WO1998038981B1 - Hydrocarbon gels as suspending and dispersing agents and products - Google Patents
Hydrocarbon gels as suspending and dispersing agents and productsInfo
- Publication number
- WO1998038981B1 WO1998038981B1 PCT/US1998/003978 US9803978W WO9838981B1 WO 1998038981 B1 WO1998038981 B1 WO 1998038981B1 US 9803978 W US9803978 W US 9803978W WO 9838981 B1 WO9838981 B1 WO 9838981B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition according
- gel composition
- weight percent
- gel
- hydrocarbon
- Prior art date
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract 10
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract 10
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract 9
- 239000002270 dispersing agent Substances 0.000 title abstract 2
- 239000000499 gel Substances 0.000 title abstract 2
- 239000000375 suspending agent Substances 0.000 title abstract 2
- 239000000047 product Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract 33
- 239000000126 substance Substances 0.000 claims abstract 12
- 239000007788 liquid Substances 0.000 claims abstract 9
- 239000007787 solid Substances 0.000 claims abstract 9
- 229920001400 block copolymer Polymers 0.000 claims abstract 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 8
- 239000000463 material Substances 0.000 claims 6
- 239000011787 zinc oxide Substances 0.000 claims 6
- 229920000359 diblock copolymer Polymers 0.000 claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 4
- 239000005083 Zinc sulfide Substances 0.000 claims 4
- 229940088710 antibiotic agent Drugs 0.000 claims 4
- 239000003153 chemical reaction reagent Substances 0.000 claims 4
- 239000003995 emulsifying agent Substances 0.000 claims 4
- 229920006030 multiblock copolymer Polymers 0.000 claims 4
- 239000000377 silicon dioxide Substances 0.000 claims 4
- 239000004408 titanium dioxide Substances 0.000 claims 4
- 229910052984 zinc sulfide Inorganic materials 0.000 claims 4
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- 239000003814 drug Substances 0.000 claims 3
- 239000000417 fungicide Substances 0.000 claims 3
- 239000004009 herbicide Substances 0.000 claims 3
- 239000000575 pesticide Substances 0.000 claims 3
- 239000007762 w/o emulsion Substances 0.000 claims 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims 2
- 229910052582 BN Inorganic materials 0.000 claims 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- 229920000881 Modified starch Polymers 0.000 claims 2
- 229920002472 Starch Polymers 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 2
- 239000003570 air Substances 0.000 claims 2
- 150000001298 alcohols Chemical class 0.000 claims 2
- 229940035674 anesthetics Drugs 0.000 claims 2
- 239000003242 anti bacterial agent Substances 0.000 claims 2
- 230000000844 anti-bacterial effect Effects 0.000 claims 2
- -1 antibacterials Substances 0.000 claims 2
- 239000002775 capsule Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 229940079593 drug Drugs 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- 239000002360 explosive Substances 0.000 claims 2
- 239000003193 general anesthetic agent Substances 0.000 claims 2
- 239000011521 glass Substances 0.000 claims 2
- 235000011187 glycerol Nutrition 0.000 claims 2
- 239000010439 graphite Substances 0.000 claims 2
- 229910002804 graphite Inorganic materials 0.000 claims 2
- 239000004615 ingredient Substances 0.000 claims 2
- 229910010272 inorganic material Inorganic materials 0.000 claims 2
- 239000011147 inorganic material Substances 0.000 claims 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 2
- 235000013980 iron oxide Nutrition 0.000 claims 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims 2
- 239000012567 medical material Substances 0.000 claims 2
- 239000002923 metal particle Substances 0.000 claims 2
- 239000010445 mica Substances 0.000 claims 2
- 229910052618 mica group Inorganic materials 0.000 claims 2
- 239000011707 mineral Substances 0.000 claims 2
- 235000019426 modified starch Nutrition 0.000 claims 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims 2
- 150000002902 organometallic compounds Chemical class 0.000 claims 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims 2
- 239000010702 perfluoropolyether Chemical class 0.000 claims 2
- 239000013503 personal care ingredient Substances 0.000 claims 2
- 235000019271 petrolatum Nutrition 0.000 claims 2
- 239000004033 plastic Substances 0.000 claims 2
- 229920003023 plastic Polymers 0.000 claims 2
- 229920000223 polyglycerol Polymers 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 229920001296 polysiloxane Chemical class 0.000 claims 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- 239000002210 silicon-based material Chemical class 0.000 claims 2
- 239000002195 soluble material Substances 0.000 claims 2
- 239000008107 starch Substances 0.000 claims 2
- 235000019698 starch Nutrition 0.000 claims 2
