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WO2000067709A2 - Compositions coiffantes permettant d'augmenter le volume des cheveux et d'ameliorer leur maintien - Google Patents

Compositions coiffantes permettant d'augmenter le volume des cheveux et d'ameliorer leur maintien Download PDF

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Publication number
WO2000067709A2
WO2000067709A2 PCT/US2000/003910 US0003910W WO0067709A2 WO 2000067709 A2 WO2000067709 A2 WO 2000067709A2 US 0003910 W US0003910 W US 0003910W WO 0067709 A2 WO0067709 A2 WO 0067709A2
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WO
WIPO (PCT)
Prior art keywords
composition
peg
hair
wherem
han
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Application number
PCT/US2000/003910
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English (en)
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WO2000067709A3 (fr
Inventor
Raymond Edward Bolich, Jr.
Jean Patterson Dalhover
Kenneth Wayne Rigney
Alic Anthony Scott
David Michael Stentz
Original Assignee
The Procter & Gamble Company
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Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to AU32328/00A priority Critical patent/AU3232800A/en
Publication of WO2000067709A2 publication Critical patent/WO2000067709A2/fr
Publication of WO2000067709A3 publication Critical patent/WO2000067709A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/90—Block copolymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present mvention relates to hair stylmg compositions which provide improved hair volume and hair hold performance.
  • the present mvention relates to hair stylmg compositions which leave a polyalkylene glycol-containing residue on dry hair that provides for a DRY HAIR INDEX of at least 242
  • Hair stylmg compositions are well known and are commercially available m a variety of forms mcludmg mousses, gels, lotions, pumps, or hairsprays Many of these products contain various hair styling agents to provide temporary hair stylmg benefits such as body, hold, luster, improved hair feel, and good style retention.
  • hairsprays have become especially popular among consumers as an effective means for stylmg or "setting" the hair
  • the hairspray compositions typically comp ⁇ se gums or resms stylmg agents to provide for good style retention and hair feel benefits
  • Most of the hairsprays, however, are sprayed onto the hair after the hair is styled m order to temporarily secure the desired hair style
  • One method of providing temporary hair stylmg benefits from a stylmg product while stylmg the hair involves the use of a hair mousse.
  • Many hair mousse products have been formulated such that the hair mousse composition can be applied to wet or damp hair before stylmg or "setting" the hair.
  • the hair mousse compositions are aqueous formulations which contam water-soluble stylmg agents that provide adhesive properties to the hair while the hair is wet and bemg styled.
  • These stylmg agents can form hard breakable films on the hair as the stylmg process is near completion, and this can result m an unacceptable hair style or m a hair style that cannot be restyled unless additional water and/or supplemental stylmg products are added to the hair.
  • the use of aqueous hair mousse compositions which contam water-soluble stylmg agents can leave the hair feelmg unduly sticky and stiff
  • these aqueous hair mousse compositions are effective in providing good hair styling performance and improved hair feel, they are also typically applied to wet or damp hair, and often lead to the application of an additional styling product once the hair has dried m order to achieve the desired final hairstyle form
  • aqueous aerosol hair mousse composition that provides good hair stylmg performance and improved hair feel
  • These hair mousse compositions are also typically applied to wet or damp han to achieve the desired hair conditioning benefits and generally require reapp cation of the composition or another stylmg product to maintain or modify the original hairstyle
  • hair stylmg compositions which provide for a desired hair style to be achieved and maintained, and which can be applied or sprayed on the hair dunng the stylmg process
  • a recent method of making a hair styling composition that can be applied to wet and/or dry hair during the styling process, and provide unproved stylmg performance is described m JP 8-346608, published June 23, 1998
  • the hair stylmg compositions disclosed m this publication contam polyalkylene glyceryl ethers stylmg agents to provide for sustamed hair stylmg performance and improved aesthetics such as longer moisture and luster to the hair.
  • polyalkylene glyceryl ether stylmg agents typically do not readily penetrate into the hair and can remain on the hair fibers to provide the improved hair stylmg benefits
  • the polyalkylene glyceryl ether containing compositions disclosed in this particular publication tend to provide minimal or no hold to the hair, and this can result m poor style achievement and poor style retention performance
  • compositions disclosed m this publication use certam stylmg agents which deliver hair style performance to dry hair, and provide for the dry hair to be restyled without havmg to reapply the composition and without requiring the use of another stylmg product
  • the stylmg agents descnbed in this reference m include amomc, catiomc, amphotenc, and noniomc stylmg polymers, preferably sulfonated amomc stylmg polymers which have an average molecular weight of from about 500 to about 5,000,000
  • These stylmg agents however, have exceptional cohesive strength which provides for the hair fibers to be firmly held together, and this can cause the dry hair to feel coarse and be difficult to comb, style, and restyle
  • hair stylmg compositions particularly aerosol hair styling compositions
  • these aerosol hair styling compositions compnse low molecular weight polyalkylene glycol stylmg agents that are liquids or semisolids under ambient conditions and that can remain as a liquid or semisolid after the compositions have been applied and allowed to dry on the hair
  • the ability of these select polyalkylene glycol stylmg agents to remain as a liquid or semisolid provides for improved dry hair aesthetics such as smooth and easily styled hair in addition to the improved restyhng performance
  • hair styling compositions, especially aqueous hair styling compositions which comprise select low molecular weight polyalkylene glycol styling agents can provide not only unproved dry hair feel and stylmg performance, but also provide for improved hair volume and hair hold performance
  • These compositions provide certam properties as defined by a DRY HAIR INDEX and are particularly useful for providing supenor hair volume and hair hold performance
  • the hair styling compositions of the present mvention when evaluated on dry hair, provides for the dry hair
  • aqueous hair styling composition which provides improved hair volume and hair hold performance, and which leaves a polyalkylene glycol- containing residue on dry hair that provides for a DRY HAIR INDEX of at least 242
  • a non-aqueous hair stylmg composition which provides unproved hair volume and hair hold performance, and which leaves a polyalkylene glycol-containing residue on dry hair that provides for a DRY HAIR INDEX of at least 266
  • a hair stylmg composition m the form of a hair mousse which provides improved hair volume and hair hold performance, and which leaves a polyalkylene glycol-containing residue on dry hair that provides for a DRY HAIR INDEX of at least 242
  • a hair styling composition which provides for a DRY HAIR INDEX of at least 242, and further which provides for improved dry hair restyling performance
  • the present mvention is directed to aqueous hair styling compositions which comprise (a) from about 12% to about 90% by weight of a polyalkylene glycol that is substantially free of polyalkylene glyceryl ethers and that has a number average molecular weight of from about 190 to about 1500 and from about 5 to about 35 repeating alkylene oxide radicals wherem each of the repeating alkylene oxide radicals has from 2 to 6 carbon atoms, and (b) from about 1% to about 88% by weight of water, wherem after application and drying of the composition on dry hair the composition provides for a DRY HAIR INDEX ol at least 242
  • the present mvention is also directed to non-aqueous hair stylmg compositions which comprise from about 12% to about 90% by weight of a polyalkylene glycol that is substantially free of polyalkylene glyceryl ethers and that has a number average molecular weight of from about 190 to about 1500 and from about 5 to about 35 repeating alkylene oxide radical
  • the present mvention is also directed to a hair mousse composition which comprises from about 12% to about 90% by weight of a polyalkylene glycol that is substantially free of polyalkylene glyceryl ethers and that has a number average molecular weight of from about 190 to about 1500 and from about 5 to about 35 repeatmg alkylene oxide radicals wherein each of the repeating alkylene oxide radicals has from 2 to 6 carbon atoms; and (b) from about 1% to about 88% by weight of a liquid carrier; wherein after application and drying of the composition on dry hair the composition provides for a DRY HAIR INDEX of at least 242.
