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WO2003037292A1 - Lingettes cosmetiques seches a surface structuree - Google Patents

Lingettes cosmetiques seches a surface structuree Download PDF

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Publication number
WO2003037292A1
WO2003037292A1 PCT/EP2002/011673 EP0211673W WO03037292A1 WO 2003037292 A1 WO2003037292 A1 WO 2003037292A1 EP 0211673 W EP0211673 W EP 0211673W WO 03037292 A1 WO03037292 A1 WO 03037292A1
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WO
WIPO (PCT)
Prior art keywords
acid
fatty
alkyl
esters
oil
Prior art date
Application number
PCT/EP2002/011673
Other languages
German (de)
English (en)
Inventor
Hermann Henzen
Mark Leonard
Virginia Lazarowitz
Heike Kublik
Jackie Searle
Timothy Morris
Original Assignee
Cognis Deutschland Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Deutschland Gmbh & Co. Kg filed Critical Cognis Deutschland Gmbh & Co. Kg
Publication of WO2003037292A1 publication Critical patent/WO2003037292A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049—Cleaning or scouring pads; Wipes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q9/00—Preparations for removing hair or for aiding hair removal
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Definitions

  • the invention is in the field of cosmetics and relates to facial tissues with a special structure, which contain defined care and cleaning substances with particulate wax bodies, are moistened before use and are distinguished by good sensory properties combined with good foam and cleaning properties.
  • Facial tissues are a form of application that is becoming increasingly important in the field of personal care. These are usually wet wipes that represent textile fabrics, nonwovens or even tissue papers that are soaked in a cleaning or care formulation.
  • structureless, non-woven fabrics are impregnated and / or coated with formulations containing surfactants and care agents and then dried. Depending on the size of the wearer, this can be impregnated disposable washcloths or smaller cleaning pads.
  • Hygiene and easy handling of these agents meet today's demands in terms of user friendliness, effectiveness and time saving.
  • the requirements for the cleaning effect, the skin feel during and after use and the ease of use pose a technical challenge to the
  • the amount of foam, stability and foam structure generated after moistening has a significant influence on the sensory sensation during and after cleaning.
  • the suitable foam structure and sufficient foam volume after moistening are difficult to achieve with your hands without strong mechanical processing of the cloth. This problem can be made increasingly difficult by other nourishing non-surfactant additives.
  • the invention relates to dry facial tissues, characterized in that they have a uniform, structured surface with punctiform to oval depressions and are impregnated with a solution containing
  • a fine-pored, voluminous foam can be generated quickly with little mechanical influence.
  • the size of the wax particles and the structured tissue surface on the one hand have an influence on the foam properties, on the other hand wax bodies and cleaning components leave a pleasant feeling on the skin during and after cleaning.
  • the formulation, containing the aqueous surfactant system and the finely dispersed wax body, enables impregnation or coating of the carrier materials in one manufacturing process.
  • the special carrier systems to which the present invention relates can be constructed in one or more layers.
  • appropriate tissue fabrics made of fiber or fleece are also suitable.
  • natural fibers include silk, cellulose, keratin, wool, cotton, jute, linen, flak, for synthetic fibers acetate, acrylate, cellulose ester, polyamide, polyester, polyolefin, polyvinyl alcohol, polyurethane fibers , or polyolefin fabrics hydrophilized by additives and mixtures of these fibers or fabrics.
  • Reaction products of 1 part of polyethylene glycol with 2 parts of fatty acids with 10 to 12 carbon atoms or their derivatives are used for the hydrophilization of the polyolefin-containing fabrics.
  • Non-woven fabrics are preferred, since these can be better provided with the desired structure according to the invention; supports made of viscose-polyester mixtures are particularly suitable for this.
  • carrier systems of 50 to 90% by weight of viscose and 50 to 10% by weight of polyester which are crosslinked by the action of water are preferred, carriers of 60 to 80% by weight of viscose and 40 to 20% by weight of polyester are particularly preferred; up to 70% by weight viscose and 35 to 30% by weight polyester.
  • the size of the cloths is generally between 100 and 500 mm in length and between 100 and 500 mm in width, with length and width dimensions between 120 and 220 mm being preferred.
  • the fabric can also be in the form of a glove and may then have multiple layers, so that the inner fabric layer of the glove turns out to be more hydrophobic, has a barrier function and offers protection against the hand coming into contact with the formulation or with moisture.
  • the carrier substances of the cosmetic tissues according to the invention have a uniform, structured surface with punctiform to oval depressions due to their production - the action of water with a so-called hydroentanglement belt.
  • These depressions - also called dimples - have a round to oval shape with 0.1 to 1 mm, preferably 0.2 to 0.6 mm in diameter respectively. Width and 0.5 to 5.0 mm, preferably 0.8 to 1.5 mm in diameter respectively. Length. They can be on both sides or only from one side. In the case of one-sided depressions, they take up between 50 and 99%, preferably between 60 and 85%, of the thickness of the support; in the case of depressions on both sides, this proportion must be divided accordingly. An average of between 500 and 4000, preferably between 1500 and 3500, and particularly preferably between 2500 and 3200 of such dimples are present per 100 mm 2 support surface.
  • the recesses contribute to the advantageous foam development. They hold small air bubbles which, when the Cloth which accelerate and improve the foam formation caused by the formulation and mechanical processing - mainly by rubbing between the hands. In this way, they contribute to an advantageous fine-pored foam structure with a large foam volume.
  • the weight of the carrier has an influence on the foam quality and quantity.
