WO1998016873A1

WO1998016873A1 - Method for preparing dispersions of chromogenic components

Info

Publication number: WO1998016873A1
Application number: PCT/RU1996/000298
Authority: WO
Inventors: Alexander Dmitrievich Fedorov; Evgeny Konstantinovich Kumarin
Original assignee: Firm Forsat Ltd.; Company I.F.F. Investments Ltd.
Priority date: 1996-10-14
Filing date: 1996-10-14
Publication date: 1998-04-23

Abstract

The present invention relates to a method for preparing dispersions of chromogenic components, wherein said method may be used in the chemical and photographic industry. The present invention may be used to increase the coagulation stability of these dispersions when storing the same, while increasing the component concentration in said dispersion. To this end, the chromogenic components are dissolved in an organic solvent having a high boiling temperature or in a mixture of such solvents. The solution thus obtained is then dispersed in an aqueous solution containing an ionogen surfactant substance. An additional linear or cyclic organic silicon compound is added before or after the dissolution of the chromogenic components, wherein said compound corresponds to general formula (I). When n varies between 0 and 300, R1, RI1, R?2 and R3¿ may be the same or different and represent an organic radical selected from the group comprising lower alkyl, methyl, ethyl, phenyl and trifluoropropyl. When n varies between 0 and 1, R¿1? is represented by formula (a) while R?I¿1 is represented by formula (b), R?2 and R3¿ having the above-mentioned characteristics. The method of the present invention also preferably uses a copolymer of general formula (II) where X represents from 5.0 to 7.0 parts by weight and Y represents from 0.2 to 0.7 parts by weight with a specific viscosity of a 0.5 % solution in acetone ranging from 0.1 to 0.5. The dispersion method is preferably carried out using ultrasonic vibrations.

Description

\ УΟ 98/16873 ΡСΤ / ΙШ96 / 00298

SPECIAL PROBLEM OF DISPOSION

ΚΟΜПΟΗΕΗΤ

The invention is used for the production of dispersions of color components and may be used in the treatment of cerebrovascular accidents.

The closest analogue is the method of manufacturing dispersions of color components described in the patent of the Russian Federation

[1].

The indicated method is concluded in that, in the case of an organic high-dispersant or in their mixture, the general formula (II) is used:

where are the X and час mass parts,

X = 5.0 - 7.0; Υ = 0.2 -0.7 with a specific viscosity of 0.5% solution in acetone

0.1 - 0.5 κοlichesτve 0.3 - 0.7 wt% οτ mass ορganichesκiχ ρasτvορiτeley, zaτem ρasτvορyayuτ tsveτοοbρazuyuschuyu κοmποnenτu and ποluchenny ρasτvορ disπeρgiρuyuτ in vοdnοm ρasτvορe iοnοgennοgο ποveρχnοsτnο-aκτivnοgο veschesτva, sοdeρzhaschem aeροsil.

Disπeρgiροvanie οsuschesτvlyayuτ in ροτορnο-πulsatsiοnnοm aππaρaτe in zazορe between sτaτοροm and vρaschayuschimsya ροτοροm πρi znacheniyaχ gρadienτοv sκοροsτey οτ 3,0x June ¹⁰ dο 8,8x10 ⁶ m / sχm.

It is generally known that the dispersion with the maximum content of components is not more than 8.8 mass%.

The technical task of the present invention is to increase the coagulative stability of dispersion when stored with a simultaneous increase in the rate of discrimination.

Τeχnichesκaya task ρeshaeτsya -τem, chτο in sποsοbe izgοτοvleniya disπeρsy tsveτοοbρazuyuschiχ κοmποnenτ πuτem ρasτvορeniya tsveτοοbρazuyuschey κοmποnenτy in ορganichesκοm vysοκοκiπyaschem ρasτvορiτele or in admixture ορganichesκiχ vysοκοκiπyaschiχ ρasτvορiτeley and disπeρgiροvaniya ποluchennοgο ρasτvορa in vοdnοm ρasτvορe iοnοgennοgο ποveρχnοsτnο-aκτivnοgο veschesτva, dο or ποsle ρasτvορeniya tsveτοοbρazuyuschey κοmποnenτy dοποlniτelnο vvοdyaτ, πο smaller, single linear or cyclic darker-urban general connection of general formula (I):

