WO1997036205A1

WO1997036205A1 - Color liquid crystal display device and its manufacture

Info

Publication number: WO1997036205A1
Application number: PCT/JP1996/000755
Authority: WO
Inventors: Mariko Urushibara; Hirotaka Imayama; Ryooji Iwamura; Hitoshi Azuma; Masao Uehara; Shigeyuki Okada
Original assignee: Hitachi, Ltd.
Priority date: 1996-03-22
Filing date: 1996-03-22
Publication date: 1997-10-02

Abstract

A color liquid crystal display device which can display high-quality pictures by preventing the deterioration of the picture quality resulting from light leakage and uneven color tones caused by spacers scattered on a displaying picture element section by resolving such a trouble that the color tone and contrast of a color liquid crystal panel and the picture quality are deteriorated by spacers on the entire surface of a substrate. Since two glass substrates having patterned transparent electrodes are faced to each other with spacer beads in between and spacer beads are distributed on a black matrix formed on a color filter constituting the color liquid crystal panel, no spacer exists in the displaying picture element section. Therefore, the light leakage, etc., caused by the spacers does not occur and a color liquid crystal display which has high cell gap height accuracy and can display high-quality pictures can be obtained.

Description

Specification

Technical Field

The present invention relates to a color liquid crystal display device in which a cell gap is formed using a spacer material and a method for manufacturing the same. Background art

A color liquid crystal panel used in a conventional color liquid crystal display device is arranged at a fixed interval through a spherical or cylindrical spacer made of silica, alumina, plastic, etc. between a pair of transparent electrodes facing each other. In general, a cell gap was maintained and liquid crystal was sealed in the gap. This spacer material is sprayed on the electrode substrate. If the spray density is not uniform within the panel surface, cell gap unevenness is caused, and accordingly, color unevenness and contrast of the liquid crystal panel are caused. A phenomenon such as a drop in image quality and a decrease in image quality was observed.

Therefore, as a method of uniformly dispersing the spacer material on the substrate, in the related art, a spraying method using a dry method and a wet method is used. These spraying methods disperse the spacer material over the entire surface of the substrate by, for example, spraying nitrogen gas onto a nozzle attached to the container containing the spacer material or utilizing a pressure difference in the container.

However, according to the conventional method in which a spacer material is sprayed on the entire surface of the substrate, as shown in FIG. 3, the display pixel portion 2 (red R, blue B, green G) formed on the substrate also has a spacer. Material 7 adhered, and the monitor material 7 adhered to the display pixel section 2 As a result, light is always transmitted regardless of the driving of the liquid crystal panel, and a height variation of several meters between the display pixel portion 2 of the substrate and the black matrix 4 is caused by Since the cell gap becomes non-uniform depending on where the spacer material 7 adheres, there is a problem that the color tone contrast of the color liquid crystal panel is reduced and the image quality is degraded.

The present invention solves such a problem, and prevents a deterioration in image quality such as light leakage and color tone unevenness caused by the spreader material 7 scattered in the display pixel portion 2, thereby achieving a high quality color image. It is an object to provide a liquid crystal display device and a method for manufacturing the same. Disclosure of the invention

In order to solve the above-mentioned problems, the present invention provides a color liquid crystal display device in which a pair of glass substrates on which transparent electrodes having a predetermined pattern are formed are opposed to each other via a spacer material. The cell gap is formed by distributing and placing spacer materials in the area corresponding to the black matrix formed in FIG.

By distributing the spacer material in the area corresponding to the black matrix, since the spacer material is hardly present in the display pixel portion, light leakage or the like due to the spacer material is prevented. At the same time, it is possible to obtain a high-quality color liquid crystal display device with high cell gap height accuracy. BRIEF DESCRIPTION OF THE FIGURES

FIG. 1 is a plan view of a panel used in a color liquid crystal display device of the present invention in which spacer materials are dispersed on a black matrix of a color filter substrate.

(a) Structure and cross-sectional view (b) are shown.

Fig. 2 is a schematic diagram of a spacer disperser. Fig. 3 is a plan view (a) and a cross-sectional view (b) of a conventional color LCD panel. FIG. 4 shows a sectional view (a) and a plan view (b) of a color filter substrate A used in the present invention.

FIG. 5 shows a cross-sectional view (a) and a plan view (b) of a color filter substrate B used in the present invention.

FIG. 6 shows a sectional view (a) and a plan view (b) of a color filter substrate C used in the present invention.

FIG. 7 shows a sectional view (a) and a plan view (b) of a color filter substrate D used in the present invention.

Fig. 8 shows a method of dispersing and distributing spacer materials by applying electric charges to the black matrix of a color filter substrate or a transparent electrode having the same pitch and pattern width as the black matrix. FIG.

Fig. 9 shows the dispersion of spacer material by applying charges to the black matrix of a color filter substrate or transparent electrodes having the same pitch and pattern width as the black matrix and the display pixel area. Sectional drawing which shows the arrangement method. FIG. 10 shows a sectional view (a) and a plan view (b) of a drive electrode substrate A used in the present invention.

FIG. 11 shows a sectional view (a) and a plan view (b) of a drive electrode substrate B used in the present invention.

FIG. 12 is a cross-sectional view showing a method of dispersing and disposing a spacer material by applying a charge to a transparent electrode having the same pitch and pattern width as the black matrix of the drive electrode substrate.

FIG. 13 shows a spacer formed by applying a charge to a transparent electrode having the same pitch and pattern width as the black matrix of the drive electrode substrate, and to other transparent electrode parts other than the above-mentioned electrode. Sectional drawing which shows the dispersion | distribution arrangement method of a material.

FIG. 14 is a sectional view (a) of dummy pattern substrates A, B, and C used in the present invention. (b), (c) and plan view (d) are shown.

FIG. 15 shows a method of disposing a spacer material using a dummy pattern substrate.

FIG. 16 is a schematic diagram showing the principle of a dispersing device for a spacer material by the jet method.

FIG. 17 is a cross-sectional view of a color filter substrate used for dispersing a spacer material by the jet method.

FIG. 18 is a main configuration diagram showing the principle of dispersion of the spacer material by the jet method.

FIG. 19 shows sectional views (a) and (b) and a plan view (c) of dummy pattern substrates D and E used for the wet dispersion method.

FIG. 20 is a principal configuration diagram showing the principle of a device for dispersing a spacer material on a dummy pattern substrate for a color filter by a dot method.

FIG. 21 is a cross-sectional view showing a dispersion arrangement method in which a spacer material is arranged on a black matrix of a color filter substrate using a dummy pattern substrate in the jet method dispersion method.