  • the fabrics have a weight per square meter of 10 to 150 g, preferably 20 to 120 g, particularly preferably 40 to 100 g and especially 70 to 90 g and a thickness of 0.1 to 1.5 mm, preferably 0.2 to 1.0 mm, particularly preferably 0.4 to 0.8 mm and especially 0.6 to 0.7 mm.
  • the properties of the carrier must be coordinated with the components of the applied formulation in order to achieve the synergistic effect with regard to cleaning and sensory properties.
  • the weight ratio of the dry tissue to the applied cleaning and care solution should be 60:40 to 90:10 and preferably 85:15 to 80:20.
  • the impregnation solution contains surfactants and wax dispersions with average particle sizes from 0.08 to 13 ⁇ m.
  • Nonionic, anionic, cationic and / or amphoteric or amphoteric surfactants may be present as surface-active substances, the proportion of which in the impregnating or coating solutions is usually about 5 to 80, preferably 10 to 70 and particularly preferably 20 to 35% by weight. -%.
  • anionic surfactants are soaps, alkyl benzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, fatty acid ether sulfates, hydroxymate sulfate ethersulfates, hydroxymethane sulfate ethersulfate, hydroxymate sulfate etherates , Mono- and dialkyl sulfosuccinates, mono- and dialkyl sulfosuccinates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid isethonates,
  • anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of nonionic surfactants are fatty alcohol polyglycol ethers, alkyl phenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine poly- lyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed formals, optionally partially oxidized alk (en) yloligoglycosides or glucoronic acid derivatives, fatty acid N-alkylglucamides, protein hydrolysates (especially vegetable products based on wheat), polyol fatty acid esters, sugar esters, sorbitan esters, polysorbates and amine oxides.
  • nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of cationic surfactants are quaternary ammonium compounds and ester quats, in particular quaternized fatty acid trialkanolamine ester salts.
  • Typical examples of amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines. The surfactants mentioned are exclusively known compounds.
  • Typical examples of particularly suitable mild, i.e. particularly skin-compatible surfactants are fatty alcohol polyglycol ether sulfates, monoglyceride sulfates, mono- and / or dialkyl sulfosuccinates, mate fatty acid taurides, Fettklaregluta-, ⁇ -olefinsulfonates, ether carboxylic acids, alkyl oligoglucosides, fatty acid glucamides, alkylamidobetaines, amphoacetates and / or protein fatty acid condensates, the latter preferably based on wheat proteins.
  • particularly suitable mild, i.e. particularly skin-compatible surfactants are fatty alcohol polyglycol ether sulfates, monoglyceride sulfates, mono- and / or dialkyl sulfosuccinates, mate fatty acid taurides, Fettklaregluta-, ⁇ -olefinsulfonates, ether carboxylic acids,
  • Preferred surfactants in the present invention are sodium laureth sulfate, sodium lauroyl lactylate, sodium lauroyl sarcosinate, disodium cocoamphodiacetate, sodium cocoamphoacetate, cocamidopropyl betaine, cocamide DEA, alkyl oligoglucoside and mixtures thereof.
  • Nonionic surfactants are particularly preferably selected from the group formed by alkyl oligoglucosides, cocamidopropyl betaine, PEG-7 glyceryl cocoat, Laureth-4, ceteareth-12, ceteareth-20 and / or beheneth-10, and surfactant mixtures of are particularly preferred Alkyl oligoglycosides and cocamidopropyl betaine, which are present in a ratio of 15: 1 to 1: 1, preferably 10: 1 to 2: 1 and particularly preferably 8: 1 to 5: 1.
  • the proportion of the wax bodies contained in the wax dispersions is 10 to 60% by weight, preferably 15 to 50% by weight and particularly preferably 20 to 45% by weight, based on the predispersed wax dispersion, which in turn is present in quantities in the impregnating and coating solutions according to the invention from 1 to 25% by weight, preferably 2 to 20% by weight and particularly preferably in amounts of 5 to 10% by weight.
  • Possible wax bodies in the wax dispersions are: wax esters, alkylene glycol esters, fatty acid alkanolamides, partial glycerides, triglycerides, esters of polyvalent and / or monohydric, optionally hydroxyl-substituted carboxylic acids, fatty alcohols, fatty alcohol ethoxylates, fatty ketones, fatty acids, fatty aldehydes, ring opening fatty acids, fatty ether oxides, fatty carbonates as well as their mixtures.
  • alkylene glycol esters (Ia) and wax esters (Ib), which form the preferred wax bodies, are usually mono- and / or diesters of alkylene glycols which follow the formulas (Ia and Ib),
  • R J CO for a linear or branched, saturated or unsaturated acyl radical with 6 to 22 carbon atoms
  • R 2 for hydrogen or R ⁇ O
  • A for a linear or branched alkylene radical with 2 to 4 carbon atoms and n for numbers from 1 to 5 stands.
  • Typical examples are mono- and / or diesters of ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, triethylene glycol or tetraethylene glycol with fatty acids having 6 to 22, preferably 12 to 18 carbon atoms, since there are: caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid , Lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures.
  • the use of ethylene glycol mono- and / or distearate and of esters of linear saturated fatty acids with cetyl alcohol is particularly preferred.
  • R 3 CO is a linear or branched, saturated or unsaturated acyl radical having 6 to 22 carbon atoms
  • R 4 is hydrogen or an optionally hydroxy-substituted alkyl radical having 1 to 4 carbon atoms
  • B is a linear or branched alkyl group having 1 to 4 carbon atoms stands.
  • Typical examples are condensation products of ethanolamine, methylethanolamine, diethanolamine, propanolamine, methylpropanolamin and dipropanolamine and their mixtures with caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, oleic acid, isostearic acid Elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and Erucic acid and its technical mixtures.
