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WO2009056962A3 - A system for storing and fulling of hydrogen - Google Patents

A system for storing and fulling of hydrogen Download PDF

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Publication number
WO2009056962A3
WO2009056962A3 PCT/IB2008/002919 IB2008002919W WO2009056962A3 WO 2009056962 A3 WO2009056962 A3 WO 2009056962A3 IB 2008002919 W IB2008002919 W IB 2008002919W WO 2009056962 A3 WO2009056962 A3 WO 2009056962A3
Authority
WO
WIPO (PCT)
Prior art keywords
tank
hydrogen
storage tank
heat
offset
Prior art date
Application number
PCT/IB2008/002919
Other languages
French (fr)
Other versions
WO2009056962A2 (en
Inventor
Phiroze Patel
Original Assignee
Phiroze Patel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phiroze Patel filed Critical Phiroze Patel
Priority to EP08844848A priority Critical patent/EP2217848A2/en
Publication of WO2009056962A2 publication Critical patent/WO2009056962A2/en
Publication of WO2009056962A3 publication Critical patent/WO2009056962A3/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00Use of gas-solvents or gas-sorbents in vessels
    • F17C11/005Use of gas-solvents or gas-sorbents in vessels for hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0021Carbon, e.g. active carbon, carbon nanotubes, fullerenes; Treatment thereof
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0026Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0078Composite solid storage mediums, i.e. coherent or loose mixtures of different solid constituents, chemically or structurally heterogeneous solid masses, coated solids or solids having a chemically modified surface region
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0084Solid storage mediums characterised by their shape, e.g. pellets, sintered shaped bodies, sheets, porous compacts, spongy metals, hollow particles, solids with cavities, layered solids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/45Hydrogen technologies in production processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

A hydrogen storage system provides a pressurized storage tank 21 in a motor vehicle 10, the tank containing a heat exchanger 27 and an adsorbent material 22 comprising a soft mass of carbon micro-fibres in the form of carbon wool with a surface area of about 2250m2 /g - 4000m2 /g, having a metal, preferably palladium, dispersed over the surface of the adsorbent in nano-particulate form. The metal is preferably precipitated in ionic form from a solution, and may be reduced after precipitation to a metallic form by hydrogenation at an elevated temperature. A refuelling station 1 comprises a supply of hydrogen H at a first working temperature of about 36K - 77K and a first working pressure up to about 300 bar, which is supplied to the tank 21 via first releasable couplings 9, 24, and a supply of refrigerated helium gas He at about 20K which is simultaneously circulated via second releasable couplings 8, 24 through the heat exchanger 27 in the tank 21 to offset the heat of adsorption. An auxiliary tank 28 contains compressed hydrogen gas H at ambient temperature which is injected in controlled amounts into the storage tank 21 to offset the heat of desorption as the storage tank empties.
PCT/IB2008/002919 2007-11-01 2008-10-23 A system for effective storing and fuelling of hydrogen WO2009056962A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08844848A EP2217848A2 (en) 2007-11-01 2008-10-23 A system for storing and fuelling of hydrogen

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN2174/MUM/2007 2007-11-01
IN2174MU2007 2007-11-01

Publications (2)

Publication Number Publication Date
WO2009056962A2 WO2009056962A2 (en) 2009-05-07
WO2009056962A3 true WO2009056962A3 (en) 2010-01-07

Family

ID=39790457

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/IN2007/000591 WO2009057127A1 (en) 2007-11-01 2007-12-14 A system for effective storing and fuelling of hydrogen
PCT/IB2008/002919 WO2009056962A2 (en) 2007-11-01 2008-10-23 A system for effective storing and fuelling of hydrogen

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/IN2007/000591 WO2009057127A1 (en) 2007-11-01 2007-12-14 A system for effective storing and fuelling of hydrogen

Country Status (2)

Country Link
EP (1) EP2217848A2 (en)
WO (2) WO2009057127A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009057127A1 (en) * 2007-11-01 2009-05-07 Patel Phirose A system for effective storing and fuelling of hydrogen
WO2012049622A1 (en) * 2010-10-15 2012-04-19 Phiroze H Patel An adsorbent system and an apparatus for effective storing and fuelling of hydrogen
FR2979002B1 (en) * 2011-08-12 2014-11-07 Coldway METHOD FOR FILLING A GAS STORAGE TANK
WO2014124873A1 (en) * 2013-02-12 2014-08-21 Shell Internationale Research Maatschappij B.V. Hydrogen quality differentiation at refuelling station

