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WO2018196032A1 - Toilet-flush detergent and preparation method therefor - Google Patents

Toilet-flush detergent and preparation method therefor Download PDF

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Publication number
WO2018196032A1
WO2018196032A1 PCT/CN2017/083429 CN2017083429W WO2018196032A1 WO 2018196032 A1 WO2018196032 A1 WO 2018196032A1 CN 2017083429 W CN2017083429 W CN 2017083429W WO 2018196032 A1 WO2018196032 A1 WO 2018196032A1
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WO
WIPO (PCT)
Prior art keywords
parts
paste
detergent
toilet
stirring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2017/083429
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French (fr)
Chinese (zh)
Inventor
龚彩萍
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Individual
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Individual
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009—Sulfides
    • C08K2003/3036—Sulfides of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Definitions

  • the invention relates to a cleaning agent, in particular to a cleaning agent for a toilet bowl and a preparation method thereof.
  • the toilet After using the toilet every time, if only the tap water is used to flush the toilet, not only can the bacteria in the toilet be cleaned, but also the toilet taste is difficult to eliminate.
  • the toilet cleaner When using the toilet cleaner, the toilet can be kept bright and clean, and the odor can be quickly removed.
  • the conventional toilet cleaning agent has poor durability, bactericidal effect is not obvious, and the effective substances in the storage process are easily decomposed, and the conventional cleaning agent for the toilet generally contains the finished phosphorus product, which causes certain pollution to the natural environment.
  • a detergent for a toilet bowl comprising 5-7 parts by weight of water, 4-6 parts of sodium petroleum sulfonate, 26-30 parts of sodium dodecylbenzenesulfonate, and a blue dye. 6-10 parts, 11-13 parts of sustained release excipient, 0.9-1.5 parts of inorganic nano antibacterial powder, 35-40 parts of imidazoline, and 1.5-3.5 parts of trimethylolpropane.
  • the sustained release excipient is a mixture of xanthan gum and stearic acid.
  • the inorganic nano antibacterial powder is a commercially available transparent paste composed of a zinc salt, nano titanium dioxide, and silicon oxide.
  • the scent of the modified nano-fragrance may be a spice such as pine, pine, grass or the like.
  • the invention also provides a preparation method of the above-mentioned toilet cleaner, comprising the following steps:
  • Step 1 Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat.
  • the blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added in the hot state, and the heating temperature in the kneader is maintained at 40. -80 ° C, stirring and kneading time is 0.5-1 h, and then naturally cooled to prepare a paste-like preform cleaning paste;
  • Step 2 Add nano-fragrance, original name powder in a kneading machine containing a paste-like pre-form cleaning paste, Stirring was continued for 30 min until the paste was uniform and then processed into a finished product.
  • the cleaning agent for toilets of the invention releases effective substances in water, and achieves the effects of deodorization, scale inhibition and bacteriostasis during flushing.
  • This product is a phosphorus-free formula and does not cause secondary pollution to the environment.
  • Detergent cleaner including 5 parts by weight of water, 4 parts of sodium petroleum sulfonate, 26 parts of sodium dodecylbenzene sulfonate, 6 parts of blue dye, 11 parts of slow release excipient, inorganic nano antibacterial powder 0.9 Parts, 35 parts of imidazoline and 1.5 parts of trimethylolpropane.
  • the sustained release excipient is a mixture of xanthan gum and stearic acid;
  • the inorganic nano antibacterial powder is a commercially available transparent paste composed of zinc salt, nano titanium dioxide and silicon oxide;
  • the fragrance of the modified nano essence The type may be a spice such as pine, pine, grass or the like.
  • the preparation method of the cleaning agent for toilets of the present invention comprises the following steps:
  • Step 1 Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat.
  • the blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added while maintaining the heating temperature in the kneader at 70. °C, stirring and kneading time is 0.5h, and then naturally cooled to form a paste-like preform cleaning paste;
  • Step 2 Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.
  • the toilet cleaning agent is put into the toilet tank, avoid blocking the water outlet.
  • the toilet cleaner is partially dissolved in the water tank. Press the pump button after each use of the toilet.
  • the surface of the flushed toilet bowl is clean and free of stains. ,odorless.
  • Detergent cleaner 6 parts by weight of water, 4 parts of sodium petroleum sulfonate, 30 parts of sodium dodecyl benzene sulfonate, 8 parts of blue dye, 12 parts of slow release excipient, inorganic nano antibacterial powder 1 Parts, 38 parts of imidazoline and 2 parts of trimethylolpropane.
  • the sustained release excipient is a mixture of xanthan gum and stearic acid;
  • the inorganic nano antibacterial powder is a commercially available transparent paste composed of zinc salt, nano titanium dioxide and silicon oxide;
  • the fragrance of the modified nano essence The type may be a spice such as pine, pine, grass or the like.
  • the preparation method of the cleaning agent for toilets of the present invention comprises the following steps:
  • Step 1 Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading with stirring heating device.
  • sodium dodecylbenzene sulfonate is added.
  • a chemical reaction occurs in the kneader and generates heat.
  • the blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added while maintaining the kneading.
  • the heating temperature in the machine is 40 ° C
  • the stirring and kneading time is 1 h, and then naturally cooled to prepare a paste pre-form cleaning paste;
  • Step 2 Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.
  • the toilet cleaning agent is put into the toilet tank, avoid blocking the water outlet.
  • the toilet cleaner is partially dissolved in the water tank. Press the pump button after each use of the toilet.
  • the surface of the flushed toilet bowl is clean and free of stains. ,odorless.
  • Detergent cleaner 7 parts by weight of water, 4 parts of sodium petroleum sulfonate, 27 parts of sodium dodecyl benzene sulfonate, 8 parts of blue dye, 13 parts of slow release excipient, inorganic nano antibacterial powder 1.2 Parts, 38 parts of imidazoline and 3 parts of trimethylolpropane.
  • the sustained release excipient is a mixture of xanthan gum and stearic acid;
  • the inorganic nano antibacterial powder is a commercially available transparent paste composed of zinc salt, nano titanium dioxide and silicon oxide;
  • the fragrance of the modified nano essence The type may be a spice such as pine, pine, grass or the like.
  • the preparation method of the cleaning agent for toilets of the present invention comprises the following steps:
  • Step 1 Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat.
  • the blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added while maintaining the heating temperature in the kneader at 70. °C, stirring and kneading time is 1h, then naturally cooled to make a paste-like preform cleaning paste;
  • Step 2 Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.
  • the toilet cleaning agent is put into the toilet tank, avoid blocking the water outlet.
  • the toilet cleaner is partially dissolved in the water tank. Press the pump button after each use of the toilet.
  • the surface of the flushed toilet bowl is clean and free of stains. ,odorless.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)

