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WO1997033960A1 - Composition detergente granulee et d'une densite elevee - Google Patents

Composition detergente granulee et d'une densite elevee Download PDF

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Publication number
WO1997033960A1
WO1997033960A1 PCT/JP1997/000666 JP9700666W WO9733960A1 WO 1997033960 A1 WO1997033960 A1 WO 1997033960A1 JP 9700666 W JP9700666 W JP 9700666W WO 9733960 A1 WO9733960 A1 WO 9733960A1
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Prior art keywords
group
weight
composition
carbon atoms
formula
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PCT/JP1997/000666
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English (en)
Japanese (ja)
Inventor
Shuji Tagata
Hirokazu Uenaka
Makoto Kubo
Takaya Sakai
Masaaki Yamamura
Noboru Moriyama
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Kao Corporation
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Publication of WO1997033960A1 publication Critical patent/WO1997033960A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C11D17/065—High-density particulate detergent compositions

Definitions

  • the present invention relates to high density nonionic detergent compositions. More specifically, the present invention relates to a nonionic high-density granular detergent composition having a high detergency and comprising an amidoamine oxide-type surfactant excellent in biodegradability and safety as a main component of the surfactant.
  • Detergents for clothing are surfactants that solubilize dirt or dissolve and disperse in laundry liquid, alkaline agents that promote the decomposition and solubilization (emulsification) of dirt, polymer compounds that disperse dirt, It is basically composed of a sequestering agent or the like for removing calcium, magnesium, or the like that lowers the ability of the surfactant from the washing liquid.
  • a sequestering agent or the like for removing calcium, magnesium, or the like that lowers the ability of the surfactant from the washing liquid.
  • detergent builder those that do not exhibit cleaning performance by themselves, but are intended to improve the detergency by combining with a surfactant.
  • the above-mentioned sequestering agent is a substance for more effectively expressing the performance of the surfactant, and is a very important builder.
  • Surfactants serve the primary function of removing soil from the fibers, as described above.
  • Surfactants used in detergents are broadly classified into anionic and nonionic surfactants.
  • anionic surfactants include alkylbenzene sulfonates having 8 to 16 carbon atoms, sulfates of higher alcohols having 10 to 18 carbon atoms, ct-olefin sulfonates, alkane sulfonates (SAS ), Ct monosulfofatty acid ester salts and the like
  • typical nonionic surfactants include polyoxetylene alkyl ether, polyoxyethylene alkyl phenyl ether and the like.
  • Non-ionic activators combining amine oxides and carbonates are disclosed in JP-A-47-340.
  • JP-A61-283695 is an amide amine oxide type surfactant.
  • the agent is disclosed as a shampoo or a liquid detergent, and it is disclosed that an amide amine oxide is combined with an acylated amino acid.
  • it does not disclose the use of zeolite or silicate in combination.
  • it does not suggest that when an amide oxide type surfactant is used as a main component of a surfactant in a high-density granular detergent composition, an excellent detergency can be obtained.
  • an object of the present invention is to provide a high-density granular detergent having excellent detergency by using an amide amine oxide surfactant as a main detergent base.
  • the present inventors have found that the high-density granular detergent obtained by a production process including spray drying using amide amine oxide represented by the following formula (I) as a main cleaning component, The present inventors have found that they exhibit superior detergency as compared with a high-density granular detergent produced based on a surfactant, and have completed the present invention.
  • the present invention provides: (a) 15 to 50% by weight of an amide amine oxide type surfactant represented by the following general formula (I):
  • R 2 and R 3 are an alkyl group or alkylene group having 1 to 3 carbon atoms or H.
  • RiH an alkyl group having 1 to 5 carbon atoms Or an alkylene group, and n is 1 to 5.
  • the alkaline agent (c) is a crystalline silicate of the following formula (II) and / or (III). x (M 2 O) ⁇ y (SiO ⁇ z (Me m O n) ⁇ w (H 2 0) (II)
  • M represents an element in the la group of the periodic table
  • Me represents one or a combination of two or more elements selected from the group consisting of the Ila group element, the lib group element, the Hla group element, the ra group element and the ⁇ group element.
  • Y / ⁇ 0.5 to 2.6
  • zZx 0.01 to 1.0
  • w 0 to 20
  • n / m 0.5 to 2.0.
