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WO2003067579A1 - Optical recording/reproducing method and optical recording medium - Google Patents

Optical recording/reproducing method and optical recording medium Download PDF

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Publication number
WO2003067579A1
WO2003067579A1 PCT/JP2003/000531 JP0300531W WO03067579A1 WO 2003067579 A1 WO2003067579 A1 WO 2003067579A1 JP 0300531 W JP0300531 W JP 0300531W WO 03067579 A1 WO03067579 A1 WO 03067579A1
Authority
WO
WIPO (PCT)
Prior art keywords
information recording
recording layer
layer
optical
information
Prior art date
Application number
PCT/JP2003/000531
Other languages
French (fr)
Japanese (ja)
Inventor
Yuichi Sabi
Takashi Iwamura
Mitsuaki Oyamada
Sakuya Tamada
Original Assignee
Sony Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sony Corporation filed Critical Sony Corporation
Priority to JP2003566845A priority Critical patent/JPWO2003067579A1/en
Priority to US10/472,269 priority patent/US7092343B2/en
Priority to CA002441559A priority patent/CA2441559A1/en
Priority to EP03737436A priority patent/EP1469460A4/en
Priority to KR1020037012278A priority patent/KR100943103B1/en
Publication of WO2003067579A1 publication Critical patent/WO2003067579A1/en

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Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/004Recording, reproducing or erasing methods; Read, write or erase circuits therefor
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/2403Layers; Shape, structure or physical properties thereof
    • G11B7/24035Recording layers
    • G11B7/24038Multiple laminated recording layers
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/004Recording, reproducing or erasing methods; Read, write or erase circuits therefor
    • G11B7/005Reproducing
    • G11B7/0051Reproducing involving phase depth effects
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/004Recording, reproducing or erasing methods; Read, write or erase circuits therefor
    • G11B7/005Reproducing
    • G11B7/0052Reproducing involving reflectivity, absorption or colour changes
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/246Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B2007/0003Recording, reproducing or erasing systems characterised by the structure or type of the carrier
    • G11B2007/0009Recording, reproducing or erasing systems characterised by the structure or type of the carrier for carriers having data stored in three dimensions, e.g. volume storage
    • G11B2007/0013Recording, reproducing or erasing systems characterised by the structure or type of the carrier for carriers having data stored in three dimensions, e.g. volume storage for carriers having multiple discrete layers