- 239000004094 surface-active agent Substances 0.000 claims 2
- 239000000454 talc Substances 0.000 claims 2
- 229910052623 talc Inorganic materials 0.000 claims 2
- 239000001993 wax Substances 0.000 claims 2
- 239000004264 Petrolatum Substances 0.000 claims 1
- 239000010775 animal oil Substances 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 235000006708 antioxidants Nutrition 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 230000009969 flowable effect Effects 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 239000002480 mineral oil Substances 0.000 claims 1
- 239000007764 o/w emulsion Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 claims 1
- 229940066842 petrolatum Drugs 0.000 claims 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 claims 1
- 239000003755 preservative agent Substances 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 235000015096 spirit Nutrition 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 230000000475 sunscreen effect Effects 0.000 claims 1
- 239000000516 sunscreening agent Substances 0.000 claims 1
- 229920000428 triblock copolymer Polymers 0.000 claims 1
- 229960005486 vaccine Drugs 0.000 claims 1
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 1
- 239000008158 vegetable oil Substances 0.000 claims 1
- 229920002725 thermoplastic elastomer Polymers 0.000 abstract 1
Abstract
Hydrocarbon gels comprising from about 0.1 to about 50 percent on a weight basis of diblock, triblock, multiblock and/or radial block copolymers based on synthetic thermoplastic rubbers or mixtures, in a mixture with a hydrocarbon, one or more hydrocarbon-soluble substances, or mixtures thereof, which are useful as suspending or dispersing agents for solids and/or liquids.
Claims
1. A hydrocarbon gel composition having solids or liquids suspended or dispersed therein, said composition comprising:
(a) from about 20 to about 95 weight percent of a hydrocarbon, optionally comprising one or more hydrocarbon- soluble substances;
(b) a polymeric gel component comprising from about 0.1 to about 50 weight percent of one or more diblock copolymers, one or more triblock, radial block and/or multiblock copolymers, or a mixture thereof, comprising from about 0 to about 100 weight percent said of one or more diblock copolymer and from about 100 to about 0 weight percent of said one or more triblock, radial block and/or multiblock copolymer; and
(c) a suspended or dispersed component comprising from about 0.01 to about 75 weight percent of one or more solids and/or liquids suspended or dispersed therein, wherein said liquids are selected from the group consisting of water containing one or more water-soluble materials, glycerin, propylene glycol, butylene glycol , alcohols, acids, surfactants, emulsifiers, polyglycerols , ethers, fluorinated compounds, perfluoropolyethers, silicones, silicon- containing compounds, and mixtures thereof.
2. A gel composition according to claim 1 wherein the hydrocarbon has a vapor pressure of up to 600 mg Hg at 20 °C.
3. A gel composition according to claim 1 wherein said gelling component comprises about 0.1 to 25 weight percent of one or more triblock, radial block and/or multiblock copolymers, and from about 70 to about 99.9 weight percent of one or more diblock copolymers .
22
4. A gel composition according to claim 1 which comprises about 0.1 to 10 weight percent of one or more triblock, radial block, and/or multiblock copolymers, and from about 70 to about 99.9 weight percent of one or more diblock copolymers .
5. A gel composition according to claim 1 wherein the total weight of said polymeric gel component in said hydrocarbon is from about 0.5 to about 30 weight percent.
6. A gel composition according to claim 1 wherein said hydrocarbon is selected from the group consisting of mineral oils, mineral solvents, petrolatum, waxes, mineral spirits, synthetic hydrocarbons, animal oils, vegetable oils, and mixtures thereof .
7. A gel composition according to claim 1 which also comprises one or more hydrocarbon-soluble substances selected from the group consisting of esters, waxes, petrolatums, resins, and mixtures thereof in amounts of up to 50 weight percent, based on the total weight of the composition.
8. A gel composition according to claim 1 wherein said solid or liquid suspended therein comprises a solid and/or non-hydrocarbon oil liquid which is dispersed in said gel and remains substantially suspended or evenly dispersed therein.
9. A gel composition according to claim 8 wherein said solid or liquid comprises a member selected from the group consisting of personal care ingredient, agricultural substances and veterinary medicines .
23
10. A gel composition according to claim 9 wherein said personal care ingredient comprises pigmented makeup, sunscreens, or sunblocks.
11. A gel composition according to claim 9 wherein said agricultural substances comprises pesticides, fungicides, or herbicides.
