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WO2008003729A3 - Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres - Google Patents

Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres Download PDF

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Publication number
WO2008003729A3
WO2008003729A3 PCT/EP2007/056779 EP2007056779W WO2008003729A3 WO 2008003729 A3 WO2008003729 A3 WO 2008003729A3 EP 2007056779 W EP2007056779 W EP 2007056779W WO 2008003729 A3 WO2008003729 A3 WO 2008003729A3
Authority
WO
WIPO (PCT)
Prior art keywords
derivatives
free
preparation
aqueous dispersion
radical polymerization
Prior art date
Application number
PCT/EP2007/056779
Other languages
English (en)
Other versions
WO2008003729A2 (fr
Inventor
Patrick Lacroix-Desmazes
Jeff Tonnar
Original Assignee
Patrick Lacroix-Desmazes
Jeff Tonnar
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Patrick Lacroix-Desmazes, Jeff Tonnar filed Critical Patrick Lacroix-Desmazes
Priority to EP07787075A priority Critical patent/EP2049573A2/fr
Priority to MX2008016485A priority patent/MX2008016485A/es
Priority to US12/308,977 priority patent/US20090306302A1/en
Publication of WO2008003729A2 publication Critical patent/WO2008003729A2/fr
Publication of WO2008003729A3 publication Critical patent/WO2008003729A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/04—Azo-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Procédé de polymérisation radicalaire en dispersion aqueuse pour la préparation de polymères mettant en oeuvre (A) au moins un monomère éthyléniquement insaturé dont l'un d'entre eux est mis en oeuvre à titre de monomère principal et est choisi parmi le styrène et ses dérivés, l'acide acrylique et ses dérivés, l'acide méthacrylique et ses dérivés, les diéniques, les esters vinyliques, les éthers vinyliques, les dérivés vinyliques de la pyridine, l'acide vinylsulphonique et ses dérivés, l'acide vinylphosphonique et ses dérivés et les monomères N-vinyliques, (B) au moins un agent générateur de radicaux choisis parmi les diazocomposés, les peroxydes et les dialkyldiphénylalcanes, (C) de l'iode moléculaire, et (D) au moins un oxydant dont la solubilité dans l'eau est d'au moins 10 g/l dont au moins un peut être l'un de (B); qui comprend les étapes selon lesquelles (1) on introduit dans un réacteur au moins une fraction de chacun des composés (A), (B), (C) et (D); et (2) on fait réagir le contenu du réacteur, tout en y introduisant le solde éventuel de chacun des composés (A), (B), (C) et (D). Procédé de polymérisation radicalaire en dispersion aqueuse pour la préparation de copolymères à blocs au départ de polymères préparés par le procédé susmentionné.
PCT/EP2007/056779 2006-07-04 2007-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres WO2008003729A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP07787075A EP2049573A2 (fr) 2006-07-04 2007-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
MX2008016485A MX2008016485A (es) 2006-07-04 2007-07-04 Procedimiento de polimerización por radicales libres en dispersión acuosa para la preparación de polímeros.
US12/308,977 US20090306302A1 (en) 2006-07-04 2007-07-04 Process of free-radical polymerization in aqueous disperasion for the preparation of polymers

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0606079 2006-07-04
FR0606079A FR2903409A1 (fr) 2006-07-04 2006-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
US81827606P 2006-07-05 2006-07-05
US60/818,276 2006-07-05

Publications (2)

Publication Number Publication Date
WO2008003729A2 WO2008003729A2 (fr) 2008-01-10
WO2008003729A3 true WO2008003729A3 (fr) 2008-05-08

Family

ID=37719193

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/EP2007/056778 WO2008003728A1 (fr) 2006-07-04 2007-07-04 Procédé de polymérisation radicalaire dans une dispersion aqueuse permettant la préparation d'un copolymère séquencé comprenant au moins une séquence de polymère halogéné
PCT/EP2007/056779 WO2008003729A2 (fr) 2006-07-04 2007-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/056778 WO2008003728A1 (fr) 2006-07-04 2007-07-04 Procédé de polymérisation radicalaire dans une dispersion aqueuse permettant la préparation d'un copolymère séquencé comprenant au moins une séquence de polymère halogéné

Country Status (6)

