WO1998031533A1 - Raccord de tuyauterie - Google Patents
Raccord de tuyauterie Download PDFInfo
- Publication number
- WO1998031533A1 WO1998031533A1 PCT/GB1998/000146 GB9800146W WO9831533A1 WO 1998031533 A1 WO1998031533 A1 WO 1998031533A1 GB 9800146 W GB9800146 W GB 9800146W WO 9831533 A1 WO9831533 A1 WO 9831533A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coupler
- polymer
- fibres
- substrate
- heating
- Prior art date
Links
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims abstract description 23
- 238000010438 heat treatment Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000000758 substrate Substances 0.000 claims abstract description 10
- 238000007789 sealing Methods 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 13
- 229920005992 thermoplastic resin Polymers 0.000 claims description 12
- 229920001187 thermosetting polymer Polymers 0.000 claims description 10
- 229920001601 polyetherimide Polymers 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 229920002492 poly(sulfone) Polymers 0.000 claims description 4
- 239000004697 Polyetherimide Substances 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 229920006287 phenoxy resin Polymers 0.000 claims description 3
- 239000013034 phenoxy resin Substances 0.000 claims description 3
- -1 polyethersulphones Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004642 Polyimide Substances 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229920006020 amorphous polyamide Polymers 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920006132 styrene block copolymer Polymers 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 17
- 229910052799 carbon Inorganic materials 0.000 description 17
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 239000003365 glass fiber Substances 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 230000002787 reinforcement Effects 0.000 description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000002654 heat shrinkable material Substances 0.000 description 1
- 229920006258 high performance thermoplastic Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000013521 mastic Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/522—Joining tubular articles
- B29C66/5221—Joining tubular articles for forming coaxial connections, i.e. the tubular articles to be joined forming a zero angle relative to each other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/34—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
- B29C65/3404—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint
- B29C65/3408—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising single particles, e.g. fillers or discontinuous fibre-reinforcements
- B29C65/3416—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising single particles, e.g. fillers or discontinuous fibre-reinforcements comprising discontinuous fibre-reinforcements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/34—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
- B29C65/3404—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint
- B29C65/342—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising at least a single wire, e.g. in the form of a winding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/34—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
- B29C65/3404—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint
- B29C65/3436—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising independent continuous fibre-reinforcements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/34—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
- B29C65/3404—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint
- B29C65/344—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint being a woven or non-woven fabric or being a mesh
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
- B29C65/483—Reactive adhesives, e.g. chemically curing adhesives
- B29C65/4835—Heat curing adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/50—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like
- B29C65/5042—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like covering both elements to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/114—Single butt joints
- B29C66/1142—Single butt to butt joints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/53—Joining single elements to tubular articles, hollow articles or bars
- B29C66/532—Joining single elements to the wall of tubular articles, hollow articles or bars
- B29C66/5326—Joining single elements to the wall of tubular articles, hollow articles or bars said single elements being substantially flat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/34—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
- B29C65/3472—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint
- B29C65/3484—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint being non-metallic
- B29C65/3492—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the composition of the heated elements which remain in the joint being non-metallic being carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/50—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like
- B29C65/5007—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like characterised by the structure of said adhesive tape, threads or the like
- B29C65/5014—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like characterised by the structure of said adhesive tape, threads or the like being fibre-reinforced
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/50—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like
- B29C65/5007—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like characterised by the structure of said adhesive tape, threads or the like
- B29C65/5021—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like characterised by the structure of said adhesive tape, threads or the like being multi-layered
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/50—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like
- B29C65/5007—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like characterised by the structure of said adhesive tape, threads or the like
- B29C65/5028—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like characterised by the structure of said adhesive tape, threads or the like being textile in woven or non-woven form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/72—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
- B29C66/721—Fibre-reinforced materials
- B29C66/7212—Fibre-reinforced materials characterised by the composition of the fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/7394—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoset
- B29C66/73941—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoset characterised by the materials of both parts being thermosets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
- B29K2309/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2023/00—Tubular articles
- B29L2023/22—Tubes or pipes, i.e. rigid
Definitions
- the present invention relates to a method of sealing pipes, and other substrates.
- it relates to a method of sealing a joint between two pipes using an improved pipe coupler.
- WO92/05674 discloses an electrically-heated tape comprising a conductive polymer.
