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WO1997002119A1 - Protective wood preservatives - Google Patents

Protective wood preservatives Download PDF

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Publication number
WO1997002119A1
WO1997002119A1 PCT/EP1996/002884 EP9602884W WO9702119A1 WO 1997002119 A1 WO1997002119 A1 WO 1997002119A1 EP 9602884 W EP9602884 W EP 9602884W WO 9702119 A1 WO9702119 A1 WO 9702119A1
Authority
WO
WIPO (PCT)
Prior art keywords
wood
wood preservative
quaternary ammonium
weight
polymeric quaternary
Prior art date
Application number
PCT/EP1996/002884
Other languages
German (de)
French (fr)
Inventor
Volker Barth
Helmut HÄRTNER
Original Assignee
Rütgers Organics Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rütgers Organics Gmbh filed Critical Rütgers Organics Gmbh
Priority to AU63602/96A priority Critical patent/AU6360296A/en
Priority to EP96922896A priority patent/EP0842019A1/en
Publication of WO1997002119A1 publication Critical patent/WO1997002119A1/en
Priority to NO975821A priority patent/NO975821L/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B27K3/15—Impregnating involving polymerisation including use of polymer-containing impregnating agents
    • B27K3/156—Combined with grafting onto wood fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16—Inorganic impregnating agents
    • B27K3/163—Compounds of boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B27K3/38—Aromatic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B27K3/50—Mixtures of different organic impregnating agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02—Polyamines

Definitions

  • the invention relates to preventive wood preservatives which are free of heavy metals and have a good fungicidal action.
  • these polymeric quaternary ammonium borates also have an insecticidal action.
  • relatively large amounts of the active ingredient are required in order to achieve adequate protection of the wood against insects.
  • boron salts wash out slowly, so that the fungicidal and the insecticidal action are lost if the wood impregnated therewith is exposed to the weather.
  • Polymeric quaternary ammonium borates are the reaction products of amines with ethylene oxide or propylene oxide and boron compounds known from EP-A 0 355 316, in particular those which are obtained by simultaneous reaction of amines of the general formulas I or II
  • A is a group of the formulas - (CH 2 ) "-, - (CH 2 CH 2 OCH 2 OH)" - or - (CH 2 CH 2 NHCH 2 CH 2 ) "- x numbers from 1 to 55 and n an integer from 1 to 20 mean.
  • silane (3- (4-fluoro-3-phenoxy-phenyl) propyl (dimethyl) silane is known from JP-A 61 229883 as an insecticidal compound and is available under the trade name Silafluofen. However, the compound is insoluble in water and does not penetrate well in wood, even if it is applied to wood in the form of a solution in an organic solvent.
  • the combination of the two components results in a multiple synergistic effect: the combination becomes water-soluble. It penetrates deeply into the wood treated with it and the washout behavior of polymeric quaternary ammonium borate is significantly reduced.
  • the active ingredient combination according to the invention can contain further compatible active ingredients.
  • the addition of a product of 25-75 parts by weight of fatty amine ethoxylate and 75-25 parts by weight is recommended unsaturated fatty acid.
  • the addition of this product known from an earlier application by the applicant (P 195 15 211.5), results in a further improvement in the depth of penetration into the wood and permits a further reduction in the amounts of active substance.
  • polymeric, quaternary ammonium borate 0.01-5% by weight, in particular 0.2-05% by weight of silafluofen 0 -15% by weight, in particular 5-10% by weight of product
  • These agents are concentrates that are diluted with water to use concentrations in the range of 0.5-25% before use.
  • the use concentration depends on the selected application method: If the wood preservative is applied without pressure, the preferred use concentration is in the range of 5-15%, the agent is introduced into wood with the help of vacuum pressure processes. the preferred use concentration is in the range of 0.5-3% by weight.
  • a wood preservative concentrate is made by mixing
  • Test specimens made from pine sapwood are immersed in this diluted wood preservative solution for 24 hours and then dried.
  • the average wood preservative absorption is 83.2 g / m 2 .
  • a part of impregnated test wood is planed 1 or 2 mm. Afterwards, egg larvae of the longhorn beetle are applied to the test timbers and kept under biological conditions.
  • Example 2 Analogously to Example 1, a wood preservative concentrate is produced and tested.
  • the concentrate has the following composition:

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention pertains to heavy metal-free wood preservatives that contain polymeric quaternary ammonium borate and (4-ethoxyphenyl) (3-(fluoro-3-phenoxyphenyl)propyl-(dimethyl)silane.