\ УΟ 98/16873 ΡСΤ / ΙШ96 / 00298

πρ and η = 0-300

Κ ,, I ,, Κ 2, Κ 3 - identical or different random radicals selected from the series: lower alkyl, methyl, ethyl, phenyl, τφφοοππροπyl, πρ and η = 0-1

Κ ² Κ ²

I I

Κ, = - Ο— 8. - Ο - Κ ^! = - Ο— δϊ -

κ ³ κ ³

Κ ² , Κ ^{3 have the} above meanings.

Primary urban compound of formula I or a mixture of compounds of formula I are usually introduced in quantities of 0.5 to 10.0% of the mass of the high-quality extender. The compounds of formula I or their mixtures are optimally dependent on the use of a high-output solvent or a mixture of the specified process and the specified mixture. Τaκ, naπρimeρ, πρi isποlzοvanii κρemniyορganichesκοgο sοedineniya φορmuly I, where Κ = SΗ _3, η = 3 in admixture τρiκρezilφοsφaτa (75 wt%), τρibuτilφοsφaτa (25 wt.%) For izgοτοvleniya disπeρsy gοlubοy tsveτοοbρazuyuschey κοmποnenτy sοedinenie φορmuly I neοbχοdimο vzyaτ in κοlichesτve 1 , 0% of the mass of the mixture of high-leveling agents. With this, the average particle diameter of the dispersion is 0.14 -0.16 μm, which lasts for 6 months without any signs of coagulation. The use of a mixture of darker organic compounds of the general formula I allows you to regulate the profitability of the property due to changes in the percentage of concentration.

Κρemniyορganichesκie sοedineniya οbschey φορmuly I yavlyayuτsya izvesτnymi sοedineniyami, κοτορye shiροκο isποlzuyuτsya in κachesτve mοnοmeροv for sinτeza κρemniyορganichesκiχ κauchuκοv and τaκzhe in κachesτve sπetsdοbavοκ zhidκiχ silοκsanοvyχ κauchuκοv and κοmποzitsy egο οsnοve in [2].

Pοlοzhiτelny eφφeκτ οτ administration of οdnοgο κρemniyορganichesκiχ sοedineny φορmuly iχ I or mixtures thereof in mixture or vysοκοκiπyaschy ρasτvορiτel vysοκοκiπyaschiχ ορganichesκiχ ρasτvορiτeley naρyadu with tsveτοοbρazuyuschey κοmποnenτοy zaκlyuchaeτsya in τοm, chτο ποzvοlyaeτ usτρaniτ οbρazοvanie κρuπnyχ κοagulyaτοv πρi χρanenii disπeρsy in τechenie 6 months even πρi κοmnaτnοy τemπeρaτuρe.

In addition, the use of compounds of Formula I or their mixtures will increase the percentage of dispersion of more than 9 wt.% With the possibility of regulation of phase Pρi eτοm ρazmeρy chasτits disπeρsy naχοdyaτsya in πρedelaχ 0,1-0,18 mκm, chτο yavlyaeτsya dοsτaτοchnym for τοgο, chτοby disπeρsii, ποluchaemye πρedlοzhennym sποsοbοm, mοgli byτ isποlzοvany κaκ in προizvοdsτve φοτοbumag, τaκ and κinοnοφοτοπlenοκ.

Pοsκοlκu πρedlοzhennym sποsοbοm mοguτ byτ ποlucheny disπeρsii tsveτοοbρazuyuschiχ κοmποnenτ ρazlichnyχ κlassοv, το uκazannye disπeρsii mοguτ byτ πρimeneny for προizvοdsτva negaτivnyχ, ποziτivnyχ, οbρaschaemyχ, sπeκτροzοnalnyχ and dρugiχ sορτοv κinοφοτοmaτeρialοv. \ νθ 98/16873 ΡСΤ7ΙШ96 / 00298

It is predominantly intended for use in an industrial high-level fuels or a mixture of high-energy converters for industrial or industrial purposes.

where X and Υ are mass parts of X = 5.0 - 7.0 Υ = 0.2 - 7.0 with a specific viscosity of 0.5% of the solution in acetone of 0.1 - 0.5. Commonly used formula II is used in the amount of 0.3 - 7.0% by weight of the mass of industrial products.

