluted with respect to the inhibitors but will contain their optimum concentration, regardless of whatever dilution needed corresponding to the lesser frost resistance requirement.
  • Middling frost resistant liquid of health safety in an increased degree To one ton of the product 523,8 kg water, 272,6 kg caustic potash of 50 w%, 121 kg acetic acid of 96 w%, 23 kg formic acid of 99 w%, 50 kg glycerine, 8,3 kg sodium-benzoate.
  • 0,5 kg sodium-trimetaphosphate, 0,5 kg sodium-hexametaphosphate and 0,3 kg borax are to be blended.
  • the crystal point of the liquid is -23°C, whilst its lower temperature limit is -36°C.
  • the pH of the liquids manufactured in the treated way is in any case in the range of 8,7 ⁇ 0,1. If there is a departure therefrom due to the fluctuation of the components' water content, a small quantity of acid or alkali is to be added to set the pH prescribed.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

Liquide de refroidissement caloporteur et résistant au gel. Ce liquide est à base d'acétate de potassium et de formiate de potassium, et il renferme, à titre de constituants inhibant l'érosion et la corrosion, de 4 à 6 % en poids de glycérine, de 0,8 à 0,9 % en poids de benzoate alcalin, de 0,08 à 0,12 % en poids de polymétaphosphates alcalins, et de 0,02 à 0,04 % en poids de borax. On maintient à une valeur optimale la concentration des constituants inhibant l'érosion et la corrosion, et ce, indépendamment de la teneur en eau du liquide. Selon un mode de réalisation, il s'agit de 0,15 à 0,20 % en poids de triazole benzoïque ou tolylique.
PCT/HU1996/000011 1995-03-01 1996-02-29 Liquides de refroidissement resistants au gel et exempts de glycol WO1996026990A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU48886/96A AU4888696A (en) 1995-03-01 1996-02-29 Glycol-free frost resistant cooling liquids
SK1183-97A SK282138B6 (sk) 1995-03-01 1996-02-29 Multikomponentná mrazuvzdorná chladiaca a teplonosná kvapalina

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
HU9500624A HU214046B (en) 1995-03-01 1995-03-01 Antifreeze cooling and calorifer liquid free from glycol
HUP9500624 1995-03-01

Publications (1)

Publication Number Publication Date
WO1996026990A1 true WO1996026990A1 (fr) 1996-09-06

Family

ID=10986552

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/HU1996/000011 WO1996026990A1 (fr) 1995-03-01 1996-02-29 Liquides de refroidissement resistants au gel et exempts de glycol

Country Status (5)

Country Link
AU (1) AU4888696A (fr)
CZ (1) CZ286256B6 (fr)
HU (1) HU214046B (fr)
SK (1) SK282138B6 (fr)
WO (1) WO1996026990A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999009108A1 (fr) * 1997-08-18 1999-02-25 Clariant Gmbh Sols refrigerants de faible viscosite a proprietes anticorrosion ameliorees
WO2001005906A1 (fr) * 1999-07-16 2001-01-25 Texaco Development Corporation Associations synergiques de carboxylates utilises comme additifs antigels et inhibiteurs de corrosion dans des fluides de transfert thermique
US6221276B1 (en) * 1995-10-17 2001-04-24 Abb Installaatiot Oy Heat transfer liquid with potassium formate for ventilation and air conditioning installations
CN1304520C (zh) * 2003-11-13 2007-03-14 杨毅男 一种有机盐汽车冷却液
US7638069B2 (en) 2005-12-29 2009-12-29 Texaco Inc. Potassium propionates for use as freezing point depressants and corrosion protection in heat transfer fluids
US7704406B2 (en) 2002-08-02 2010-04-27 Basf Aktiengesellschaft Glycol-free aqueous antifreeze compositions comprising dicarboxylic acid salts
WO2017009652A1 (fr) * 2015-07-14 2017-01-19 Kilfrost Group Plc Composition de fluide caloporteur et utilisation
CN113490821A (zh) * 2019-02-08 2021-10-08 株式会社电装 热传输介质及热传输系统
JP2023527743A (ja) * 2020-05-17 2023-06-30 バイオベース・スウェーデン・アクチエボラグ 熱移動流体

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0306972A1 (fr) * 1987-09-10 1989-03-15 Eszakmagyarországi Vegyimüvek Fluide de refroidissement résistant au gel et ne contenant pas de glycol
EP0345613A1 (fr) * 1988-06-07 1989-12-13 Hoechst Aktiengesellschaft Fluides fonctionnels à base de glycols, inhibiteurs de la corrosion et physiologiquement favorables
US5079036A (en) * 1990-07-27 1992-01-07 Betz Laboratories, Inc. Method of inhibiting freezing and improving flow and handleability characteristics of solid, particulate materials
EP0573287A1 (fr) * 1992-06-03 1993-12-08 Texaco Development Corporation Inhibiteurs de la corrosion pour fluides de transfert de chaleur

