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WO2024166840A1 - Composition de produit de nettoyage - Google Patents

Composition de produit de nettoyage Download PDF

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Publication number
WO2024166840A1
WO2024166840A1 PCT/JP2024/003614 JP2024003614W WO2024166840A1 WO 2024166840 A1 WO2024166840 A1 WO 2024166840A1 JP 2024003614 W JP2024003614 W JP 2024003614W WO 2024166840 A1 WO2024166840 A1 WO 2024166840A1
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WO
WIPO (PCT)
Prior art keywords
component
less
mass
cleaning
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/JP2024/003614
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English (en)
Japanese (ja)
Inventor
渉 上野
宏紀 小島
敏正 久米
勝也 齊川
雅弥 福田
大輝 石炭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to CN202480010949.1A priority Critical patent/CN120641545A/zh
Priority to AU2024218057A priority patent/AU2024218057A1/en
Publication of WO2024166840A1 publication Critical patent/WO2024166840A1/fr
Anticipated expiration legal-status Critical
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers

Definitions

  • the present invention relates to a cleaning composition.
  • Japanese Patent Laid-Open Publication No. 7-286195 discloses a method for producing a granular nonionic detergent composition, in which (a) a nonionic surfactant, (b) a porous inorganic powder containing 50% by weight or more of SiO2 , and (c) a soap are uniformly kneaded and mixed in predetermined amounts to form a solid detergent, and then an inorganic powder is added as a grinding aid to crush the solid detergent into powdery or granular detergent particles.
  • a high bulk density granular nonionic detergent composition containing (a) a nonionic surfactant, (b) a clay mineral, (c) an oil-absorbing carrier, (d) a specified polymer chelate builder, and (e) a positively charged nitrogen atom-containing compound which has a positively charged nitrogen atom in its molecule, is at least partially dissolved in the nonionic surfactant (a), and is adsorbed to the clay mineral (b).
  • 2004-10681 discloses a granular detergent composition which contains (a) a specified amine compound, (b) a sulfonate salt, (c) a specified nonionic compound, and (d) a water-soluble inorganic salt, and has a surfactant equivalent content according to JIS K3362:1998 of 10 to 60 mass %.
  • the present invention provides a detergent composition which has excellent cleaning properties, rinsing properties and finish properties for textile products and further imparts antibacterial properties to the textile products.
  • the finish quality refers to reducing the amount of undissolved cleaning composition and reducing streaks remaining on the item to be cleaned.
  • the present invention comprises the following component (A) in an amount of 5% by mass or more and 40% by mass or less, the following component (B) in an amount of 20% by mass or more and 80% by mass or less, the following component (C) in an amount of 5% by mass or more and 40% by mass or less, the following component (D) in an amount of 0.1% by mass or more and 5.0% by mass or less, and the following component (E) in an amount of 0.1% by mass or more and 10% by mass or less, a mass ratio (a2)/[(a1)+(a2)] of the content of the (a2) component to the total content of the (a1) component and the (a2) component is 0 or more and 0.5 or less; a mass ratio (b2)/[(b1)+(b2)] of the content of the (b2) component to the total content of the (b1) component and the (b2) component is 0.2 or more and 0.8 or less; a mass ratio (C)/[(B)+(C)] of the content of the (C) component to
  • the present invention provides a detergent composition that has excellent cleaning, rinsing and finishing properties for textile products, and further imparts antibacterial properties to the textile products.
  • the mechanism by which the detergent composition of the present invention has excellent cleaning properties, rinsing properties and finishing properties for textile products and further imparts antibacterial properties to the textile products is not clear, but is presumed to be as follows. It is presumed that the cleaning ability of the detergent composition of the present invention against sebum stains is improved by using a nonionic surfactant as component (a1), an anionic surfactant as component (a2), and an alkaline agent as component (b1) in combination. It is also presumed that the cleaning power of the detergent composition of the present invention against muddy soils is improved by the combined use of component (a2) and the anionic polymer (E).
  • the cleaning composition of the present invention achieves both rinsability and finish by containing a specific component (A) and further by controlling the ratio of the water-soluble inorganic salt of component (B) to the water-insoluble inorganic salt of component (C) within a specific range.
  • the finish in the present invention refers to reducing the amount of undissolved part of the cleaning composition and reducing streaks on the washed object.
  • the combination of components (A) to (E) in the cleaning composition of the present invention provides excellent cleaning properties, rinsing properties and finishing properties for textile products without impairing the antibacterial activity of component (D).
  • the action mechanism of the cleaning composition of the present invention is not limited to the above-mentioned mechanism.
  • the cleaning composition of the present invention contains the following components (A), (B), (C), (D) and (E) in given amounts.
  • the component (A) is one or more surfactants selected from the group consisting of (a1) nonionic surfactants and (a2) anionic surfactants.
  • the component (A) may be a surfactant containing one or more surfactants selected from the component (a1) and, optionally, one or more surfactants selected from the component (a2).
  • the component (a1) is a nonionic surfactant, and from the viewpoint of cleaning performance, the component (a1) can be one or more selected from the group consisting of polyoxyalkylene alkyl or alkenyl ethers, alkyl (poly)glycosides (glycoside-type nonionic surfactants), sorbitan-based nonionic surfactants, compounds in which an alkylene oxide is added between the ester bonds of long-chain fatty acid alkyl esters, fatty acid monoglycerides, and sucrose fatty acid esters.
  • (a1-1) a nonionic surfactant containing alkyleneoxy groups and having an average added mole number of alkyleneoxy groups of 1 or more and 30 or less (hereinafter referred to as component (a1-1)).
  • the alkyleneoxy group of the component (a1-1) is preferably one or more groups selected from alkyleneoxy groups having from 2 to 4 carbon atoms, and more preferably one or more groups selected from an ethyleneoxy group and a propyleneoxy group.
  • the average number of moles of alkyleneoxy groups added in the component (a1-1) is, from the viewpoint of cleansing ability against sebum stains, 1 or more, preferably 6 or more, more preferably 8 or more, and 30 or less, preferably 25 or less, more preferably 20 or less, and even more preferably 15 or less.
  • the component (a1-1) is preferably a nonionic surfactant represented by the following general formula (a1-1).
  • R 1a is an aliphatic hydrocarbon group having 8 to 18 carbon atoms
  • R 2a is a hydrogen atom or a methyl group.
  • CO is a carbonyl group
  • m is the number of 0 or 1.
  • the A 1a O group is one or more selected from alkyleneoxy groups having 2 to 4 carbon atoms.
  • n is the average number of moles added of the A 1a O groups, and is a number of 1 to 30.
  • R 1a is an aliphatic hydrocarbon group, preferably a group selected from an alkyl group and an alkenyl group.
  • the A 1a O group is one or more selected from alkyleneoxy groups having from 2 to 4 carbon atoms, preferably one or more selected from alkyleneoxy groups having from 2 to 3 carbon atoms, more preferably an ethyleneoxy group.
  • the different alkyleneoxy groups may be bonded in a block manner or a random manner.
