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WO2014119039A1 - Composition de nettoyage liquide à base d'huile - Google Patents

Composition de nettoyage liquide à base d'huile Download PDF

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Publication number
WO2014119039A1
WO2014119039A1 PCT/JP2013/075076 JP2013075076W WO2014119039A1 WO 2014119039 A1 WO2014119039 A1 WO 2014119039A1 JP 2013075076 W JP2013075076 W JP 2013075076W WO 2014119039 A1 WO2014119039 A1 WO 2014119039A1
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WO
WIPO (PCT)
Prior art keywords
polyglyceryl
oil
liquid cleansing
cleansing composition
oily liquid
Prior art date
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PCT/JP2013/075076
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English (en)
Japanese (ja)
Inventor
花子 秋山
Original Assignee
株式会社ファンケル
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Publication date
Application filed by 株式会社ファンケル filed Critical 株式会社ファンケル
Priority to CN201380060335.6A priority Critical patent/CN104812362A/zh
Priority to HK15110152.6A priority patent/HK1209352A1/xx
Publication of WO2014119039A1 publication Critical patent/WO2014119039A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the present invention relates to an oily liquid cleansing composition.
  • Oily liquid cleansing compositions have been marketed for the purpose of removing skin stains and oily makeup cosmetics.
  • the oily liquid cleansing composition is superior in cleansing effect as compared with the emulsion-type cream-like composition, the emulsion-type cleansing composition, or the aqueous liquid-gel-like cleansing composition.
  • various makeup cosmetics that have better makeup than conventional cosmetics have been developed, and oily liquid cleansing compositions corresponding to these have been desired.
  • eye makeup cosmetics have been developed with many excellent preparations with good makeup.
  • One type is a formulation called an “oil-based solvent type” in which a resin having high adhesion to a volatile oil is dispersed or dissolved, and has a high waterproof effect.
  • an eye makeup cosmetic As an “oil-based solvent” eye makeup cosmetic, an eye makeup cosmetic containing trimethylsiloxysilicic acid, an acrylic-silicone graft copolymer, and a low-boiling silicone oil (Patent Document 1: Japanese Patent Laid-Open No. 7-196449). Gazette), rosin ester compounds, oil-soluble resins, and oleaginous cosmetics containing volatile oils (Patent Document 2: Japanese Patent Laid-Open No. 2009-114099).
  • the other type is a formulation called an “emulsion resin type” in which an aqueous emulsion polymer is blended as a film forming agent, and a combination system of an emulsion and an emulsion resin, which is called an “emulsion / emulsion resin composite type”.
  • emulsion resin composite type eye makeup cosmetics include alkyl acrylate / vinyl acetate copolymer emulsion, alkyl acrylate copolymer emulsion, carbon black, polyhydric alcohol, water-soluble film forming agent And oil-in-water cosmetics (Patent Document 3: JP 2010-77042 A).
  • Non-Patent Document 1 In order to remove the former “oil-based solvent” type eye makeup cosmetic, the removal effect cannot be obtained unless an oil agent highly compatible with the cosmetic is blended.
  • Emsion resin type and “Emulsion / emulsion resin composite type” eye makeup cosmetics are referred to as “film type” on the market and can be removed with hot water or water-based cleaning agents.
  • An object of the present invention is to provide an oily liquid cleansing composition that acts on both an emulsion / emulsion resin composite type eye makeup cosmetic and an oily solvent type eye makeup cosmetic.
  • the main configuration of the present invention is as follows.
  • Polyglyceryl fatty acid esters are polyglyceryl-20 octaisononanoate, polyglyceryl hexaisonononanoate, polyglyceryl-20 heptaisonononanoate, polyglyceryl-20 hexacaprylate, polyglyceryl-20 octacaprylate, polyglyceryl-20 decaprylate, penta Decaprylic acid polyglyceryl-20, hexacapric acid polyglyceryl-20, octacapric acid polyglyceryl-20, diisostearic acid polyglyceryl-10, isostearic acid polyglyceryl-10, triisostearic acid polyglyceryl-10, capric acid polyglyceryl-10, lauric acid polyglyceryl- 5, polyglyceryl-2 caprate, polyglyceryl-6 caprylate, polyglyceryl-10 caprylate, capri Is one or more selected from polyglyceryl-2 (3) oily liquid cleansing
  • the oily liquid cleansing composition according to (8), wherein the diester oil of a monovalent branched fatty acid and a divalent alcohol is butylene glycol diisononanoate.
  • a cleansing composition having strong detergency for both an emulsion / emulsion resin composite type eye makeup cosmetic and an oily solvent type eye makeup cosmetic is provided. Furthermore, the composition of the present invention has excellent pore dirt removal properties, can be used with wet hands, has excellent washability, and has storage stability over time.