  • (b) is preferably a crystalline aluminosilicate.
  • the anionic surfactant is a higher fatty acid salt having 10 to 18 carbon atoms, a sulfate salt of a linear or branched primary or secondary alcohol having 10 to 18 carbon atoms, or an alcohol having 8 to 20 carbon atoms.
  • the nonionic surfactant is a polyoxyalkylene alkyl ether, a polyoxyalkylene alkyl phenol ether, a polyoxyalkylene sorbitan fatty acid ester, a polyoxyalkylene glycol ether, It is preferably at least one selected from a polyoxyalkylene sorbitan fatty acid ester, a polyoxyalkylene fatty acid ester, a polyoxyethylene polyoxypropylene block polymer, and an alkynyl-methylglucamine.
  • compositions comprise 20-40% by weight of (a), 8-30% by weight of (b) and 10-40% by weight of (c).
  • composition may further comprise a polycarboxylate having an average molecular weight of 1,000 to 100,000.
  • composition Asuparagin di acetate salts and Z or inhibit mud as further organic builders key Consequences amino disuccinic acid salt from 0.5 to 20 weight 0/0 contains or at 1.0 to 5 weight Asuparagin di acetate as an organic builder, 0 /. It is good to contain.
  • the present invention provides a high-density granular detergent having excellent biodegradability and high detergency by using the above (a) as a main component and using (b) and (c) as a builder.
  • nonionic high-density granular detergent composition of the present invention will be described.
  • the amide amine oxide type surfactant used in the present invention is represented by the above general formula (I). Most effective when R 2 and R 3 are methyl. Is most effective when the carbon number is 12-14.
  • component of Ami door Min O key side type surfactant is 15 to 50 weight in the composition 0/0, preferably 20-40% by weight blend. If the amount of component (a) is less than 15% by weight, the detergency will decrease. If it exceeds 50% by weight, the hygroscopicity will increase, the powder properties will decrease, and Ca ions and Mg present in water will be reduced. Such as ions It is more susceptible to hardness and reduces cleaning power.
  • Both amorphous and crystalline aluminosilicates can be used.
  • deterioration of the solubility of the detergent after storage at high humidity is further improved.
  • amorphous aluminosilicate used in the present invention examples include those represented by the following general formula G), which have high oil absorption and high cation exchange ability.
  • M is a metal atom
  • a, b, and c represent the number of moles of each component.
  • 0.7 ⁇ a ⁇ 2.0, 0.8 ⁇ b ⁇ 4, and c is any positive number. It is. ]
  • the resulting white precipitate slurry is then heated to 70-100 ° C, preferably 90-100 ° C. It can be advantageously obtained by performing a heat treatment at a temperature of 10 minutes or more and 10 hours or less, preferably 5 hours or less, followed by filtration, washing and drying.
  • a heat treatment at a temperature of 10 minutes or more and 10 hours or less, preferably 5 hours or less, followed by filtration, washing and drying.
  • the pH of the dispersion is measured based on JIS K 6220. That is, weigh out about 5 g of a sample in a hard Erlenmeyer flask, add 100 ⁇ of water without carbonic acid, stopper and shake for 5 minutes. Measure the pH by the glass electrode method (JIS Z 8802 7.2.3) using the liquid after shaking as the test liquid.
  • amorphous aluminosilicate having a pH of 5% dispersion of 9.0 or more, it is possible to obtain a high-density detergent composition whose solubility is not deteriorated when stored under high humidity conditions.
  • amorphous aluminosilicate is dispersed in a 2% aqueous NaOH solution lOOmf, and stirred at 25 ° C for 16 hours under a constant temperature condition, and SiO 2 in the filtrate is colorimetrically determined. 25 vol., Pl56, 1976), the amount of which is less than 0.5 g as amorphous aluminosilicate.
  • aluminosilicate crystalline generally all SANYO which is said to Zeorai bets, the following formula a '(M 2 0) ⁇ 2 0 3 ⁇ b' (SiO ⁇ w (H 2 O) (iii)
  • M is an alkali metal atom
  • a ', b', w represent the molar ratio of each component, and generally 0.7 ⁇ a ' ⁇ 1.5, 0.8 ⁇ b' ⁇ 6,, w It is a positive number.
  • zeolite a synthetic zeolite having an average primary particle size of 0.1 to 10 ⁇ typified by A-type, X-type, and P-type zeolites is suitably used.
  • Zeolite ⁇ Powder and zeolite or zeolite slurry may be blended as zeolite aggregated dry particles obtained by drying.
  • the aluminosilicate is incorporated in the composition in an amount of 5 to 60% by weight, preferably 8 to 30% by weight, particularly preferably 15 to 30% by weight. If the amount of aluminosilicate is out of this range, the detergency will decrease.
  • alkali agent used in the present invention examples include inorganic alkali metal salts and polyphosphate salts. Specifically, the following (1) and (2) can be used.