  • the use of stearic acid ethanolamide is particularly preferred.
  • Partial glycerides represent mono and / or diesters of glycerol with linear, saturated fatty acids, namely for example caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, behenic acid and their technical mixtures. They follow the formula (III),
  • R 6 and R 7 independently of one another for hydrogen or R 5 CO, x, y and z in total for 0 or for numbers from 1 to 30 and X for is an alkali or alkaline earth metal with the proviso that at least one of the two radicals R 6 and R 7 is hydrogen.
  • Typical examples are lauric acid, lauric, coconut fatty, retriglycerid Kokosfett Maschinen-, palmitic, Palmitinklaretriglycerid, oleic, stearic acid diglyceride, tallow fatty acid, Talgfettklarediglycerid, BehenTalkremo- noglycerid, which can contain from the production process small amounts of triglyceride Behen Text Redig lycerid and technical mixtures thereof which is subordinate to.
  • esters of monovalent and polyvalent, optionally hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms examples include palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, malonic acid, maleic acid, fumaric acid, adipic acid, sebacic acid, azelaic acid, dodecanedioic acid, phthalic acid, isophthalic acid and in particular succinic acid and malic acid and mixtures thereof, in particular citric acid, citric acid into consideration.
  • the fatty alcohols contain 6 to 22, preferably 12 to 18 and in particular 16 to 18 carbon atoms in the alkyl chain.
  • Typical examples are capronic alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capricine alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linoleolyl alcohol, linoleolyl alcohol, linoleolyl alcohol, linoleol alcohol alcohol , Erucyl alcohol and brassidyl alcohol and their technical mixtures.
  • the esters can be present as full or partial esters, preferably mono- and especially diesters of carboxylic or hydroxycarboxylic acids.
  • Typical examples are succinic acid mono- and dilauryl esters, succinic acid mono- and dicetearly esters, Succinic acid mono- and distearyl esters, tartaric acid mono- and dilauryl esters, tartaric acid mono- and dicoco alkyl esters, tartaric acid mono- and dicetearyl esters, citric acid mono-, di- and trilauryl esters, citric acid mono-, di- and tricocoalkyl monoesters, and citric acid alkyl ester and tricetearyl esters.
  • fatty alcohols As a third group of wax bodies, fatty alcohols, fatty alcohol ethoxylates and fatty acids can be used, which follow the formulas (IV a, b and c),
  • R 8 represents a linear, optionally hydroxy-substituted alkyl radical and / or acyl radical having 16 to 48, preferably 18 to 36 carbon atoms.
  • suitable alcohols are cetearyl alcohol, hydroxystearyl alcohol, behenyl alcohol and oxidation products of long-chain paraffin. Ethoxylated behenyl alcohols in particular are preferred as wax bodies.
  • Fat ketones which are considered as components preferably follow the formula (V),
  • R 9 and R 10 independently of one another represent alkyl and / or alkenyl radicals having 1 to 22 carbon atoms, with the proviso that they have a total of at least 24 and preferably 32 to 48 carbon atoms.
  • the ketones can be prepared by methods known in the art, for example by pyrolysis of the corresponding fatty acid magnesium salts.
  • the ketones can be symmetrical or asymmetrical, but the two radicals R 13 and R 14 preferably differ only by one carbon atom and are derived from fatty acids having 16 to 22 carbon atoms.
  • Fatty aldehydes suitable as wax bodies preferably correspond to the formula (VI)
  • R n CO represents a linear or branched acyl radical having 24 to 48, preferably 28 to 32, carbon atoms.
  • R n CO represents a linear or branched acyl radical having 24 to 48, preferably 28 to 32, carbon atoms.
  • R 12 and R 13 independently of one another represent alkyl and / or alkenyl radicals having 1 to 22 carbon atoms, with the proviso that in total they have at least 24 and preferably 32 to 48 carbon atoms.
  • Fat ethers of the type mentioned are usually prepared by acidic condensation of the corresponding fatty alcohols. Fat ethers with particularly advantageous pearlescent properties are obtained by condensation of fatty alcohols having 16 to 22 carbon atoms, such as, for example, cetyl alcohol, cetearyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, behenyl alcohol and / or erucyl alcohol.
  • Fatty carbonates preferably of the formula (VIII), are also suitable as components,
  • R 14 and R 15 independently of one another represent alkyl and / or alkenyl radicals having 1 to 22 carbon atoms, with the proviso that they have a total of at least 24 and preferably 32 to 48 carbon atoms.
  • the substances are obtained by transesterifying, for example, dimethyl or diethyl carbonate with the corresponding fatty alcohols in a manner known per se. Accordingly, the fatty carbonates can be constructed symmetrically or asymmetrically. However, carbonates are preferably used in which R 14 and R 15 are identical and represent alkyl radicals having 16 to 22 carbon atoms.
  • Transesterification products of dimethyl or diethyl carbonate with cetyl alcohol, cetearyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, behenyl alcohol and / or erucyl alcohol in the form of their mono- and diesters or their technical mixtures are particularly preferred.
  • the epoxy ring opening products are known substances which are usually prepared by acid-catalyzed reaction of terminal or internal olefin oxides with aliphatic alcohols.
  • the reaction products preferably follow the formula (IX)
  • R 16 and R 17 represent hydrogen or an alkyl radical having 10 to 20 carbon atoms, with the proviso that the sum of the carbon atoms of R 16 and R 17 is in the range from 10 to 20 and R 18 represents an alkyl and / or alkenyl radical having 12 to 22 carbon atoms and / or the radical of a polyol having 2 to 15 carbon atoms and 2 to 10 hydroxyl groups.