Country Link
US (2) US8541524B2 (fr)
EP (2) EP2041185B1 (fr)
JP (1) JP5201419B2 (fr)
FR (1) FR2903409A1 (fr)
MX (1) MX2008016485A (fr)
WO (2) WO2008003728A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7741524B2 (en) 2003-04-22 2010-06-22 Solvay (Societe Anonyme) Iodinated organic substances of low molecular mass and process for preparing them
FR2903409A1 (fr) * 2006-07-04 2008-01-11 Solvay Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
DE102008054482A1 (de) * 2008-12-10 2010-06-17 Wacker Chemie Ag Pfropfcopolymere und deren Verwendung als Low-Profile-Additive
JP2013018953A (ja) * 2011-06-15 2013-01-31 Canon Inc 高分子粒子の製造方法
KR101507999B1 (ko) 2011-08-03 2015-04-07 인하대학교 산학협력단 Ｒｉｔｐ 중합법과 용액 재결정법을 이용한 안정화된 단분산 구형 고분자 입자의 제조 방법
JP6312599B2 (ja) * 2011-12-21 2018-04-18 ソルヴェイ（ソシエテ アノニム） 塩化ビニリデン重合体の製造方法
US9394394B2 (en) * 2013-09-30 2016-07-19 Honeywell International Inc. Synthesis of chlorotrifluoroethylene-based block copolymers by iodine transfer polymerization
FR3053970A1 (fr) 2016-07-13 2018-01-19 Centre National De La Recherche Scientifique (Cnrs) Procede de synthese d'une polyolefine par romp en presence d'un catalyseur a base de ruthenium
EP4107229A4 (fr) 2020-02-21 2024-03-06 Swimc LLC Polymères antitaches, amorces, kits et procédés
WO2023005567A1 (fr) 2021-07-30 2023-02-02 Basf Se Composition et son utilisation dans la polymérisation d'émulsion à base d'eau vivante contrôlée
CN119463072A (zh) * 2024-11-11 2025-02-18 苏州大学 一种基于光控原位溴-碘转换可逆-失活自由基聚合法制备星形嵌段共聚物的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040054108A1 (en) * 2002-07-23 2004-03-18 Mestach Dirk Emiel Paula Method for polymerizing ethylenically unsaturated monomers by degenerative iodine transfer
FR2858319A1 (fr) * 2003-08-01 2005-02-04 Solvay Procede de preparation de substances organiques iodees de faible masse moleculaire et substances organiques iodees de faible masse moleculaire
WO2007085623A1 (fr) * 2006-01-26 2007-08-02 Rhodia Operations Procede de preparation par polymerisation par transfert d'iode d'un copolymere a architecture controlee de type telomere ou de copolymere a bloc issu de monomeres vinyl phosphonate

Family Cites Families (15)

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US3467636A (en) * 1967-02-24 1969-09-16 Du Pont Redox catalyst system for preparing vinylidene fluoride interpolymers
LU73211A1 (fr) 1975-08-18 1977-04-15
JPS5386787A (en) * 1977-09-30 1978-07-31 Daikin Ind Ltd Polymer having fluorine-containing segment and its production
JPS63260914A (ja) * 1987-04-17 1988-10-27 Nippon Mektron Ltd ブロツク共重合体の製造方法
BE1007648A3 (fr) * 1993-10-21 1995-09-05 Solvay Procede pour la polymerisation radicalaire du chlorure de vinyle a ph acide en dispersion aqueuse.
EP1026152B1 (fr) * 1997-03-31 2006-07-26 Daikin Industries, Limited Procede de production de derives d'acide ethersulfonique de perfluorovinyle
EP0947527A1 (fr) 1998-04-03 1999-10-06 The B.F. Goodrich Company Copolymères à blocs au milieu aqueux et un procédé pour leur production
US6911515B2 (en) * 2001-03-23 2005-06-28 University Of Pennsylvania Aqueous room temperature living radical polymerization of vinyl halides
FR2826658B1 (fr) * 2001-06-29 2003-09-05 Rhodia Chimie Sa Synthese de polymeres par voie radicalaire controlee en miniemulsion
FR2839725A1 (fr) * 2002-05-17 2003-11-21 Solvay Polymeres alpha-fluoroacryliques a faible indice de polydispersite, procede pour les synthetiser et procede de fabrication d'articles les mettant en oeuvre
FR2839724B1 (fr) * 2002-05-17 2005-08-05 Solvay Procedes de polymerisation radicalaire pour preparer des polymeres halogenes et polymeres halogenes
US7741524B2 (en) * 2003-04-22 2010-06-22 Solvay (Societe Anonyme) Iodinated organic substances of low molecular mass and process for preparing them
EP1622853A1 (fr) * 2003-04-22 2006-02-08 SOLVAY (Société Anonyme) Substances organiques iodees a faible poids moleculaire et procede pour les preparer
FR2903409A1 (fr) * 2006-07-04 2008-01-11 Solvay Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
WO2008155324A1 (fr) * 2007-06-21 2008-12-24 Dsm Ip Assets B.V. Procédé permettant d'obtenir de faibles niveaux de monomères libres dans une émulsion de copolymère séquencé préparée par polymérisation par transfert d'iode (inverse)

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040054108A1 (en) * 2002-07-23 2004-03-18 Mestach Dirk Emiel Paula Method for polymerizing ethylenically unsaturated monomers by degenerative iodine transfer
FR2858319A1 (fr) * 2003-08-01 2005-02-04 Solvay Procede de preparation de substances organiques iodees de faible masse moleculaire et substances organiques iodees de faible masse moleculaire
WO2007085623A1 (fr) * 2006-01-26 2007-08-02 Rhodia Operations Procede de preparation par polymerisation par transfert d'iode d'un copolymere a architecture controlee de type telomere ou de copolymere a bloc issu de monomeres vinyl phosphonate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2049573A2 *

Also Published As

Publication number Publication date
MX2008016485A (es) 2009-02-25
WO2008003729A2 (fr) 2008-01-10
US8541524B2 (en) 2013-09-24
US20090306302A1 (en) 2009-12-10
US20090292071A1 (en) 2009-11-26
JP5201419B2 (ja) 2013-06-05
EP2049573A2 (fr) 2009-04-22
EP2041185B1 (fr) 2019-01-09
FR2903409A1 (fr) 2008-01-11
JP2009541567A (ja) 2009-11-26
WO2008003728A1 (fr) 2008-01-10
EP2041185A1 (fr) 2009-04-01

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