  • Crystalline silicate used in the present invention lay preferred alkali metal salt of silicic acid (Si0 2), among others, SiO zZ M s 0 of the alkali metal silicate (wherein, M represents an alkali metal) forces; 0.5 What is 2.6 is preferably used.
  • Conventionally known crystalline silicates have a power of SiO 2 ZM 2 ⁇ of 1.9 to 4.0; those having a ratio exceeding 2.6 may not be suitable for the formulation of the high-density detergent which is the object of the present invention.
  • the preferred crystalline silicate used in the present invention has the following composition.
  • M represents an element of group la of the periodic table
  • Me represents one or more elements selected from group Ila, nb, nia, group IVa, or group VIII of the periodic table.
  • Y / x 0.5 ⁇ 2.6
  • z / x 0.0 ⁇ ⁇ 1.0
  • w 0 ⁇ 20
  • n 0.5 to 2.0.
  • M is selected from the group la elements of the periodic table, and examples of the group la elements include Na and K. These may be used alone or, for example, a mixture of Na 20 and K 20 to constitute the M 20 component.
  • Me is selected from the group Ila element, group lib element, group Ilia element, group IVa element or group VIII element of the periodic table, for example, Mg, Ca, Zn, Y, Ti, Zr, Fe and the like. These are not particularly limited, but are preferably Mg and Ca from the viewpoint of resources and safety. These are alone or may also be a mixture of two or more, good example MgO, even constitute Me m 0 n components such as CaO are mixed les.
  • y / x is 0.5 to 2.6, and preferably 1.5 to 2.2.
  • X is less than 0.5, the water resistance is insufficient, and the masking property, solubility, and powder properties of the detergent composition are significantly adversely affected.
  • y / x exceeds 2.6, the alkalinity becomes low and the alkalinity becomes insufficient, and the ion exchange ability also becomes low, making it insufficient as an ion exchanger.
  • z / x is from 0.01 to 1.0, preferably from 0.02 to 0.9.
  • x, y, and z are not particularly limited as long as they are in the relationship represented by the y / x ratio and the z / x ratio described above.
  • ⁇ is ⁇ (Na 20) ⁇ x' + ⁇ " x (M 2 0) as in the previous SL for example x becomes.
  • z (Me m 0.) component is the same in put that z when composed of two or more.
  • nZm indicates the number of oxygen ions coordinated to the element, and is substantially selected from values of 0.5, 1.0, 1.5, and 2.0.
  • each component is required as a raw material, but is not particularly limited in the present invention.
  • Known compounds are appropriately used.
  • M 2 0 component, the Me "O n component, alone or oxides of the composite of each of those said elements, hydroxides, salts, and the element containing organic minerals are used.
  • M as the raw material of 2 0 component, NaOH, KOH, Na 2 CO 3, K 2 CO 3, Na 2 SO ⁇ etc.
  • Me m O n component CaCO 3, MgCO 3, Ca (OH) 2 , Mg (OH) 2 , MgO, ZrO 2 , dolomite, etc.
  • SiO 2 component examples include kaite, kaolin, talc, fused silica, and sodium silicate.
  • the method for preparing the crystalline silicate represented by the general formula ( ⁇ ) is to mix the above-mentioned raw material components at a predetermined ratio so that the desired crystalline silicate has x, y, and z values.
  • 300-1500. C preferably 500-1000. C, more preferably 600-900.
  • a method of firing and crystallization in the range of C is exemplified. In this case, if the heating temperature is lower than 300, the crystallization is insufficient and the water resistance is poor, and if the heating temperature exceeds 1500 ° C, the particles become coarse particles and the ion exchange ability decreases.
  • the heating time is usually 0.1 to 24 hours. Such firing can be usually performed in a heating furnace such as an electric furnace or a gas furnace.
  • crystalline silicate represented by the resulting general formula (II) with, a pH of 11 or more in a 0.1 wt 0/0 aqueous dispersion exhibits excellent alkalizing ability.
  • the buffering effect of aluminum carbonate is particularly strong, and it has an excellent alkali buffering effect even when compared to sodium carbonate or lithium carbonate.
  • the crystalline silicate represented by the general formula ( ⁇ ) has an ion exchange capacity of at least 100 mg of CaCOCO 3 mg Z g, preferably 200 mg to 600 mg of CaCO 3 mg Z g. Is one of the substances having
  • the crystalline silicate represented by the general formula (II) has an alkali function and an alkali buffering effect as described above, and further has an ion exchange function.
  • the washing conditions can be suitably adjusted.
  • the crystalline silicate represented by the general formula (II) preferably has an average particle size of 0.1 to ⁇ 00 ⁇ , more preferably 1 to 60 ⁇ . If the average particle size exceeds 100 ⁇ , the rate of onset of ion exchange tends to decrease, leading to a decrease in detergency. On the other hand, if it is less than 0.1 ⁇ , the specific surface area is increased, so that the hygroscopicity and CO 2 absorption are increased, and the quality tends to be remarkably deteriorated.