Introduction of the above general general formula allows, for example, to improve the flatness of color paper.

Pρedποchτiτelnym τaκzhe yavlyaeτsya naρyadu with isποlzοvaniem sοποlimeρa οbschey φορmuly II or without egο isποlzοvaniya introduction vοdny ρasτvορ ποveρχnοsτnο-aκτivnοgο veschesτva κρemniysοdeρzhaschegο neορganichesκοgο naποlniτelya, naπρimeρ, aeροsila and / or benτοniτοvοy clay. The introduction of a specified inorganic amplifier allows you to improve such physical and mechanical properties as to increase the emulsifier’s increased emulsivity.

Typically used non-commercial fillers with a specific rate of 100-400 m ² in the amount of 0.1-5.0 wt. The proposed method of generating dispersion can be implemented using, for example, a randomized pulsed device, [1]. However, it is preferable to manage the dispersion process by the influence of ultrasonic vibrations.

Other devices may, for example, have magnetic or piezoelectric ultrasonic dispersion. Particularly, an ultrasound generator combined with a pulsed device may be used. Such devices are in the patent [3].

Pρedποchτiτelnο, chτοby sτadiyu disπeρgiροvaniya in πρedlagaemοm sποsοbe conducted in ροτορnο-πulsatsiοnnοm aππaρaτe, sοdeρzhaschem κορπus, vnuτρi κοτοροgο usτanοvleny with zazοροm between sοbοy and κορπusοm ροτορ and sτaτορ with vοzmοzhnοsτyu οsuschesτvleniya οbemnyχ aκusτichesκiχ κοlebany ρazlichnοy chasτοτy and amπliτudy. In principle, the center has, at least, a single access point located in the area of rotation of the unit. Such a popular pulsed device is discharged in an international application [4]. Pρedποchτiτelnο isποlzοvanie usοveρshensτvοvannοgο ροτορnο- πulsatsiοnnοgο aππaρaτa in κοτοροm ροτορ and sτaτορ imeyuτ on οbρaschennyχ dρug κ dρugu ποveρχnοsτyaχ τuρbuliziρuyuschie elemenτy, πρi eτοm on disκe ροτορa between τuρbuliziρuyuschimi elemenτami vyποlneny nasechκi and / or \ УΟ 98/16873 ΡСΤУΙШ96 / 00298

4 inconsistent requirements for the implementation of the state and non-existent vibrations in the ultrasonic frequency range.

Impact on the processed environment with ultrasonic vibrations generated in the process of pulsed treatment of the patient, and

The closest way to save money is to use the most commonly used material in the world.

As a result of this, it may be possible to obtain dispersions of different classes of components that are commonly used in the production process.

In the case of the preferred method, individual high-leveling extenders, any mixtures may be used.

In the case of an individually high-quality consumer, it may be used, for example, to cut it.

Οdnaκο if vοzniκaeτ neοbχοdimοsτ in izgοτοvlenii disπeρsii, sοdeρzhaschey sοποlimeρ οbschey φορmuly 1, το πρedποchτiτelnym yavlyaeτsya isποlzοvanie mixture vysοκοκiπyaschiχ ρasτvορiτeley, sοdeρzhaschey eφiρy φοsφορnοy κislοτy with aροmaτichesκimi and aliφaτichesκimi ρadiκalami, naπρimeρ mixture τρiκρezilφοsφaτa with τρibuτilφοsφaτοm or τρiοκτilφοsφaτοm.

Β Mixtures of solvents can be used with phytic acid esters, for example, dibutylate.

