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WO2003018192A3 - Method for the production of 2-propylheptanol and hydroformylating catalysts and the further use thereof for carbonylation, hydrocyanation and hydrogenation - Google Patents

Method for the production of 2-propylheptanol and hydroformylating catalysts and the further use thereof for carbonylation, hydrocyanation and hydrogenation Download PDF

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Publication number
WO2003018192A3
WO2003018192A3 PCT/EP2002/009455 EP0209455W WO03018192A3 WO 2003018192 A3 WO2003018192 A3 WO 2003018192A3 EP 0209455 W EP0209455 W EP 0209455W WO 03018192 A3 WO03018192 A3 WO 03018192A3
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WIPO (PCT)
Prior art keywords
represent
hydrogenation
propylheptanol
hydrocyanation
carbonylation
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PCT/EP2002/009455
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German (de)
French (fr)
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WO2003018192A2 (en
Inventor
Wolfgang Ahlers
Rocco Paciello
Thomas Mackewitz
Martin Volland
Original Assignee
Basf Ag
Wolfgang Ahlers
Rocco Paciello
Thomas Mackewitz
Martin Volland
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Publication date
Application filed by Basf Ag, Wolfgang Ahlers, Rocco Paciello, Thomas Mackewitz, Martin Volland filed Critical Basf Ag
Priority to AU2002324067A priority Critical patent/AU2002324067A1/en
Publication of WO2003018192A2 publication Critical patent/WO2003018192A2/en
Publication of WO2003018192A3 publication Critical patent/WO2003018192A3/en

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    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention relates to a method for the production of 2-propylheptanol, comprising the hydroformylation of butene, aldol condensation of the hydroformylation product thus obtained and the catalytic hydrogenation thereof. The invention also relates to novel catalysts for the hydroformylation step and to the further use thereof for carbonylation, hydrocyanation and hydrogenation based on a complex of a metal of the VIIIth subgroup with at least one ligand of general formula (1), wherein respectively two adjacent radicals R1,R2,R3 and R4 together with the carbon atoms of the pyrool ring to which they are bound can also represent a condensed ring system with 1,2 or 3 other rings, with the proviso that at least one of the radicals R1,R2,R3 and R4 do not represent hydrogen and R5 and R6 are not joined to each other, R5 and R6 independently from each other represent cylcoalkyl, heterocycloalkyl, aryl or heteroaryl, whereby one of the radicals R5 or R6 can also represent a bivalent bridging group Y binding similar or different ligands of formula (I) to each other in a covalent manner, and a and b independently from each other represent 0 or 1. .
PCT/EP2002/009455 2001-08-24 2002-08-23 Method for the production of 2-propylheptanol and hydroformylating catalysts and the further use thereof for carbonylation, hydrocyanation and hydrogenation WO2003018192A2 (en)

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US8524628B2 (en) 2004-06-12 2013-09-03 Lg Chem, Ltd. Phosphorus-containing catalyst composition and hydroformylation process using the same
CN104822456A (en) * 2012-12-04 2015-08-05 陶氏技术投资有限责任公司 Bidentate ligands for hydroformylation of ethylene

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