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WO1998031460A1 - Sorbant impregne efficace pour une multiplicite de gaz - Google Patents

Sorbant impregne efficace pour une multiplicite de gaz Download PDF

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Publication number
WO1998031460A1
WO1998031460A1 PCT/US1997/008815 US9708815W WO9831460A1 WO 1998031460 A1 WO1998031460 A1 WO 1998031460A1 US 9708815 W US9708815 W US 9708815W WO 9831460 A1 WO9831460 A1 WO 9831460A1
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WO
WIPO (PCT)
Prior art keywords
sorbent
carbon
copper
impregnated
solution
Prior art date
Application number
PCT/US1997/008815
Other languages
English (en)
Inventor
Larry A. Brey
Original Assignee
Minnesota Mining And Manufacturing Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining And Manufacturing Company filed Critical Minnesota Mining And Manufacturing Company
Priority to AU31414/97A priority Critical patent/AU3141497A/en
Publication of WO1998031460A1 publication Critical patent/WO1998031460A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D9/00—Composition of chemical substances for use in breathing apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes

Definitions

  • TECHNICAL FIELD This invention relates to a treated sorbent.
  • the sorbent is effective against a multiplicity of gas and vapor hazards.
  • Air purifying gas and vapor respirators are extensively used for protection against gas and vapor hazards. These respirators contain filtering elements capable of removing toxic gases and vapors from air and means for delivering the filtered air to the breathing zone of the wearer.
  • activated carbon sorbents against certain war gases such as hydrogen cyanide, arsine, and phosgene. These sorbents are called whetlerites.
  • Type A whetlerites can be prepared by depositing copper ammine carbonate in the pores of activated carbon and decomposing it to CuO by heat treatment at 150°C. Type A whetlerites are easy to prepare and are made from relatively inexpensive and readily available materials.
  • a drawback to using whetlerites is that they evolve ammonia in use, particularly when used in humid conditions.
  • the evolution of ammonia can be uncomfortable for the user.
  • the evolution can be minimized by drying the product at high temperature. However, drying at high temperature is expensive and care must be taken not to ignite the whetlerites.
  • Type A whetlerites typically exhibit mediocre performance against some common industrial hazards, such as formaldehyde.
  • Salts of ammine forming metals may be added with the hexamine in order to minimize ammonia evolution.
  • concentration of metal increases, so does the odor of formaldehyde, which in some cases may be more objectionable than the odor of ammonia.
  • N1OSH Institute of Occupational Safety and Health
  • filters may lie tested for certification.
  • These include standards for carbon tetrachloride (a surrogate for the entire class of organic gases and vapors), sulfur dioxide, chlorine, hydrogen chloride, formaldehyde, hydrogen sulfide (escape only), hydrogen fluoride, chlorine dioxide, ammonia, and methylamine.
  • acids gases including hydrogen cyanide, hydrogen sulfide, and chlorine
  • Type E sulfur dioxide
  • ammonia Type K
  • Sorbents have been made that are effective against multiple gas or vapor hazards.
  • U.S. Patent No. 4,677,096 describes an air cleaning material that the patentees claim has properties simultaneously satisfying European requirements for Types A, B, E, and K air filters.
  • the material uses a porous substrate impregnated with zinc oxide and a water soluble salt.
  • the water soluble salt is preferably zinc chloride, and a chromic acid salt is preferably admixed with the zinc oxide and the zinc chloride.
  • German Patent DE 323 1717 describes a sorbent capable of adsorbing both oxidizable/acidic gases and low molecular weight basic gases.