  • n is the average number of moles of A 1a O groups added and is a number of 1 to 30.
  • n is 1 or more, preferably 6 or more, more preferably 8 or more, and 30 or less, preferably 25 or less, more preferably 20 or less, and even more preferably 15 or less, from the viewpoint of cleansing ability against sebum stains.
  • m is preferably 0 from the viewpoint of cleaning properties.
  • R 2a is preferably a hydrogen atom from the viewpoint of cleaning properties.
  • nonionic surfactants that do not have an alkyleneoxy group other than component (a1-1) include one or more selected from sucrose fatty acid esters, glycerin fatty acid esters, sorbitan fatty acid esters, alkyl glycosides, and glyceryl monoethers.
  • the component (a2) is an anionic surfactant.
  • the component (a2) is preferably one or more selected from alkylarylsulfonic acid type surfactants, sulfate ester type surfactants, alkanesulfonic acid type surfactants, olefinsulfonic acid type surfactants, sulfosuccinic acid alkyl ester type surfactants, sulfo fatty acid ester type surfactants, and fatty acids and their salts, more preferably one or more selected from alkylarylsulfonic acid type surfactants, sulfate ester type surfactants, sulfosuccinic acid alkyl ester type surfactants, and fatty acids and their salts, and even more preferably one or more selected from alkylarylsulfonic acid type surfactants, and fatty acids and their salts.
  • component (a2) is a salt
  • examples of the salt include inorganic salts such as sodium salt, potassium salt, ammonium salt, magnesium salt, etc., and organic salts such as monoethanolamine salt, diethanolamine salt, triethanolamine salt, morpholine salt, etc.
  • the salt of component (a2) is preferably an inorganic salt selected from alkali metal salts such as sodium salt, potassium salt, etc. and alkaline earth metal salts such as magnesium salt, etc., more preferably an alkali metal salt, and even more preferably a sodium salt.
  • the component (a2) examples include one or more compounds selected from the compounds represented by the following general formula (a2-1) (hereinafter referred to as the component (a2-1)), the compounds represented by the general formula (a2-2) (hereinafter referred to as the component (a2-2)), the compounds represented by the general formula (a2-3) (hereinafter referred to as the component (a2-3)), and the compounds represented by the general formula (a2-4) (hereinafter referred to as the component (a2-4)).
  • the component (a2) is preferably one or more selected from the components (a2-1), (a2-2), and (a2-3), and more preferably one or more selected from the components (a2-1) and (a2-2).
  • R 3a -B-SO 3 M (a2-1) [In formula (a2-1), R 3a represents an alkyl group having 9 to 14 carbon atoms, B represents a benzene ring, the carbon atom of R 3a bonded to the carbon atom of B is a secondary carbon atom, and M represents a cation.
  • R 4a -COOM (a2-2) [In formula (a2-2), R 4a represents an alkyl group or an alkenyl group having 10 to 18 carbon atoms, and M represents a cation.]
  • R 5a -O-(AO) n -SO 3 M (a2-3) [In formula (a2-3), R 5a is an aliphatic hydrocarbon group having 10 to 18 carbon atoms, AO group is one or more alkyleneoxy groups selected from an ethyleneoxy group and a propyleneoxy group, n is a number of 0 to 20, and M is a cation.]
  • R 6a -CH(SO 3 M) COOR 7a (a2-4) [In formula (a2-4), R 6a represents an alkyl group having 8 to 18 carbon atoms, R 7a represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and M represents
  • R 3a represents an alkyl group having 9 or more carbon atoms, preferably 10 or more carbon atoms, and preferably 14 or less, more preferably 13 or less carbon atoms.
  • M is preferably a hydrogen ion, an alkali metal ion such as a sodium ion or a potassium ion, an alkaline earth metal (1/2 atom) ion such as a magnesium ion or a calcium ion, or an organic ammonium ion.
  • the organic ammonium salt may be a salt with an amine such as monoethanolamine, diethanolamine, or triethanolamine.
  • M is preferably an alkali metal ion such as a sodium ion or a potassium ion, or an alkanol ammonium ion such as a monoethanol ammonium ion or a diethanol ammonium ion, and more preferably a sodium ion.
  • the component (a2-1) is preferably a p-alkylbenzenesulfonate in which the alkyl group has from 10 to 14 carbon atoms, and more preferably a sodium p-alkylbenzenesulfonate in which the alkyl group has from 10 to 14 carbon atoms. That is, the component (a2-1) is preferably a compound in which, in general formula (a2-1), R 3a is an alkyl group having from 10 to 14 carbon atoms, and M is a sodium ion.
  • R 4a is an alkyl group or alkenyl group having 10 or more, preferably 11 or more, and 18 or less, preferably 16 or less, more preferably 14 or less, and even more preferably 13 or less.
  • R 4a can be one or more groups selected from a linear alkyl group, a branched alkyl group, a linear alkenyl group, and a branched alkenyl group, and is preferably a linear alkyl group.
  • M is preferably a hydrogen ion, an alkali metal ion such as a sodium ion or a potassium ion, an alkaline earth metal (1/2 atom) ion such as a magnesium ion or a calcium ion, or an organic ammonium ion.
  • the organic ammonium salt may be a salt with an amine such as monoethanolamine, diethanolamine, or triethanolamine.
  • M is preferably an alkali metal ion such as a sodium ion or a potassium ion, or an alkanol ammonium ion such as a monoethanol ammonium ion or a diethanol ammonium ion, and more preferably a sodium ion.
  • the component (a2-2) is preferably one or more selected from lauric acid, myristic acid, isostearic acid, palmitic acid, isopalmitic acid, oleic acid, and salts thereof, more preferably one or more selected from lauric acid, myristic acid, palmitic acid, and salts thereof, and even more preferably one or more selected from lauric acid, myristic acid, and salts thereof.
  • the component (a2-2) is preferably a compound in which, in general formula (a2-2), R 4a is an alkyl group having from 10 to 16 carbon atoms and M is a cation, and more preferably a compound in which M is a hydrogen ion or a sodium ion.
  • R 5a is an aliphatic hydrocarbon group having an integer of preferably 10 or more, more preferably 11 or more, even more preferably 12 or more, and preferably 18 or less, more preferably 16 or less, even more preferably 14 or less.
  • R 5a is a linear or branched aliphatic hydrocarbon group, preferably a linear aliphatic hydrocarbon group, and more preferably a linear alkyl group.
  • the AO group is one or more alkyleneoxy groups selected from an ethyleneoxy group and a propyleneoxy group.
  • the AO group contains an ethyleneoxy group and a propyleneoxy group
  • the ethyleneoxy group and the propyleneoxy group may be in a block bond or a random bond. From the viewpoint of improving cleaning properties, it is preferable that the AO group is a group containing an ethyleneoxy group.
  • n is the average number of moles of AO groups added, and is a number between 0 and 20. From the viewpoint of improving cleaning performance, n is 0 or more, and from the viewpoint of improving cleaning performance, n is 20 or less, preferably 16 or less, more preferably 12 or less, even more preferably 8 or less, and even more preferably 4 or less.
