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WO2008107571A3 - Silicates mixtes de lithium. - Google Patents

Silicates mixtes de lithium. Download PDF

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Publication number
WO2008107571A3
WO2008107571A3 PCT/FR2008/000148 FR2008000148W WO2008107571A3 WO 2008107571 A3 WO2008107571 A3 WO 2008107571A3 FR 2008000148 W FR2008000148 W FR 2008000148W WO 2008107571 A3 WO2008107571 A3 WO 2008107571A3
Authority
WO
WIPO (PCT)
Prior art keywords
silicates
mixed lithium
lithium silicates
mixed
space group
Prior art date
Application number
PCT/FR2008/000148
Other languages
English (en)
Other versions
WO2008107571A2 (fr
Inventor
Gerard Quoirin
Jean-Marie Tarascon
Christian Masquelier
Charles Delacourt
Philippe Poizot
Francis Taulelle
Original Assignee
Centre Nat Rech Scient
Gerard Quoirin
Jean-Marie Tarascon
Christian Masquelier
Charles Delacourt
Philippe Poizot
Francis Taulelle
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre Nat Rech Scient, Gerard Quoirin, Jean-Marie Tarascon, Christian Masquelier, Charles Delacourt, Philippe Poizot, Francis Taulelle filed Critical Centre Nat Rech Scient
Priority to EP08761851A priority Critical patent/EP2118007A2/fr
Priority to JP2009548714A priority patent/JP2010517913A/ja
Priority to CA002677711A priority patent/CA2677711A1/fr
Publication of WO2008107571A2 publication Critical patent/WO2008107571A2/fr
Publication of WO2008107571A3 publication Critical patent/WO2008107571A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/32—Alkali metal silicates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Silicon Compounds (AREA)
  • Secondary Cells (AREA)

Abstract

L'invention concerne des silicates mixtes de lithium. Les silicates mixtes ont la formule Li2MII(1 x)MIIIxSiO4(OH)x (I) dans laquelle 0≤ x≤ 1 et M est Fe, Co, Mn ou Ni. Ils sont caractérisés en ce qu'ils sont sous forme de particules substantiellement sphériques et non coalescées, ayant une dimension de 400 à 600 nm et qu'ils ont une structure dans le groupe d'espace Pna21 et éventuellement dans le groupe d'espace Pccn. Les silicates sont obtenus par précipitation en milieu aqueux ô partir de précurseurs. Utilisation comme matière active d'électrode pour des dispositifs électrochimiques.
PCT/FR2008/000148 2007-02-09 2008-02-07 Silicates mixtes de lithium. WO2008107571A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP08761851A EP2118007A2 (fr) 2007-02-09 2008-02-07 Silicates mixtes de lithium.
JP2009548714A JP2010517913A (ja) 2007-02-09 2008-02-07 混合されたケイ酸リチウム
CA002677711A CA2677711A1 (fr) 2007-02-09 2008-02-07 Silicates mixtes de lithium

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0700932A FR2912398B1 (fr) 2007-02-09 2007-02-09 Silicates mixtes de lithium
FR0700932 2007-02-09

Publications (2)

Publication Number Publication Date
WO2008107571A2 WO2008107571A2 (fr) 2008-09-12
WO2008107571A3 true WO2008107571A3 (fr) 2009-06-25

Family

ID=38466368

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2008/000148 WO2008107571A2 (fr) 2007-02-09 2008-02-07 Silicates mixtes de lithium.

Country Status (6)

Country Link
EP (1) EP2118007A2 (fr)
JP (1) JP2010517913A (fr)
CN (1) CN101652321A (fr)
CA (1) CA2677711A1 (fr)
FR (1) FR2912398B1 (fr)
WO (1) WO2008107571A2 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5350849B2 (ja) * 2009-03-23 2013-11-27 株式会社豊田中央研究所 リチウム二次電池
US8999282B2 (en) 2010-02-22 2015-04-07 Massachusetts Institute Of Technology Carbophosphates and related compounds
JP5566723B2 (ja) * 2010-03-01 2014-08-06 古河電気工業株式会社 微粒子混合物、活物質凝集体、正極活物質材料、正極、２次電池及びこれらの製造方法
JP5653637B2 (ja) 2010-03-01 2015-01-14 古河電気工業株式会社 正極活物質材料、正極、２次電池及びこれらの製造方法
CN101920972B (zh) * 2010-06-28 2011-12-14 宁波大学 一种用于锂离子电池的硅酸钴锂正极材料的制备方法
EP2588412A1 (fr) * 2010-06-30 2013-05-08 Höganäs AB Matériau de cathode en silicate double de lithium et fer et sa production
WO2012127762A1 (fr) * 2011-03-23 2012-09-27 ヤマハ発動機株式会社 Composition électriquement conductrice, système de dispersion, procédé de production d'une composition électriquement conductrice et batterie à électrolyte solide
JP5754808B2 (ja) * 2011-10-13 2015-07-29 太平洋セメント株式会社 二次電池用正極活物質及びその製造方法
WO2014155408A1 (fr) * 2013-03-25 2014-10-02 株式会社豊田自動織機 Composé de silicate de lithium contenant de l'hydrogène, son procédé de production, matériau actif positif pour batterie secondaire à électrolyte non aqueux, électrode positive pour batterie secondaire à électrolyte non aqueux et batterie secondaire à électrolyte non aqueux
KR101527286B1 (ko) * 2013-09-30 2015-06-09 고려대학교 산학협력단 리튬 이차 전지용 음극의 형성 방법
CN110127712A (zh) * 2019-05-15 2019-08-16 浙江工业大学 常压水解法制备具有微纳结构的介孔硅酸锂空心球的方法
CN118039890B (zh) * 2024-01-18 2025-02-14 深圳新源邦科技有限公司 一种硅钼酸锂材料及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4764497A (en) * 1981-12-23 1988-08-16 Tokuyama Soda Kabushiki Kaisha Amorphous, spherical inorganic compound and process for preparation thereof
WO2002027824A1 (fr) * 2000-09-26 2002-04-04 HYDRO-QUéBEC Procédé de synthèse de matériau à base de lixm1-ym'y(xo4)n
WO2004056704A1 (fr) * 2002-12-20 2004-07-08 Rockwood Additives Limited Procede de production de compositions de silicate de magnesium synthetique

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4764497A (en) * 1981-12-23 1988-08-16 Tokuyama Soda Kabushiki Kaisha Amorphous, spherical inorganic compound and process for preparation thereof
WO2002027824A1 (fr) * 2000-09-26 2002-04-04 HYDRO-QUéBEC Procédé de synthèse de matériau à base de lixm1-ym'y(xo4)n
WO2004056704A1 (fr) * 2002-12-20 2004-07-08 Rockwood Additives Limited Procede de production de compositions de silicate de magnesium synthetique

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ARROYO-DE DOMPABLO ET AL: "On-demand design of polyoxianionic cathode materials based on electronegativity correlations: An exploration of the Li2MSiO4 system (M=Fe, Mn, Co, Ni)", ELECTROCHEMISTRY COMMUNICATION, ELSEVIER, AMSTERDAM, NL, vol. 8, no. 8, August 2006 (2006-08-01), pages 1292 - 1298, XP005591198, ISSN: 1388-2481 *

Also Published As

Publication number Publication date
CN101652321A (zh) 2010-02-17
WO2008107571A2 (fr) 2008-09-12
FR2912398A1 (fr) 2008-08-15
CA2677711A1 (fr) 2008-09-12
FR2912398B1 (fr) 2009-04-24
JP2010517913A (ja) 2010-05-27
EP2118007A2 (fr) 2009-11-18

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