- WO93/08013 shows a heat-recoverable article for use on pipe joints.
- the article is a sleeve containing heat-recoverable fabric.
- Conductive fibres may be incorporated into the fabric to enable it to be heated to recover the fabric.
- EP-A-0158519 discloses a heat-recoverable article using a heat-recoverable fabric with heat-recoverable polyethylene filaments in the warp and glass fibre yarn in the weft. A resistance heating wire is interleaved with the fibres in the weft of the fabric. The fabric is coated with mastic.
- Such rigid joints may be obtained by forming a coupler by wrapping a layer of pre- polymer one or more times about the joint between two pipes and then heating the pre- polymer to convert it to a thermoset polymer.
- the heat required to convert the pre-polymer to thermoset polymer may be supplied by applying a source of heat to the outside of the wrapped pipe.
- a source of heat to the outside of the wrapped pipe.
- the layer or layers of pre-polymer will be relatively thick. It is thus difficult to ensure uniform heating of the pre-polymer.
- a substrate such as a joint between the ends of two pipes, which method comprises:
- the pre-polymer layer is in contact (directly or indirectly) with conductive fibres (preferably carbon fibres and optionally also glass fibres as reinforcement, and preferably in the form of a fabric), and the pre-polymer is heated to cure it by causing electrical current to flow through the conductive fibres.
- conductive fibres preferably carbon fibres and optionally also glass fibres as reinforcement, and preferably in the form of a fabric
- the conductive fibres are preferably embedded in the pre-polymer. Heating is preferably carried out whilst the layer is pressed in contact with the substrate, preferably by means of an external pressurization device (rather than say by incorporating heat- shrinkable material into the layer).
- a preferred pressurization device is a bladder or other device operated pneumatically.
- the present invention is particularly suitable for joining GRP (glass reinforced polyester or other plastic) pipes.
- the pre-polymer is preferably a high performance thermoplastic resin, (usually together with an appropriate curing agent) and particularly one which has low brittleness.
- a suitable resin is one comprising the adhesive composition disclosed in US 5470622, the disclosure of which is incorporated herein by reference. That adhesive composition has low brittleness, but satisfactory stiffness and chemical resistance. Many other attempts to reduce brittleness have resulted in resins of poor stiffness and poor chemical resistance.
- the adhesive composition of US 5470622 comprises a blend of (1) about 10 to about 75 parts by weight of an essentially amorphous thermoplastic resin selected from the group consisting of polysulphones, polyethersulphones, polystyrene, polyphenylene oxide, amorphous polyamides, phenoxy resins, amorphous polyimides, polyetherimides, polyetherimide/silicone block copolymers, polyurethanes, amorphous polyesters, polycarbonates, and acrylic resins such as polymethyl methacrylate, styrene/acrylonitrile and styrene block copolymers, (2) about 90 to about 25 parts by weight of an uncured thermosetting resin, and (3) a curing agent if necessary.
- an adhesive composition can remain substantially uncured for at least about one year at 25 °C.
- thermoplastic resin is used in the adhesive to provide an overall adhesive composition that is strong, tough and leathery at room temperature in the uncured state.
- the thermoplastic resin is generally present in an amount from about 10 parts to about 75 parts, preferably from about 15 parts to about 60 parts, and particularly from about 25 parts to about 45 parts (all parts herein are by weight). Any of a wide range of thermoplastic resins may be utilized as components of the adhesive composition of the present invention.
- the preferred class of thermoplastic resins may be defined as amorphous thermoplastic resins, that is resins which are essentially amorphous (as defined in Saechtling International Plastics Handbook for the Technologist, Engineer and User, Second Edition, 1987, Hanser Publishers, Kunststoff, at page 1, incorporated herein by reference).
- the term "essentially amorphous" as used herein means that the resin is at most about 25% crystalline, preferably at most about 20% crystalline, particularly at most about 15% crystalline, and especially at most about 5% crystalline. A mixture of resins may be used if desired.
- the thermoplastic resin is of high molecular weight and may be rigid or rubbery at room temperature.
- Illustrative amorphous thermoplastic resins that can be used in the practice of this invention are polyetherimides, such as the UltemTM resins commercially available from General Electric Company, polyetherimide/silicone block copolymers, such as the SiltemTM resins commercially available from General Electric Company, polysulfones, such as Poly sulf one P-1700TM, commercially available from Union Carbide Corporation, and phenoxy resins, such as Phenoxy PKH-JTM commercially available from Union Carbide Corporation.