  • the average number of moles of the propyleneoxy group added when AO contains a propyleneoxy group, the average number of moles of the propyleneoxy group added is preferably 4 or less, more preferably 3 or less, and preferably 0 or more. In the general formula (a2-3), the average number of moles of the propyleneoxy group added may be 0. In the general formula (a2-3), when AO contains an ethyleneoxy group, the average number of moles of the ethyleneoxy group added is preferably 0 or more and preferably 10 or less, more preferably 5 or less, and even more preferably 4 or less.
  • M is preferably a hydrogen ion, an alkali metal ion such as a sodium ion or a potassium ion, an alkaline earth metal (1/2 atom) ion such as a magnesium ion or a calcium ion, or an organic ammonium ion.
  • the organic ammonium salt may be a salt with an amine such as monoethanolamine, diethanolamine, or triethanolamine.
  • M is preferably an alkali metal ion such as a sodium ion or a potassium ion, or an alkanol ammonium ion such as a monoethanol ammonium ion or a diethanol ammonium ion, and is more preferably a sodium ion.
  • R 6a is preferably an alkyl group having 8 or more carbon atoms, more preferably 10 or more, even more preferably 12 or more, and preferably 18 or less, more preferably 16 or less.
  • R 7a is preferably an alkyl group having 1 or more carbon atoms and preferably 5 or less, more preferably 4 or less, and even more preferably 3 or less.
  • M is preferably a hydrogen ion, an alkali metal ion such as a sodium ion or a potassium ion, an alkaline earth metal (1/2 atom) ion such as a magnesium ion or a calcium ion, or an organic ammonium ion.
  • the organic ammonium salt may be a salt with an amine such as monoethanolamine, diethanolamine, or triethanolamine.
  • M is preferably an alkali metal ion such as a sodium ion or a potassium ion, or an alkanol ammonium ion such as a monoethanol ammonium ion or a diethanol ammonium ion, and is more preferably a sodium ion.
  • the component (a2-4) is preferably an ⁇ -sulfofatty acid methyl ester sodium salt, in which, in general formula (a2-4), R 6a is an alkyl group having 11 to 14 carbon atoms, R 7a is a methyl group, and M is a sodium ion.
  • the component (B) is one or more water-soluble inorganic salts selected from the components (b1) and (b2).
  • the component (B) may be a water-soluble inorganic salt containing one or more water-soluble inorganic salts selected from the component (b1) and one or more water-soluble inorganic salts selected from the component (b2).
  • the water-soluble inorganic salt in component (B) refers to an inorganic salt that dissolves in an amount of 1 g or more in 100 g of water at 20°C.
  • the component (b1) is a water-soluble inorganic salt, and a 0.1 g/L aqueous solution of the water-soluble inorganic salt has a pH of 9.0 or higher at 20° C.
  • the component (b2) is a water-soluble inorganic salt, and the pH of a 0.1 g/L aqueous solution of the water-soluble inorganic salt at 20° C. is less than 9.0.
  • the cleaning composition of the present invention by using the components (b1) and (b2) in an appropriate ratio, it is possible to prevent the cleaning composition from remaining undissolved in water and to prevent a decrease in cleaning properties, even if the cleaning composition contains the water-insoluble inorganic component (C) described below.
  • a composite electrode for pH measurement e.g., glass-laid sleeve type, manufactured by Horiba, Ltd.
  • a saturated potassium chloride aqueous solution 3.33 mol/L
  • a pH meter e.g., pH/ion meter F-23, manufactured by Horiba, Ltd.
  • a pH 4.01 standard solution phthalate standard solution
  • a pH 6.86 standard solution neutral phosphate standard solution
  • a pH 9.18 standard solution borate standard solution
  • the pH measurement electrode is immersed in the thermostatically adjusted standard solution for 3 minutes, and calibration operations are performed in the order of pH 6.86 ⁇ pH 9.18 ⁇ pH 4.01.
  • a 0.1 g/L aqueous solution of the (b1) or 0.1 g/L aqueous solution of the (b2) component to be measured is adjusted to 20°C, and the electrode of the pH meter is immersed in the sample, and the pH is measured after 1 minute.
  • the component (b1) is a water-soluble inorganic salt having a pH of 9.0 or more at 20° C. in a 0.1 g/L aqueous solution.
  • the component (b1) may be an alkaline agent.
  • Examples of the component (b1) include one or more alkaline agents selected from alkali metal carbonates, alkali metal silicates, tripolyphosphates, alkali metal sulfites, alkali metal hydroxides, alkali metal perborates, and alkali metal percarbonates.
  • the alkali metal carbonate may be at least one selected from sodium carbonate, potassium carbonate, and sodium sesquicarbonate, with sodium carbonate being preferred.
  • the alkali metal silicate may be at least one selected from sodium silicate, potassium silicate, sodium metasilicate, and potassium metasilicate.
  • Tripolyphosphates include alkali metal salts of tripolyphosphate.
  • Alkali metal sulfites include sodium sulfite.
  • the alkali metal hydroxide may be at least one selected from sodium hydroxide and potassium hydroxide.
  • Alkali metal perborates include sodium perborate.
  • the alkali metal percarbonate includes sodium percarbonate.
  • the component (b1) is preferably one or more selected from alkali metal carbonates, more preferably one or more selected from sodium carbonate and potassium carbonate, and even more preferably sodium carbonate.
  • Component (b2) is a water-soluble inorganic salt having a pH of less than 9.0 in a 0.1 g/L aqueous solution at 20° C.
  • Component (b2) may be one or more compounds selected from inorganic sulfates, inorganic halogen compounds, and alkali metal hydrogen carbonates.
  • Component (b2) preferably contains one or more water-soluble inorganic salts selected from inorganic sulfates and alkali metal hydrogen carbonates.
  • the component (b2) may be one or more compounds selected from sodium sulfate, magnesium sulfate, aluminum sulfate, potassium sulfate, sodium chloride, potassium chloride, calcium chloride, magnesium chloride, sodium hydrogen carbonate, and potassium hydrogen carbonate.
  • the component (b2) may be a hydrate or anhydrous.
  • the component (C) is a water-insoluble inorganic component.
  • the component (C) may be a water-insoluble carrier.
  • water-insoluble means that 1 g or more of the component does not dissolve in 100 g of water at 20°C.
  • the component (C) may be one or more selected from amorphous silica, calcium silicate, clay minerals, crystalline aluminosilicates, and amorphous aluminosilicates, and is preferably one or more selected from clay minerals and crystalline aluminosilicates.
  • the component (C) when used in a specific ratio with the component (B), has the effect of suppressing the amount of dissolution of the detergent composition after washing of the items to be washed and reducing the turbidity of the rinse water.
  • the average primary particle diameter of component (C) is preferably 0.1 ⁇ m or more, more preferably 1 ⁇ m or more, and preferably 10 ⁇ m or less, more preferably 5 ⁇ m or less.