Abstract

A toilet-flush detergent and a preparation method therefor. The toilet-flush detergent comprises in parts by weight: 5-7 parts of water, 4-6 parts of petroleum sodium sulfonate, 26-30 parts of sodium dodecyl benzene sulfonate, 6-10 parts of a blue dye, 11-13 parts of a sustained release excipient, 0.9-1.5 parts of an inorganic nanoscale antibacterial powder, 35-40 parts of imidazoline, and 1.5-3.5 parts of trimethylolpropane. The described detergent releases active substances in water, achieving effects of deodorization, scale inhibition and bacteriostasis during flushing, and is free of phosphorus and does not cause secondary pollution to the environment.

Description

一种抽水马桶用清洁剂及其制备方法Cleaning agent for toilet bowl and preparation method thereof 技术领域Technical field

本发明涉及清洁剂，尤其涉及一种抽水马桶用清洁剂及其制备方法。The invention relates to a cleaning agent, in particular to a cleaning agent for a toilet bowl and a preparation method thereof.

背景技术Background technique

在每次使用马桶后，若只用自来水冲马桶，不仅无法清理马桶内各种细菌，而且厕所味道难以消除，在冲马桶时使用抽水马桶用清洁剂，可令马桶保持光亮洁净，迅速去除异味。After using the toilet every time, if only the tap water is used to flush the toilet, not only can the bacteria in the toilet be cleaned, but also the toilet taste is difficult to eliminate. When using the toilet cleaner, the toilet can be kept bright and clean, and the odor can be quickly removed.