- polyetherimides such as the UltemTM resins commercially available from General Electric Company
- polyetherimide/silicone block copolymers such as the SiltemTM resins commercially available from General Electric Company
- polysulfones such as Poly sulf one P-1700TM
- phenoxy resins such as Phenoxy PKH-JTM commercially available from Union Carbide Corporation.
- the adhesive composition also contains a curable thermosetting resin or mixtures thereof.
- a curable thermosetting resin or mixtures thereof.
- Such resins are defined on pages 1 and 2 of the Seechtling Plastics Handbook referred to above.
- the thermosetting resin preferably has a functionality greater than 2.
- the thermosetting resin is generally present in an amount from about 90 parts to about 25 parts, preferably from about 85 parts to about 40 parts, and particularly from about 75 to about 55 parts by weight of the adhesive composition.
- the weight ratio of the thermoplastic resin to the thermosetting resin generally falls within a range from about 1:9 to about 3:1.
- the thermosetting resin may be a liquid or solid at room temperature and when cured (in the absence of the thermoplastic resin) may be rigid or rubbery.
- thermosetting resin may suitably be a liquid epoxy resin
- thermoplastic resin due to blending with the thermoplastic resin the resulting adhesive composition is not itself liquid but is instead a tough leathery film.
- Liquid epoxy resins are described in some detail in Volume 2 of Engineered Materials Handbook, Engineering Plastics, published by ASM International, particularly at pages 240-241, and the description therein is incorporated by reference.
- epoxy resin is used herein to mean any of the conventional dimeric, oligomeric or polymeric epoxy materials containing a plurality, ie at least 2, of epoxy functional groups.
- Types of epoxy resins that can be used include, for example, the reaction product of bisphenol A and epichlorohydrin, the reaction product of phenol and formaldehyde (novolac resin) and epichlorohydrin, cycloaliphatic and peracid epoxies, glycidyl esters, the reaction product of epichlorohydrin and p-amino phenol, the reaction product of expichlorohydrin and gloxal tetraphenol and the like.
- the layer of pre-polymer will generally be applied as a "pre-preg", ie a layer of fibre reinforcement impregnated with the pre-polymer.
- the reinforcement may be the glass fibres and carbon fibres, and/or fabric thereof, (either being referred to herein for convenience as the "G/C fabric") so that a layer of pre- polymer extends on either side of the fabric.
- Such a layer of pre-polymer applied to the G/C fabric may be the only layer used to form the joint. In general, however, it will be desirable to provide multiple layers of pre-polymer around the joint between the pipes in order to obtain a high degree of rigidity.
- the multiple layers may be obtained by wrapping multiple individual sheets of pre-preg around the pipe but is preferably obtained by repeatedly winding a single strip of pre-preg around the pipe joint.
- pre-preg multiple layers of pre-preg are used it is preferred that the majority of the layers be reinforced only with non-conductive fibre eg glass fibre.
- a preferred arrangement is to use two layers of pre-preg reinforced only with glass, above and below a layer comprising a carbon only fabric or a carbon and glass fabric.
- a fabric formed from glass fibres and carbon fibres provides both heating for the pre-polymer and reinforcement for the cured polymer, and is therefore the preferred choice.
- the fabric is preferably a woven fabric in which the carbon fibres extend circumferentially or helically around the joint when the fabric is in position on the joint. Where it is desirable that fibres extend helically with respect to the pipe, this can result from helical wrapping of a tape or other layer, or from spiral wrappings of a layer the fibres of which run at an angle to its length.
- the woven fabric may have both carbon and glass fibres extending in one direction and only glass fibres extending in a direction substantially at right angles or obliquely thereto.
- the carbon or other conductive fibres may be distributed in a non-uniform manner in the fabric in order for example to provide non-uniform heating across the coupler.
- the fabric is preferably in the form of a wrap-around sheet, ie a sheet which can be wrapped around the pipes to be joined and whose ends can be overlapped to form a sleeve.
- the carbon fibres extend circumferentially in the sheet but do not extend to the extremity of one of the overlapping ends of the sheet.