Definitions

  • the present invention relates to an optical recording / reproducing method for at least reproducing or recording information and an optical recording medium.
  • optical recording media for example, optical discs
  • Higher recording densities in optical recording media are usually realized by a method of shortening the wavelength of irradiation light and increasing the numerical aperture of an objective lens. By combining this with the multi-layered information recording layer, a dramatic increase in density can be realized.
  • the return light to the information recording layer at a position far from the incident surface is the light of the optical recording medium while the light is being detected. Since the light passes through the other information recording layer located on the incident surface side and returns, the amount of light decreases.
  • an optical disk can be roughly classified into two types.
  • phase modulation method represented by the so-called CD-R or DVD-R of a CD-ROM (Compact Disc-Read Only Memory) disk, a write-once CD or DVD (Digital Versatile Disc). It is.
  • phase modulation method while the reflectance in an information recording mark and the reflectance in the vicinity thereof are made equal to make the reflectance constant, the optical path length in the information recording mark and the optical path length in the vicinity are determined. By making them different, the phase of the reflected light changes, causing interference in the light spot, and as a result, the amount of return light changes.
  • the other is a reflectivity modulation method represented by an optical disk using a phase-change material such as a rewritable CD or DVD, that is, a so-called CD-RW or DVD-RW.
  • a change in the amount of return light due to a difference in reflectance is directly detected by utilizing the fact that the reflectance in an information recording mark is lower than the surrounding reflectance.
  • the information holding layer that is, the information recording layer in the phase modulation method represented by the above-mentioned CDR and DVDR is generally constituted by a recording film made of an organic dye.
  • the optical recording medium in which the recording film is made of the organic dye material has advantages such as easy production, easy handling of the material, and low cost.
  • the reflectance is maintained almost constant without changing before and after recording, which causes effective interference between the information recording mark and its surroundings. Is needed.
  • the structure is such that a metal film of Ag or the like is laminated so that the reflectance does not change before and after recording.
  • the present invention relates to an optical recording / reproducing method for at least reproducing / recording information on an optical recording medium and the recording medium, wherein the configuration of the optical recording medium is such that two or more information recording layers are laminated.
  • the multilayer information recording layer of the optical recording medium can be constituted by a recording film made of an organic dye, thereby simplifying the production and reducing the price. It is an object of the present invention to provide an optical recording medium and an optical recording / reproducing method capable of obtaining good recording / reproducing characteristics for an information recording layer.
  • the optical recording / reproducing method of the present invention is a method for reproducing or recording at least information on an optical recording medium, and as the optical recording medium, one main surface on the light incident side of the optical recording medium; It has a plurality of information recording layers between it and the other main surface on the opposite side, and the first information recording layer closest to the other main surface is the phase modulation type information recording layer, Using an optical recording medium in which the recording layer is a reflectance modulation type information recording layer, the first information recording layer is phase-modulated by light incident from one main surface side. In this case, information is reproduced or recorded in accordance with the method described above, and information is reproduced or recorded in the other information recording layer in accordance with the reflectance modulation method.
  • the optical recording medium of the present invention has one main surface through which light can enter, and a plurality of information recording layers between the other main surface opposite to the one main surface,
  • the first information recording layer closest to the other main surface is a phase modulation type information recording layer
  • the other information recording layer is a reflectance modulation type information recording layer.
  • At least one information recording layer of a plurality of information recording layers has physical properties by light absorption.
  • a structure containing an organic material that causes a change to cause a change in an optical constant can be provided, and an organic dye can be used as the organic material.
  • a plurality of information recording layers are provided between one main surface on the light incident side and the other main surface on the opposite side, and the other main surface has Using an optical recording medium in which the near first information recording layer is a phase modulation type information recording layer and the other information recording layer is a reflectance modulation type information recording layer, light incidence from one principal surface side
  • the near first information recording layer is a phase modulation type information recording layer
  • the other information recording layer is a reflectance modulation type information recording layer
  • the first information recording layer closest to the other main surface is a phase modulation type information recording layer.
  • Signal detection can be performed by a phase modulation method.
  • the other information recording layer is a reflectance modulation type information recording layer, signal detection can be performed by a reflectance modulation method. .
  • the optical recording medium used in the optical recording / reproducing method according to the present invention is a phase modulation type information recording layer.
  • the principle of recording is to cause a change in the refractive index before and after recording.
  • the refractive index of the organic dye film before recording is set so as to be significantly different from the refractive index of the adjacent layer, for example, the substrate, and the reflection at the interface between the organic dye film and another material layer in contact with the organic dye film.
  • the refractive index of the organic dye film after recording is set to be close to the refractive index of the other material layer forming the above-described interface, and the interface between the organic dye film and the substrate is set.
  • the phase modulation type information recording layer can be formed by changing the optical path length by recording by such a change in the refractive index.
  • FIG. 1 is a schematic configuration diagram (cross-sectional view) of an optical disc according to an embodiment of the present invention.
  • FIG. 2 is a cross-sectional view of the optical disc having three information recording layers.
  • FIG. 3 is a schematic configuration diagram of an embodiment of an optical pickup for reproducing and recording information with respect to the optical disc of FIG. 1, and
  • FIGS. 4A and 4B show the width of the guide groove of the information recording layer.
  • FIG. 9 is a diagram showing the result of measuring the modulation factor while changing.
  • the present invention relates to a method for at least reproducing or recording information on an optical recording medium, wherein the optical recording medium has one main surface on a light incident side with respect to the optical recording medium and another main surface on the opposite side.
  • a plurality of information recording layers between the main surface and the first information recording layer closest to the other main surface.
  • the first information recording layer Is an optical recording / reproducing method in which information is reproduced or recorded by a phase modulation method, and information is reproduced or recorded in another information recording layer by a reflectance modulation method.
  • the present invention also provides the optical recording / reproducing method, wherein
  • the reflectance before recording at the position corresponding to the information recording mark is R.
  • the rate of change (R. — R) ZR. Is smaller than the modulation degree of the reproduction detection signal of the information recording mark, and the other information recording layer has the same rate of change of the information recording mark (R D -R) ZR. Is equal to or greater than the modulation degree of the reproduction detection signal of the information recording mark.
  • the present invention has one main surface through which light can enter, and a plurality of information recording layers between the other main surface opposite to the one main surface.
  • the first information recording layer closest to the optical recording medium is a phase modulation type information recording layer
  • the other information recording layer is a reflectance modulation type information recording layer.
  • the present invention provides the optical recording medium, wherein the width of the recording area of the reflectance modulation type information recording layer is wider than the width of the recording area of the phase modulation type information recording layer.
  • the present invention also provides the optical recording medium, wherein the first information recording layer has a reflectance before recording at a position corresponding to an information recording mark. Assuming that the reflectance after recording at the same position is R, the rate of change (R.I.R) ZR. Is smaller than the modulation degree of the reproduction detection signal of the information recording mark, and the other information recording layers have the same rate of change of the information recording mark (R.-R
  • the present invention provides the optical recording medium, wherein a plurality of information recording layers are provided. At least one or more of the information recording layers is formed of a recording film whose optical constant changes due to light absorption.
  • the present invention provides the above-mentioned optical recording medium, wherein the recording film further contains an organic material which causes a change in physical properties due to light absorption to cause a change in an optical constant.
  • the present invention is configured such that in the optical recording medium, an organic dye is further used as an organic material.
  • the present invention is configured such that in the optical recording medium, a reflection layer is provided on the other main surface side of the first information recording layer.
  • FIG. 1 shows a schematic configuration diagram (cross-sectional view) of an optical disk as one embodiment of the present invention.
  • the optical disc 10 has a reflective layer 12, a first information recording layer 21, an intermediate layer 13, a second information recording layer 22, and a surface protective layer (light transmitting layer) on a substrate 11. 1) and 4 are laminated.
  • the information recording layer is composed of the first information recording layer 21 and the second information recording layer.
  • the optical disc 10 of the present embodiment has a configuration in which the light L is incident not from the substrate 11 side but from the side opposite to the substrate 11, that is, from the surface protective layer 14 side.
  • Guide grooves are provided on the substrate 11 and the intermediate layer 13 so that the first information recording layer 21 and the second information recording layer 22 can be tracked, respectively.
  • the first information recording layer 21 or the second information recording layer 22 a film that changes the optical constant due to light absorption can be used.
  • only one of the first information recording layer 21 and the second information recording layer 22 may be a film that changes the optical constant by light absorption.
  • the optical constant changes due to light absorption, causing the information recording layer to buckle.
  • the folding ratio changes.
  • the first information recording layer 21 and the second information recording layer 22 can be formed of an organic material film, for example, an organic dye film.
  • the organic dye film is made of a material that changes its physical properties by light absorption (for example, the molecular structure changes due to thermal decomposition, or the molecular arrangement changes as it is, or a composite thereof).
  • organic dye film a conventionally known material, for example, triphenylamine tetramer or the like can be used.
  • the recording film constituting the information recording layer is formed of an organic dye film in this manner, there is an advantage that the production can be simplified and the price can be reduced.
  • the reflection layer 12 a film having a high reflectance with respect to the incident light L is formed.
  • a metal film for example, an Ag alloy sputtered film or the like can be used.
  • a material having a high transmittance to the incident light L is used.
  • a UV curable resin can be used.
  • the thickness of the intermediate layer 13 is preferably 5 to 50 ⁇ m.
  • the first information recording layer 21 is a phase modulation type information recording layer capable of reproducing or recording information by a phase modulation method.
  • the reflectance before recording at the position corresponding to the information recording mark before the recording is R.
  • R is the reflectance after recording at the same position (R. — R) ZR.
  • the force is formed so as to be smaller than the modulation degree of the reproduction detection signal of the information recording mark.
  • the first information recording layer 21 can be a phase modulation type information recording layer.
  • the first information recording layer 21 is provided with the reflection layer 12 on the side opposite to the light incident surface.
  • the width of the recording area is defined in accordance with the wavelength of the light source of the readout optical system and the numerical aperture NA of the condenser lens so that a signal with a sufficient degree of modulation is obtained and SZN is increased.
  • the first information recording layer 21 is provided with the reflection layer 12 made of a material having a relatively high reflectance on the side opposite to the light incident surface. Both the reflectance of the information recording layer 21 before recording and the reflectance after recording are close to the reflectance of the reflection layer 12, and the optical constant between the information recording mark and the information recording layer 21 before recording is low. Since the refractive index is different, the optical path length during the round trip to the reflective layer 12 is different.
  • the second information recording layer 22 is a reflectance modulation type information recording layer capable of reproducing or recording information by a reflectance modulation method.
  • the reflectance before recording at the position corresponding to the information recording mark before recording is R.
  • the reflectance after recording at the same position as R, the rate of change (R.-R) / R. Is formed so as to be equal to or higher than the modulation degree of the reproduction detection signal of the information recording mark.
  • the second information recording layer 22 is used as a reflectance modulation type information recording layer. It can be
  • the width of the recording area is defined in accordance with the wavelength ⁇ of the light source of the readout optical system and the numerical aperture ⁇ ⁇ of the condenser lens.
  • the width of the recording area may be different even if the first information recording layer 21 is formed using the same material.
  • the recording films constituting the two information recording layers 21 and 22 are formed of organic dye films, the following operation is performed.
  • the refractive index of the organic dye film before recording is set so as to be significantly different from the refractive index of an adjacent layer, for example, the substrate, so that reflection occurs at the interface between the organic dye film and the substrate, and the recording is performed.
  • the refractive index of the subsequent organic dye film is set so as to be close to the refractive index of the substrate to reduce the reflectance at the interface between the organic dye film and the substrate. This makes it possible to detect the signal.
  • the reflectance modulation method since the reflectance is directly detected, the information is reproduced or recorded by the reflectance modulation method.
  • the reflective layer 12 when the reflective layer 12 is provided on the recording film, the change in the reflectance before and after the recording becomes small, and the above-described change in the refractive index changes the optical path length in the recording film. Changes the phase of light before and after recording. This makes it possible to detect a signal by using the interference of return lights having different phases.
  • the information is reproduced or recorded by the phase modulation method. Therefore, when the recording film constituting the information recording layers 21 and 22 is formed by the organic dye film, the phase modulation depends on the presence or absence of the reflection layer 12. Reproduction or recording of information by either It can also be configured to perform.
  • the recording area has two surfaces having a step formed by the guide groove therebetween, that is, a surface close to the light incident side (lane). And the surface farther from the light incident side (groove) may be provided on either surface.
  • the recording area is provided in the land section or the group section, reflection is performed in accordance with the spot size of the incident light L (wavelength of the light source; determined according to I and the numerical aperture NA of the objective lens).
  • the width of the recording area is adjusted so that a sufficient degree of modulation can be obtained by the rate modulation method or the phase modulation method, and the information can be reproduced or recorded on the information recording layers 21 and 22.
  • the width of the recording area must be 0.12 to 0.1 to adopt the reflectance modulation method. It is preferable that the width of the recording area be 0.09 to 0.22 m in order to adopt the phase modulation method.
  • the wavelength of the light source is, for example, in the range of 360 to 460 nm, the wavelength becomes shorter than that of a normal optical disc such as a CD-R, so that the size of the optical spot is reduced.
  • the recording density of the optical recording medium can be improved.
  • the first information recording layer 21 and the second information recording layer 22 can perform reproduction and recording with the same optical head.
  • the optical disc for focusing can be used, for example.
  • the light spot caused by the incident light L is moved between the first information recording layer 21 and the second information recording layer 22 by moving in a direction substantially perpendicular to the surface, and the respective information recording layers 21 are moved. Or reproduction of information for 22 And record.
  • FIG. 3 shows a schematic configuration diagram of an embodiment of an optical pickup for reproducing and recording information.
  • This optical pick-up consists of a light source 51 and a grating 52
  • the light source 51 is configured as a unit including a semiconductor laser that emits laser light having a wavelength of, for example, 405 nm, a collimator, and anamorphism.
  • the objective lens 55 is composed of two optical lenses.
  • the light detecting section 58 functions as a sub-body detector and an RF detector.
  • the optical disk 40 is the optical disk 10 of the above-described embodiment, the optical disk has only one information recording layer made of an organic dye. Even so, it is possible to reproduce and record information.
  • the reflection layer 12 is provided adjacent to the first information recording layer 21, and the reflectance is increased by the reflection layer 12, so that the first information recording layer 2
  • the signal intensity from 1 can be increased, and the change in reflectance before and after recording can be reduced.
  • the transmittance of the second information recording layer 22 is increased so that a sufficient amount of light can be obtained.
  • 1 information recording layer 2 1.
  • the rate of change of the reflectance before and after recording at a position corresponding to the information recording mark (R Q -R) / R. Is larger than the modulation degree of the reproduction detection signal of the information recording mark, it is possible to employ the reflectance modulation method for reproducing and recording information on the second information recording layer 22.
  • the recording density of the optical disk 10 is dramatically increased.
  • the organic dye when used as a material of the information recording layer, that is, when the recording film constituting the information recording layer is formed of the organic dye film, further simplification of manufacturing and cost reduction are achieved. The cost can be reduced.
  • a dielectric protection film may be formed between each of the information recording layers 21 and 22 and the intermediate layer 13 or between the second information recording layer 22 and the surface protection layer 14.
  • An optical system was constructed using a blue LD, ie, a semiconductor laser diode (emission wavelength: 405 nm) with a luminescent color, and a numerical aperture (NA) of 0.85 as the light source. .
  • each layer of the optical disc 10 had the following configuration.
  • Substrate 11 Polycarbonate resin Reflective layer 1 2: Sputtered Ag alloy film 30 nm
  • First information recording layer 21 Organic dye film (triphenylamine tetramer) 40 nm
  • Middle layer 13 UV cured resin 30 m
  • Second information recording layer 22 Organic dye film (triphenylamine tetramer) 40 nm
  • the thickness of the intermediate layer 13 is desirably 15 ⁇ m or more in order to suppress the crosstalk between the first information recording layer 21 and the second information recording layer 22, the thickness is 30 ⁇ m. m.
  • the first information recording layer 21 and the second information recording layer 22 each include a triphenylamine tetramer, more specifically, N, N'-bis (4-diphenylamino- 4-biphenyl). N, N'-diphenylbenzidine 6-4) is used. O Hereinafter, it is abbreviated as triphenylamine.
  • the refractive index of triphenylamine is 2.31, and the absorption coefficient is 0.13.
  • the refractive index after recording is 2.1.
  • This triphenylamine can be formed by vapor deposition.
  • the intermediate layer 13 and the surface protective layer 14 were made of a UV-curable resin with the trade name SD-301, but other materials, a method using a UV-curable adhesive, It is also possible to form with a combination of one sheet and adhesive.
  • the material of the reflective layer 12 may be any material as long as the readout optical system has a sufficiently high reflectance at the wavelength of the light source.
  • the base material It is also possible to use.
  • the information recording layer 21 and 22 it is also possible to use another organic dye material optimized when using a blue LD as a light source. If there is another material capable of spin-coat sputtering, the information recording layer may be formed by spin coating or sputtering.
  • an optical disk 10 having the configuration shown in FIG. 1 was manufactured as follows.
  • a substrate 11 made of a polycarbonate material having guide grooves (for the first information recording layer 21) formed by an injection method is removed.
  • an Ag alloy film was formed on the substrate 11 by sputtering to form a reflective layer 12.
  • a first information recording layer 21 was formed on the reflective layer 12 by forming a film of triphenylamine by vapor deposition.
  • an intermediate layer 13 made of a UV-curable resin was formed on the first information recording layer 21.
  • a stamper having a shape of a guide groove (for the second information recording layer 22) was pressed against the intermediate layer 13, and the guide groove was transferred by UV curing.
  • the track pitch of the guide grooves in the guide grooves for the first information recording layer 21 and the guide grooves for the second information recording layer 22 was both 0.32 ⁇ m.
  • the depth of each guide groove was set to 2 On m.
  • the surface near the light incident side, that is, the land portion, of the step formed by the guide groove was used as a recording area.
  • the guide groove for the first information recording layer 21 formed on the substrate 11 has a recording area for sufficiently obtaining a detection signal by the phase modulation method.
  • the width of the 531 key, that is, the land portion was set to 0.12 m.
  • the guide groove for the second information recording layer 22 formed on the intermediate layer 13 is a recording area for performing reproduction or recording on the second information recording layer 22 by a reflectance modulation method.
  • the width of the land portion was 0.16 m, which was wider than the guide groove for the first information recording layer 21.
  • a second information recording layer 22 was formed on the intermediate layer 13 by forming a film of triphenylamine by vapor deposition.
  • optical disk 10 of Example 1 a surface protective layer 14 made of a UV-curable resin was formed, and an optical disc 10 having the configuration shown in FIG. 1 was produced. This was designated as optical disk 10 of Example 1.
  • the amount of reflected light was measured while the amount of incident light was kept constant.
  • the return light quantity from the second information recording layer 22 was 13%, and the return light quantity from the first information recording layer 21 was 14%. This means that the reflectance when the information recording layer is a single layer of the first information recording layer 21 is 25%, and the light transmittance in the second information recording layer 22 is 74%. Does not contradict.
  • the transmittance in the information recording mark after the recording of the second information recording layer 22 is 78%, the transmittance is averaged to 76% in the entire recording area.
  • the amount of return light from the information recording layer 21 increases, but this is a problem that does not affect the characteristics of a signal obtained by the return light, and thus causes no problem.
  • the recording conditions are as follows.
  • the linear velocity during recording was 5.72 m / s, and the recording pattern was the pattern of a carrier wave with a mark length and space length of 0.69 m. JP03 / 00531
  • the light intensity at the time of recording was set to 5.0 mW, and the 0.69 m mark was recorded by irradiating it with seven pulses of Duty 50%.
  • the transmittance of the second information recording layer 22 is 7 4
  • optical disc 10 Since the optical disc 10 is a write-once type (write-once type), recording is performed before the first information recording layer 21, so that the recording of the first information recording layer 21 is performed. At this time, since the second information recording layer 22 has not been recorded at all, the transmittance is constant and the required recording power hardly varies.
  • first information recording layer 21 and the second information recording layer 22 are recorded on the optical disc 10 of Example 1 in this order, and the recording is performed for all the recording errors. After that, the first information recording layer 21 was read.
  • the transmittance of the second information recording layer 22 became larger than in the previous case, but the amount of light returned from the first information recording layer 21 was about 15%, and the first information Between recording layer 21 and second information recording layer 22 Since the gap was sufficiently empty, almost no intersymbol interference between the layers was observed, and a signal waveform almost the same as that obtained when recording was performed only on the first information recording layer 21 was obtained.
  • the two information recording layers 21 and 22 can improve the recording density as compared with an optical disc having a single information recording layer.
  • the reflective layer 12 made of a metal film was not provided between the first information recording layer 21 and the substrate 11, and the first information recording was performed.
  • the layer 21 has the same film configuration and guide groove shape (width of recording area of 0.16 m) as the second information recording layer 22, and the other components are the same as those of the optical disc 10 of the first embodiment.
  • an optical disc of a comparative example was manufactured.
  • the amount of light detected from the first information recording layer 21 is reduced to 10%, the S / N is reduced, and the focus servo is also unstable. It was a level that did not become.
  • the second information recording layer 22 is also provided with a reflective layer and uses the same detection principle as the first information recording layer 21, the first It goes without saying that no signal from the information recording layer 21 can be obtained at all.
  • a third information recording layer 23 is further provided on the incident surface side, and a total of three information recording layers 21, An optical disk 20 on which 22 and 23 were formed was manufactured, and was used as an optical disk 20 of Example 2.
  • Example 2 the thickness of the Ag metal film forming the reflection layer 12 was set to 50 nm.
  • the second information recording layer 22 and the third information recording layer 23 have the same configuration (material ⁇ film thickness) as the second information recording layer 22 of the optical disc 10 of the first embodiment. ⁇ An organic dye film with the width of the recording area) was used. Further, in this case, two intermediate layers 13 were formed. At this time, the reflectance of the first information recording layer 21 was 35%.
  • the amount of return light before recording was 10% of the amount of incident light, and a signal with a modulation factor of 30% was detected.
  • Example 2 it was shown that the use of the configuration of Example 2 can achieve a practical level even with an optical disc having three information recording layers.
  • the reflective layer 12 made of an Ag metal film was not formed, or the reflective layer 12 had a thickness of 30 nm.
  • the amount of light returned from the first information recording layer 21 was too small to detect and the focus servo was not applied.
  • the width of the recording area of the second information recording layer 22 is set to 0.06 to 03 00531
  • Fig. 4A shows the results of measuring the modulation of the reproduction detection signal while changing it within the range of 0.26 m.
  • the modulation was 40% as described above, but as shown in Fig. 4 ⁇ ⁇ ⁇ , when the width of the recording area was further reduced, the modulation It can be seen that the degree decreases.
  • the amplitude of the detection signal simply decreases when the width of the information recording mark decreases, and it is considered that the modulation degree decreases by the decrease in the recording area.
  • the modulation degree increases as the width of the information recording mark increases, but on the other hand, the crosstalk increases as the width approaches the track pitch. Will not work.
  • the track pitch is 0.32 m, so if the width of the information recording mark is 0.25, the crosstalk will be 20 dB (the carrier level of the recording track). And the carrier level of the adjacent track).
  • the degree of modulation is preferably 30% or more empirically in consideration of the ratio to the noise level, and if it is less than 30%, SZN is insufficient and is not practical.
  • the optimum value of the width P of the recording area differs depending on the diameter of the optical spot.
  • the light spot of the incident light L has a light distribution with a wide skirt called an airy disk, so that the information recording mark is usually smaller than the light spot. Therefore, when a signal is detected by the reflectance modulation method, the ratio of the reflectance in the information recording mark to the reflectance before recording becomes larger than the modulation degree of the detection signal.
  • FIG. 4B shows the result of measuring the modulation of the reproduction detection signal while changing the width of the recording area of the first information recording layer 21 in the range of 0.04 to 0.28 m. .
  • the modulation factor was 50% as described above, but as shown in Fig. 4B, when the width of the recording area became narrower, the modulation factor decreased. It turns out that it falls.
  • the guide groove was formed by exposing the fore-registry with an electron beam in the mastering process. However, if the width was too narrow, the disturbance of the wall surface became conspicuous, resulting in an increase in noise level.
  • the degree of modulation was to some extent, the noise level increased and the SZN decreased, so that it was not practical with a recording area width of 0.09 m or less. At 0.22 m, the degree of modulation decreased to about 30%, and the S / N also decreased, which was not practical.
  • first information recording layer 21 and the second information recording layer 22 show completely different characteristics depending on the width of the recording area. This is considered to be because the reflectance in the information recording mark after recording is significantly different between the first information recording layer 21 and the second information recording layer 22.
  • the optical recording medium has two or three information recording layers 21, 22, and 23 made of an organic dye and allows light to enter from the side opposite to the substrate 11.
  • the present invention is applied to 10
  • the present invention can be applied to other configurations.
  • the substrate is made a transparent substrate, and a reflective layer is provided on the opposite side of the information recording layer farthest from the substrate. .
  • the material of the information recording layer is not limited to the organic dye, and other materials can be used.
  • the type of optical disc is not limited to write-once type
  • the shape of the optical recording medium is not limited to a disk as long as a plurality of information recording layers are provided and light can be incident on the plurality of information recording layers.
  • the first information recording layer farthest from one main surface, which is a light incident surface is a phase modulation type information recording layer, regardless of the configuration of the optical recording medium.
  • the recording layer is configured to be a reflectance modulation type information recording layer.
  • a signal is detected by the phase modulation method for the first information recording layer, and a signal is detected by the reflectance modulation method for the other information recording layers.
  • a signal can be detected with a high degree of modulation.
  • the reflectance can be increased by the reflection layer, so that the signal from the first information recording layer can be sufficiently detected. You can do it.
  • the recording film constituting the information recording layer is formed of an organic dye film
  • the production can be further simplified and the price can be reduced.