FIG. 22 shows a sectional view (a) and a plan view (b) of the dispersion film. FIG. 23 is a process chart showing a method for dispersing and disposing a spacer material using a dispersion filter.

FIG. 24 shows a sectional view (a) and a plan view (b) of a main part of the dispersion filter with electrodes.

FIG. 25 is a process chart showing a method of dispersing and disposing a spacer material using a dispersion filter with electrodes.

FIG. 26 is a main part configuration diagram showing a method of dispersing a spacer material using a fine nozzle. FIG. 27 is a main part configuration diagram showing a method of dispersing a spacer material using a plurality of fine nozzles. BEST MODE FOR CARRYING OUT THE INVENTION

Hereinafter, an embodiment of the present invention will be described in detail with reference to the drawings. FIG. 1 shows the configuration of a liquid crystal panel according to one embodiment of the present invention. FIG. 1 (a) is a plan view of a color liquid crystal panel, and FIG. 1 (b) is a cross-sectional view taken along line AA ′ of FIG. 1 (a). The color liquid crystal panel joins two opposing substrates 1 and 101 (a color filter substrate and a drive electrode substrate) via a spacer material, in this example, a spacer bead 7 as an example. It is produced by pouring the liquid crystal 6 into the gap. Of the two opposing substrates, the lower one, the color filter substrate 1, has a display pixel area (red R, blue B, 綠 G) and a black matrix 4, which is a light shielding layer between them. In addition, a drive electrode 8 made of a thin film transistor is formed on a glass substrate on a drive electrode substrate 101 as an upper substrate, and an alignment film 5 is formed on the surface thereof. In the color liquid crystal panel of the color liquid crystal display device of the present invention, the spacer bead 7 is provided at a predetermined interval on at least one of the color filter substrate 1 and the drive electrode substrate 101. In this case, the beads 7 for the spacers are dispersed and arranged on the black matrix 4 formed on the color filter substrate to form a cell gap. . In addition, the upper and lower substrates 1 and 101 are joined via a spacer bead 7 disposed only on the black matrix 4 to achieve a cell gap height accuracy of ± A high-precision cell gap of 0.05 m or less is formed, and as shown in the conventional example of FIG. 3, light leakage and uneven color tone caused by spacer material 7 scattered in the display pixel unit 2 Image quality is prevented from deteriorating. By using these substrates, a high-quality color liquid crystal display device can be realized.

Next, the spacer beads 7 are applied to the black filter formed on the color filter substrate 1. An embodiment in which the matrix is dispersedly arranged on the matrix 4 or on a predetermined position of the drive electrode substrate 101 will be described in detail below.

(Example 1)

Utilizing the charge of the spacer beads, the black matrix formed on the color filter substrate is charged with a charge having a different polarity from that of the spacer beads. A method for dispersing spacer beads only on a liquid will be described.

FIG. 2 is a schematic diagram of a bead dispersing device for a spacer used in this embodiment. The bead dispersing device for spacers consists of 15 beads stirring vessel for spacer, 16 nozzles for ejecting beads for spacer, 17 nozzles for ejecting compressed gas, 19 beads dispersing chamber for spacer, and cover. 2 0. Reference numeral 18 denotes a compressed gas supply device. In the bead stirring vessel 15 for pressure, which is applied with a pressure higher than the atmospheric pressure, spacer beads 7 having a particle size of 6 to 9 m are monodispersed in a dry state. The container 15 is provided with a bead spray nozzle 16 for a sensor. Around the spacer bead ejection nozzle 16, a compressed gas ejection nozzle 17 for supplying / injecting the compressed gas from the compressed gas supply device 18 is arranged, for example, concentrically. By ejecting the compressed gas from 17, a negative pressure is generated in the spacer bead injection nozzle 16, and using this force, the bead dispersing chamber 1 separated by the cover 20 using the force. The bead 7 for a spacer is sprayed on the board 21 inserted in the board 9. At this time, the spacer beads 7 are electrically charged, and the dispersed spacer beads 7 fall naturally by their own weight and are dispersed and arranged on the substrate 21. 22 is a chuck for the substrate 21.

Using the above apparatus, the beads 7 for the spacer were dispersed. In the present invention, spherical beads having a particle size of 6 to 9 m made of a plastic material are used as spacer materials. In addition, spherical beads having a particle diameter of 6 to 9 ^ m, such as a cylindrical force or alumina, can be used. In addition, when the beads for splicer 7 fall naturally, the beads for sprinkler whose abrasive grain size has increased due to agglomeration, etc., will naturally drop in the initial stage after ejection due to the increase in their own weight. For this reason, it is desirable that the substrate 21 should be carried into the apparatus after a while after the spacer beads are ejected.

The above-described embodiment uses a Coulomb force to disperse and disperse the beads for the Hess base on the black matrix formed on the color filter substrate. The structure of the color filter substrate A will be described with reference to FIG. The black matrix 4 of the color filter substrate 1 is made of a conductive material such as carbon or molybdenum as a component thereof, and is wired so that a uniform arbitrary voltage can be directly applied only to the black matrix 4. Substrate.

FIG. 8 shows the principle of dispersal arrangement of beads for a spacer using Coulomb force using the color filter substrate A described above. When the color filter substrate A is introduced into the apparatus (FIG. 2) in which the beads 7 for spraying are sprayed, the wiring is connected to the black matrix 4 so that A charge having a polarity different from that of the beads 7 is applied (tens to hundreds of V). At this time, an attractive force is generated between the spacer beads 7 and the black matrix 4 by the Coulomb force, and the spacer beads are guided only on the black matrix 4 by this attractive force and distributed. Can be placed.

The above dispersion method can also be realized by using a color filter substrate B or C or D.

Fig. 5 shows the structure of the color filter substrate B. The color filter substrate B is a substrate having electrodes 10 buried along the black matrix 4 and having a wiring structure so that a voltage can be arbitrarily applied. This is, for example, A pitch and pattern width mask similar to the pattern of black matrix 4 is formed on glass substrate 1 by trilithography technology, and is transparent on black matrix 4 by sputtering technology and printing technology. It can be manufactured by forming the electrode 10 and then forming the alignment film 5. The transparent electrodes 10 formed on the black matrix 4 are arranged so that a uniform voltage can be arbitrarily applied.

Fig. 6 shows the structure of the empty filter substrate C. The color filter substrate C has a wiring structure that allows a uniform arbitrary voltage to be directly applied to the black matrix 4, and the uniform voltage is applied to the display pixel section 2 independently of the black matrix 4. Has a wiring structure that can be applied arbitrarily.

In FIG. 6, reference numeral 9 denotes a power supply, and 80 denotes a wiring.