Description

Vorbeugende HolzschutzmittelPreventive wood preservatives
Die Erfindung betrifft schwermetallfreie vorbeugende Holzschutzmittel mit guter fungizider Wirkung.The invention relates to preventive wood preservatives which are free of heavy metals and have a good fungicidal action.
Aus EP-A 0 355 316 ist bekannt, polymere quartare Am¬ moniumborate als fungizid wirkende Holzschutzmittel mit guter Eindringtiefe einzusetzen.It is known from EP-A 0 355 316 to use polymeric quaternary ammonium borates as fungicidal wood preservatives with good penetration depth.
Gemäß EP-A 0 498 162 haben diese polymeren quartären Ammoniumborate auch eine insektizide Wirkung. Jedoch werden relativ große Einbringmengen des Wirkstoffs ge¬ braucht, um einen ausreichenden Schutz des Holzes gegen Insekten zu erzielen. Außerdem waschen Borsalze langsam aus, so daß sich die fungizide und die insektizide Wir¬ kung bei längerer Gebrauchsdauer verliert, wenn das damit imprägnierte Holz der Bewitterung ausgesetzt ist.According to EP-A 0 498 162, these polymeric quaternary ammonium borates also have an insecticidal action. However, relatively large amounts of the active ingredient are required in order to achieve adequate protection of the wood against insects. In addition, boron salts wash out slowly, so that the fungicidal and the insecticidal action are lost if the wood impregnated therewith is exposed to the weather.
Eine Verringerung der Wirkkonzentration und eine Ver¬ besserung der Langzeitwirkung der polymeren quartären Ammoniumborate wird erreicht, wenn diese mit Kupfersalz und Alkanolamin kombiniert werden, wie dies aus EP-A 0 556 454 bekannt ist. Leider werden in diesen Mitteln toxische Kupferverbindungen eingesetzt. Es ist daher Aufgabe der Erfindung, schwermetallfreie, lösemittelfreie vorbeugende Holzschutzmittel mit guter r- fungizider Wirkung bereitzustellen, die auch bei Bewit¬ terung eine gute Langzeitbeständigkeit haben.A reduction in the active concentration and an improvement in the long-term effect of the polymeric quaternary ammonium borates is achieved if these are combined with copper salt and alkanolamine, as is known from EP-A 0 556 454. Unfortunately, toxic copper compounds are used in these agents. It is therefore an object of the invention to provide heavy metal-free, solvent-free preventive wood preservatives with good fungicidal activity, which have good long-term stability even when weathered.
Die Lösung der Aufgabe erfolgt durch Holzschutzmittel gemäß der Ansprüche 1-5.The problem is solved by wood preservatives according to claims 1-5.
Es wurde gefunden, daß Kombinationen von polymeren quartären Ammoniumboraten und (4-Ethoxyphenyl)- (3-(4-fluoro-3-phenoxy-phenyl)propyl-(dimethyl)silan mit Wasser klare Lösungen bilden, daß diese Lösungen und die in ihnen gelösten Wirkstoffe tief in Holz ein¬ dringen, nach der Trocknung nicht mehr auswaschen und auch bei geringer Einbringmenge eine gute insektizide und fungizide Langzeitwirkung ergeben.It has been found that combinations of polymeric quaternary ammonium borates and (4-ethoxyphenyl) - (3- (4-fluoro-3-phenoxy-phenyl) propyl- (dimethyl) silane with water form clear solutions that these solutions and those in them dissolved active ingredients penetrate deeply into wood, do not wash out after drying and have a good long-term insecticidal and fungicidal action even when the amount is small.
Polymere quartare Ammoniumborate sind die aus EP-A 0 355 316 bekannten Umsetzungsprodukte von Aminen mir Ethylen- oder Propylenoxid und Borverbindungen, insbesondere solche, die erhalten werden durch gleich¬ zeitige Umsetzung von Aminen der allgemeinen Formeln I oder IIPolymeric quaternary ammonium borates are the reaction products of amines with ethylene oxide or propylene oxide and boron compounds known from EP-A 0 355 316, in particular those which are obtained by simultaneous reaction of amines of the general formulas I or II
R: R* R« R : R * R «
//
//
R1 -N (D N-A-N (II)R 1 -N (D NAN (II)