  • the average primary particle diameter of component (C) is measured using a laser diffraction/scattering type particle size distribution measuring device (e.g., HORIBA, LA-950). This average primary particle diameter is the D50 (median diameter) of the cumulative particle size distribution based on volume.
  • component (C) examples include amorphous aluminosilicates (oil absorption capacity: 285 mL/100 g) described in JP-A-9-132794, JP-A-7-10526, JP-A-6-227811, and JP-A-8-119622.
  • the calcium silicate of component (C) may be Fluorite R (manufactured by Tokuyama Corp., oil absorption capacity: 400 to 500 mL/100 g), the amorphous silica of component (C) may be Tokusil NR (manufactured by Tokuyama Corp., oil absorption capacity: 210 to 270 mL/100 g) or Silopure (manufactured by Fuji Silysia Chemical Ltd., oil absorption capacity: 240 to 280 mL/100 g), and the amorphous aluminosilicate of component (C) may be TIXOREX25 (manufactured by Korea-Futsu Chemical Co., Ltd., 220 to 270 mL/100 g).
  • the crystalline aluminosilicate may be zeolite.
  • zeolites include crystalline aluminosilicates such as A-type, X-type, and P-type zeolites.
  • the crystalline aluminosilicate is preferably A-type zeolite (for example, trade name "Toyobuilder" manufactured by Tosoh Corporation, oil absorption capacity according to JIS K 5101 method: 40 mL/100 g or more).
  • P-type zeolite for example, trade names "Doucil A24", “ZSEO64”, etc.; both manufactured by Crosfield; oil absorption capacity 60 to 150 mL/100 g
  • X-type for example, trade name "WessalithXD” manufactured by Degussa; oil absorption capacity 80 to 100 mL/100 g
  • WO 98/4262 zeolite The hybrid zeolite described in No. 2 is also suitable.
  • the clay mineral of component (C) is bentonite.
  • the bentonite preferably has an ion exchange capacity of 50 to 100 meq/100 g.
  • the bentonite may be one or more selected from the group consisting of alkali metal or alkaline earth metal montmorillonite, saponite or hectorite, smectitic clay, illite, attapulgite and kaolinite. Powdered or granulated bentonite may be used. For example, see JP 2008-189719 A for the granulated clay mineral.
  • the component (D) is a cationic surfactant.
  • the component (D) may be a quaternary ammonium salt type surfactant.
  • the component (D) may have one or more functions selected from a bactericidal action, an antibacterial action, and a disinfecting action.
  • the quaternary ammonium salt surfactant of the component (D) is preferably at least one selected from the group consisting of compounds represented by the following general formula (d1) and compounds represented by the following general formula (d2):
  • R 1d is an aliphatic hydrocarbon group having from 8 to 18 carbon atoms
  • R 2d is a group selected from an aliphatic hydrocarbon group having from 8 to 18 carbon atoms, an alkyl group having from 1 to 3 carbon atoms, and a hydroxyalkyl group having from 1 to 3 carbon atoms
  • R 3d and R 4d are each independently a group selected from an alkyl group having from 1 to 3 carbon atoms, and a hydroxyalkyl group having from 1 to 3 carbon atoms
  • X ⁇ is an anion.
  • R 5d is an aliphatic hydrocarbon group having from 8 to 18 carbon atoms
  • R 6d and R 7d are each independently a group selected from an alkyl group having from 1 to 3 carbon atoms and a hydroxyalkyl group having from 1 to 3 carbon atoms
  • X ⁇ is an anion.
  • the number of carbon atoms in R 1d is preferably 9 or more, more preferably 10 or more, even more preferably 12 or more, and preferably 16 or less.
  • R 1d is preferably an alkyl group or an alkenyl group, and more preferably an alkyl group.
  • R 2d is a group selected from an aliphatic hydrocarbon group having 8 to 18 carbon atoms, an alkyl group having 1 to 3 carbon atoms, and a hydroxyalkyl group having 1 to 3 carbon atoms.
  • R 2d is an aliphatic hydrocarbon group having 8 to 18 carbon atoms, from the viewpoint of detergency, R 2d is preferably an alkyl or alkenyl group having 8 or more and preferably 14 or less, more preferably 12 or less, and more preferably an alkyl group.
  • R 3d and R 4d are each independently a group selected from an alkyl group having 1 to 3 carbon atoms and a hydroxyalkyl group having 1 to 3 carbon atoms. It is preferable that R 3d and R 4d are each independently a group selected from an alkyl group having 1 to 3 carbon atoms. Examples of the alkyl group having 1 to 3 carbon atoms include a methyl group, an ethyl group, and a propyl group. Examples of the hydroxyalkyl group having 1 to 3 carbon atoms include a hydroxymethyl group, a hydroxyethyl group, and a hydroxypropyl group.
  • X- is an anion.
  • the anion include one or more anions selected from a halogen ion and an alkyl sulfate ion having 1 to 3 carbon atoms.
  • the halogen ion include a chloride ion, a bromide ion, and an iodide ion.
  • the alkyl sulfate ion having 1 to 3 carbon atoms include a methyl sulfate ion, an ethyl sulfate ion, and a propyl sulfate ion.
  • R 5d is an aliphatic hydrocarbon group having from 8 to 18 carbon atoms. From the viewpoint of antibacterial performance, the number of carbon atoms in R 5d is preferably 8 or more, more preferably 10 or more, even more preferably 12 or more, and preferably 18 or less, more preferably 16 or less. R 5d is preferably an alkyl group or an alkenyl group, and more preferably an alkyl group.
  • R 6d and R 7d are each independently a group selected from an alkyl group having 1 to 3 carbon atoms and a hydroxyalkyl group having 1 to 3 carbon atoms. It is preferable that R 6d and R 7d are each independently a group selected from an alkyl group having 1 to 3 carbon atoms. Examples of the alkyl group having 1 to 3 carbon atoms include a methyl group, an ethyl group, and a propyl group. Examples of the hydroxyalkyl group having 1 to 3 carbon atoms include a hydroxymethyl group, a hydroxyethyl group, and a hydroxypropyl group.
  • X- is an anion.
  • the anion include one or more anions selected from a halogen ion and an alkyl sulfate ion having 1 to 3 carbon atoms.
  • the halogen ion include a chloride ion, a bromide ion, and an iodide ion.
  • the alkyl sulfate ion having 1 to 3 carbon atoms include a methyl sulfate ion, an ethyl sulfate ion, and a propyl sulfate ion.
  • the compound of general formula (d2) include N-dodecyl-N,N-dimethyl-N-benzyl ammonium salt, N-tridecyl-N,N-dimethyl-N-benzyl ammonium salt, N-tetradecyl-N,N-dimethyl-N-benzyl ammonium salt, N-pentadecyl-N,N-dimethyl-N-benzyl ammonium salt, N-hexadecyl-N,N-dimethyl-N-benzyl ammonium salt, N-dodecyl-N,N-diethyl-N-benzyl ammonium salt, N-tridecyl-N,N-diethyl-N-benzyl ammonium salt, N-tetra ...