然而传统的抽水马桶用清洁剂持久力差、杀菌效果不明显、储藏过程中有效物质易分解等缺点也较为突出，并且传统的抽水马桶用清洁剂一般含有磷成品，会对自然环境造成一定污染。However, the conventional toilet cleaning agent has poor durability, bactericidal effect is not obvious, and the effective substances in the storage process are easily decomposed, and the conventional cleaning agent for the toilet generally contains the finished phosphorus product, which causes certain pollution to the natural environment.

发明内容Summary of the invention

本发明的目的提供一种抽水马桶用清洁剂及其制备方法，解决上述现有技术问题中的一个或者多个。It is an object of the present invention to provide a toilet bowl cleaning agent and a method of preparing the same that solves one or more of the above prior art problems.

根据本发明的一个方面，提供一种抽水马桶用清洁剂，按重量份包括水5-7份、石油磺酸钠4-6份、十二烷基苯磺酸钠26-30份、蓝色染料6-10份、缓释赋形剂11-13份、无机纳米抗菌粉0.9-1.5份、咪唑啉35-40份、三羟甲基丙烷1.5-3.5份。According to an aspect of the present invention, there is provided a detergent for a toilet bowl comprising 5-7 parts by weight of water, 4-6 parts of sodium petroleum sulfonate, 26-30 parts of sodium dodecylbenzenesulfonate, and a blue dye. 6-10 parts, 11-13 parts of sustained release excipient, 0.9-1.5 parts of inorganic nano antibacterial powder, 35-40 parts of imidazoline, and 1.5-3.5 parts of trimethylolpropane.

在一些实施方式中：缓释赋形剂为黄原胶与硬脂酸的混合物。In some embodiments: the sustained release excipient is a mixture of xanthan gum and stearic acid.

在一些实施方式中：无机纳米抗菌粉为市售的且由锌盐、纳米二氧化钛与氧化硅构成的透明膏状物。In some embodiments: the inorganic nano antibacterial powder is a commercially available transparent paste composed of a zinc salt, nano titanium dioxide, and silicon oxide.

在一些实施方式中：改性的纳米香精的香型可以是松木、松杉、青草等香料。In some embodiments, the scent of the modified nano-fragrance may be a spice such as pine, pine, grass or the like.

本发明还提供了上述的一种抽水马桶用清洁剂的制备方法，包括以下步骤：The invention also provides a preparation method of the above-mentioned toilet cleaner, comprising the following steps:

步骤一：准确称取自来水，放入不锈钢桶中，边缓慢搅拌边加入石油磺酸钠，待石油磺酸钠固体溶解后，再缓慢倒入具有搅拌加热装置的捏合机中，在缓慢搅拌下，加入十二烷基苯磺酸钠，此时捏合机内产生化学反应并产生热量，趁热依次加入蓝色染料、稀释赋形剂、无机纳米抗菌粉，保持捏合机内的加热温度在40-80℃，搅拌捏合时间为0.5-1h，之后自然冷却，制成膏状预制体清洁膏；Step 1: Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat. The blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added in the hot state, and the heating temperature in the kneader is maintained at 40. -80 ° C, stirring and kneading time is 0.5-1 h, and then naturally cooled to prepare a paste-like preform cleaning paste;

步骤二：在盛有膏状预制体清洁膏的捏合机中加入纳米香精、原名粉， 持续搅拌30min，直至膏体均匀，随后加工成型成成品。Step 2: Add nano-fragrance, original name powder in a kneading machine containing a paste-like pre-form cleaning paste, Stirring was continued for 30 min until the paste was uniform and then processed into a finished product.

本发明的抽水马桶用清洁剂在水中释放有效物质，在冲厕时达到去味、抑垢、抑菌的效果，本品为无磷配方，不会对环境造成二次污染。The cleaning agent for toilets of the invention releases effective substances in water, and achieves the effects of deodorization, scale inhibition and bacteriostasis during flushing. This product is a phosphorus-free formula and does not cause secondary pollution to the environment.