  • the present mvention is also directed to hair stylmg compositions which compose (a) from about 65% to about 99% by weight of a polyalkylene glycol that is substantially free of polyalkylene glyceryl ethers and that has a number average molecular weight of from about 190 to about 1500 and from about 5 to about 35 repeatmg alkylene oxide radicals wherem each of the repeatmg alkylene oxide radicals has from 2 to 6 carbon atoms; and (b) from about 1% to about 30% by weight of a liquid earner; wherem after application and drying of the composition on dry hair the composition provides for a DRY HAIR INDEX of at least 242.
  • hair stylmg compositions which compnse select low molecular weight polyalkylene glycol styling agents can provide for improved hair volume and hair hold performance.
  • compositions of the present invention compnse select polyal-kylene glycols that can be deposited on the hair and form reformable welds on the hair fibers which provide for improved hair volume and hair hold performance. These compositions are intended for application to dry hair, and are preferably formulated as leave-on hair stylmg products
  • leave-on refers to compositions that contam ingredients that are intended to be deposited and left on the hair for extended periods (e g, several hours or days) until the mgredients are subsequently removed by water and/or by shampooing the hair
  • reducible weld refers to residues which are left on dry hair and which contain materials that are liquid or semisolid at ambient condition, and that can remain as a liquid or semisolid after the compositions descnbed herem have been applied and allowed to dry on the hair
  • ambient conditions refers to surrounding conditions at about one atmosphere of pressure, at about 50% relative humidity, and at about 25°C
  • compositions of the present invention refers to preferred negative limitations of the compositions of the present invention, and are directed to the amount and concentration of polyalkylene glyceryl ether stylmg agents, or denvatives thereof, in the compositions
  • substantially free means that the compositions preferably contain less than an effective amount of such agents when used alone to provide any hair stylmg performance when the compositions are applied to the han
  • the negative limitations pertain only to those polyalkylene glyceryl ether styling agents which are also a liquid or semisolid under ambient conditions, and which are not sihcone-contaming materials
  • the compositions preferably contain less than 5%, more preferably less than 2%.
  • compositions of the present invention can comprise, consist of, or consist essentially of the essential elements and limitations of the invention descnbed herem, as well as any of the additional or optional ingredients, components, or limitations descnbed herem
  • the hair stylmg compositions of the present invention compnse a liquid or semisolid hair styling agent suitable for bemg left on dry hair as a liquid or semisolid after the composition has been applied and allowed to dry on the hair.
  • These hair stylmg agents provide for a fluid film to be left on the hair which can be characterized as a reformable weld that provides improved hair volume and hair hold performance
  • the concentration of the stylmg agent may vary with each selected hair stylmg formulation, but such concentrations will generally range from about 12% to about 90%, preferably from about 12% to about 75%, more preferably from about 15% to about 50%, even more preferably from about 15% to about 25%, by weight of the composition.
  • concentration of the stylmg agent preferably ranges from about 65% to about 99%, more preferably from about 65% to about 95%, even more preferably from about 65% to about 90%, by weight of the composition.
  • Suitable stylmg agents for use m the hair styling compositions of the present mvention include an> known or otherwise effective hair stylmg agents, other than polyalkylene glyceryl ethers, that are liquids or semisohds under ambient conditions and that can remain a liquid or semisolid after the composition has been applied and allowed to dry on dry hair It has been found that certain liquid or semisolid styling agents, particularly low molecular weight polyalkylene glycols, can provide for a fluid film to be left on the hair that provides for improved dry hair feel properties, and improved hair volume and hair hold performance
  • Nonlimitmg examples of stylmg agents suitable for use in the hair styling compositions of the present mvention include polyalkylene glycols, polyethylene/polypropylene glycol copolymers. polyethylene/polypropylene diol copolymers, polyglycenns, and mixtures thereof, and/or their derivatives, and or mixtures thereof, excludmg the polyalkylene glyceryl ethers which are also liquids or semisohds under ambient conditions.
  • Prefened styling agents suitable for use herein include those polyalkylene glycols which conform to the formula
  • R is selected from the group consistmg of H, methyl, and mixtures thereof
  • these matenals are polymers of ethylene oxide, which are also known as polyethylene oxides, polyoxyethylenes, and polyethylene glycols
  • these materials are polymers of propylene oxide, which are also known as polypropylene oxides, polyoxypropylenes, and polypropylene glycols
  • R is methyl
  • n has an average value of from 4 to about 35, preferably from about 5 to about 35, more preferably from about 5 to about 30, and even more preferably from about 5 to about 20
  • preferred polyalkylene glycol polymers mclude polyethylene/polypropylene glycol copolymers (e.g., methoxy, ethoxy, propoxy, butoxy, and pentoxy, polyethylene/polypropylene glycols), t ⁇ glycenn, hexaglycenn, PPG-4, PPG-6, PEG-5, PEG-6, PEG-8, PEG-12, PEG-14, PEG-18, PEG- 20, PEG-32, and mixtures thereof.
  • polyethylene/polypropylene glycol copolymers e.g., methoxy, ethoxy, propoxy, butoxy, and pentoxy, polyethylene/polypropylene glycols
  • t ⁇ glycenn e.g., methoxy, ethoxy, propoxy, butoxy, and pentoxy, polyethylene/polypropylene glycols
  • t ⁇ glycenn e.g., methoxy, ethoxy,
  • polyalkylene glycols which have a number average molecular weight of from about 190 to about 1500, preferably from about 300 to about 1200, more preferably from about 400 to about 1000; and from about 5 to about 35, preferably from about 5 to about 30, more preferably from about 5 to about 20, repeatmg alkylene oxide radicals wherem each of the repeating alkylene oxide radicals has from 2 to 6 carbon atoms
  • PPG-4 wherem R equals methyl and n has an average value of about 4
  • PEG-8 wherem R equals H and n has an average value of about 8
  • PEG-12 wherem R equals H and n has an average value ot about 12
  • PEG-12 is also known as Carbowax 600, which is available from Umon Carbide
  • PEG-20 wherem R equals H and n has an average value
  • the hair stylmg compositions of the present invention may further comprise one or more optional styling polymers which can help provide improved initial hair hold performance.