R" mit 2 bis 20, vorzugsweise 3 bis 10, Mol Ethylen- oder Propylenoxid und 0,6 bis 1,5, vorzugsweise 1 Mol Bor¬ säure, Borsäureester oder Salzen der Borsäure, jeweils pro Mol Stickstoffäquivalent, wobei Rx Cβ-C22- Alkyl oder Cβ-C22-Alkenyl bedeutet oder, wenn R2 und R3 Grup¬ pen der Formel -(C2H40)xH oder
Figure imgf000005_0001
darstellen, R1 auch d-c«-Alkyl bedeuten kann, R2 und R3 gleich oder verschieden sind und Wasserstoff, Cj_-C22-Alkyl oder eine Gruppe der Formeln -(C2H40)xH, -(C3H6θ)xH oder -CH2CH2CH2NH2 bedeuten, R4 und R6 Cι-C4-Alkyl oder eine Gruppe der Formeln -(C2H40)-3IH, oder - ( C3Hβ0 ) xli . A eine Gruppe der Formeln -(CH2)„-, -(CH2CH2OCH2OH)„- oder -(CH2CH2NHCH2CH2)„- x Zahlen von 1 bis 55 und n eine ganze Zahl von 1 bis 20 bedeuten.R " with 2 to 20, preferably 3 to 10, moles of ethylene or propylene oxide and 0.6 to 1.5, preferably 1 mole of boric acid, boric acid ester or salts of boric acid, in each case per mole of nitrogen equivalent, where R x C β -C 22 - Alkyl or C β- C 22 alkenyl or when R 2 and R 3 groups of the formula - (C 2 H 4 0) x H or
Figure imgf000005_0001
represent, R 1 can also mean dc «alkyl, R 2 and R 3 are identical or different and are hydrogen, Cj_-C 22 alkyl or a group of the formulas - (C 2 H 4 0) x H, - (C 3 H 6 θ) x H or -CH 2 CH 2 CH 2 NH 2 , R 4 and R 6 C ι -C 4 alkyl or a group of the formulas - (C 2 H 4 0) - 3I H, or - ( C 3 H β 0) x left. A is a group of the formulas - (CH 2 ) "-, - (CH 2 CH 2 OCH 2 OH)" - or - (CH 2 CH 2 NHCH 2 CH 2 ) "- x numbers from 1 to 55 and n an integer from 1 to 20 mean.
(4-Ethoxyphenyl)-(4-ethoxyphenyl) -
(3-(4-fluoro-3-phenoxy-phenyl)propyl(dimethyl)silan ist aus JP-A 61 229883 als insektizid wirkende Verbindung bekannt und unter dem Handelsnamen Silafluofen erhält¬ lich. Die Verbindung ist allerdings in Wasser unlöslich und dringt schlecht in Holz ein, auch wenn sie z.B. in Form einer Lösung in einem organischen Lösemittel auf Holz aufgebracht wird.(3- (4-fluoro-3-phenoxy-phenyl) propyl (dimethyl) silane is known from JP-A 61 229883 as an insecticidal compound and is available under the trade name Silafluofen. However, the compound is insoluble in water and does not penetrate well in wood, even if it is applied to wood in the form of a solution in an organic solvent.
Durch Kombination der beiden Komponenten ergibt sich ein mehrfacher synergistischer Effekt: Die Kombination wird wasserlöslich. Sie dringt tief in damit behandel¬ tes Holz ein und das Auswaschverhalten von polymerem quartärem Ammoniumborat wird deutlich reduziert.The combination of the two components results in a multiple synergistic effect: the combination becomes water-soluble. It penetrates deeply into the wood treated with it and the washout behavior of polymeric quaternary ammonium borate is significantly reduced.
Die erfindungsgemäße Wirkstoffkombination kann weitere verträgliche Wirkstoffe enthalten. Insbesondere emp¬ fiehlt sich der Zusatz eines Produktes aus 25-75 Gew.-Teilen Fettaminethoxylat und 75-25 Gew.-Teilen ungesättigter Fettsäure. Der Zusatz dieses, aus einer älteren Anmeldung der Anmelderin (P 195 15 211.5) be¬ kannten Produktes ergibt eine weitere Verbesserung der Eindringtiefe in das Holz und erlaubt eine weitere Re¬ duzierung der Wirkstoffmengen.The active ingredient combination according to the invention can contain further compatible active ingredients. In particular, the addition of a product of 25-75 parts by weight of fatty amine ethoxylate and 75-25 parts by weight is recommended unsaturated fatty acid. The addition of this product, known from an earlier application by the applicant (P 195 15 211.5), results in a further improvement in the depth of penetration into the wood and permits a further reduction in the amounts of active substance.
Entsprechende Holzschutzmittel enthalten dannAppropriate wood preservatives then contain
50-99 Gew.% polymeres, quartäres Ammoniumborat 0,01-5 Gew.%, insbesondere 0,2-05 Gew.% Silafluofen 0 -15 Gew.%, insbesondere 5-10 Gew.% Produkt aus50-99% by weight of polymeric, quaternary ammonium borate 0.01-5% by weight, in particular 0.2-05% by weight of silafluofen 0 -15% by weight, in particular 5-10% by weight of product
