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WO2018179452A1 - Produit cosmétique à base de substrat - Google Patents

Produit cosmétique à base de substrat Download PDF

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Publication number
WO2018179452A1
WO2018179452A1 PCT/JP2017/014599 JP2017014599W WO2018179452A1 WO 2018179452 A1 WO2018179452 A1 WO 2018179452A1 JP 2017014599 W JP2017014599 W JP 2017014599W WO 2018179452 A1 WO2018179452 A1 WO 2018179452A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
keratinic material
wet product
substrate
water emulsion
Prior art date
Application number
PCT/JP2017/014599
Other languages
English (en)
Inventor
Gaurav Agarwal
Soumi SARKAR
Manasi SAWANT
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Publication of WO2018179452A1 publication Critical patent/WO2018179452A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the invention relates to a substrate based product, and notably to a substrate based cosmetic products.
  • the invention relates to wet products impregnated with a liquid formulation which comprises solid particles dispersed in it, where dispersed particles are transferred to a keratinic material from the wet product upon wiping.
  • the present invention relates also to a method and process for preparing said wet product and a method and process for caring and/or improving a keratin material by application of said wet product to the surface of said keratin material.
  • the present invention relates more particularly to topical applications, and especially to cosmetic applications.
  • the international patent application WO2002100231 A1 describes a wipe having a substrate and having a film forming polymer and oil absorbing particles coating one side of the substrate.
  • international patent application WO2009074895A1 describes a laminated oil absorbing wipe comprising a non-pigmented thermoplastic nonwoven substrate layer and a pigmented thermoplastic nonwoven substrate layer.
  • US patent application n°2007/0212398 describes a dry wipe prepared by coating a hydrophobic powder on a wet substrate and then by drying it. US patent application n°2007/0212398 also describes a method of removing sand from a skin surface using the wipe.
  • cosmetic products comprising dispersed solid particles are applied on skin only after cleaning the skin. Accordingly, this is a two-step method.
  • the present invention aims to solve the technical problem of providing a product having a dual functionality, for example including cleansing of a keratinic material and/or removing make-up from a keratinic material and providing an additional effect on such keratinic material.
  • the invention aims to solve the technical problem of providing an additional effect on a keratinic material by deposition of solid particles.
  • the present invention also aims to solve the technical problem of adding a sufficient quantity of solid particles to a substrate to provide a benefit to said keratinic material, especially for cosmetic applications.
  • the present invention aims to solve the technical problem of providing a cosmetic formulation comprising solid particles, said formulation being suitable for a good impregnation of a substrate, notably for substrate based cosmetic products, and preferably having a viscosity of less than 2,000 mPa-s.
  • a good impregnation means that the formulation is suitable for impregnating the substrate with the desired amount of solid particles contained in the formulation.
  • the present invention aims to solve the technical problem of providing a single step method for cleansing a keratinic material and/or removing make-up from a keratinic material and providing an additional effect on such keratinic material.
  • the present invention relates to a wet product, preferably a cosmetic product, comprising: a water insoluble substrate and at least one oil-in-water emulsion comprising more than 0.1 %, preferably more than 0.5%, and more preferably more than 1%, by weight of one or more solid particles relative to the total weight of the oil-in-water emulsion.
  • Dry product here means that the substrate does not contain any liquid apart from naturally moisture retained in the substrate.
  • the product is wet.
  • Wet product here means that the substrate contains liquid in addition to naturally moisture retained it. Such additional liquid is typically provided by applying liquid on the substrate.
  • the wet product as described above, wherein said insoluble substrate comprises a fibrous substrate, preferably a fibrous layer, preferably a non- woven fiber substrate.
  • said water insoluble substrate forms a sheet or pile of sheets.
  • Water insoluble is defined herein as a substrate that does not dissolve in or readily break apart upon immersion in water.
  • the solid support comprises at least a fibrous layer. It comprises for example woven fibers, knitted fibers, non-woven fibers, paper, a polymeric film and/or a polymeric mesh.