  • Typical examples are ring opening products of ⁇ -dodecenepoxide, ⁇ -hexadecenepoxide, ⁇ -octadecenepoxide, ⁇ -eicosen-epoxide, ⁇ -docosenepoxide, i-dodecenepoxide, i-hexadecenepoxide, i-octadecenepoxide, i-eicosenepoxide and / or i-docoholalkenepoxide with laurylalkosenepoxide , coconut fatty alcohol, myristyl alcohol, cetyl alcohol, cetearyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, behenyl alcohol and / or erucyl alcohol.
  • Ring opening products of hexa- and / or octadecene epoxides with fatty alcohols having 16 to 18 carbon atoms are preferably used.
  • polyols are, for example, the following substances: glycerol; Alkylene glycols, such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons; technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10 such as technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight; Methyl compounds, such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol; Lower alkyl glu
  • Waxes and lipids from the group formed by glyceryl oleate, cetyl palmitate, hydrogenated castor oil, glyceryl stearate, fatty alcohols (dodecyl, myristyl alcohol, cetearyl alcohol), glycol distearate and alpha-hydroxy acid esters (such as tristearyl) are particularly preferred Citrate, Distearyl Malic Acid Ester).
  • the impregnation solutions of the facial tissues according to the invention are preferably free of silicones, silicone compounds and silicone polymers in order to ensure an advantageous feeling on the skin.
  • the particle sizes of the wax dispersions that are used in the impregnation and coating solutions have a significant influence on the sensory properties and foam and cleaning properties of the wipes.
  • You need for the optimal setting Average particle sizes in the dispersions are from 0.08 to 13 ⁇ m, preferably 0.1 to 10 ⁇ m, particularly preferably 0.5 to 4 ⁇ m and especially 1 to 2 ⁇ m.
  • the conventional methods for dispersion production known to the person skilled in the art are selected.
  • the particle sizes can be set by varying the loading of the dispersions in high-pressure homogenizers.
  • wax bodies should be selected that have a melting point or. Have melting range from 50 to 85 ° C, preferably from 55 to 70 ° C.
  • the particle sizes were determined using the Coulter LS 230 laser particle analyzer from Beckman Coulter.
  • the device also uses the PIDS (polarized intensity differential scattering) method to expand the measuring range to the submicron range.
  • the laser generates light with a wavelength of 750 nm, which is supplemented by the PIDS technology with the wavelengths 450, 600 and 900 nm.
  • the 132 detectors have a total measuring range of 0.04 - 2000 ⁇ m, which is divided into 116 size classes.
  • the software evaluates either according to the Frauhofhof see diffraction theory or according to the scattered light theory according to Mie.
  • the measured samples were diluted by a factor of 100 by the sample feed module, with demineralized water serving as the dispersing medium.
  • the sample feed module ensures constant circulation of the dispersed sample through the measuring cell.
  • the circulating sample was subjected to an ultrasound treatment of 30 s. This was done using an ultrasound module from Beckman Coulter connected to the measuring device.
  • the evaluation was carried out exclusively according to the scattered light theory according to Mie using a refractive index of 1.47 for the dispersed medium.
  • the average particle size data given relate to the D 50 value of the volume distribution.
  • the surfactant formulations with nourishing, finely dispersed particulate wax dispersions of a defined particle size are applied to the structured fabric in such a way that the dispersion, after the subsequent drying process by warm air drying, vacuum drying or drum drying, is loosely applied to the carrier as a discontinuous layer liable.
  • the temperature during the drying process should be chosen so that the dispersion does not adhere too strongly to the structured fabric. This also presupposes that the depressions in the tissue and the particle sizes of the wax body particles are coordinated with one another.
  • the dimples in the tissue may only be smaller or significantly larger than the dispersed and subsequently applied wax body particles, since otherwise a simple dispersion of the particles during foam formation is not guaranteed.
  • the impregnated and dried facial tissues are dry to the touch.
  • the residual water content after drying or water content of the dry facial tissues according to the invention is between 0.1 and 4% by weight, preferably 0.5 to 3% by weight and particularly preferably between 0.8 and 2% by weight of water, based on the Weight of the dry, non-impregnated carrier.
  • the dried cloth preferably consists of 40 to 90% by weight of carrier and 10 to 60% by weight of cleaning and care substances, particularly preferably it contains 50 to 75% by weight of carrier and 25 to 50% by weight of cleaning and care substances.
  • Dry facial tissues which have a uniform, structured surface with punctiform depressions and are impregnated with a solution containing
  • Impregnation solutions containing are especially
  • Preferred further auxiliaries in the impregnation solutions are cationic polymers which are used in the impregnation solutions for the facial tissues according to the invention in amounts of 0.02 to 3% by weight, preferably 0.05 to 1% by weight and particularly preferably in amounts of 0.1 to 0 , 5% by weight can be used.
  • cationic polymers such as a quaternized hydroxyethyl cellulose available under the name Polymer JR 400® from Amerchol, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinylpyrrolidone / vinylimidazole polymers such as e.g.
  • Luviquat® condensation products of polyglycols and amines, quaternized collagen polypeptides such as lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®L / Grünau), quaternized wheat polypeptides, polyethyleneimine, copolymers of acrylic acid with dimethyldiallylammonium chloride (Merquat® 550 / Chemviron), polyaminopolyamides, such as, for example described in FR 2252840 A and its crosslinked water-soluble polymers, cationic chitin derivatives such as quaternized chitosan, optionally microcrystalline, condensation products of dihaloalkylene, such as e.g.