Fettaminethoxylat und ungesättigterFatty amine ethoxylate and unsaturated
Fettsäure ad 100 Gew.% Wasser.Fatty acid ad 100% by weight water.
Diese Mittel sind Konzentrate, die vor Gebrauch mit Wasser auf Gebrauchskonzentrationen im Bereich von 0,5-25 % verdünnt werden. Dabei richtet sich die Ge¬ brauchskonzentration nach dem gewählten Anwendungsver¬ fahren: Wird das Holzschutzmittel drucklos aufgebracht, so liegt die bevorzugte Gebrauchskonzentration im Be¬ reich von 5-15 %, wird das Mittel mit Hilfe von Vakuum- Druck-Verfahren in Holz eingebracht, liegt die bevor¬ zugte Gebrauchskonzentration im Bereich von 0,5-3 Gew.%.These agents are concentrates that are diluted with water to use concentrations in the range of 0.5-25% before use. The use concentration depends on the selected application method: If the wood preservative is applied without pressure, the preferred use concentration is in the range of 5-15%, the agent is introduced into wood with the help of vacuum pressure processes. the preferred use concentration is in the range of 0.5-3% by weight.
Beispiel 1example 1
Es wird ein Holzschutzmittelkonzentrat hergestellt durch Vermischen vonA wood preservative concentrate is made by mixing
92 Gew.-Teilen polymerem quartärem Ammoniumborat92 parts by weight of polymeric quaternary ammonium borate
(hergestellt nach Beispiel 1 der EP-A 0 355 316) 0,5 Gew.-Teilen Silafluofen 7,5 Gew.-Teilen Wasser(produced according to Example 1 of EP-A 0 355 316) 0.5 part by weight of silafluofen 7.5 parts by weight of water
Das Konzentrat wird mit Wasser im Verhältnis 1:9 (=10%ige Gebrauchskonzentration) verdünnt.The concentrate is diluted with water in a ratio of 1: 9 (= 10% use concentration).
In diese verdünnte Holzschutzmittellösung werden Probe¬ körper aus Kiefernsplintholz 24 h lang eingetaucht und danach getrocknet.Test specimens made from pine sapwood are immersed in this diluted wood preservative solution for 24 hours and then dried.
Die mittlere Holzschutzmittelaufnahme beträgt 83,2 g/m2. Ein Teil imprägnierter Probehölzer wird 1 bzw. 2 mm abgehobelt. Danach werden Eilarven des Hausbockkä¬ fers auf die Probehölzer aufgebracht und unter biologi¬ schen Bedingungen gehalten.The average wood preservative absorption is 83.2 g / m 2 . A part of impregnated test wood is planed 1 or 2 mm. Afterwards, egg larvae of the longhorn beetle are applied to the test timbers and kept under biological conditions.
Ergebnis:Result:
Überlebensrate nach 4-wöchiger Prüfung: ohne Abhobeln 0 %Survival rate after 4 weeks of testing: without planing 0%
1 mm abgehobelt 10 %1 mm planed 10%
Überlebensrate nach 12-wöchiger Prüfung:Survival rate after 12 weeks of testing:
1 mm abgehobelt 2 %1 mm planed 2%
2 mm abgehobelt 9 %.2 mm planed 9%.
Beispiel 2Example 2
Analog zu Beispiel 1 wird ein Holzschutzmittelkonzen¬ trat hergestellt und getestet. Das Konzentrat hat fol¬ gende Zusammensetzung:Analogously to Example 1, a wood preservative concentrate is produced and tested. The concentrate has the following composition:
87 Gew.-Teile polymeres quartäres Ammoniumborat (hergestellt nach Beispiel 1 der EP-A 0 355 316) 0,5 Gew.-Teile Silafluofen 5 Gew.-Teile eines Produktes aus je gleichen87 parts by weight of polymeric quaternary ammonium borate (produced according to Example 1 of EP-A 0 355 316) 0.5 part by weight of silafluofen 5 parts by weight of the same product
Gewichtsteilen Kokosfettaminethoxylat je 1/3 mit einem EO-Gehalt von 10, 15 und 20 Ethylenoxideinheiten pro Molekül und UndecylensäureParts by weight of coconut fatty amine ethoxylate each 1/3 with an EO content of 10, 15 and 20 ethylene oxide units per molecule and undecylenic acid
7,5 Gew.-Teile Wasser7.5 parts by weight of water
Ergebnis:Result:
Überlebensrate nach 4-wöchiger Prüfung: ohne Abhobeln 0 %Survival rate after 4 weeks of testing: without planing 0%
1 mm abgehobelt 0 %1 mm planed 0%
Überlebensrate nach 12-wöchiger Prüfung:Survival rate after 12 weeks of testing:
1 mm abgehobelt 0 %1 mm planed 0%
2 mm abgehobelt 0 % 2 mm planed 0%