  • the substrate sheet comprises at least one fibrous layer of non- woven fibers.
  • the substrate is made of a non-woven material.
  • non-woven it is meant, in the sense of this invention, a solid substrate or support including fibers in which the individual fibers or filaments are arranged in a disordered manner in a sheet-like structure and which are neither woven nor knitted.
  • the fibers of the nonwoven body are generally linked to one another, under the effect of a mechanical action (for example, by needle-punching, air jet, water jet, etc.), or under the effect of a. thermal action, or by adding a binder.
  • Such a non-woven material is, for example, defined by standard ISO 9092, as a web or a sheet of fibers oriented directionally or at random, bound by friction and/or cohesion and/or adhesion, excluding paper or products obtained by weaving, knitting, tufting or stitching incorporating threads or bonding filaments.
  • a non-woven material differs from a paper by the length of the fibers used. In paper, the fibers are shorter.
  • nonwoven materials based on cellulose fibers that are produced by wet process and have short fibers as in paper. The difference between a nonwoven material and a paper is generally the absence of a hydrogen bond between the fibers in a nonwoven material.
  • the fibers can be natural fibers, synthetic fibers or mixtures thereof.
  • Non limiting examples of synthetic fibers are Polyester, Polyolefin (Polypropylene, Polyethylene), Polyamide (Nylon 6, Nylon 66), Viscose, Acrylic fibers, Modacrylic fibers, Poly vinylidene chloride and Spandex.
  • Example of natural fiber includes cellulosic fibers (such as wood pulp, cotton, hemp, jute, and flax fibers), silk, and keratin (such as wool and camel hair fibers).
  • the solid support typically has a density of 30 g/m2 to 400 g/m2, preferably 40 g/m2 to 80 g/m2.
  • product according to the invention comprising a cellulosic based substrate.
  • said substrate is a hydrophilic substrate, preferably a cellulosic substrate.
  • said oil-in-water emulsion comprises one or more ingredients selected from the group consisting of cosmetic whitening agents, UV protection agents, skin hydration agents and any mixture thereof.
  • VA 100% Viscose nonwoven with aperture texture
  • a product according to the invention comprising a cellulosic substrate (such as for example Viscose) enhances the delivery of solid particles to the skin resulting in improved whitening or lightening of the skin.
  • a cellulosic substrate such as for example Viscose
  • said solid substrate is in the shape of the desired application area.
  • the solid substrate has to be applied on at least one area of the skin of a user. It can be for example applied on a member of the user such as an arm or a leg, or preferably, the skin on the face of the user.
  • solid substrate is a face mask capable of defining at least one central through opening, intended to receive a nose of the user, and at least two upper through openings for placing in front of the eyes of the user.
  • the solid substrate is a face mask.
  • the solid substrate has a rounded shape, for example a circular or oval shape.
  • the solid substrate has a polygonal shape.
  • said solid substrate comprises at least two through openings intended to be placed facing the eyes of a user, and another through opening intended to be placed facing the mouth of a user.
  • the face mask may also comprise a slit delimiting a flapper intended to be pushed away by the nose of the user, to delimit a nose insertion through opening.
  • the slit delimits a through opening without flapper.
  • the solid substrate is deformable to the touch, to adapt to the conformation of the body surface.
  • a solid substrate adapted to fit the face of a user may have a surface area ranging from 0.25 cm 2 to 500 cm 2 , preferably from 200 cm 2 to 450 cm 2 .
  • the solid substrate typically has a density of 30 g/m 2 to 400 g/m 2 , preferably 30 g/m 2 to 200 g/m 2 and even more preferably 40 g/m 2 to 80 g/m 2 .
  • formulations presenting a good impregnation of the substrate should have a low viscosity, typically lower than 2000 mPa.s.
  • a low viscosity of the formulation it is difficult to keep solid particles homogeneously dispersed in the formulation which should be impregnated on the substrate.