具体实施方式detailed description

下面通过实施例对本发明作进一步详细说明。The invention will now be further described in detail by way of examples.

实施例1：Example 1:

抽水马桶用清洁剂，按重量份包括水5份、石油磺酸钠4份、十二烷基苯磺酸钠26份、蓝色染料6份、缓释赋形剂11份、无机纳米抗菌粉0.9份、咪唑啉35份、三羟甲基丙烷1.5份。Detergent cleaner, including 5 parts by weight of water, 4 parts of sodium petroleum sulfonate, 26 parts of sodium dodecylbenzene sulfonate, 6 parts of blue dye, 11 parts of slow release excipient, inorganic nano antibacterial powder 0.9 Parts, 35 parts of imidazoline and 1.5 parts of trimethylolpropane.

其中，缓释赋形剂为黄原胶与硬脂酸的混合物；无机纳米抗菌粉为市售的且由锌盐、纳米二氧化钛与氧化硅构成的透明膏状物；改性的纳米香精的香型可以是松木、松杉、青草等香料。Wherein, the sustained release excipient is a mixture of xanthan gum and stearic acid; the inorganic nano antibacterial powder is a commercially available transparent paste composed of zinc salt, nano titanium dioxide and silicon oxide; the fragrance of the modified nano essence The type may be a spice such as pine, pine, grass or the like.

本发明抽水马桶用清洁剂的制备方法：包括以下步骤：The preparation method of the cleaning agent for toilets of the present invention comprises the following steps:

步骤一：准确称取自来水，放入不锈钢桶中，边缓慢搅拌边加入石油磺酸钠，待石油磺酸钠固体溶解后，再缓慢倒入具有搅拌加热装置的捏合机中，在缓慢搅拌下，加入十二烷基苯磺酸钠，此时捏合机内产生化学反应并产生热量，趁热依次加入蓝色染料、稀释赋形剂、无机纳米抗菌粉，保持捏合机内的加热温度在70℃，搅拌捏合时间为0.5h，之后自然冷却，制成膏状预制体清洁膏；Step 1: Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat. The blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added while maintaining the heating temperature in the kneader at 70. °C, stirring and kneading time is 0.5h, and then naturally cooled to form a paste-like preform cleaning paste;

步骤二：在盛有膏状预制体清洁膏的捏合机中加入纳米香精、原名粉，持续搅拌30min，直至膏体均匀，随后加工成型成成品。Step 2: Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.

将抽水马桶用清洁剂放入马桶水箱中，应避免堵住出水口，抽水马桶清洁剂在水箱内部分溶解到水里，每次使用马桶后按下抽水按钮，经冲刷过的厕盆表面光洁无污渍、无异味。Put the toilet cleaning agent into the toilet tank, avoid blocking the water outlet. The toilet cleaner is partially dissolved in the water tank. Press the pump button after each use of the toilet. The surface of the flushed toilet bowl is clean and free of stains. ,odorless.

实施例2：Example 2:

抽水马桶用清洁剂，按重量份包括水6份、石油磺酸钠4份、十二烷基苯磺酸钠30份、蓝色染料8份、缓释赋形剂12份、无机纳米抗菌粉1份、咪唑啉38份、三羟甲基丙烷2份。Detergent cleaner, 6 parts by weight of water, 4 parts of sodium petroleum sulfonate, 30 parts of sodium dodecyl benzene sulfonate, 8 parts of blue dye, 12 parts of slow release excipient, inorganic nano antibacterial powder 1 Parts, 38 parts of imidazoline and 2 parts of trimethylolpropane.

其中，缓释赋形剂为黄原胶与硬脂酸的混合物；无机纳米抗菌粉为市售的且由锌盐、纳米二氧化钛与氧化硅构成的透明膏状物；改性的纳米香精的香型可以是松木、松杉、青草等香料。Wherein, the sustained release excipient is a mixture of xanthan gum and stearic acid; the inorganic nano antibacterial powder is a commercially available transparent paste composed of zinc salt, nano titanium dioxide and silicon oxide; the fragrance of the modified nano essence The type may be a spice such as pine, pine, grass or the like.