  • 6 is a graph showing the removal rate of emulsion / emulsion resin composite eye makeup using the oil-based liquid cleansing compositions of Example 1 and Comparative Examples 1 to 16.
  • 6 is a graph showing the removal rate of oil-based solvent-type eye makeup using the oil-based liquid cleansing compositions of Example 1 and Comparative Examples 1 to 16. It is a graph which shows the measurement result of the particle size distribution of an O / W emulsification particle diameter when a lot of water is added to the cleansing composition of Example 2. It is a graph which shows the measurement result of the particle size distribution of O / W emulsification particle diameter when a large amount of water is added to the cleansing composition of Comparative Example 17.
  • FIG. 1 It is a graph about the result of having measured the square plug dissolution rate of Example 2 and Comparative Examples 18 and 19.
  • FIG. It is a graph which shows the result of having measured the skin water transpiration
  • FIG. 1 It is a graph which shows the result of having measured the skin water transpiration
  • Oily liquid cleansing oil is a preparation that contains a liquid oil as a main component and a small amount of a surfactant and the like, and can easily wash and wash away skin dirt and cosmetics.
  • the present inventor has proposed that a composition containing caprylyl caprylate and / or caprylyl caprate as a constituent of an oily liquid cleansing oil is not only an oily makeup cosmetic, but also an emulsion resin type and an emulsion / emulsion resin composite type eye. It has been found that it is excellent in removing makeup cosmetics.
  • Capryl caprylate and caprylyl caprate used in the present invention are known substances as ester oils, and are used as oily agents in cosmetics. This compound can be used alone or a mixture of both.
  • Caprylyl caprylate is sold by BASF Japan under the trade name of Cethiol 88 and can be used.
  • a mixed oil of capryl caprylate and caprylyl caprate is expressed as (caprylic acid / capric acid) caprylyl.
  • (Caprylic acid / Capric acid) Caprylyl is also sold by BASF Japan under the trade name of cethiol RLF.
  • the amount of caprylyl caprylate and / or caprylyl caprate is preferably 2 to 50% by mass in the oily liquid cleansing oil. If it is less than 2% by mass, the makeup cosmetic removal performance may be inferior.
  • the oily liquid cleansing oil of the present invention can be used as long as it is an oil that is usually blended with cleansing oil.
  • a liquid or pasty oil agent is used at 25 ° C.
  • the liquid or pasty oil agent at 25 ° C. include ester oils, silicone oils, animal and vegetable oils, hydrocarbon oils, higher fatty acids, higher alcohols and the like.
  • silicone oil as a synthetic oil agent in order to increase detergency.
  • silicone oil include dimethicone, diphenylsiloxyphenyl trimethicone, and caprylyl methicone.
  • Animal and vegetable oils include olive oil and jojoba oil, hydrocarbon oils include liquid paraffin and squalane, higher fatty acids include isostearic acid and oleic acid, and higher alcohols include octyldodecanol and oleyl alcohol.
  • the total amount of the liquid or pasty oil agent at 25 ° C. and caprylyl caprylate and / or caprylyl caprate is preferably 40 to 95% by mass based on the total amount of the oily liquid cleansing composition. If it is less than 40% by mass, the effect of raising the makeup cosmetic from the skin will be poor, and if it exceeds 95% by mass, it will be difficult to wash off after the makeup cosmetic is familiarized.
  • polyglycerol fatty acid ester is used.
  • Polyglycerin fatty acid esters include polyglyceryl octaisononanoate-20, polyglyceryl hexaisonononanoate, polyglyceryl-20 heptaisononanoate, polyglyceryl-20 hexacaprylate, polyglyceryl octacaprylate-20, polyglyceryl-20 decaprylate, pentadeca Polyglyceryl-20 caprylate, polyglyceryl-20 hexacaprate, polyglyceryl-20 octacaprate, polyglyceryl-10 diisostearate, polyglyceryl-10 isostearate, polyglyceryl-10 triisostearate, polyglyceryl-10 caprate, polyglyceryl laurate-5 , Polyglyceryl-2 caprate, polyglyceryl-6 caprylate, polyglyceryl-10 caprylate, cap Le acid polyglyceryl-2 and the like.
  • the blending amount of the polyglycerin fatty acid ester used in the present invention is preferably 1 to 40% by mass, particularly 5 to 25% by mass with respect to the total composition of the oily liquid cleansing composition of the present invention.
  • the amount is less than 1% by mass, the cleaning properties and washing properties of the composition are insufficient.