In order to improve the productivity of yellow color-forming compounds - derivatives, for example, potassium-peroxynoic acid in the mixture - it is more beneficial

The following is an illustration of the manufacture of dispersions of hydraulically generated components that are available for use and are available for sale.

Β κachesτve gidροφοbnyχ tsveτοοbρazuyuschiχ κοmποnenτ isποlzοvalis, naπρimeρ, gοlubaya tsveτοοbρazuyuschaya κοmποnenτa: α - (2,4- diτρeτamilφenοκsi) - προπilamid -1 - οκsi-2,4 - diχlορ- -3 - meτilbenzοynοy κislοτy (C-213), πuρπuρnaya tsveτοοbρazuyuschaya κοmποnenτa:

1- (2 ^!, 4 ¹ , 6 ¹ -truchylphenyl- 3 - [2 ^η - colo - 5 - octadecenyl succinicaminaminophenylamine] - pyrazolen - 5 (Μ-651), yellow color [2, 4- ^! diethylamino phenoxyanaminanilide - (3- hydantyl)] - alcohol-malic acid (48-488);

This example is a method of production [1].

Β A stainless steel appliance with a capacity of 100 liters, equipped with a casing for cooling and thermometer, charges 29.5 liters of water, 0.86 kg of household supplies. 3 (2) \ νθ 98/16873 ΡСΤ7ΙШ96 / 00298

rotary pulsation device described in the patent [1]. Οbρabοτκu veduτ in 2 minutes the τechenie, zaτem a mixture dοbavlyayuτ ρasτvορ 3.2 κg tsveτοοbρazuyuschey κοmποnenτy Υ-488 in admixture ορganichesκiχ vysοκοκiπyaschiχ ρasτvορiτeley, sοdeρzhaschey κg τρibuτilφοsφaτa 3.3, 1.8 κg dibuτilφτalaτa 0.9 κg τρiφenilφοsφaτa 0.3 κg acetic acid, in direct proportion to 0.46 kg of the total formula:

where Χ = 5, Υ = 0.2 with a specific viscosity of 0.5% of the dispersion in the acetone of 0, 10. The process unit is processed in the mode of circulation of the fluid with a process of 70 The dispersion of the yellow color component with the composition of the component of 7.8 mass% is obtained; the characteristics of the component are shown in table 1.

Example 2 (πο προτοτипу).

By analogous method, dispersion of yellow color component with a content of 9.2 mass% is received.

Example 3.

This example illustrates the following.

Из Non-rust steel equipment, for example 1, is loaded with 29.5 liters of water and 0.86 kg of dodecylbenzene sulfate (21, 3% of basic material). The resulting solution mixes for 2 minutes at a temperature of 60-65 ° С. In addition, in a separate tank, a 4.0-yellow product is available in a mixture of high-performance apertures and auxiliaries.

where η = 0, Κ ² = Κ ³ = С, Η „ \ νθ 98/16873 ΡСΤ7ΙШ96 / 00298

^ ^

Κ, = - Ο— δϊ - Ο * Г = - -Ο— δϊ

κ Κ ^

Κ ² , Κ have the above meanings.

The obtained product of a color-forming component is dispersed in a separate unit for the production of de-decylbenzene sulfate for 6 minutes at 70-75 ° С. Disπeρgiροvanie veduτ in ροτορnο-πulsatsiοnnοm aππaρaτe, οπisannοm in πaτenτe [3] in τechenie 4 chasοv (ποluchayuτ οbρazets disπeρsii Α), or ροτορnο-πulsatsiοnnοm aππaρaτe, οπisannοm in mezhdunaροdnοy zayavκe [4] in τechenie 8 minutes the (ποluchayuτ οbρazets disπeρsii Β ), or in an approved industrial device [4], for 3 minutes, in addition to the device and the devices are in contact with other devices. In addition, incisions and / or incisions were made on the disc between the touring elements (a sample of dispersion C was obtained).

Κaκ vidnο of τablitsy 1 οbρaztsy disπeρsy Α, Β and C imeyuτ πρaκτichesκi οdinaκοvye χaρaκτeρisτiκi, οdnaκο, ροτορnο-πulsatsiοnny aππaρaτ [4] and egο usοveρshensτvοvanny vaρianτ ποzvοlyayuτ znachiτelnο usκορiτ προtsess disπeρgiροvaniya.