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Abstract

An optical recording medium having two or more information recording layers in which information is recorded at high recording density. The incidence of light on the information recording layer disposed far from the top layer through which light enters and the returning light from the information recording layer can be detected at high efficiency. The recording/reproducing characteristics are favorable. An optical recording/reproducing method for at least reproducing/recording information from/on this optical recording medium is also disclosed. The optical recording medium (10) comprises information recording layers (21, 22) between a first major surface on which light can be incident and a second major surface opposed to the first major surface. The first information recording layer (21) nearest to the second major surface is a phase-modulation information recording layer, and the second information recording layer (22) is a reflectance-modulation information recording layer. Information is reproduced or recorded from or in the first information recording medium (21) of the optical recording medium (10) by a phase modulation method, and information is reproduced or recorded from or in the second information recording layer (22) by a reflectance modulation method.

Description

明細書  Specification
光記録再生方法及び光記録媒体 技術分野  Optical recording / reproducing method and optical recording medium
本発明は、 少なく とも情報の再生又は記録を行う光記録再生方 法及び光記録媒体に係わる。 背景技術  The present invention relates to an optical recording / reproducing method for at least reproducing or recording information and an optical recording medium. Background art
光記録媒体、 例えば光ディ スクにおける高記録密度化は、 通常 、 照射光の短波長化及び対物レンズの開口数を上げる方法によつ て実現しているが、 更にこの方法と情報保持層即ち情報記録層の 多層化とを組み合わせるこ とにより、 飛躍的な高密度化の実現が 可能となる。  Higher recording densities in optical recording media, for example, optical discs, are usually realized by a method of shortening the wavelength of irradiation light and increasing the numerical aperture of an objective lens. By combining this with the multi-layered information recording layer, a dramatic increase in density can be realized.
しかし、 光記録媒体において、 情報記録層の多層化即ち複数の 情報記録層の積層がなされると、 各情報記録層における光吸収に よって、 光記録媒体に対する光入射側の主面 (入射面) から見て 遠い位置にある情報記録層ほど光の到達量が低下するという問題 力 ある。  However, in an optical recording medium, when the information recording layers are multi-layered, that is, when a plurality of information recording layers are stacked, the main surface (incident surface) on the light incident side of the optical recording medium due to light absorption in each information recording layer. There is a problem that the farther the information recording layer is from the viewpoint, the lower the amount of light that can reach.
これは、 複数の情報記録層に対して単一光源を使用する場合に は避けられない問題である。  This is an inevitable problem when a single light source is used for a plurality of information recording layers.
また、 情報記録層からの戻り光、 即ち再生検出光についても同 様であり、 入射面から遠い位置にある情報記録層に対する戻り光 は、 その光検出がなされる途上で、 光記録媒体の光入射面側に位 置する他の情報記録層を透過して戻されることから、 その光量が 低下する。  The same applies to the return light from the information recording layer, that is, the reproduction detection light. The return light to the information recording layer at a position far from the incident surface is the light of the optical recording medium while the light is being detected. Since the light passes through the other information recording layer located on the incident surface side and returns, the amount of light decreases.
従って、 入射面から遠い情報記録層ほど、 その反射率を高く設 定する必要がある。 また同時に、 その変調度も同程度に高い必要 力 ある。 ところで、 光記録媒体例えば光ディスクの検出原理は、 2通り に大別することができる。 Therefore, it is necessary to set the reflectance higher for an information recording layer farther from the incident surface. At the same time, the degree of modulation needs to be as high as possible. By the way, the principle of detecting an optical recording medium, for example, an optical disk can be roughly classified into two types.
1つは、 C D— R O M ( Compact Disc-Read Only Memory ) 丁 イ スクゃ、 追記型の C D或いは D V D ( Digital Versatile Disc ) の、 いわゆる C D— R或いは D V D— R等に代表される、 位相 変調方式である。  One is the phase modulation method represented by the so-called CD-R or DVD-R of a CD-ROM (Compact Disc-Read Only Memory) disk, a write-once CD or DVD (Digital Versatile Disc). It is.
この位相変調方式では、 情報記録マーク中の反射率とその周辺 の反射率とを同一と して反射率を一定とする一方で、 情報記録マ ―クにおける光路長とその周辺における光路長とを異ならせるこ とにより、 反射光の位相を変化させて光スポッ ト内で干渉を起こ し、 結果と して戻り光量を変化させるものである。  In this phase modulation method, while the reflectance in an information recording mark and the reflectance in the vicinity thereof are made equal to make the reflectance constant, the optical path length in the information recording mark and the optical path length in the vicinity are determined. By making them different, the phase of the reflected light changes, causing interference in the light spot, and as a result, the amount of return light changes.
他の 1つは、 書き換え可能型の C D或いは D V Dである、 いわ ゆる C D— R Wや D V D— R W等における相変化材料を用いた光 ディ スクに代表される、 反射率変調方式である。 この反射率変調 方式では、 情報記録マーク中の反射率がその周囲の反射率より も 低いことを利用して、 反射率の違いによる戻り光の光量変化を直 接検出する ものである。  The other is a reflectivity modulation method represented by an optical disk using a phase-change material such as a rewritable CD or DVD, that is, a so-called CD-RW or DVD-RW. In this reflectance modulation method, a change in the amount of return light due to a difference in reflectance is directly detected by utilizing the fact that the reflectance in an information recording mark is lower than the surrounding reflectance.
ところで、 上述した C D— Rや D V D— Rに代表される位相変 調方式における情報保持層即ち情報記録層は、 有機色素から成る 記録膜によって構成することが一般的である。 そして、 このよう に、 記録膜が有機色素材料によって構成される光記録媒体は、 そ の製造が容易で、 また材料の取り扱いが簡便であり、 廉価である などの利点を有する。  By the way, the information holding layer, that is, the information recording layer in the phase modulation method represented by the above-mentioned CDR and DVDR is generally constituted by a recording film made of an organic dye. As described above, the optical recording medium in which the recording film is made of the organic dye material has advantages such as easy production, easy handling of the material, and low cost.
この位相変調方式にあっては、 記録前と後とで反射率が変化す ることなく、 ほぼ一定に保持されることが、 情報記録マークとそ の周辺とで効果的に干渉を起こさせる上で必要になる。  In this phase modulation method, the reflectance is maintained almost constant without changing before and after recording, which causes effective interference between the information recording mark and its surroundings. Is needed.
このために、 実際に C D— R等においては、 その有機色素から 成る記録膜によつて構成される情報記録層に対して、 厚い A u も しく は A g等による金属膜が積層された構造として、 記録の前後 で反射率変化を来たすことがないように構成されている。 For this reason, in the case of a CD-R or the like, a thick Au is required for the information recording layer composed of the recording film composed of the organic dye. Alternatively, the structure is such that a metal film of Ag or the like is laminated so that the reflectance does not change before and after recording.
ところが、 このように、 膜厚を大き く した金属膜を情報記録層 に積層させる構造を、 情報記録層の多層化に適用することは、 入 射面から遠い位置にある情報記録層に対して入射光が届かなく な るという問題が生じる。  However, applying a structure in which a metal film having a large thickness is laminated on an information recording layer to multi-layer the information recording layer as described above requires an information recording layer far from the incident surface to be applied to the information recording layer. There is a problem that the incident light cannot reach.
従って、 このような従来の有機色素から成る記録膜の設計を、 そのまま情報記録層の多層化に適用することはできない。 発明の開示  Therefore, such a conventional design of a recording film made of an organic dye cannot be directly applied to a multilayer information recording layer. Disclosure of the invention
本発明は、 光記録媒体に対して少なく とも情報の再生又は記録 を行う光記録再生方法とその記録媒体にあって、 その光記録媒体 の構成を、 2層以上の情報記録層が積層された多層構造の光記録 媒体と し、 光記録媒体の入射側から遠い位置にある情報記録層に 対して、 高効率をもって光入射及び戻り光の検出を行うことがで きるようにする。  The present invention relates to an optical recording / reproducing method for at least reproducing / recording information on an optical recording medium and the recording medium, wherein the configuration of the optical recording medium is such that two or more information recording layers are laminated. An optical recording medium having a multi-layered structure, capable of detecting light incident and returned light with high efficiency on an information recording layer located far from the incident side of the optical recording medium.
また、 本発明においては、 光記録媒体の多層の情報記録層を、 共に有機色素から成る記録膜によつて構成することを可能にして 、 製造の簡易化、 価格の低廉化を図り、 しかも各情報記録層に関 して良好な記録再生特性が得られるようにした光記録媒体及び光 記録再生方法を提供するものである。  Further, in the present invention, the multilayer information recording layer of the optical recording medium can be constituted by a recording film made of an organic dye, thereby simplifying the production and reducing the price. It is an object of the present invention to provide an optical recording medium and an optical recording / reproducing method capable of obtaining good recording / reproducing characteristics for an information recording layer.
本発明の光記録再生方法は、 光記録媒体に対して少なく とも情 報の再生又は記録を行う方法であって、 光記録媒体として、 光記 録媒体に対する光入射側の一の主面と、 これとは反対側の他の主 面との間に複数の情報記録層とを有し、 他の主面に最も近い第 1 の情報記録層が位相変調型情報記録層とされ、 他の情報記録層が 反射率変調型情報記録層とされた光記録媒体を用い、 一の主面側 からの光入射により、 第 1 の情報記録層に対しては位相変調方式 により情報の再生又は記録を行い、 他.の情報記録層に対しては反 射率変調方式により情報の再生又は記録を行う ものである。 The optical recording / reproducing method of the present invention is a method for reproducing or recording at least information on an optical recording medium, and as the optical recording medium, one main surface on the light incident side of the optical recording medium; It has a plurality of information recording layers between it and the other main surface on the opposite side, and the first information recording layer closest to the other main surface is the phase modulation type information recording layer, Using an optical recording medium in which the recording layer is a reflectance modulation type information recording layer, the first information recording layer is phase-modulated by light incident from one main surface side. In this case, information is reproduced or recorded in accordance with the method described above, and information is reproduced or recorded in the other information recording layer in accordance with the reflectance modulation method.
本発明の光記録媒体は、 光を入射させることが可能な一の主面 と、 この一の主面とは反対側の他の主面との間に複数の情報記録 層とを有し、 他の主面に最も近い第 1の情報記録層が位相変調型 情報記録層とされ、 他の情報記録層が反射率変調型情報記録層と されたものである。  The optical recording medium of the present invention has one main surface through which light can enter, and a plurality of information recording layers between the other main surface opposite to the one main surface, The first information recording layer closest to the other main surface is a phase modulation type information recording layer, and the other information recording layer is a reflectance modulation type information recording layer.
また、 上述の本発明の光記録再生方法に用いる光記録媒体、 並 びに上述の本発明の光記録媒体において、 複数の情報記録層の少 なく とも 1層以上の情報記録層を光吸収により物性変化を起こし て光学定数の変化を起こす有機材料を含有する構成とすることが でき、 この有機材料と して有機色素を用いることができる。  Further, in the optical recording medium used in the optical recording / reproducing method of the present invention described above, and in the optical recording medium of the present invention described above, at least one information recording layer of a plurality of information recording layers has physical properties by light absorption. A structure containing an organic material that causes a change to cause a change in an optical constant can be provided, and an organic dye can be used as the organic material.
上述の本発明の光記録再生方法によれば、 光入射側の一の主面 とその反対側の他の主面との間に複数の情報記録層とを有し、 他 の主面に最も近い第 1 の情報記録層が位相変調型情報記録層とさ れ、 他の情報記録層が反射率変調型情報記録層とされた光記録媒 体を用い、 一の主面側からの光入射により、 第 1の情報記録層に 対しては位相変調方式により情報の再生又は記録を行い、 他の情 報記録層に対しては反射率変調方式により情報の再生又は記録を 行う ことにより、 光記録媒体の一の主面側から光を入射させて、 光記録媒体の複数の情報記録層に対して情報の再生や記録を行う ことが可能になる。  According to the optical recording / reproducing method of the present invention described above, a plurality of information recording layers are provided between one main surface on the light incident side and the other main surface on the opposite side, and the other main surface has Using an optical recording medium in which the near first information recording layer is a phase modulation type information recording layer and the other information recording layer is a reflectance modulation type information recording layer, light incidence from one principal surface side By reproducing or recording information on the first information recording layer by a phase modulation method, and by reproducing or recording information on another information recording layer by a reflectance modulation method, It is possible to reproduce and record information on a plurality of information recording layers of the optical recording medium by irradiating light from one main surface side of the recording medium.
上述の本発明の光記録媒体の構成によれば、 他の主面に最も近 い第 1 の情報記録層が位相変調型情報記録層とされているので、 第 1 の情報記録層に対して位相変調方式により信号検出を行うこ とができる。 また、 他の情報記録層は反射率変調型情報記録層と されているので、 反射率変調方式により信号検出を行うことがで さる。 . 尚、 本発明による光記録再生方法に用いる光記録媒体においてAccording to the configuration of the optical recording medium of the present invention described above, the first information recording layer closest to the other main surface is a phase modulation type information recording layer. Signal detection can be performed by a phase modulation method. Further, since the other information recording layer is a reflectance modulation type information recording layer, signal detection can be performed by a reflectance modulation method. . In the optical recording medium used in the optical recording / reproducing method according to the present invention,