  • the examples include one or more compounds selected from the group consisting of ammonium salts, N-pentadecyl-N,N-diethyl-N-benzyl ammonium salts, N-hexadecyl-N,N-diethyl-N-benzyl ammonium salts, N-dodecyl-N-methyl-N-ethyl-N-benzyl ammonium salts, N-tridecyl-N-methyl-N-ethyl-N-benzyl ammonium salts, N-tetradecyl-N-methyl-N-ethyl-N-benzyl ammonium salts, N-pentadecyl-N-methyl-N-ethyl-N-benzyl ammonium salts, and N-hexadecyl-N-methyl-N-ethyl-N-benzyl ammonium salts.
  • the component (D) is preferably one or more selected from benzalkonium chloride and alkyltrimethylammonium chloride.
  • the benzalkonium chloride is preferably a compound represented by the general formula (d2) above.
  • the alkyltrimethylammonium chloride is preferably a compound represented by the general formula (d1) above.
  • the component (E) is an anionic polymer.
  • the component (E) include a polymer having a carboxylic acid group or a salt thereof and having a weight average molecular weight of 3,000 or more.
  • Examples of the component (E) include one or more polymers selected from polyacrylic acid and its salts, copolymers of acrylic acid and maleic acid and their salts, and polymaleic acid and its salts (hereinafter referred to as component (E1)).
  • the polyacrylic acid and salts thereof include at least one selected from polyacrylic acid, sodium polyacrylate, potassium polyacrylate, and the like, and preferably at least one selected from sodium polyacrylate and potassium polyacrylate.
  • the copolymer of acrylic acid and maleic acid and its salt may be one or more selected from the copolymer of acrylic acid and maleic acid, the sodium salt of the copolymer of acrylic acid and maleic acid, and the potassium salt of the copolymer of acrylic acid and maleic acid, and preferably one or more selected from the sodium salt of the copolymer of acrylic acid and maleic acid and the potassium salt of the copolymer of acrylic acid and maleic acid.
  • the molar ratio of the copolymer of acrylic acid and maleic acid, in terms of the mole number of acrylic acid/the mole number of maleic acid, is preferably 1/99 or more, more preferably 10/90 or more, and preferably 99/1 or less, more preferably 90/10 or less.
  • the polymaleic acid and salts thereof include at least one selected from polymaleic acid, sodium polymaleate, potassium polymaleate, and the like, and preferably at least one selected from sodium polymaleate and potassium polymaleate.
  • the (E1) component may be a copolymer containing a monomer other than acrylic acid and maleic acid that is copolymerizable with acrylic acid and/or maleic acid, so long as it does not interfere with the manifestation of the effects of the present invention.
  • the monomer other than acrylic acid and maleic acid that is copolymerizable with acrylic acid and/or maleic acid include one or more selected from vinyl monomers, acrylic monomers, and styrene monomers, and more specifically, one or more selected from methacrylic acid, methyl acrylate, ethyl acrylate, methyl methacrylate, and styrene.
  • the molar ratio of the monomer other than acrylic acid and maleic acid that is copolymerizable with acrylic acid and/or maleic acid in the (E1) component is preferably 0 mol% or more, and preferably 5 mol% or less, more preferably 3 mol% or less, and even more preferably 0 mol%. Therefore, the polyacrylic acid and its salts, the copolymer of acrylic acid and maleic acid and its salts, and the polymaleic acid and its salts of the present invention may be polymers or copolymers that contain, among all constituent monomers, monomers other than acrylic acid and maleic acid that are copolymerizable with acrylic acid and/or maleic acid in the range of 0 mol % to 5 mol %.
  • the weight average molecular weight of component (E) is preferably 3,000 or more, more preferably 3,500 or more, even more preferably 4,000 or more, still more preferably 5,000 or more, still more preferably 6,000 or more, still more preferably 7,000 or more, still more preferably 8,000 or more, still more preferably 9,000 or more, still more preferably 10,000 or more, and preferably 100,000 or less, more preferably 50,000 or less, still more preferably 25,000 or less, and still more preferably 15,000 or less.
  • the weight average molecular weight can be measured according to the following method for measuring weight average molecular weight.
  • the weight average molecular weight of component (E) can be measured by GPC (gel permeation chromatography), and the weight average molecular weight (Mw) can be determined using a conversion standard substance.
  • GPC gel permeation chromatography
  • Mw weight average molecular weight
  • the cleaning composition of the present invention contains the component (A) in an amount of 5% by mass or more, preferably 7% by mass or more, more preferably 9% by mass or more, and even more preferably 11% by mass or more in terms of detergency, and 40% by mass or less, preferably 30% by mass or less, more preferably 25% by mass or less, and even more preferably 20% by mass or less in terms of rinsing ability.
  • the present invention contains the component (a2) as the component (A), the mass of the component (a2) is expressed as a value converted into a sodium salt.
  • the mass ratio (a2)/[(a1)+(a2)] of the content of the (a2) component to the total content of the (a1) component and the (a2) component is 0 or more, preferably 0.05 or more, more preferably 0.10 or more, and even more preferably 0.15 or more, from the viewpoint of cleaning performance, and is 0.5 or less, preferably 0.45 or less, more preferably 0.40 or less, and even more preferably 0.35 or less, from the viewpoint of rinsing performance and antibacterial performance.
  • the detergent composition of the present invention contains component (B) in an amount of 20% by mass or more, preferably 25% by mass or more, more preferably 30% by mass or more, and even more preferably 40% by mass or more in terms of cleaning performance, and 80% by mass or less, preferably 70% by mass or less, more preferably 65% by mass or less, even more preferably 60% by mass or less, and even more preferably 55% by mass or less in terms of suppressing residual dissolution.
  • the mass ratio (b2)/[(b1)+(b2)] of the content of the (b2) component to the total content of the (b1) component and the (b2) components is 0.2 or more, preferably 0.30 or more, more preferably 0.35 or more, and even more preferably 0.40 or more, from the viewpoints of suppressing residual dissolution and antibacterial performance, and is 0.8 or less, preferably 0.7 or less, more preferably 0.65 or less, even more preferably 0.60 or less, even more preferably 0.55 or less, and even more preferably 0.50 or less, from the viewpoints of cleaning performance and antibacterial performance.
  • the detergent composition of the present invention contains component (C) in an amount of 5% by mass or more, preferably 10% by mass or more, more preferably 15% by mass or more, even more preferably 20% by mass or more, and even more preferably 25% by mass or more, in terms of suppressing residual dissolution, and 40% by mass or less, preferably 35% by mass or less, more preferably 32.5% by mass or less, and even more preferably 30% by mass or less, in terms of suppressing formation of residual streaks.
  • the mass ratio (C)/[(B)+(C)] of the content of the (C) component to the total content of the (B) component and the (C) component is greater than 0, preferably 0.05 or more, more preferably 0.1 or more, even more preferably 0.15 or more, even more preferably 0.20 or more, even more preferably 0.25 or more, even more preferably 0.30 or more, from the viewpoint of suppressing the formation of residual streaks, and is 0.50 or less, preferably 0.45 or less, more preferably 0.40 or less, even more preferably 0.38 or less.