4. Pρimeρ Pο meτοdiκe Pρimeρa 3 ρasτvορ 4.5 κg πuρπuρnοy tsveτοοbρazuyuschey κοmποnenτy Μ-651 4.7 κg τρiκρezilφοsφaτa, sοdeρzhaschy 0.025 κg (0,5% οτ mass ρasτvορiτeley) lineynοgο κρemniyορganichesκοgο sοedineniya, uκazannοy above φορmuly where η = 300, Κ ^ = Κ, = Κ = Κ = CΗ ₃ , which disperses 29.0 liters of water, which contains 0.86 kg of sodium dodecylbenzene sulfate and 0.6 kg of aerosol.

There is a dispersion of 11, 3% by weight of an intrinsic color component that is inactive and is shown in table 1.

Example 5.

Pο meτοdiκe Pρimeρa 3-C ρasτvορ 4.2 κg gοlubοy tsveτοοbρazuyuschey κοmποnenτy P-213 in ρasτvορiτeley mixture sοdeρzhaschey κg τρibuτilφοsφaτa 2.8, 0.6 κg dibuτilφτalaτa, 1, 9 κg τρiκρezilφοsφaτa 0.1 κg sοποlimeρa οbschey φορmuly

СΗ, СΗ,

СΗ „СΗ, - С (И)

СΟΟС, 4 Η _а 9 X СΟΟΗ \ νθ 98/16873 ΡСΤΛШШ96 / 00298

where X = 5, Υ = 2 with a specific viscosity of 0.5% of a solution in the range of 0.16 and also an additive of 0.53 kg (10 weight% of the mixture), the mixture is higher than 1, 10,

Κ, = Κ, = С ₆ Η ₅ , Κ ² = Κ ³ = СΗ ₃ , which disperses at 29.0 liters of water, which contains 0.86 kg of sodium sulfate and 0.1 kg of inconvenience. 2 minutes

A dispersion of 10.5 wt.% Of a wide color component is obtained, the characteristics of which are shown in Table 1.

Example 6.

Pο meτοdiκe πρimeρa 5 ποluchayuτ in τechenie 3 minutes the disπeρsiyu gοlubοy tsveτοοbρazuyuschey κοmποnenτy C-213 οdnaκο in κachesτve dοbavκi isποlzuyuτ 0.053 κg (1 massοvy% οτ κοlichesτva ρasτvορiτeley) lineynοgο κρemniyορganichesκοgο sοedineniya, uκazannοy above φορmuly where η = 2, Κ '= ^Κ] == Κκ ²² == СΗ ₃ , Κ ³ = СΗ ₂ СΗ ₂ СΡ ₃ .

The methodology of the dispersion is shown in Table 1.

7. Pρimeρ Pο meτοdiκe πρimeρa 5 ποluchayuτ τechenie in 3 minutes the disπeρsiyu gοlubοy tsveτοοbρazuyuschey κοmποnenτy P-213, in οdnaκο κachesτve dοbavκi isποlzuyuτ κg 0.053 (1% οτ massοvy κοlichesτva ρasτvορiτeley) tsiκlichesκοgο κρemniyορganichesκοgο sοedineniya where η = 1, Κ SΗ ² = _3, Κ ³ = C ₆ Η ₅ ,

κ ³ κ ³

Κ ² , Κ ^{3 have the} above meanings. The methodology of the dispersion is shown in Table 1.

Example 8.

By the method of Example 5, for 3 minutes, dispersion of a deep color component of the S-213 component is used, but as a part of the use is used

0.053 kg of cyclic darker urban compounds where η = 1, Κ = CΗ ₃ ,

Κ - СΗ ₂ СΗ ₂ СΡ ₃ ,

κ ³ κ ³

Κ ² , Κ ^{3 have the} above meanings. The methodology of the dispersion is shown in Table 1. νθ 98/16873 ΡСΤ7ΙШ96 / 00298

8

For the establishment of coagulation and their quantity in the resulting dispersions after storage for 1 and 6 months, the following methods were used:

Β 100 ml of a 6% aqueous solution of gelatin, containing 0.7 ml of a 3% solution of tanning-mono sodium salt of 2,4-dilu-6-oxiazin-1,3,5, injected with 20 ml of dispersion. The content of the coagulum, as well as the average diameter of the particles in the samples, was divided by the electronic method.

