WO1996034833A1 - Procede et dispositifs permettant d'ameliorer l'aptitude a la deshydratation mecanique de boues de curage - Google Patents
Procede et dispositifs permettant d'ameliorer l'aptitude a la deshydratation mecanique de boues de curage Download PDFInfo
- Publication number
- WO1996034833A1 WO1996034833A1 PCT/DE1996/000740 DE9600740W WO9634833A1 WO 1996034833 A1 WO1996034833 A1 WO 1996034833A1 DE 9600740 W DE9600740 W DE 9600740W WO 9634833 A1 WO9634833 A1 WO 9634833A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sludge
- freezing
- thawing
- mechanical
- sewage sludge
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 41
- 239000010801 sewage sludge Substances 0.000 title claims abstract description 29
- 230000008569 process Effects 0.000 title claims abstract description 19
- 239000010802 sludge Substances 0.000 claims abstract description 47
- 238000010257 thawing Methods 0.000 claims abstract description 24
- 238000007710 freezing Methods 0.000 claims abstract description 23
- 230000008014 freezing Effects 0.000 claims abstract description 23
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims description 9
- 230000003750 conditioning effect Effects 0.000 claims description 6
- 238000005057 refrigeration Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 230000000813 microbial effect Effects 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000002918 waste heat Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 19
- 210000004027 cell Anatomy 0.000 abstract description 11
- 244000005700 microbiome Species 0.000 abstract description 6
- 210000002421 cell wall Anatomy 0.000 abstract description 4
- 230000006378 damage Effects 0.000 abstract description 3
- 239000003570 air Substances 0.000 description 11
- 230000029087 digestion Effects 0.000 description 6
- 239000010865 sewage Substances 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 238000011105 stabilization Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000010426 asphalt Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002817 coal dust Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 239000010841 municipal wastewater Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/18—Treatment of sludge; Devices therefor by thermal conditioning
- C02F11/20—Treatment of sludge; Devices therefor by thermal conditioning by freezing
Definitions
- the invention relates to a method for improving the mechanical dewaterability of aqueous sludges with a considerable microbial content and devices for carrying out the method.
- sludges occur in very large quantities, particularly in municipal sewage treatment plants, but also in agriculture and in the treatment of industrial waste water in waste water treatment plants with at least one biological treatment stage. Representing such sludges, the invention is described below for sewage sludge from the disposal of municipal wastewater.
- Sewage sludge is so difficult to dewater mechanically because the cell water bound within the cells of the microorganisms cannot be removed with the usual presses and centrifuges and the water contained in the slime layers on the surface of the microorganisms can be removed at most to a small extent.
- An aerobic or anaerobic stabilization improves the dewaterability, since the biomass and thus the amount of cell water is reduced and because the ratio of organic mass to inorganic mass in the sludge is thereby reduced.
- the best results in terms of low odor and improvement in drainability are obtained with the mesophile Digestion of sewage sludge, ie during anaerobic digestion at approx. 35 ° C.
- the invention has for its object to improve the mechanical dewaterability of aqueous sludges with a considerable microbial content, in particular of municipal sewage sludge, and to avoid the disadvantages of the known methods for improving dewaterability.
- the first stage of the mechanical dewatering most of the water contained in the sludge between the microorganisms is removed, and in the second stage cell water is additionally removed from the cells destroyed by the freezing process.
- mechanical dewatering devices of different designs and sizes adapted to the respective sludge properties can be used.
- the water separated in the second stage is particularly nutrient-rich due to the contents of the cell water and therefore has a particularly high biological oxygen requirement. An introduction into a digestion tower, if there is one, is therefore more advantageous than introducing this water into the activated sludge basin of the sewage treatment plant.
- the injury according to the invention to the cell walls of the microorganisms contained in the sludge is also advantageous for thermal drying.
- the process according to the invention can also considerably improve the mechanical dewaterability of excess activated sludge, which is far more difficult to dewater than digested sludge.
- the time-consuming aerobic or anaerobic stabilization of the sludge and the expensive devices for carrying out such sludge stabilization are not required in this case.
- the proportion of inorganic substances in the excess sludge of municipal sewage treatment plants is typically about 1/3 before digestion and about 1/2 after digestion, the application of the process according to the invention to excess activated sludge and subsequent thermal drying also gives a larger amount of fuel with a higher calorific value than when used on digested sewage sludge.
- the dried sewage sludge can be used to substitute fossil fuels, for example when used in cement kilns, asphalt mixing plants, waste incineration plants, etc.