12. A gel composition according to claim 9 wherein said veterinary medicine comprises dewormers, vaccines or other medicines.
13. A gel composition according to claim 1 which also comprises an effective amount of one or more stabilizers, preservatives, ant ioxidant s , phosphorescing substances, or colorants.
14. A gel composition according to claim 1 in the form of a soft flowable gel .
15. A gel composition according to claim 1 in the form of a stiff self-supporting gel.
16. A water-in-oil emulsion comprising a gel composition according to claim 1 and sufficient water to form said water-in-oil emulsion, and one or more emulsifying agents.
17. A water-in-oil emulsion comprising a gel composition according to claim 1 and sufficient water to form said oil-in-water emulsion, and one or more emulsifying agents.
18. A gel composition according to claim 1 wherein said polymeric gel component comprises a blend of an S-EB-S triblock copolymer and on S-EP diblock copolymer .
24
19. A gel composition according to claim 1 wherein said suspended or dispersed component is a solid selected from the group consisting of zinc oxide, coated zinc oxide, surface-treated zinc oxide, titanium dioxide, surface-treated titanium dioxide, phosphorescent substances, molybdenum oxide, zinc sulfide, copper-doped zinc sulfide, graphite, explosive materials, pesticides, herbicides, fungicides, air-sensitive chemicals or reagents, moisture- sensitive chemicals or reagents, boron nitride, iron oxides, talc, mica, plastics, polymers and polymeric materials, silica, silicon dioxide, aluminum oxide, inorganic materials, organometallic compounds, metal particles, phosphorescent or fluorescent materials, medical materials such as antibacterials, antibiotics, and anesthetics, glass, clays, gums, capsules containing various ingredients, starch, modified starches, and mixtures thereof.
20. A gel composition according to claim 1 wherein said suspended or dispersed component is a solid selected from the group consisting of zinc oxide, coated zinc oxide, surface-treated zinc oxide, titanium dioxide, surface-treated titanium dioxide, phosphorescent substances, molybdenum oxide, zinc sulfide, copper-doped zinc sulfide, graphite, explosive materials, pesticides, herbicides, fungicides, air-sensitive chemicals or reagents, moisture- sensitive chemicals or reagents, boron nitride, iron oxides, talc, mica, plastics, polymers and polymeric materials, silica, silicon dioxide, aluminum oxide, inorganic materials, organometallic compounds, metal particles, phosphorescent or fluorescent materials, medical materials such as antibacterials, antibiotics, and anesthetics, glass, clays, gums, capsules containing various ingredients, starch, modified starches, liquids selected from the group consisting of water, water containing one or more water-soluble materials, glycerin, propylene
25 glycol, butylene glycol , alcohols, acids, surfactants, emulsifiers, polyglycerols , ethers, polar esters, fluorinated compounds, perfluoropolyethers , silicones, silicon-containing compounds, and mixtures thereof, and mixtures of solids and liquids.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002283324A CA2283324C (en) | 1997-03-07 | 1998-03-02 | Hydrocarbon gels as suspending and dispersing agents and products |
| BR9808842-4A BR9808842A (en) | 1997-03-07 | 1998-03-02 | Hydrogarbon gels as suspending and dispersing agents and products |
| AU65391/98A AU734440B2 (en) | 1997-03-07 | 1998-03-02 | Hydrocarbon gels as suspending and dispersing agents and products |
| JP53863698A JP2002513436A (en) | 1997-03-07 | 1998-03-02 | Hydrocarbon gels and products as suspending and dispersing agents |
| EP98911441A EP0969805A1 (en) | 1997-03-07 | 1998-03-02 | Hydrocarbon gels as suspending and dispersing agents and products |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3381197P | 1997-03-07 | 1997-03-07 | |
| US60/033,811 | 1998-01-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO1998038981A1 WO1998038981A1 (en) | 1998-09-11 |
| WO1998038981B1 true WO1998038981B1 (en) | 1998-11-12 |