  • the total concentration of such optional styling polymers ranges from about 0.25% to about 5%, preferably from about 0.5% to about 2 5%, by weight of the compositions
  • Optional stylmg polymers for use m combmation with the stylmg agent defined herein mclude any known or otherwise effective stylmg polymer, provided that the optional styling polymer is soluble in the liquid carrier descnbed herem which contams the optional stylmg polymer and stylmg agent, and provided that under test conditions of 27°C and 15% relative humidity the optional stylmg polymer is insoluble in the residue described herein and can form a solid film that is surrounded by the styling agent material after evaporation of the liquid carrier and any other volatile materials contained in the hair styling compositions of the present invention.
  • Such optional styling polymers include, but are not limited to, polysaccha ⁇ de styling polymers.
  • suitable polysaccha ⁇ de stylmg polymers mclude amomc polysacchandes, catiomc polysacchandes, and glucosamine polysaccha ⁇ de derivatives.
  • the glucosam-ine polysacchande derivatives are the preferred optional stylmg polymers.
  • Suitable optional catiomc polysacchande stylmg polymers for use herem m include, but are not limited to, copolymers of hydroxyethylcellulose and diallyldimethyl ammomum chlonde (referred to m the mdustry by CTFA as Polyquatermum-4) such as those commercially available from National Starch (B ⁇ dgewater, New Jersey) under the CELQUAT tradename (e g , CELQUAT L-200 and CELQUAT H- 100); and catiomc quaternary ammonium-containing polymers, mcludmg, for example, homopolymers of hydroxyethyl cellulose reacted with a tnmethyl ammomum substituted epoxide, (referred to m the mdustry by CTFA as Polyquatern ⁇ um-10) such as those commercially available from Amerchol Corp.
  • Optional preferred polysacchande stylmg polymers for use in combmation with the styling agent m the hair stylmg compositions of the present mvention m clude those polysacchande stylmg polymers which are derived from chitm, a glucosamine polysacchande that is extracted from the shells of crabs, lobsters, and the like.
  • chitin to make a chitm denvative for use in the compositions herein is the preparation of Chitosan, a water-soluble chitm denvative that is prepared by the known process of deacylation of the chitm compound.
  • the chitm denvatives can also be prepared by other methods well known m the art for the preparation of such matenals, mcludmg the hydroxypropylation of the chitm compound.
  • the chitm denvatives suitable for use as an optional stylmg polymer herem m clude those chitm denvatives which are commercially available m a neutralized or unneutralized form.
  • suitable neutralizing agents include, but are not limited to, lactic acid, pyrrohdone carboxylic acid, and glycohc acid.
  • suitable neutralizing agents include, but are not limited to, lactic acid, pyrrohdone carboxylic acid, and glycohc acid.
  • Specific examples of preferred chitin derivatives for use as an optional styling polymer include, but are not limited to, Kytamer L and Kytamer PC (both are neutralized Chitosan materials commercially available from the Amerchol Corp , located m Edison, New Jersey), and Hydagen HCMF molecular weight (MW) of 50,000 to 1,000,000, Hydagen DCMF MW of 300,000 to 2,000,000, and Hydagen CMFP MW of 500,000 to 5,000,000 ( all are unneutralized Chitosan materials commercially available from the Henkel Corp , located in Hoboken, New Jersey) Kytamer L is the most prefened chitin derivative
  • the total concentration of the liquid carrier m the composition will vary with the type of liquid carrier selected, the type of styling agent used m combination with the liquid earner, and the solubility of the selected styling agent m the selected liquid carrier, and so forth Preferred total concentration of the liquid carrier ranges from about 1% to about 88%, preferably from about 3% to about 88%, more preferably from about 5% to about 85%, by weight of the composition.
  • Suitable liquid earners for use m the hair stylmg compositions of the present mvention include volatile liquid carrier matenals.
  • volatile refers to matenals which have a boilmg pomt of less than about 260°C, preferably from about 50°C to about 260°C, more preferably from about 60° C to about 200°C (at about one atmosphere of pressure)
  • Nonlrmitmg examples of volatile liquid carriers include water, orgamc solvents such as C r C 6 alkanols, carbitol, and acetone; and combmations thereof
  • suitable C r C 6 alkanols include, but are not limited to, ethanol, n-propanol, isopropanol, n-butanol, amyl alcohol, and mixtures thereof
  • Preferred C r C 6 alkanols m clude C 2 -C 4 monohydnc alcohols such as ethanol, isopropanol, and mixtures thereof
  • water is preferably mcluded at concentrations of from about 40% to about 88%, more preferably from about 50% to about 88%, even more preferably from about 60% to about 88%, and the C,-C 6 alkanols are preferably mcluded at total concentrations of from about 1% to about 15%, more preferably from about 3% to about 15%, even more preferably from about 5% to about 10%, by weight of the composition.
  • the hair stylmg compositions of the present invention when evaluated on dry hair, provide for specific hair volume and hair hold values as defined by the DRY HAIR INDEX which is determined as described hereinbelow It has been found that hair stylmg compositions which exhibit the DRY HAIR INDEX properties defined herem are especially effective in providing unproved hair volume and hair hold performance
  • the hair stylmg compositions of the present invention are characterized by providing for a DRY HAIR INDEX of at least 242, preferably from 242 to about 600, more preferably from 266 to about 600, and even more preferably from 280 to about 600
  • the DRY HAIR INDEX as described above can be determined or otherwise characterized, when the compositions of the present invention are evaluated on dry hair, by the following expressions
  • the Hair Volume Index is defined as the mean hair volume value for each test product mdexed to three controls
  • the term "mdexed” means that dry hair switches which have been treated with a han stylmg composition of the present mvention are visually evaluated for hair volume usmg a scale of 0 to 10, based on the visual reference of three control dry hair switches which are assigned respective hair volume values of 0, 5, and 10
  • the three control switches which are used as visual reference switches in the procedure for determining the Hair Volume Index m include (1) an untreated dry hair switch with an assigned hair volume value of 0, (2) a dry hair switch which has been treated with Control Product A (descnbed m detail heremafter), and which has an assigned hair volume value of 5, and (3) a dry hair switch which has been treated with Control Product B (descnbed m detail heremafter), and which has an assigned hair volume value of 10
  • the Han Hold Index is predicted by measuring the hair hold values of dry hair switches which have been treated with the hair stylmg compositions of the present mvention, and indexing these measured values to that of two control dry han switches which are assigned respective hair hold values of 0 and 100
  • the two control switches which are used m the procedure for determimng the Hair Hold Index m include (1) a dry hair switch which has been treated with Control Product A (descnbed m detail heremafter), and which has an assigned hair hold value of 100, and (2) a dry han switch which has been treated with Control Product B (descnbed m detail heremafter), and which has an assigned hair hold value of 0.