  • Dibromobutane with bisdialkylamines e.g. Bis-dimethylamino-1,3-propane, cationic guar gum, e.g. Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese, quaternized ammonium salt polymers such as e.g. Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol.
  • bisdialkylamines e.g. Bis-dimethylamino-1,3-propane
  • cationic guar gum e.g. Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese
  • quaternized ammonium salt polymers such as e.g. Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol.
  • Cationic guar gum and / or quaternized ammonium salt polymers are preferably used in the preparations according to the invention.
  • solutions and / or dispersions used for impregnation can also contain, as further auxiliaries and additives, oil bodies, emulsifiers, plasticizers, refatting agents, polymers, lecithins, phospholipids, biogenic active substances, UV light protection factors, antioxidants, deodorants rantien, antiperspirants, antidandruff agents, film formers, hydrotropes, solubilizers, preservatives, perfume oils, dyes and the like contain.
  • auxiliaries and additives oil bodies, emulsifiers, plasticizers, refatting agents, polymers, lecithins, phospholipids, biogenic active substances, UV light protection factors, antioxidants, deodorants rantien, antiperspirants, antidandruff agents, film formers, hydrotropes, solubilizers, preservatives, perfume oils, dyes and the like contain.
  • esters of linear C 1 -C 4 -fatty acids with branched alcohols in particular 2-ethylhexanol, esters of C 18 -C 38 -alkylhydroxycarboxylic acids with linear or branched C 6 -C 22 -fatty alcohols are suitable (cf.
  • dioctyl malates esters of linear and / or branched fatty acids with polyhydric alcohols (such as propylene glycol, dimer diol or trimer triol) and / or Guerbet alcohols, triglycerides based on C 6 -C 0 fatty acids, liquid mono- / di- / triglyceride mixtures Basis of C 6 -C 8 fatty acids, esters of ⁇ fatty alcohols and / or Guerbet alcohols with aromatic carboxylic acids, especially benzoic acid, esters of C 2 -C 2 dicarboxylic acids with linear or branched alcohols with 1 to 22 carbon atoms or polyols with 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C 6 -C 22 fatty alcohol carbonates, such as dicaprylyl Carbonates (Ceti)
  • Suitable emulsifiers are nonionic surfactants from at least one of the following groups:
  • Partial esters of polyglycerol (average degree of self-condensation 2 to 8), polyethylene glycol (molecular weight 400 to 5000), trimethylolpropane, pentaerythritol, sugar alcohols (e.g. sorbitol), alkyl glucosides (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) (e.g. cellulose) saturated and / or unsaturated, linear or branched fatty acids with 12 to 22 carbon atoms and / or hydroxycarboxylic acids with 3 to 18 carbon atoms and their adducts with 1 to 30 mol ethylene oxide;
  • Block copolymers e.g. Polyethylene glycol 30 dipolyhydroxystearate;
  • Polymer emulsifiers e.g. Pemulen types (TR-1, TR-2) from Goodrich;
  • the adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols or with castor oil are known, commercially available products. These are mixtures of homologs whose average degree of alkoxylation is the ratio of the amounts of ethylene oxide and / or propylene oxide and Substrate with which the addition reaction is carried out corresponds.
  • C 12/18 - fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE 2024051 PS as refatting agents for cosmetic preparations.
  • Alkyl and / or alkenyl oligoglycosides their preparation and their use are known from the prior art. They are produced in particular by reacting glucose or oligosaccharides with primary alcohols with 8 to 18 carbon atoms.
  • glycoside residue both monoglycosides in which a cyclic sugar residue is glycosidically bonded to the fatty alcohol and oligomeric glycosides with a degree of oligomerization of up to about 8 are suitable.
  • the degree of oligomerization is a statistical mean value which is based on a homolog distribution customary for such technical products.
  • sorbitan sorbitan, sorbitan sesquiisostearate, sorbitan come diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan dioleate, trioleate, Sorbitanmonoerucat, Sorbitansesquierucat, Sorbitandierucat, Sorbitantrierucat, Sorbitanmonoricinoleat, Sorbitansesquiricinoleat, Sorbitandiricinoleat, Sorbitantriricinoleat, Sorbitanmonohydroxystearat, Sorbitansesquihydroxystearat, sorbitan tandihydroxystearat, Sorbitantrihydroxystearat, Sorbitanmonotartrat , Sorbitan sesquitarate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate,
  • polyglycerol esters are polyglyceryl-2 dipolyhydroxystearates (Dehymuls® PGPH), polyglycerol-3-diisostearates (Lameform® TGI), polyglyceryl-4 isostearates (Isolan® GI 34), polyglyceryl-3 oleates, diisostearoyl polyglyceryl-3 dihydrogen - sostearate (Isolan® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care® 450), Polyglyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether (Chimexane® NL), Polyglyceryl-3 Distearate (Creophor® GS 32) and Polyglyceryl Polyricinoleate (Admul® WOL 1403) Polyglyceryl
  • polystyrene resin examples include the mono-, di- and triesters of trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, taig fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like which are optionally reacted with 1 to 30 mol of ethylene oxide.
  • Typical anionic emulsifiers are aliphatic fatty acids with 12 to 22 carbon atoms, such as, for example, palmitic acid, stearic acid or behenic acid, and dicarboxylic acids with 12 to 22 carbon atoms, such as, for example, azelaic acid or sebacic acid.
  • Zwitterionic surfactants can also be used as emulsifiers.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example the coconut acylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylm -3-hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glyc
  • Suitable emulsifiers are ampholytic surfactants.