Fig. 7 shows the structure of the color filter substrate D. The color filter substrate D has a wiring structure in which the electrodes 11 are embedded along the black matrix 4 so that a voltage can be arbitrarily applied, and is independent of the black matrix 4. In addition, the wiring structure is such that a uniform voltage can be arbitrarily applied to the display pixel portion 2.

In particular, when the color filter substrate C or the color filter substrate D is used, the electrodes 10 and 11 embedded on the black matrix 4 or the black matrix 4 are provided with spacer beads 7. As shown in FIG. 9, by applying a voltage so as to have a different polarity charge and applying a voltage to the display pixel portion 2 so as to have the same polarity charge as the spacer beads 7. In addition, since the attractive force acts on the spacer beads 7 on the black matrix 4 and the repulsive force acts on the spacer beads 7 on the display pixel section 2, the spacers are more efficiently placed on the black matrix 4 of the color filter substrate 1. It is possible to disperse the beads 7 for use.

(Example 2)

Next, in Example 2, the electric charge of the spacer beads was used to drive By applying a spacer bead and a different polarity charge to the black matrix formed on the electrode substrate 101, the spacer bead is distributed only on a predetermined position of the substrate 101. A method of dispersing spacer beads to be arranged will be described.

FIG. 10 shows the structure of the drive electrode substrate A used in this embodiment. The drive electrode substrate A has a drive electrode 8 on which a transparent electrode 12 having the same pitch and pattern width as the black matrix 4 described above is formed. Are wired so that a uniform voltage can be arbitrarily applied. Further, when the drive electrode substrate 101 and the color filter substrate are joined via the spacer bead 7, the relative positional relationship such that the transparent electrode 12 and the black matrix 4 overlap. This is because, for example, the same pitch and pattern width mask as the pattern of the black matrix 4 is formed on the glass substrate 1 by the photolithography technology, and the sputtering technology and the printing technology are used. It can be manufactured by forming a transparent electrode on the driving electrode and then forming an alignment film.

FIG. 12 shows the principle of the dispersed arrangement of the beads for the spacer using the Coulomb force using the drive electrode substrate A. When the drive electrode substrate A is inserted into the spraying chamber 19 sprayed for the spacer of the apparatus shown in FIG. 2 described above, the transparent electrode 1 having the same pitch and pattern width as the black matrix 4 is used. A charge having a polarity different from that of the spacer bead 7 is applied to the wiring connected to 2 (several tens to several hundreds of V). At this time, an attractive force is generated between the spacer beads 7 and the transparent electrode 12 by the Coulomb force, and the spacer beads can be guided and dispersed only on the transparent electrode 12 by the attractive force. .

The dispersion method described above can also be realized by using the drive electrode substrate B. FIG. 11 shows the structure of the drive electrode substrate B. The drive electrode substrate B has the same pitch and pattern width as the black matrix 4 on the drive electrode. In addition to the formation of the bright electrodes 12, the transparent electrodes 13 are formed on the drive electrodes corresponding to the display pixels excluding the transparent electrodes 12, and these transparent electrodes 12, 13 are formed. Are wired so that a uniform voltage can be applied independently. Further, when the drive electrode substrate and the color filter substrate are joined via the spacer beads ベー, the transparent electrode 12 and the black matrix 4 have a relative positional relationship such that they overlap each other. This is because, for example, a mask having the same pitch and pattern width as the pattern of the black matrix 4 is formed on a glass substrate by photolithography technology, and the transparent electrode 12 having the same pattern is formed by sputtering technology or the like. It is formed on the drive electrode by printing technology. Next, similarly, a transparent electrode 13 corresponding to a display pixel is formed on a portion other than the formed transparent electrode 12, and thereafter, an alignment film is formed.

In particular, when the substrate B is used, charges having a different polarity from the beads 7 for the spacer are applied to the transparent electrode 12 having the same pitch and pattern width as the black matrix 4 of the driving electrode substrate 101. By applying a voltage to the transparent electrode 13 formed on the drive electrode excluding the transparent electrode 12 so as to have the same polarity as that of the spacer beads 7. 13 As shown in Fig. 13, the attractive force acts on the spacer beads 7 in the former and the repulsive force acts on the spacer beads 7 in the latter, so that a pitch similar to the black matrix 4 of the drive electrode substrate 101 is more efficiently used. Further, it is possible to disperse the spacer beads 7 only on the transparent electrode 12 having the pattern width.

(Example 3)

Next, as an example, a dummy pattern substrate having electrodes having the same pitch and butter width as the black matrix of the color filter substrate was used by utilizing the charge of the spacer beads, By applying an electric charge of a different polarity to that of the spacer beads, the spacer beads are separated on the pattern. A method of dispersing beads for spacers in which spacer beads are transferred onto black matrix formed on a color filter substrate by using electrostatic force after being scattered is described. .

FIG. 14 shows the structure of the dummy pattern substrate A used in the present invention. The substrate A has a groove with a depth of 3 to 1 Om having the same pitch and pattern width as the above-mentioned black matrix 4 on the surface of the substrate A, and a uniform groove on the base of the groove. The transparent electrode 24 is formed so that a voltage can be arbitrarily applied. Also, it is not particularly specified as a substrate material. For the dummy pattern substrate A, a pattern mask having the same pitch and pattern width as the black matrix 4 of the color filter substrate is formed on the substrate by photolithography, for example, and dry or wet etching is performed. The groove can be formed in the required pattern shape by using this method, and the electrode can be buried by spattering.

FIG. 15 shows a process of a method for dispersing beads for a spacer using the dummy pattern substrate A described above. Using the bead dispersion device for spacers shown in FIG. 2 of Example 1, the beads for spacers are dispersed in the dummy pattern substrate. As a dispersion method, a method similar to the principle shown in FIG. 8 of the first embodiment is used. That is, as shown in FIG. 15 (b), the electrodes 24 formed on the dummy pattern substrate A23 are made to have the same pattern as the pattern of the black matrix 4 of the color filter substrate 1 in a single pattern. By applying a voltage of several tens to several hundreds V so as to have a different polarity from the electric charge of the bead 7, the attractive force due to the Coulomb force generated between the bead 7 for spacer and the electrode 24. The beads 7 for spacers are dispersed and arranged only on the pattern of the black matrix 4 by using.

The dummy pattern board B or C shown in FIGS. 14 (b) and (c) is used as the dummy pattern board shown in FIGS. 15 (a) and (c). Is also possible. The electrode pattern substrate B shown in FIG. 14 (b) has electrodes 24 formed in a convex state at the same pitch and pattern width as the black matrix 4 of the color filter substrate. This is a substrate that has a wiring structure that can apply arbitrarily.This is a photomask that forms a pattern mask similar to the black matrix 4 pattern of the color filter substrate, and Alternatively, it can be produced by forming electrodes by a printing technique.

