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WO2006007995A3 - Method for the production of flameproof, expandable polystyrol - Google Patents

Method for the production of flameproof, expandable polystyrol Download PDF

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Publication number
WO2006007995A3
WO2006007995A3 PCT/EP2005/007398 EP2005007398W WO2006007995A3 WO 2006007995 A3 WO2006007995 A3 WO 2006007995A3 EP 2005007398 W EP2005007398 W EP 2005007398W WO 2006007995 A3 WO2006007995 A3 WO 2006007995A3
Authority
WO
WIPO (PCT)
Prior art keywords
flameproof
production
expandable
polystyrol
styrol
Prior art date
Application number
PCT/EP2005/007398
Other languages
German (de)
French (fr)
Other versions
WO2006007995A2 (en
Inventor
Klaus Hahn
Gerd Ehrmann
Joachim Ruch
Markus Allmendinger
Bernhard Schmied
Jan Holoch
Original Assignee
Basf Ag
Klaus Hahn
Gerd Ehrmann
Joachim Ruch
Markus Allmendinger
Bernhard Schmied
Jan Holoch
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Klaus Hahn, Gerd Ehrmann, Joachim Ruch, Markus Allmendinger, Bernhard Schmied, Jan Holoch filed Critical Basf Ag
Priority to EP05772383A priority Critical patent/EP1771502A2/en
Priority to MX2007000052A priority patent/MX2007000052A/en
Publication of WO2006007995A2 publication Critical patent/WO2006007995A2/en
Publication of WO2006007995A3 publication Critical patent/WO2006007995A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0019Use of organic additives halogenated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/3461Making or treating expandable particles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/02Halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/02Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/03Extrusion of the foamable blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene
    • C08J2325/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The invention relates to a method for the production of flameproof, expandable styrol polymers (EPS) by extruding a styrol polymer melt containing a propellant and flameproof agents through a nozzle plate with subsequent under water granulation. The residence time of the flameproof agent is less than 30 minutes at a melting temperature in the region of between 140 to 220 °C.
PCT/EP2005/007398 2004-07-15 2005-07-08 Method for the production of flameproof, expandable polystyrol WO2006007995A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP05772383A EP1771502A2 (en) 2004-07-15 2005-07-08 Method for the production of flameproof, expandable polystyrol
MX2007000052A MX2007000052A (en) 2004-07-15 2005-07-08 Method for the production of flameproof, expandable polystyrol.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004034516.3 2004-07-15
DE102004034516A DE102004034516A1 (en) 2004-07-15 2004-07-15 Process for the preparation of flame-retardant, expandable polystyrene

Publications (2)

Publication Number Publication Date
WO2006007995A2 WO2006007995A2 (en) 2006-01-26
WO2006007995A3 true WO2006007995A3 (en) 2006-04-06

Family

ID=35285600

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2005/007398 WO2006007995A2 (en) 2004-07-15 2005-07-08 Method for the production of flameproof, expandable polystyrol

Country Status (5)

Country Link
EP (1) EP1771502A2 (en)
KR (1) KR20070042180A (en)
DE (1) DE102004034516A1 (en)
MX (1) MX2007000052A (en)
WO (1) WO2006007995A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101578953B1 (en) 2007-11-21 2015-12-18 바스프 에스이 Flameproof expandable styrene polymers, and method for the production thereof