Claims

Patentansprüche claims
1. Holzschutzmittel, dadurch gekennzeichnet, daß es polymeres quartäres Ammoniumborat und (4-Ethoxy- phenyl) (3-(-fluoro-3-phenoxy-phenyl)propyl-(di¬ methyl)silan (=Silafluofen) enthält.1. Wood preservative, characterized in that it contains polymeric quaternary ammonium borate and (4-ethoxy-phenyl) (3 - (- fluoro-3-phenoxy-phenyl) propyl- (di-methyl) silane (= silafluofen).
2. Holzschutzmittel nach Anspruch 1, dadurch gekenn¬ zeichnet, daß es weitere verträgliche Wirkstoffe enthält.2. Wood preservative according to claim 1, characterized gekenn¬ characterized in that it contains other compatible active ingredients.
3. Holzschutzmittel nach Anspruch 2, dadurch gekenn¬ zeichnet, daß es als weitere Komponente ein Pro¬ dukt aus Fettaminethoxylat und ungesättigter Fett¬ säure enthält.3. Wood preservative according to claim 2, characterized gekenn¬ characterized in that it contains as a further component a product from fatty amine ethoxylate and unsaturated fatty acid.
4. Holzschutzmittel nach den Ansprüchen 1-3, dadurch gekennzeichnet, daß es als Konzentrat vorliegt, das vor Gebrauch mit Wasser auf die gewünschte Gebrauchs-Konzentration verdünnt wird.4. Wood preservative according to claims 1-3, characterized in that it is present as a concentrate which is diluted with water to the desired use concentration before use.
5. Holzschutzmittelkonzentrat bestehend aus polymerem quartärem Ammoniumborat 50-99 Gew.% Silaflofen 0,01- 5 Gew.% insbesondere 0,2 -0,5 Gew.% Produkt aus Fettaminethoxylat und ungesättigter Fettsäure 0-15 Gew.% insbesondere 5-10 Gew.% Wasser ad 100 Gew.% 5. Wood preservative concentrate consisting of polymeric quaternary ammonium borate 50-99 wt.% Silaflofen 0.01-5 wt.%, In particular 0.2-0.5 wt.% Product of fatty amine ethoxylate and unsaturated fatty acid 0-15 wt.%, in particular 5-10 wt.% water a d 100 wt.%
PCT/EP1996/002884 1995-07-06 1996-07-02 Protective wood preservatives WO1997002119A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU63602/96A AU6360296A (en) 1995-07-06 1996-07-02 Protective wood preservatives
EP96922896A EP0842019A1 (en) 1995-07-06 1996-07-02 Protective wood preservatives
NO975821A NO975821L (en) 1995-07-06 1997-12-11 wood preservative

