WO2018184051A1 - Matériau non tissé conçu pour être utilisé dans des structures de cœurs absorbants ayant des capacités d'acquisition/distribution intrinsèques - Google Patents
Matériau non tissé conçu pour être utilisé dans des structures de cœurs absorbants ayant des capacités d'acquisition/distribution intrinsèques Download PDFInfo
- Publication number
- WO2018184051A1 WO2018184051A1 PCT/AT2017/000032 AT2017000032W WO2018184051A1 WO 2018184051 A1 WO2018184051 A1 WO 2018184051A1 AT 2017000032 W AT2017000032 W AT 2017000032W WO 2018184051 A1 WO2018184051 A1 WO 2018184051A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- absorbent core
- core structure
- filaments
- nonwoven
- superabsorbent polymer
- Prior art date
Links
- 230000002745 absorbent Effects 0.000 title claims abstract description 79
- 239000002250 absorbent Substances 0.000 title claims abstract description 79
- 239000000463 material Substances 0.000 title claims abstract description 26
- 238000009826 distribution Methods 0.000 title abstract description 40
- 229920000247 superabsorbent polymer Polymers 0.000 claims abstract description 50
- 229920002678 cellulose Polymers 0.000 claims abstract description 27
- 239000001913 cellulose Substances 0.000 claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 claims abstract description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- 239000002131 composite material Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 35
- 230000008569 process Effects 0.000 claims description 31
- 229920000433 Lyocell Polymers 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- 230000014759 maintenance of location Effects 0.000 abstract description 5
- 239000011162 core material Substances 0.000 description 85
- 239000000047 product Substances 0.000 description 65
- 239000000843 powder Substances 0.000 description 33
- 230000015271 coagulation Effects 0.000 description 18
- 238000005345 coagulation Methods 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000011282 treatment Methods 0.000 description 12
- 239000000853 adhesive Substances 0.000 description 11
- 230000001070 adhesive effect Effects 0.000 description 11
- 239000012530 fluid Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 238000009987 spinning Methods 0.000 description 9
- 238000013461 design Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000005056 compaction Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 5
- 239000004416 thermosoftening plastic Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 239000012943 hotmelt Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 206010021639 Incontinence Diseases 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 230000002860 competitive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000004583 superabsorbent polymers (SAPs) Substances 0.000 description 3
- 239000004831 Hot glue Substances 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- UPWPBIUUSLIWAI-UHFFFAOYSA-N [4-(4-aminophenyl)sulfonylphenyl]urea Chemical compound C1=CC(NC(=O)N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 UPWPBIUUSLIWAI-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229960001506 brilliant green Drugs 0.000 description 1
- HXCILVUBKWANLN-UHFFFAOYSA-N brilliant green cation Chemical compound C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 HXCILVUBKWANLN-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- GMBYRECIACINKD-GFAZQMFJSA-N dallergy Chemical group CNC[C@H](O)C1=CC=CC(O)=C1.C=1C=CC=NC=1C(CCN(C)C)C1=CC=C(Cl)C=C1.C1([C@@H](CO)C(=O)OC2C[C@@H]3[N+]([C@H](C2)C2C3O2)(C)C)=CC=CC=C1 GMBYRECIACINKD-GFAZQMFJSA-N 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
- D04H1/4258—Regenerated cellulose series
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
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- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
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- B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
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- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
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- B32B7/09—Interconnection of layers by mechanical means by stitching, needling or sewing
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- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/013—Regenerated cellulose series
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- B32B2555/00—Personal care
- B32B2555/02—Diapers or napkins
Definitions
- This invention relates to a thin, flexible absorbent core structure with intrinsic acquisition and distribution capabilities, and, more particularly, to an absorbent core composed of an essentially pure cellulose nonwoven web formed from essentially continuous filaments and multibonded by merged filaments, hydrogen bonding and physical intermingling of filaments, combined with superabsorbent polymers.
- This absorbent core is distinguished by its lack of fluff pulp as a component.
- This absorbent core is thin, flexible, absorbent with excellent liquid retention; the nonwoven web used is capable of acquiring and distributing the liquid to the absorbent polymer, as well as holding the absorbent polymer in position both dry and wet; used in a hygiene or personal care product, for example a baby diaper or feminine hygiene pad, this absorbent core reduces product weight, thickness, and shipping costs.
- essentially pure cellulose shall address the fact that cellulosic moulded bodies, e.g. made according to the lyocell process, always contain a small amount of polymers other than cellulose, namely hemicellulose. This does not influence in any way the suitability for the use according to this invention.
- U.S. 8,260,533 teaches the use of thermoplastic adhesives, printed onto a nonwoven in a desired pattern, and adhering the superabsorbent polymer onto this pattern of adhesive.
- This pattern places the superabsorbent polymer powder in desired locations and keeps the powder separated so that liquid can reach most of the powder. Additionally, both when dry or wet and swollen, the powder is held in place.
- This core usually requires a separate special pulp containing acquisition/distribution layer.
- WO 2012/052172 teaches the use ultrasonic bonding of two layers of nonwovens, forming pockets for the superabsorbent polymer powder to reside. These pockets hold the superabsorbent polymer powder, both when dry and when wet and swollen. These pockets allow enough space for the superabsorbent polymer powder to absorb and swell freely. This core usually requires a through air bonded nonwoven acquisition/distribution layer.
- U.S. 2014/291987 teaches the use of a nonwoven layer with pre-formed pockets, into which the superabsorbent polymer powder is dispensed, then covered with a standard nonwoven sheet; adhesives are used to bond the cover nonwoven to the pre-formed nonwoven.