  • the detergent composition of the present invention contains component (D) in an amount of 0.1% by mass or more, preferably 0.5% by mass or more, more preferably 0.7% by mass or more, even more preferably 1.0% by mass or more, and even more preferably 2.0% by mass or more, and the upper limit is not particularly limited, but may be, for example, 5.0% by mass or less, further 4.0% by mass or less, further 3.5% by mass or less, and further 3.0% by mass or less.
  • the detergent composition of the present invention contains component (E) in an amount of 0.1% by mass or more, preferably 1.0% by mass or more, more preferably 2.0% by mass or more, even more preferably 3.0% by mass or more, even more preferably 4.0% by mass or more, and 10% by mass or less, preferably 8.0% by mass or less, more preferably 6.0% by mass or less, even more preferably 5.0% by mass or less.
  • the ratio of the content of component (A) to the total content of surfactants contained in the cleaning composition, (A)/(total content of surfactants), is preferably 50 mass% or more, more preferably 60 mass% or more, even more preferably 70 mass% or more, and even more preferably 80 mass% or more, from the viewpoint of cleaning performance, and is preferably 98 mass% or less, more preferably 96 mass% or less, and even more preferably 94 mass% or less, from the viewpoint of antibacterial performance.
  • the total surfactants contained in the cleaning composition may be the total content of component (A), component (D), and the following component (F).
  • the cleaning composition of the present invention may contain, as component (F), any surfactant other than components (A) and (D).
  • the surfactant other than the components (A) and (D) may be one or more selected from amphoteric surfactants.
  • the amphoteric surfactant may be one or more selected from N-alkanoylaminopropyl-N,N-dimethylamine oxide, N-alkyl-N,N-dimethylamine oxide, N-alkanoylaminopropyl-N,N-dimethyl-N-carboxymethylammonium betaine, N-alkyl-N,N-dimethyl-N-carboxymethylammonium betaine, N-alkyl-N,N-dimethyl-N-sulfopropylammonium sulfobetaine, N-alkyl-N,N-dimethyl-N-(2-hydroxysulfopropyl)ammonium sulfobetaine, N-alkanoylaminopropyl-N,N-dimethyl-N-sulfopropylammonium sulfobetaine, and N-alkanoylaminopropyl-N,N-dimethyl-N-(2-hydroxys
  • the cleaning composition of the present invention contains component (F)
  • the cleaning composition of the present invention contains component (F) in an amount of preferably 0.1% by mass or more, more preferably 0.2% by mass or more, even more preferably 0.3% by mass or more, and preferably 2% by mass or less, more preferably 1.5% by mass or less, even more preferably 1.2% by mass or less, in terms of cleaning performance and foaming.
  • the cleaning composition of the present invention may optionally contain, as the component (G), a polyalkylene glycol having a weight average molecular weight of 100 or more and 100,000 or less.
  • the component (G) may be one or more selected from polyethylene glycol and polypropylene glycol.
  • the weight average molecular weight of component (G) is 100 or more, preferably 1,000 or more, more preferably 5,000 or more, and 100,000 or less, preferably 30,000 or less, more preferably 20,000 or less, and even more preferably 15,000 or less.
  • the weight average molecular weight herein is a value determined by gel permeation chromatography using polystyrene as a standard substance.
  • the cleaning composition of the present invention contains component (G), from the viewpoint of stability, contains component (G) in an amount of preferably 0.001% by mass or more, more preferably 0.01% by mass or more, even more preferably 0.1% by mass or more, still more preferably 0.2% by mass or more, and preferably 5% by mass or less, more preferably 4% by mass or less, even more preferably 3% by mass or less, still more preferably 2% by mass or less, and still more preferably 1% by mass or less.
  • the cleaning composition of the present invention may optionally contain, as component (H), one or more enzymes selected from proteases, lipases and amylases.
  • Proteases include, for example, serine proteases (EC 3.4.21) and metalloproteases (EC 3.4.17 or EC 3.4.24).
  • suitable proteases include neutral or alkaline serine proteases such as subtilisin (EC 3.4.21.62).
  • lipases examples include triacylglycerol lipase (EC 3.1.1.3), phospholipase A2 (EC 3.1.1.4), lysophospholipase (EC 3.1.1.5), monoglyceride lipase (EC 3.1.1.23), galactolipase (EC 3.1.1.26), phospholipase A1 (EC 3.1.1.32), and lipoprotein lipase (EC 3.1.1.34).
  • amylases examples include ⁇ -amylase (EC 3.2.1.1), ⁇ -amylase (EC 3.2.1.2) and/or glucoamylase (EC 3.2.1.3), etc.
  • Suitable examples of amylases include neutral or alkaline ⁇ -amylases, preferably of microbial origin, such as bacteria or fungi.
  • the detergent composition of the present invention contains component (H)
  • the detergent composition of the present invention contains component (H) in an amount, in terms of cleaning performance, of preferably 0.002 mass % or more, more preferably 0.004 mass % or more, even more preferably 0.008 mass % or more, and preferably 0.12 mass % or less, more preferably 0.1 mass % or less, even more preferably 0.08 mass % or less, and still more preferably 0.04 mass % or less, in terms of the amount of enzyme protein in the detergent composition.
  • the mass of the component (H) is calculated as the amount of enzyme protein.
  • the enzyme protein can be quantified, for example, using a protein assay kit, Lowry kit, manufactured by Nacalai Tesque, Inc., in accordance with the instruction manual.
  • the cleaning composition of the present invention may optionally contain (I) a chelating agent (hereinafter referred to as "component (I)").
  • component (I) include aminopolyacetic acids such as ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, and hydroxyethyliminodiacetic acid, or salts thereof; organic acids such as citric acid, lactic acid, tartaric acid, and malic acid, or salts thereof; 1-hydroxyethylidene-1,1-diphosphonic acid, diethylenetriaminepenta(methylenephosphonic acid), and alkali metal or lower amine salts thereof; and these can be used in combination with one or more of them.
  • salts of component (I) include alkali metal salts such as sodium salts and potassium salts, and salts with lower amines such as monoethanolamine, diethanolamine and triethanolamine.
  • the detergent composition of the present invention contains component (I)
  • the detergent composition of the present invention contains component (I) in an amount of preferably 0.5% by mass or more, more preferably 1.0% by mass or more, and even more preferably 2.0% by mass or more in terms of cleaning performance, and preferably 10% by mass or less, more preferably 8% by mass or less, and even more preferably 6% by mass or less in terms of formulation.
  • the cleaning composition of the present invention may contain water.
  • water examples include ion-exchanged water, purified water, and distilled water. Water is used as the remainder other than components (A) to (I) and any optional components. Water also includes water used to add the components of the cleaning composition.
  • the cleaning composition of the present invention may optionally contain other components known in the field of laundry detergents, such as bleaching agents (such as bleach activators), anti-redeposition agents, organic reducing agents, fluorescent brightening agents, foam inhibitors (such as silicones), organic solvents, fragrances, colorants, antibacterial agents (such as triclosan), etc. (excluding those that fall under components (A) to (I)).
