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WO2001076735A1 - Procede de preparation de catalyseurs fischer-tropsch - Google Patents

Procede de preparation de catalyseurs fischer-tropsch Download PDF

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Publication number
WO2001076735A1
WO2001076735A1 PCT/US2000/010520 US0010520W WO0176735A1 WO 2001076735 A1 WO2001076735 A1 WO 2001076735A1 US 0010520 W US0010520 W US 0010520W WO 0176735 A1 WO0176735 A1 WO 0176735A1
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
carrier
compound
active metal
cobalt
Prior art date
Application number
PCT/US2000/010520
Other languages
English (en)
Inventor
Gyanesh P. Khare
Original Assignee
Phillips Petroleum Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Company filed Critical Phillips Petroleum Company
Priority to AU2000246479A priority Critical patent/AU2000246479A1/en
Publication of WO2001076735A1 publication Critical patent/WO2001076735A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/023—Coating using molten compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group

Definitions

  • This invention relates to Fischer-Tropsch catalysts, and more
  • Synthesis gas (typically a mixture of carbon monoxide and
  • Fischer-Tropsch catalyst is typically comprised of a particulate carrier
  • an active metal particularly cobalt, iron, manganese, or
  • the invention provides a novel process for preparing a Fischer-ray
  • Tropsch catalyst comprising the steps of: impregnating a particulate carrier with
  • an active metal selected from cobalt, iron, manganese, nickel and mixtures
  • particulate carrier can be an oxide of silicon, aluminum, titanium, zinc,
  • Alumina is most
  • the active metal compound preferably has an active metal
  • active metal compounds include halides, nitrates, sulfates, acetates and
  • the active metal compound preferably has a
  • melting point in the range of about 25-400°C, most preferably about 25-100°C.
  • the most preferred active metal is cobalt, and the most preferred cobalt compound is
  • cobalt(II) nitrate hexahydrate Any suitable means can be used to mix the particulate carrier and
  • the mixing is carried out at a temperature approximately
  • mixing temperature for cobalt(II) nitrate hexahydrate is preferably in the range
  • mixing is typically less than 1 hour, most typically about 15-30 minutes.
  • the particulate carrier is impregnated with the active metal
  • the active metal compound is a hydrate and loses water of
  • the impregnated carrier is preferably dried in
  • the impregnated carrier is then calcined at a suitable temperature, typically in
  • Calcination is preferably carried out in a
  • the particulate carrier can be impregnated with a
  • promoter metal to enhance the catalytic activity or to modify its selectivity.
  • Useful promoter metals are potassium, chromium, magnesium, zirconium, ruthenium, thorium, hafnium cerium, rhenium, uranium, vanadium, titanium,
  • Preferred promoters are selected from platinum,
  • Impregnation of the particulate carrier with the promoter metals is
  • the metal promoter containing compound will be any metal promoter metal.
  • the metal promoter containing compound will be any metal promoter containing compound.
  • the particulate is soluble in water. According to an incipient wetness technique, the particulate
  • carrier can be sprayed with an impregnation solution, having a suitable
  • promoter metal compound dissolved in water or other solvent, while agitating
  • the active metal in the finished catalyst can be, by way of
  • the particulate carrier could also be
  • a particulate alumina carrier obtained from Condea Chemie,
  • the cobalt impregnated alumina was allowed to cool, and then transferred from
  • a Catalyst was prepared in accordance with the process described
  • the evaporator to impregnate the alumina carrier and to dry the impregnated carrier.
  • the dried impregnated carrier was calcined at 230°C for 2 hours in an air flow
  • impregnated carrier was calcined at 230°C for 2 hours in an air flow of 1.5
  • a particulate alumina carrier obtained from Condea Chemie,
  • the mixture was next heated on a hot plate to dryness while stirring.
  • the reactor used in this catalyst test was a 300 cc stirred tank
  • the stirring speed was maintained at 1200 rpm during all tests, which was
  • Catalyst Catalyst A Catalyst B 1 Catalyst C
  • the data for Catalyst B is an average of two runs except for the Co content where only one of the two runs was analyzed for Co content.
  • Catalyst A illustrates that the catalyst has a low attrition even using calcining

