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WO1996035647A1 - Procede de ralentissement de la vitesse de prise des ciments au phosphate de magnesium - Google Patents

Procede de ralentissement de la vitesse de prise des ciments au phosphate de magnesium Download PDF

Info

Publication number
WO1996035647A1
WO1996035647A1 PCT/AU1996/000284 AU9600284W WO9635647A1 WO 1996035647 A1 WO1996035647 A1 WO 1996035647A1 AU 9600284 W AU9600284 W AU 9600284W WO 9635647 A1 WO9635647 A1 WO 9635647A1
Authority
WO
WIPO (PCT)
Prior art keywords
magnesium
compound
cement
potassium
phosphate
Prior art date
Application number
PCT/AU1996/000284
Other languages
English (en)
Inventor
Peter Allan Williams
Gary Ralph Dennis
Nilmini Sureka Joshua
Brian Patrick Sloane
Original Assignee
James Hardie Research Pty. Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by James Hardie Research Pty. Limited filed Critical James Hardie Research Pty. Limited
Priority to AU54928/96A priority Critical patent/AU5492896A/en
Priority to EP96911867A priority patent/EP0830325A4/fr
Priority to JP8533606A priority patent/JPH11505204A/ja
Publication of WO1996035647A1 publication Critical patent/WO1996035647A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B9/00—Magnesium cements or similar cements
    • C04B9/04—Magnesium cements containing sulfates, nitrates, phosphates or fluorides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B12/00—Cements not provided for in groups C04B7/00 - C04B11/00
    • C04B12/02—Phosphate cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators or shrinkage compensating agents
    • C04B22/06—Oxides, Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators or shrinkage compensating agents
    • C04B22/08—Acids or salts thereof
    • C04B22/10—Acids or salts thereof containing carbon in the anion, e.g. carbonates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0094—Agents for altering or buffering the pH; Ingredients characterised by their pH
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/20—Retarders
    • C04B2103/22—Set retarders