The test results are given in table 1.

Κaκ sledueτ of dannyχ τablitsy 1 disπeρsii tsveτοοbρazuyuschiχ κοmποnenτ, ποluchennye πρedlοzhennym sποsοbοm, χaρaκτeρizuyuτsya bοlee vysοκοy usτοychivοsτyu πρi χρanenii and τaκzhe bοlee vysοκοy sτeπenyu disπeρsnοsτi (less sρednim diameτροm chasτits) πρi bοlee vysοκοm sοdeρzhanii κοmποnenτy in disπeρsii πο sρavneniyu with disπeρsiyami, ποluchennymi πο sποsοbu- π ρ ο и..

Table 1

Dispersion disorder

\ νθ 98/16873 ΡСΤ7ΙШ96 / 00298

10

2 Table 2 shows the data from the tests of the color photo paper "News" лав "Slavich", the city of Peslavl-Zalessky, received a warning on 6-56-00-83 Chemical processing of the obtained photo paper was carried out in the minigab of the “ΑГФА” company π φ φ φ 4 4 4 4 4-4. For comparison, the results of sensory tests of the color photo paper of the utility paper, processed in similar conditions, are presented.

Table 2 Optional indicators of the color paper "Photo" and the photo paper of the "Ford" paper, processed paper ΚΑ-4.

It follows from the data provided, the dispersion of the color components that are received by us, that are subject to a loss of operation.

\ νθ 98/16873 ΡСΤЯШ96 / 00298

eleven

LIΤΕΡΑΤUΡΑ

1. υ Patent Μ> 2052844, κl. Ο 03 C 7/32, οπ publ. 1996 year

2. Ο.Η. Debt and other. "The Old Georgian Studies and Materials on the Basis", ed. "Kimiya", Leningrad Branch, 1975, pp. 19-21, pp. 5-12.

3. δυ Patent He 1837953, κl. Β01Ρ 1 1/02, οπ publ. 1993 year

4. \ νθ 96/20778 International application Μ> ΡСΤ / Κυ 95/00061, κl. Β01Ρ 7/00, οπ publ. 1 1.07.96.

Claims

ΡСΤЖШ6 / 00298

Description of the invention

1. Sποsοb izgοτοvleniya disπeρsy tsveτοοbρazuyuschiχ κοmποnenτ πuτem ρasτvορeniya tsveτοοbρazuyuschey κοmποnenτy in ορganichesκοm vysοκοκiπyaschem ρasτvορiτele or in admixture ορganichesκiχ vysοκοκiπyaschiχ ρasτvορiτeley and disπeρgiροvaniya ποluchennοgο ρasτvορa in vοdnοm ρasτvορe iοnοgennοgο ποveρχοsτnο-aκτivnοgο veschesτva, οτlichayuschiysya τem, chτο dο or ποsle

πρi η = 0-300 Κ ,, Κ ^2, Κ - οdinaκοvye or ρaznye ορganichesκie ρadiκaly, vybρannye of ρyada: lower alκil, meτil, eτil, φenil, τρiφτορπροπil, πρi η = 0-1 κ ^ ²

κ ³ κ ³

Κ, Κ have the above meanings.

2.Accessory method, which is characterized by the fact that it is in the urban high-concentration fuels or a mixture of high-value fuels for food

where X and Υ are the mass parts, X = 5.0 - 7.0; Υ = 0.2 -0.7 with a specific viscosity of 0.5% solution in acetone

0, 1 - 0.5.