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007107493A1 (en) 2006-03-22 2007-09-27 Basf Se Method and device for granulating polymer melts containing blowing agent
EP2025700A1 (en) * 2007-08-01 2009-02-18 Ineos Europe Limited process for the production of expandable polystyrene (eps) comprising flame retardant additives
AT505735A1 (en) 2007-09-14 2009-03-15 Sunpor Kunststoff Gmbh METHOD FOR THE PRODUCTION OF EXPANDABLE STYROLOPLYMERISES
PL2062935T3 (en) 2007-11-21 2012-09-28 Basf Se Method for inserting solid particles in polymer melts
AT510311B1 (en) 2010-08-27 2013-02-15 Sunpor Kunststoff Gmbh FLAME-PROTECTED, HEAT-DAMPING POLYMERISATES AND METHOD FOR THE PRODUCTION THEREOF
ITMI20120571A1 (en) 2012-04-06 2013-10-07 Versalis Spa "PROCEDURE FOR THE ADDITION AND TRANSPORT OF LABEL ADDITIVES IN CURRENT MATERIALS"
ES2752053T3 (en) 2012-12-28 2020-04-02 Total Res & Technology Feluy Expandable vinyl aromatic polymers containing graphite particles that have a polymodal particle size distribution
BR112015014742A2 (en) 2012-12-28 2017-07-11 Total Res & Technology Feluy expandable vinyl aromatic polymers comprising platelet needle coke particles
EP2868686B1 (en) * 2013-11-05 2018-12-26 Coperion GmbH Method and device for producing a polymer melt containing additives and blowing agents
MA41344B1 (en) 2015-01-14 2019-01-31 Synthos Sa Combination of silica and graphite and its use to reduce the thermal conductivity of a vinyl aromatic polymer foam
MA41342A (en) 2015-01-14 2017-11-21 Synthos Sa PROCESS FOR THE PRODUCTION OF EXPANDABLE AROMATIC VINYL POLYMER GRANULATES WITH REDUCED THERMAL CONDUCTIVITY
ES2718408T3 (en) 2015-01-14 2019-07-01 Synthos Sa Expandable vinyl aromatic polymer granulate and expanded vinyl aromatic polymer foam comprising geopolymer composite material and their use therein
WO2016113328A1 (en) 2015-01-14 2016-07-21 Synthos S.A. Use of a mineral having perovskite structure in vinyl aromatic polymer foam
UA125517C2 (en) 2016-07-20 2022-04-13 Сінтос С.А. Use of geopolymeric additive in combination with non-brominated flame retardant in polymer foams
WO2018015494A1 (en) 2016-07-20 2018-01-25 Synthos S.A. Modified geopolymer and modified geopolymer composite and process for the production thereof
KR20190039400A (en) 2016-07-20 2019-04-11 신도스 에스.에이. Method for producing a geopolymer or a geopolymer complex

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4236579A1 (en) * 1992-06-04 1993-12-09 Basf Ag Process for the production of foam boards with high compressive strength from styrene polymers
DE19819058A1 (en) * 1998-04-29 1999-11-04 Basf Ag Expandable slightly foamed styrene polymerizate particles of coarse cell structure, useful as insulating or packing materials

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2960897A (en) 1996-05-28 1998-01-05 Basf Aktiengesellschaft Expandable styrene polymers containing carbon black
ATE196158T1 (en) 1997-05-14 2000-09-15 Basf Ag EXPANDABLE STYRENE POLYMERS CONTAINING GRAPHITE PARTICLES
ITMI20012515A1 (en) 2001-11-30 2003-05-30 Enichem Spa VINYLAOMATIC POLYMERS WITH IMPROVED FIRE BEHAVIOR

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4236579A1 (en) * 1992-06-04 1993-12-09 Basf Ag Process for the production of foam boards with high compressive strength from styrene polymers
DE19819058A1 (en) * 1998-04-29 1999-11-04 Basf Ag Expandable slightly foamed styrene polymerizate particles of coarse cell structure, useful as insulating or packing materials

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ANONYMOUS: "Processing heat sensitive material in extruded polymer foam - using downstream mixer fed via extruder to prevent high temp. in precess", RESEARCH DISCLOSURE, vol. 270, no. 052, 10 October 1986 (1986-10-10), Emsworth, GB, XP002354832 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101578953B1 (en) 2007-11-21 2015-12-18 바스프 에스이 Flameproof expandable styrene polymers, and method for the production thereof

Also Published As

Publication number Publication date
EP1771502A2 (en) 2007-04-11
DE102004034516A1 (en) 2006-02-16
WO2006007995A2 (en) 2006-01-26
KR20070042180A (en) 2007-04-20
MX2007000052A (en) 2007-03-28

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