Family
ID=21872576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1998/003978 WO1998038981A1 (en) | 1997-03-07 | 1998-03-02 | Hydrocarbon gels as suspending and dispersing agents and products |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6433068B1 (en) |
| EP (2) | EP1728497B1 (en) |
| JP (1) | JP2002513436A (en) |
| KR (1) | KR20000076010A (en) |
| CN (1) | CN1329017C (en) |
| AU (1) | AU734440B2 (en) |
| BR (1) | BR9808842A (en) |
| CA (1) | CA2283324C (en) |
| WO (1) | WO1998038981A1 (en) |
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| FR3094220B1 (en) | 2019-03-29 | 2022-02-25 | Chanel Parfums Beaute | Peelable film-forming cosmetic composition |
| FR3094228B1 (en) | 2019-03-29 | 2022-04-01 | Chanel Parfums Beaute | Primer for long-lasting makeup |
| FR3094222B1 (en) | 2019-03-29 | 2021-09-10 | Chanel Parfums Beaute | Long-lasting cosmetic composition |
| FR3094226B1 (en) | 2019-03-29 | 2021-11-26 | Chanel Parfums Beaute | Long-lasting cosmetic composition |
| FR3098109B1 (en) | 2019-07-03 | 2022-02-04 | Chanel Parfums Beaute | Moisturizing solid cosmetic composition |
| FR3098110B1 (en) | 2019-07-03 | 2022-02-04 | Chanel Parfums Beaute | Solid cosmetic composition |
| FR3098108B1 (en) | 2019-07-03 | 2022-04-01 | Chanel Parfums Beaute | Long-lasting solid cosmetic composition |
| FR3098107B1 (en) | 2019-07-03 | 2022-07-29 | Chanel Parfums Beaute | Solid cosmetic composition |
| EP4003287A1 (en) | 2019-07-24 | 2022-06-01 | Shiseido Company, Ltd. | A water-in-oil emulsion with emollient and methods of using the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4164563A (en) | 1975-03-24 | 1979-08-14 | Minnesota Mining And Manufacturing Company | Non-greasy compositions |
| US4369284A (en) | 1977-03-17 | 1983-01-18 | Applied Elastomerics, Incorporated | Thermoplastic elastomer gelatinous compositions |
| US4716183A (en) | 1985-11-22 | 1987-12-29 | Raychem Corp. | Styrene-diene block copolymer compositions |
| GB8617559D0 (en) | 1986-07-18 | 1986-08-28 | Raychem Ltd | Gels |
| US5221534A (en) | 1989-04-26 | 1993-06-22 | Pennzoil Products Company | Health and beauty aid compositions |
| US5358664A (en) * | 1992-10-15 | 1994-10-25 | Caschem, Inc. | Gelled oil compositions |
| US5840338A (en) * | 1994-07-18 | 1998-11-24 | Roos; Eric J. | Loading of biologically active solutes into polymer gels |
| US5578299A (en) * | 1994-10-20 | 1996-11-26 | The Andrew Jergens Company | Rinse-off skin conditioner |
| US5558872A (en) | 1995-03-07 | 1996-09-24 | Healthpoint Medical Limited Partnership | Gelled mineral oil skin protectant |
| US5945095A (en) * | 1995-06-21 | 1999-08-31 | L'oreal | Cosmetic composition including a polymeric particle dispersion |
| WO1997008282A1 (en) * | 1995-08-29 | 1997-03-06 | Pennzoil Products Company | Transparent gel candles |
| US5749111A (en) * | 1996-02-14 | 1998-05-12 | Teksource, Lc | Gelatinous cushions with buckling columns |
| KR19990082675A (en) | 1996-02-20 | 1999-11-25 | 토레슨 조지 | Solid and Semi-Solid Hydrocarbon Gels and Their Uses |
| US5705175A (en) | 1996-02-29 | 1998-01-06 | Pennzoil Products Company | Non-aqueous controlled release insect repellent and insecticide gels |
-
1998
- 1998-01-15 US US09/007,838 patent/US6433068B1/en not_active Expired - Lifetime
- 1998-03-02 EP EP05077827A patent/EP1728497B1/en not_active Expired - Lifetime
- 1998-03-02 JP JP53863698A patent/JP2002513436A/en not_active Ceased
- 1998-03-02 EP EP98911441A patent/EP0969805A1/en not_active Ceased
- 1998-03-02 BR BR9808842-4A patent/BR9808842A/en not_active Application Discontinuation
- 1998-03-02 WO PCT/US1998/003978 patent/WO1998038981A1/en not_active Application Discontinuation
- 1998-03-02 CN CNB988039656A patent/CN1329017C/en not_active Expired - Lifetime
- 1998-03-02 KR KR1019997008096A patent/KR20000076010A/en not_active Ceased
- 1998-03-02 CA CA002283324A patent/CA2283324C/en not_active Expired - Lifetime
- 1998-03-02 AU AU65391/98A patent/AU734440B2/en not_active Ceased
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