  • the average particle size referred to here is the particle size The median diameter of the distribution.
  • the crystalline silicate having such an average particle size and particle size distribution can be prepared by crushing using a crusher such as a vibration mill, a hammer-mill, a ball mill, a roller-mill and the like. For example, it can be easily obtained by grinding with a HB-0 type vibration mill (manufactured by Chuo Kakoki Co., Ltd.).
  • This crystalline silicate has the general formula (III)
  • Is represented as being in force; general formula ( ⁇ ) in the x ', y' is preferably a is I. 7 2. 2 and y ' 0, the cation exchange capacity is 100 to 400 CaCO 3 mgZg can be used and is one of the substances having an ion trapping ability in the present invention.
  • the crystalline silicate represented by the general formula (III) has such an alkali function and an alkali buffering effect, and further has an ion exchange function, by appropriately adjusting the blending amount thereof, The washing conditions can be suitably adjusted.
  • the production method of the crystalline silicate represented by the general formula (II) is described in JP-A-60-227895 (corresponding to US Pat. No. 4,664,839 or US Pat. No. 4,820,439). It is obtained by firing the glassy sodium silicate at 200 to 1000 ° C to make it crystalline. Details of the synthesis method are described in, for example, Phys, Chem. Glasses, 7, 127-138 (1966), and Z. Kris in llogr., 129, 396-404 (1969).
  • the crystalline silicate represented by the general formula (III) is, for example, Na-SKS-6j
  • Powders and granules can be obtained as (5-Na 2 Si 20 i).
  • the crystalline silicate represented by the general formula (III) has an average particle size of 0.1 to !, similarly to the crystalline silicate represented by the general formula (III). It is preferably 00 ⁇ , more preferably 1 to 60 ⁇ .
  • a crystalline silicate represented by the general formula (II) can be used alone or in combination of two or more.
  • polyphosphates such as orthophosphate, metaphosphate, pyrophosphate, tripolyphosphate, and hexametaphosphate can be used.
  • salts H, Na, and K are common.
  • Component (c) is used in an amount of 5 to 60% by weight of the composition. /. , Preferably 10 to 40 weight 0/0 compounded.
  • the crystalline silicate accounts for preferably 10 to 100% by weight, more preferably 30 to 80% by weight, and particularly preferably 50 to 80% by weight of the alkaline agent contained in the composition.
  • the following anionic surfactant and no or nonion surfactant (a ') can be blended.
  • the weight ratio of (a ′) Z (a) is 1/100 to 100/100, preferably 50 100 or less.
  • the following can be used as the anionic surfactant and the nonionic surfactant (a ').
  • C10-C18 higher fatty acid salts C10-C18 linear or branched primary or secondary alcohol sulfates, C8-C20 alcohol ethoxy sulfates , Alkyl (C B -C, benzenesulfonate, alkanesulfonate (SAS), ⁇ -olefin sulfonate and ⁇ _sulfofatty acid alkyl ester salt)
  • Anionic surfactants • Nonionic surfactants
  • the anionic surfactant and the nonionic surfactant may be blended alone, or a mixture of both may be blended.
  • organic builders can be used in addition to inorganic builders such as aluminosilicate.
  • Phosphonic acid salts such as ethane-1,1-diphosphonic acid, ethane-1,2, -triphosphonic acid
  • Polymer electrolytes such as polyethylene glycol, polybutyl alcohol, polyvinyl pyrrolidone, carboxymethyl cellulose, polyaspartic acid, etc.
  • Organic acid salts such as diglycolic acid and oxydisuccinic acid
  • Z is a monomer and / or its salt copolymerizable with (anhydrous) maleic acid or maleate such as 1-8 olefins, acrylic acid, methacrylic acid, itaconic acid, methallyl sulfonic acid, etc., and m is a copolymer one molecular weight have the values shown a several hundred to 100,000.
  • M is H, Na, ⁇ , a ⁇ 3.
  • ⁇ is a monomer capable of being homopolymerized, and examples thereof include acrylic acid, methacrylic acid, and maleic acid.
  • M ′ indicates that the molecular weight of the homopolymer is several hundred to 100,000. It is straightforward.
  • Homopolymer salts include Na, ,, NH and the like.
  • the amount of the copolymer (IV) or the homopolymer of the formula (V) and the homopolymer of the formula (V) in 4) is 1 to 8 parts by weight, preferably 2 to 6 parts by weight, based on 100 parts by weight of the detergent composition.
  • these polycarboxylates salts of acrylic acid-maleic acid copolymer and salts of polyacrylic acid (Na, ⁇ , and ⁇ ⁇ ⁇ ⁇ , respectively, are particularly excellent.
  • a molecular weight of 1,000 to 80,000 is suitable.
  • Biodegradation When the following builder is blended as an organic builder having good properties, a detergent composition exhibiting excellent cleaning performance can be obtained.