- a first metal or other electrode extending across the width of the sheet at or towards one end, links the carbon fibres at one of the overlapping ends of the sheet; while a second such electrode extends across the width at or towards an opposite end but is clear of the ends of the carbon fibres. This second electrode will make contact with the fibres when the sleeve is in its wrapped-around configuration around the pipe.
- the electrodes are used to bus electric current to the carbon or other conductive fibres.
- a self-contained heater the carbon or other conductive fibres
- an external pressurization device pneumatically or otherwise operated
- a substantially homogeneous temperature parallel to a surface of the coupler if necessary by supplying more electrical power to the edges of the layer to compensate for heat loss.
- Substantially homogeneous pressurization can be achieved by using a suitable pressurization system, particularly a pneumatic system.
- a good bond can thus be achieved with no air inclusions since any air between the various layers of the coupler and between the coupler and the substrate is squeezed out.
- the electrical heater to be constructed and operated to achieve a temperature within the prepolymer of, say 165-200°C especially about 175 °C, for from 5-15, especially about 10, minutes.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Abstract
La présente invention concerne un procédé permettant d'étanchéiser un substrat tel qu'un tuyau et consistant à (a) entourer ledit substrat d'un raccord comprenant un prépolymère contenant des fibres de renforcement; (b) chauffer le raccord afin que le prépolymère se solidifie et devienne rigide, le raccord comprenant en outre des fibres conductrices au travers desquelles on fait passer un courant électrique afin de provoquer l'échauffement.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9700927.8 | 1997-01-17 | ||
GBGB9700927.8A GB9700927D0 (en) | 1997-01-17 | 1997-01-17 | Pipe coupler |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998031533A1 true WO1998031533A1 (fr) | 1998-07-23 |
Family
ID=10806145
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1998/000146 WO1998031533A1 (fr) | 1997-01-17 | 1998-01-16 | Raccord de tuyauterie |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB9700927D0 (fr) |
WO (1) | WO1998031533A1 (fr) |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3235289A (en) * | 1961-12-27 | 1966-02-15 | Jones & Hunt Inc | Butt joints on reinforced plastic pipe and method of forming same |
US3865662A (en) * | 1973-04-06 | 1975-02-11 | Allied Chem | Method for sealing shell-like thermoplastic objects |
EP0098024A1 (fr) * | 1982-06-29 | 1984-01-11 | i.c. Möller a/s | Procédé de raccordement de tuyaux préfabriqués et isolés à la chaleur et raccord de soudure pour celui-ci |
US4428789A (en) * | 1981-03-05 | 1984-01-31 | Ube Industries, Ltd. | Process for firmly bonding a thermoplastic covering sheet on a hard article |
EP0158519A2 (fr) * | 1984-04-06 | 1985-10-16 | N.V. Raychem S.A. | Objet à reprise thermique |
US4560428A (en) * | 1984-08-20 | 1985-12-24 | Rockwell International Corporation | System and method for producing cured composites |
EP0173446A1 (fr) * | 1984-07-24 | 1986-03-05 | Merseyside And North Wales Electricity Board | Renforcement pour éléments de support |
US5010440A (en) * | 1988-12-09 | 1991-04-23 | Mamiko Endo | Pipe liner having electrically conductive wires for hardening and electrostatic build-up prevention |
WO1991018239A1 (fr) * | 1990-05-22 | 1991-11-28 | Kb Komposit Försäljnings Ab | Conteneur destine notamment a un fluide sous pression |
WO1993008013A1 (fr) * | 1991-10-23 | 1993-04-29 | N.V. Raychem S.A. | Article thermoreformable |
US5470622A (en) * | 1990-11-06 | 1995-11-28 | Raychem Corporation | Enclosing a substrate with a heat-recoverable article |
WO1996005386A1 (fr) * | 1994-08-08 | 1996-02-22 | Conductive Composites Technology, Inc. | Elements en resine composite durcie de pointe et procede d'elaboration de ces elements |