、 第 1 の情報記録層と更に他の情報記録層を有機色素膜によって 構成する場合、 記録の前後で屈折率の変化を起こすことを記録原 理とするものである。 つま り、 例えば記録前の有機色素膜の屈折 率を、 隣接する層例えば基板の屈折率と大きく異なるように設定 して、 有機色素膜とこれに接する他の材料層との界面において反 射が生じる.ようにすると共に、 記録後の有機色素膜の屈折率を、 上述の界面を形成する他の材料層の屈折率に近.くなるように設定 して、 有機色素膜と基板との界面における反射率を低下させるこ とにより、 記録情報信号の検出を反射率を直接検出するいわゆる 反射率変調型情報記録層とすることができる。 In the case where the first information recording layer and the other information recording layer are formed of an organic dye film, the principle of recording is to cause a change in the refractive index before and after recording. In other words, for example, the refractive index of the organic dye film before recording is set so as to be significantly different from the refractive index of the adjacent layer, for example, the substrate, and the reflection at the interface between the organic dye film and another material layer in contact with the organic dye film. At the same time, the refractive index of the organic dye film after recording is set to be close to the refractive index of the other material layer forming the above-described interface, and the interface between the organic dye film and the substrate is set. By reducing the reflectance in the above, it is possible to detect a recording information signal as a so-called reflectance modulation type information recording layer that directly detects the reflectance.
一方、 このような屈折率変化による記録によつて光路長を変化 させ位相変調型情報記録層をも構成することができるものである  On the other hand, the phase modulation type information recording layer can be formed by changing the optical path length by recording by such a change in the refractive index.
図面の簡単な説明 BRIEF DESCRIPTION OF THE FIGURES
図 1 は、 本発明の一実施の形態の光ディ スクの概略構成図 (断 面図) であり、 図 2 は、 情報記録層を 3層とした光ディ スクの断 面図であり、 図 3 は、 図 1 の光ディ スクに対して、 情報の再生や 記録を行う光学ピックァップの一形態の概略構成図であり、 図 4 A及び図 4 Bは、 情報記録層の案内溝の幅を変えて変調度を測定 した結果を示す図である。 発明を実施するための最良の形態  FIG. 1 is a schematic configuration diagram (cross-sectional view) of an optical disc according to an embodiment of the present invention. FIG. 2 is a cross-sectional view of the optical disc having three information recording layers. FIG. 3 is a schematic configuration diagram of an embodiment of an optical pickup for reproducing and recording information with respect to the optical disc of FIG. 1, and FIGS. 4A and 4B show the width of the guide groove of the information recording layer. FIG. 9 is a diagram showing the result of measuring the modulation factor while changing. BEST MODE FOR CARRYING OUT THE INVENTION
本発明は、 光記録媒体に対して少なく とも情報の再生又は記録 を行う方法であって、 光記録媒体として、 光記録媒体に対する光 入射側の一の主面と、 これとは反対側の他の主面との間に複数の 情報記録層とを有し、 他の主面に最も近い第 1の情報記録層が位 相変調型情報記録層とされ、 他の情報記録層が反射率変調型情報 記録層とされた光記録媒体を用い、 一の主面側からの光入射によ り、 第 1 の情報記録層に対しては位相変調方式により情報の再生 又は記録を行い、 他の情報記録層に対しては反射率変調方式によ り情報の再生又は記録を行う光記録再生方法である。 The present invention relates to a method for at least reproducing or recording information on an optical recording medium, wherein the optical recording medium has one main surface on a light incident side with respect to the optical recording medium and another main surface on the opposite side. A plurality of information recording layers between the main surface and the first information recording layer closest to the other main surface. Using an optical recording medium with a phase modulation type information recording layer and another information recording layer with a reflectance modulation type information recording layer, the first information recording layer Is an optical recording / reproducing method in which information is reproduced or recorded by a phase modulation method, and information is reproduced or recorded in another information recording layer by a reflectance modulation method.
また本発明は、 上記光記録再生方法において、 光記録媒体の第 The present invention also provides the optical recording / reproducing method, wherein
1 の情報記録層では情報記録マーク中に相当する位置における記 録前の反射率を R。 として同位置の記録後の反射率を Rとすると きの変化率 (R。 — R ) Z R。 を情報記録マークの再生検出信号 の変調度より小とし、 他の情報記録層では情報記録マークの同様 の変化率 (R D - R ) Z R。 を情報記録マークの再生検出信号の 変調度以上とする。 In the information recording layer of No. 1, the reflectance before recording at the position corresponding to the information recording mark is R. Assuming that the reflectance after recording at the same position is R, the rate of change (R. — R) ZR. Is smaller than the modulation degree of the reproduction detection signal of the information recording mark, and the other information recording layer has the same rate of change of the information recording mark (R D -R) ZR. Is equal to or greater than the modulation degree of the reproduction detection signal of the information recording mark.
本発明は、 光を入射させることが可能な一の主面と、 この一の 主面とは反対側の他の主面との間に複数の情報記録層とを有し、 他の主面に最も近い第 1の情報記録層が位相変調型情報記録層と され、 他の情報記録層が反射率変調型情報記録層とされた光記録 媒体である。  The present invention has one main surface through which light can enter, and a plurality of information recording layers between the other main surface opposite to the one main surface. The first information recording layer closest to the optical recording medium is a phase modulation type information recording layer, and the other information recording layer is a reflectance modulation type information recording layer.
また本発明は、 上記光記録媒体において、 反射率変調型情報記 録層の記録ェリアの幅を、 位相変調型情報記録層の記録ェリァの 幅より も広く した構成とする。  Further, the present invention provides the optical recording medium, wherein the width of the recording area of the reflectance modulation type information recording layer is wider than the width of the recording area of the phase modulation type information recording layer.
また本発明は、 上記光記録媒体において、 第 1の情報記録層は 情報記録マーク中に相当する位置における記録前の反射率を R。 と して同位置の記録後の反射率を Rとするときの変化率 (R。 一 R ) Z R。 が情報記録マークの再生検出信号の変調度より小とさ れ、 他の情報記録層は情報記録マークの同様の変化率 (R。 - R The present invention also provides the optical recording medium, wherein the first information recording layer has a reflectance before recording at a position corresponding to an information recording mark. Assuming that the reflectance after recording at the same position is R, the rate of change (R.I.R) ZR. Is smaller than the modulation degree of the reproduction detection signal of the information recording mark, and the other information recording layers have the same rate of change of the information recording mark (R.-R
) Z R。 が情報記録マークの再生検出信号の変調度以上とされた 構成とする。 ) Z R. Is set to be equal to or higher than the modulation degree of the reproduction detection signal of the information recording mark.
また本発明は、 上記光記録媒体において、 複数の情報記録層の うち少なく とも 1層以上の情報記録層が、 光吸収により光学定数 の変化を起こす記録膜により形成されている構成とする。 Further, the present invention provides the optical recording medium, wherein a plurality of information recording layers are provided. At least one or more of the information recording layers is formed of a recording film whose optical constant changes due to light absorption.
また本発明は、 上記光記録媒体において、 さ らに記録膜が光吸 収により物性変化を起こ して光学定数の変化を起こす有機材料を 含有する構成とする。  Further, the present invention provides the above-mentioned optical recording medium, wherein the recording film further contains an organic material which causes a change in physical properties due to light absorption to cause a change in an optical constant.
また本発明は、 上記光記録媒体において、 さ らに有機材料とし て有機色素を用いる構成とする。  Further, the present invention is configured such that in the optical recording medium, an organic dye is further used as an organic material.
また本発明は、 上記光記録媒体において、 第 1の情報記録層の 他の主面側に反射層が設けられている構成とする。  Further, the present invention is configured such that in the optical recording medium, a reflection layer is provided on the other main surface side of the first information recording layer.
図 1 は、 本発明の一実施の形態として、 光ディ スクの概略構成 図 (断面図) を示す。  FIG. 1 shows a schematic configuration diagram (cross-sectional view) of an optical disk as one embodiment of the present invention.
この光ディ スク 1 0 は、 基板 1 1上に、 反射層 1 2、 第 1の情 報記録層 2 1、 中間層 1 3、 第 2 の情報記録層 2 2、 表面保護層 (光透過層) 1 4 とを積層して構成されている。  The optical disc 10 has a reflective layer 12, a first information recording layer 21, an intermediate layer 13, a second information recording layer 22, and a surface protective layer (light transmitting layer) on a substrate 11. 1) and 4 are laminated.
即ち情報記録層を第 1 の情報記録層 2 1及び第 2 の情報記録層 That is, the information recording layer is composed of the first information recording layer 21 and the second information recording layer.
2 2 の 2層としている。 . 2 2 layers. .
また、 本実施の形態の光ディ スク 1 0では、 基板 1 1側からで はなく、 基板 1 1 とは反対の側即ち表面保護層 1 4側から光 Lを 入射させる構成となっている。  Further, the optical disc 10 of the present embodiment has a configuration in which the light L is incident not from the substrate 11 side but from the side opposite to the substrate 11, that is, from the surface protective layer 14 side.
基板 1 1上及び中間層 1 3上には、 図示しないが案内溝を設け て、 それぞれ第 1の情報記録層 2 1 と第 2の情報記録層 2 2の ト ラ ッキングができるようにする。  Guide grooves (not shown) are provided on the substrate 11 and the intermediate layer 13 so that the first information recording layer 21 and the second information recording layer 22 can be tracked, respectively.
第 1 の情報記録層 2 1又は第 2 の情報記録層 2 2には、 光吸収 により光学定数の変化を起こす膜を用いることができる。  As the first information recording layer 21 or the second information recording layer 22, a film that changes the optical constant due to light absorption can be used.
尚、 第 1 の情報記録層 2 1又は第 2 の情報記録層 2 2のうち、 一方のみを光吸収により光学定数の変化を起こす膜としてもよい o  In addition, only one of the first information recording layer 21 and the second information recording layer 22 may be a film that changes the optical constant by light absorption.
光吸収により光学定数が変化することにより、 情報記録層の屈 折率が変化する。 The optical constant changes due to light absorption, causing the information recording layer to buckle. The folding ratio changes.
そして、 これら第 1の情報記録層 2 1及び第 2の情報記録層 2 2 は、 有機材料膜例えば有機色素膜により構成することができる o  The first information recording layer 21 and the second information recording layer 22 can be formed of an organic material film, for example, an organic dye film.
この有機色素膜は、 光吸収により物性変化 (例えば熱分解を起 こ し分子構造が変化する、 又は分子はそのままで分子配列が変化 する、 或いはこれらの複合) する材料により構成する。  The organic dye film is made of a material that changes its physical properties by light absorption (for example, the molecular structure changes due to thermal decomposition, or the molecular arrangement changes as it is, or a composite thereof).
このような有機色素膜と しては、 従来公知の材料、 例えばト リ フェニルァ ミ ン 4量体等を用いることができる。  As such an organic dye film, a conventionally known material, for example, triphenylamine tetramer or the like can be used.
このように情報記録層を構成する記録膜を有機色素膜により形 成したときには、 製造の簡易化、 価格の低廉化を図ることができ る利点を有する。  When the recording film constituting the information recording layer is formed of an organic dye film in this manner, there is an advantage that the production can be simplified and the price can be reduced.
反射層 1 2 と しては、 入射光 Lに対する反射率の大きい膜を形 成する。  As the reflection layer 12, a film having a high reflectance with respect to the incident light L is formed.
この反射層 1 2 には、 金属膜例えば A g合金スパッタ膜等を用 いることができる。  As the reflection layer 12, a metal film, for example, an Ag alloy sputtered film or the like can be used.
中間層 1 3及び表面保護層 1 4には、 入射光 Lに対する透過率 の大きい材料を用いる。 例えば U V硬化性樹脂を用いることがで さる。  For the intermediate layer 13 and the surface protective layer 14, a material having a high transmittance to the incident light L is used. For example, a UV curable resin can be used.
中間層 1 3の厚さは、 好ま しく は 5〜 5 0 μ mとする。  The thickness of the intermediate layer 13 is preferably 5 to 50 μm.
さ らに、 第 1 の情報記録層 2 1を、 位相変調方式により情報の 再生又は記録が可能な位相変調型情報記録層とする。  Further, the first information recording layer 21 is a phase modulation type information recording layer capable of reproducing or recording information by a phase modulation method.
そのために、 情報記録マ一ク中に相当する位置における記録前 の反射率を R。 と し、 同位置の記録後の反射率を Rとしたときの 変化率 (R。 — R ) Z R。 力^ 情報記録マークの再生検出信号の 変調度より小となるように形成する。  Therefore, the reflectance before recording at the position corresponding to the information recording mark before the recording is R. Where R is the reflectance after recording at the same position (R. — R) ZR. The force is formed so as to be smaller than the modulation degree of the reproduction detection signal of the information recording mark.
これにより、 記録前後の反射率の変化が非常に小さ くなるため 、 位相変調方式により変調された信号を検出することが可能にな り、 第 1 の情報記録層 2 1 を位相変調型情報記録層とすることが できる。 This makes it possible to detect a signal modulated by the phase modulation method, since the change in reflectance before and after recording is very small. Thus, the first information recording layer 21 can be a phase modulation type information recording layer.
このように記録前後の反射率の変化が非常に小さ くなるように するために、 第 1の情報記録層 2 1では、 光の入射面とは反対側 に反射層 1 2を設けている。 また、 充分な変調度の信号が得られ かつ S Z Nを高くするように、 読み出し光学系の光源の波長ス と 集光レンズの開口数 N Aに対応して記録ェリァの幅を規定する。  In order to make the change in reflectance before and after recording extremely small, the first information recording layer 21 is provided with the reflection layer 12 on the side opposite to the light incident surface. In addition, the width of the recording area is defined in accordance with the wavelength of the light source of the readout optical system and the numerical aperture NA of the condenser lens so that a signal with a sufficient degree of modulation is obtained and SZN is increased.
このように、 第 1 の情報記録層 2 1 に対して、 比較的反射率の 大きい材料が用いられる反射層 1 2が光の入射面とは反対側に設 けられていることにより、 第 1 の情報記録層 2 1 における記録前 の反射率も記録後の反射率も、 共に反射層 1 2の反射率に近く な そして、 情報記録マークと記録前の情報記録層 2 1 とでは光学 定数が異なり屈折率が異なるので、 反射層 1 2 まで往復する間の 光路長が異なつてく る。  As described above, the first information recording layer 21 is provided with the reflection layer 12 made of a material having a relatively high reflectance on the side opposite to the light incident surface. Both the reflectance of the information recording layer 21 before recording and the reflectance after recording are close to the reflectance of the reflection layer 12, and the optical constant between the information recording mark and the information recording layer 21 before recording is low. Since the refractive index is different, the optical path length during the round trip to the reflective layer 12 is different.