  • the present invention comprises the use of an oil-in-water emulsion having a viscosity sufficient to homogeneously disperse solid particles, said emulsion being diluted prior to impregnation of the substrate to get a good impregnation of the substrate.
  • the present invention relates to an oil-in-water emulsion comprising solid particles, and in particular dispersable powders for cosmetic products.
  • said oil-in-water emulsion is a cream.
  • the oil-in-water emulsion prior to dilution with an aqueous solution has viscosity of more than 2,000 mPa.s.
  • the oil-in-water emulsion prior to dilution with an aqueous solution has viscosity ranging from 50 to 75 UD (Deviation Units).
  • the viscosity measurement is generally performed at 25°C, using a Rheomat RM180 viscometer equipped with a M3 spindle, the measurement being performed after 10 minutes of rotation of the spindle in the composition (after which time stabilization of the viscosity and of the spin speed of the spindle are observed), at a shear rate of 200rpm.
  • 12-22 (M3) UD corresponds to 46-60 (M2) UD which is calculated around 280-15 420 CPS.
  • the oil-in-water emulsion after dilution with an aqueous solution has viscosity of less than 2,000 mPa.s. Accordingly, said oil-in-water emulsion in the wet product has a viscosity of less than 2,000 mPa.s.
  • said oil-in-water emulsion prior to dilution of the oil-in-water emulsion with an aqueous solution, comprises 40 to 90% by weight of water relative to the total weight of said emulsion.
  • said oil-in-water emulsion prior to dilution of the oil-in-water emulsion with an aqueous solution, comprises at least 0.4, preferably from 2 to 15%, more preferably 2 to 13%, and even more preferably 5 to 12%, by weight of solid particles relative to the total weight of the emulsion.
  • said oil-in-water emulsion, and preferably the cream formulation is diluted before, preferably just before, impregnating the substrate.
  • the oil-in-water emulsion may comprise one or more skin care agents.
  • a skin care agent is selected from the group consisting of: humectants, moisturizers, whitening agents, anti-oxidants, cleansing agents, free radical scavengers, skin tone altering agents, anti-acne agents, anti-pimple agents, anti-aging agents, anti- wrinkle agents, anti-inflammatory agents, soothing agents, skin texture treatment agents, anti-perspirant agents, anti-bacterial agents, nourishing agents, sebum and/or moisture absorbers, and any combination thereof.
  • the oil-in-water emulsion according to the invention further comprises at least one physiologically acceptable excipient.
  • the physiologically acceptable excipient is selected from the group consisting of: oils, surfactants, structuring agents, sunscreen filters, preservatives, acidifying and/or alkalizing agents, buffering agents, chelating agents, coloring additives, and any combination thereof.
  • the solid particles according to the invention may or may not be surface-coated, and in particular they may be surface-treated with silicones, amino acids, fluoro derivatives or any other substance that promotes the dispersion and compatibility of the solid particles in the composition.
  • mineral solid particles examples include talc, mica, silica, kaolin, calcium carbonate, magnesium carbonate, hydroxyapatite, glass or ceramic microcapsules.
  • Solid particles used in the compositions according to the present invention may be in lamellar, globular or spherical form, in the form of fibers or in any other intermediate form between these defined forms.
  • said solid particles are selected from the group consisting of mineral or organic, colored or uncolored, pigments, nacreous agents and opacifiers, glitter flakes, active particles, mineral fillers, dyes and any mixture thereof.
  • said solid particles are selected from the group consisting of talc; a metal oxide, for example titanium dioxide, iron oxide; silica and any mixture thereof.
  • said solid particles provide an immediate optical effect because of the deposition on the skin surface.
  • said solid particles are selected from the group consisting of oil absorbing powders, such as for example talc, perlite and any mixture thereof.
  • the wet product comprising oil absorbing powders targets oil control from skin and also gives a mattifying effect by deposition of said particles on skin.