  • Control shampoo product In preparation for control and test product application on hair switches which are used in the procedure for the determination of the Hair Volume Index, the hair switches are pre-treated with a control shampoo product After treatment with the control shampoo product, and before application of the control or test product, the hair switches are allowed to dry in a temperature/humidity control room having 24°C/50% relative humidity (heremafter RH)
  • the control shampoo product is prepared usmg conventional formulation and mixing techniques for formulating shampoo compositions
  • the control shampoo product has the following formulation
  • the treatment process for application of the control shampoo product on the hair switches mclude wetting the han switches with tap water for 30 seconds, followed by applying 2 0 cc of the control shampoo product to each han switch
  • the han switches are then lathered for 30 seconds, followed by nnsmg each han switch with tap water for 60 seconds
  • the excess water is squeezed from each hair switch by running the mdex and middle fingers along the length of the switch with firm pressure
  • the han switches are then combed through once with a beautician's comb
  • the han switches are then dried by hanging the switches m a hot box for 3 hours at 60°C
  • the dry han switches are then hung on a bar m a 24°C/50% RH control room
  • a total of ten switches are treated in preparation for application of the control and suitable test product formulations which are used in the procedure for the determination of the Han Volume Index Additionally, all water used to rinse the shampoo control product, the control products, and any test products from the han
  • Control hair styling products The following han stylmg formulations are used as the control products which are applied to the han switches referred to herem as the control dry han switches.
  • the control dry han switches are used as the reference switches m the evaluation procedures for determining the Han Volume Index and Hair Hold Index values
  • control han -stylmg products are each prepared by combining all of the respective listed components, except the propellant, and mixing the combination for 40 mmutes to ensure a homogenous composition.
  • the resultant homogenous liquid mixmre is then filled mto an aerosol contamer, and the propellant is added.
  • the control dry han switches are treated with 6 grams of the respective control product.
  • the control dry han switches are treated with 1.13 grams of the respective control product.
  • the control han styling products have the following formulations:
  • the hair volume value of a dry han switch which is used in the determination of the Han Volume Index, is determined by having panelists visually evaluate a dry han switch which has been treated with a composition of the present invention for hair volume attribute usmg a scale of 0 to 10, wherein 0 is "most volume” and 10 is "least volume "
  • the dry hair switches are evaluated by visually comparing the volume attribute of each switch relative to three control switches which have been assigned a hair volume value of 0, 5, or 10
  • the dry hair control switch which has been untreated is identified as the visual control for each volume attribute with an assigned value of 0
  • the dry hair control switch which has been treated with Control Product A is identified as the visual control for each volume attnbute with an assigned value of 5
  • the dry hair control switch which has been treated with Control Product B is identified as the visual control for each volume attribute with an assigned value of 10
  • the dry han switches used in the procedure for the determination of the Han Volume Index are 60 gram/25 4 centimeters (cm) long Asian ponytail han switches supplied by Advanced Testing Laboratories located in Cincinnati, Ohio
  • the switches are kept hanging on a bar in a temperature/humidity control room havmg 24°C/50% RH
  • 6 grams of the test product are applied to each switch
  • a preferred han mousse embodiment of the present mvention has a solids content of 23%, and that 6 grams of this hair mousse formulation was sufficient to provide complete even distnbution of the product throughout the switch m the determination of han volume values
  • the gram amount of hair stylmg compositions in the form of non-mousse products that is applied to each switch is determined usmg the following procedure ( 1 ) determine the percent solids of the test product by usmg a method well known m the art for making such percent solids determinations, (2) divide 23% by the determined percent solids value, and then multiply this resulting value by 6 grams (the final value equals the gram amount of product that is applied to the hair switch), and
  • Each panelist visually evaluates seven test product treated dry han switches relative to the three control dry han switches that are used as visual references
  • Two of the seven test product treated dry hair switches are control switches which have been mcluded in the evaluation as test product treated han switches
  • the three reference control han switches are hung above the test product treated hair switches to establish an easily accessible reference pomt for the panelist
  • the control dry han switches which are mcluded as test product treated switches must be evaluated such that the volume attnbute is assigned a value that corresponds with that of the identical reference control switch
  • the test product treated dry han switch has been treated with Control Product A (assigned volume value of 5)
  • this switch must be evaluated such that the volume attnbute is assigned a value of 4 to 6
  • the cntena that this test product treated switch hair volume value is from 4 to 6 ensures that the hair volume values for this switch, and other switches evaluated along with this switch, are evaluated under intended test conditions
  • a minimum of eight panelists evaluate the test product treated dry han switches The panelists are instructed to stand approximately six feet away from the bar on which the han switches are hung, and to evaluate only the middle 50% portion of the han switches to avoid any bias associated with the shoulder slope and/or flip end portions of the han switches.
  • the panelists record the han volume values on the test ballot
  • a total of seven dry han switches are evaluated by each panelist, one switch for each test product mcludmg the control switches that are evaluated as a test product treated dry han switch Therefore, a total of five different compositions of the present mvention can be evaluated m a given evaluation procedure, resultmg m at least eight han volume values bemg obtamed for each treated dry han switch
  • the mean hair volume value for dry ha-ir switches that have been treated with a test product is determined by averaging scores from all of the panelists for each test product treated dry hair switch
  • the Hair Volume Index is defined as the mean han volume value for each test product treated dry han switch as visually indexed to reference control switches usmg the assigned volume values of 0, 5, and 10 for the controls
  • the mean han volume value, or Han Volume Index is determined usmg the statistical method as set forth in the Multifactor ANOVA Test Method d. Hair Hold Index:
  • the han hold value of a treated dry han switch which is used m the determination of the Hair Hold Index, is determined by treating the han switch with a composition of the present invention, setting the hair switch in a hair style usmg an A-Frame apparatus, shakmg the han switch to disrupt the A-Frame hair style, and measunng the remaining A-Frame hair style using a Mitutoyo CD-8C digital cahper instrument commercially available from Mitutoyo LTD located m Japan
  • Two control dry han switches are analyzed along with the test product treated dry han switches A dry han switch which has been treated with Control Product A is identified as the control for a dry han switch that has an assigned han hold value of 100, and a dry han switch which has been treated with Control Product B is identified as the control for a dry han switch that has an assigned value of 0
  • A-Frame refers to a 45° angled apparatus that is 76 2cm long, 25 4cm tall, and that is made of a non-porous mate ⁇ al such as plexiglas
  • Other "A-Frame” han stylmg apparatus can be used provided that the apparatus are made of a non-porous matenal
  • the dry han switches used m the procedure for the determination of the Han Hold Index are 10 gram han switches which are 22 9 cm long, flat, European vngm han switches supplied by Advanced Testmg Laborato ⁇ es located m Cincinnati, Ohio Each han switch is approximately 4 8 cm wide and 0 013 cm thick
