WO1998030391A1 - Procede pour produire des articles stratifies - Google Patents
Procede pour produire des articles stratifies Download PDFInfo
- Publication number
- WO1998030391A1 WO1998030391A1 PCT/US1997/000130 US9700130W WO9830391A1 WO 1998030391 A1 WO1998030391 A1 WO 1998030391A1 US 9700130 W US9700130 W US 9700130W WO 9830391 A1 WO9830391 A1 WO 9830391A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- laminate
- resin
- coating
- gasket
- film
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000000758 substrate Substances 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 29
- 239000004033 plastic Substances 0.000 claims abstract description 18
- 229920003023 plastic Polymers 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims description 47
- 239000011347 resin Substances 0.000 claims description 46
- 238000000576 coating method Methods 0.000 claims description 38
- 239000011248 coating agent Substances 0.000 claims description 35
- 238000000465 moulding Methods 0.000 claims description 15
- 239000000945 filler Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 8
- 239000011707 mineral Substances 0.000 claims description 7
- 229920001187 thermosetting polymer Polymers 0.000 claims description 6
- 239000002023 wood Substances 0.000 claims description 6
- 229920006267 polyester film Polymers 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 239000011342 resin composition Substances 0.000 claims description 5
- 239000004634 thermosetting polymer Substances 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 3
- 239000010408 film Substances 0.000 claims 6
- 239000011094 fiberboard Substances 0.000 claims 2
- 229920001225 polyester resin Polymers 0.000 claims 2
- 239000004645 polyester resin Substances 0.000 claims 2
- 230000001681 protective effect Effects 0.000 claims 2
- 239000010409 thin film Substances 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 28
- 239000002650 laminated plastic Substances 0.000 abstract description 2
- 125000006850 spacer group Chemical group 0.000 abstract description 2
- 238000005266 casting Methods 0.000 description 19
- 239000008199 coating composition Substances 0.000 description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 239000002985 plastic film Substances 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 229920006305 unsaturated polyester Polymers 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000000748 compression moulding Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000010438 granite Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000006223 plastic coating Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 240000007182 Ochroma pyramidale Species 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000013023 gasketing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/043—Ornamental plaques, e.g. decorative panels, decorative veneers containing wooden elements
Definitions
- Serial No. 08/206,810 itself is a continuation-in-part of Serial No. 07/882,839 filed May
- the subject invention relates generally to a method of preparing laminated boards, sheets or articles — useful as partitions, shelves, countertops and bathroom vanities -which is more economical and less labor-intensive than existing methods.
- the present method also enables a consumer to purchase standard size laminated boards, sheets or articles, customize the shape of the laminate for the consumer's individual use, and join the articles to provide a finished look without the need of professional assistance.
- One aspect of the invention provides a method of manufacture of an article which comprises a substrate and a plastic coating.
- the plastic coating may be an in situ polymerized thermoplastic or thermoset material laminated to any rigid substrate but preferably a cellulosic product such as wood or particle board. Where a mineral-like appearance is desired, the subject invention may utilize the compositions disclosed in my earlier patent applications, which have the appearance of
- Another aspect of the invention provides a plastic edge piece which is attached to the
- the plastic edge piece is made of the same plastic material as is
- the area of the applied plastic is then sanded for smoothness.
- the present invention also provides a method for producing coated substrates and
- the present invention is particularly useful for the production of laminates comprising
- thermoplastic or thermoset resin having a mineral appearance
- the subject invention also has several economic advantages. First, it uses existing
- the laminates are made without the use of solvents which can constitute an
- Figure 1 illustrates the use of a 4' x 8' x 5/8" particle board as the substrate in the
- Channels (4) allow excess casting resin to flow from the mold.
- Figure 2 illustrates the molding process of this invention in which a thin plastic film
- the flowable casting or coating resin (7) is placed on top of the film (6) and if desired can be smoothed using a doctor blade.
- the substrate (8) with the gasket (9) attached is lowered on the spread resin (7) and the
- FIG. 3 illustrates the process of the present invention in which the casting resin is
- Figure 4 illustrates a laminate (1) comprising a board (16) with surface coatings on
- composition as the coating by means of dowels (19).
- FIGS 5, 6 and 7 show edge pieces in cross section finished in various shapes by the
- the subject invention provides a method for producing a preformed, laminated article
- plastic material in a liquid or semi-liquid state, said plastic material being held in place by a
- the present invention also relates to laminates having a smooth mineral surface appearance.
- the invention further concerns a plastic edge piece which may be cast separately and
- the present invention is based on a compression molding process for the manufacture
- the coating resin can be the same or
- the present invention also includes the laminate made by the process of the present invention
- the coating employed in the present invention can be a pre-polymerized liquid
- thermoplastic or thermoset resins Suitable pre-polymerized or partially polymerized
- thermoplastic resins include acrylic resins such as polymethyl methylmethacrylate, and
- methyl methacrylate copolymers such as are obtained by copolymerization with alkyl
- the coating or casting resins employed in the present invention are thermosettable polymers
- the prepolymerized resins are employed in liquid form, the
- thermosettable resins the preferred resins are the unsaturated polyester resins
- glycol or diethylene glycol in the presence of an unsaturated dicarboxylic acid or anhydride
- the prepolymerized unsaturated polyester is then dissolved in a
- polyesters which can be cured by further polymerization to form tough solid coatings are well
- the resin including any filler should have a fluidity at room temperature adequate to fill the
- compositions having viscosities in the range of 500 to 40,000 centipoises are suitable in the
- the casting resins or coating compositions employed in the present invention As indicated, the casting resins or coating compositions employed in the present invention
- inventions are preferably filled resin compositions which give the coating an inorganic mineral
- Such composites are then crushed and pulverized to a desired particle size for
- fillers employed include particulates of themoset polyesters and/or acrylic resins containing
- powdered inorganic materials as talc, silica, gypsum, powdered glass, clay, silicates and
- the fillers can be employed over a
- the casting resin or coating composition usually also contains a catalyst which
- the coating composition may also contain pigments, u-v light
- coating composition provides its surface characteristic to the resulting laminate.
