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WO1999035698A3 - Hydrogen catalysis power cell for energy conversion systems - Google Patents

Hydrogen catalysis power cell for energy conversion systems Download PDF

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Publication number
WO1999035698A3
WO1999035698A3 PCT/US1998/022822 US9822822W WO9935698A3 WO 1999035698 A3 WO1999035698 A3 WO 1999035698A3 US 9822822 W US9822822 W US 9822822W WO 9935698 A3 WO9935698 A3 WO 9935698A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
heat
power cell
energy conversion
hydrogen catalysis
Prior art date
Application number
PCT/US1998/022822
Other languages
French (fr)
Other versions
WO1999035698A2 (en
WO1999035698A9 (en
Inventor
Randell L Mills
William R Good
James M Kendall
Original Assignee
Black Light Power Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Black Light Power Inc filed Critical Black Light Power Inc
Priority to EP98967045A priority Critical patent/EP1029380A4/en
Priority to AU36349/99A priority patent/AU734961B2/en
Priority to CA002304752A priority patent/CA2304752C/en
Publication of WO1999035698A2 publication Critical patent/WO1999035698A2/en
Publication of WO1999035698A3 publication Critical patent/WO1999035698A3/en
Publication of WO1999035698A9 publication Critical patent/WO1999035698A9/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0094—Atomic hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C1/00—Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid
    • F02C1/04—Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid the working fluid being heated indirectly
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C1/00—Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid
    • F02C1/04—Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid the working fluid being heated indirectly
    • F02C1/05—Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid the working fluid being heated indirectly characterised by the type or source of heat, e.g. using nuclear or solar energy
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F27/00—Control arrangements or safety devices specially adapted for heat-exchange or heat-transfer apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044—Temperature measurement
    • B01J2208/00061—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00415—Controlling the temperature using electric heating or cooling elements electric resistance heaters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00477—Controlling the temperature by thermal insulation means
    • B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00058—Temperature measurement
    • B01J2219/00063—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00096—Plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00132—Controlling the temperature using electric heating or cooling elements
    • B01J2219/00135—Electric resistance heaters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/0015—Controlling the temperature by thermal insulation means
    • B01J2219/00155—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00157—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

An energy conversion system is provided for generating heat based on hydrogen catalysis and for transferring the generated heat to a working fluid and utilizing the heat or converting it to mechanical or electrical energy. The energy conversion system comprises a hydrogen catalysis power cell, the power cell comprising a heat transfer assembly having at least one reaction chamber containing the means to dissociate molecular hydrogen gas to atomic hydrogen and a delivery assembly connected in fluid communication to the reaction chamber for delivering hydrogen gas and vaporous catalyst for hydrogen catalysis. The delivery assembly comprises a catalyst vessel for generating the vaporous catalyst, a source of hydrogen gas, and a semi-permeable membrane assembly connected in fluid communication with the hydrogen gas source and the heat transfer assembly. The power cell further comprises means for regulating the temperature of the catalyst vessel and means for regulating the temperature surrounding the semi-permeable membrane. An energy conversion system is also provided having a hydrogen catalysis power cell as described herein, a working fluid for receiving the heat released from hydrogen catalysis, means for converting the heat in the working fluid to mechanical or electrical energy, and preferably means to balance the heat removed by the working fluid with the energy produced by hydrogen catalysis.
PCT/US1998/022822 1997-10-29 1998-10-28 Hydrogen catalysis power cell for energy conversion systems WO1999035698A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP98967045A EP1029380A4 (en) 1997-10-29 1998-10-28 Hydrogen catalysis power cell for energy conversion systems
AU36349/99A AU734961B2 (en) 1997-10-29 1998-10-28 Hydrogen catalysis power cell for energy conversion systems
CA002304752A CA2304752C (en) 1997-10-29 1998-10-28 Hydrogen catalysis power cell for energy conversion systems

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6345197P 1997-10-29 1997-10-29
US60/063,451 1997-10-29

Publications (3)