  • R represents a hydrogen atom or a hydroxyl group
  • X represents a hydrogen atom, an alkali metal or an ammonium group.
  • the builder of 1) to 2) is incorporated in the composition in an amount of 0.5 to 20% by weight, preferably 1.0 to 10% by weight. Among them, 1) shows an excellent effect. Furthermore, the system containing 1.0 to 5% by weight of 1) shows excellent cleaning performance. Further, the following components can be blended as components other than the above.
  • bleaching agent examples include sodium percarbonate, sodium perborate (preferably monohydrate), and an adduct of sodium hydrogen peroxide, and particularly preferred is sodium percarbonate.
  • bleach activator examples include tetraacetylethylenediamine, acetooxybenzenesulfonate, an organic peracid precursor, and a metal catalyst in which a transition metal is stabilized with a sequestering agent.
  • Enzymes can be classified according to their reactivity as follows: hydrolases, hydrolases, oxidoreductases, tesmolases, transferases, and isomerases. However, any of them can be applied to the present invention. Particularly preferred are hydrolases, including proteases, esterases, lipases, carbohydrases, nucleases, cellulases and amylases.
  • proteases include pepsin, trypsin, chymotrypsin, collagenase, keratinase, elastase, sptilisin, BPN, papain, promerin, carboxypeptidases A and B, aminopeptidases, aspaspyreptidase A and B, and commercially available products include Sabinaze, Alcalase (Novo Industries), API21 (Showa Denko KK), Maxacal (Gistprocades), and Protea described in JP-A-5-43892. One K-14 or K-16 force;
  • esterases include gastric lipase, buncreatic lipase, plant lipases, phospholipases, cholinesterases and phosphotase.
  • a commercially available lipase such as ribolase (Novo Industry Co., Ltd.) can be used.
  • carbohydrases include cellulase, maltase, saccharase, amylase, pectinase, lysozyme, ⁇ -glycosidase and ⁇ -glycosidase.
  • cellulase commercially available products such as Celzym (Novo Industry Co., Ltd.)
  • Celzym Novo Industry Co., Ltd.
  • amylase commercially available termamyl (Novo Industry Co., Ltd.) and the like can be used.
  • a reducing agent sodium sulfite, sodium bisulfite, calcium salt, magnesium salt, polyol, boron compound, etc.
  • Various bluing agents may be added as needed. For example, the following structures (a) and (b) are recommended.
  • D represents a blue-purple monoazo, disazo or anthraquinone dye residue, X and and are hydroxyl groups; substituted with an amino group, a hydroxyl group, a sulfonic acid group, a carboxylic acid group or an alkoxy group.
  • R represents a hydrogen atom or a lower alkyl group, provided that R represents a hydrogen atom, and (1) X and Y> simultaneously represent a hydroxyl group or an alkanolamino group; , And Y, except when one of them is a hydroxyl group and the other is an alkano-lamino group, and n represents an integer of 2 or more.
  • D 2 represents a blue to purple azo or anthraquinone dye residue; Represents a hydrogen atom or a lower alkyl group, and X 2 and Y 2 represent the same or different alkanolamino groups or hydroxyl groups.
  • the caking inhibitor include p-toluenesulfonate, xylenesulfonate, acetate, sulfosuccinate, tanolek, finely divided silica, clay, magnesium oxide and the like.
  • a porous material such as finely divided silica can be used as a carrier for the nonionic surfactant.
  • Clay smectite-like clay is also effective as a softening agent.
  • Antioxidants include tert-butylhydroxytoluene, 4,4'-butylidenebis- (6-tert-butyl-3-methylphenol), 2,2'-butylidenebis- (6-tert-butyl-4-methylphenol) And monostyrenated cresol, distyrenated cresol, monostyrenated phenol, distyrenated phenol, ⁇ , ⁇ -bis (4-hydroxyphenyl) cyclohexane and the like.
  • fluorescent dyes 4,4'-bis- (2-sulfostyryl) -biphenyl salt, 4,4'-bis- (4-1-chloro-3-sulfostyryl) -biphenylinole salt, 2- (styrylphenyl) naphthothiazole derivative
  • 4,4'-bis (triazol-2-yl) stilbene derivatives and bis (triazinylamino) stilbene disulfonic acid derivatives are contained in the composition in an amount of 0 to 1% by weight. can do.
  • a fragrance conventionally used in detergents for example, a fragrance described in JP-A-63-101496 can be used.
  • the high-density detergent composition of the present invention is a powdery or granular composition
  • its production method is not particularly limited, and a conventionally known method can be used.
  • a method of spraying a nonionic surfactant onto spray-dried particles to increase the density or a method of increasing the density while directly absorbing nonions into the powder component containing the oil absorbing carrier.
  • a crystalline aluminosilicate is blended as an aluminosilicate, a small amount thereof may be added during granulation or immediately before the completion of granulation in order to use it as a surface modifier for the granulated material.