The structure of the dummy pattern substrate C is shown in Fig. 14 (c). In the dummy substrate C, the electrodes 24 having the same pitch and pattern width as the black matrix 4 of the color fill substrate are embedded in the substrate 23 so that a voltage can be arbitrarily applied. This is a substrate having a wiring structure. In this method, a groove similar to the pattern of the black matrix 4 is formed on a glass substrate by a photolithography technique, and an electrode is formed in a concave portion by a sputtering technique or a printing technique. The electrode 24 is wired so that a uniform voltage can be arbitrarily applied. The same material as that of the substrate is sputtered or printed on the electrode 24 to form the electrode 24 embedded in the substrate 23. Can be formed.

Returning to FIG. 15, after the spacer beads 7 are dispersed and arranged on the dummy pattern substrate A, while maintaining the voltage applied to the electrodes 24 formed on the dummy pattern substrate 23, FIG. Invert as shown in (c), and align with the black matrix 4 of the substrates A to D shown in FIGS. 4 to 7 of the first embodiment. After the pattern positions S of both have been set, the voltage applied to the electrodes 24 of the dummy pattern substrate 23 is made the same polarity as that of the spacer beads 7 to cause repulsion, and the black matrix of the color filter substrate 1 is actuated. By making the voltage applied to the box 4 different from that of the spacer beads 7, the spacer beads 7 generate a repulsive force from the dummy pattern board 23 by Coulomb force, and a Move to black matrix 4 and distribute to receive attraction. In particular, when the above-described color filter substrate C or D is used, the transparent electrodes 10 and 11 having a pattern having the same pitch and pattern width as or on the black matrix 4 are used. In addition to applying a charge of the same polarity as that of the spacer beads 7 to the display pixel section 2 and applying a charge of the same polarity as the spacer beads 7 to the display pixel portion 2, more efficient blackening is achieved. It is also possible to disperse the beads 7 for the spacer only on the matrix 4.

(Example 4)

Next, as a fourth embodiment, a dummy pattern substrate having electrodes having the same pitch and pattern width as the black matrix of the color-fill substrate using the charge of the spacer beads was used. The spacer beads are dispersed and arranged on the pattern by applying a spacer bead and a different polarity charge to this electrode, and then the electrostatic bead is used to place a bead on the drive electrode substrate at a predetermined position. A method for dispersing a bead for use in transferring a bead for the use of a sensor will be described.

Using the dummy pattern substrate A, B or C shown in FIGS. 14 (a), (b), and (c) of FIG. 14 of the third embodiment, the spacer beads shown in FIG. 2 of the first embodiment are used. The dispersing device disperses the beads 7 for the dummy pattern substrate. As a dispersing method, a method similar to the principle shown in FIGS. 4 to 7 of the first embodiment is used. The electrodes 24 formed on the dummy pattern substrate A have the same polarity as the black matrix pattern of the color filter substrate so that the electrodes 24 have a polarity different from that of the electric charge of the spacer beads 7. By applying a voltage of 100 V, the spacer beads 7 are dispersed only on the black matrix pattern 4 using the attractive force of the Coulomb force generated between the spacer beads 7 and the spacer beads 7. Let it.

The spacer beads 7 are dispersed in the dummy pattern substrate by using the dummy pattern substrate B or C shown in FIG. 14 of the third embodiment. Is also possible.

Next, after the spacer beads 7 were dispersed and arranged on the dummy pattern substrate A, the spacer beads were inverted while maintaining the voltage applied to the electrodes formed on the dummy pattern substrate. 1 Pattern matching is performed with a transparent electrode 12 having a pattern of the same pitch and pattern width as the black matrix 4 formed on the drive electrode substrate A or B shown in FIGS. After the pattern positions of both are set, the voltage applied to the electrodes 24 of the dummy pattern substrate 23 is set to the same polarity as the beads 7 for the spacers, and the black matrix 7 of the drive electrode substrate 101 is set to the same polarity. By making the voltage applied to the transparent electrode 12 having a pattern of the same pitch and pattern width different from that of the spacer beads 7, the spacer beads 7 are separated from the dummy pattern substrate by Coulomb force. Receives a repulsive force and an attractive force from the drive electrode substrate 101, moves and disperses them on the transparent electrodes 12 having a pattern having the same pitch and pattern width as the black matrix 4.

In particular, when the driving electrode substrate B is used, in addition to applying the charge of the opposite polarity to the spacer beads 7 to the transparent electrode 12 having the same pitch and pattern width as the black matrix 4, By applying a charge of the same polarity as that of the spacer beads 7 to the transparent electrode 13 other than the transparent electrode 12 having a pattern of the same pitch and pattern width as the black matrix 4, It is possible to efficiently disperse the spacer beads 7 only on the pattern having the same pitch and pattern width as the black matrix.

(Example 5)

Next, examples of another method of dispersing beads for a spacer will be described. The glass substrate is immersed in a solution in which the beads for spacers are dispersed, and is lifted obliquely upward to take advantage of the steps of the black matrix formed on the color filter substrate. Disperse the beads for This is a bead dispersing method for a spacer.

Fig. 16 shows the principle of the bead dispersing device for spacers using the jet method.

The apparatus is composed of a substrate transfer section including a chuck 27 and an arm 28, and a solution tank 26 for a bead dispersion solution 25 for a spacer.

The substrate 21 is fixed to a chuck 27 whose entrance angle and discharge angle with respect to the liquid surface of the solution tank can be adjusted arbitrarily. This chuck 27 is an arm 2 whose vertical speed can be adjusted. Attached to 8. By using such an apparatus, the substrate 21 can be taken out of the spacer bead dispersion solution 25 at an arbitrary angle and at an arbitrary speed.

The bead dispersion solution 25 is prepared by converting a bead made of silica, alumina, polyethylene, etc. with a particle size of several meters into pure water or 30% isopropanol mixed pure water. Dispersion and stirring are used, and the mixing amount of beads for spacer is 10 to 30 w%. The spacer beads 7 are completely monodispersed in the solution.

FIG. 17 shows a cross section of the color filter substrate 1 used in this dispersion method. The color matrix substrate 1 has a black matrix pattern portion having a depth of about 2 m and a width of about 10 m due to manufacturing processes such as film formation.