これにより、 位相変調方式により変調された信号を検出するこ とが可能になる。  This makes it possible to detect a signal modulated by the phase modulation method.
一方、 第 2の情報記録層 2 2を、 反射率変調方式により情報の 再生又は記録が可能な反射率変調型情報記録層とする。  On the other hand, the second information recording layer 22 is a reflectance modulation type information recording layer capable of reproducing or recording information by a reflectance modulation method.
そのために、 情報記録マーク中に相当する位置における記録前 の反射率を R。 とし、 同位置の記録後の反射率を Rとしたときの 変化率 (R。 - R ) / R。 が情報記録マークの再生検出信号の変 調度以上となるように形成する。  Therefore, the reflectance before recording at the position corresponding to the information recording mark before recording is R. And the reflectance after recording at the same position as R, the rate of change (R.-R) / R. Is formed so as to be equal to or higher than the modulation degree of the reproduction detection signal of the information recording mark.
これにより、 記録前後の反射率の変化が大き く なるため、 反射 率変調方式により変調された信号を検出することが可能になり、 第 2 の情報記録層 2 2を反射率変調型情報記録層とすることがで きる。  As a result, since the change in reflectance before and after recording becomes large, it is possible to detect a signal modulated by the reflectance modulation method, and the second information recording layer 22 is used as a reflectance modulation type information recording layer. It can be
そして、 充分な変調度の信号が得られかつ S Z Nが高く なるよ うに、 第 2 の情報記録層 2 2では、 読み出し光学系の光源の波長 λ と集光レンズの開口数 Ν Αに対応して記録ェリァの幅を規定す o And a signal with a sufficient degree of modulation is obtained and SZN becomes high. Thus, in the second information recording layer 22, the width of the recording area is defined in accordance with the wavelength λ of the light source of the readout optical system and the numerical aperture 集 光 of the condenser lens.
従って、 第 1 の情報記録層 2 1 と同じ材料を使用して構成して いても、 記録エリアの幅が異なることがある。  Therefore, the width of the recording area may be different even if the first information recording layer 21 is formed using the same material.
さ らに、 2層の情報記録層 2 1, 2 2を構成する記録膜を有機 色素膜により形成したときには次のように作用する。  Further, when the recording films constituting the two information recording layers 21 and 22 are formed of organic dye films, the following operation is performed.
この場合には、 記録の前後で屈折率の変化を起こすため、 記録 膜に対して反射膜を設けなく ても信号検出することも可能である o  In this case, since the refractive index changes before and after recording, it is possible to detect signals without providing a reflective film to the recording film.o
つま り、 記録前の有機色素膜の屈折率を、 隣接する層例えば基 板の屈折率と大き く異なるように設定して、 有機色素膜と基板の 界面において反射が生じるようにすると共に、 記録後の有機色素 膜の屈折率を基板の屈折率に近く なるように設定して、 有機色素 膜と基板の界面における反射率を低下させる。 これにより、 信号 を検出することが可能になる。  In other words, the refractive index of the organic dye film before recording is set so as to be significantly different from the refractive index of an adjacent layer, for example, the substrate, so that reflection occurs at the interface between the organic dye film and the substrate, and the recording is performed. The refractive index of the subsequent organic dye film is set so as to be close to the refractive index of the substrate to reduce the reflectance at the interface between the organic dye film and the substrate. This makes it possible to detect the signal.
この場合は、 反射率を直接検出するので、 反射率変調方式によ り情報の再生又は記録が行われる。  In this case, since the reflectance is directly detected, the information is reproduced or recorded by the reflectance modulation method.
一方、 記録膜に対して反射層 1 2を設けると、 記録の前後で反 射率の変化が小さ く なり、 上述の屈折率の変化により記録膜内の 光路長が変化するため、 反射した戻り光の位相を記録の前後で変 化させる。 これにより、 位相の異なる戻り光の干渉を利用して信 号を検出することが可能になる。  On the other hand, when the reflective layer 12 is provided on the recording film, the change in the reflectance before and after the recording becomes small, and the above-described change in the refractive index changes the optical path length in the recording film. Changes the phase of light before and after recording. This makes it possible to detect a signal by using the interference of return lights having different phases.
この場合は、 位相変調方式により情報の再生又は記録が行われ 従って、 情報記録層 2 1, 2 2 を構成する記録膜を有機色素膜 により形成したときには、 反射層 1 2の有無によって、 位相変調 方式或いは反射率変調方式のいずれにより情報の再生又は記録を 行う構成ともすることができる。 In this case, the information is reproduced or recorded by the phase modulation method. Therefore, when the recording film constituting the information recording layers 21 and 22 is formed by the organic dye film, the phase modulation depends on the presence or absence of the reflection layer 12. Reproduction or recording of information by either It can also be configured to perform.
尚、 第 1 の情報記録層 2 1 と第 2 の情報記録層 2 2 において、 記録ヱリ アは、 案内溝による段差を間に有する 2つの面、 即ち光 の入射側に近い面 (ラ ン ド部) と、 光の入射側から遠い面 (グル —ブ部) とのうち、 どちらの面に設けてもよい。  In the first information recording layer 21 and the second information recording layer 22, the recording area has two surfaces having a step formed by the guide groove therebetween, that is, a surface close to the light incident side (lane). And the surface farther from the light incident side (groove) may be provided on either surface.
ラ ン ド部とグループ部のいずれに記録エリァを設ける場合でも 、 入射光 Lのスポッ 卜の大きさ (光源の波長; I及び対物レンズの 開口数 N Aに応じて決まる) に対応して、 反射率変調方式或いは 位相変調方式によって充分な変調度が得られ、 情報記録層 2 1, 2 2 の情報の再生又は記録が可能となるように、 記録ェリアの幅 Regardless of whether the recording area is provided in the land section or the group section, reflection is performed in accordance with the spot size of the incident light L (wavelength of the light source; determined according to I and the numerical aperture NA of the objective lens). The width of the recording area is adjusted so that a sufficient degree of modulation can be obtained by the rate modulation method or the phase modulation method, and the information can be reproduced or recorded on the information recording layers 21 and 22.
¾r a¾. £ "5 - ) o ¾r a¾. £ "5-) o
例えば、 光源の波長; lが 4 0 5 n m、 対物レンズの開口数 N A が 0 . 8 5 のときには、 反射率変調方式を採用するためには記録 エリ アの幅を 0 . 1 2〜 0 . 2 5 mとすることが望ましく、 位 相変調方式を採用するためには記録ェリ アの幅を 0 . 0 9〜 0 . 2 2 mとすることが望ま しい。  For example, when the wavelength of the light source; l is 405 nm and the numerical aperture NA of the objective lens is 0.85, the width of the recording area must be 0.12 to 0.1 to adopt the reflectance modulation method. It is preferable that the width of the recording area be 0.09 to 0.22 m in order to adopt the phase modulation method.
光源の波長スは、 例えば 3 6 0〜 4 6 0 n mの範囲内とすれば 、 C D— R等の通常の光ディ スクより短い波長となるので、 光ス ポッ 卜の大きさを小さ くすることができ、 光記録媒体の記録密度 を向上することができる。  If the wavelength of the light source is, for example, in the range of 360 to 460 nm, the wavelength becomes shorter than that of a normal optical disc such as a CD-R, so that the size of the optical spot is reduced. Thus, the recording density of the optical recording medium can be improved.
第 1 の情報記録層 2 1及び第 2の情報記録層 2 2 は、 同一の光 へッ ドにより再生や記録を行う ことが可能である。  The first information recording layer 21 and the second information recording layer 22 can perform reproduction and recording with the same optical head.
. 有機色素膜から成る情報記録層を 1層有する光ディ スクに再生 や記録を行うための光ヘッ ドを有する光学ピックアップを用いて 、 例えばフォーカシング (フォーカス合わせ) のための光デイ ス クの主面に略垂直な方向の移動により、 入射光 Lによる光スポッ トを第 1 の情報記録層 2 1 と第 2 の情報記録層 2 2 との間で移動 させて、 それぞれの情報記録層 2 1又は 2 2に対して情報の再生 や記録を行う こ とができ る。 Using an optical pickup with an optical head for reproducing and recording on an optical disc with one information recording layer composed of an organic dye film, the optical disc for focusing (focusing) can be used, for example. The light spot caused by the incident light L is moved between the first information recording layer 21 and the second information recording layer 22 by moving in a direction substantially perpendicular to the surface, and the respective information recording layers 21 are moved. Or reproduction of information for 22 And record.
こ こで、 上述の本実施の形態の構成の先ディ スク 1 0に対して Here, with respect to the first disk 10 of the configuration of the present embodiment described above,
、 情報の再生や記録を行う光学ピックアツプの一形態の概略構成 図を図 3 に示す。 FIG. 3 shows a schematic configuration diagram of an embodiment of an optical pickup for reproducing and recording information.
この光学ピッ クアップは、 光源 5 1 と、 グレーティ ング 5 2 と This optical pick-up consists of a light source 51 and a grating 52
、 偏光ビームスプリ ッタ ( P B S ) 5 3 と、 ス / 4板 5 4 と、 対 物レンズ 5 5 と、 ウ ォ ラ ス ト ンプリズム 5 6 と、 集光レンズ及び シリ ン ドリ カルレンズとなるレンズ群 5 7 と、 光検出部 5 8 とを 備えて成る。 光源 5 1 は、 図示しないが例えば波長 4 0 5 n mの レーザ光を出射する半導体レーザと、 コリメータ と、 アナモプリ ズムを備えたュニッ ト と して構成されている。 対物レンズ 5 5 は 2枚の光学レンズにより構成されている。 光検出部 5 8は、 サ一 ボディ テクタ及び R Fディ テクタとして作用するものである。 , A polarizing beam splitter (PBS) 53, a quarter-wave plate 54, an objective lens 55, a Wollaston prism 56, and a lens group serving as a condenser lens and a cylindrical lens 5 7 and a photodetector 58. Although not shown, the light source 51 is configured as a unit including a semiconductor laser that emits laser light having a wavelength of, for example, 405 nm, a collimator, and anamorphism. The objective lens 55 is composed of two optical lenses. The light detecting section 58 functions as a sub-body detector and an RF detector.
このような構成の光学ピックアップにより、 光ディ スク 4 0が 、 上述の本実施の形態の光ディ スク 1 0であっても、 有機色素か ら成る情報記録層が 1層のみの光ディ スクであ ても、 情報の再 生や記録を行う ことが可能である。  With the optical pickup having such a configuration, even if the optical disk 40 is the optical disk 10 of the above-described embodiment, the optical disk has only one information recording layer made of an organic dye. Even so, it is possible to reproduce and record information.
上述の本実施の形態によれば、 第 1の情報記録層 2 1に隣接し て反射層 1 2 を設けたことにより、 反射層 1 2 により反射率を高 めて第 1 の情報記録層 2 1からの信号強度を大きくすることが可 能になり、 記録前後の反射率の変化を小さ くするこ とができ る。  According to the above-described embodiment, the reflection layer 12 is provided adjacent to the first information recording layer 21, and the reflectance is increased by the reflection layer 12, so that the first information recording layer 2 The signal intensity from 1 can be increased, and the change in reflectance before and after recording can be reduced.
そして、 情報記録マーク中に相当する位置における記録前後の 反射率の変化率 (R。 一 R ) / R。 を情報記録マークの再生検出 信号の変調度より小と しているため、 第 1の情報記録層 2 1に対 する情報の再生や記録に位相変調方式を採用することが可能にな る o  Then, the change rate of the reflectance before and after recording at the position corresponding to the information recording mark (R.I.R) / R. Is smaller than the modulation degree of the information recording mark reproduction detection signal, so that the phase modulation method can be used for reproducing and recording information on the first information recording layer 21 o
一方、 第 2の情報記録層 2 2 は、 反射層を設けていないため、 第 2の情報記録層 2 2 における透過率を高めて、 充分な光量を第 1 の情報記録層 2 1 に到達させることができる。 On the other hand, since the second information recording layer 22 does not have a reflective layer, the transmittance of the second information recording layer 22 is increased so that a sufficient amount of light can be obtained. 1 information recording layer 2 1.
また、 情報記録マーク中に相当する位置における記録前後の反 射率の変化率 (R Q - R ) / R。 を情報記録マークの再生検出信 号の変調度より も大き く しているため、 第 2の情報記録層 2 2 に 対する情報の再生や記録に反射率変調方式を採用することが可能 になる。 Also, the rate of change of the reflectance before and after recording at a position corresponding to the information recording mark (R Q -R) / R. Is larger than the modulation degree of the reproduction detection signal of the information recording mark, it is possible to employ the reflectance modulation method for reproducing and recording information on the second information recording layer 22.
これにより、 例えば有機色素を情報記録層の材料として用いな がら、 2層以上の情報記録層 2 1 , 2 2を有する光ディ スク 1 0 を実現することができる。  This makes it possible to realize an optical disc 10 having two or more information recording layers 21 and 22 while using, for example, an organic dye as a material for the information recording layer.
そして、 このように情報記録層 2 1, 2 2が多層になることに より、 光ディ スク 1 0 の記録密度が飛躍的に上昇する。  Then, by forming the information recording layers 21 and 22 in multiple layers, the recording density of the optical disk 10 is dramatically increased.
また、 このように有機色素を情報記録層の材料と して用いたと き、 即ち情報記録層を構成する記録膜を有機色素膜により形成し たときには、 さ らに製造の簡易化や、 価格の低廉化を図ることが できる。  In addition, when the organic dye is used as a material of the information recording layer, that is, when the recording film constituting the information recording layer is formed of the organic dye film, further simplification of manufacturing and cost reduction are achieved. The cost can be reduced.
尚、 各情報記録層 2 1, 2 2 と中間層 1 3 の間や、 第 2 の情報 記録層 2 2 と表面保護層 1 4 との間に誘電体保護膜を形成しても よい。  Note that a dielectric protection film may be formed between each of the information recording layers 21 and 22 and the intermediate layer 13 or between the second information recording layer 22 and the surface protection layer 14.
次に、 実際に上述の実施の形態の構成を有する光ディ スグを作 製して特性を調べた。  Next, an optical disk having the configuration of the above-described embodiment was actually manufactured and its characteristics were examined.
(実施例 1 )  (Example 1)
光源としてブル一 L D即ち発光色がブル一である半導体レーザ ダイォ一 ド (発振波長 4 0 5 n m ) を用い、 開口数 (N A ) が 0 . 8 5 の対物レンズを用いて光学系を構成した。  An optical system was constructed using a blue LD, ie, a semiconductor laser diode (emission wavelength: 405 nm) with a luminescent color, and a numerical aperture (NA) of 0.85 as the light source. .
そして、 光ディ スク 1 0 の各層の構成をこの光学系に最適化し "—  Then, the structure of each layer of the optical disk 10 was optimized for this optical system.
即ち光ディ スク 1 0の各層を下記の構成とした。  That is, each layer of the optical disc 10 had the following configuration.
基板 1 1 : ポリ 力一ポネ一 ト樹脂 反射層 1 2 : A g合金スパッタ膜 3 0 n m Substrate 11: Polycarbonate resin Reflective layer 1 2: Sputtered Ag alloy film 30 nm
第 1 の情報記録層 2 1 : 有機色素膜 ( ト リ フヱニルァミ ン 4量 体) 4 0 n m  First information recording layer 21: Organic dye film (triphenylamine tetramer) 40 nm
中間層 1 3 : U V硬化樹脂 3 0 m  Middle layer 13: UV cured resin 30 m
第 2 の情報記録層 2 2 : 有機色素膜 ( ト リ フヱニルァミ ン 4量 体) 4 0 n m  Second information recording layer 22: Organic dye film (triphenylamine tetramer) 40 nm
表面保護層 1 4 : U V硬化樹脂 8 Q m  Surface protective layer 14: UV cured resin 8 Qm