Definitions

  • This invention relates to a method of slowing the setting rate of hydrated
  • the most commonly used hydrated cement is portland cement formed by
  • portland cement has
  • alkaline cement reaction products carbonate to calcium carbonate reducing its
  • magnesium ammonium phosphate (NH 4- vlgPO 4 .6H 2 O), commonly known as struvite, as a hydrated cement is well documented. This
  • ammonium phosphate cements have an initial setting time of about 1 to 5 minutes.
  • borax or halides such as sodium chloride or
  • Borax has disadvantages including in that it is
  • Chlorides in general are not desirable additives
  • Barium salts are not desirable in view of cost and toxicity problems.
  • this invention consists in a method for slowing the setting
  • the invention consists in a cementitious article formed
  • Suitable magnesium phosphate cements include ammonium magnesium phosphate cements and potassium magnesium phosphate cements (MgKPO 4 nH 2 O).
  • the cement is chosen depending on its end application.
  • magnesium phosphate cement is ammonium magnesium
  • a suitable base is ammonia.
  • the cement in order to prepare the cement, the
  • ammonia is added to mono ammonium phosphate to which magnesium oxide is
  • the ratio of ammonia to phosphate is 0.5-2.0: 1 , most
  • the ratio of magnesium to phosphate is 7-1 : 1 , most preferably 3:1.
  • Ratios of ammonia to phosphate above 2:1 tend to produce crumbly cements.
  • magnesium phosphate cement is a potassium magnesium
  • phosphate cement a suitable base is potassium hydroxide or potassium carbonate.
  • the base is preferably added to mono
  • potassium to phosphate is 0.5-2.0:1, most preferably 1:1 and the ratio of
  • magnesium to phosphate is 7- 1 : 1 , most preferably 3:1. Ratios of magnesium to phosphate greater than 7: 1 tend to result in cements having reduced setting times and
  • the invention consists in a method of slowing the setting
  • the invention consists in a method of slowing the
  • ammonium phosphate compound is preferably mono ammonium
  • the potassium compound is preferably potassium carbonate and the
  • magnesium compound is preferably magnesium oxide. It will be apparent, however, that other materials may be used as the source of phosphate, potassium and
  • the setting time of the hydrated cement according to this invention can be
  • the pH of the cement is controlled by adjusting the pH of the cement at the time of setting.
  • the pH of the cement is controlled by adjusting the pH of the cement at the time of setting.
  • the pH is preferably controlled by using
  • potassium carbonate is used as it has some
  • the hydrated cement prepared by the method of the invention can be any suitable material.
  • density modifiers such as flyash, expanded polystyrene beads,
  • cenospheres vermiculite, perlite or predigested calcium silicate hydrate.
  • additives can include fibre reinforcements such as cellulose, glass, polymer or
  • the hydrated cement can be prepared as a foam cement.
  • the magnesium potassium phosphate cement prepared by the method of this
  • the hydrated cement prepared according to this invention may be readily
  • the hydrated cement prepared according to this invention may be formed, for
  • the setting time may be further delayed by the addition of yet more water to
  • the method can form cements with various levels of hydration in terms of
  • the cement has a
  • oxide as the source of magnesium other materials may be used or the materials may be used.
  • the mole ratio of K 2 C0 3 :NH 4 H 2 PO 4 :MgO:H 2 O is suitably 1:2:6:6.
  • the purity of the raw materials is not crucial to the formation of the cement
  • the dry raw materials can be pre-packaged in
  • cements a two component hydrated cement mix comprising a first
  • water can be achieved by use of a meter or fixed volume containers.
  • cooling in a dissicator has been measured to be about 2% of the original length.
  • the pH of the cured magnesium potassium phosphate cement is suitably
  • magnesium potassium phosphate cement is not subject to any known reaction with
  • the applications of the cement according to this invention include:-
  • Example 1 Retarding an ammonium magnesium phosphate cement containing flvash.
  • This formulation corresponds to a mole ratio of NH 3 :NH 4 H 2 PO 4 :MgO:H 2 O
  • the mono ammonium phosphate, ammonia and water were first mixed
  • Example 2 Retarding a potassium magnesium phosphate cement optionally
  • the formulation used in this example was as follows:
  • This formulation corresponds to a mole ratio of K 2 CO 3 :NH 4 H 2 PO 4 :MgO:H 2 O
  • the mono ammonium phosphate was mixed with water and the potassium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

Procédé destiné à ralentir la vitesse de prise d'un ciment au phosphate de magnésium, consistant à ajouter une base appropriée à un mélange aqueux non curé ou partiellement curé du ciment au phosphate de magnésium en quantité suffisante pour élever le pH et réduire au minimum la dissolution MgO/Mg(OH)2. Les ciments au phosphate de magnésium appropriés incluent les ciments au phosphate ammoniacomagnésien et les ciments au phosphate de potassium-magnésium.
PCT/AU1996/000284 1995-05-10 1996-05-09 Procede de ralentissement de la vitesse de prise des ciments au phosphate de magnesium WO1996035647A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU54928/96A AU5492896A (en) 1995-05-10 1996-05-09 A method of slowing the setting rate of magnesium phosphate cements
EP96911867A EP0830325A4 (fr) 1995-05-10 1996-05-09 Procede de ralentissement de la vitesse de prise des ciments au phosphate de magnesium
JP8533606A JPH11505204A (ja) 1995-05-10 1996-05-09 燐酸マグネシウムセメントの硬化速度を遅延させる方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AUPN2911A AUPN291195A0 (en) 1995-05-10 1995-05-10 A hydrated composition
AUPN2911 1995-05-10

Publications (1)

Publication Number Publication Date
WO1996035647A1 true WO1996035647A1 (fr) 1996-11-14

Family

ID=3787259

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/AU1996/000284 WO1996035647A1 (fr) 1995-05-10 1996-05-09 Procede de ralentissement de la vitesse de prise des ciments au phosphate de magnesium

Country Status (5)