  • the sorbent uses activated carbon impregnated with an ammine forming metal iodide, preferably zinc iodide, and also preferably containing iodine, silver nitrate, or copper sulfate.
  • an ammine forming metal iodide preferably zinc iodide, and also preferably containing iodine, silver nitrate, or copper sulfate.
  • U.S. Patent No. 5,492,882 describes a material that uses activated carbon impregnated with at least one compound from each of the following three groups: (a) sulfuric acid and sulfuric acid salts, (b) molybdenum compounds, and (c) copper compounds and zinc compounds. This material is commercially available from the Calgon Carbon Corporation under the designation Calgon URC.
  • the sorbents should not only be effective against a wide range of toxic or noxious gases and vapors, but they should do so with a minimum bulk or volume. This is because when the filter is incorporated into a respirator, greater bulk makes the respirator cumbersome and less comfortable to wear, and may interfere with vision.
  • the filter should also exhibit a low pressure drop. Filters with a higher ilow resistance are harder for the wearer to breathe through.
  • the sorbent material should not release gases such as ammonia into the breathing zone where the wearer will inhale them.
  • the sorbent material should also be readily manufacturable at low cost.
  • the sorbent should meet relevant NIOSH or other certification standards.
  • This invention provides a sorbent useful in a respirator against a multiplicity of gases.
  • the sorbent is a whetlerite-type sorbent having impregnated thereon at least one ammine forming metal.
  • the sorbent is also impregnated with an amino substituted carboxylic or sulfonic salt.
  • the sorbent may be used in a respirator cartridge as the sole sorbent or mixed or layer loaded with other sorbents, such as unimpregnated carbon.
  • the sorbent may be used in filter masks, either as the sole sorbent or mixed with other sorbents.
  • This invention provides both a single stage and a two-stage impregnation method of making a multi-gas sorbent.
  • the sorbent is contacted with an ammoniacal solution containing a copper and/or zinc compound, ammonium carbonate or ammonium bicarbonate, the salt of an ammine forming metal, and a formaldehyde reactive compound.
  • the sorbent is first contacted with a solution containing a copper and/or zinc compound.
  • the sorbent is contacted with a solution containing the salt of an ammine forming metal.
  • the solution in the first or second stage contains a formaldehyde reactive compound.
  • the sorbent preferably can be made to meet current NIOSH standards for multi-gas sorbents with respect to sulfur dioxide, ammonia, and formaldehyde.
  • the sorbent material can be contained in a small volume.
  • the flow resistance through a filter made of the sorbent can be desirably low.
  • the sorbent preferably can be made to evolve little or no ammonia odor. It has a high activity and can be mixed or layered with unimpregnated carbon to minimize cost. It can be manufactured at low temperature and even at low temperature it can be made to evolve little or no ammonia odor.
  • the base sorbent for the present invention is carbon.
  • the processes for deriving carbon for use in sorbents are well known in the art.
  • the carbon may be derived from many different sources, including coconut, coal, charcoal, and coke
  • activated carbon i.e., carbon that has been treated to make it more porous and absorbent when compared to non-treated carbon, is preferred, with activated carbon derived from coconut being most preferred.
  • the carbon may be in many forms, such as granules, pellets, fibers, or cloths. It is possible that alumina, natural and synthetic clays, silica gels, or other similar sorbents might be suitable for use as a base sorbent, either alone or in combination with carbon
  • the base sorbent is impregnated with either a zinc or copper compound.