本发明抽水马桶用清洁剂的制备方法：包括以下步骤：The preparation method of the cleaning agent for toilets of the present invention comprises the following steps:

步骤一：准确称取自来水，放入不锈钢桶中，边缓慢搅拌边加入石油磺酸钠，待石油磺酸钠固体溶解后，再缓慢倒入具有搅拌加热装置的捏合 机中，在缓慢搅拌下，加入十二烷基苯磺酸钠，此时捏合机内产生化学反应并产生热量，趁热依次加入蓝色染料、稀释赋形剂、无机纳米抗菌粉，保持捏合机内的加热温度在40℃，搅拌捏合时间为1h，之后自然冷却，制成膏状预制体清洁膏；Step 1: Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading with stirring heating device. In the machine, under slow agitation, sodium dodecylbenzene sulfonate is added. At this time, a chemical reaction occurs in the kneader and generates heat. The blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added while maintaining the kneading. The heating temperature in the machine is 40 ° C, the stirring and kneading time is 1 h, and then naturally cooled to prepare a paste pre-form cleaning paste;

步骤二：在盛有膏状预制体清洁膏的捏合机中加入纳米香精、原名粉，持续搅拌30min，直至膏体均匀，随后加工成型成成品。Step 2: Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.

将抽水马桶用清洁剂放入马桶水箱中，应避免堵住出水口，抽水马桶清洁剂在水箱内部分溶解到水里，每次使用马桶后按下抽水按钮，经冲刷过的厕盆表面光洁无污渍、无异味。Put the toilet cleaning agent into the toilet tank, avoid blocking the water outlet. The toilet cleaner is partially dissolved in the water tank. Press the pump button after each use of the toilet. The surface of the flushed toilet bowl is clean and free of stains. ,odorless.

实施例3：Example 3:

抽水马桶用清洁剂，按重量份包括水7份、石油磺酸钠4份、十二烷基苯磺酸钠27份、蓝色染料8份、缓释赋形剂13份、无机纳米抗菌粉1.2份、咪唑啉38份、三羟甲基丙烷3份。Detergent cleaner, 7 parts by weight of water, 4 parts of sodium petroleum sulfonate, 27 parts of sodium dodecyl benzene sulfonate, 8 parts of blue dye, 13 parts of slow release excipient, inorganic nano antibacterial powder 1.2 Parts, 38 parts of imidazoline and 3 parts of trimethylolpropane.

其中，缓释赋形剂为黄原胶与硬脂酸的混合物；无机纳米抗菌粉为市售的且由锌盐、纳米二氧化钛与氧化硅构成的透明膏状物；改性的纳米香精的香型可以是松木、松杉、青草等香料。Wherein, the sustained release excipient is a mixture of xanthan gum and stearic acid; the inorganic nano antibacterial powder is a commercially available transparent paste composed of zinc salt, nano titanium dioxide and silicon oxide; the fragrance of the modified nano essence The type may be a spice such as pine, pine, grass or the like.

本发明抽水马桶用清洁剂的制备方法：包括以下步骤：The preparation method of the cleaning agent for toilets of the present invention comprises the following steps:

步骤一：准确称取自来水，放入不锈钢桶中，边缓慢搅拌边加入石油磺酸钠，待石油磺酸钠固体溶解后，再缓慢倒入具有搅拌加热装置的捏合机中，在缓慢搅拌下，加入十二烷基苯磺酸钠，此时捏合机内产生化学反应并产生热量，趁热依次加入蓝色染料、稀释赋形剂、无机纳米抗菌粉，保持捏合机内的加热温度在70℃，搅拌捏合时间为1h，之后自然冷却，制成膏状预制体清洁膏；Step 1: Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat. The blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added while maintaining the heating temperature in the kneader at 70. °C, stirring and kneading time is 1h, then naturally cooled to make a paste-like preform cleaning paste;

步骤二：在盛有膏状预制体清洁膏的捏合机中加入纳米香精、原名粉，持续搅拌30min，直至膏体均匀，随后加工成型成成品。Step 2: Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.