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un procédé de préparation de catalyseurs Fischer-Tropsch. Ce procédé comprend les étapes consistant: à imprégner un support particulaire au moyen d'un métal actif sélectionné dans le cobalt, le fer, le manganèse et le nickel, par mélange du support particulaire avec un composé de métal actif particulaire, à une température approximativement égale ou supérieure au point de fusion du composé de métal actif, mais inférieure à la température à laquelle le composé se décompose; puis à calciner le support ainsi imprégné en vue de produire le catalyseur.
PCT/US2000/010520 2000-04-07 2000-04-18 Procede de preparation de catalyseurs fischer-tropsch WO2001076735A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2000246479A AU2000246479A1 (en) 2000-04-07 2000-04-18 Process for preparing fischer-tropsch catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US54486000A 2000-04-07 2000-04-07
US09/544,860 2000-04-07

Publications (1)

Publication Number Publication Date
WO2001076735A1 true WO2001076735A1 (fr) 2001-10-18

Family

ID=24173896

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/010520 WO2001076735A1 (fr) 2000-04-07 2000-04-18 Procede de preparation de catalyseurs fischer-tropsch

Country Status (2)

Country Link
AU (1) AU2000246479A1 (fr)
WO (1) WO2001076735A1 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003012008A3 (fr) * 2001-07-27 2004-04-29 Sasol Tech Pty Ltd Production de cire produite par synthese fischer-tropsch
US7012104B2 (en) 2002-10-16 2006-03-14 Conocophillips Company Fischer-Tropsch processes and catalysts made from a material comprising boehmite
US7071239B2 (en) 2002-10-16 2006-07-04 Conocophillips Company Fischer-Tropsch processes and catalysts using stabilized supports
US7176160B2 (en) 2002-10-16 2007-02-13 Conocophillips Company Method for forming a Fischer-Tropsch catalyst using a boehmite support
US7186757B2 (en) 2003-10-16 2007-03-06 Conocophillips Company Silica-alumina catalyst support with bimodal pore distribution, catalysts, methods of making and using same
US7341976B2 (en) 2002-10-16 2008-03-11 Conocophillips Company Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
EP1935964A1 (fr) * 2006-12-19 2008-06-25 Bp Exploration Operating Company Limited Catalyseur Fischer-Tropsch
WO2008075023A1 (fr) * 2006-12-19 2008-06-26 Bp Exploration Operating Company Limited Catalyseur de fischer-tropsch
US7402612B2 (en) 2002-10-16 2008-07-22 Conocophillips Company Stabilized transition alumina catalyst support from boehmite and catalysts made therefrom
US7541310B2 (en) 2003-10-16 2009-06-02 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same
DE102008025307A1 (de) * 2008-05-27 2009-12-03 Süd-Chemie AG Kobalt-Fischer-Tropsch-Katalysator
EP3061525A4 (fr) * 2013-10-22 2017-05-24 Korea Institute of Energy Research Catalyseur à base de cobalt fondé sur une structure métallique pour réaction de fischer-tropsch pour la production sélective d'huile de synthèse, procédé de préparation associé et procédé de préparation sélective d'huile de synthèse au moyen du catalyseur à base de cobalt fondé sur une structure métallique

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4209424A (en) * 1977-12-12 1980-06-24 Societe Chimique de la Grande Paroisse, Azote et Products Chimiques Catalyst for manufacturing amines from alcohols
US5008234A (en) * 1988-06-17 1991-04-16 Her Majesty The Queen In The Right Of Canada, As Represented By The Minister Of Energy Mines And Resources Process for the preparation of catalytic metal clusters
US5360779A (en) * 1993-10-14 1994-11-01 Phillips Petroleum Company Preparation of supported sulfur compositions
US5714092A (en) * 1993-05-13 1998-02-03 Gastec, N.V. Process for the production of hydrogen/carbon monoxide mixtures or hydrogen from methane
US5981608A (en) * 1995-06-16 1999-11-09 Shell Oil Company Catalyst and process for the preparation of hydrocarbons