中間層 1 3 の膜厚は、 第 1 の情報記録層 2 1及び第 2 の情報記 録層 2 2の間のクロス トークを抑制するためには 1 5 β m以上が 望ま しいため、 3 0 mと した。  Since the thickness of the intermediate layer 13 is desirably 15 βm or more in order to suppress the crosstalk between the first information recording layer 21 and the second information recording layer 22, the thickness is 30 μm. m.
第 1 の情報記録層 2 1及び第 2 の情報記録層 2 2 には、 ト リ フ ェニルァミ ン 4量体、 より詳細には N, N ' —ビス ( 4 ージフエ ニルァ ミ ノ _ 4 一 ビフヱニル) 一 N, N ' —ジフヱニルベンジジ ンヽ 英語名称は N, ' -Bis(4-diphenylamino-4-biphenyl)-N, N' -di phenylbenzidine ( C a s N o . 7 2 1 8 — 4 6 — 4 ) を用いた o 以下ト リ フエニルアミ ンと略記する。  The first information recording layer 21 and the second information recording layer 22 each include a triphenylamine tetramer, more specifically, N, N'-bis (4-diphenylamino- 4-biphenyl). N, N'-diphenylbenzidine 6-4) is used. O Hereinafter, it is abbreviated as triphenylamine.
光源の波長 4 0 5 n mにおける ト リ フヱニルァミ ンの屈折率は 2 . 3 1、 吸収係数は 0 . 1 3である。 また、 記録後の屈折率は 2 . 1 となる。  At the wavelength of the light source of 450 nm, the refractive index of triphenylamine is 2.31, and the absorption coefficient is 0.13. The refractive index after recording is 2.1.
この ト リ フヱニルァミ ンは、 蒸着により成膜することができる This triphenylamine can be formed by vapor deposition.
O O
尚、 中間層 1 3及び表面保護層 1 4には、 商品名 S D - 3 0 1 の U V硬化樹脂を使用したが、 他の材料や、 U V硬化性粘着材を 用いる方法や、 ポリ力一ボネ一 卜シ一 トと粘着材の組み合わせで 形成することも可能である。  The intermediate layer 13 and the surface protective layer 14 were made of a UV-curable resin with the trade name SD-301, but other materials, a method using a UV-curable adhesive, It is also possible to form with a combination of one sheet and adhesive.
また、 反射層 1 2の材料については、 読み出し光学系の光源波 長での反射率が充分に高いものであればよいので、 上述したブル — L Dを光源とする場合には、 例えば A 1 をベースとした材料を 用いることも可能である。 Further, the material of the reflective layer 12 may be any material as long as the readout optical system has a sufficiently high reflectance at the wavelength of the light source. The base material It is also possible to use.
さ らに、 第 1及び第 2の情報記録層 2 1及び 2 2について、 ブ ル一 L Dを光源とする場合に最適化された他の有機色素材料を用 いることも可能である。 他の材料でスビンコ一 トゃスパッタが可 能なものがあれば、 スピンコー トやスパッ夕により情報記録層を 成膜してもよい。  Further, for the first and second information recording layers 21 and 22, it is also possible to use another organic dye material optimized when using a blue LD as a light source. If there is another material capable of spin-coat sputtering, the information recording layer may be formed by spin coating or sputtering.
上述した各材料を使用して、 次のように図 1 に示した構成の光 ディ スク 1 0 を作製した。  Using each of the above-described materials, an optical disk 10 having the configuration shown in FIG. 1 was manufactured as follows.
まず、 イ ンジヱクショ ン法により (第 1の情報記録層 2 1用の ) 案内溝が形成されたポリ カーボネー ト材料から成る基板 1 1を し /*—  First, a substrate 11 made of a polycarbonate material having guide grooves (for the first information recording layer 21) formed by an injection method is removed.
次に、 基板 1 1上に、 スパッ夕により A g合金膜を成膜して反 射層 1 2 を形成した。  Next, an Ag alloy film was formed on the substrate 11 by sputtering to form a reflective layer 12.
続いて、 反射層 1 2上に、 蒸着により ト リ フヱニルァミ ンを成 膜して第 1 の情報記録層 2 1を形成した。  Subsequently, a first information recording layer 21 was formed on the reflective layer 12 by forming a film of triphenylamine by vapor deposition.
次に、 第 1の情報記録層 2 1上に、 U V硬化樹脂から成る中間 層 1 3を形成した。  Next, an intermediate layer 13 made of a UV-curable resin was formed on the first information recording layer 21.
さ らに、 この中間層 1 3に対して、 (第 2 の情報記録層 2 2用 の) 案内溝の形状を有するスタンパを押し付けて、 U V硬化させ て案内溝を転写した。  Further, a stamper having a shape of a guide groove (for the second information recording layer 22) was pressed against the intermediate layer 13, and the guide groove was transferred by UV curing.
尚、 第 1 の情報記録層 2 1用の案内溝及び第 2の情報記録層 2 2用の案内溝において、 案内溝の トラック ピッチは共に 0 . 3 2 ^ mと した。 また、 案内溝の深さも共に 2 O n mとした。  The track pitch of the guide grooves in the guide grooves for the first information recording layer 21 and the guide grooves for the second information recording layer 22 was both 0.32 ^ m. In addition, the depth of each guide groove was set to 2 On m.
また、 第 1 の情報記録層 2 1及び第 2 の情報記録層 2 2におい て、 案内溝による段差のうち、 光の入射側に近い面即ちラン ド部 を記録ェリ アと した。  In the first information recording layer 21 and the second information recording layer 22, the surface near the light incident side, that is, the land portion, of the step formed by the guide groove was used as a recording area.
そして、 基板 1 1上に形成する第 1の情報記録層 2 1用の案内 溝は、 位相変調方式による検出信号を充分得るために、 記録エリ 531 ァ即ちラン ド部の幅が 0 . 1 2 mとなるようにした。 The guide groove for the first information recording layer 21 formed on the substrate 11 has a recording area for sufficiently obtaining a detection signal by the phase modulation method. The width of the 531 key, that is, the land portion was set to 0.12 m.
中間層 1 3上に形成する第 2 の情報記録層 2 2用の案内溝は、 第 2 の情報記録層 2 2 に対して反射率変調方式により再生又は記 録を行うために、 記録ェリア即ちラン ド部の幅を 0 . 1 6 ; mと 第 1の情報記録層 2 1用の案内溝より広く した。  The guide groove for the second information recording layer 22 formed on the intermediate layer 13 is a recording area for performing reproduction or recording on the second information recording layer 22 by a reflectance modulation method. The width of the land portion was 0.16 m, which was wider than the guide groove for the first information recording layer 21.
続いて、 中間層 1 3上に、 蒸着により ト リ フヱニルァミ ンを成 膜して第 2 の情報記録層 2 2を形成した。  Subsequently, a second information recording layer 22 was formed on the intermediate layer 13 by forming a film of triphenylamine by vapor deposition.
そして、 第 2 の情報記録層 2 2上に、 U V硬化樹脂から成る表 面保護層 1 4を形成して、 図 1 に示した構成の光ディ スク 1 0を 作製した。 これを、 実施例 1 の光ディ スク 1 0 とした。  Then, on the second information recording layer 22, a surface protective layer 14 made of a UV-curable resin was formed, and an optical disc 10 having the configuration shown in FIG. 1 was produced. This was designated as optical disk 10 of Example 1.
(評価)  (Evaluation)
実施例 1 の光ディ スク 1 0 に対して、 まず入射光量を一定にし て反射光量を測定した。  First, with respect to the optical disc 10 of Example 1, the amount of reflected light was measured while the amount of incident light was kept constant.
その結果、 第 2の情報記録層 2 2からの戻り光量は 1 3 ,%であ り、 第 1の情報記録層 2 1からの戻り光量は 1 4 %であった。 これは、 情報記録層を第 1 の情報記録層 2 1 の単層とした場合 の反射率が 2 5 %であり、 第 2 の情報記録層 2 2における光透過 率が 7 4 %であるこ とと矛盾しない。  As a result, the return light quantity from the second information recording layer 22 was 13%, and the return light quantity from the first information recording layer 21 was 14%. This means that the reflectance when the information recording layer is a single layer of the first information recording layer 21 is 25%, and the light transmittance in the second information recording layer 22 is 74%. Does not contradict.
尚、 第 2 の情報記録層 2 2の記録後の情報記録マーク中の透過 率は 7 8 %だが、 記録ェリァ全体では平均化されて透過率 7 6 % となるので、 記録後は第 1の情報記録層 2 1からの戻り光量が增 加することになるが、 これは戻り光により得られる信号の特性に 影響を与えない程度の差であるので問題はない。  Although the transmittance in the information recording mark after the recording of the second information recording layer 22 is 78%, the transmittance is averaged to 76% in the entire recording area. The amount of return light from the information recording layer 21 increases, but this is a problem that does not affect the characteristics of a signal obtained by the return light, and thus causes no problem.
続いて、 この実施例 1 の光ディ スク 1 0 に対して記録再生実験 を行った。  Subsequently, a recording / reproducing experiment was performed on the optical disc 10 of the first embodiment.
まず、 第 2 の情報記録層 2 2 に記録を行った。 記録の条件は次 の通りである。 記録時の線速度を 5 . 7 2 m / s、 記録パターン をマーク長及びスペース長が 0 . 6 9 mである搬送波のパタ一 JP03/00531 ンと した。 また、 記録時の光強度を 5 . O m Wとし、 0 . 6 9 mのマークを D u t y 5 0 %の 7つのパルスで照射して記録した o First, recording was performed on the second information recording layer 22. The recording conditions are as follows. The linear velocity during recording was 5.72 m / s, and the recording pattern was the pattern of a carrier wave with a mark length and space length of 0.69 m. JP03 / 00531 Also, the light intensity at the time of recording was set to 5.0 mW, and the 0.69 m mark was recorded by irradiating it with seven pulses of Duty 50%.
その結果、 変調度が 4 0 %の矩形の信号が得られた。  As a result, a rectangular signal with a modulation factor of 40% was obtained.
ここで、 前述したように第 2 の情報記録層 2 2 の透過率は 7 4 Here, as described above, the transmittance of the second information recording layer 22 is 7 4
%であり、 第 1の情報記録層 2 1への記録の際には、 第 2の情報 記録層 2 2 における損失を考慮して入射光量をその分増加させる 必要がある。 しかしながら、 この入射光量以外には、 記録特性に は影響を与えないため問題はない。 When recording on the first information recording layer 21, it is necessary to increase the amount of incident light in consideration of the loss in the second information recording layer 22. However, there is no problem since other than the incident light amount does not affect the recording characteristics.
また、 この光ディ スク 1 0 は、 ライ トワンス型 (追記型) であ ることから、 記録は第 1 の情報記録層 2 1から先に行われるため 、 第 1の情報記録層 2 1の記録の際には第 2の情報記録層 2 2は 全く記録がなされていない状態であるため、 透過率が一定であり 、 必要な記録パワーにも変動がほとんど無い。  Since the optical disc 10 is a write-once type (write-once type), recording is performed before the first information recording layer 21, so that the recording of the first information recording layer 21 is performed. At this time, since the second information recording layer 22 has not been recorded at all, the transmittance is constant and the required recording power hardly varies.
続いて、 実施例 1 の光ディ スク 1 0 に対して、 第 1 の情報記録 層 2 1 に記録を行い、 第 2 の情報記録層 2 2 には全く記録が行わ れていない状態で第 1 の情報記録層 2 1を再生した。  Subsequently, with respect to the optical disc 10 of the first embodiment, recording was performed on the first information recording layer 21, and the first information recording layer 22 was recorded without recording on the first information recording layer 22. The information recording layer 21 was reproduced.
その結果、 第 2 の情報記録層 2 2のみを記録 ·再生した場合と ほとんど同じ信号が得られた。 変調度は 5 0 %であった。  As a result, almost the same signal was obtained as in the case where only the second information recording layer 22 was recorded / reproduced. The degree of modulation was 50%.
即ち第 1 の情報記録層 2 1 と第 2 の情報記録層 2 2 とから同様 の信号が得られることが示された。  That is, it was shown that a similar signal was obtained from the first information recording layer 21 and the second information recording layer 22.
さ らに、 実施例 1の光ディ スク 1 0 に対して、 第 1の情報記録 層 2 1、 第 2 の情報記録層 2 2 の順に記録を行い、 全記録ェリ了 に対して記録を行つた後に、 第 1 の情報記録層 2 1 の読み出しを 行った。  Further, the first information recording layer 21 and the second information recording layer 22 are recorded on the optical disc 10 of Example 1 in this order, and the recording is performed for all the recording errors. After that, the first information recording layer 21 was read.
その結果、 第 2 の情報記録層 2 2の透過率が先の場合より大き く なったが、 第 1 の情報記録層 2 1からの戻り光量は 1 5 %程度 であり、 また第 1 の情報記録層 2 1 と第 2 の情報記録層 2 2 の間 隔が充分に空いているために、 層間の符号間干渉もほとんど観察 されず、 上述した第 1 の情報記録層 2 1 のみに記録を行った場合 とほぼ同じ信号波形が得られた。 As a result, the transmittance of the second information recording layer 22 became larger than in the previous case, but the amount of light returned from the first information recording layer 21 was about 15%, and the first information Between recording layer 21 and second information recording layer 22 Since the gap was sufficiently empty, almost no intersymbol interference between the layers was observed, and a signal waveform almost the same as that obtained when recording was performed only on the first information recording layer 21 was obtained.
これにより、 実施例 1の光ディ スク 1 0では、 2層の情報記録 層 2 1及び 2 2に対して、 記録 · 再生が正しく行われることがわ 力、る。 ·  Thus, it is clear that the recording / reproducing is properly performed on the two information recording layers 21 and 22 in the optical disc 10 of the first embodiment. ·
従って、 2層の情報記録層 2 1及び 2 2により、 情報記録層が 単層である光ディ スクより も記録密度を向上させることができる こと力 示された。  Accordingly, it was shown that the two information recording layers 21 and 22 can improve the recording density as compared with an optical disc having a single information recording layer.
(比較例) ·  (Comparative example) ·
一方、 比較対照の構成として、 本発明を適用せず、 第 1の情報 記録層 2 1 と基板 1 1 との間に金属膜から成る反射層 1 2を設け ないで、 かつ第 1 の情報記録層 2 1を第 2 の情報記録層 2 2 と同 様の膜構成及び案内溝形状 (記録ェリアの幅 0 . 1 6 m ) と し 、 その他は実施例 1 の光ディ スク 1 0 と同一の構成と して、 比較 例の光ディ スクを作製した。  On the other hand, as a configuration for comparison, the present invention was not applied, the reflective layer 12 made of a metal film was not provided between the first information recording layer 21 and the substrate 11, and the first information recording was performed. The layer 21 has the same film configuration and guide groove shape (width of recording area of 0.16 m) as the second information recording layer 22, and the other components are the same as those of the optical disc 10 of the first embodiment. As a configuration, an optical disc of a comparative example was manufactured.
この比較例の光ディ スクでは、 第 1の情報記録層 2 1からの検 出光量は 1 0 %に低下してしまい、 S / Nが低下し、 フォーカス サ一ボも不安定になり、 実用にならないレベルとなっていた。  In the optical disc of this comparative example, the amount of light detected from the first information recording layer 21 is reduced to 10%, the S / N is reduced, and the focus servo is also unstable. It was a level that did not become.
また、 他の比較対照の構成として、 第 2の情報記録層 2 2 にも 反射層を設けて、 第 1 の情報記録層 2 1 と同じ検出原理を用いる 構成と した場合には、 第 1の情報記録層 2 1からの信号が全く得 られないことは言うまでも無い。  As another configuration for comparison, when the second information recording layer 22 is also provided with a reflective layer and uses the same detection principle as the first information recording layer 21, the first It goes without saying that no signal from the information recording layer 21 can be obtained at all.
(実施例 2 )  (Example 2)