  • Ampholytic surfactants are understood to mean those surface-active compounds which, in addition to a C 8 / i 8 alkyl or acyl group, contain at least one free amino group and at least one -COOH or -SO 3 H group in the molecule are capable of forming inner salts.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each with about 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and Ci 2 / i 8 -acylsarcosine.
  • cationic surfactants are also suitable as emulsifiers, those of the esterquat type, preferably methylquaternized difatty acid triethanolamine ester salts, being particularly preferred.
  • Anionic, zwitterionic, amphoteric and nonionic polymers include, for example, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and polyesters and their esters, uncommon , Acrylamido propyltrimethylammonium chloride / acrylate copolymers, octylacrylamide / methyl methacrylate tert.butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers, polyvinylpyrrolidone, vinyl pyrrolidone / vinyl acetate copolymers, vinyl pyrrolidone / dimethylaminoethyl methacrylate and optionally acrylate / dimethylaminoethyl meth
  • UV light protection factors are understood to mean, for example, organic substances (light protection filters) which are liquid or crystalline at room temperature and which are able to absorb ultraviolet rays and absorb the energy absorbed in the form of longer-wave radiation, e.g. To give off heat again.
  • UVB filters can be oil-soluble or water-soluble. As oil-soluble substances e.g. to call:
  • esters of salicylic acid preferably salicylic acid 2-ethylhexyl ester, salicylic acid 4-isopropylbenzyl ester, salicylic acid homomethyl ester;
  • benzophenone preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4 ⁇ - methylbenzophenone, 2.2 ⁇ - dihydroxy-4-methoxybenzophenone;
  • esters of benzalmalonic acid preferably 4-methoxybenzmalonic acid di-2-ethylhexyl ester;
  • Triazine derivatives such as 2,4,6-trianilino- (p-carbo-2 , -ethyl-r-hexyloxy) -l, 3,5-triazine and octyl triazone, as described in EP 0818450 AI or dioctyl butamido triazone (Uvasorb® HEB);
  • Typical UV-A filters are, in particular, derivatives of benzoyl methane such as l- (4, -tert.Butylphenyl) -3- (4-methoxyphenyl) propan-l, 3-dione, 4-tert-butyl -4 , - methoxydibenzoylmethane (Parsol® 1789), l-phenyl-3- (4 , -isopropylphenyl) propane-l, 3-dione and enamine compounds, as described in DE 19712033 AI (BASF).
  • the UV-A and UV-B filters can of course also be used in mixtures.
  • Particularly favorable combinations consist of the derivatives of benzoyl methane , for example 4-tert-butyl 4 ⁇ methoxydibenzoylmethane (Parsol 1789) and 2-cyano-3,3-phenylcinnamate-2-ethyl-hexyl ester (Octocrylene), in combination with Esters of cinnamic acid, preferably 2-ethylhexyl 4-methoxycinnamate and / or propyl 4-methoxycinnamate and / or isoamyl 4-methoxycinnamate.
  • benzoyl methane for example 4-tert-butyl 4 ⁇ methoxydibenzoylmethane (Parsol 1789) and 2-cyano-3,3-phenylcinnamate-2-ethyl-hexyl ester (Octocrylene)
  • Esters of cinnamic acid preferably 2-ethylhexyl 4-methoxyc
  • water-soluble filters such as 2-phenylbenzimidazole-5-sulfonic acid and its alkali, alkaline earth, ammonium, alkylammonium, alkanolammonium and glucammonium salts.
  • insoluble light protection pigments namely finely dispersed metal oxides or salts, are also suitable for this purpose.
  • suitable metal oxides are, in particular, zinc oxide and titanium dioxide and, in addition, oxides of iron, zirconium, silicon, manganese, aluminum and cerium and mixtures thereof.
  • Silicates (talc), barium sulfate or zinc stearate can be used as salts.
  • the oxides and salts are used in the form of the pigments for skin-care and skin-protecting emulsions and decorative cosmetics.
  • the particles should have an average diameter of less than 100 nm, preferably between 5 and 50 nm and in particular between 15 and 30 nm. They can have a spherical shape, but it is also possible to use particles which have an ellipsoidal shape or shape which differs from the spherical shape in some other way.
  • the pigments can also be surface-treated, ie hydrophilized or hydrophobicized. Typical examples are coated titanium dioxides such as titanium dioxide T 805 (Degussa) or Eusolex® T2000 (Merck). So-called micro- or nanopigments are preferably used in sunscreens. Micronized zinc oxide is preferably used.
  • Other suitable UV light protection filters are in the overview by P.Finkel in S ⁇ FW-Journal 122, 543 (1996) and Parf.Kosm. 3, 11 (1999).
  • secondary light stabilizers of the antioxidant type can also be used, which interrupt the photochemical reaction chain which is triggered when UV radiation penetrates the skin.
  • amino acids e.g. glycine, histidine, tyrosine, tryptophan
  • imidazoles e.g. urocanic acid
  • peptides such as D, L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g.
  • carotenoids carotenoids
  • carotenes eg ⁇ -carotene, ⁇ -carotene, lycopene
  • chlorogenic acid and their derivatives lipoic acid and their derivatives (eg dihydrolipoic acid), aurothioglucose, propylthiou-racil and other thiols (eg thioredoxin, Glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, ⁇ -linoleyl, cholesteryl and glyceryl esters ) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and their derivatives (esters, ethers, peptides, lipids, nucleic acid and
  • (metal) chelators e.g. ⁇ -hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), ⁇ -hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts , Bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g. ⁇ -linolenic acid, linoleic acid, oleic acid), folic acid and their derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and derivatives (e.g.
  • biogenic active ingredients are tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy) ribonucleic acid and its fragmentation products, ⁇ -glucans, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudo-ceramides, penal ceramides, Plant extracts, such as To understand prunus extract, Bambaranus extract and vitamin complexes.