Next, Fig. 18 shows the principle of the method of dispersing beads for spacers by the jet method. The color filter substrate 1 is fixed to the chuck 27, and is completely immersed in the spacer bead dispersion solution 2δ by the movement of the arm 28. Thereafter, the chuck 27 is tilted in the solution 25 so as to be at an angle of 10 to 45 degrees with respect to the solution surface, and a constant angle of 5 to 100 mm Zs is maintained by the arm 28 while maintaining a constant angle. Increase diagonally at speed. As shown in Fig. 17, the cross-section of substrate 1 is the pattern of black matrix 4 due to the manufacturing process such as film formation. The concave portion has a depth of about 2 m and a width of about 1 Q μm, and as the chuck 27 rises, the spacer beads 7 are dispersed and arranged along the concave shape. . The dispersion arrangement ratio of the spacer beads 7 depends on the viscosity of the solution 25, the angle of the chuck 27, the rising speed, and the like. By controlling this value arbitrarily, the spacer beads can be adjusted. 7 can be controlled. The adhesion of the spacer beads 7 to the back surface of the substrate 1 can be completely removed by, for example, an air knife that blows high-pressure air to the back surface, although not shown.

The method of dispersing the spacer beads by the slit method is a method in which the spacer beads 7 are dispersed and adhered to the concave portions by using the groove shape formed on the surface of the substrate 1. Therefore, by using the color filter substrate A or B or C or D shown in FIG. 4 to FIG. It is also possible to disperse the beads 7 only on the black matrix 4.

(Example 6)

Next, a dummy pattern substrate having a groove shape similar to that of the black matrix of the color filter substrate is immersed in a solution 25 in which spacer beads 7 are dispersed, and is slid upward. By pulling up, the spacer beads 7 are dispersed and arranged on the dummy pattern, and then the black matrix 4 formed on the color filter or the drive A method of dispersing the spacer beads 7 for transferring the spacer beads 7 onto a predetermined position on the substrate will be described.

The dummy pattern substrate D used in this embodiment is shown in FIG. On the surface of the dummy pattern substrate D23, grooves having the same pitch and pattern width as the black matrix of the color filter substrate are formed. The groove has a concave shape with a depth of l to 6 m and a width of about 8 to 10 μm. An electrode 24 to which pressure can be applied is formed. This is a black matrix by photolithography. A pattern mask reverse to that of the evening is formed, a groove is formed in a required pattern shape by dry or wet etching, and then an electrode 24 is formed at the bottom of the groove by sputtering. At this time, the electrode may be embedded in the groove bottom. Various materials such as glass and ceramics can be used as the substrate material.

For dispersing the spacer beads 7, a spacer bead dispersing apparatus according to the jet method shown in FIG. 16 of Example 5 was used. The beads dispersed solution for spacer 25 contains beads for sensors made of silica, alumina, polypropylene, etc. with a particle size of several meters, pure water or 30% isopropanol. The mixture is mixed and stirred in pure water, and the mixing amount of the beads 7 for the spacer is 10 to 30 w%. The spacer beads 7 are completely monodispersed in the solution 25.

Next, Fig. 20 shows the principle of the method of dispersing beads for spacers by the nip unit method. The dummy pattern substrate 23 is fixed to the chuck 27, and is completely immersed in the bead dispersion solution 25 for spacer by the movement of the arm 28. Then, chuck 27 is tilted in the solution so that it is at 10 to 45 degrees with respect to the surface of solution 25, and rises obliquely at a constant speed of 5 to 10 Omm / s while maintaining the angle. Let it. In the cross section of the dummy pattern substrate 23, the pattern portion similar to the black matrix 4 is in a recessed state with a depth of about 2 m and a width of about 10 m. Accordingly, spacer beads 7 are dispersedly arranged along the concave shape.

Next, a method of transferring the spacer beads 7 arranged on the dummy pattern substrate 23 onto the color filter substrate 1 is shown in FIG.

A voltage different from that of the spacer beads 7 is applied to the electrode 24 of the dummy substrate D 23 so that the dispersed beads 7 for the spacer do not move. The spacer beads 7 are adsorbed to the dummy pattern substrate 23 using the Coulomb force. Invert while maintaining this applied voltage, and match the pattern with the black matrix 4 of the color filter substrate A or B or C or D1. After the pattern positions of both are set, the voltage applied to the electrodes 24 of the dummy pattern substrate 23 is set to the same polarity as that of the spacer beads 7, and the black matrix 4 of the color filter substrate 1 is set. The bead 7 has a different polarity from the voltage applied to the spacer beads 7 so that the spacer beads 7 generate a repulsive force from the dummy pattern substrate 23 due to the Coulomb force, and Since the substrate 1 receives an attractive force, it can be moved on the black matrix 4 and distributed.

Especially when the color filter substrate C or the color filter substrate D is used, the electrodes 10 and 11 embedded under the black matrix 4 or the black matrix 4 are different from the spacer beads 7. By applying a voltage so as to have a polar charge and applying a voltage to the display pixel portion 2 so as to have the same polar charge as the spacer beads 7 as shown in FIG. Since the attractive force acts on the black matrix 4 and the repulsive force acts on the spacer beads 7 in the display pixel section 2, the black matrix 4 on the color filter substrate 1 is more efficiently placed on the black matrix 4. It is only possible to disperse the spacer beads 7.

Since the dispersion of the spacer beads 7 on the dummy pattern substrate 23 is performed by using the unevenness of the substrate surface, the dispersion can be performed by using the dummy pattern substrate E shown in FIG. is there. The dummy pattern substrate D23 has a wiring structure in which a pattern electrode 24 similar to the black matrix is embedded inside the substrate 23, and a groove is formed on the dummy pattern substrate D23 so that a uniform voltage can be arbitrarily applied. In addition, an electrode wired so that a uniform voltage can be arbitrarily applied independently to the surface of the dummy pattern substrate except for the pattern electrode 24 similar to the black matrix 4 described above. 29. This is the photo sog Raffi's Black Matrix C. A turn mask is formed, electrodes are formed by a snow, a laser, or a printing technique, and a substrate layer is formed on the entire surface by sputtering and a printing technique. Then, a pattern mask opposite to the black matrix pattern is formed by photolithography, and grooves are formed in the required pattern shape by dry or wet etching. It is manufactured by forming a pattern mask similar to the liquid pattern, and forming a convex shape on the surface by sputtering and printing technology.

In particular, when transferring the spacer beads 7 to the color filter substrate 1 using the dummy pattern substrate E, the black matrix 4 or the electrodes 10 buried under the black matrix 4 are used. A voltage is applied to 11 so that it has a charge of a different polarity from the spacer beads 7, and a voltage is applied to the display pixel section 2 so that it has a charge of the same polarity as the spacer beads 7. As a result, as shown in FIG. 9 of the first embodiment, an attractive force acts on the black matrix 4 and a repulsive force acts on the beads 7 for the display in the display pixel portion 2, thereby improving the efficiency. It is possible to disperse the spacer beads 7 only on the black matrix 4.