  • the switches are kept overnight hanging on a bar in a temperature/humidity control room havmg 24°C/50% RH
  • han stylmg compositions in the form of a han mousse product 1 13 grams of the test product are applied to each switch It has been found that a preferred han mousse embodiment of the present mvention has a solids content of 23%, and that 1 13 grams of this han mousse formulation was sufficient to provide complete even distribution of the product throughout the switch m the determination of han hold values
  • the gram amount of han stylmg compositions m the form of non-mousse products that is applied to each switch is determined usmg the following procedure ( 1 ) determine the percent solids of the test product by usmg a method well known m the art for making such percent solids determinations, (2) divide 23% by the determined percent solid value, and then multiply this resultmg value by 1 13 grams (the final value equals the gram amount of product that is applied to the hair
  • Test product, and the control products are applied to the han switches m the 24°C/50% RH control room
  • the appropriate amount of tap water, if applicable, is applied to each hair switch followed by application of the appropriate amount of test or control product
  • the test or control product is applied to each han switch by splitting the gram amount of product in half, and applymg each half-product portion along the workable hair area of each side of the switch
  • workable han refers to all han which is between the lowest end of plexiglas materials holding the han and 3 8 cm above the bottom of the han switch
  • the han switches are held between two pieces of plexiglas materials by using adhesive material such as epoxy glue
  • Suitable plexiglas materials include those plexiglas matenals which are 2 6 cm long, 7 75 cm wide, and 0 15 cm thick
  • the product half-portions are applied by patting and or stroking with constant pressure up and down the workable area of both sides of each han switch
  • Each hair switch is then massaged or milked for 10 seconds such that the test or control product is distributed evenly throughout the switch
  • Each han switch is then lightly stroked once by positioning the switch between the index and middle fingers, and running the mdex and middle fingers once along the workable area of the switch with constant pressure
  • Each han switch is then divided m 2 equal sections, and hung on the A-Frame descnbed heremabove, such that one-half of the switch is rested on the left side of the A-Frame and one-half of the switch is rested on the nght side of the A-Frame
  • the han switches, while positioned on the A-Frame as described above are allowed to dry for 3 hours m the 24°C/50% RH control room Once drying is complete, each dry hair switch is prepared for han hold measurements
  • each hair switch is placed on a suitable wnst action shaker such as the Burrell Model 75 (commercially available from VWR Scientific) to disrupt then A- Frame han style
  • the han switches are placed on the shaker such that the top of the switches is placed in a three-finger clamp that is perpendicular to the shaker arm, to establish vertical hangmg of the switches
  • the han switches are allowed to shake for 15 mmutes
  • the han switches are hung vertically using a "C" clamp While still m the A-Frame han style, the half-sections of each switch are simultaneously stroked once by wrapping the hands around each half-section and running the hands with constant pressure once from the lowest end of the clamp holdmg the switch to the end of the switch Each switch half-section is then slowly released and allowed to freely move
  • Each switch han style, which was created by the A-Frame, is then measured for hair hold usmg the Mitutoyo CD-8C digital cahper descnbed hereinbefore
  • the han hold measurement is taken on the area between the inner edge of each switch half-section by measuring the horizontal distance that is located 3 8 cm above the bottom of each inner edge
  • the honzontal distance measurement is taken to the nearest millimeter usmg the Mitutoyo CD-8C digital cahper
  • a set consisting of five han switches are tested for each test or control product A total of ten different compositions can be evaluated in a given evaluation procedure, eight test products and
  • the hair stylmg compositions of the present invention preferably mclude aerosol han styling embodiments, especially han mousse embodiments
  • the aerosol han stylmg compositions of the present mvention compnse the stylmg agent and liquid earner descnbed herem, and further compnse a propellant suitable for aerosol delivery of the composition to the desned application surface
  • the total concentration of the propellant in the aerosol han stylmg composition can include one or more propellants, the total propellant concentration typically ranging from about 5% to about 40%, preferably from about 5% to about 25%, more preferably from about 5% to about 15%, by weight of the composition.
  • Nonlimiting examples of suitable propellants mclude hydrocarbons, nitrogen, carbon dioxide, mtrous oxide, atmosphenc gas, 1,2-difluoroethane (Hydrofluorocarbon 152A) supplied as Dymel 152A by Dupont, d methylether, and mixtures thereof.
  • hydrocarbon propellants specific examples of which mclude propane, butane, and isobutane.
  • hydrocarbon propellant containing a mixture of propane and isobutane specific examples of which mclude Aeron A-46 and Aeron A-70 (both are commercially available from Diversified CPC)
  • the han stylmg compositions of the present mvention may further compnse one or more optional components known or otherwise effective for use m han care or personal care products, provided that the optional components are physically and chemically compatible with the essential components descnbed herem, or do not otherwise unduly impan product stability, aesthetics, or performance.
  • optional components are disclosed in International Cosmetic Ingredient Dictionary, Fifth Edition, 1993, and CTFA Cosmetic Ingredient Handbook, Second Edition, 1992, both of which are incorporated by reference herem m their entirety.
  • Optional Gelling Agent The han stylmg compositions of the present invention preferably further compnse a gelling agent to help provide the desired viscosity to the residue which remains on the hair after the composition has been applied and allowed to dry on the hair
  • the preferred optional gelling agent also helps to provide for unproved han hold performance.
  • Suitable optional gelling agents mclude any material known or otherwise effective m providmg any gelling or measurable viscosity increase to the residue
  • concentrations of the optional gelling agent m the compositions range from about 0 1% to about 10%, preferably from about 0.2% to about 5 0%, by weight of the compositions
  • Nonlimiting examples of suitable optional gelling agents mclude crosslinked carboxylic acid polymers, unneutralized crosslinked carboxylic acid polymers, unneutralized modified crosslinked carboxylic acid polymers, crosslinked ethylene/maleic anhydride copolymers, unneutralized crosslinked ethylene/maleic anhydride copolymers (e g , EMA 81 commercially available from Monsanto), unneutralized crosslinked allyl ether/acrylate copolymers (e g , Salcare SC90 commercially available from Allied Colloids); unneutralized crosslinked copolymers of sodium polyacrylate, mineral oil, and PPG-1 tndeceth-6 (e.g., Salcare SC91 commercially available from Allied Colloids); unneutralized crosslinked copolymers of methyl vmyl ether and maleic anhydride (e g , Stabileze QM-PVM/MA copolymer commercially available from International Specialty Products), hydrophobically modified nomomc cellulose polymers
  • Preferred optional gelling agents mclude water-soluble unneutralized crosslinked ethylene/maleic anhydride copolymers, water-soluble unneutralized crosslinked carboxylic acid polymers, and water-soluble hydrophobically modified nomomc cellulose polymers
  • the crosslinked carboxylic acid polymers and hydrophobically modified nomomc cellulose polymers are descnbed m detail herembelow Carboxylic Acid Polymers
  • the optional carboxylic acid polymers suitable for use herem are those crosslinked compounds containing one or more monomers denved from acrylic acid, substituted acrylic acids, esters of acrylic acid, esters of substituted acrylic acids, corresponding salts thereof, and combmations thereof, wherem the crosslinking agent contains two or more carbon-carbon double bonds and is denved from a polyhydnc alcohol
  • these carboxylic acid polymers mclude crosslinked carboxylic acid homopolymers and crosslinked carboxylic acid copolymers Combmations of these two types of polymers are also useful herem.