  • Cosmetic deodorants counteract, mask or eliminate body odors.
  • Body odors arise from the action of skin bacteria on apocrine sweat, whereby unpleasant smelling breakdown products are formed. Accordingly, deodorants contain active ingredients which act as germ-inhibiting agents, enzyme inhibitors, odor absorbers or odor maskers.
  • germ-inhibiting agents such as.
  • Esterase inhibitors are suitable as enzyme inhibitors. These are preferably trialky guide rates such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and in particular triethyl citrate (Hydagen® CAT). The substances inhibit enzyme activity and thereby reduce odor.
  • trialky guide rates such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and in particular triethyl citrate (Hydagen® CAT).
  • the substances inhibit enzyme activity and thereby reduce odor.
  • esterase inhibitors include sterol sulfates or phosphates, such as, for example, lanosterol, cholesterol, campesteric, stigmasterol and sitosterol sulfate or phosphate, dicarboxylic acids and their esters, such as, for example, glutaric acid, glutaric acid monoethyl ester, glutaric acid diethyl ester, Adipic acid, adipic acid monoethyl ester, adipic acid diethyl ester, malonic acid and malonic acid diethyl ester, hydroxycarboxylic acids and their esters such as citric acid, malic acid, tartaric acid or tartaric acid diethyl ester and zinc glycinate.
  • dicarboxylic acids and their esters such as, for example, glutaric acid, glutaric acid monoethyl ester, glutaric acid diethyl ester, Adipic acid, adipic acid monoethyl ester, a
  • Suitable odor absorbers are substances that absorb odor-forming compounds and can retain them to a large extent. They lower the partial pressure of the individual components and thus also reduce their speed of propagation. It is important that perfumes must remain unaffected. Odor absorbers are not effective against bacteria. They contain, for example, a complex zinc salt of ricinoleic acid or special, largely odorless fragrances, which are known to the person skilled in the art as "fixators", such as, for example, the main component. B. extracts of Labdanum or Styrax or certain abietic acid derivatives. Fragrance agents or perfume oils act as odor maskers and, in addition to their function as odor maskers, give the deodorants their respective fragrance.
  • Perfume oils are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers, stems and leaves, fruits, fruit peels, roots, woods, herbs and grasses, needles and branches as well as resins and balms. Animal raw materials, such as civet and castoreum, are also suitable. Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type.
  • Fragrance compounds of the ester type are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexyl propionate, styrallyl propionate and benzyl salicylate.
  • the ethers include, for example, benzyl ethyl ether
  • the aldehydes include, for example, the linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, lilial and bourgeonal
  • the ketones include, for example, the joonones and methylcedryl ketone
  • the alcohols are anethole
  • Citronellol Citronellol
  • eugenol isoeugenol
  • Geraniol linalool
  • the hydrocarbons mainly include the terpenes and balsams.
  • fragrance oils of lower volatility which are mostly used as aroma components, are also suitable as perfume oils, e.g. sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, vetiver oil, oliban oil, galbaneum oil, labdanum oil and lavandin oil.
  • Antiperspirants reduce sweat formation by influencing the activity of the eccrine sweat glands and thus counteract armpit wetness and body odor.
  • Aqueous or anhydrous formulations of antiperspirants typically contain the following ingredients:
  • non-aqueous solvents such as As ethanol, propylene glycol and / or glycerin.
  • Salts of aluminum, zirconium or zinc are particularly suitable as astringent antiperspirant active ingredients.
  • suitable antiperspirant active ingredients are, for example, aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesquichlorohydrate and their complex compounds, for. B. with propylene glycol-1,2.
  • titrants can contain the usual oil-soluble and water-soluble auxiliaries in smaller quantities. Examples of such oil-soluble auxiliaries are:
  • water-soluble additives are e.g. Preservatives, water-soluble fragrances, pH adjusting agents, e.g. Buffer mixtures, water soluble thickeners, e.g. water-soluble natural or synthetic polymers such as e.g. Xanthan gum, hydroxyethyl cellulose, polyvinyl pyrrolidone or high molecular weight polyethylene oxides.
  • Common film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or its salts and similar compounds.
  • Piroctone olamine (1-hydroxy-4-methyl-6- (2,4,4-trimythylpentyl) -2- (1H) -pyridinone monoethanolamine salt
  • Baypival® (climbazole), Ketoconazol®, (4-acetyl -l - ⁇ - 4- [2- (2.4-dichlorophenyl) r-2- (lH-imidazol-l-ylmethyi) -l, 3-dioxylan-c-4-ylmethoxyphenyl ⁇ piperazine, ketoconazole, elubiol, selenium disulfide, sulfur colloidal sulfur polyehtylenglykolsorbitanmonooleat, Schwefelrizinolpolyehtoxylat, Schwfel tar distillate, salicylic acid (or in combination with hexachlorophene), undecylenic acid monoethanolamide sulfosuccinate Na salt, Lamepon® UD (protein unde
  • Possible insect repellents are N, N-diethyl-m-toluamide, 1,2-pentanediol or ethyl butyl acetylaminopropionate
  • Hydrotropes such as ethanol, isopropyl alcohol or polyols can also be used to improve the flow behavior during application.
  • Polyols that come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups.
  • the polyols can also contain further functional groups, in particular amino groups, or be modified with nitrogen. Typical examples are
  • Alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons;
  • Methyl compounds such as, in particular, trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
  • Dialcohol amines such as diethanolamine or 2-amino-l, 3-propanediol.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid, as well as the silver complexes known under the name Surfacine® and the other classes of substances listed in Appendix 6, Parts A and B of the Cosmetics Ordinance.
