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WO2018156036A1 - Composition d'étanchéité pour pneumatiques - Google Patents

Composition d'étanchéité pour pneumatiques Download PDF

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Publication number
WO2018156036A1
WO2018156036A1 PCT/PL2017/000014 PL2017000014W WO2018156036A1 WO 2018156036 A1 WO2018156036 A1 WO 2018156036A1 PL 2017000014 W PL2017000014 W PL 2017000014W WO 2018156036 A1 WO2018156036 A1 WO 2018156036A1
Authority
WO
WIPO (PCT)
Prior art keywords
sealing composition
sealing
weight
composition according
mixture
Prior art date
Application number
PCT/PL2017/000014
Other languages
English (en)
Inventor
Wieslaw Hreczuch
Darota DOMARECKA
Arkadiusz Chrusciel
Dominik Gschwender
Original Assignee
Aircom Automotive Sp. Z.O.O. Sp. K.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aircom Automotive Sp. Z.O.O. Sp. K. filed Critical Aircom Automotive Sp. Z.O.O. Sp. K.
Priority to PCT/PL2017/000014 priority Critical patent/WO2018156036A1/fr
Publication of WO2018156036A1 publication Critical patent/WO2018156036A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C73/00—Repairing of articles made from plastics or substances in a plastic state, e.g. of articles shaped or produced by using techniques covered by this subclass or subclass B29D
    • B29C73/16—Auto-repairing or self-sealing arrangements or agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds

Definitions

  • the invention relates to a sealing composition for automobile tires, in particular to be applied to the interior surface of a tire by a compressor without the need to remove the pneumatic valve.
  • the primary categories of ingredients of known tire sealing compositions comprise anti-freezing agents including mainly ethylene glycol, propylene glycol or other polyhydric alcohols such as glycerol, polyoxyalkylene glycol, or calcium chloride, fillers such as silica, bentonite, aluminum hydroxide, viscosity modifiers, dispersing agents, surfactants, preservatives , corrosion inhibitors, vegetable oils, crosslinking catalysts, latex, fibers from a group comprising cellulose, glass, carbon and asbestos fibers and many other functional ingredients.
  • anti-freezing agents including mainly ethylene glycol, propylene glycol or other polyhydric alcohols such as glycerol, polyoxyalkylene glycol, or calcium chloride, fillers such as silica, bentonite, aluminum hydroxide, viscosity modifiers, dispersing agents, surfactants, preservatives , corrosion inhibitors, vegetable oils, crosslinking catalysts, latex, fibers from a group comprising cellulose, glass
  • a number of ingredients of known sealing compositions for automobile tires is harmful to health or environment. These include for instance ethylene glycol or carcinogenic asbestos fibers known from applications US4713114A and US4337322A. However safer natural substitutes such as flour and vegetable oils known from US patent application US5059636A, or molasses known from application US7807732A or glycerol known from international patent application PCT/CN2011/080946, or synthetic propylene glycol disclosed in patent application US5364463A have been successfully used in sealing preparations for automobile tires.
  • a frequent functional additive to sealing compositions for tires includes also anti-foaming substances, for instance silicone emulsions disclosed in application US5059636 A.
  • a group of high-performance sealants with valuable performance properties includes liquid sealing compositions based on synthetic or natural latex.
  • compositions for application to the interior surface of the tread of a pneumatic tire to facilitate relative movement between contacting portions of the interior surface when the tire is driven deflated comprise a polybutene, an acrylic polymer or a polyolefin as a gelling agent for the polybutene, and a particulate solid puncture sealing material.
  • Preferred gelling agents are polyethylenes, especially a mixture of high density and low density polyethylenes.
  • suitable puncture sealing materials are rubber crumb and wood flour.
  • Chinese patent application CN103555122 (A) relates to a macromolecuiar self-mending self-sealing hot melting polymeric glue for automobile tires and a preparation method thereof.
  • the self-sealing polymeric glue comprises the following main components in percentage by weight: 30-38% of styrenic thermoplastic elastomer, 40-45% of thermoplastic polymer resin with the relative molecular weight of 200-2000, 5-15% of plasticized softening component, 1-2% of anti-aging antioxidant component, 0-2% of catalyzing promoting component and 0- 8% of filling temperature-resistant component.
  • the macromolecular self- mending self-sealing hot melting polymeric glue provided by the invention is sprayed on the surface of the inner wall of an automobile tire, a uniform coating with the thickness not less than 3.5mm is formed so as to play roles in leak prevention, puncture prevention and bullet prevention, so that the glue can be used for military vehicles.
  • WO2016115560 there is known a high performance sealant for repairing punctures in tires which includes a highly filtered natural rubber Iatex, an ultra-fine inorganic powder, a polyamide suspension, and an antifreeze agent that includes water and at least one of ethylene glycol and propylene glycol.
  • the high performance sealant can readily pass through a valve stem of a tire without removing the core and seal, and provides a strong and durable sealing of the puncture.
  • Indian patent application IN6310DEN2012 (A) relates to an elastomeric composition having a self-sealing property, which is usable, in particular, as an anti- puncture layer in a tire object, and containing at least (a significant percentage of parts by weight percent of a solid elastomer): an unsaturated solid diene elastomer; between 30 and 90 percent of a hydrocarbon resin; 0 to less than 30 percent of a filler; between 0.5 and 15 percent of thiuram polysulfide.
  • elastomer composition having a self-sealing property which can be used in particular as puncture-resistant layer in an inflatable article, based on at least (phr meaning parts by weight per 100 parts of solid elastomer): a blend of at least two solid elastomers, a polybutadiene or butadiene copolymer elastomer, referred to as "elastomer A”, and a natural rubber or synthetic polyisoprene elastomer, referred to as "elastomer B”, the elastomer A: elastomer B ratio by weight being within a range from 10: 90 to 90 : 10 between 30 and 90 phr of a hydrocarbon resin; from 0 to less than 30 phr of filler.
  • Chinese patent application TW201525114 discloses a sealant composition; the sealant composition comprises latex emulsion, nanoporous particles, surfactant, anti-freezing agent, wetting agent, and water.
  • the sealant composition of the present application achieves a good sealing performance for the puncture of the tire.
  • Japanese patent application J P 2014214313 (A) there is known a color sealant composition with self-sealing performance useful for a tire which includes 10 to 60 pts.wt. of surface modified silica, 0.05 to 5 pts. wt. of pigment, 40 to 100 pts.wt. of polybutene having a number average molecular weight of 1000 to 1500, 60 to 300 pts.wt. of polybutene having a number average molecular weight of 2000 to 3000, and 5 to 15 pts.wt. of peroxide, to 100 pts. wt. of raw rubber.
  • US2014138004 (Al) an elastomer composition having a self-sealing property which includes a blend of at least two solid elastomers, in which "elastomer A” is a polybutadiene or butadiene copolymer eiastomer, in which "eiastomer B is a natural rubber or synthetic polyisoprene eiastomer, and in which an elastomer A: elastomer B weight ratio is within a range from 10: 90 to 90 : 10 with phr meaning parts by weight per 100 parts of solid eiastomer; and from 0 to less than 120 phr of filler, which includes from 0 to less than 30 phr of reinforcing filler.
  • the composition may be used to form a puncture-resistant layer in an inflatable article, such as a tire.