  • the deposition of such particles can also work as an anti-adhesive layer for impurities such as dust, pollutants, etc, generally referred to in the present invention as pollutant or pollutants.
  • the wet composition comprises an oil-in-water emulsion comprising a quantity of solid particles sufficient to give a dual functionality of the wet product, i.e. for cleansing of human skin and/or removal of make-up from human skin together with providing an additional effect on skin.
  • the formulation comprises less than 12.8% by weight of solid particles prior to dilution relative to the total weight of the oil-in-water emulsion.
  • the formulation comprises from 9 to 13% by weight of solid particles prior to dilution relative to the total weight of the oil-in-water emulsion.
  • said oil-in-water emulsion comprises less than 5%, preferably less than 4%, more preferably less than 3%, by weight of one or more solid particles relative to the total weight of the oil-in-water emulsion.
  • the diluted oil-in-water emulsion comprises from 0.1 to 4%, preferably from 0.1 to 3.2%, by weight of one or more solid particles relative to the total weight of the oil-in-water emulsion. In one embodiment, said oil-in-water emulsion comprises at least 40 % by weight of water relative to the total weight of the oil-in-water emulsion.
  • the diluted oil-in-water emulsion comprises from 40 to 95% by weight of water relative to the total weight of the oil-in-water emulsion.
  • the aqueous phase comprises water and any cosmetically acceptable ingredients for formulating the oil-in-water emulsion.
  • the emulsion is prepared according to an O/W emulsion hot process, which is known by the skilled person.
  • the emulsion is typically prepared according to manufacturing processes and methods known by the skilled person.
  • the present invention relates to a wet product comprising a cosmetic formulation and a substrate.
  • the wet product is a cosmetic solid product for cleansing human skin and/or removing make-up from human skin.
  • the substrate based products are wipes, facial mask pads, and other.
  • the invention also relates to a packaging comprising one or more wet products according to the present invention.
  • the wet product according to the present invention enables to deposit a cosmetic formulation, and in particular an oil-in-water emulsion, comprising dispersed solid particles, for example by wiping the surface of a keratinic material.
  • the wet product according to the present invention enables to provide an additional effect on a keratinic material. Accordingly, the wet product according to the invention enhances the functionality of prior art substrates knwon for cleansing skin and/or removing make-up from skin. Advantageously, the wet product according to the present invention provides a new sensorial experience to the user.
  • the wiping action results in the cleansing of the skin surface and/or the removal of make-up from skin surface while during this wiping action, the emulsion is deposited on skin surface or transferred to skin surface, thereby providing a good sensory feel on skin.
  • the wet product according to the present invention avoids deposition of one or more pollutants on skin and/or provides a good repelling of pollutants to avoid their deposition on skin, i.e. is pollutant repellent.
  • the wet product according to the present invention provides an optical effect on the skin surface, typically after wiping the skin surface.
  • the invention also relates to a method for cleansing a keratinic material and/or removing make-up from a keratinic material, said method comprising putting a wet product as defined in the present invention into contact with said keratinic material for cleansing said keratinic material and/or removing make-up from said keratinic material, said method comprising providing an additional effect on said keratinic material, said additional effect being preferably selected from the group consisting of whitening said keratinic material, UV protection of said keratinic material, hydration of said keratinic material, providing a mattifying effect to said keratinic material, depositing on said keratinic material of an anti- adhesive layer avoiding dust and/or pollutants, and any combination thereof.
  • the invention also relates to a method of cosmetic treatment for whitening or lightening a keratinic material, wherein said treatment comprises putting a wet product as defined in the present invention into contact with human skin, for example by wiping said keratinic material, for a time sufficient to provide whitening or lightening of said keratinic material.
  • the invention also relates to a method of cosmetic treatment for protecting a keratinic material from a pollutant, wherein said treatment comprises putting a wet product as defined in the present invention into contact with human skin, for example by wiping said keratinic material, for a time sufficient to protect said keratinic material from a pollutant.
  • the "keratinic material” means in particular skin, and more specifically skin of a human being.