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996041745A1 (en) * 1995-06-09 1996-12-27 Zvi Horovitz High bulk density, parallel carbon fibers
US20030044603A1 (en) * 2001-08-31 2003-03-06 Showa Denko K.K. Fine carbon and method for producing the same
US20040031390A1 (en) * 2002-08-14 2004-02-19 Vitaliy Myasnikov Onboard hydrogen storage unit with heat transfer system for use in a hydrogen powered vehicle
WO2005084170A2 (en) * 2003-09-18 2005-09-15 Enernext, Llc Storage device and method for sorption and desorption of molecular gas contained by storage sites of nano-filament laded reticulated aerogel
EP1726565A1 (en) * 2003-12-05 2006-11-29 Mitsubishi Heavy Industries, Ltd. Carbon material and flue gas treatment apparatus
WO2006130113A1 (en) * 2005-05-31 2006-12-07 Cyclect Electrical Engineering Pte Ltd A method of producing a material for adsorption of fluids
EP1808923A1 (en) * 2004-09-27 2007-07-18 Kabushiki Kaisha Toyota Jidoshokki Method of using hydrogen storage tank and hydrogen storage tank
EP1826051A1 (en) * 2004-11-18 2007-08-29 Kabushiki Kaisha Toyota Jidoshokki Hydrogen tank cooling device and cooling method in hydrogen fuel automobile, and hydrogen fuel automobile
DE102006052109A1 (en) * 2006-11-06 2008-05-08 Robert Bosch Gmbh Fluid storage with thermal management
WO2009057127A1 (en) * 2007-11-01 2009-05-07 Patel Phirose A system for effective storing and fuelling of hydrogen

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61134593A (en) * 1984-11-30 1986-06-21 Agency Of Ind Science & Technol Heat exchange device using hydrogen occlusion alloy
US4749384A (en) * 1987-04-24 1988-06-07 Union Carbide Corporation Method and apparatus for quick filling gas cylinders
US5458784A (en) 1990-10-23 1995-10-17 Catalytic Materials Limited Removal of contaminants from aqueous and gaseous streams using graphic filaments
SG109408A1 (en) * 1999-06-04 2005-03-30 Univ Singapore Method of reversibly storing h2, and h2-storage system based on metal-doped carbon-based materials
US6305442B1 (en) * 1999-11-06 2001-10-23 Energy Conversion Devices, Inc. Hydrogen-based ecosystem
US6596055B2 (en) * 2000-11-22 2003-07-22 Air Products And Chemicals, Inc. Hydrogen storage using carbon-metal hybrid compositions
JP2004108570A (en) * 2002-07-22 2004-04-08 Toyota Motor Corp Hydrogen storage container
US6991671B2 (en) * 2002-12-09 2006-01-31 Advanced Technology Materials, Inc. Rectangular parallelepiped fluid storage and dispensing vessel

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996041745A1 (en) * 1995-06-09 1996-12-27 Zvi Horovitz High bulk density, parallel carbon fibers
US20030044603A1 (en) * 2001-08-31 2003-03-06 Showa Denko K.K. Fine carbon and method for producing the same
US20040031390A1 (en) * 2002-08-14 2004-02-19 Vitaliy Myasnikov Onboard hydrogen storage unit with heat transfer system for use in a hydrogen powered vehicle
WO2005084170A2 (en) * 2003-09-18 2005-09-15 Enernext, Llc Storage device and method for sorption and desorption of molecular gas contained by storage sites of nano-filament laded reticulated aerogel
EP1726565A1 (en) * 2003-12-05 2006-11-29 Mitsubishi Heavy Industries, Ltd. Carbon material and flue gas treatment apparatus
EP1808923A1 (en) * 2004-09-27 2007-07-18 Kabushiki Kaisha Toyota Jidoshokki Method of using hydrogen storage tank and hydrogen storage tank
EP1826051A1 (en) * 2004-11-18 2007-08-29 Kabushiki Kaisha Toyota Jidoshokki Hydrogen tank cooling device and cooling method in hydrogen fuel automobile, and hydrogen fuel automobile
WO2006130113A1 (en) * 2005-05-31 2006-12-07 Cyclect Electrical Engineering Pte Ltd A method of producing a material for adsorption of fluids
DE102006052109A1 (en) * 2006-11-06 2008-05-08 Robert Bosch Gmbh Fluid storage with thermal management
WO2009057127A1 (en) * 2007-11-01 2009-05-07 Patel Phirose A system for effective storing and fuelling of hydrogen

Also Published As

Publication number Publication date
WO2009057127A1 (en) 2009-05-07
WO2009056962A2 (en) 2009-05-07
EP2217848A2 (en) 2010-08-18

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