- the slag resulting from the combustion of the sewage sludge can also be used mixed with the raw materials and thus used.
- auxiliaries such as coal dust or polymers for the conditioning, by means of which the calorific value of the dried sludge does not deteriorate but rather The opposite is improved.
- the process according to the invention is also suitable for sludge to which no conditioning agents have been added.
- FIGS. 1 and 2 which are described in more detail below, have some special advantages.
- FIG. 1 shows schematically the essential parts of a system for freezing and thawing pre-dewatered sewage sludge 1.
- This sludge is applied to a conveyor belt 3 from a storage container 2 with the aid of a conveyor device not shown in FIG. 1, for example a thick matter pump.
- this conveyor belt has a high proportion of gaps, as is the case, for example, with wire link belts.
- the mesh size is chosen so small that no sludge falls through the mesh. Since a puncture-resistant sludge can be produced with various of the drainage devices normally used, this requirement can be met without difficulty.
- the sludge applied to the conveyor belt 3 is frozen using a refrigeration system.
- the conveyor belt is moved with the aid of a drive device (not shown in FIG.
- the sludge which is generally frozen on the conveyor belt, does not have to be rearranged for thawing.
- the sludge passes into a container 5 via a discharge device 4, which also contains a conveying device which may be necessary but is not shown in FIG. 1, for example a thick matter pump Device for mechanical drainage 6 supplied.
- the sludge 7 dewatered in this device 6 can, for example, be a device for thermal drying are fed, and the separated water 8 can, for example, be returned to the sewage treatment plant or passed into a digestion tower which may be present.
- the freezing and thawing process is carried out with the aid of a compression refrigeration system with a compressor 9, a condenser 10, an evaporator 11 and an expansion valve 12.
- the heat required to evaporate the refrigerant is supplied to the evaporator by circulating air, which extracts the corresponding heat from the sludge on the conveyor belt.
- the speed of the conveyor belt 3 and the layer height of the sludge on the conveyor belt are set so that the sludge completely freezes in the freezing area.
- the air is circulated in the freezing area by fans, which are usually components of air-cooled refrigeration system evaporators 11. If these fans are not sufficient to generate an adequately large air flow, an additional fan, which is not shown in FIG. 1, can be installed.
- ambient air 13 is passed through the condenser 10 of the refrigeration machine and is thereby heated. With the help of the heated air, the sludge is thawed.
- the heat output transmitted on the condenser 10 corresponds to the sum of the cooling output transmitted on the evaporator 11 and the compressor output. A greater heat output is therefore available than is required for thawing.
- the air used for thawing is not completely saturated with water vapor, a small amount of water is also extracted from the sludge during the thawing process.
- the air can be circulated as in the freezing area. A circulation of the air in the thawing area is advantageous if the exhaust air from this area has to be cleaned.
- the sludge should lie as loosely as possible with a crumbly structure on the conveyor belt so that the air can flow through the sludge layer without difficulty.
- a crumbly structure can generally be achieved with mechanical sewage sludge dewatering. If there is no crumbly structure at the outlet of a conveyor device installed between the storage container 2 and the conveyor belt 3, such a structure can be produced by simple comminution devices downstream of the conveyor device, for example perforated sheets or else by more complex commercially available granulators .
- the mechanically pre-dewatered sludge 1 is introduced from a storage container 2 via a conveying and granulating device 14 into a fluidized bed 15, which is fluidized by an air flow which is circulated and cooled by the evaporator of a refrigerator.
- a fluidized bed 15 which is fluidized by an air flow which is circulated and cooled by the evaporator of a refrigerator.
- the frozen sludge granulate is conveyed into a thawing device 16, which is shown only schematically in FIG. 2 and which also includes the condenser of the refrigerator.
- Thawing can be carried out like the freezing process in a fluidized bed or, as shown in FIG. 1, in a flowed-through layer lying on a conveyor belt.
- FIGS. 1 and 2 both have the advantage that frozen sludge on the surface of the device does not have to be removed with special devices such as scrapers or scratches.
- the method according to the invention can be carried out continuously with both devices, so that the cooling capacity of the refrigerator can be used for freezing and the waste heat of the refrigerator can be used simultaneously for thawing.