  • Perfume oils and flavors are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid, as well as the silver complexes known under the name Surfacine® and the other classes of substances listed in Appendix 6, Parts A and B of the Cosmetics Ordinance.
  • Perfume oils include mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers (lily, lavender, roses, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, cumin, juniper), fruit peel (bergamot, lemon, Oranges), roots (mace, angelica, celery, cardamom, costus, iris, calmus), woods (pine, sandal, guaiac, cedar, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme) ), Needles and twigs (spruce, fir, pine, mountain pine), resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax).
  • Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Fragrance compounds of the ester type are e.g.
  • the ethers include, for example, benzyl ethyl ether, the aldehydes e.g.
  • the linear alkanals with 8 to 18 carbon atoms citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, lilial and bourgeonal, to the ketones e.g. the Jonone, ⁇ -Isomethylionon and Methylcedrylketon, to the alcohols Anethol, Citronellol, Eugenol, Isoeugenol, Geraniol, Linalool, Phenylethylalkohol and Terpineol, to the hydrocarbons belong mainly the Terpenes and Balsame. However, preference is given to using mixtures of different fragrances which together produce an appealing fragrance.
  • Essential oils of lower volatility which are mostly used as aroma components, are also suitable as perfume oils, e.g. Sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, vetiver oil, oliban oil, galbanum oil, labolanum oil and lavandin oil.
  • perfume oils e.g. Sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, vetiver oil, oliban oil, galbanum oil, labolanum oil and lavandin oil.
  • Suitable flavors are, for example, peppermint oil, spearmint oil, anise oil, star anise oil, cumin oil, eucalyptus oil, fennel oil, lemon oil, winter green oil, clove oil, menthol and the like. dyes
  • the dyes which can be used are those substances which are suitable and approved for cosmetic purposes, as compiled, for example, in the publication "Cosmetic Dyes” by the Dye Commission of the German Research Foundation, Verlag Chemie, Weinheim, 1984, pp. 81-106. Examples are culinary red A (CI 16255), patent blue V (CI42051), indigo (CI73015), chlorophyllin (CI75810), quinoline yellow (CI47005), titanium dioxide (CI77891), indanthrene blue RS (CI 69800) and madder varnish (CI58000). Luminol may also be present as the luminescent dye. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
  • Table 2a Composition of impregnation solution, quantity in% by weight of active substance
  • Table 2b Composition of the impregnation solution, quantity in% by weight of active substance

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Abstract

La présente invention concerne des lingettes cosmétiques sèches caractérisées en ce qu'elles présentent une surface uniformément structurée comprenant des creux ponctuels à ovales et en ce qu'elles sont imprégnées d'une solution qui renferme (a) des agents tensioactifs anioniques et/ou cationiques et/ou non ioniques et/ou amphotères et/ou zwitterioniques, ainsi que (b) des dispersions de cire comprenant des particules de taille particulaire moyenne allant de 0,08 à 13 mu m. La composition d'une structure de support spécifique avec des auxiliaires de taille particulaire définie conduit à une production de mousse et à un effet nettoyant optimaux et à une analyse sensorielle favorable.
PCT/EP2002/011673 2001-10-26 2002-10-18 Lingettes cosmetiques seches a surface structuree WO2003037292A1 (fr)

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DE10152942 2001-10-26
DE10152942.2 2001-10-26

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JP (1) JP4824907B2 (fr)
DE (1) DE10162184A1 (fr)
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WO2004052322A1 (fr) * 2002-12-12 2004-06-24 Henkel Kommanditgesellschaft Auf Aktien Lingettes pour soigner des fibres de keratine
WO2004062702A1 (fr) * 2003-01-08 2004-07-29 Johnson & Johnson Gmbh Produits comprenant une feuille et une dispersion de cire
WO2004062630A1 (fr) * 2003-01-08 2004-07-29 Cognis Ip Management Gmbh Dispersions de cire
WO2005034887A1 (fr) * 2003-09-11 2005-04-21 Kimberly-Clark Worldwide, Inc. Lingettes imbibees de lotion presentant une stabilite amelioree
WO2007070520A1 (fr) * 2005-12-12 2007-06-21 Milliken & Company Dispositif de nettoyage
US7547443B2 (en) 2003-09-11 2009-06-16 Kimberly-Clark Worldwide, Inc. Skin care topical ointment
EP2070508A1 (fr) * 2007-12-14 2009-06-17 Johnson and Johnson GmbH Composition de soin dermatologique
WO2011022061A1 (fr) * 2009-08-21 2011-02-24 S. C. Johnson & Son, Inc. Lingette nettoyante « verte » activée par l'eau
WO2013082430A1 (fr) 2011-12-01 2013-06-06 L'oreal Lingette sèche pour diminuer des frisottis et l'électricité statique et pour augmenter le brillant sur les cheveux et faciliter la prévention de la récurrence de l'électricité statique et des frisottis
CN112920915A (zh) * 2012-11-28 2021-06-08 艺康美国股份有限公司 使用聚乙烯亚胺乙氧基化物的泡沫稳定化
FR3134008A1 (fr) * 2022-03-31 2023-10-06 L'oreal Composition pour le soin d’une matière kératineuse

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US10137062B2 (en) 2011-12-01 2018-11-27 L'oreal Dry wipe to decrease frizz, static and increase shine on hair and aid in prevention of reoccurance of static and frizz
CN112920915A (zh) * 2012-11-28 2021-06-08 艺康美国股份有限公司 使用聚乙烯亚胺乙氧基化物的泡沫稳定化
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