  • the puncture-resistant layer may be used in combination with an air
  • the known latex sealing composition includes a surfactant, propylene glycol and natural rubber, synthetic rubber or a mixture of natural and synthetic rubber.
  • the composition is temperature-resistant down to (-) 35 °C and may be used for instance as a sealant for tires.
  • the invention also describes the method of preparing the composition according to the invention. The method comprises the addition of propylene glycol to the surfactant to produce a mixture with propylene glycol and combining polypropylene glycol mixture with a rubber emulsion.
  • a fibrous or a non-fibrous filler, as well as a binder and antioxidant may be added to the polypropylene glycol mixture, before it is mixed with rubber.
  • the excessive coagulability of latex reduces the stability of the sealing composition over time, stiil the maintenance of limited latex coagulability on walls with high surface energy and electrical charge, as is the case for porous surfaces of damaged rubber tires, is desired.
  • the coagulability of latex which is a component of a high-performance sealing composition, is thus the object of optimization.
  • the sealing composition according to the invention was developed based on the analysis of the phenomenon of latex flocculation and coagulation based on the theory of stability of lyophobic dispersions by Derjaguin, Landau, Vervey, and Overbeek (DLVO), taking into account the structure of latex micelle particle comprising a tangled chain of cis 1,4-polyisoprene surrounded with a spherical layer of phospholipid particles with their hydrophobic part turned to the polyisoprene macromolecule.
  • DLVO Derjaguin, Landau, Vervey, and Overbeek
  • the macromolecule is an appropriate polymer of synthetic rubber (e.g. polybutadiene, polychloroprene etc.), stabilized with a synthetic surfactant.
  • synthetic rubber e.g. polybutadiene, polychloroprene etc.
  • the increase of the potential repulsion energy of micelles may be obtained by increasing the thickness of the electrical double layer and zeta potential with the ionic strength of the solution phase kept low (lack of strong electrolytes).
  • the essence of the sealing composition according to the invention is based on the use of amphiphilic copolymer of ethylene oxide, propylene oxide and 2- ethylhexan-l-ol as a surfactant, and its interaction with other ingredients of the said composition which facilitates maximum reduction of the number of ingredients of the sealing composition and at the same time ensures favorable environmental performance and high sealing performance even in extreme temperatures.
  • molecules of this compound demonstrate steric specificity which creates a dimensionally-oriented structure on the interfacial surface of suspended particles of latex emulsion, solid particles and the liquid phase of the sealing composition ingredients and on the inner surface of a tire and its space filled with air, and also on the surface of the puncture thus facilitating the penetration of other components of the sealing composition thus increasing its effectiveness, including the effectiveness of sealing the hole where the tire is punctured.
  • Sterically specific amphiphilic structure of the amphiphilic copolymer used also has impact on keeping the suspension homogenous without its quick breaking, preventing coagulation and cross-linking of ingredients of the sealing composition during its storage.
  • the sterically specific amphiphilic compound, included in the sealing composition according to the invention and acting as a surfactant, constitutes polydispersion mixtures of block copolymers obtained as a result of oxypropylating of 2-ethylhexan-l-ol and the subsequent polyoxyethylenating with 8 to 12 moles of oxirane leading to the production of a mixture of products with polyether properties with the general formula (I): where and j are natural numbers between 0 -20.
  • Analytical research conducted by the authors of this study shows that the product of the reaction in question may also contain up to 30% by weight of diols of general formula (II),
  • a, b and c are natural numbers from 0-30 which also demonstrate partial amphiphilic properties.
  • the described structure of molecules and the ingredients of the mixture of products makes it impossible to define their hydrophilic and lipophilic balance and explains specific characteristics and properties different from other amphiphilic compounds known from prior art.
  • the said properties include for instance the lack of gelling, irrespective of concentration in aqueous solutions, and a significantly higher minimum surface of particles adsorbed at the phase boundary. This indicates a different self-organization of the discussed structures in solvent solutions.
  • the sealing composition for automobile tires according to the invention contains a surfactant, at least one polyhydric alcohol from a group comprising glycerol, ethylene glycol, propylene glycol, natural latex, water and possibly mineral fillers, yet it contains amphiphilic block copolymer which is a po!ydispersion mixture of compounds of general formula (I) and (II), in the amount of 1-5% by weight where compounds of type ⁇ 1 ⁇ are a polydisperston mixture with the content of individual homologues defined by Poisson distribution or other distribution similar to Poisson distribution, with average content of mer units of propylene oxide per 1 mole of 2-ethylhexan-l-ol and variances falling in the range from 1-3, and the average content of mer units of ethylene oxide per 1 mole of 2-ethylhexan-l-ol and variances falling in the range from 8-13.
  • a surfactant at least one polyhydric alcohol from a group comprising glycerol, ethylene glycol, prop
  • the amphophilic copolymer included in the sealing composition is a polydispersion mixture which contains homologues with a different number of oxyalkylene groups, the amount similar to the content defined by Poisson distribution, the expected value and variance v ⁇ 3): where: x clay - mole fraction of an oligomer molecule containing n monomers xo - initial mole fraction of a starter in a reaction mixture v - average degree of oxyethylenating (expected value and variance of distribution) n - number of mers of oxirane in a molecule e - a basis of a natural algorithm in the preferred embodiment, the sealing composition according to the invention may include at least one mineral filler selected from a group comprising bentonite and ground glass.
  • the sealing composition according to the invention is a mobile liquid in temperature range from -30 to +70°C.