  • substituted refers to chemical moieties known or otherwise effective for attachment to gelling agents or other compounds.
  • substituents m clude those listed and descnbed m C Hansch and A. Leo, Substituent Constants for Correlation Analysis in Chemistry and Biology (1979), which listing and descnption are incorporated herem by reference Examples of such substituents mclude, but are not limited to, alkyl, alkenyl, alkoxy, hydroxy, oxo, nitro, amino, aminoalkyl (e g , armnomethyl, etc ), cyano, halo, carboxy, alkoxyaceyl (e g , carboethoxy, etc ), thiol, aryl, cycloalkyl, heteroaryl, heterocycloalkyl (e g , pipe ⁇ dinyl, morpholinyl, pyrrohdinyl, etc ), umno, thioxo, hydroxyal
  • Preferred first monomers include acrylic acid, methacrylic acid, and ethacry c acid, C1.4 alcohol acrylate esters, C1.4 alcohol methacrylate esters, C1.4 alcohol ethacrylate esters, and mixtures thereof, with acrylic acid, methacrylic acid, C1.4 alcohol acrylate esters, C1.4 alcohol methacrylate esters, and mixtures thereof being the most preferred
  • Preferred second monomers include Cg_4o alkyl acrylate esters, with C 10-30 alkyl acrylate esters bemg the most preferred
  • the preferred crosslinked carboxv c acid copolymers mclude those copolymers which have a first monomer selected from the group consistmg of acrylic acid, methacrylic acid, C1.4 alcohol acrylate esters, C ⁇ _ 4 alcohol methacrylate esters, and mixtures thereof, and a CI Q_3O alkyl acrylate ester second monomer
  • Examples of commercially available crosslinked carboxylic acid copolymers suitable for use herem include copolymers of Ci 0-30 alkyl acrylates with one or more monomers of acrylic acid, methacrylic acid, or one of then short cham (1 e C1 -.4 alcohol) esters, wherem the crosslinkmg agent is an allyl ether of sucrose or pentaerytntol
  • These copolymers are known as acrylates/C 10-30 alkyl acrylate crosspolymers and are commercially available as Carbopol® 1342, Pemulen TR-1, and Pemulen TR-2, from B F Goodnch Suitable crosslinked carboxylic acid polymers are more fully descnbed m
  • the preferred optional gelling agent suitable for use in the han stylmg compositions of the present mvention also mclude water-soluble hydrophobically modified nomomc cellulose polymers
  • water-soluble hydrophobically modified nomomc polymers refers to those water-soluble nomomc polymers which have been modified to compnse substituted hydrophobic groups to make the polymer less soluble m water
  • the nomomc cellulose polymers compnse a water-soluble cellulosic chain (or hydrophihc cellulosic cham) which forms the backbone, wherem the backbone compnse substituted hydrophobic groups
  • Suitable substituted hydrophobic groups include C8-C22 alkyl, arylalkyl, alkylaryl groups, and mixtures thereof
  • the degree of substitution on the backbone should be from about 0 10% to about 1 0%, depending on the particular polymer backbone
  • the nomomc cellulose polymers generally contam a ratio of hydrophilic substituents to hydro
  • Suitable cellulose ether substrates include any known or otherwise effective water-soluble nomomc cellulose ether
  • suitable water-soluble nomomc cellulose ethers mclude, but are not limited to, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, hydroxypropyl methyl cellulose, ethyl hydroxyethyl cellulose, and methyl hydroxyethyl cellulose
  • the amount of the nomomc substituent e g , methyl, hydroxyethyl, or hydroxypropyl substituent
  • the preferred cellulose ether substrate is hydroxyethyl cellulose (HEC) which has a weight average molecular weight of from about 50,000 to about 700,000 It has been found that hydroxyethyl cellulose is the most hydrophilic suitable cellulose ether substrate, and therefore, can allow for greater modification than other suitable water-soluble cellulose ether substrates before water-insolubility is achieved Accordmgly control of the modification process and control of the properties of the modified substrate can be more precise with hydroxyethyl cellulose substrates Hydrophihcity of the most commonly used nomomc cellulose ethers ranges from hydroxyethyl to hydroxypropyl to hydroxypropylmefhyl to methyl, with hydroxyethyl bemg the most hydrophilic and methyl being the least hydrophilic
  • the long cham alkyl modifier can be attached to the cellulose ether substrate via an ether, ester, or urethane linkage
  • the ether linkage is preferred
  • the size and effect of the hydrocarbon cham of suitable modifiers effectively conceals any noticeable effect derived from functional groups other than alkyl halides which links the modifier to the substrate
  • the long cham alkyl modifier is an epoxide containing an alphahydroxyalkyl radical, an isocyanate containing a urethane radical, or an acyl chloride containing an acyl radical
  • the effect of these functional groups are unnoticeable and the performance of the hydrophobically modified nomomc cellulose polymer is not significantly different from a polymer modified with an alkyl halide modifier
  • Natrosol Plus Grade 330 is a hydrophobically modified hydroxyethylcellulose which has a weight average molecular weight of approximately 300,000 pnor to modification, which has been substituted with from about 0 4% to about 0 8%, by weight, of an alkyl modifier having sixteen carbon atoms, and which has a hydroxyethyl molar substitution of from about 3 0 to about 3 7
  • Natrosol Plus CS Grade D-67 is a hydrophobically modified hydroxyethylcellulose which has a weight average molecular weight of approximately 700,000 prior to modification, which has been substituted with from about 0 50% to about 0 95%, by weight, of an alkyl modifier havmg sixteen carbon atoms, and which has a hydroxyethyl
  • cellulose polymers which can provide measurable viscosity mcrease to the residue are also suitable for use as an optional gelling agent herem
  • suitable cellulose polymers include a water-soluble hydrophobically modified catiomc cellulose polymer commercially available as Quatrosoft from Amerchol Optional Feel Enhancers
  • the han stylmg compositions of the present mvention may further compnse a feel enhancer to help provide unproved dry han feel
  • Concentrations of the optional feel enhancer will typically range from about 0 1% to about 15%, preferably from about 0 2% to about 10%, more preferably from about 0 5% to about 10%, by weight of the compositions
  • Suitable optional feel enhancers mclude nonvolatile silicones, catiomc polymers excludmg the catiomc polymers suitable for use as optional stylmg polymers or optional gelling agents herem, catiomc surfactants, and mixtures thereof These feel enhancers help to provide unproved dry han feel benefits such as nonsticky, unstiff, flexible, and natural feelmg han
  • Nonlimiting examples of nonvolatile silicones suitable for use as an optional feel enhancer herein include nonvolatile soluble silicones, nonvolatile insoluble silicones, or combmations thereof
  • the term “soluble” means that the silicone feel enhancer is miscible with the liquid carrier so as to form part of the same phase
  • the term “insoluble” means that the silicone feel enhancer forms a separate, discontmuous phase from the liquid earner, such as m the form of an emulsion, microemulsion, or a suspension of droplets of the silicone