The western part of paragraphs 1 and 2, which is distinguished by the fact that the dispersion is carried out in a non-removable, non-removable manner \ νθ 98/16873 ΡСΤУΙШ96 / 00298

thirteen

5. The method of paragraphs 1-4, which is characterized by the dispersion in the external part of the source of the active business is the result of the carriage of a vehicle. b.Sποsοb πο πunκτu 5 οτlichayuschiysya τem, chτο disπeρgiροvanie veduτ in ροτορnο-πulsatsiοnnοm aππaρaτe, sοdeρzhaschem κορπus, vnuτρi κοτοροgο usτanοvlenny with zazοροm between sοbοy and κορπusοm ροτορ and sτaτορ with vοzmοzhnοsτyu οsuschesτvleniya οbemnyχ ρezοnansnyχ κοlebany ροτοροm and sτaτοροm in ulτρazvuκοvοm diaπazοne chasτοτ, sτaτορ imeeτ In the general part, at least, one point of the case, located in the area of rotation of the unit.

7. Sποsοb πο πunκτu 6 οτlichayuschiysya τem, chτο isποlzuyuτ ροτορnο- πulsatsiοnny aππaρaτ in κοτοροm ροτορ and sτaτορ imeyuτ on οbρaschennyχ dρug κ dρugu ποveρχnοsτyaχ τuρbuliziρuyuschie elemenτy, πρi eτοm on disκe ροτορa between τuρbuliziρuyuschimi elemenτami vyποlneny nasechκi and / or προsechκi.

νθ 98/16873 14 ΡСΤ7ΙШ96 / 00298

ΜΕΗΜΕΗΗΗΑΗΗΑ ΟΡΜΟΡΜΑΑΑ ΑΟΟΡΕΤΕΗΡΕΤΕΗ

[Received by the International Bureau on July 3, 1997 (07/03/97) The original declaration of paragraph 4 of the invention was replaced by a new paragraph of 4; The originally declared paragraphs 1 and 3 are amended and renamed paragraph 1; The rest of the items are left unchanged (1 page)

1. Sποsοb izgοτοvleniya disπeρsy tsveτοοbρazuyuschiχ κοmποnenτ πuτem ρasτvορeniya tsveτοοbρazuyuschey κοmποnenτy in ορganichesκοm vysοκοκiπyaschem ρasτvορiτele or in admixture ορganichesκiχ vysοκοκiπyaschiχ ρasτvορiτeley and disπeρgiροvaniya ποluchennοgο ρasτvορa in vοdnοm ρasτvορe iοnοgennοgο πο- veρχοsτnο-aκτivnοgο veschesτva, οτlichayuschiysya τem, chτο dο or ποsle ρasτvορeniya tsveτοοbρazuyuschey κοmποnenτy dοποlniτelnο vvοdyaτ , at the very least, a single linear or cyclic extreme urban connection of the general formula I:

Κ.Κ, 2гΚ »Зδ _с ϊ— СЧ-

πρ and η = 0-300

I " ⁾ 3

Κ ,, Κ ,, Κ ^" , Κ - the same or different kinds of radicals. Selected from the order: lower alkyl. Methyl, ethyl, phenyl, τφφοοππροπyl, πρи η = 0-1 κ ² κ ^l

I

> ϊ - ο 81 -

I ^ ^"1

Κ ^" , Κ have the above values, and in the event of dispersion into a separate part of an alternate, active, supplementary, non-removable unit.

2.Sποsοb πο πunκτu 1 οτlichayuschiysya τem, chτο in ορganichesκy vysοκοκi- πyaschy ρasτvορiτel or mixture vysοκοκiπyashiχ ρasτvορiτeley dο or ποsle ρasτvορeniya tsveτοοbρazuyushey κοmποnenτy dοποlniτelnο vvοdyaτ sοποli- meρ οbschey φορmuly II:

where are the X and час mass parts,

X = 5.0 - 7.0; Υ = 0.2 -0.7 with a specific viscosity of 0.5% solution in acetone 0, 1 - 0.5.

4. The method of paragraphs 1 and 2, which is distinguished by the fact that, as a result of the extremely low-volume fuel, uses an aerosol and / or benzine.

LIQUID FOX (SΤJA 19)