  • a crystalline silicate When a crystalline silicate is blended, it is preferable to add the crystalline silicate at the time of increasing the bulk density or to add the crystalline silicate by dry blending.
  • the alkali metal carbonate when blended, it may be added to the slurry, during granulation or during dry blending.
  • the amide amine oxide as the component (a) may be added before or after the spray drying step.
  • the average particle size of the nonionic high-density granular detergent composition of the present invention is desirably 200 to 1000 ⁇ , preferably 200 to 600 ⁇ in order to obtain preferable powder properties. Further, the bulk density of the detergent composition of the present invention is about 0.5 to 1.2 gm, preferably about 0.6 to 1.0 gZn ⁇ .
  • the detergent composition of the present invention can be used at a concentration suitable for each washing depending on washing methods such as washing machine washing and pickling washing, as well as the amount of clothes and water, the degree of dirt, and the use of machines. it can.
  • washing machine washing it can be used at a washing concentration of 0.03 to 0.3% by weight.
  • a non-ionic high-density granular detergent composition having excellent detergency is obtained by using an amide amine oxide type surfactant having excellent biodegradability and excellent safety as a main component of the surfactant. Things are obtained.
  • Inventive product 1 of Table 1 was prepared by the following method.
  • high-density granular detergent compositions were prepared according to the above-mentioned schemes at respective mixing ratios.
  • the surfactants blended in the present products 18, 19, 20 and 26 were added to the slurry before spray drying.
  • the porous silicic compound of the product 12 of the present invention was added to the high-speed mixer and the amount of zeolite added to the high-speed mixer was reduced accordingly.
  • the resulting high-density granular detergent composition was subjected to a detergency test by the following method. The results are shown in Tables 1-4.
  • An artificially stained cloth having the following composition was attached to the cloth to prepare an artificially stained cloth.
  • the artificial contaminated liquid was attached to the cloth using a gravure roll coater.
  • Process for manufacturing the artificially stained cloth artificially contaminated liquid is adhered to the fabric, the cell capacity of a gravure roll 58cm a / m 2 coating fabric speed l .O m Z min, drying rate 100 e C, drying time 1 minute question went.
  • the cloth used was a cotton cloth 2003 (manufactured by Tanito Shoten).
  • Nonoremitic acid n-hexadecyl 2.18 weight 0 / o
  • the detergency was measured by measuring the reflectance at 550 nm of the original cloth before and after cleaning with a self-recording colorimeter (manufactured by Shimadzu Corporation), and the cleaning rate (./.) was calculated using the following formula. The measured average value was shown as detergency. Reflectance after cleaning-reflectance before cleaning
  • Porous silica compound Thixorex 25 (manufactured by Kofran Chemical Co.)
  • TP tripolyphosphate
  • HP sodium hexametaphosphate
  • AE-1 Nonionic surfactant, polyoxyethylene dodecyl ether (HLB, 13.1)
  • AM Na salt of acrylic acid / maleic acid (7-3 molar ratio) copolymer, average molecular weight 70,000
  • PA Na salt of polyacrylic acid average molecular weight 8000
  • the product 29 of the present invention in Table 5 was prepared by the following method.
  • a high-density granular detergent composition was obtained by dry-mixing 0.1 kg of the enzyme (average particle size: 430 ⁇ , allegory density: 780 g gl)
  • ASD A blended in the product 33 of the present invention was added to the slurry before spray drying.
  • the porous silica compound was added to a high-speed mixer in the same manner as silicate, and granulated.A predetermined amount of AE-1 heated to 70 ° C was added, and the mixture was granulated and Zeolite was added. Granulation was performed, and the remaining zeolite was further added to granulate to obtain a high-density granular detergent composition.
  • the resulting high-density granular detergent composition was subjected to a detergency test by the following method. Table 5 shows the results.
  • the same artificially contaminated liquid as in Example 1 was attached to the cloth to prepare an artificially contaminated cloth.
  • the artificial contaminated liquid was attached to the cloth using a gravure roll coater. Apply artificially contaminated liquid to cloth
  • the process of fabricating the artificially stained cloth was carried out with a gravure roll cell capacity of 58 cm 3 Z m 2 , a coating speed of 1.0 m / min, a drying speed of 100 ° C., and a drying time of 1 minute.
  • the cloth used was a cotton gold cloth 2003 (manufactured by Tanito Shoten). Reflectance after cleaning-reflectance before cleaning