  • the amount is more than 40% by mass, the fluidity is poor and the oily liquid cannot be maintained. May occur.
  • a nonionic surfactant other than polyglycerin fatty acid ester can be blended.
  • polyoxyethylene alkyl ethers polyoxyethylene (10) isostearyl ether, polyoxyethylene (10) octyldodecyl ether, etc.
  • sorbitan fatty acid esters as sorbitan isostearate, sorbitan laurate, coconut fatty acid sorbitan, etc.
  • fatty acid polyethylene glycols polyethylene glycol isostearate (8), polyethylene glycol (10) oleate, polyoxyethylene castor oil, polyethylene glycol (30) hydrogenated castor oil, polyoxyethylene sorbitan fatty acid esters, etc.
  • the oil-based liquid cleansing composition of the present invention includes an anionic surfactant, a cationic surfactant, and an amphoteric surfactant as long as the effects of the present invention are not impaired, other than the nonionic surfactant.
  • An agent can be blended.
  • oily thickener can be blended in the oily liquid cleansing composition of the present invention.
  • oil thickeners include inulin stearate, behenic acid / glycosyl eicosane diacid, dextrin palmitate, dextrin (palmitate / octanoic acid), and the like.
  • oily liquid cleansing composition of the present invention when a diester of a monovalent fatty acid and a divalent alcohol is used as an ester oil, it is highly compatible with makeup cosmetics and exhibits an excellent cleaning function and is washed away. Performance is improved.
  • monovalent fatty acids include 2-ethylhexanoic acid, isononanoic acid, caproic acid, caprylic acid, capric acid and the like.
  • diester oils of branched fatty acids such as 2-ethylhexanoic acid and isononanoic acid and dihydric alcohols are excellent in detergency, and also excellent in functions that can be used with wet hands.
  • divalent alcohol examples include ethylene glycol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, neopentyl glycol, and 1,2-pentanediol.
  • dihydric alcohols propylene glycol, 1,3-butylene glycol, and dipropylene glycol are preferable for obtaining higher detergency.
  • diester oils of monovalent branched fatty acids and divalent alcohols include ethylene glycol di-2-ethylhexanoate, propylene glycol di2-ethylhexanoate, and 1,3-butylene glycol di-2-ethylhexanoate.
  • diisononanoic acid BG diisononanoic acid
  • various ingredients commonly used in cosmetics such as polyhydric alcohols, polyalkylene glycols, saccharides, lower alcohols, polymers, organic, inorganic powders, preservatives, antioxidants and other functional ingredients It can mix
  • water can also be mix
  • the content is preferably 20% by mass or less.
  • Example 1 Preparation of oily liquid cleansing composition A model of a cleansing composition that has been previously confirmed to have a cleaning effect such as oily lipstick, etc., and that does not have a cleaning effect on an emulsion / emulsion resin composite type mascara. A prescription was prepared and used as a basic prescription.
  • Oily component and activator were heated to 80 ° C., stirred and mixed with a disperser, and cooled to room temperature to prepare an oily liquid cleansing composition.
  • the test piece is pressed against the artificial leather on the base with a guide bar with a load of 15 g / cm 2 and is reciprocated 50 times at 0.5 times the speed change mode (6 cm back and forth is about 2 minutes).
  • (12) Remove the test piece and wipe the dirt of the artificial leather on the base with ethanol.
  • (13) 0.2 mL of purified water is dropped on the cleaned artificial leather of the base.
  • the test piece is pressed against the artificial leather of the pedestal with a guide bar with a load of 15 g / cm 2 and is reciprocated 10 times at a speed change mode of 0.5 times speed.
  • (15) Remove the test piece and wash away the dirt remaining on the artificial leather attached to the test piece with distilled water using a washing bottle.
  • R1 [(L * (9) ⁇ L * (2)) 2 + (a * (9) ⁇ a * (2)) 2 + (b * (9) ⁇ b * (2)) 2 ] 1 / 2
  • R2 [(L * (16) ⁇ L * (9)) 2 + (a * (16) ⁇ a * (9)) 2 + (b * (16) ⁇ b * (9)) 2 ] 1 / 2
  • Eyeliner removal rate (R2 / R1) * 100 (%)
  • the removal rate of the eyeliner when using the oily liquid cleansing oil blended with caprylyl (caprylic acid / capric acid) of Example 1 was 36.5%.
  • the eyeliner removal rate was 9.3% to 22.8%, and it was found that the removal effect was 2 to 4 times higher.
  • Example 1 Caprylic acid / Capric acid
  • the removal effect of the mascara manufactured by Company S was the highest.