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4209424A (en) * 1977-12-12 1980-06-24 Societe Chimique de la Grande Paroisse, Azote et Products Chimiques Catalyst for manufacturing amines from alcohols
US5008234A (en) * 1988-06-17 1991-04-16 Her Majesty The Queen In The Right Of Canada, As Represented By The Minister Of Energy Mines And Resources Process for the preparation of catalytic metal clusters
US5714092A (en) * 1993-05-13 1998-02-03 Gastec, N.V. Process for the production of hydrogen/carbon monoxide mixtures or hydrogen from methane
US5360779A (en) * 1993-10-14 1994-11-01 Phillips Petroleum Company Preparation of supported sulfur compositions
US5981608A (en) * 1995-06-16 1999-11-09 Shell Oil Company Catalyst and process for the preparation of hydrocarbons

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003012008A3 (fr) * 2001-07-27 2004-04-29 Sasol Tech Pty Ltd Production de cire produite par synthese fischer-tropsch
US7262225B2 (en) 2001-07-27 2007-08-28 Sasol Technology (Proprietary) Limited Production of fischer-tropsch synthesis produced wax
US7402612B2 (en) 2002-10-16 2008-07-22 Conocophillips Company Stabilized transition alumina catalyst support from boehmite and catalysts made therefrom
US7012104B2 (en) 2002-10-16 2006-03-14 Conocophillips Company Fischer-Tropsch processes and catalysts made from a material comprising boehmite
US7071239B2 (en) 2002-10-16 2006-07-04 Conocophillips Company Fischer-Tropsch processes and catalysts using stabilized supports
US7176160B2 (en) 2002-10-16 2007-02-13 Conocophillips Company Method for forming a Fischer-Tropsch catalyst using a boehmite support
US7341976B2 (en) 2002-10-16 2008-03-11 Conocophillips Company Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
US7449496B2 (en) 2002-10-16 2008-11-11 Conocophillips Company Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
US7186757B2 (en) 2003-10-16 2007-03-06 Conocophillips Company Silica-alumina catalyst support with bimodal pore distribution, catalysts, methods of making and using same
US7541310B2 (en) 2003-10-16 2009-06-02 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same
WO2008075023A1 (fr) * 2006-12-19 2008-06-26 Bp Exploration Operating Company Limited Catalyseur de fischer-tropsch
WO2008075030A2 (fr) 2006-12-19 2008-06-26 Bp Exploration Operating Company Limited Catalyseur de fischer-tropsch
WO2008075030A3 (fr) * 2006-12-19 2008-08-07 Bp Exploration Operating Catalyseur de fischer-tropsch
EP1935964A1 (fr) * 2006-12-19 2008-06-25 Bp Exploration Operating Company Limited Catalyseur Fischer-Tropsch
US8053482B2 (en) 2006-12-19 2011-11-08 Bp Exploration Operating Company Limited Fischer-tropsch catalyst
DE102008025307A1 (de) * 2008-05-27 2009-12-03 Süd-Chemie AG Kobalt-Fischer-Tropsch-Katalysator
DE102008025307A8 (de) * 2008-05-27 2010-04-29 Süd-Chemie AG Kobalt-Fischer-Tropsch-Katalysator
EP3061525A4 (fr) * 2013-10-22 2017-05-24 Korea Institute of Energy Research Catalyseur à base de cobalt fondé sur une structure métallique pour réaction de fischer-tropsch pour la production sélective d'huile de synthèse, procédé de préparation associé et procédé de préparation sélective d'huile de synthèse au moyen du catalyseur à base de cobalt fondé sur une structure métallique

Also Published As

Publication number Publication date
AU2000246479A1 (en) 2001-10-23

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