- Blends of fluff pulp with superabsorbent polymer powder as described in U.S. 5,147,343 and U.S. 5,599,335, are low cost and absorbent, but do not contain the superabsorbent polymer powder, either dry or wet, and do not easily place the superabsorbent polymer powder in desired locations, are not thin nor lightweight, and do require a separate acquisition/distribution layer.
- ultrasonic bonding of such structures is a complex process, is slow and requires select nonwovens able to be ultrasonically bonded.
- Most polymers able to be ultrasonically bonded are thermoplastic and synthetic. These can interfere with absorbency of liquids.
- absorbent products such as those used in baby diapers, feminine hygiene pads and adult incontinence products, are usually composed of a liquid permeable topsheet, an acquisition/distribution layer, an absorbent core (including a sheet material as a "core wrap") and a liquid impermeable backsheet.
- Most current absorbent cores where high absorbency is needed, are composed of fluff pulp and superabsorbent polymer.
- Superabsorbent polymer absorbs and holds many times its own weight in liquid, but it is slower to absorb this liquid than, for example, fluff pulp.
- Fluff pulp absorbs less fluid, but does so rapidly; unfortunately, fluff pulp releases fluids easily, especially under pressure, weight or load. Additionally, when superabsorbent absorbs liquids, it swells and forms a gel. If
- superabsorbent polymer is used in high concentrations, it forms a mass of swollen particles, which can restrict movement of liquid to unused
- An acquisition/distribution layer has a top surface with a function to rapidly acquire or absorb liquids and rapidly move them from the surface to the distribution layer.
- the distribution layer's purpose is to move liquid both to the absorbent core as well as in the x-y direction along the surface of the absorbent core. This maximizes usage of the absorbent surface area.
- the entire fluff/superabsorbent polymer mixture is wrapped in a sheet material, either tissue or nonwoven.
- Tissue has very low strength especially when wet, but is low cost.
- Nonwovens have higher wet strength, but are more costly.
- the hygiene or personal care article be as thin and lightweight as possible, while still meeting performance requirements. Additionally, it is desired that such a product be low cost and without excessive complicated process issues.
- This material is designed to be a sustainable and cost effective nonwoven with good absorbency. It is clear that an essentially pure cellulosic material has better absorbent capacity and superior liquid management properties (liquid uptake, good spreadability and good wicking) than synthetic polymers such as polypropylene and polyester, which are typically used for the majority of hygiene components.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Vascular Medicine (AREA)
- Heart & Thoracic Surgery (AREA)
- Biomedical Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Nonwoven Fabrics (AREA)
Abstract
La présente invention concerne une structure de cœur absorbant comprenant : (a) une nappe de non-tissé en cellulose essentiellement pure formée à partir de filaments essentiellement continus et multiliés par des filaments fusionnés, des liaisons hydrogène et/ou un enchevêtrement physique de filaments, et (b) combinée à un polymère superabsorbant, pour une utilisation dans des produits d'hygiène. Le produit est mince, léger et flexible et a une résistance mécanique à l'état humide et sec élevée, une excellente capacité d'absorption et de rétention, et maintient le polymère superabsorbant à l'emplacement pour lequel il a éé conçu, qu'il soit sec et/ou humide et gonflé. L'invention concerne en outre l'utilisation de ladite structure de cœur absorbant pour la fabrication d'un produit d'hygiène. Un produit d'hygiène caractérisé en ce qu'il contient la structure de cœur absorbant selon l'invention, l'utilisation de ladite structure de cœur combinée à un autre matériau non tissé pour obtenir un composite non tissé pour des applications d'hygiène et l'utilisation de ladite structure de cœur absorbant pour introduire des fonctions de couche d'acquisition/distribution, d'enveloppe de cœur et de cœur absorbant dans un seul et même produit et/ou structure d'hygiène sont en outre décrits.
Priority Applications (1)
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PCT/AT2017/000032 WO2018184051A1 (fr) | 2017-04-03 | 2017-04-03 | Matériau non tissé conçu pour être utilisé dans des structures de cœurs absorbants ayant des capacités d'acquisition/distribution intrinsèques |
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PCT/AT2017/000032 WO2018184051A1 (fr) | 2017-04-03 | 2017-04-03 | Matériau non tissé conçu pour être utilisé dans des structures de cœurs absorbants ayant des capacités d'acquisition/distribution intrinsèques |
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WO2012052172A1 (fr) | 2010-10-20 | 2012-04-26 | Vynka Bvba | Structure absorbante respectueuse de l'environnement |
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WO2013153235A1 (fr) | 2012-04-13 | 2013-10-17 | Libeltex | Structures absorbantes unitaires comprenant un noyau absorbant et/ou une couche d'acquisition et de dispersion pour articles absorbants |
WO2014001487A1 (fr) | 2012-06-29 | 2014-01-03 | Concepts For Success (C4S) E.K. | Structure absorbante collée par fusion à chaud comprenant des fibres et des particules superabsorbantes et procédé de fabrication d'une telle structure |
WO2014009506A1 (fr) | 2012-07-13 | 2014-01-16 | Glatfelter Falkenhagen Gmbh | Bande intercalaire absorbante douce comprenant des concentrations élevées de matériau superabsorbant, des fibres cellulosiques et un liant appliqué en surface |
US20140163506A1 (en) * | 2012-12-10 | 2014-06-12 | The Procter & Gamble Company | Absorbent Articles with Channels and/or Pockets |
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