Country Link
EP (1) EP0830325A4 (fr)
JP (1) JPH11505204A (fr)
KR (1) KR19990014664A (fr)
AU (1) AUPN291195A0 (fr)
WO (1) WO1996035647A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6136088A (en) * 1997-10-09 2000-10-24 Mbt Holding Ag Rapid setting, high early strength binders
FR2809724A1 (fr) * 2000-06-05 2001-12-07 Rhodia Chimie Sa Nouveau liant hydraulique phosphomagnesien, et mortier obtenu a partir de ce liant
US6518212B1 (en) 2000-09-18 2003-02-11 The University Of Chicago Chemically bonded phospho-silicate ceramics
WO2004105939A1 (fr) 2003-05-27 2004-12-09 Lg Chem. Ltd. Catalyseur pour vapocraquage d'hydrocarbures, procede de preparation de ce dernier et procede de preparation d'olefines legeres dans lequel le catalyseur est utilise
US7462581B2 (en) * 2003-09-09 2008-12-09 Halliburton Energy Services, Inc. Treatment fluids comprising starch and ceramic particulate bridging agents and methods of using these fluids to provide fluid loss control
US7491267B2 (en) 2001-08-10 2009-02-17 Ceratech, Inc. Composite materials and methods of making and using such composite materials
US8523997B2 (en) 2010-01-14 2013-09-03 Engineered Arresting Systems Corporation Cellular phosphate ceramics and methods of manufacture and use
CN113562998A (zh) * 2021-08-24 2021-10-29 北京科技大学 一种用镁矿石粉制备磷酸镁水泥净浆的方法
CN115724643A (zh) * 2022-11-01 2023-03-03 辽宁科技大学 一种可控水化反应的高耐火磷酸镁水泥基材料及制备方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100322856B1 (ko) * 1999-06-30 2002-02-09 노재연 석고 및 시멘트의 수화 반응 지연제
DE10032220A1 (de) * 2000-07-03 2002-01-24 Sanatis Gmbh Magnesium-ammonium-phosphat-Zemente, deren Herstellung und Verwendung
CN120504508B (zh) * 2025-07-21 2025-09-19 西安石油大学 一种改性磷酸钾镁水泥及其应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2522548A (en) * 1946-10-03 1950-09-19 Thoger G Jungersen Method of making a phosphate gel and mold with phosphate gel binder
US3960580A (en) * 1974-11-21 1976-06-01 W. R. Grace & Co. Magnesium phosphate concrete compositions
US4436555A (en) * 1982-09-23 1984-03-13 The United States Of America As Represented By The United States Department Of Energy Magnesium phosphate glass cements with ceramic-type properties
US4444594A (en) * 1982-12-09 1984-04-24 Armstrong World Industries, Inc. Acid cured inorganic binder compositions which are compatible with mineral wool
AU4347385A (en) * 1984-06-27 1986-01-02 J.R. Simplot Company Stabilization of setting times of phosphate-boned magnesia cements
EP0219952A1 (fr) * 1985-10-15 1987-04-29 Stauffer Chemical Company Compositions de ciments de phosphate de magnésium à prise rapide contenant des retardateurs de prise
US4786328A (en) * 1987-07-16 1988-11-22 American Stone-Mix, Inc. Magnesium phosphate cement systems

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4756762A (en) * 1987-07-16 1988-07-12 American Stone-Mix, Inc. Magnesium phosphate cement systems

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2522548A (en) * 1946-10-03 1950-09-19 Thoger G Jungersen Method of making a phosphate gel and mold with phosphate gel binder
US3960580A (en) * 1974-11-21 1976-06-01 W. R. Grace & Co. Magnesium phosphate concrete compositions
US4436555A (en) * 1982-09-23 1984-03-13 The United States Of America As Represented By The United States Department Of Energy Magnesium phosphate glass cements with ceramic-type properties
US4444594A (en) * 1982-12-09 1984-04-24 Armstrong World Industries, Inc. Acid cured inorganic binder compositions which are compatible with mineral wool
AU4347385A (en) * 1984-06-27 1986-01-02 J.R. Simplot Company Stabilization of setting times of phosphate-boned magnesia cements
EP0219952A1 (fr) * 1985-10-15 1987-04-29 Stauffer Chemical Company Compositions de ciments de phosphate de magnésium à prise rapide contenant des retardateurs de prise
US4786328A (en) * 1987-07-16 1988-11-22 American Stone-Mix, Inc. Magnesium phosphate cement systems