The spacer beads 7 can be dispersed by using a drive electrode substrate. After dispersing the spacer beads 7 on the dummy pattern substrate D or E, the beads are inverted while maintaining the voltage applied to the electrodes 24 formed on the dummy pattern substrate 23, and the first of the first embodiment. Pattern alignment with the transparent electrode 12 having the same pitch and pattern width as the black matrix 4 formed on the drive electrode substrate 101 shown in FIG. 2 is performed. After the pattern positions of both are set, the voltage applied to the electrode 24 of the dummy pattern substrate 23 is set to the same polarity as that of the beads 7 for the spacer, and the same pitch and pitch as those of the black matrix 4 of the drive electrode substrate 101 are used. The voltage applied to the transparent electrode 1 2 having the pattern width -By making the polarity of the beads 7 different from that of the beads 7, the beads 7 of the spacer receive a repulsive force from the dummy pattern substrate 23 and an attractive force from the substrate 1 by a cooler, so that the black mat It is moved and dispersed on the transparent electrode 12 having the same pitch and pattern width as the liquid 4.

In particular, when the drive electrode substrate B is used, in addition to applying a charge of a different polarity to the spacer beads 7 to the transparent electrode 12 having the same pitch and pattern width as the black matrix 4, By applying a charge of the same polarity as the spacer beads 7 to the transparent electrode 13 other than the transparent electrode 13 having a pattern with the same pitch and pattern width as the black matrix, more efficient It is possible to disperse spacer beads on the electrode 12 having the same pitch and pattern width as the black matrix 4.

(Example 7)

Next, a dispersion filter having holes in a pattern similar to the black matrix of the color filter substrate is placed on the color filter substrate or the drive electrode substrate, and spacer beads are placed in the filter holes. Example of the method for dispersing spacer beads by disposing spacer beads on the black matrix formed on the color filter substrate or the drive electrode substrate by arranging them one by one. explain.

Fig. 22 shows the dispersion filter. '

The dispersion filter 30 is a flat substrate that is larger than the color filter substrate and the drive electrode substrate to be used, and has the same pitch and pattern width as the black matrix 4 and the spacer beads 7 to be used. A hole 31 having a diameter about 0.5 to 4 m larger than the diameter is provided. The shape of the hole 31 may be a shape other than a circle, such as a polygon such as a square or a hexagon, or an ellipse, into which one spacer bead can be inserted. The substrate material of the filter 30 is made of various materials such as glass and ceramics, and the thickness of the substrate depends on the spacer used. The diameter should be equal to or more than 1.5 times the diameter of beads 7 for use.

FIG. 23 shows a conceptual diagram of a method of dispersing and disposing the spacer beads 7 using the dispersing filter 30. Using the spacer bead dispersing device shown in FIG. 2 of the first embodiment, the dispersing filter 30 is set on the empty filter substrate or the driving electrode substrate and then inserted into the device. The spacer beads 7 sprayed from the spacer bead ejection nozzles 16 are sprayed on the filter 30 or in the holes 31. A flat plate having a linear shape on one side, such as a scrubber 32, is used on the filter 30. By removing the spacer beads 7 while making contact with the surface of the filter 30, an empty space is obtained. Only one spacer bead 7 exists in the hole 31. As shown in Fig. 23, after the scraper 32 is scanned, the filter 30 is removed, so that the black matrix 4 formed on the empty filter substrate or the drive electrode substrate 1 is removed. 01 Disperse and arrange spacer beads 7 on 1.

Further, as the color filter substrate 1, a color filter substrate A or B or C or D shown in FIGS. 4 to 7 of the first embodiment may be used. The electrodes 10 and 11 having the same pitch and pattern width as the black matrix 4 or the black matrix of the color finoleta substrate 1 are made to have a different polarity from the electric charge of the beads 7 for the spacer. By doing so, the spacer beads 7 are adsorbed on the color filter substrate 1, and the spacer beads 7 can be more efficiently dispersed only on the black matrix 4. In particular, when a color filter substrate C or D is used, spacer beads are provided on the transparent electrodes 10 and 11 having a pattern of the same pitch and pattern width on the black matrix 4 or the black matrix. In addition to applying a charge having a different polarity to that of the black matrix 7, a charge having the same polarity as that of the spacer beads 7 is applied to the display pixel portion 2 to the black matrix 4. It is possible to disperse the spacer beads 7 only in the case. Similarly, using the drive electrode substrate A or B shown in FIG. 10 or FIG. 11 of the second embodiment, the same pitch and pattern width as the black matrix 4 of the drive electrode substrate 101 are used. By making the transparent electrode 12 having a transparent electrode 12 of a different polarity from the electric charge of the spacer beads 7, the spacer beads 7 become black mats on the drive electrode substrate 101. A transparent electrode 1 having a pattern with the same pitch and pattern width as that of the matrix 4 is adsorbed to the transparent electrode i 2 having a pattern with the same pitch and pattern width as the matrix 4, and more efficiently having a pattern with the same pitch and pattern width as the black matrix 4. It is possible to disperse the beads 7 for the spacer only on 2. In particular, when the driving electrode substrate B is used, in addition to applying a charge having a different polarity from the spacer beads 7 to a transparent electrode having a pattern having the same pitch and pattern width as the black matrix 4, By applying a charge of the same polarity as that of the spacer beads 7 to a transparent electrode other than a transparent electrode having a pattern of the same pitch and pattern width as the black matrix 4, it is possible to further improve the efficiency. It is possible to disperse the spacer beads 7 only on the same pitch and pattern width as the black matrix 4.

(Example 8)

Next, a filter with a dispersion electrode having holes in a pattern similar to the black matrix of the color filter substrate is placed on the color filter substrate or the drive electrode substrate, and the filter holes are formed using electrostatic force. The spacer beads are guided one by one into the section, and the spacer beads are dispersed and arranged at a predetermined position on the black matrix formed on the color filter substrate or on the drive electrode substrate. The method of dispersing the spacer beads will be described.

Fig. 24 shows a filter with dispersion electrodes.