  • Copper and zinc compounds were traditionally selected for their ability to retain war gases such as phosgene and hydrogen cyanide.
  • the zinc and copper compounds are used to impregnate the carbon for reactivity against acid gases and oxidizable gases.
  • suitable copper and zinc compounds include metallic copper, metallic zinc, copper carbonate, zinc carbonate, copper or cuprous oxide, and zinc oxide. Copper and zinc carbonate are preferred because they dissolve readily in the impregnating solution and act to stabilize it. Copper carbonate is most preferred because it is relatively inexpensive and readily available.
  • the sorbent is also impregnated with the salt of an ammine forming metal.
  • Suitable metals include, in addition to zinc and copper, cobalt, nickel, and iron. These compounds form complexes with ammonia, thereby eliminating it from the air that is filtered.
  • these salts in combination with the copper or zinc compound(s), help reduce ammonia off-gassing.
  • Suitable compounds include cobalt bromide, copper bromide, iron bromide, nickel bromide, zinc bromide, cobalt chloride, copper chloride, iron chloride, nickel chloride, zinc chloride, cobalt iodide, copper iodide, iron iodide, nickel iodide, and zinc iodide.
  • the preferred compounds are the copper chloride and cobalt chloride compounds because of the stability of the ammine complexes that are formed with these compounds.
  • Other suitable compounds may include copper acetate, cobalt acetate, iron acetate, nickel acetate, zinc acetate, cobalt chloroacetate, copper chloroacetate, iron chloroacetate, nickel chloroacetate, zinc chloroacetate, cobalt dichloroacetate, copper dichloroacetate, iron dichloroactate, nickel dichloroacetate, zinc dichloroacetate, cobalt formate, copper formate, iron formate, nickel formate, zinc formate, cobalt propionate, copper propionate, iron propionate, nickel propionate, and zinc propionate.
  • the preferred copper or zinc compound is copper carbonate and the preferred salt of an ammine forming metal is cobalt chloride. It is believed that the combination of these two compounds may provide enhanced reactivity against sulfur dioxide in addition to the benefits realized by the present invention.
  • the sorbent is also impregnated with a formaldehyde reactive compound
  • the formaldehyde reactive compound is a primary or secondary amine bearing either zero or two carbonyl substituents attached directly to the amino nitrogen atom as disclosed in U.S. Patent No. 4,443,354 to Eian, the disclosure of which is incorporated herein by reference.
  • the preferred formaldehyde reactive compounds are the amino substituted carboxylic salts and amino substituted sulfonic salts Suitable amino substituted carboxylic salts include the salts of amino acids, such as potassium glycinate.
  • Suitable amino substituted sulfonic salts include sulfanilic acid sodium salt, saccharine sodium salt, the salts of sulfamic acid (sulfamates), and metanilic acid sodium salt.
  • sulfamates are preferred.
  • the resulting sorbent exhibits reactivity against a variety of gases and vapors.
  • the reactivity of the sorbent permits the use of lower volumes X impregnated carbon versus unimpregnated carbon in the sorbent.
  • the sorbent may be made in either a single or two-stage impregnation
  • the single stage impregnation involves soaking the base sorbent in an ammoniacal solution containing the salt of a copper and/or zinc compound, ammonium carbonate or bicarbonate, the salt of an ammine forming metal, and a formaldehyde reactive compound.
  • the ammonium carbonate or bicarbonate is added to the solution because it helps to dissolve the copper or zinc in the solution. It is believed that other compounds exhibiting the same dissolving characteristics may be substituted for ammonium carbonate or ammonium bicarbonate, such as carbamate
  • the sorbent is soaked for a period of time ranging from ten minutes to about an hour.
