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WO1997011775A3 - Supported catalyst system, process for its production and its use in polymerising olefines - Google Patents

Supported catalyst system, process for its production and its use in polymerising olefines Download PDF

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Publication number
WO1997011775A3
WO1997011775A3 PCT/EP1996/004071 EP9604071W WO9711775A3 WO 1997011775 A3 WO1997011775 A3 WO 1997011775A3 EP 9604071 W EP9604071 W EP 9604071W WO 9711775 A3 WO9711775 A3 WO 9711775A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst system
olefines
polymerising
production
supported catalyst
Prior art date
Application number
PCT/EP1996/004071
Other languages
German (de)
French (fr)
Other versions
WO1997011775A2 (en
Inventor
Cornelia Fritze
Bernd Bachmann
Frank Kueber
Original Assignee
Hoechst Ag
Exxon Chemical Patents Inc
Cornelia Fritze
Bernd Bachmann
Frank Kueber
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag, Exxon Chemical Patents Inc, Cornelia Fritze, Bernd Bachmann, Frank Kueber filed Critical Hoechst Ag
Priority to DE59610623T priority Critical patent/DE59610623D1/en
Priority to AT96932549T priority patent/ATE245665T1/en
Priority to US09/101,249 priority patent/US6271164B1/en
Priority to EP96932549A priority patent/EP0859800B1/en
Publication of WO1997011775A2 publication Critical patent/WO1997011775A2/en
Publication of WO1997011775A3 publication Critical patent/WO1997011775A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The present invention relates to a catalyst system containing at least one metallocene and at least one inertised support and preferably at least one co-catalyst. To produce the inertised support, at least one inorganic oxide is treated with at least one metal-organic compound, preferably in an inorganic solvent. The present invention also relates to a polymer with a melting point ≥ 158 °C, a regio error proportion < 0.2 % and a triple activity > 98.0 %.
PCT/EP1996/004071 1995-09-28 1996-09-18 Supported catalyst system, process for its production and its use in polymerising olefines WO1997011775A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE59610623T DE59610623D1 (en) 1995-09-28 1996-09-18 SUPPORTED CATALYST SYSTEM, METHOD FOR THE PRODUCTION THEREOF AND ITS USE FOR THE POLYMERIZATION OF OLEFINS
AT96932549T ATE245665T1 (en) 1995-09-28 1996-09-18 SUPPORTED CATALYST SYSTEM, METHOD FOR THE PRODUCTION THEREOF AND ITS USE FOR THE POLYMERIZATION OF OLEFINS
US09/101,249 US6271164B1 (en) 1995-09-28 1996-09-18 Supported catalyst system, process for its production and its use in polymerizing olefins
EP96932549A EP0859800B1 (en) 1995-09-28 1996-09-18 Supported catalyst system, process for its production and its use in polymerising olefines

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP95115278 1995-09-28
EP95115278.4 1995-09-28

Publications (2)

Publication Number Publication Date
WO1997011775A2 WO1997011775A2 (en) 1997-04-03
WO1997011775A3 true WO1997011775A3 (en) 1997-06-05

Family

ID=8219660

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1996/004071 WO1997011775A2 (en) 1995-09-28 1996-09-18 Supported catalyst system, process for its production and its use in polymerising olefines

Country Status (7)

Country Link
US (1) US6271164B1 (en)
EP (1) EP0859800B1 (en)
AT (1) ATE245665T1 (en)
CA (1) CA2241812A1 (en)
DE (1) DE59610623D1 (en)
ES (1) ES2203714T3 (en)
WO (1) WO1997011775A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7148174B2 (en) 2001-06-22 2006-12-12 Celanese Ventures Gmbh Non-metallocene catalyst system