  • the sealing composition according to the invention is applied to the interior surface of an automobile tire by a compressor without the need to remove the valve.
  • Fig. 1 shows a schematic structure of !atex micelle, sectional view
  • Fig. 2 presents a family of Poisson distribution curves for concentrations of individual oligomers with six different average degrees of oxyalkilenating
  • Fig. 3 a) is a schematic structure of a monolayer of a surface film of a known conventional linear surfactant; b) is a schematic structure of a monolayer of a surface film with a sterically specific amphophilic copolymer.
  • the micelle with rubber latex shown in fig. 1, is composed of a tangled chain of cis 1,4-polyisoprene surrounded with a spherical layer of phospholipid molecules with their hydrophobic surface turned to the polyisoprene macromolecule; the broken lines indicate an electrical double layer of a latex micelle.
  • the key function of the amphiphilic copolymer used involving the exceptionally effective and quick action of the sealing composition according to the invention also involves a proper foaming of the sealing composition when applied which facilitates even dispersion of ingredients of the composition according to the invention on the interior surface of a tire while using a minimum amount thereof.
  • the exceptionally low stability of the foam produced results in immediate wetting and maximum contact of the sealing agent with the surface it is supposed to act on.
  • the applied sterically specific amphiphilic copolymer also plays a crucial role in the removal of remains of the sealing composition from the interior surface of a tire in the case of its repair/vulcanization and further use.
  • Attempts to use linear surfactants known from prior art as a substitute such as oxyethylated fatty alcohols have failed or the results were moderate in a limited scope of functions played as compared to the sterically specific amphiphilic copolymer used in the sealing composition according to the invention.
  • the negative results obtained involved latex coagulation and a lack of possibility to dose the emulsion to a tire or its excessive stability which did not have the sealing effect.
  • the sealing composition according to the invention is not classified as a dangerous chemical product in the meaning of principles of Regulation no. 1272/2008 of the European Parliament and of the Council (EC), and is chemically neutral which means that is does not for example cause corrosion of an automobile tire or plastic packaging.
  • the composition according to the invention remains liquid enough to facilitate its automatic application in the temperature range from -30°C to +70°C.
  • the composition according to the invention shows high sealing performance.
  • the effectiveness of the composition according to the invention was measured using a method based on sealing a puncture made in an inflated tire by means of a standard steel spike with diameter of up to 6 mm causing a drop of overpressure from 2.5 bar to 0.9 bar/min. due to decompression.
  • the puncture is sealed within up to 10 minutes and remains effective for at least 24 hours and a distance of up to 2000 km and driving speed of up to SO km/h.
  • a mixture of 17% by weight of glycerol, 9% by weight of ethylene glycol, 20% by weight of propylene glycol, 26% by weight of natural latex being a 60% ⁇ by weight) water emulsion, 25% by weight of water was prepared, and then while mixing carefully 3% of the reactive mixture obtained by oxypropylating of 1 mol of 2- ethy[hexan-l-ol with 1 mol of propylene oxide was added and then the product obtained was subject to oxyethylenating with 9 moles of oxirane in the presence of zinc hexacyanocobaltate as a dimethyl cyanide catalyst.
  • the sealing composition according to the invention being a stable suspension of ingredients, was obtained.
  • the obtained sealing composition remained a mobile liquid in the temperature range from -30°C to +70°C. Slight breaking occurred during storage at +S0°C but the composition was easily blended by shaking.
  • the sealing composition according to the invention being a stable suspension of ingredients, was obtained and applied in the amount of 450 ml to an automobile tire size 255/55 R1S by a compressor without the need to remove the AV valve, the process took 80 seconds.
  • the obtained sealing composition remained a mobile liquid in the temperature range from -30°C to +70°C. Slight breaking occurred during storage at 80°C but the composition was easily blended by shaking.
  • a mixture containing 17% by weight of glycerol, 9 % by weight of ethylene glycol, 20 % by weight of propylene glycol, 26 % by weight of natural latex being a 60% (by weight) water emulsion, 25% by weight of water was made, and then while mixing carefully 1% by weight of the product obtained by oxypropylating of 1 mole of 2- ethylhexan-l-ol with 1 mole of propylene oxide was added and then the product obtained was subject to oxyethylenating with 13 moles of oxirane in the presence of calcium catalyst.
  • the sealing composition according to the invention being a stable suspension of ingredients, was obtained and applied in the amount of 450 ml to an automobile tire size 255/55 R18, by a compressor without the need to remove the AV valve, the process took 80 seconds.
  • the obtained sealing composition remained a mobile liquid in the temperature range from -30°C to +70°C. Slight breaking occurred during storage at 80°C but the composition was easily blended by shaking.
  • the puncture was sealed within up to 10 minutes and was effective for at least 24 hours for a distance of up to 2000km and driving speed of up to 80 km/h.
  • a stable suspension of ingredients was obtained and applied in the amount of 450 ml to an automobile tire size 255/55 R18, by a compressor without the need to remove the AV valve, the process took 80 seconds.
  • the obtained sealing composition remained a mobile liquid in the temperature range from -30°C to +70°C. Slight breaking occurred during storage at 80°C but the composition was easily blended by shaking. During road tests, the puncture in the tire made with a standard steel spike with a diameter of 6mm was not effectively sealed.
  • a mixture containing 17% by weight of glycerol, 9 % by weight of ethylene glycol, 20 % by weight of propylene glycol, 26 % by weight of natural latex being a 60% (by weight) water emulsion, 25% by weight of water was made and then while mixing carefully 3% by weight of the product obtained by oxyethylenating of alcohols of fraction C12-14 (coconut fraction) with 22 moles of oxirane in the presence of an alkaline catalyst (NaOH).
  • NaOH alkaline catalyst