将抽水马桶用清洁剂放入马桶水箱中，应避免堵住出水口，抽水马桶清洁剂在水箱内部分溶解到水里，每次使用马桶后按下抽水按钮，经冲刷过的厕盆表面光洁无污渍、无异味。Put the toilet cleaning agent into the toilet tank, avoid blocking the water outlet. The toilet cleaner is partially dissolved in the water tank. Press the pump button after each use of the toilet. The surface of the flushed toilet bowl is clean and free of stains. ,odorless.

以上所述仅是本发明的一种实施方式，应当指出，对于本领域普通技术人员来说，在不脱离本发明创造构思的前提下，还可以做出若干相似的变形和改进，这些也应视为本发明的保护范围之内。 The above is only one embodiment of the present invention, and it should be noted that some similar variations and modifications may be made by those skilled in the art without departing from the inventive concept. It is considered to be within the scope of protection of the present invention.

Claims (5)

一种抽水马桶用清洁剂，其特征在于：按重量份包括水5-7份、石油磺酸钠4-6份、十二烷基苯磺酸钠26-30份、蓝色染料6-10份、缓释赋形剂11-13份、无机纳米抗菌粉0.9-1.5份、咪唑啉35-40份、三羟甲基丙烷1.5-3.5份。A detergent for toilet bowl, characterized in that it comprises 5-7 parts of water, 4-6 parts of sodium petroleum sulfonate, 26-30 parts of sodium dodecylbenzene sulfonate, and 6-10 parts of blue dye by weight. The sustained release excipient is 11-13 parts, the inorganic nano antibacterial powder is 0.9-1.5 parts, the imidazoline is 35-40 parts, and the trimethylolpropane is 1.5-3.5 parts. 根据权利要求1所述的一种抽水马桶用清洁剂，其特征在于：所述缓释赋形剂为黄原胶与硬脂酸的混合物。A detergent for toilets according to claim 1, wherein the sustained release excipient is a mixture of xanthan gum and stearic acid. 根据权利要求1所述的一种抽水马桶用清洁剂，其特征在于：所述无机纳米抗菌粉为市售的且由锌盐、纳米二氧化钛与氧化硅构成的透明膏状物。A detergent for toilets according to claim 1, wherein said inorganic nano antibacterial powder is a commercially available transparent paste composed of a zinc salt, nano titanium dioxide and silicon oxide. 根据权利要求1所述的一种抽水马桶用清洁剂，其特征在于：所述改性的纳米香精的香型可以是松木、松杉、青草等香料。The detergent for toilets according to claim 1, wherein the modified nano-flavor is scented with spices such as pine, pine, and grass. 一种制备权利要求1-4任一项所述抽水马桶用清洁剂的制备方法,其特征在于,包括以下步骤:A method for preparing a detergent for a toilet according to any one of claims 1 to 4, characterized in that it comprises the following steps: 步骤一:准确称取自来水，放入不锈钢桶中，边缓慢搅拌边加入石油磺酸钠，待石油磺酸钠固体溶解后，再缓慢倒入具有搅拌加热装置的捏合机中，在缓慢搅拌下，加入十二烷基苯磺酸钠，此时捏合机内产生化学反应并产生热量，趁热依次加入蓝色染料、稀释赋形剂、无机纳米抗菌粉，保持捏合机内的加热温度在40-80℃，搅拌捏合时间为0.5-1h，之后自然冷却，制成膏状预制体清洁膏；Step 1: Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat. The blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added in the hot state, and the heating temperature in the kneader is maintained at 40. -80 ° C, stirring and kneading time is 0.5-1 h, and then naturally cooled to prepare a paste-like preform cleaning paste; 步骤二:在盛有膏状预制体清洁膏的捏合机中加入纳米香精、原名粉，持续搅拌30min，直至膏体均匀，随后加工成型成成品。 Step 2: Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.
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