  • the composition of the comparative example was also inferior to the examples, but had a solvent-type mascara removal effect. From the results of Evaluation Test 1 and Evaluation Test 2 described above, it has been clarified that the composition of the present invention has a strong cleansing power for both water-soluble eyeliner and solvent-type mascara. .
  • Example 1 and Comparative Examples 1 to 16 Usability Evaluation with Wet Hands Evaluation of usability of a cleansing agent was performed to evaluate whether or not it can be used with wet hands.
  • the oily liquid cleansing compositions of Example 1 and Comparative Examples 1 to 16 were weighed in a test tube by 3.5 g, added with 0.105 g of water, and the transparency was visually evaluated. If it is transparent, water is dissolved in the oily liquid cleansing composition, which is an index that can exhibit the cleansing function. As a result, all of Example 1 and Comparative Examples 1 to 16 did not become cloudy, and all were evaluated as having a function usable with wet hands.
  • Example 1 The composition of Example 1 exhibited a high “nob” necessary for cleansing properties.
  • Example 1 was stable at 25 ° C.
  • the composition of Example 1 from Evaluation Tests 3, 4, and 5 has characteristics that can be handled even with wet hands, which is a basic performance necessary for cleansing agents, good "spread", and stability over time. It became clear that.
  • Example 2 An oily liquid cleansing composition of Example 2 was prepared by adding 1,3-butylene glycol diisononanoate (designated name: diisononanoic acid BG) as a diester oil of a monovalent branched fatty acid and a divalent alcohol. Moreover, in order to evaluate the effect of the composition of Example 2, a composition (Comparative Example 17) in which diisononanoic acid BG was substituted with the same amount of cetyl ethylhexanoate was prepared and the effect was evaluated.
  • diisononanoic acid BG 1,3-butylene glycol diisononanoate
  • the volume average emulsion particle size when washing out the oily liquid cleansing composition of Comparative Example 17 is 9.841 ⁇ m, whereas the volume average emulsion particle size when washing out the oily liquid cleansing composition of Example 2 is 1. It was 410 ⁇ m.
  • the composition of Example 2 is remarkably finer than the composition of Comparative Example 17.
  • ⁇ Evaluation Test 8> Solubility Test of Artificial Square Plug The effect of dissolving the square plug of the oily liquid cleansing composition of Example 2 was tested.
  • the test method is as follows. (1) The components shown in Table 8 are mixed at 70 ° C. and then cooled to prepare an artificial horn plug. (2) An artificial square plug is filled in a hole with a diameter of 5 mm ⁇ formed in an acrylic plate, extruded 5 mm with an aluminum stick, and cut with a spatula. About 100 square plugs cut out mg. (3) Adhere the bottom surface (circular surface) of the cylindrical square plug onto the slide glass with instant adhesive. (4) Place the slide glass in the specified position and take a picture using a microscope. (5) Tokyo Rika Kikai Co., Ltd.
  • Multi Shaker MMS and slide glass are connected with a thread so that the slide glass shakes up and down, and the artificial glass plug adhering part of the slide glass is immersed in the oil-based liquid cleansing composition.
  • the artificial horn plug on the slide glass was shaken in the oily liquid cleansing composition for 0 minutes.
  • (7) By image analysis, determine the total value of the height and cylindrical diameter of the artificial horn plug before shaking in (4) and the total value of the height and cylindrical diameter of the artificial horn plug after shaking in (6).
  • the difference after shaking was taken as the amount of decrease in horn plugs. This figure is an indicator of the solubility of horn plugs.
  • the amount of reduction in square plugs was measured three times, and the average value was obtained.
  • composition (refer Table 9) of the comparative examples 18 and 19 which does not contain caprylic caprylic acid or caprylyl capric acid was prepared, and it used as a comparison control.
  • the amount of reduction of the horn plug is shown in FIG.
  • the solubility of horn plugs of Example 2 blended with (caprylic acid / capric acid) caprylyl was 24% compared with Comparative Example 18 not containing (caprylic acid / capric acid) caprylyl, and Comparative Example 19 blended with dicaprylyl carbonate. Compared to 13%. It was confirmed that the oily liquid cleansing composition of Example 2 was superior in the effect of removing pore dirt as compared with the control product. Moreover, when the oily liquid cleansing composition of Example 2 was actually used for skin cleaning and the dirt state of the pores before and after washing was observed with a magnifying glass, it was confirmed that it had an excellent pore dirt removing effect.
  • Example 2 and Comparative Examples 18 and 19 the amount of water transpiration before and after cleansing was measured in the same manner, and the difference (increase value) in the amount of water transpiration was determined.
  • the measurement results are shown in FIG.