  • the cleaning composition of the present invention may be a solid cleaning composition.
  • the cleaning composition of the present invention may be in the form of a tablet, powder, granule, granules, or paste. From the viewpoint of solubility, the cleaning composition of the present invention is preferably a cleaning composition selected from a tablet, powder, granule, granule, and paste, and more preferably a cleaning composition selected from a tablet, powder, and paste.
  • the cleaning composition of the present invention may be a powder cleaning composition.
  • the cleaning composition of the present invention can be produced by a known method.
  • it can be produced by applying a spray drying method, a dry neutralization method, a dry granulation method, a dry blend method, a fluidized bed drying method, a thin film drying method, an extrusion granulation method, a rolling granulation method, a stirring granulation method, a compaction granulation method, a surfactant carrying method, or a combination of methods selected from these.
  • the bulk density of the cleaning composition of the present invention will vary depending on the production method, but is preferably 0.2 g/ cm3 or more, more preferably 0.3 g/ cm3 or more, even more preferably 0.35 g/ cm3 or more, and is preferably 1 g/ cm3 or less, more preferably 0.95 g/ cm3 or less, even more preferably 0.9 g/ cm3 or less.
  • the average particle size of the cleaning composition of the present invention is preferably 100 ⁇ m or more, more preferably 150 ⁇ m or more, even more preferably 200 ⁇ m or more, and preferably 800 ⁇ m or less, more preferably 750 ⁇ m or less, even more preferably 700 ⁇ m or less.
  • This average particle size is determined by vibrating a standard sieve according to JIS Z 8801 for 5 minutes and then calculating the mass fraction based on the size of the sieve openings.
  • the present invention provides a cleaning agent article comprising the cleaning agent composition of the present invention and a water-soluble film for packaging the cleaning agent composition.
  • the present invention provides a cleaning agent article comprising the cleaning agent composition of the present invention and a water-soluble film, in which the cleaning agent composition is packaged in the water-soluble film.
  • the cleaning article of the present invention may be a cleaning article comprising the cleaning composition of the present invention packaged in a water-soluble film. That is, the cleaning composition of the present invention may be a cleaning composition packaged in a water-soluble film.
  • water-soluble refers to a water-soluble film in which 500 g of 30° C. ion-exchanged water is placed in a 1-liter glass beaker, a Teflon (registered trademark) stirrer having a diameter of 8 cm is placed in the beaker, 1 g of the film to be evaluated is placed in the beaker, and the film is stirred at 100 rpm for 30 minutes, after which no insoluble matter is apparent.
  • Teflon registered trademark
  • the thickness of the water-soluble film is preferably 1 ⁇ m or more, more preferably 10 ⁇ m or more, even more preferably 50 ⁇ m or more, and preferably 200 ⁇ m or less, more preferably 150 ⁇ m or less, even more preferably 100 ⁇ m or less.
  • the water-soluble film is preferably composed of a polymer.
  • the water-soluble film can be obtained by methods known in the art, such as casting, blow molding, extrusion, injection molding of polymers, etc.
  • Non-limiting examples of polymers for producing water-soluble films include polyvinyl alcohol (PVA), vinyl alcohol copolymers, polyvinylpyrrolidone, polyalkylene oxides, (modified) cellulose, (modified) cellulose-ethers or -esters or -amides, polycarboxylic acids and their salts such as polyacrylates, maleic acid/acrylic acid copolymers, polyamino acids or peptides, polyamides such as polyacrylamides, polysaccharides such as starch and gelatin, natural gums such as xanthan and carragum.
  • PVA polyvinyl alcohol
  • vinyl alcohol copolymers polyvinylpyrrolidone
  • polyalkylene oxides polyalkylene oxides
  • Vinyl alcohol copolymers are copolymers of vinyl alcohol with other monomers, such as ethylene, acrylic acid.
  • the water-soluble film comprises a polymer selected from the group consisting of polyacrylates and water-soluble acrylates, methylcellulose, sodium carboxymethylcellulose, dextrin, ethylcellulose, hydroxyethylcellulose, maltodextrin, polymethacrylates, polyvinyl alcohol, vinyl alcohol copolymers, hydroxypropylmethylcellulose (HPMC), and combinations thereof.
  • the water-soluble film comprises a polymer selected from polyvinyl alcohol, vinyl alcohol copolymers, and hydroxypropylmethylcellulose.
  • the water-soluble film comprises polyvinyl alcohol, for example, Solvron available from Aicello Co., Ltd. Suitable polymers for producing water-soluble films are described, for example, in U.S. Pat. No. 6,995,126.
  • the total area of the water-soluble film in contact with the detergent composition of the present invention is, from the viewpoint of further enhancing product stability, preferably 10 cm2 or more, more preferably 20 cm2 or more, even more preferably 30 cm2 or more, and still more preferably 40 cm2 or more, and from the same viewpoint, preferably 100 cm2 or less, more preferably 70 cm2 or less, even more preferably 60 cm2 or less, and still more preferably 45 cm2 or less.
  • the cleaning articles of the present invention can be made by any suitable process known in the art, such as known detergent pouch making processes. Exemplary pouch making processes are described in U.S. Patent Nos. 6,995,126, 7,127,874, 8,156,713, 7,386,971, 7,439,215, and U.S. Patent Application Publication No. 2009/199877.
  • the amount of contents per cleaning article of the present invention is preferably 5 g or more, more preferably 8 g or more, even more preferably 10 g or more, and preferably 50 g or less, more preferably 30 g or less, even more preferably 25 g or less.
  • each of the cleaning articles of the present invention is, for example, a quadrilateral, with the length of one side preferably being 1 cm or more and 5 cm or less, and the thickness preferably being 1 cm or more and 5 cm or less, more preferably being 1 cm or more and 4 cm or less.
  • the mass of each of the cleaning articles of the present invention is preferably 5 g or more, more preferably 10 g or more, even more preferably 15 g or more, and preferably 50 g or less, more preferably 40 g or less, even more preferably 30 g or less.
  • each of the cleaning articles of the present invention is, for example, a rectangular parallelepiped shape, with a vertical length of preferably 5 cm to 20 cm, a horizontal length of preferably 1 cm to 4 cm, and a thickness of preferably 1 cm to 5 cm, more preferably 1 cm to 4 cm.
  • the mass of each of the cleaning articles of the present invention is preferably 5 g or more, more preferably 10 g or more, and preferably 50 g or less, more preferably 40 g or less, even more preferably 30 g or less, even more preferably 20 g or less.
  • the detergent article of the present invention may be, for example, a detergent article in which the detergent composition of the present invention is packaged in a water-soluble film, the major axis diameter of the maximum projected area of the detergent article is 30 mm or more and 200 mm or less, the aspect ratio between the major axis diameter and the minor axis diameter perpendicular to the major axis diameter (major axis diameter/minor axis diameter) is 5 or more, and the burst strength is 300 N or more.