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, Volume 121, No. 18, 1994, Columbus, Ohio, USA, A.K. SARKAR, "Investigation of Reaction/Bonding Mechanisms in Regular and Retarded Magnesium Ammonium Phosphate Cement Systems", page 433, Abstract No. 211501U; & CERAM. TRANS., 1994, 40, (CEMENT TECHNOLOGY), pages 281-288. *
DERWENT ABSTRACT, Accession No. 78-33133A/18, Class L02; & JP,B,53 010 094 (MATSUSHITA ELEC WORKS), 11 April 1978. *
DERWENT ABSTRACT, Accession No. 80-54778C/31, Class E33, L02; & SU,A,694 466 (BELGOROD CONS MATER), 30 October 1979. *
PATENT ABSTRACTS OF JAPAN, C-843, page 118; & JP,A,03 080 137 (NIPPON CHEM IND CO LTD), 4 April 1991. *
PATENT ABSTRACTS OF JAPAN, C-843, page 118; & JP,A,03 080 138 (NIPPON CHEM IND CO LTD), 4 April 1991. *
PATENT ABSTRACTS OF JAPAN, C-972, page 151; & JP,A,04 119 951 (NIPPON CHEM IND CO LTD), 21 April 1992. *
See also references of EP0830325A4 *

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6136088A (en) * 1997-10-09 2000-10-24 Mbt Holding Ag Rapid setting, high early strength binders
DE19846414B4 (de) * 1997-10-09 2007-07-12 Construction Research & Technology Gmbh Phosphatzementbindemittel, Verfahren zu seiner Herstellung und seine Verwendung, insbesondere als Reparaturmörtel
FR2809724A1 (fr) * 2000-06-05 2001-12-07 Rhodia Chimie Sa Nouveau liant hydraulique phosphomagnesien, et mortier obtenu a partir de ce liant
WO2001094270A1 (fr) * 2000-06-05 2001-12-13 Rhodia Chimie Nouveau liant hydraulique phosphomagnesien, et mortier obtenu a partir de ce liant
US6518212B1 (en) 2000-09-18 2003-02-11 The University Of Chicago Chemically bonded phospho-silicate ceramics
US7491267B2 (en) 2001-08-10 2009-02-17 Ceratech, Inc. Composite materials and methods of making and using such composite materials
US7863494B2 (en) 2003-05-27 2011-01-04 Lg Chem, Ltd. Hydrocarbon steam cracking catalyst, method for preparing the same and method for preparing light olefin by using the same
EP1628760A4 (fr) * 2003-05-27 2010-09-29 Lg Chemical Ltd Catalyseur pour vapocraquage d'hydrocarbures, procede de preparation de ce dernier et procede de preparation d'olefines legeres dans lequel le catalyseur est utilise
WO2004105939A1 (fr) 2003-05-27 2004-12-09 Lg Chem. Ltd. Catalyseur pour vapocraquage d'hydrocarbures, procede de preparation de ce dernier et procede de preparation d'olefines legeres dans lequel le catalyseur est utilise
US7462581B2 (en) * 2003-09-09 2008-12-09 Halliburton Energy Services, Inc. Treatment fluids comprising starch and ceramic particulate bridging agents and methods of using these fluids to provide fluid loss control
US8523997B2 (en) 2010-01-14 2013-09-03 Engineered Arresting Systems Corporation Cellular phosphate ceramics and methods of manufacture and use
CN113562998A (zh) * 2021-08-24 2021-10-29 北京科技大学 一种用镁矿石粉制备磷酸镁水泥净浆的方法
CN115724643A (zh) * 2022-11-01 2023-03-03 辽宁科技大学 一种可控水化反应的高耐火磷酸镁水泥基材料及制备方法
CN115724643B (zh) * 2022-11-01 2024-02-20 辽宁科技大学 一种可控水化反应延长凝结时间的高耐火磷酸镁水泥基材料及制备方法

Also Published As

Publication number Publication date
EP0830325A1 (fr) 1998-03-25
KR19990014664A (ko) 1999-02-25
JPH11505204A (ja) 1999-05-18
EP0830325A4 (fr) 1999-07-21
AUPN291195A0 (en) 1995-06-01

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