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WO2018175812A3 - Composite 3d-printed reactors for gas absorption, purification, and reaction - Google Patents

Composite 3d-printed reactors for gas absorption, purification, and reaction Download PDF

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Publication number
WO2018175812A3
WO2018175812A3 PCT/US2018/023889 US2018023889W WO2018175812A3 WO 2018175812 A3 WO2018175812 A3 WO 2018175812A3 US 2018023889 W US2018023889 W US 2018023889W WO 2018175812 A3 WO2018175812 A3 WO 2018175812A3
Authority
WO
WIPO (PCT)
Prior art keywords
composite
purification
reaction
gas absorption
reactors
Prior art date
Application number
PCT/US2018/023889
Other languages
French (fr)
Other versions
WO2018175812A2 (en
Inventor
Du T. Nguyen
Roger D. Aines
Sarah E. Baker
William L. Bourcier
Eric B. Duoss
James S. OAKDALE
Megan M. Smith
William L. Smith
Joshuah K. STOLAROFF
Congwang YE
Original Assignee
Lawrence Livermore National Security, Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lawrence Livermore National Security, Llc filed Critical Lawrence Livermore National Security, Llc
Priority to EP18771559.4A priority Critical patent/EP3600837A4/en
Publication of WO2018175812A2 publication Critical patent/WO2018175812A2/en
Publication of WO2018175812A3 publication Critical patent/WO2018175812A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/20—After-treatment of capsule walls, e.g. hardening
    • B01J13/206—Hardening; drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407—Constructional details of adsorbing systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • B01J13/14—Polymerisation; cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28042—Shaped bodies; Monolithic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2805—Sorbents inside a permeable or porous casing, e.g. inside a container, bag or membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00—Products made by additive manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/202—Alcohols or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20421—Primary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Gas Separation By Absorption (AREA)
  • Mechanical Engineering (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Composite Materials (AREA)

Abstract

A composite material for gas capture, notably CO2 capture and storage. The composite material includes a mixture of a solid or liquid reactive filler and a gas-permeable polymer such that the reactive filler forms micron-scale domains in the polymer matrix.
PCT/US2018/023889 2017-03-24 2018-03-22 Composite 3d-printed reactors for gas absorption, purification, and reaction Ceased WO2018175812A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP18771559.4A EP3600837A4 (en) 2017-03-24 2018-03-22 Composite 3d-printed reactors for gas absorption, purification, and reaction

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/468,297 2017-03-24
US15/468,297 US10300430B2 (en) 2017-03-24 2017-03-24 Composite 3D-printed reactors for gas absorption, purification, and reaction

Publications (2)

Publication Number Publication Date
WO2018175812A2 WO2018175812A2 (en) 2018-09-27
WO2018175812A3 true WO2018175812A3 (en) 2018-12-06

Family

ID=63582069

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2018/023889 Ceased WO2018175812A2 (en) 2017-03-24 2018-03-22 Composite 3d-printed reactors for gas absorption, purification, and reaction

Country Status (3)

Country Link
US (2) US10300430B2 (en)
EP (1) EP3600837A4 (en)
WO (1) WO2018175812A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2715184C1 (en) * 2018-11-30 2020-02-25 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (Институт катализа СО РАН, ИК СО РАН) Method of producing sorbents
CN110591369B (en) * 2019-09-17 2021-04-20 西安交通大学 Polysiloxane precursor for photocuring 3D printing and its preparation and forming method
CN110744061B (en) * 2019-09-30 2022-06-07 中广核工程有限公司 Reactor core filter screen composite manufacturing method and system
US20230271379A1 (en) * 2020-08-06 2023-08-31 Signify Holding B.V. Continuous hollow tube printing using fdm
US12121878B2 (en) 2020-10-21 2024-10-22 Lawrence Livermore National Security, Llc Polymer formulations for extrusion of composite CO2 sorbents
WO2022164442A1 (en) * 2021-01-29 2022-08-04 Hewlett-Packard Development Company, L.P. Removal of volatile organic compounds
US20220372314A1 (en) * 2021-05-21 2022-11-24 ExxonMobil Technology and Engineering Company Additive Manufacturing Techniques And Ink Formulations For Incorporating Adsorbent Particles

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8834605B2 (en) * 2011-02-18 2014-09-16 Lawrence Livermore National Security, Llc. Separation of a target substance from a fluid or mixture using encapsulated sorbents
WO2014153535A2 (en) * 2013-03-22 2014-09-25 Gregory Thomas Mark Three dimensional printing
US20150010461A1 (en) * 2012-02-17 2015-01-08 The University Court Of The University Of Glasgow Apparatus and methods for the preparation of reaction vessels
US20160067891A1 (en) * 2014-09-09 2016-03-10 Lawrence Livermore National Security, Llc System and method for 3d printing of aerogels
WO2016154278A1 (en) * 2015-03-23 2016-09-29 Basf Corporation Carbon dioxide sorbents for indoor air quality control

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US5204055A (en) * 1989-12-08 1993-04-20 Massachusetts Institute Of Technology Three-dimensional printing techniques
US8394350B2 (en) 2009-05-28 2013-03-12 Lawrence Livermore National Security, Llc Catalyst functionalized buffer sorbent pebbles for rapid separation of carbon dioxide from gas mixtures
US8361195B2 (en) 2009-05-28 2013-01-29 Lawrence Livermore National Security, Llc Slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures
US20110244085A1 (en) * 2010-03-31 2011-10-06 Multisorb Technologies Inc. Oxygen, water vapor, and carbon dioxide absorption in a single use container
US9073000B2 (en) * 2012-03-14 2015-07-07 Corning Incorporated Segmented reactors for carbon dioxide capture and methods of capturing carbon dioxide using segmented reactors
US9062586B2 (en) * 2012-04-05 2015-06-23 Corning Incorporated Impermeable polymer coating on selected honeycomb channel surfaces
DE102014222685A1 (en) * 2014-11-06 2016-05-12 Wacker Chemie Ag Process for the preparation of silicone elastomer parts
US9925516B2 (en) * 2014-12-02 2018-03-27 Numat Technologies, Inc. Formation of high surface area metal-organic frameworks

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8834605B2 (en) * 2011-02-18 2014-09-16 Lawrence Livermore National Security, Llc. Separation of a target substance from a fluid or mixture using encapsulated sorbents
US20150010461A1 (en) * 2012-02-17 2015-01-08 The University Court Of The University Of Glasgow Apparatus and methods for the preparation of reaction vessels
WO2014153535A2 (en) * 2013-03-22 2014-09-25 Gregory Thomas Mark Three dimensional printing
US20160067891A1 (en) * 2014-09-09 2016-03-10 Lawrence Livermore National Security, Llc System and method for 3d printing of aerogels
WO2016154278A1 (en) * 2015-03-23 2016-09-29 Basf Corporation Carbon dioxide sorbents for indoor air quality control

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
VERICELLA, JOHN J ET AL.: "Encapsulated liquid sorbents for carbon dioxide c apture", NATURE COMMUNICATIONS, 2015, pages 1 - 7, XP055402834 *

Also Published As

Publication number Publication date
US20190232247A1 (en) 2019-08-01
WO2018175812A2 (en) 2018-09-27
US20180272268A1 (en) 2018-09-27
EP3600837A4 (en) 2021-01-13
US10300430B2 (en) 2019-05-28
EP3600837A2 (en) 2020-02-05
US11148114B2 (en) 2021-10-19

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