次に、 反射膜の膜厚を厚く して、 第 1の情報記録層 2 1からの 反射光量を更に上げた例を示す。 このようにすることにより、 よ り多層の場合にも第 1の情報記録層 2 1からの検出が容易になる こ こでは、 図 2に示すように、 第 2 の情報記録層 2 2に加えて 、 入射面側にさらに第 3の情報記録層 2 3を設けて、 合計 3層の 情報記録層 2 1, 2 2 , 2 3を形成した光ディ スク 2 0を作製し 、 実施例 2の光ディ スク 2 0 とした。 Next, an example in which the thickness of the reflective film is increased to further increase the amount of light reflected from the first information recording layer 21 will be described. By doing so, the detection from the first information recording layer 21 becomes easier even in the case of a multilayer structure. Here, as shown in FIG. 2, in addition to the second information recording layer 22, a third information recording layer 23 is further provided on the incident surface side, and a total of three information recording layers 21, An optical disk 20 on which 22 and 23 were formed was manufactured, and was used as an optical disk 20 of Example 2.
尚、 この実施例 2では、 反射層 1 2 を構成する A g金属膜の膜 厚を 5 0 n mと した。 また、 第 2 の情報記録層 2 2及び第 3 の情 報記録層 2 3 には、 実施例 1 の光ディ スク 1 0 の第 2 の情報記録 層 2 2 と同等な構成 (材料♦ 膜厚 ·記録エリァの幅) の有機色素 膜を用いた。 また、 この場合には、 中間層 1 3が 2層形成される このとき、 第 1 の情報記録層 2 1 における反射率は 3 5 %であ つた。  In Example 2, the thickness of the Ag metal film forming the reflection layer 12 was set to 50 nm. In addition, the second information recording layer 22 and the third information recording layer 23 have the same configuration (material ♦ film thickness) as the second information recording layer 22 of the optical disc 10 of the first embodiment. · An organic dye film with the width of the recording area) was used. Further, in this case, two intermediate layers 13 were formed. At this time, the reflectance of the first information recording layer 21 was 35%.
この実施例 2の光ディ スク 2 0 に対して、 第 1の情報記録層 2 1からの戻り光量を観測した。  With respect to the optical disc 20 of Example 2, the amount of light returned from the first information recording layer 21 was observed.
その結果、 記録前の戻り光量は入射光量に対し 1 0 %となり、 変調度 3 0 %の信号が検出された。  As a result, the amount of return light before recording was 10% of the amount of incident light, and a signal with a modulation factor of 30% was detected.
即ちこの実施例 2 の構成を用いれば、 情報記録層が 3層である 光ディ スクでも実用可能なレベルを達成できることが示された。  That is, it was shown that the use of the configuration of Example 2 can achieve a practical level even with an optical disc having three information recording layers.
これに対して、 比較対照として、 図 2 に示す光ディ スク 2 0 に おいて、 A g金属膜から成る反射層 1 2を形成しない場合や、 反 射層 1 2 の膜厚が 3 0 n m程度しかない場合には、 第 1 の情報記 録層 2 1からの戻り光量が小さ過ぎて検出できず、 フォーカスサ ―ボがかからなく なった。  On the other hand, as a comparison, in the optical disc 20 shown in FIG. 2, the reflective layer 12 made of an Ag metal film was not formed, or the reflective layer 12 had a thickness of 30 nm. When it was only about the extent, the amount of light returned from the first information recording layer 21 was too small to detect and the focus servo was not applied.
ここで、 上述の実施例において第 1の情報記録層 2 1 と第 2の 情報記録層 2 2 の記録エリ アの幅をそれぞれ 0 · 1 2 ^ m、 0 . 1 6 ^ mと した理由を実験結果に基づいて説明する。 ここでは、 記録ェリ ァの幅を変えて同様の実験を行った結果を示す。  Here, the reason why the width of the recording area of the first information recording layer 21 and the width of the recording area of the second information recording layer 22 were set to 0.12 ^ m and 0.16 ^ m in the above embodiment, respectively. A description will be given based on experimental results. Here, we show the results of a similar experiment performed by changing the width of the recording area.
まず、 第 2の情報記録層 2 2 の記録ェリァの幅を、 0 . 0 6〜 03 00531 First, the width of the recording area of the second information recording layer 22 is set to 0.06 to 03 00531
0 . 2 6 mの範囲で変えて、 再生検出信号の変調度を測定した 結果を図 4 Aに示す。 Fig. 4A shows the results of measuring the modulation of the reproduction detection signal while changing it within the range of 0.26 m.
記録ェリ アの幅を 0 . Ι δ μ πιと した場合は、 前述のように変 調度が 4 0 %であったが、 図 4 Αより記録ェリアの幅をさ らに狭 くすると、 変調度が低下することがわかる。  When the width of the recording area was set to 0 .Ι δ μ πι, the modulation was 40% as described above, but as shown in Fig. 4 す る と, when the width of the recording area was further reduced, the modulation It can be seen that the degree decreases.
これは、 反射率変調方式では、 情報記録マークの幅が狭くなる と単純に検出信号の振幅が小さ く なるからであり、 記録ェリァが 狭く なつた分だけ変調度が低下したためと考えられる。  This is because, in the reflectivity modulation method, the amplitude of the detection signal simply decreases when the width of the information recording mark decreases, and it is considered that the modulation degree decreases by the decrease in the recording area.
また、 この反射率変調方式では、 情報記録マークの幅が広いほ ど変調度は上昇するが、 その一方でその幅がトラック ピッチに近 づく ほどクロス トークが增大するため高密度記録には向かなくな る。 上述の実施例では トラ ック ピッチを 0 . 3 2 mとしている ので、 情報記録マ一クの幅を 0 . 2 5 とするとクロス トーク が一 2 0 d B (記録トラ ックのキャ リ アレベルと隣接トラ ックの キャ リ アレベルの比) まで上昇し、 それ以上の幅では実用になら なかった。 変調度については、 ノイズレベルとの比との兼ね合い で、 経験上 3 0 %以上であることが好ましく、 3 0 %未満では S Z Nが不足して実用的ではない。  Also, in this reflectivity modulation method, the modulation degree increases as the width of the information recording mark increases, but on the other hand, the crosstalk increases as the width approaches the track pitch. Will not work. In the above embodiment, the track pitch is 0.32 m, so if the width of the information recording mark is 0.25, the crosstalk will be 20 dB (the carrier level of the recording track). And the carrier level of the adjacent track). The degree of modulation is preferably 30% or more empirically in consideration of the ratio to the noise level, and if it is less than 30%, SZN is insufficient and is not practical.
これらのことから、 反射率変調方式の場合は、 記録エリ ァの幅 を 0 . 1 2〜 0 . 2 5 mの範囲内とすることが望ましいこと力 わかる。 そして、 上述の実施例で採用した記録エリアの幅 0 . 1 6 mにおいては良好な特性が得られる。  From these facts, it can be seen that in the case of the reflectance modulation method, it is desirable to set the width of the recording area within the range of 0.12 to 0.25 m. Good characteristics can be obtained with a width of 0.16 m of the recording area employed in the above embodiment.
また、 記録ェリアの幅 Pは、 光スポッ ト径に応じて最適値が異 なる。 光スポッ ト径は入射光の波長; I と対物レンズの開口数 N A の関数であり、 ス / N A = α とすると、 本実施例では I = 0 . 4 The optimum value of the width P of the recording area differs depending on the diameter of the optical spot. The light spot diameter is a function of the wavelength of the incident light; I and the numerical aperture N A of the objective lens. Assuming that S / N A = α, I = 0.4 in this embodiment.
0 5 μ m . N A = 0 . 8 5であること力ヽら、 0 5 μm. N A = 0.85
0 . 2 5 « < P < 0 . 5 2 5 α  0. 2 5 «<P <0 .5 2 5 α
が好ま しいことがわかる。 なお、 この式では単位はすべて mを 03 00531 用いた。 It turns out that is preferable. In this formula, all units are m 03 00531 Used.
尚、 入射光 Lの光スポッ トは、 エアリーディ スク と呼ばれる裾 野の広い光分布を有するために、 通常情報記録マークは光スポッ 卜より も小さ く なる。 そのため、 反射率変調方式により信号の検 出を行う場合には、 情報記録マーク中の反射率の記録前の反射率 に対する比が検出信号の変調度より大き く なる。  Incidentally, the light spot of the incident light L has a light distribution with a wide skirt called an airy disk, so that the information recording mark is usually smaller than the light spot. Therefore, when a signal is detected by the reflectance modulation method, the ratio of the reflectance in the information recording mark to the reflectance before recording becomes larger than the modulation degree of the detection signal.
次に、 第 1 の情報記録層 2 1 の記録ェリアの幅を 0 . 0 4〜 0 . 2 8 mの範囲で変えて、 再生検出信号の変調度を測定した結 果を図 4 Bに示す。  Next, FIG. 4B shows the result of measuring the modulation of the reproduction detection signal while changing the width of the recording area of the first information recording layer 21 in the range of 0.04 to 0.28 m. .
記録エリアの幅が 0 . 1 2 ^ mであった場合は、 前述のように 変調度が 5 0 %であつたが、 図 4 Bより記録ェリァの幅がこれよ り も狭くなると変調度が低下することがわかる。  When the width of the recording area was 0.12 ^ m, the modulation factor was 50% as described above, but as shown in Fig. 4B, when the width of the recording area became narrower, the modulation factor decreased. It turns out that it falls.
さ らに、 案内溝はマスタ リ ングプロセスにおいてフォ 卜 レジス 卜に電子ビームで露光を行って形成したが、 幅が狭すぎると壁面 の乱れが目立つようになり、 ノイズレベルの上昇を招いた。  In addition, the guide groove was formed by exposing the fore-registry with an electron beam in the mastering process. However, if the width was too narrow, the disturbance of the wall surface became conspicuous, resulting in an increase in noise level.
従って、 変調度がある程度あっても、 ノイズレベルが上昇し S Z Nが低下するため、 記録ェリ アの幅が 0 . 0 9 m以下では実 用的ではなかった。 また、 0 . 2 2 mでは変調度が 3 0 %程度 まで低下し、 S / Nがやはり低下し、 実用的ではなかった。  Therefore, even if the degree of modulation was to some extent, the noise level increased and the SZN decreased, so that it was not practical with a recording area width of 0.09 m or less. At 0.22 m, the degree of modulation decreased to about 30%, and the S / N also decreased, which was not practical.
これらのことから、 位相変調方式で情報の再生又は記録を行う 場合には、 記録エリ アの幅を 0 . 0 9 111以上 0 . 以下 の範囲内とすることが望ま しいことがわかる。 そして、 上述の実 施例で採用した記録ェリアの幅 0 . 1 2 ^ mにおいては良好な特 性が得られる。  From these facts, it can be seen that when information is reproduced or recorded by the phase modulation method, it is desirable to set the width of the recording area in the range of 0.009111 or more and 0.0 or less. Good characteristics can be obtained with the recording area width of 0.12 ^ m adopted in the above embodiment.
また、 位相変調方式の場合の記録エリアの幅 Pの最適値は、 光 波長ス、 対物レンズの開口数 N Aの関数として、 λ / Ν Α = α と する と、  The optimum value of the width P of the recording area in the case of the phase modulation method is λ / Ν Ν = α as a function of the optical wavelength and the numerical aperture NA of the objective lens.
0 . 1 9 α; < Ρ < 0 . 4 6 α: JP03/00531 が好ま しいことがわかる。 なお、 この式では単位はすべて ^ mを いた。 0. 1 9 α; <0 <0. 4 6 α: It turns out that JP03 / 00531 is preferable. In this equation, the unit was ^ m.
そして、 図 4 A及び図 4 Bより、 記録ェリァの幅への依存性は 、 第 1 の情報記録層 2 1 と第 2の情報記録層 2 2でそれぞれ全く 異なる特性を示すことがわかる。 これは、 記録後の情報記録マ一 ク中の反射率が第 1の情報記録層 2 1 と第 2の情報記録層 2 2で は大き く異なることによると考えられる。  4A and 4B that the first information recording layer 21 and the second information recording layer 22 show completely different characteristics depending on the width of the recording area. This is considered to be because the reflectance in the information recording mark after recording is significantly different between the first information recording layer 21 and the second information recording layer 22.
上述の実施の形態及び実施例では、 有機色素から成る情報記録 層 2 1, 2 2, 2 3を 2層又は 3層有し、 基板 1 1 とは反対の側 から光を入射させる光記録媒体 1 0に本発明を適用した場合であ るが、 その他の構成にも本発明を適用することができる。  In the above embodiments and examples, the optical recording medium has two or three information recording layers 21, 22, and 23 made of an organic dye and allows light to enter from the side opposite to the substrate 11. Although the present invention is applied to 10, the present invention can be applied to other configurations.
例えば光記録媒体の基板側から光を入射させる構成も可能であ り、 その場合には、 基板を透明基板とすると共に、 基板から最も 遠い情報記録層の基板とは反対側に反射層を設ける。  For example, a configuration in which light is incident from the substrate side of an optical recording medium is also possible.In this case, the substrate is made a transparent substrate, and a reflective layer is provided on the opposite side of the information recording layer farthest from the substrate. .
このように構成すれば、 基板側から光を入射させ情報記録層を With this configuration, light is incident from the substrate side and the information recording layer is formed.
1層有する光記録媒体との互換性を確保して、 同一の光へッ ドに より、 いずれの光記録媒体に対しても再生や記録を行うことが可 能になる。 Compatibility with an optical recording medium having one layer is ensured, and reproduction and recording can be performed on any optical recording medium using the same optical head.
また、 情報記録層の材料は有機色素に限らず、 その他の材料を 用いることが可能である。 光ディ スクのタイプも追記型に限らず The material of the information recording layer is not limited to the organic dye, and other materials can be used. The type of optical disc is not limited to write-once type
、 書き換え型や、 再生専用型も可能である。 Rewrite type and read only type are also possible.
さ らに、 複数の情報記録層を設けて、 この複数の情報記録層に 光を入射させることが可能であれば、 光記録媒体の形状はディ ス ク状には限定されない。  Furthermore, the shape of the optical recording medium is not limited to a disk as long as a plurality of information recording layers are provided and light can be incident on the plurality of information recording layers.
そして、 本発明では、 光記録媒体をいずれの構成とする場合で も、 光の入射面となる一の主面から最も遠い第 1の情報記録層が 位相変調型情報記録層となり、 他の情報記録層が反射率変調型情 報記録層となるように構成する。 本発明は、 上述の実施の形態に限定されるものではなく、 本発 明の要旨を逸脱しない範囲でその他様々な構成が取り得る。 According to the present invention, the first information recording layer farthest from one main surface, which is a light incident surface, is a phase modulation type information recording layer, regardless of the configuration of the optical recording medium. The recording layer is configured to be a reflectance modulation type information recording layer. The present invention is not limited to the above-described embodiment, and can take various other configurations without departing from the gist of the present invention.
上述の本発明によれば、 第 1の情報記録層に対しては位相変調 方式により信号を検出し、 他の情報記録層に対しては反射率変調 方式により信号を検出して、 いずれも充分な変調度で信号を検出 することが可能になる。  According to the present invention described above, a signal is detected by the phase modulation method for the first information recording layer, and a signal is detected by the reflectance modulation method for the other information recording layers. A signal can be detected with a high degree of modulation.
これにより、 複数の情報記録層において良好な記録再生特性が ィ守 れ ο  As a result, good recording / reproducing characteristics can be maintained in a plurality of information recording layers.
従って、 2層以上の情報記録層を有する高密度の光記録媒体を 実現することが可能になる。  Therefore, it is possible to realize a high-density optical recording medium having two or more information recording layers.
特に、 第 1 の情報記録層の他の主面側に反射層を設ける構成と したときには、 反射層により反射率を高めることができるので、 第 1 の情報記録層からの信号を充分に検出できるようにすること ができる。  In particular, when the reflection layer is provided on the other main surface side of the first information recording layer, the reflectance can be increased by the reflection layer, so that the signal from the first information recording layer can be sufficiently detected. You can do it.
また、 特に情報記録層を構成する記録膜を有機色素膜により形 成したときには、 さ らに製造の簡易化、 価格の低廉化を図ること ができる。  In particular, when the recording film constituting the information recording layer is formed of an organic dye film, the production can be further simplified and the price can be reduced.