  • nonvolatile as used m this context means that the silicone feel enhancer has a boilmg pomt of at least about 265°C, preferably at least about 275°C, more preferably at least about 300°C Such matenals exhibit very low or no significant vapor pressure at ambient conditions
  • Suitable nonvolatile soluble silicones mclude silicone copolyols, such as dimethicone copolyols, e g
  • Suitable nonvolatile insoluble silicones include those insoluble silicone fluids such as polyalkylsiloxanes, polyarylsiloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, and mixtures thereof Other nonvolatile insoluble silicone fluids havmg feel enhancing properties can also be used
  • silicone fluid refers to those silicone materials which have a viscosity of less than about 1 000,000 centistokes (cs) at 25°C
  • the viscosity of the fluid will be between about 5 cs and about 1,000.000 cs, preferably between about 10 cs and about 300,000 cs at 25 C C
  • the viscosity can be measured by means of a glass capillary viscometer as set forth in Dow Coming Co ⁇ orate Test Method CTM0004, July 20, 1970
  • R is alkyl or aryl
  • x is an mteger from about 7 to about 8,000 "A” represents groups which block the ends of the silicone chams
  • the alkyl or aryl groups substituted on the siloxane cham (R) or at the ends of the siloxane chams (A) may have any structure as long as the resulting silicones remain fluid at ambient conditions, are hydrophobic, are neither irritating, toxic nor otherwise harmful when applied to the han or skin, are compatible with the other components of the composition, are chemically stable under normal use and storage conditions, and are capable of bemg deposited on and of improving the feel of han or skin
  • Suitable A groups mclude methyl, ethyl, phenyl, phenylene, hydroxy, methoxy, ethoxy, propoxy, and aryloxy
  • the two R groups on the silicone atom may represent the same group or different groups
  • the two R groups represent the same group Suitable R groups mclude methyl, ethyl, propyl, phenyl, methy-phenyl and phenylmethyl
  • the preferred silicone fluids are polydimethylsiloxane, polydiethylsiloxane, and polymethylphenylsiloxane Polydimethylsiloxane is most preferred
  • nonvolatile insoluble silicone fluids include, but are not limited to, polydimethylsiloxanes such as the Viscasil R® and SF96® senes (commercially available from the General Electnc Co ), and the Dow Corning 200® senes (commercially available from Dow Coming Co ⁇ ), polymethylphenylsiloxane such as SF1075® methyl phenyl fluid (commercially available from the General Electnc Co ), and 556 Cosmetic Grade Fluid® (commercially available from Dow Corning Co ⁇ ), and a polypropylene oxide modified polydimethylsiloxane such as Dow Corning DC- 1248®
  • silicone fluids are disclosed m U S Patent 2,826,551, issued to Geen, U S Patent 3,964,500, issued to Drakoff, on June 22, 1976, U S Patent 4,364,837, issued to Pader, and Bntish Patent 849,433, issued to Woolston, all of which disclosures are mco ⁇ orated herem by reference
  • suitable silicone feel enhancers include insoluble silicone gum
  • the "silicone gums” will typically have a mass molecular weight m excess of about 200,000, generally between about 200,000 and about 1,000,000 Specific examples include polydimethyl
  • silicone feel enhancers include a silicone resm
  • Silicone resins are highly crosslinked polymeric siloxane systems The crosslinkmg is mtroduced through the inco ⁇ oration of mfunctional and tetrafunctional silanes with monofunctional or difunctional, or both, silanes during manufacture of the silicone resm
  • the degree of crosslinkmg that is requned in order to result m a silicone resm will vary accordmg to the specific silane units inco ⁇ orated mto the silicone resm
  • silicone materials which have a sufficient level of tnfunctional and tetrafunctional siloxane monomer units (and hence, a sufficient level of crosslinking) such that they dry down to a rigid, or hard, film are considered to be silicone resms
  • the ratio of oxygen atoms to silicon atoms is indicative of the level of crosslinking in a particular silicone material Silicone materials which have at least about 1 1 oxygen atoms per silicon
  • optional materials suitable for use m the hair stylmg compositions of the present invention mclude, but are not limited to, preservatives, surfactants, conditioning polymers, electrolytes, fatty alcohols, hair dyes, antidandruff actives, odor masking agents, pH adjusting agents, perfume oils, perfume solubilizmg agents, sequestermg agents, emollients, lubncants and penetrants such as vanous lanolm compounds, protem hydrolysates and other protein denvatives, sunscreens, volatile silicone fluids, and lsoparrafins
  • the concenttation of such optional ingredients generally ranges from zero to about 25%, more typically from about 0 05% to about 25%, even more typically from about 0 1% to about 15%, by weight of the composition
  • the han stylmg compositions of the present invention may be prepared by any known or otherwise effective technique suitable for providmg a han stylmg composition, provided that the composition is formulated to provide for hair volume and han hold performance as defined by the DRY HAIR INDEX described herem
  • Methods for preparmg the han stylmg compositions of the present mvention mclude conventional formulation and mixing techniques Suitable methods include combining the stylmg agent with the liquid carrier, and thoroughly mixing until the stylmg agent is homogenously dispersed and dissolved in the liquid carrier Any remaining mgredients such as perfume, the optional stylmg polymer, and the optional preferred gelling agent, can then be added and dispersed mto the mixture The resultant liquid mixture is then packaged mto a suitable contamer for packagmg such han stylmg compositions
  • the aerosol han styling composition of the present mvention can be contamed or dispensed in any known or otherwise effective aerosol contamer or delivery system All such contamers or delivery systems should be compatible with the essential and any selected optional mgredients of the han stylmg composition of the present mvention Typically, the aerosol han stylmg composition of the present mvention are packaged mto an aerosol dispenser, and propellant is then added Alternatively, pressurized aerosol dispensers can be used where the propellant is separated from contact with the han stylmg composition by use of specialized contamers such as a two compartment can of the type sold under the tradename SEPRO from American National Can Co ⁇
  • the hair stylmg compositions of the present mvention are used m a conventional manner to provide for dry han style, han volume, and han hold performance
  • An effective amount of the composition is either sprayed or applied onto dry han before or after the han is styled
  • effective amount means an amount sufficient to provide the han volume, han hold, and style performance desned accordmg to the length and texture of the han
  • han mousse compositions of the present mvention Each of the exemplified compositions are prepared by combmmg all of the listed components, except the propellant, and mixing the combmation for 40 mmutes. The resultant liquid mixture is then filled into an aerosol contamer, and the propellant is added.