-
1997
- 1997-01-17 GB GBGB9700927.8A patent/GB9700927D0/en active Pending
-
1998
- 1998-01-16 WO PCT/GB1998/000146 patent/WO1998031533A1/fr active Application Filing
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3235289A (en) * | 1961-12-27 | 1966-02-15 | Jones & Hunt Inc | Butt joints on reinforced plastic pipe and method of forming same |
US3865662A (en) * | 1973-04-06 | 1975-02-11 | Allied Chem | Method for sealing shell-like thermoplastic objects |
US4428789A (en) * | 1981-03-05 | 1984-01-31 | Ube Industries, Ltd. | Process for firmly bonding a thermoplastic covering sheet on a hard article |
EP0098024A1 (fr) * | 1982-06-29 | 1984-01-11 | i.c. Möller a/s | Procédé de raccordement de tuyaux préfabriqués et isolés à la chaleur et raccord de soudure pour celui-ci |
EP0158519A2 (fr) * | 1984-04-06 | 1985-10-16 | N.V. Raychem S.A. | Objet à reprise thermique |
EP0173446A1 (fr) * | 1984-07-24 | 1986-03-05 | Merseyside And North Wales Electricity Board | Renforcement pour éléments de support |
US4560428A (en) * | 1984-08-20 | 1985-12-24 | Rockwell International Corporation | System and method for producing cured composites |
US5010440A (en) * | 1988-12-09 | 1991-04-23 | Mamiko Endo | Pipe liner having electrically conductive wires for hardening and electrostatic build-up prevention |
WO1991018239A1 (fr) * | 1990-05-22 | 1991-11-28 | Kb Komposit Försäljnings Ab | Conteneur destine notamment a un fluide sous pression |
US5470622A (en) * | 1990-11-06 | 1995-11-28 | Raychem Corporation | Enclosing a substrate with a heat-recoverable article |
WO1993008013A1 (fr) * | 1991-10-23 | 1993-04-29 | N.V. Raychem S.A. | Article thermoreformable |
WO1996005386A1 (fr) * | 1994-08-08 | 1996-02-22 | Conductive Composites Technology, Inc. | Elements en resine composite durcie de pointe et procede d'elaboration de ces elements |
Non-Patent Citations (1)
Title |
---|
MENG HOU ET AL: "RESISTANCE WELDING OF CONTINUOUS GLASS FIBRE-REINFORCED POLYPROPYLENE COMPOSITES", COMPOSITES MANUFACTURING, vol. 3, no. 3, 1 January 1992 (1992-01-01), pages 153 - 163, XP000349830 * |
Also Published As
Publication number | Publication date |
---|---|
GB9700927D0 (en) | 1997-03-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5470622A (en) | Enclosing a substrate with a heat-recoverable article | |
US5313034A (en) | Thermoplastic welding | |
EP0430377B1 (fr) | Article à reprise dimensionnelle | |
US5236765A (en) | Heat-recoverable article | |
US4775501A (en) | Heat recoverable article comprising conductive polymer compositions | |
CA1260664A (fr) | Article thermoretrecissable | |
US5030487A (en) | Heat recoverable article comprising conductive polymer compositions | |
EP0556290B1 (fr) | Enrobage d'un substrat a l'aide d'un article thermoreformable | |
EP0723994A4 (fr) | Composition de resine epoxyde, preimpregne et materiau composite renforce par des fibres | |
JPS61139440A (ja) | 硬化性布部材 | |
WO1998031533A1 (fr) | Raccord de tuyauterie | |
US3183142A (en) | Reinforced resinous structural material | |
DE102016121693B4 (de) | Verfahren zum Herstellen eines Duroplast-Thermoplast-Verbundbauteils | |
EP0027708B1 (fr) | Tuyau renforcé en matière thermoplastique | |
JP2622421B2 (ja) | 導電性ポリマーを使用して物品を接合する方法と器具 | |
EP0610279A1 (fr) | Article et son procede de fixation a un objet allonge | |
KR20240092595A (ko) | 파이-형상의 프리폼 및 그 본딩된 조인트 | |
CA1339458C (fr) | Dispositifs de raccordement comportant un element polymere conducteur, et methode connexe | |
CA1231823A (fr) | Article dimensionnellement conformable par retrecissement | |
KR960002862B1 (ko) | 치수복원이 가능한 제품 및 그 제조방법 | |
JPS6164434A (ja) | 繊維強化ポリマー物品 | |
JPS61261517A (ja) | プラスチツク被覆鋼矢板 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): CA JP MG US |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
NENP | Non-entry into the national phase |
Ref country code: JP Ref document number: 1998533953 Format of ref document f/p: F |
|
122 | Ep: pct application non-entry in european phase |