The dispersion film with electrodes 3 3 is a flat substrate larger than the color filter substrate 1 to be used, and the spacer beads 7 to be used along the same pitch and pattern width as the black matrix 4. 0.5 to 4 m from the diameter of A hole 35 having a larger diameter is provided. The shape of the holes 35 is not limited to a circle, but may be any shape such as a polygon such as a square or a hexagon, or an oval such that one spacer bead can be inserted. The filter 33 has electrodes 36 and 37 formed on the filter surface and the pore wall, and particularly has an electrode 3 having the same size as the bead diameter for the spacer used on the pore wall. 7 are formed along the hole wall. The substrate is made of various materials such as glass and ceramics, and the thickness of the substrate is at least twice the diameter of the spacer beads 7 used.

Fig. 25 shows a conceptual diagram of the bead dispersing method for spacers using a dispersing film with electrodes. Using the spacer bead dispersing device shown in FIG. 2 of the first embodiment, the dispersing filter 33 is placed on the empty filter substrate 1 or the driving electrode substrate 101 and then inserted into the device. At this time, the substrate with electrodes 33 has the surface electrode 34 in the same polarity as the electric charge of the spacer beads 7, and the pore wall electrodes 36, 37 in the order from the closest to the surface electrode 34. It is applied so that the charge of the service bead 7 and the different polarity, the same polarity, the different polarity... The spacer beads 7 sprayed from the spacer bead ejection nozzles 16 move to the holes because a repulsive force is generated on the filter surface and a bow (force) is generated in the holes 35. At this time, since the holes have different charges by electrodes having the same size as the diameter of the spacer beads 7 to be used, the hole 35 has one spacer bead 7. Thereafter, in order from the hole electrodes 36 and 37 formed on the color filter substrate side, the electric charges are inverted and one space existing in the hole portion 35 is formed. The beads 7 for the spacer are moved to the color filter side by the size of the pore electrodes 36 and 37. The charge reversal of the pore electrodes 36 and 37 is repeated so that the beads 7 for the spacer are obtained. Is guided along the hole wall on the black matrix 4 of the empty filter substrate 1 or on the predetermined position of the drive electrode. It is possible to disperse the spacer beads 7 only on the black matrix 4. The dispersion of the beads 7 for the spacer can be arbitrarily controlled by changing the number of holes and the density of the filter.

Further, as the color filter substrate, a color filter substrate A or B or C or D shown in FIGS. 4 to 7 of the first embodiment may be used. The black matrix 4 of the empty filter substrate or an electrode having the same pitch and pattern width as the black matrix 4 is made to have a different polarity from the electric charge of the spacer beads 7 so that The spacer beads are adsorbed on the color filter substrate 1, and the spacer beads 7 can be more efficiently dispersed on the black matrix 4. In particular, when a color filter substrate C or D is used, spacer beads 7 are provided on the transparent electrodes 10 and 11 having the same pitch and pattern width as the black matrix 4 or the same as the black matrix 4. By applying a charge of the same polarity as that of the spacer beads 7 to the display pixel section 2 in addition to applying a charge of a different polarity to the black matrix 4, Only the spacer beads 7 can be dispersed.

Similarly, as the driving electrode substrate, the driving electrode substrate A or B shown in FIG. 10 or FIG. 11 of Embodiment 2 may be used. The transparent electrode 12 having the same pitch and pattern width as the black matrix 4 of the drive electrode substrate 101 is made to have a different polarity from the electric charge of the spacer beads 7 so as to form a spacer for the spacer. The beads 吸着 adhere to the transparent electrode 12 having the same pitch and pattern width as the black matrix 4 on the drive electrode substrate 101, and the same pitch as the black matrix 4 more efficiently. Further, it is possible to disperse the spacer beads 7 only on the transparent electrode 12 having the pattern width. In particular, when the drive electrode substrate B is used, in addition to applying a charge of a different polarity to the spacer beads 7 to the transparent electrode 12 having the same pitch and pattern width as the black matrix 4, Pitch and flutter similar to that of Matrix 4 By applying a charge of the same polarity as that of the spacer beads 7 to the transparent electrodes 13 other than the transparent electrodes 1 and 2 having the same width as in the black matrix 4, it is more efficient. It is possible to disperse the spacer beads 7 only on the pitch and pattern width.

(Example 9)

Finally, liquefied glass is spouted from a fine nozzle having a fine opening with a diameter of several meters, so that the liquid glass is spread over a black matrix formed on the color filter substrate and a predetermined position on the drive electrode substrate. The method of dispersing the beads for the spacer in which the beads for the distributor are dispersed will be described.

Figure 26 shows the method of dispersing and distributing beads for a spacer using the fine nozzle method. The device consists of a solution tank (not shown), a fine nozzle 42 for ejecting the solution, and a pump (not shown) for replenishing the solution to the fine nozzle 42. Then, a color filter substrate or a drive electrode substrate is provided. The liquid tank is filled with liquefied glass, and liquefied glass is ejected from a fine nozzle 42 having a fine piston mechanism by an ink jet method. The diameter of the fine nozzle 42 used in this embodiment is very small, that is, a few meters, and the liquefied glass that has been ejected is separated from the fine nozzle 42 by a spherical shape in the atmosphere. The glass beads adhere to the color filter substrate and are used as spacer beads 43 having a required height. By moving the fine nozzle 42 along the black matrix 41 of the color filter substrate 40, or by fixing the fine nozzle 42 and moving the glass substrate 40, the black matrix is obtained. It is possible to disperse the spacer beads 43 on the box 41. Similarly, spacer beads 43 can be dispersedly arranged on the drive electrode substrate 40 along the same pitch and pattern width as the black matrix 41. The number of the fine nozzles 40 is not limited to one, and a plurality of fine nozzles 40 may be provided at intervals of the black matrix 41 of the empty filter substrate 40 as shown in FIG. 27. By installing a plurality of nozzles 42, the work efficiency can be improved. In such a dispersing method using the ink jet method, it is possible to disperse the spacer beads 43 at an arbitrary location, and arbitrarily adjust the diameter of the fine nozzles 42 for the spacer. The height of beads 43 can be changed. Also, the arrangement density of the spacer beads 43 can be arbitrarily changed by adjusting the moving speed of the substrate 40 or the fine nozzle 42.

According to Examples 1 to 9 described above, when dispersed on a color filter substrate, only on a black matrix, and when dispersed on a drive electrode substrate, the same pitch and pitch as those of the black matrix were used. It is possible to disperse spacer beads only at predetermined positions of the pattern width. Using these substrates, pattern alignment is performed on the drive electrode substrate or color filter substrate to which no spacer beads are attached, respectively, and then the substrates are joined together to achieve a gap height accuracy of 0.05. High-precision and high-quality liquid crystal panels within a distance of m can be obtained.

As is clear from the above Examples 1 to 9, as shown in FIG. 1, the entrance ratio of the black material to the projection area of the black matrix of the liquid crystal panel is 70 to 100%. The adhesion of beads to the display pixel area can be suppressed to 30% or less, which significantly improves image quality such as light leakage and uneven color tone.