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Sealing Material Composition (AREA)

Abstract

Composition d'étanchéité pour pneumatiques automobiles. La composition comprend au moins un alcool polyhydrique issu d'un groupe comprenant du glycérol, de l'éthylène glycol, du propylène glycol, du latex naturel, de l'eau et éventuellement des charges minérales, ainsi qu'un copolymère séquencé amphiphile qui est un mélange par polydispersion de composés de la formule générale (I) et (II), dans la quantité de 1 à 5 % en poids, des composés de type (I) étant un mélange par polydispersion ayant la teneur d'homologues individuels définis par la distribution de Poisson ou une autre distribution similaire à la distribution de Poisson, avec une teneur moyenne en unités mères d'oxyde de propylène pour 1 mole de 2-éthylhexan-l-ol et des variances se situant dans la plage de 1-3 et la teneur moyenne en unités mères d'oxyde d'éthylène pour 1 mole de 2-éthylhexan-l-ol et des variances tombant dans la plage de 8-13.
PCT/PL2017/000014 2017-02-23 2017-02-23 Composition d'étanchéité pour pneumatiques WO2018156036A1 (fr)

Priority Applications (1)

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PCT/PL2017/000014 WO2018156036A1 (fr) 2017-02-23 2017-02-23 Composition d'étanchéité pour pneumatiques

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Application Number Priority Date Filing Date Title
PCT/PL2017/000014 WO2018156036A1 (fr) 2017-02-23 2017-02-23 Composition d'étanchéité pour pneumatiques

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Citations (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1444288A (en) 1921-09-03 1923-02-06 Heinrich H Warmund Sealing fluid for pneumatic tires and the like
US2357650A (en) 1940-04-08 1944-09-05 Blanche R Connolly Puncture sealing composition and manufacture thereof
US4294730A (en) 1976-02-13 1981-10-13 Dunlop Limited Gelled lubricant composition for run-flat tires comprising polybutene acrylic or polyolefin gelling agent and particulate solid puncture sealing material
US4337322A (en) 1981-09-08 1982-06-29 Jaspon Lawrence E Tire filling composition
US4713114A (en) 1985-08-12 1987-12-15 Smith Gerald P Tire sealing and balancing composition
US5059636A (en) 1990-11-13 1991-10-22 Grenga Paul A Tire sealant composition
US5364463A (en) 1992-06-02 1994-11-15 Hull Jack L Tire ballast and sealant
EP1836249A2 (fr) 2004-11-23 2007-09-26 Accessories Marketing, Inc. Matiere de latex a base de propylene glycol
US20090023837A1 (en) * 2007-07-17 2009-01-22 The Yokohama Rubber Co., Ltd. Emulsion coagulant
US20090272476A1 (en) 2008-05-02 2009-11-05 Continental Tire North America, Inc. Sealant material composition, self-sealing pneumatic tire, and preparation thereof
US7807732B2 (en) 2004-04-08 2010-10-05 Fogal Sr Robert D Tire sealant composition
EP2269811A1 (fr) * 2009-06-29 2011-01-05 Sumitomo Rubber Industries, Ltd. Produit d'obturation anti-crevaison
CN102006987A (zh) 2008-02-18 2011-04-06 Tek环球有限公司 轮胎修补密封组合物
US20110165408A1 (en) 2008-06-24 2011-07-07 Societe De Technologie Michelin Self-Sealing Elastomer Composition
CN103555122A (zh) 2013-11-15 2014-02-05 洛阳骏腾能源科技有限公司 一种用于汽车轮胎的高分子自补密封热熔聚合胶
US20140138004A1 (en) 2011-07-29 2014-05-22 Michelin Recherche Et Technique S.A. Self-sealing elastomer composition for a pneumatic object
JP2014214313A (ja) 2013-04-26 2014-11-17 クムホ タイヤ カンパニー インコーポレイテッドＫｕｍｈｏ Ｔｉｒｅｃｏ．，Ｉｎｃ． 自己密封性能を持つタイヤ用カラーシーラント組成物
EP2889352A1 (fr) * 2012-08-21 2015-07-01 Sumitomo Rubber Industries, Ltd. Agent d'obturation de perforation
TW201525114A (zh) 2013-12-19 2015-07-01 Top Alliance Technology Ltd 一種密封膠組合物
IN2012DN06310A (fr) 2010-01-28 2015-09-25 Michelin & Cie
US20160032215A1 (en) 2010-01-28 2016-02-04 Compagnie Generale Des Etablissements Michelin Elastomer Composition for a Tire Object having a Self-Sealing Property
WO2016115560A1 (fr) 2015-01-16 2016-07-21 Illinois Tool Works Inc. Composition d'agent étanchéifiant haute performance pour réparation de pneu