  • the sorbent is dried at a temperature ranging between 125°C to 190°C for a period of time determined by the mass transfer of water and ammonia out of the carbon pores. It is believed that drying the sorbent at higher temperatures, such as between 165°C and 190°C, helps to reduce the ammonia off- gassing.
  • the base sorbent is impregnated with either a zinc or copper compound.
  • the copper or zinc compound is dissolved in an ammoniacal impregnating solution containing sufficient ammonia to dissolve the copper or zinc compound.
  • Compounds such as ammonium carbonate may be added to assist in dissolving the zinc and copper compounds in the solution.
  • the sorbent is soaked in the solution ranging between ten minutes t ⁇ approximately one hour. Thereafter, the excess impregnation solution may be drained off.
  • the sorbent is heated in order to dry it and, in the case of whetlerites, to convert the copper compound to copper oxide.
  • the treated sorbent need only be heated to a temperature in the range of 1 10°C to 130°C. Notwithstanding the foregoing, the sorbent may contain copper or zinc oxide without adversely affecting the characteristics of the sorbent.
  • the carbon is heated until it appears dry. Additional heating may be employed to ensure that the carbon is dry and has a low level of residual ammonia.
  • the sorbent After drying, the sorbent is contacted with the salt of an ammine forming metal in a solution that is substantially free of ammonia. These compounds do not damage the initial zinc or copper impregnation because the impregnates of the first step are not significantly soluble in the substantially ammonia-free aqueous solution of the second stage impregnation.
  • the zinc and copper compounds react with the salts of the ammine forming metals to give activity against the targeted gases and vapors.
  • the pH may be adjusted upward, compatible with the salt compound. This adjustment helps to prevent damage to the zinc or coppei impregnate of the first impregnation step because it prevents the basic impregnated salts from being extracted from the carbon.
  • the sorbent is also treated with a formaldehyde reactive compound This compound may be added either in the first or second step
  • At least one, preferably two, ammine forming metals are present in some form, such as an oxide or salt
  • both copper and cobalt are present
  • at least one formaldehyde reactive compound is present
  • sulfamate is present.
  • the sorbent may be loaded into a respirator cartridge for use in respirators Suitable cartridges and respirators include the 3M Series 5000, 3M Series 6000, and 3M Series 7000 respirators and cartridges available from available from Minnesota Mining & Manufacturing Company of St Paul, Minnesota (“3M")
  • the sorbent may be layer-loaded with unimpregnated sorbent Alternatively, the sorbent of the present invention and the unimpregnated soibent may be blended togethei Additional elements may be included in the cartridge, including drying elements and filters for various hazards such as smoke.
  • the sorbent may also be incorporated into a filter mask Kepi sentalivc filter masks include the 3M Series 4000 mask available from 3M As with the cartridge, the sorbent may be mixed with an unimpregnated sorbent
  • Copper impregnating solutions were prepared by combining deionized water, basic copper carbonate [assumed composition CuCO* Cu(OH) 2 , 55 6% Cu, 2.0% CO 2 ], aqueous ammonia [assumed composition 29% NH ⁇ ,], and ammonium carbonate [assumed composition (NH 4 ) CO,, 34 2% NH 3 , 54 3% C0 2 J
  • the solution composition is specified by specifying the percent copper, percent ammonia, and percent carbon dioxide. In some cases, additional components weie added to the impregnating solutions. All component compositions are expressed as weight percentages.
  • the carbon used was Kuraray GC activated carbon from Kuraray Chemical Company, Osaka, Japan, with a US standard mesh size of 16 x 35 (0 5 mm x 1 5 mm).