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Cette invention concerne une composition détergente granulée et d'une densité élevée, laquelle composition possède d'excellentes qualités de biodégradabilité et de sécurité, ainsi qu'une meilleure détergence. Cette composition comprend, dans des proportions spécifiques, (a) un tensioactif à base d'oxyde d'amidoamine, (b) un sel aluminosilicate et (c) un agent alcalin, ladite composition possédant une densité apparente variant entre 0,6 et 1,2 g/ml. Le tensioactif à base d'oxyde d'amidoamine correspond à la formule générale (I) où R1 représente alcényle ou alkyle C10-C20; R2 et R3 représentent chacun H, alcényle ou alkyle C1-C3; R4 représente H, alcényle ou alkyle C1-C5; et enfin, n varie entre 1 et 5.
PCT/JP1997/000666 1996-03-13 1997-03-05 Composition detergente granulee et d'une densite elevee WO1997033960A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP5611496A JPH09241678A (ja) 1996-03-13 1996-03-13 非イオン性高密度粒状洗剤組成物
JP8/56114 1996-03-13

Publications (1)

Publication Number Publication Date
WO1997033960A1 true WO1997033960A1 (fr) 1997-09-18

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PCT/JP1997/000666 WO1997033960A1 (fr) 1996-03-13 1997-03-05 Composition detergente granulee et d'une densite elevee

Country Status (2)