  • the wet product is applied on a skin surface area, for example on the face. In one embodiment, after application of the mixture on the skin, said wet product is wiped on said skin surface area for a certain period of time to deliver sufficient amount of said emulsion and solid particles to skin thereby providing the desired technical effects.
  • the present invention relates to a process for preparing a wet product according to the invention.
  • the invention relates to a method for preparing a wet product as defined in the present invention, said method comprising preparing an oil-in-water emulsion comprising one or more solid particles, diluting said oil-in-water emulsion under continuous, stirring with an aqueous solution to obtain a diluted emulsion, and impregnating a water insoluble substrate by said diluted emulsion to form a wet product as defined in the present invention.
  • the concentration of ingredients in the diluted emulsion will depend on the dilution ratio.
  • the dilution ratio is advantageously selected in a way that the diluted emulsion comprises 0.5 to 4%, more preferably 0.5 to 3%, and even more preferably 1 to 3%, by weight of one or more solid particles relative to the total weight of said emulsion.
  • the oil-in-water emulsion prior to dilution, comprises from 0.4 to 15%, preferably from 2 to 5%, by weight of one or more solid particles relative to the total weight of the oil-in-water emulsion.
  • the invention relates to a method for preparing a wet product as defined in the present invention, said method comprising:
  • the diluted emulsion comprises from 0.1 to 4%, preferably from 0.1 to 3.2%, by weight of one or more solid particles relative to the total weight of the oil- in-water emulsion.
  • said impregnation of the substrate is done under continuous stirring of the diluted emulsion in order to avoid sedimentation of the dispersed particles in the emulsion.
  • said impregnation of the substrate can be done by dipping the substrate in the emulsion or by spraying said emulsion on one or more substrate surfaces, either on a part of the surface or on the totality thereof.
  • the wet product according to the invention comprises a weight ratio of said emulsion relative to the substrate ranging from 2 to 6, more preferably from 2.5 to 4, and even more preferably from 3 to 4 (w/w).
  • the emulsion prior to dilution forms a substantially homogeneous composition.
  • the diluted emulsion forms a substantially homogeneous composition upon stirring and preferably during a period of time sufficient to prepare a substrate impregnated with said diluted emulsion.
  • homogeneous composition it is meant that at least the solid particles are homogeneously dispersed.
  • Figure 1 is a bar graphic showing skin hydration increase expressed in % relative to skin hydration prior to application of different wet products according to the invention.
  • Figure 2 is a bar graphic showing skin lightness increase expressed in % relative to skin hydration prior to application of different wet products according to the invention.
  • Figure 3 is a bar graphic showing repletion to pollutant (anti-adhesive properties).
  • Example 1 An oil-in-water emulsion is prepared according to procedures known in the art.
  • the oil-in-water emulsion (o/w emulsion) comprises 2.9 % by weight of titanium dioxide and 4 % by weight of talc.
  • the said o/w emulsion has been diluted by adding water in 1 :3 ratio (o/w emulsion/added water; weight/weight) and under continuous stirring.
  • the original o/w emulsion and the resulting diluted emulsion are as follows (Table 1):
  • the diluted composition given in Table 1 was applied on various nonwoven substrates varying in their composition.
  • the impregnation level was 1 :3 (w/w of substrate weight/liquid formula weight). Skin lightening effect on skin after wiping skin with the wet product was better if a cellulosic substrate based product was used. Skin hydration was better after wiping skin with the wet product if a synthetic substrate based product was used.
  • PV is 65-35% Polyester-Viscose Blend
  • V 100%Viscose
  • Figure 3 shows the results obtained with the cleansing wipe without powders (column in the middle), with a wet product according to the invention (right column), and for untreated skin (left column). The results are expressed in values relative to untreated skin, i.e. skin prior to cleansing (value of about 1).