- Such finish is accomplished by having a thin flexible plastic film which
- the laminate but still adheres sufficiently to serve as a protective layer prior to use of the
- Plastic films useful in the process of the present invention include polyolefin films,
- the gasket material can be any solid material including metal, plastic or wood.
- the gasket material can be controllably compressed to a desired
- particularly preferred material is cardboard since it can be readily cut to provide the gasket
- Hard rubber, elastomeric polyolefins and flexible polyurethane foams are also useful as
- gasketing material as are many composites made from resins and cellulosic fibers.
- the substrate to which the coating is applied can be any semi-rigid or rigid material
- cellulosic type of material such as solid wood boards, plywood, balsa sheets, particle boards and related composites containing
- cellulosic fibers other substrates or cores for the laminates of the present invention include
- substrate or core can also be enhanced during the molding process by laminating the opposing
- Such edges can be provided in several ways such as by spraying, brushing or
- any visible seam between the laminate and the edge or nose strip can be additionally coated
- edge piece should be cast from the same composition that is employed for the surface layer of
- #6 spindle at 100 rpm is evenly spread to a thickness of slightly more than 1/16".
- the unsaturated polyester contained a polymerized resin
- the assembly is subjected to a pressure of approximately 100 psi and the platen in
- contact with the resin is heated to a temperature of 200 °F. which is maintained for a period of
- the resulting laminate contains a 1/16" layer of smooth surfaced granite like material
- the film can be mechanically removed at any time and preferably is retained to
- the uncoated edges of the particle board can be sawn off or spray coated or brushed
- the uncoated edge portions are
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Abstract
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97902839A EP0912343A1 (fr) | 1991-11-07 | 1997-01-06 | Procede pour produire des articles stratifies |
AU16916/97A AU732825B2 (en) | 1997-01-06 | 1997-01-06 | Method for producing laminated articles |
KR1019980706887A KR20000064546A (ko) | 1997-01-06 | 1997-01-06 | 적층 물품을 제조하는 방법 |
CA002247267A CA2247267A1 (fr) | 1991-11-07 | 1997-01-06 | Procede pour produire des articles stratifies |
JP10535142A JP2000507896A (ja) | 1997-01-06 | 1997-01-06 | 積層物品を製造する方法 |
PCT/US1997/000130 WO1998030391A1 (fr) | 1991-11-07 | 1997-01-06 | Procede pour produire des articles stratifies |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78898291A | 1991-11-07 | 1991-11-07 | |
CA002247267A CA2247267A1 (fr) | 1991-11-07 | 1997-01-06 | Procede pour produire des articles stratifies |
PCT/US1997/000130 WO1998030391A1 (fr) | 1991-11-07 | 1997-01-06 | Procede pour produire des articles stratifies |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998030391A1 true WO1998030391A1 (fr) | 1998-07-16 |
Family
ID=27170804
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1997/000130 WO1998030391A1 (fr) | 1991-11-07 | 1997-01-06 | Procede pour produire des articles stratifies |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP0912343A1 (fr) |
WO (1) | WO1998030391A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1360065A4 (fr) * | 2001-01-04 | 2005-07-20 | Akbar Ghahary | Stratifies ayant l'apparence de la pierre |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4643921A (en) * | 1984-07-27 | 1987-02-17 | Inax Corporation | Simulated marble article |
US4711799A (en) * | 1983-12-12 | 1987-12-08 | Gove Gene G | Apparatus and method for making a counter top and product of same |
US5304592A (en) * | 1991-11-07 | 1994-04-19 | Akbar Ghahary | Mineral-like plastics |
US5354592A (en) * | 1993-01-14 | 1994-10-11 | Thomas Miskell | Solid surfacing edge treatment method and article |
US5494548A (en) * | 1994-11-22 | 1996-02-27 | Baca; John M. | Edging structure for use with marble or granite tile |
US5504126A (en) * | 1991-11-07 | 1996-04-02 | Safas Corporation | Mineral-like coating and methods of using same |
-
1997
- 1997-01-06 EP EP97902839A patent/EP0912343A1/fr not_active Withdrawn
- 1997-01-06 WO PCT/US1997/000130 patent/WO1998030391A1/fr not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4711799A (en) * | 1983-12-12 | 1987-12-08 | Gove Gene G | Apparatus and method for making a counter top and product of same |
US4643921A (en) * | 1984-07-27 | 1987-02-17 | Inax Corporation | Simulated marble article |
US5304592A (en) * | 1991-11-07 | 1994-04-19 | Akbar Ghahary | Mineral-like plastics |
US5504126A (en) * | 1991-11-07 | 1996-04-02 | Safas Corporation | Mineral-like coating and methods of using same |
US5354592A (en) * | 1993-01-14 | 1994-10-11 | Thomas Miskell | Solid surfacing edge treatment method and article |
US5494548A (en) * | 1994-11-22 | 1996-02-27 | Baca; John M. | Edging structure for use with marble or granite tile |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1360065A4 (fr) * | 2001-01-04 | 2005-07-20 | Akbar Ghahary | Stratifies ayant l'apparence de la pierre |
Also Published As
Publication number | Publication date |
---|---|
EP0912343A1 (fr) | 1999-05-06 |
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