  • the cartridges were filled with a layer of 50 cubic centimeters of unimpregnated activated carbon and a layer of 55 cubic centimeters of impregnated activated carbon. These samples are called layer loaded They weie tested with the impregnated layer on top, i.e., contacting the contaminated atmosphere first.
  • NIOSH standards specify that for a combination organic vapor/acid gas approval, the a filter must exhibit a service life as defined by the test protocol of at least 15 minutes for sulfur dioxide; at least 25 minutes for ammonia; and at least 50 minutes for formaldehyde.
  • Example 1 A copper impregnating solution was prepared as described above containing 5% copper, 5% ammonia, 7.5% carbon dioxide, and 6% sulfamic acid To 1000 grams of this solution was added 584 grams of Kuraray GC activated carbon After soaking for about 30 minutes, the carbon was separated from the supernatant liquid by vacuum filtration. The wet carbon was dried at 1 10°C with periodic stirring until it appeared dry and then was further dried at 160°C for several hours. The carbon recovered weighed 668 grams.
  • a second impregnation was carried out by soaking 335 grams of the above intermediate impregnated carbon in a 0.8 molal solution of cobalt chloride The carbon was then filtered from the supernatant liquid and dried at 140°C to a constant weight. The recovered carbon weighed 359 grams
  • the impregnated carbon was also layer loaded as described above by adding a layer of 55 cubic centimeters (cc) of impregnated carbon and 50 cubic centimeters of unimpregnated Kuraray GC carbon in a 3M Series 6000 respirator cartridge
  • the formaldehyde service life was measured in this configuration and found to be 1 16 minutes.
  • Carbon was impregnated and dried as described in the first impregnating step in Example 1.
  • a second impregnating step was carried out by soaking 1 2 grams of this intermediate impregnated carbon in a 0 8 molal solution of cup ⁇ c chloride. The carbon was then filtered from the supernatant liquid and dried at
  • the impregnated carbon was layer loaded using a layer of 55 cc of impregnated carbon and 50 cc of unimpregnated carbon as described above
  • the formaldehyde service life in this configuration was measured and found to be 29 minutes.
  • a second impregnation was carried out by soaking 195 grams of the above intermediate impregnated carbon in 387 grams of a 0 8 molal solution of cobalt chloride which had been pH adjusted to pH 6 with potassium hydroxide The carbon was then filtered from the supernatant liquid and dried at 1 10°C The recovered carbon weighed 216 grams.
  • the impregnated carbon was layer loaded using a layer of 55 cc of impregnated carbon and 50 cc of unimpregnated carbon in a 3M Series 6000 respirator cartridge as described above and tested for service life against sulfur dioxide (SO 2 S L.), ammonia service life (NH ⁇ S L ), and formaldehyde service life (form S.L.). Service lives are given in minutes and the lesults are given in Table 2
  • Example 4 and Comparative Examples C1-C3 An impregnating solution was prepared as described above containing 6% copper, 9% ammonia, 6% carbon dioxide, and 6% sulfamic acid To 2000 gia s of this solution was added 1000 grams of Kuraiay GC carbon Aftei soaking, the excess solution was drained off and the carbon was dried at 140°C for about four hours The carbon recovered weighed 1 149 grams A portion of the above intermediate impregnated carbon weighing 350 grams was redried at 165°C for several hours A second impregnation was carried out by soaking 250 grams of the redried carbon in 500 grams of 0 8 molal solution of cobalt chloride The carbon was then filtered from the supernatant liquid and dried at 110°C for several hours The recovered carbon weighed 268 grams