Claims

請求の範囲 The scope of the claims
. 光記録媒体に対して少なく とも情報の再生又は記録を行う光 記録再生方法であって、 An optical recording / reproducing method for reproducing or recording information on at least an optical recording medium,
上記光記録媒体として、 該光記録媒体に対する光入射側の一 の主面と、 これとは反対側の他の主面との間に複数の情報記録 層とを有し、 上記他の主面に最も近い第 1の情報記録層が、 位 相変調型情報記録層とされ、 他の情報記録層が反射率変調型情 報記録層とされた光記録媒体を用い、  The optical recording medium has a plurality of information recording layers between one main surface on a light incident side with respect to the optical recording medium and another main surface on the opposite side, and the other main surface. The first information recording layer closest to the optical recording medium is a phase modulation type information recording layer, and the other information recording layer is a reflectance modulation type information recording layer using an optical recording medium.
上記一の主面側からの光入射により、 上記第 1の情報記録層 に対しては、 位相変調方式により情報の再生又は記録を行い、 上記他の情報記録層に対しては、 反射率変調方式により情報の 再生又は記録を行う  By the light incident from the one main surface side, information is reproduced or recorded on the first information recording layer by a phase modulation method, and the reflectance modulation is performed on the other information recording layer. Play or record information according to the method
ことを特徴とする光記録再生方法。 An optical recording / reproducing method characterized by the above-mentioned.
. 上記光記録媒体の上記第 1の情報記録層は、 情報記録マーク 中に相当する位置における記録前の反射率を R。 とし、 同位置 の記録後の反射率を Rとするときの変化率 (R。 一 R ) / R 0 力 該情報記録マークの再生検出信号の変調度より小とされ、 上記他の情報記録層は、 情報記録マークの同様の変化率 (R。 一 R ) Z R。 が、 該情報記録マークの再生検出信号の変調度以 上とされたことを特徴とする請求の範囲第 1項に記載の光記録 再生方法。 The first information recording layer of the optical recording medium has a reflectance R before recording at a position corresponding to the inside of the information recording mark. When the reflectance after recording at the same position is R, the rate of change is (R.1R) / R0 force, which is smaller than the modulation degree of the reproduction detection signal of the information recording mark. Is the same rate of change of the information recording mark (R.I.R) ZR. 2. The optical recording / reproducing method according to claim 1, wherein the optical recording / reproducing method has a modulation degree equal to or higher than a modulation degree of a reproduction detection signal of the information recording mark.
. 光を入射させることが可能な一の主面と、 該一の主面とは反 対側の他の主面との間に複数の情報記録層とを有し、 A main surface through which light can enter, and a plurality of information recording layers between the one main surface and the other main surface on the opposite side,
上記他の主面に最も近い第 1の情報記録層が位相変調型情報 記録層とされ、  The first information recording layer closest to the other main surface is a phase modulation type information recording layer,
他の情報記録層が反射率変調型情報記録層とされた  Other information recording layer was changed to reflectivity modulation type information recording layer
ことを特徴とする光記録媒体。  An optical recording medium characterized by the above-mentioned.
. 上記反射率変調型情報記録層の記録エリアの幅が、 上記位相 変調型情報記録層の記録ェリァの幅より も広いことを特徴とす る請求の範囲第 3項に記載の光記録媒体。 . The width of the recording area of the reflectance modulation type information recording layer is 4. The optical recording medium according to claim 3, wherein the width of the modulation type information recording layer is wider than the width of the recording area.
5 . 上記第 1 の情報記録層は、 情報記録マーク中に相当する位置 における記録前の反射率を R。 とし、 同位置の記録後の反射率 を Rとするときの変化率 (R。 一 R ) / R。 が、 該情報記録マ —クの再生検出信号の変調度より小とされ、 上記他の情報記録 層は、 情報記録マークの同様の変化率 (R D - R ) R 0 が、 該情報記録マークの'再生検出信号の変調度以上とされたことを 特徴とする請求の範囲第 3項に記載の光記録媒体。 5. In the first information recording layer, the reflectance before recording at a position corresponding to the information recording mark is R. Where R is the reflectivity after recording at the same position and R is the rate of change (R-one R) / R. Is smaller than the modulation degree of the reproduction detection signal of the information recording mark, and the other information recording layer has the same change rate (R D -R) R 0 of the information recording mark as the information recording mark. 4. The optical recording medium according to claim 3, wherein a modulation degree of the reproduction detection signal is set to be equal to or more than the modulation degree.
6 . 上記複数の情報記録層のうち、 少なく とも 1層以上の情報記 録層は、 光吸収により光学定数の変化を起こす記録膜により形 成されていることを特徵とする請求の範囲第 3項に記載の光記 録媒体。  6. A method according to claim 3, wherein at least one or more of the plurality of information recording layers is formed of a recording film whose optical constant changes due to light absorption. Optical recording medium according to the item.
7 . 上記記録膜が、 光吸収により物性変化を起こして光学定数の 変化を起こす有機材料を含有することを特徴とする請求の範囲 第 6項に記載の光記録媒体。  7. The optical recording medium according to claim 6, wherein the recording film contains an organic material that causes a change in optical constants due to a change in physical properties due to light absorption.
8 . 上記有機材料として有機色素が用いられていることを特徵と する請求の範囲第 7項に記載の光記録媒体。  8. The optical recording medium according to claim 7, wherein an organic dye is used as the organic material.
9 . 上記第 1の情報記録層の上記他の主面側に反射層が設けられ ている ことを特徵とする請求の範囲第 3項に記載の光記録媒体  9. The optical recording medium according to claim 3, wherein a reflection layer is provided on the other main surface side of the first information recording layer.
PCT/JP2003/000531 2002-01-22 2003-01-22 Optical recording/reproducing method and optical recording medium WO2003067579A1 (en)

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CA002441559A CA2441559A1 (en) 2002-01-22 2003-01-22 Optical recording medium with multiple information-recording layers and recording method thereon
EP03737436A EP1469460A4 (en) 2002-01-22 2003-01-22 Optical recording/reproducing method and optical recording medium
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0768652A2 (en) 1995-10-13 1997-04-16 Nec Corporation Single-substrate multi-layer optical disk for read-only storage and phase change rewritable storage
JP2001101709A (en) * 1999-10-04 2001-04-13 Sony Corp Optical recording medium, optical recording medium producing method and optical recording method
US20010016242A1 (en) * 2000-01-26 2001-08-23 Makoto Miyamoto Information recording medium
JP2001266402A (en) * 2000-03-24 2001-09-28 Toshiba Corp Single-sided, two-layer optical disc
EP1143431A2 (en) * 2000-03-27 2001-10-10 Sony Corporation Optical recording medium

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5627817A (en) * 1995-05-08 1997-05-06 International Business Machines Corporation Optical disk data storage system with multiple write-once dye-based data layers
JP3972456B2 (en) * 1998-04-09 2007-09-05 ソニー株式会社 Multi-layer disc playback apparatus and multi-layer disc playback method
EP0957477A3 (en) * 1998-05-15 2003-11-05 Matsushita Electric Industrial Co., Ltd. Optical information recording medium, recording and reproducing method therefor and optical information recording and reproduction apparatus
WO2001016947A1 (en) * 1999-08-31 2001-03-08 Kabushiki Kaisha Toshiba Optical disk, and method and apparatus for reading data from optical disk

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0768652A2 (en) 1995-10-13 1997-04-16 Nec Corporation Single-substrate multi-layer optical disk for read-only storage and phase change rewritable storage
JP2001101709A (en) * 1999-10-04 2001-04-13 Sony Corp Optical recording medium, optical recording medium producing method and optical recording method
US20010016242A1 (en) * 2000-01-26 2001-08-23 Makoto Miyamoto Information recording medium
JP2001266402A (en) * 2000-03-24 2001-09-28 Toshiba Corp Single-sided, two-layer optical disc
EP1143431A2 (en) * 2000-03-27 2001-10-10 Sony Corporation Optical recording medium

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1469460A4 *

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