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1444288A (en) 1921-09-03 1923-02-06 Heinrich H Warmund Sealing fluid for pneumatic tires and the like
US2357650A (en) 1940-04-08 1944-09-05 Blanche R Connolly Puncture sealing composition and manufacture thereof
US4294730A (en) 1976-02-13 1981-10-13 Dunlop Limited Gelled lubricant composition for run-flat tires comprising polybutene acrylic or polyolefin gelling agent and particulate solid puncture sealing material
US4337322A (en) 1981-09-08 1982-06-29 Jaspon Lawrence E Tire filling composition
US4713114A (en) 1985-08-12 1987-12-15 Smith Gerald P Tire sealing and balancing composition
US5059636A (en) 1990-11-13 1991-10-22 Grenga Paul A Tire sealant composition
US5364463A (en) 1992-06-02 1994-11-15 Hull Jack L Tire ballast and sealant
US7807732B2 (en) 2004-04-08 2010-10-05 Fogal Sr Robert D Tire sealant composition
EP1836249A2 (fr) 2004-11-23 2007-09-26 Accessories Marketing, Inc. Matiere de latex a base de propylene glycol
US20090023837A1 (en) * 2007-07-17 2009-01-22 The Yokohama Rubber Co., Ltd. Emulsion coagulant
CN102006987A (zh) 2008-02-18 2011-04-06 Tek环球有限公司 轮胎修补密封组合物
US20090272476A1 (en) 2008-05-02 2009-11-05 Continental Tire North America, Inc. Sealant material composition, self-sealing pneumatic tire, and preparation thereof
US20110165408A1 (en) 2008-06-24 2011-07-07 Societe De Technologie Michelin Self-Sealing Elastomer Composition
EP2269811A1 (fr) * 2009-06-29 2011-01-05 Sumitomo Rubber Industries, Ltd. Produit d'obturation anti-crevaison
US20160032215A1 (en) 2010-01-28 2016-02-04 Compagnie Generale Des Etablissements Michelin Elastomer Composition for a Tire Object having a Self-Sealing Property
IN2012DN06310A (fr) 2010-01-28 2015-09-25 Michelin & Cie
US20140138004A1 (en) 2011-07-29 2014-05-22 Michelin Recherche Et Technique S.A. Self-sealing elastomer composition for a pneumatic object
EP2889352A1 (fr) * 2012-08-21 2015-07-01 Sumitomo Rubber Industries, Ltd. Agent d'obturation de perforation
JP2014214313A (ja) 2013-04-26 2014-11-17 クムホ タイヤ カンパニー インコーポレイテッドＫｕｍｈｏ Ｔｉｒｅｃｏ．，Ｉｎｃ． 自己密封性能を持つタイヤ用カラーシーラント組成物
CN103555122A (zh) 2013-11-15 2014-02-05 洛阳骏腾能源科技有限公司 一种用于汽车轮胎的高分子自补密封热熔聚合胶
TW201525114A (zh) 2013-12-19 2015-07-01 Top Alliance Technology Ltd 一種密封膠組合物
WO2016115560A1 (fr) 2015-01-16 2016-07-21 Illinois Tool Works Inc. Composition d'agent étanchéifiant haute performance pour réparation de pneu

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHRUSCIEL, A. ET AL, J. SURFACT. DETERG., 2016
SHAH, D.O., J. COLLOID INTERFACE SCI, vol. 37, 1971, pages 744 - 752
SHIAO, S.Y. ET AL, ADV. COLLOID INTERFACE ,SCI., vol. 74, 1998, pages 1 - 29

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