  • the impregnated carbon was loaded into a 3M Series 6000 lespiraior cartridge. Wet air with a relative humidity of 87% was passed through the cartridge at 16 liters per minute, and the amount of outgassed ammonia was measured ovei a 5 hour period.
  • the intermediate impregnated carbon from the first impregnation step (identified in Table 3 as sample C l ) was also loaded into a sinnlai cartridge and tested similarly
  • 105 cc of Calgon URC activated caibon, lot 4146 dr 24, made by Calgon Carbon Corporation, Pittsburgh, PA (“C2") was loaded into a similar cartridge and tested similarly
  • a Mine Safety Appliances Company GME cartridge, lot 1495, made by Mine Safety Appliances Company, Pittsburgh, PA (“C3”) was tested similarly The results are reported as parts per million ammonia in the air exiting the cartridge, and are given in Table 3
  • Example 5 An impregnating solution was prepared as described above containing 7% copper, 10 5% ammonia, and 7% carbon dioxide To 2000 grams of this solution was added 1000 grams of Kuraray GC carbon After soaking, the excess solution was drained off and the carbon was dried at I60°C to a constant weight The recovered intermediate carbon weighed 1089 grams.
  • a second impregnation was carried out by soaking 250 grams of the above intermediate impregnated carbon in 499 grams of a solution 1.0 molal in cobalt chloride and 0.4 molal in potassium sulfamate. The carbon was then filtered from the supernatant liquid and dried at 1 10°C to a constant weight. The recovered carbon weighed 305 grams.
  • the impregnated carbon was layer loaded using a layer of 55 cc of impregnated carbon and 50 cc of unimpregnated carbon in a 3M Series 6000 respirator cartridge as described above and tested. Service lives are given in minutes and the results are given in Table 4.
  • Carbon was impregnated as described in the first impregnating step in Example 5.
  • a second impregnation was carried out by soaking 250 grams of the above intermediate impregnated carbon in 499 gra s of a solution 1.0 molal in cobalt chloride and 0.4 molar in potassium sulfamate which had been pH adjusted to pH 6 with potassium hydroxide.
  • the carbon was then filtered from the supernatant liquid and dried at 1 10°C to a constant weight.
  • the recovered carbon weighed 304 grams.
  • the impregnated carbon was layer loaded using a layer of 55 cc of impregnated carbon and 50 cc of unimpregnated carbon in a 3M Series 6000 respirator cartridge as described above and tested. Service lives are given in minutes and the results are given in Table 5.
  • An impregnating solution was prepared as described above containing 3.8% copper, 5.8% ammonia, 3.8% carbon dioxide, and 4.0% glycine. To 500 grams of this solution was added 250 grams of Kuraray GC carbon. After soaking, the excess solution was drained off and the carbon was dried at 1 10°C for about four hours. A second impregnation was carried out by soaking 212 grams of the above intermediate impregnated carbon in 400 grams of a solution 0 8 molal in cobalt chloride. Excess solution was then dried at 1 10°C to a constant weight.
  • the impregnated carbon was layer loaded using a layer of 55 cc of impregnated carbon and 50 cc of unimpregnated carbon in a 3M Series 6000 respirator cartridge as described above and tested. Service lives are given in minutes and the results are given in Table 6.
  • Example 8 Four hundred fifty grams of Kuraray CG carbon was treated with a solution prepared by dissolving 135 grams of basic copper carbonate [assumed composition CuCO 3 .Cu(OH) 2 , 55.6% Cu, 2.0% CO ], 133 grams of ammonium carbonate [assumed composition (NH 4 ) 2 CO 3 ; 34.2% NH , 54.3% CO 2 ] 80 grams of cobalt chloride hexahydrate, and 38.8 grams of sulfamic acid in a solution prepared by mixing 257 grams of ammonia water [assumed composition 29% NH ] and 298 grams of deionized water. The excess solution was drained off and the carbon dried at 140°C.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Pulmonology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