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0306972A1 (fr) * 1987-09-10 1989-03-15 Eszakmagyarországi Vegyimüvek Fluide de refroidissement résistant au gel et ne contenant pas de glycol
EP0345613A1 (fr) * 1988-06-07 1989-12-13 Hoechst Aktiengesellschaft Fluides fonctionnels à base de glycols, inhibiteurs de la corrosion et physiologiquement favorables
US5079036A (en) * 1990-07-27 1992-01-07 Betz Laboratories, Inc. Method of inhibiting freezing and improving flow and handleability characteristics of solid, particulate materials
EP0573287A1 (fr) * 1992-06-03 1993-12-08 Texaco Development Corporation Inhibiteurs de la corrosion pour fluides de transfert de chaleur

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6221276B1 (en) * 1995-10-17 2001-04-24 Abb Installaatiot Oy Heat transfer liquid with potassium formate for ventilation and air conditioning installations
US6059996A (en) * 1997-08-12 2000-05-09 Clariant Gmbh Low-viscosity coolant brines having improved corrosion protection
WO1999009108A1 (fr) * 1997-08-18 1999-02-25 Clariant Gmbh Sols refrigerants de faible viscosite a proprietes anticorrosion ameliorees
EP1449903A3 (fr) * 1999-07-16 2008-03-19 Texaco Development Corporation Combinaisons synergiques de carboxylates pour l'utilisation comme agents d'abaissement du point de congélation et inhibiteurs de corrosion dans des fluides de transfert de chaleur
WO2001005906A1 (fr) * 1999-07-16 2001-01-25 Texaco Development Corporation Associations synergiques de carboxylates utilises comme additifs antigels et inhibiteurs de corrosion dans des fluides de transfert thermique
US6689289B1 (en) * 1999-07-16 2004-02-10 Texaco Inc. Synergistic combinations of carboxylates for use as freezing point depressants and corrosion inhibitors in heat transfer fluids
RU2240338C2 (ru) * 1999-07-16 2004-11-20 Тексако Дивелопмент Корпорейшн Синергетические комбинации карбоксилатов для применения в качестве депрессоров температуры замерзания и ингибиторов коррозии в жидких теплоносителях
EP1087004A1 (fr) * 1999-07-16 2001-03-28 Texaco Development Corporation Combinaisons synergiques de carboxylates pour l'utilisation comme agents d'abaissement du point de congélation et inhibiteurs de corrosion dans des fluides de transfert de chaleur
CZ298580B6 (cs) * 1999-07-16 2007-11-14 Texaco Development Corporation Kapalný prostredek pro prevod tepla a jeho použití
CZ298867B6 (cs) * 1999-07-16 2008-02-27 Texaco Development Corporation Použití prostredku obsahujícího smes karboxylátu jako chladicího prostredku u automobilových motoru
US7704406B2 (en) 2002-08-02 2010-04-27 Basf Aktiengesellschaft Glycol-free aqueous antifreeze compositions comprising dicarboxylic acid salts
EP2428542A2 (fr) 2002-08-02 2012-03-14 Basf Se antigels aqueux sans glycol contenant des sels d'acides dicarboxyliques
US8202444B2 (en) 2002-08-02 2012-06-19 Basf Aktiengesellschaft Glycol-free aqueous anti-freeze agent containing dicarboxylic salts
CN1304520C (zh) * 2003-11-13 2007-03-14 杨毅男 一种有机盐汽车冷却液
US7638069B2 (en) 2005-12-29 2009-12-29 Texaco Inc. Potassium propionates for use as freezing point depressants and corrosion protection in heat transfer fluids
WO2017009652A1 (fr) * 2015-07-14 2017-01-19 Kilfrost Group Plc Composition de fluide caloporteur et utilisation
CN108138033A (zh) * 2015-07-14 2018-06-08 奇尔弗特集团股份有限公司 传热流体组合物及用途
US11292949B2 (en) 2015-07-14 2022-04-05 Kilfrost Group Plc Heat transfer fluid composition and use
CN113490821A (zh) * 2019-02-08 2021-10-08 株式会社电装 热传输介质及热传输系统
JP2023527743A (ja) * 2020-05-17 2023-06-30 バイオベース・スウェーデン・アクチエボラグ 熱移動流体

Also Published As

Publication number Publication date
SK118397A3 (en) 1998-01-14
CZ269497A3 (cs) 1998-05-13
CZ286256B6 (cs) 2000-02-16
SK282138B6 (sk) 2001-11-06
AU4888696A (en) 1996-09-18
HU214046B (en) 1997-12-29
HUT76029A (en) 1997-06-30
HU9500624D0 (en) 1995-04-28

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