In particular, the color filter substrate A or B or C or D shown in FIGS. 4 to 7 of Example 1 or the drive electrode substrate A or B shown in FIGS. 10 and 11 of Example 2 is used. When used, the black matrix is used to place spacer beads on the black matrix using the attractive force of Coulomb force. By maintaining the electric charge, the movement of the spacer beads during the movement of the substrate can be prevented.

According to this configuration, in a color liquid crystal panel in which a pair of glass substrates on which transparent electrodes of a required pattern are formed are opposed to each other through spacer beads, a color filter formed on a color filter substrate constituting the color panel is provided. By distributing the spacer beads only on the matrix, the spacer material does not exist in the display pixel area, so light leakage due to the spacer material is eliminated. At the same time, it is possible to obtain a liquid crystal panel and a color liquid crystal display device having high cell-gap height accuracy and high image quality. Industrial applicability

The color liquid crystal display device according to the present invention includes a personal computer, a television, a clock, a car navigation system, a computer game, a videophone, a measuring device, an inspection device, a processing device, an image processing device, a medical device, a monitor system, and a communication device. A high-quality display device without light leakage or uneven color tone can be provided as a display unit for various electronic devices such as conference systems. In particular, since there is no sputter material in the display pixel unit, In addition to eliminating light leakage caused by the spacer material, it is possible to obtain high-precision and high-quality color liquid crystal panels and color liquid crystal display devices with a cell gap height accuracy of 0.05 m or less at the same time. It is extremely effective.

Claims

The scope of the claims

1-A color liquid crystal display device having a spacer material between a pair of substrates, wherein the spacer material is dispersed and arranged in a black matrix region forming a liquid crystal panel. A liquid crystal display device.

2. The color liquid crystal display device according to claim 1, wherein the spacer material is spherical.

3. The color liquid crystal display device according to claim 2, wherein said spherical spacer material is made of any one of plastic, silica and alumina.

4. The color liquid crystal display device according to claim 2, wherein the size of the spherical spacer material is 9 m or less in particle size.

5. A color liquid crystal display device including a color liquid crystal panel in which a pair of glass substrates on which transparent electrodes of a predetermined pattern are formed are opposed to each other with a spacer material interposed therebetween, wherein a color filter substrate constituting the color liquid crystal panel or A color liquid crystal display device having a cell gap formed by dispersing and disposing a spacer material in at least one of the driving electrode substrates in a region corresponding to the black matrix. .

6. The color filter substrate according to claim 5, wherein an electrode is provided in a region corresponding to the black matrix, and a wiring structure capable of applying an arbitrary voltage to the electrode is provided. Item 6. A color liquid crystal display device according to item 1.

7. The color liquid crystal display device according to claim 6, wherein the electrode is a transparent electrode.

8. The color filter substrate has a wiring structure that can apply an arbitrary voltage to the electrodes corresponding to the black matrix and a wiring structure that can apply an arbitrary voltage to the display pixel section. Claim 5 Color liquid crystal display.

9. The drive electrode substrate has electrodes facing the black matrix region formed on the color filter substrate paired with the drive electrode substrate, and has a wiring to which an arbitrary voltage can be applied. 6. The color liquid crystal display device according to claim 5, wherein the color liquid crystal display device has a structure.

10. The drive electrode substrate is characterized in that it has a transparent electrode to which a voltage having a different polarity from that of the electrode can be applied on the drive electrode portion excluding the electrode facing the black matrix region. The color liquid crystal display device according to claim 5,

11. The claim 1 to claim 5, wherein an entrance ratio of the spacer material to a projection area of the black matrix is 70 to 100%. The color liquid crystal display device according to any one of the above.

1 2. Apply a different polarity charge to that of the spacer material to the electrodes provided in the color filter substrate or the drive electrode substrate corresponding to the black matrix area, and apply the black matrix described above. A method of manufacturing a color liquid crystal display device, characterized in that spacer materials are distributed and arranged on a region corresponding to a matrix.

13. Apply the charge of the spacer material and the charge of the different polarity to the electrodes provided in the black matrix area of the color filter substrate or the drive electrode, and display pixels of the color filter substrate. Apply the same polarity charge as the spacer material to the electrodes corresponding to the electrodes or the electrodes formed on the drive electrode substrate except for the area corresponding to the black matrix, and apply the black matrix to the black matrix-compatible area. A method for manufacturing a liquid crystal display device, characterized in that a laser material is distributed and arranged.

14 4. Apply a charge of a different polarity to the charge of the spacer material to the electrode of the dummy pattern in which the electrode is formed in the area corresponding to the black matrix formed on the color filter substrate, After the spacer material is dispersed and arranged on the upper surface, the force that transfers the spacer material on the dummy substrate to an area corresponding to the black matrix of the color filter substrate is transferred. Raichi A method for manufacturing a liquid crystal display device.

15. The first electrode is provided in a region corresponding to the black matrix formed on the color filter substrate, and the first electrode of the dummy substrate provided with the second electrode is provided on the surface of the substrate excluding the first electrode. By applying a charge of a different polarity to the charge of the spacer material to the first electrode and applying a charge of the same polarity to the second electrode, the spacer material is placed on the dummy pattern substrate. After the spacers are dispersed, the spacer material on the dummy substrate is transferred onto a region corresponding to the black matrix risk of the color filter substrate or the drive electrode substrate. Display device manufacturing method.

16. A method of manufacturing a liquid crystal display device having a concave portion in a region corresponding to a black matrix of a glass substrate and dispersing a spacer material in the region of the concave portion, wherein the spacer material is provided. Dispersing in a solution, immersing the glass substrate in the solution, lifting the glass substrate from the solution, and disposing the spacer material in a concave portion of the surface of the glass substrate. Display device manufacturing method.

17. The method for manufacturing a color liquid crystal display device according to claim 16, wherein the glass substrate is pulled obliquely from the solution.

18. Using a dispersion filter with holes in the area corresponding to the black matrix risk, fill the holes of this dispersion filter with a spacer material, and replace the spacer material of this dispersion filter with the color. A method for manufacturing a color liquid crystal display device, comprising: mounting a filter substrate or a drive electrode substrate on a region corresponding to black matrix.

1 9. A liquid characterized in that liquefied glass is ejected from one or more nozzles having fine openings to a position corresponding to the black matrix of the glass substrate to form a spacer material. A method for manufacturing a liquid crystal display device.

20. An electronic device equipped with the color liquid crystal display device according to any one of claims 1 to 11.