  • the difference (increase value) in the amount of water transpiration before and after cleansing of Example 2 and Comparative Example 18 was 0.3 ⁇ g / cm 2
  • the difference (increase value) in the amount of water transpiration before and after cleansing in Comparative Example 19 was 0.95 ⁇ g / cm. 2 . It was confirmed that the oily liquid cleansing composition of Example 2 did not deprive sebum more than necessary. From the above evaluation tests 6 to 9, it was clear that the composition of the present invention was excellent in properties necessary for cleansing, such as washability, solubility of horn plugs, and protection of skin barrier.
  • Formulation Example 1 Ingredient Amount (% by mass) Polyglyceryl heptaisononanoate-20 10 Polyoxyethylene glyceryl triisostearate 15 (Caprylic acid / Capric acid) Caprylyl 4.5 Glyceryl tri-2-ethylhexanoate 28.99 Propylene glycol diisononanoate 30 Cyclohexasiloxane 10 Rice bran oil 1 (Behenic acid / eicosanedioic acid) glyceryl 0.5 Stearyl glycyrrhetinate 0.01
  • Formulation example 2 Ingredient Amount (% by mass) Polyglyceryl-2 caprylate 15 Decaglycerin diisostearate 15 Squalane 10 (Caprylic acid / Capric acid) Caprylyl 10 Di-2-ethylhexanoic acid 1,3-butylene glycol 42.99 Cyclohexasiloxane 5 Meadow foam oil 1 Isostearic acid trehalose esters 0.5 Inulin stearate 0.5 Stearyl glycyrrhetinate 0.01
  • Formulation Example 3 Ingredient Amount (% by mass) Octaisononanoic acid polyglyceryl-20 8 Decaglycerin diisostearate 12 Cetyl 2-ethylhexanoate 55.79 Diisononanoic acid 1,3-butylene glycol 15 Cyclohexasiloxane 7 (Caprylic acid / Capric acid) Caprylyl 2 (Palmitic acid / octanoic acid) dextrin 0.2 Stearyl glycyrrhetinate 0.01
  • Formulation Example 4 Ingredient Amount (% by mass) Polyglyceryl hexacaprylate-20 6 Polyisoethylene stearate polyoxyethylene glyceryl 12 Propylene glycol dicaprylate 40 Cetyl 2-ethylhexanoate 32.69 Methylphenylpolysiloxane 3 (Caprylic acid / Capric acid) Caprylyl 4 Rice bran oil 0.5 Isostearic acid trehalose esters 0.1 Inulin stearate 0.5 (Behenic acid / eicosanedioic acid) Glyceryl 1.2 Stearyl glycyrrhetinate 0.01
  • Formulation Example 5 Ingredient Amount (% by mass) Polyglyceryl caprylate-10 4 Decaglycerin diisostearate 10 Diisononanoic acid 1,3-butylene glycol 40 Cetyl 2-ethylhexanoate 28.29 Olive oil 10 Methylphenyl polysiloxane 1 (Caprylic acid / Capric acid) Caprylyl 5 Rice bran oil 1 Dextrin palmitate 0.2 Inulin stearate 0.5 Stearyl glycyrrhetinate 0.01

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Abstract

L'objet de la présente invention est de fournir un produit de nettoyage qui est efficace dans l'enlèvement des préparations cosmétiques de maquillage pour les yeux de type émulsion/composite de résine d'émulsion, des préparations cosmétiques de maquillage pour les yeux de type solvant à base d'huile et des bouchons keratotiques de la peau. La solution selon l'invention concerne composition de nettoyage liquide à base d'huile préparée par composition de caprylate caprylique et/ou de caprate caprylique avec un agent huileux et un ester d'acide gras de polyglycérine.
PCT/JP2013/075076 2013-01-31 2013-09-18 Composition de nettoyage liquide à base d'huile WO2014119039A1 (fr)

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CN201380060335.6A CN104812362A (zh) 2013-01-31 2013-09-18 油性液状洁肤组合物
HK15110152.6A HK1209352A1 (en) 2013-01-31 2013-09-18 Oil-based liquid cleansing composition

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JP6433165B2 (ja) * 2014-06-10 2018-12-05 太陽化学株式会社 化粧料組成物
CN108324677B (zh) * 2018-05-16 2019-09-10 浙江艳庄化妆品有限公司 一种适用于敏感肌肤人群使用的粉底霜
JP7668625B2 (ja) * 2020-08-20 2025-04-25 太陽化学株式会社 イソステアリン酸ポリグリセリル

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JP2014148476A (ja) 2014-08-21
CN104812362A (zh) 2015-07-29

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