  • Each of the exemplified han mousse compositions provides for improved han volume and han hold performance as defined by the DRY HAIR INDEX described herem.
  • compositions of the present mvention Each of the exemplified compositions are prepared by addmg the stylmg agent to water and mixing for one hour until the stylmg agent is dissolved The remanung mgredients, except the propellant, are then added and the resultmg solution is stirred. The composition is then packaged mto an aerosol contamer, and the propellant is added.
  • Each of the exemplified han mousse compositions provides for unproved han volume and han hold performance as defined by the DRY HAIR INDEX descnbed herem.
  • the han stylmg compositions of the present invention include the pomade embodiment described below.
  • the pomade is formulated by dispersmg the Carbopol 934 into a solution containing all the listed ingredients except the aminomethylpropanol, and thoroughly mixing for 30 mmutes. The aminomethylpropanol is then slowly added to and thoroughly mixed in the resultmg solution for 10 minutes.
  • the resultant composition may be packaged into any well known contamer for packaging such pomade compositions.
  • the exemplified pomade composition of the present mvention provides for unproved hair volume and hair hold performance as defined by the DRY HAIR INDEX described herem.
  • the hair styling compositions of the present invention include the spray-on-gel embodiment described below.
  • the spray-on-gel is formulated by combining all the listed mgredients, except the propellant, and mixing the combination for 10 rmnutes.
  • the composition is then packaged mto an aerosol container, and the propellant is added.
  • the exemplified spray-on gel composition of the present mvention provides for improved han volume and hair hold performance as defined by the DRY HAIR INDEX described herein.
  • Examples XX-XXI The following Examples XX-XXI describe pump hanspray compositions of the present invention
  • Example XX is prepared by adding the ethylene/maleic anhydride copolymer (EMA 81) to water and mixing for one hour until the EMA 81 is dissolved The remaining mgredients are then added and the resultmg solution is stirred.
  • Example XXI is prepared by combmmg all of the listed mgredients, and mixing the combmation for 15 mmutes
  • Each of the exemplified hanspray compositions provides for unproved han volume and han hold performance as defined by the DRY HAIR INDEX descnbed herein
  • the han stylmg compositions of the present mvention include the han tome embodiment described below
  • the han tome is prepared by addmg the Kytamer L stylmg polymer to water and mixing for one hour until the stylmg polymer is dissolved. The remaining ingredients are then added and the resultmg solution is stirred.
  • the exemplified han tome composition of the present mvention provides for improved hair volume and han hold performance as defined by the DRY HAIR INDEX descnbed herein

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Abstract

L'invention concerne des compositions coiffantes permettant d'augmenter le volume des cheveux et d'améliorer leur maintien et permettant d'obtenir un indice de cheveux secs (DRY HAIR INDEX) d'au moins 242 après application et séchage desdites compositions sur cheveux secs. Ces compositions contiennent de 12 % environ à 90 % environ en poids d'un agent coiffant à base de polyalkylène glycol partiellement exempt d'éthers de glycéryle polyalkylène et présentant un poids moléculaire moyen en nombre d'environ 190 à environ 1500 et d'environ 5 à environ 35 radicaux répétés d'oxyde d'alkylène, chaque radical répété d'oxyde d'alkylène contenant de 2 à 6 atomes de carbone; et de 1 % environ à 88 % environ en poids d'un support liquide tel que de l'eau, un solvant organique ou une combinaison des deux. L'invention concerne également des compositions coiffantes sous forme de pommade permettant d'augmenter le volume des cheveux et d'améliorer leur maintien et contenant de 65 % environ à 99 % environ en poids d'un agent coiffant à base de polyalkylène glycol sélectionné, et de 1 % environ à 30 % environ en poids d'un support liquide.
PCT/US2000/003910 1999-05-05 2000-02-15 Compositions coiffantes permettant d'augmenter le volume des cheveux et d'ameliorer leur maintien WO2000067709A2 (fr)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002011685A3 (fr) * 2000-08-03 2002-10-31 Procter & Gamble Compositions de soin des cheveux comprenant des agents coiffant a base de polyalkylene glycol
US6635240B1 (en) 1999-05-05 2003-10-21 The Procter & Gamble Company Hair styling compositions containing select polyalkylene glycol styling agents
EP1417952A1 (fr) * 2002-11-08 2004-05-12 L'oreal Composition cosmétique capillaire en aérosol à effet de cire
US8409553B2 (en) 2002-11-08 2013-04-02 L'oreal Cosmetic composition for the hair with a waxy effect, in aerosol form
US8697143B2 (en) 2002-10-22 2014-04-15 L'oreal Heat activated durable styling compositions comprising saccharide type compounds and film forming agents

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003081780A (ja) * 2001-09-14 2003-03-19 Kao Corp 毛髪化粧料
JP4889795B2 (ja) * 2009-04-28 2012-03-07 株式会社 資生堂 整髪用化粧料
CN106714769A (zh) * 2014-09-30 2017-05-24 株式会社Mtg 液体化妆材料
WO2016112320A1 (fr) * 2015-01-09 2016-07-14 Living Proof, Inc. Compositions capillaires et leurs procédés d'utilisation

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5002075A (en) * 1987-08-06 1991-03-26 Creative Product Resource Associates, Ltd. Hydrophilic foam pad for hair styling, conditioning and coloring
JP2917445B2 (ja) * 1990-07-17 1999-07-12 ライオン株式会社 水性整髪剤組成物
JPH08165225A (ja) * 1994-12-12 1996-06-25 Mirubon:Kk パーマネントウェーブ処理剤
DE19645909C1 (de) * 1996-11-07 1998-05-07 Wella Ag Haarbehandlungsmittel zur Festigung der Haare
JPH10139632A (ja) * 1996-11-13 1998-05-26 Sunstar Inc 乳化毛髪化粧料
JP2000204025A (ja) * 1999-01-11 2000-07-25 Kose Corp 泡沫状整髪料

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6635240B1 (en) 1999-05-05 2003-10-21 The Procter & Gamble Company Hair styling compositions containing select polyalkylene glycol styling agents
WO2002011685A3 (fr) * 2000-08-03 2002-10-31 Procter & Gamble Compositions de soin des cheveux comprenant des agents coiffant a base de polyalkylene glycol
US6585965B1 (en) 2000-08-03 2003-07-01 The Procter & Gamble Company Hair care compositions comprising polyalkylene glycol styling agents
US8697143B2 (en) 2002-10-22 2014-04-15 L'oreal Heat activated durable styling compositions comprising saccharide type compounds and film forming agents
EP1417952A1 (fr) * 2002-11-08 2004-05-12 L'oreal Composition cosmétique capillaire en aérosol à effet de cire
FR2846880A1 (fr) * 2002-11-08 2004-05-14 Oreal Composition cosmetique capillaire en aerosol a effet de cire
US8409553B2 (en) 2002-11-08 2013-04-02 L'oreal Cosmetic composition for the hair with a waxy effect, in aerosol form

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