Publication Number Publication Date
WO1999035698A2 WO1999035698A2 (en) 1999-07-15
WO1999035698A3 true WO1999035698A3 (en) 1999-09-16
WO1999035698A9 WO1999035698A9 (en) 2000-01-20

Family

ID=22049277

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/022822 WO1999035698A2 (en) 1997-10-29 1998-10-28 Hydrogen catalysis power cell for energy conversion systems

Country Status (4)

Country Link
EP (1) EP1029380A4 (en)
AU (1) AU734961B2 (en)
CA (1) CA2304752C (en)
WO (1) WO1999035698A2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7689367B2 (en) 2004-05-17 2010-03-30 Blacklight Power, Inc. Method and system of computing and rendering the nature of the excited electronic states of atoms and atomic ions
US7773656B1 (en) 2003-10-24 2010-08-10 Blacklight Power, Inc. Molecular hydrogen laser

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU577588B2 (en) * 1984-04-19 1988-09-29 Tendapak Technologies Pty. Limited Meat product and process
WO2002087291A2 (en) * 2001-03-07 2002-10-31 Blacklight Power, Inc. Microwave power cell, chemical reactor, and power converter
US7188033B2 (en) 2003-07-21 2007-03-06 Blacklight Power Incorporated Method and system of computing and rendering the nature of the chemical bond of hydrogen-type molecules and molecular ions
CN104180708B (en) * 2014-08-11 2016-03-30 无锡溥汇机械科技有限公司 A Liquid Circulation Control System Connected to Containers
CN115825763B (en) * 2023-01-10 2023-10-27 伟杰科技（苏州）有限公司 Intelligent battery monitoring system and monitoring method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4081693A (en) * 1975-07-18 1978-03-28 Stone Gordon R Vehicular propulsion system
US4761349A (en) * 1987-03-19 1988-08-02 University Of Chicago Solid oxide fuel cell with monolithic core
US5302471A (en) * 1991-04-08 1994-04-12 Sanyo Electric Co. Ltd. Compact phosphoric acid fuel cell system and operating method thereof
US5702839A (en) * 1993-11-23 1997-12-30 Johnson Matthey Public Limited Company Manufacture of electrodes
US5707762A (en) * 1993-08-24 1998-01-13 Hannelore Binsmaier Nee Gallin-Ast Modular power plant for the generation of electrical energy from solar energy

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0561967A4 (en) * 1990-12-12 1993-11-18 Randel Lee Mills Energy/matter conversion methods and structures
US5632870A (en) * 1994-05-13 1997-05-27 Kucherov; Yan R. Energy generation apparatus
JP2001523331A (en) * 1995-06-06 2001-11-20 ブラック ライト パワー インコーポレイテッド Methods and structures of lower energy hydrogen

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4081693A (en) * 1975-07-18 1978-03-28 Stone Gordon R Vehicular propulsion system
US4761349A (en) * 1987-03-19 1988-08-02 University Of Chicago Solid oxide fuel cell with monolithic core
US5302471A (en) * 1991-04-08 1994-04-12 Sanyo Electric Co. Ltd. Compact phosphoric acid fuel cell system and operating method thereof
US5707762A (en) * 1993-08-24 1998-01-13 Hannelore Binsmaier Nee Gallin-Ast Modular power plant for the generation of electrical energy from solar energy
US5702839A (en) * 1993-11-23 1997-12-30 Johnson Matthey Public Limited Company Manufacture of electrodes

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1029380A4 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7773656B1 (en) 2003-10-24 2010-08-10 Blacklight Power, Inc. Molecular hydrogen laser
US7689367B2 (en) 2004-05-17 2010-03-30 Blacklight Power, Inc. Method and system of computing and rendering the nature of the excited electronic states of atoms and atomic ions

Also Published As

Publication number Publication date
AU3634999A (en) 1999-07-26
WO1999035698A2 (en) 1999-07-15
CA2304752A1 (en) 1999-07-15
AU734961B2 (en) 2001-06-28
WO1999035698A9 (en) 2000-01-20
EP1029380A4 (en) 2007-10-17
CA2304752C (en) 2009-07-14
EP1029380A2 (en) 2000-08-23

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