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19757563A1 (en) 1997-03-07 1999-07-08 Targor Gmbh Free-flowing catalyst system for olefin polymerisation
US6090325A (en) * 1997-09-24 2000-07-18 Fina Technology, Inc. Biaxially-oriented metallocene-based polypropylene films
DE19744102A1 (en) * 1997-10-06 1999-04-15 Targor Gmbh Metallocene catalyst system useful in (co)polyolefin production
DE19805329A1 (en) 1998-02-11 1999-08-12 Basf Ag Injection stretch blow molded olefin polymer containers
DE19806918A1 (en) * 1998-02-19 1999-08-26 Aventis Res & Tech Gmbh & Co Catalyst system for the production of olefin polymers, especially polypropylene
JPH11349634A (en) * 1998-06-05 1999-12-21 Mitsubishi Chemical Corp Propylene polymer
CA2341167A1 (en) * 1998-08-26 2000-03-09 Exxon Chemical Patents Inc. Branched polypropylene compositions
JP4554133B2 (en) * 1999-10-08 2010-09-29 三井化学株式会社 Metallocene compound, method for producing metallocene compound, olefin polymerization catalyst, method for producing polyolefin, and polyolefin
EP1548023B1 (en) * 1999-12-23 2013-08-14 Basell Polyolefine GmbH Transition metal compound, catalyst system and the use of the latter for the polymerisation and copolymerisation of olefins
ATE354540T1 (en) 2000-01-21 2007-03-15 United States Borax Inc NONBORATE COMPOSITION AND PRODUCTION THEREOF
ATE366738T1 (en) 2000-05-31 2007-08-15 Basell Polyolefine Gmbh METHOD FOR PRODUCING TRANSITION METAL COMPOUNDS AND THEIR USE FOR POLYMERIZING OLEFINS
DE10057009A1 (en) 2000-11-17 2002-05-29 Celanese Ventures Gmbh Non-metallocenes, processes for their preparation and their use in the polymerization of olefins
EP1373283A1 (en) * 2001-02-17 2004-01-02 Celanese Ventures GmbH Non-metallocenes, method for the production thereof and the use thereof for the polymerisation of olefins
WO2002066522A1 (en) * 2001-02-17 2002-08-29 Celanese Ventures Gmbh Transition metal compound provided as a catalyst constituent, and use thereof for producing polyolefins
DE10208252A1 (en) 2002-02-26 2003-09-04 Celanese Ventures Gmbh Non-metallocenes fixed in a convex manner, process for their preparation and their use in the polymerization of olefins
DE10213191A1 (en) 2002-03-23 2003-10-02 Celanese Ventures Gmbh Non-metallocenes, processes for their preparation and their use in the polymerization of olefins
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
JP4972284B2 (en) 2002-10-15 2012-07-11 エクソンモービル・ケミカル・パテンツ・インク Multiple catalyst systems for olefin polymerization and polymers produced therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
WO2004055070A1 (en) 2002-12-16 2004-07-01 Basell Polyolefine Gmbh Preparation of supported catalyst systems containing reduced amounts of aluminoxanes
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7598329B2 (en) * 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
US8034886B2 (en) * 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
DE102005052654A1 (en) * 2005-11-04 2007-05-16 Ticona Gmbh Process for the preparation of ultra-high molecular weight polymers using special bridged metallocene catalysts
EP1847555A1 (en) 2006-04-18 2007-10-24 Borealis Technology Oy Multi-branched Polypropylene
EP1988122A1 (en) * 2007-05-04 2008-11-05 Total Petrochemicals Research Feluy Blend for use in automobile application
BRPI0703586B1 (en) 2007-10-19 2018-02-06 Braskem S.A SUPPORTED METALOCENE CATALYST, AND HIGH AND ULTRA HIGH MOLECULAR ALPHA ETHYLENE COPOLYMERS
JP5598856B2 (en) * 2007-10-25 2014-10-01 ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング Metallocene compound, catalyst containing the same, process for producing olefin polymer using the catalyst, and olefin homopolymer and copolymer
CN101910216A (en) 2007-10-25 2010-12-08 鲁姆斯诺沃伦技术公司 Racemoselective synthesis of ansa-metallocene compounds, catalysts containing the same, process for preparing olefin polymers by using the catalysts and olefin homopolymers and copolymers
WO2009054833A2 (en) 2007-10-25 2009-04-30 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
KR101790672B1 (en) 2015-08-24 2017-10-26 주식회사 엘지화학 Transition metal compound, catalyst composition comprising the same, and method for preparing olefin polymer using the same

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GB2124240A (en) * 1982-07-15 1984-02-15 Chisso Corp Isotactic polypropylene for moulding
EP0416928A2 (en) * 1989-09-06 1991-03-13 Borealis Holding A/S New carrier catalyst for the polymerization of ethylene
EP0485820A2 (en) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft Process for preparing olefin polymers
EP0498603A2 (en) * 1991-02-04 1992-08-12 Amoco Corporation Olefin polymerization and copolymerization process
EP0619326A1 (en) * 1993-04-09 1994-10-12 Tosoh Corporation Olefin polymerization catalyst and olefin polymerisation process
EP0629632A2 (en) * 1993-06-07 1994-12-21 Mitsui Petrochemical Industries, Ltd. Novel transition metal compound for use as a polymerization catalyst
WO1995011263A1 (en) * 1993-10-22 1995-04-27 Mobil Oil Corporation An olefin polymerization or copolymerization catalyst
WO1995015815A1 (en) * 1993-12-06 1995-06-15 Mobil Oil Corporation Catalyst for use in olefin polymerization or copolymerization
EP0748824A1 (en) * 1995-06-02 1996-12-18 Chisso Corporation High stereoregular polypropylenes

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2124240A (en) * 1982-07-15 1984-02-15 Chisso Corp Isotactic polypropylene for moulding
EP0416928A2 (en) * 1989-09-06 1991-03-13 Borealis Holding A/S New carrier catalyst for the polymerization of ethylene
EP0485820A2 (en) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft Process for preparing olefin polymers
EP0498603A2 (en) * 1991-02-04 1992-08-12 Amoco Corporation Olefin polymerization and copolymerization process
EP0619326A1 (en) * 1993-04-09 1994-10-12 Tosoh Corporation Olefin polymerization catalyst and olefin polymerisation process
EP0629632A2 (en) * 1993-06-07 1994-12-21 Mitsui Petrochemical Industries, Ltd. Novel transition metal compound for use as a polymerization catalyst
WO1995011263A1 (en) * 1993-10-22 1995-04-27 Mobil Oil Corporation An olefin polymerization or copolymerization catalyst
WO1995015815A1 (en) * 1993-12-06 1995-06-15 Mobil Oil Corporation Catalyst for use in olefin polymerization or copolymerization
EP0748824A1 (en) * 1995-06-02 1996-12-18 Chisso Corporation High stereoregular polypropylenes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7148174B2 (en) 2001-06-22 2006-12-12 Celanese Ventures Gmbh Non-metallocene catalyst system

Also Published As

Publication number Publication date
US6271164B1 (en) 2001-08-07
CA2241812A1 (en) 1997-04-03
EP0859800B1 (en) 2003-07-23
ATE245665T1 (en) 2003-08-15
ES2203714T3 (en) 2004-04-16
WO1997011775A2 (en) 1997-04-03
DE59610623D1 (en) 2003-08-28
EP0859800A2 (en) 1998-08-26

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