Country Link
JP (1) JPH09241678A (fr)
WO (1) WO1997033960A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999032572A1 (fr) * 1997-12-19 1999-07-01 Akzo Nobel N.V. Procede permettant de reguler la rheologie d'un fluide aqueux et agent gelifiant utilise a cet effet
US6506710B1 (en) 1997-12-19 2003-01-14 Akzo Nobel N.V. Viscoelastic surfactants and compositions containing same
US7216709B2 (en) 1999-09-22 2007-05-15 Akzo Nobel N.V. Hydraulic fracturing using non-ionic surfactant gelling agent
US7358215B1 (en) 1999-09-07 2008-04-15 Akzo Nobel Surface Chemistry Llc Quaternary ammonium salts as thickening agents for aqueous systems

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3625126B2 (ja) * 1997-10-20 2005-03-02 花王株式会社 アスファルト乳剤用カチオン性乳化剤
JP3913369B2 (ja) * 1998-09-04 2007-05-09 花王株式会社 洗浄剤組成物
EP1104804B1 (fr) * 1999-06-14 2005-04-20 Kao Corporation Procede de production de particules detergentes a un seul noyau
JP6144576B2 (ja) * 2013-08-26 2017-06-07 花王株式会社 衣料用洗浄剤組成物
US12157868B2 (en) 2019-06-21 2024-12-03 Ecolab Usa Inc. Solidified nonionic surfactant composition comprising a solid urea binder

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5059572A (fr) * 1973-09-29 1975-05-22
JPS57150649A (en) * 1981-02-06 1982-09-17 Emery Industries Inc Amidoamine oxide of polymeric aliphatic acid
JPS5879099A (ja) * 1981-10-19 1983-05-12 ユニリ−バ−・ナ−ムロ−ゼ・ベンノ−トシヤ−プ アミドベタインおよび塩類を含有する粘稠組成物
JPS61283695A (ja) * 1985-06-11 1986-12-13 川研ファインケミカル株式会社 洗浄剤組成物
JPH06293896A (ja) * 1993-02-10 1994-10-21 Nippondenso Co Ltd 金属材料のろう付前処理剤

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5059572A (fr) * 1973-09-29 1975-05-22
JPS57150649A (en) * 1981-02-06 1982-09-17 Emery Industries Inc Amidoamine oxide of polymeric aliphatic acid
JPS5879099A (ja) * 1981-10-19 1983-05-12 ユニリ−バ−・ナ−ムロ−ゼ・ベンノ−トシヤ−プ アミドベタインおよび塩類を含有する粘稠組成物
JPS61283695A (ja) * 1985-06-11 1986-12-13 川研ファインケミカル株式会社 洗浄剤組成物
JPH06293896A (ja) * 1993-02-10 1994-10-21 Nippondenso Co Ltd 金属材料のろう付前処理剤

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JOURNAL OF AMERICAN OIL CHEMISTS' SOCIETY, (Chicago, USA), Vol. 50, No. 12, (1973), PARRIS, NICHOLAS et al., "Soap Based Detergent Formulation: V. Amphoteric Lime Soap Dispersing Agents", p. 509-512. *
JOURNAL OF AMERICAN OIL CHEMISTS' SOCIETY, (Chicago, USA), Vol. 54, No. 7, (1977), PARRIS, NICHOLAS et al., "Soap Based Detergent Formulation: XXIV. Sulfobetaine Derivatives of Fatty Amides", p. 294-296. *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999032572A1 (fr) * 1997-12-19 1999-07-01 Akzo Nobel N.V. Procede permettant de reguler la rheologie d'un fluide aqueux et agent gelifiant utilise a cet effet
US6239183B1 (en) 1997-12-19 2001-05-29 Akzo Nobel Nv Method for controlling the rheology of an aqueous fluid and gelling agent therefor
US6506710B1 (en) 1997-12-19 2003-01-14 Akzo Nobel N.V. Viscoelastic surfactants and compositions containing same
USRE41585E1 (en) * 1997-12-19 2010-08-24 Akzo Nobel Nv Method for controlling the rheology of an aqueous fluid and gelling agent therefor
US7358215B1 (en) 1999-09-07 2008-04-15 Akzo Nobel Surface Chemistry Llc Quaternary ammonium salts as thickening agents for aqueous systems
US7216709B2 (en) 1999-09-22 2007-05-15 Akzo Nobel N.V. Hydraulic fracturing using non-ionic surfactant gelling agent

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