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19524286A DE19524286A1 (en) 1995-07-06 1995-07-06 Preventive wood preservatives
DE19524286.6 1995-07-06

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EP (1) EP0842019A1 (en)
AU (1) AU6360296A (en)
DE (1) DE19524286A1 (en)
NO (1) NO975821L (en)
WO (1) WO1997002119A1 (en)

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WO2001093685A1 (en) * 2000-06-06 2001-12-13 Woodholdings Environmental, Inc. Preservative compositions for wood products
US7192470B2 (en) 2003-05-27 2007-03-20 Woodholdings Environmental, Inc. Preservative compositions for materials and method of preserving same
US7964031B2 (en) 2000-06-06 2011-06-21 Dow Corning Corporation Compositions for treating materials and methods of treating same
US8940366B2 (en) 2007-05-09 2015-01-27 Petra International Holdings, Llc Apparatus and method for treating materials with compositions
US9157190B2 (en) 2011-01-18 2015-10-13 Petra International Holdings, Llc Method for treating substrates with halosilanes
US9603358B2 (en) 2011-11-04 2017-03-28 Arch Timber Protection Limited Additives for use in wood preservation

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US7758924B2 (en) 2000-06-06 2010-07-20 Dow Corning Corporation Preservative compositions for wood products
WO2001093685A1 (en) * 2000-06-06 2001-12-13 Woodholdings Environmental, Inc. Preservative compositions for wood products
US7267714B2 (en) 2000-06-06 2007-09-11 Woodholdings Environmental, Inc. Preservative compositions for wood products
US7300502B2 (en) 2000-06-06 2007-11-27 Woodholdings Environmental, Inc. Preservative compositions for wood products
US7754288B2 (en) 2000-06-06 2010-07-13 Woodholdings Environmental, Inc. Preservative compositions for materials and method of preserving same
US7846505B2 (en) 2000-06-06 2010-12-07 Dow Corning Corporation Preservative compositions for materials and method of preserving same
US7838124B2 (en) 2000-06-06 2010-11-23 Dow Corning Corporation Preservative compositions for wood products
US7128778B2 (en) 2000-06-06 2006-10-31 Woodholdings Environmental, Inc. Preservative compositions for wood products
US7964031B2 (en) 2000-06-06 2011-06-21 Dow Corning Corporation Compositions for treating materials and methods of treating same
US7192470B2 (en) 2003-05-27 2007-03-20 Woodholdings Environmental, Inc. Preservative compositions for materials and method of preserving same
US8940366B2 (en) 2007-05-09 2015-01-27 Petra International Holdings, Llc Apparatus and method for treating materials with compositions
US9157190B2 (en) 2011-01-18 2015-10-13 Petra International Holdings, Llc Method for treating substrates with halosilanes
US9603358B2 (en) 2011-11-04 2017-03-28 Arch Timber Protection Limited Additives for use in wood preservation
US9961895B2 (en) 2011-11-04 2018-05-08 Arch Timber Protection Limited Additives for use in wood preservation

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NO975821D0 (en) 1997-12-11
NO975821L (en) 1998-01-02
EP0842019A1 (en) 1998-05-20
DE19524286A1 (en) 1997-01-09
AU6360296A (en) 1997-02-05

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