Landscapes
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment Of Sludge (AREA)
Abstract
Afin que l'aptitude à la déshydratation mécanique de boues de curage soit améliorée, ces dernières sont congelées, puis décongelées. Le processus de congélation altère les parois cellulaires des micro-organismes contenus dans les boues de curage, ce qui facilite l'écoulement de l'eau contenu dans ces cellules lors d'une opération subséquente de déshydratation mécanique des boues de curage décongelées. Ce procédé peut être appliqué en continu, la capacité frigorifique d'une machine frigorifique étant utilisée pour la congélation et la chaleur dégagée servant simultanément à la décongélation. Pour la mise en ÷uvre du procédé, des boues de curage prédéshydratées mécaniquement sont soit congelées dans une couche fluidisée, soit déposées sur une bande transporteuse (3) en vue de leur congélation ou de leur décongélation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU56437/96A AU5643796A (en) | 1995-04-29 | 1996-04-29 | Process and device for improving the mechanical dewaterabili ty of sewage sludge |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1995115862 DE19515862A1 (de) | 1995-04-29 | 1995-04-29 | Verfahren und Vorrichtungen zur Verbesserung der mechanischen Entwässerbarkeit von Klärschlamm |
| DE19515862.8 | 1995-04-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1996034833A1 true WO1996034833A1 (fr) | 1996-11-07 |
Family
ID=7760732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/DE1996/000740 WO1996034833A1 (fr) | 1995-04-29 | 1996-04-29 | Procede et dispositifs permettant d'ameliorer l'aptitude a la deshydratation mecanique de boues de curage |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU5643796A (fr) |
| DE (1) | DE19515862A1 (fr) |
| WO (1) | WO1996034833A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5974821A (en) * | 1997-05-12 | 1999-11-02 | Scherer; J. Stirling | System and method for channeled freeze processing of non-solid materials |
| DE10245214A1 (de) * | 2002-09-27 | 2004-04-08 | Ballies, Uwe, Dr.med. | Verfahren zum Entwässern von Faulschlamm |
| CN114735912A (zh) * | 2022-04-12 | 2022-07-12 | 南通爱可普环保设备有限公司 | 一种具有主动通风功能的带式污泥干化机 |
| CN115180794B (zh) * | 2022-08-01 | 2025-01-10 | 杨红兵 | 一种活性污泥快速解冻装置及方法 |
| GB202212257D0 (en) * | 2022-08-23 | 2022-10-05 | Stow Roger Valentine | Drying apparatus and associated drying process |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1182019A (en) * | 1967-11-09 | 1970-02-25 | Carves Simon Ltd | Improvements in or relating to the dewatering of sludge |
| DE2151064A1 (de) * | 1971-10-13 | 1973-04-19 | Linde Ag | Verfahren und vorrichtung zum entfernen der fluessigkeit aus einem gelartigen fluessigkeits-feststoff-gemisch |
| US3817048A (en) * | 1971-07-13 | 1974-06-18 | Water Res Ass | Dewatering sludges |
| GB1459175A (en) * | 1972-10-17 | 1976-12-22 | Atomic Energy Authority Uk | Treatment of sludges |
| JPS56155700A (en) * | 1980-05-07 | 1981-12-01 | Naomichi Fukushima | Method and apparatus for dehydration of excess sludge by freezing |
-
1995
- 1995-04-29 DE DE1995115862 patent/DE19515862A1/de not_active Withdrawn
-
1996
- 1996-04-29 WO PCT/DE1996/000740 patent/WO1996034833A1/fr active Application Filing
- 1996-04-29 AU AU56437/96A patent/AU5643796A/en not_active Abandoned
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1182019A (en) * | 1967-11-09 | 1970-02-25 | Carves Simon Ltd | Improvements in or relating to the dewatering of sludge |
| US3817048A (en) * | 1971-07-13 | 1974-06-18 | Water Res Ass | Dewatering sludges |
| DE2151064A1 (de) * | 1971-10-13 | 1973-04-19 | Linde Ag | Verfahren und vorrichtung zum entfernen der fluessigkeit aus einem gelartigen fluessigkeits-feststoff-gemisch |
| GB1459175A (en) * | 1972-10-17 | 1976-12-22 | Atomic Energy Authority Uk | Treatment of sludges |
| JPS56155700A (en) * | 1980-05-07 | 1981-12-01 | Naomichi Fukushima | Method and apparatus for dehydration of excess sludge by freezing |
Non-Patent Citations (1)
| Title |
|---|
| PATENT ABSTRACTS OF JAPAN vol. 006, no. 040 (C - 094) 12 March 1982 (1982-03-12) * |
Also Published As
| Publication number | Publication date |
|---|---|
| AU5643796A (en) | 1996-11-21 |
| DE19515862A1 (de) | 1996-10-31 |
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