L'invention concerne un sorbant, efficace pour une multiplicité de gaz, imprégné d'un composé de cuivre ou de zinc, d'un sel d'un métal formant des amines, et d'un composé réagissant au formaldehyde. Des cartouches pour appareil respiratoire et des masques à gaz équipés de ce sorbant offrent des performances améliorées.
PCT/US1997/008815 1997-01-22 1997-05-27 Sorbant impregne efficace pour une multiplicite de gaz WO1998031460A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU31414/97A AU3141497A (en) 1997-01-22 1997-05-27 Multi-gas impregnated sorbent

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US78594197A 1997-01-22 1997-01-22
US08/785,941 1997-01-22

Publications (1)

Publication Number Publication Date
WO1998031460A1 true WO1998031460A1 (fr) 1998-07-23

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PCT/US1997/008815 WO1998031460A1 (fr) 1997-01-22 1997-05-27 Sorbant impregne efficace pour une multiplicite de gaz

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AU (1) AU3141497A (fr)
WO (1) WO1998031460A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7004990B2 (en) 2003-06-26 2006-02-28 3M Innovative Properties Company Broad spectrum filter system including tungsten-based impregnant and being useful for filtering contaminants from air or other gases
WO2006119654A1 (fr) * 2005-05-06 2006-11-16 Dr. P. Pleisch Ag Matiere de filtrage pour l'adsorption de polluants presents dans l'air ambiant
US8293333B2 (en) 2008-09-02 2012-10-23 Jeffrey R. Dahn Ammonia-free gaseous air filter
WO2013025197A1 (fr) * 2011-08-15 2013-02-21 Empire Technology Development Llc Sorbants oxalates pour l'élimination de mercure
CN112717885A (zh) * 2020-12-28 2021-04-30 南通汇佰川工程技术有限公司 一种过滤器用高效活性炭的制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3231717A1 (de) * 1982-08-26 1984-03-01 Drägerwerk AG, 2400 Lübeck Luftreinigungsmittel, impraegniert und zur verwendung in filtern
US4443354A (en) * 1982-03-26 1984-04-17 Minnesota Minning And Manufacturing Company Sorbent material for reducing formaldehyde emission
EP0405404A1 (fr) * 1989-06-23 1991-01-02 Calgon Carbon Corporation Charbon activé imprégné exempt de chrome pour l'adsorption de gaz et/ou de vapeurs toxiques
WO1993010896A1 (fr) * 1991-11-27 1993-06-10 Calgon Carbon Corporation Carbone exempt de chrome, impregne et active pour l'adsorption de gaz/ou vapeurs toxiques, s'appliquant a des systemes de respiration
EP0629437A1 (fr) * 1993-06-16 1994-12-21 The Minister Of National Defence Of Her Majesty's Canadian Government Charbon actif impregné par une amine organique
FR2728476A1 (fr) * 1994-12-23 1996-06-28 App De Protection Soc Nouv Remplissages pour filtres pour la protection des voies respiratoires a grains de charbon actif impregnes et filtres comportant ces remplissages

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4443354A (en) * 1982-03-26 1984-04-17 Minnesota Minning And Manufacturing Company Sorbent material for reducing formaldehyde emission
DE3231717A1 (de) * 1982-08-26 1984-03-01 Drägerwerk AG, 2400 Lübeck Luftreinigungsmittel, impraegniert und zur verwendung in filtern
EP0405404A1 (fr) * 1989-06-23 1991-01-02 Calgon Carbon Corporation Charbon activé imprégné exempt de chrome pour l'adsorption de gaz et/ou de vapeurs toxiques
WO1993010896A1 (fr) * 1991-11-27 1993-06-10 Calgon Carbon Corporation Carbone exempt de chrome, impregne et active pour l'adsorption de gaz/ou vapeurs toxiques, s'appliquant a des systemes de respiration
EP0629437A1 (fr) * 1993-06-16 1994-12-21 The Minister Of National Defence Of Her Majesty's Canadian Government Charbon actif impregné par une amine organique
FR2728476A1 (fr) * 1994-12-23 1996-06-28 App De Protection Soc Nouv Remplissages pour filtres pour la protection des voies respiratoires a grains de charbon actif impregnes et filtres comportant ces remplissages

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7004990B2 (en) 2003-06-26 2006-02-28 3M Innovative Properties Company Broad spectrum filter system including tungsten-based impregnant and being useful for filtering contaminants from air or other gases
US7309513B2 (en) 2003-06-26 2007-12-18 3M Innovative Properties Company Broad spectrum filter system including tungsten-based impregnant and being useful for filtering contaminants from air or other gases
WO2006119654A1 (fr) * 2005-05-06 2006-11-16 Dr. P. Pleisch Ag Matiere de filtrage pour l'adsorption de polluants presents dans l'air ambiant
US8293333B2 (en) 2008-09-02 2012-10-23 Jeffrey R. Dahn Ammonia-free gaseous air filter
WO2013025197A1 (fr) * 2011-08-15 2013-02-21 Empire Technology Development Llc Sorbants oxalates pour l'élimination de mercure
US8425867B2 (en) 2011-08-15 2013-04-23 Empire Technology Development Llc Oxalate sorbents for mercury removal
CN112717885A (zh) * 2020-12-28 2021-04-30 南通汇佰川工程技术有限公司 一种过滤器用高效活性炭的制备方法

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AU3141497A (en) 1998-08-07

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