  • wet products according to the invention are good repellents of pollutants and do not allow pollutants to deposit on skin.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dermatology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un produit humide, de préférence un produit cosmétique, comprenant : un substrat insoluble dans l'eau et au moins une émulsion huile-dans-l'eau comprenant plus de 0,1 %, de préférence plus de 0,5 %, et de façon davantage préférée plus de 1 %, en poids d'une ou plusieurs particules solides par rapport au poids total de l'émulsion huile-dans-l'eau. L'invention concerne également un procédé de préparation d'un tel produit humide et ses applications.
PCT/JP2017/014599 2017-03-30 2017-03-31 Produit cosmétique à base de substrat WO2018179452A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017014598 2017-03-30
JPPCT/JP2017/014598 2017-03-30

Publications (1)

Publication Number Publication Date
WO2018179452A1 true WO2018179452A1 (fr) 2018-10-04

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PCT/JP2017/014599 WO2018179452A1 (fr) 2017-03-30 2017-03-31 Produit cosmétique à base de substrat

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022090910A1 (fr) 2020-10-26 2022-05-05 Jacob Holm & Sons Ag Textile de distribution de cbd sec

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002100231A1 (fr) 2001-06-07 2002-12-19 3M Innovative Properties Company Lingettes enduites servant a absorber le sebum
US20030073689A1 (en) * 2001-09-28 2003-04-17 L'oreal Ultrafine emulsion containing a haloalkynyl derivative
US20070212398A1 (en) 2005-01-21 2007-09-13 Tiffany Aceto Powdered wipe
US20080102050A1 (en) * 2006-10-26 2008-05-01 Mingxla Li Water-based skin care composition with polyalkylsilsesquioxane powder emulsion and method for making the same
WO2009074895A1 (fr) 2007-12-13 2009-06-18 Kimberly-Clark Worldwide, Inc. Lingette cosmétique qui donne une indication visuelle de son efficacité
US7592019B2 (en) 2000-11-30 2009-09-22 Beiersdorf Ag Cosmetic or dermatological impregnated wipes
WO2013076673A1 (fr) * 2011-11-25 2013-05-30 L'oreal Composition de type émulsion stabilisée par des particules basée sur des particules de silice hydrophobes
WO2014174007A2 (fr) * 2013-04-26 2014-10-30 L'oreal Procédé de nettoyage de matières kératiniques
WO2016173870A1 (fr) * 2015-04-28 2016-11-03 Basf Se Émulsions huile-dans-l'eau à faible viscosité pour applications cosmétiques

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7592019B2 (en) 2000-11-30 2009-09-22 Beiersdorf Ag Cosmetic or dermatological impregnated wipes
WO2002100231A1 (fr) 2001-06-07 2002-12-19 3M Innovative Properties Company Lingettes enduites servant a absorber le sebum
US20030073689A1 (en) * 2001-09-28 2003-04-17 L'oreal Ultrafine emulsion containing a haloalkynyl derivative
US20070212398A1 (en) 2005-01-21 2007-09-13 Tiffany Aceto Powdered wipe
US20080102050A1 (en) * 2006-10-26 2008-05-01 Mingxla Li Water-based skin care composition with polyalkylsilsesquioxane powder emulsion and method for making the same
WO2009074895A1 (fr) 2007-12-13 2009-06-18 Kimberly-Clark Worldwide, Inc. Lingette cosmétique qui donne une indication visuelle de son efficacité
WO2013076673A1 (fr) * 2011-11-25 2013-05-30 L'oreal Composition de type émulsion stabilisée par des particules basée sur des particules de silice hydrophobes
WO2014174007A2 (fr) * 2013-04-26 2014-10-30 L'oreal Procédé de nettoyage de matières kératiniques
WO2016173870A1 (fr) * 2015-04-28 2016-11-03 Basf Se Émulsions huile-dans-l'eau à faible viscosité pour applications cosmétiques

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022090910A1 (fr) 2020-10-26 2022-05-05 Jacob Holm & Sons Ag Textile de distribution de cbd sec

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