  • the detergent article of the present invention may be a detergent article consisting of the detergent composition of the present invention and a water-soluble film, the detergent composition is packaged in the water-soluble film, the major axis diameter of the maximum projected area of the detergent article is 30 mm or more and 200 mm or less, the aspect ratio between the major axis diameter and the minor axis diameter perpendicular to the major axis diameter (major axis diameter/minor axis diameter) is 5 or more, and the burst strength is 300 N or more.
  • the aspect ratio (major axis diameter/minor axis diameter) of the major axis diameter of the maximum projected area of the detergent article of the present invention to the minor axis diameter perpendicular to the major axis diameter is preferably 5 or more, more preferably 6 or more, even more preferably 7 or more, and still more preferably 8 or more, from the viewpoint of suppressing a decrease in detergency, and is preferably 20 or less, more preferably 16 or less, even more preferably 13 or less, and still more preferably 10 or less, from the viewpoints of ease of use and storage.
  • the major axis diameter of the maximum projected area of the cleaning article of the present invention is preferably 30 mm or more, more preferably 50 mm or more, even more preferably 80 mm or more, and preferably 200 mm or less, more preferably 160 mm or less, even more preferably 120 mm or less.
  • the minor axis diameter of the maximum projected area of the cleaning article of the present invention is preferably 5 mm or more, more preferably 10 mm or more, even more preferably 12 mm or more, still more preferably 14 mm or more, and is preferably 25 mm or less, more preferably 23 mm or less, and even more preferably 20 mm or less.
  • the maximum projected area is the area of the projection that has the maximum horizontal projected area when the cleaning article is projected horizontally from all sides.
  • "Projection” is the same as “projection” used in mathematics, that is, it means projecting a parallel light beam horizontally onto an object and projecting the shadow onto a flat surface.
  • the method for measuring the major axis diameter and minor axis diameter of the maximum projected area of the detergent article is as follows: when the shape of the maximum projected area of the detergent article is elliptical, the major axis diameter and minor axis diameter are measured as they are.
  • the maximum projected area of the cleaning article includes the water-soluble film that packages the cleaning composition, and also includes overlapping portions of the water-soluble films, such as sealed portions.
  • the ratio of the contact area of the water-soluble film with the detergent composition to the total area of the surface facing the other water-soluble film per water-soluble film is preferably 60% or more, more preferably 70% or more, even more preferably 80% or more, even more preferably 90% or more, and less than 100%.
  • the contact area of the water-soluble film with the detergent composition may be the area of the water-soluble film surface that forms the space for accommodating the detergent composition.
  • the detergent article may have an end of a water-soluble film packaging a detergent composition connected in a detachable manner to an end of a water-soluble film packaging another detergent composition.
  • the aspect ratio (long axis diameter/short axis diameter) between the major axis diameter of the maximum projected area of the detergent article and the minor axis diameter perpendicular to the major axis diameter is measured based on the calculated maximum projected area by calculating the maximum projected area of the detergent article for each water-soluble film packaging a detergent composition.
  • the aspect ratio is measured by cutting off the connected portion of the water-soluble film packaging the detergent composition.
  • a line dividing each packaged detergent composition into equal parts can be regarded as the connected portion.
  • the cleaning composition and cleaning article of the present invention can be suitably used for textile products, for hard surfaces such as tableware, or for automatic dishwashers, and is preferably used for textile products.
  • the fiber to be cleaned may be either a hydrophobic fiber or a hydrophilic fiber.
  • hydrophobic fibers include protein fibers (milk protein casein fiber, promix, etc.), polyamide fibers (nylon, etc.), polyester fibers (polyester, etc.), polyacrylonitrile fibers (acrylic, etc.), polyvinyl alcohol fibers (vinylon, etc.), polyvinyl chloride fibers (polyvinyl chloride, etc.), polyvinylidene chloride fibers (vinylidene, etc.), polyolefin fibers (polyethylene, polypropylene, etc.), polyurethane fibers (polyurethane, etc.), polyvinyl chloride/polyvinyl alcohol copolymer fibers (polycral, etc.), polyalkylene paraoxybenzoate fibers (benzoate, etc.), polyfluoroethylene fibers (polytetrafluoroethylene
  • hydrophilic fibers examples include seed hair fibers (cotton, kapok, etc.), bast fibers (hemp, flax, ramie, hemp, jute, etc.), leaf vein fibers (Manila hemp, sisal, etc.), palm fibers, rush, straw, animal hair fibers (wool, mohair, cashmere, camel hair, alpaca, vicuna, angora, etc.), silk fibers (domestic silk, wild silk), feathers, and cellulosic fibers (rayon, polynosic, cupra, acetate, etc.). From the viewpoint of finishing quality, the fiber is preferably a fiber containing cotton fiber.
  • the content of cotton fiber in the fiber is preferably 5% by mass or more, more preferably 10% by mass or more, even more preferably 15% by mass or more, still more preferably 20% by mass or more, still more preferably 40% by mass or more, still more preferably 60% by mass or more, still more preferably 80% by mass or more, and preferably 100% by mass or less, and may be 100% by mass.
  • textile products refer to fabrics such as woven fabrics, knitted fabrics, and nonwoven fabrics that use the hydrophobic and hydrophilic fibers described above, and products obtained using them, such as undershirts, T-shirts, dress shirts, blouses, slacks, hats, handkerchiefs, towels, knitwear, socks, underwear, and tights.
  • the present invention provides a method for cleaning textile products, in which textile products are cleaned with a cleaning liquid obtained by mixing the cleaning composition of the present invention with water (hereinafter referred to as the cleaning liquid of the present invention).
  • the cleaning composition of the present invention can be used in the form of a cleaning article obtained by packaging the cleaning composition of the present invention in a water-soluble film. That is, the present invention provides a method for cleaning textile products, in which textile products are cleaned with a cleaning liquid obtained by mixing the cleaning article of the present invention with water (hereinafter referred to as the cleaning liquid of the present invention as above).
  • the embodiments described in relation to the detergent composition of the present invention and the detergent article of the present invention can be appropriately applied.
  • the detergent composition of the present invention and water may be charged into a washing tank in advance and mixed to prepare the cleaning liquid of the present invention, and then the textile product to be washed is charged therein to wash the textile product.
  • a method is preferred in which the detergent composition of the present invention, water and the textile product are charged into a washing tank, and the detergent composition of the present invention is dissolved in the water while the cleaning liquid of the present invention is prepared and the textile product is washed at the same time.
  • the detergent article of the present invention can be used in the method for cleaning textile products of the present invention. In that case, the cleaning liquid can be prepared in the above-mentioned method by substituting the detergent composition of the present invention for the detergent article of the present invention.
  • the amount of water used when mixing the cleaning composition of the present invention with water is adjusted so that the total amount of the cleaning composition of the present invention is preferably 0.01 g or more, more preferably 0.1 g or more, even more preferably 0.3 g or more, and preferably 10 g or less, more preferably 1 g or less, even more preferably 0.5 g or less per 1 L of water, from the viewpoints of environmental consideration and cleaning performance.
  • the cleaning solution of the present invention contains component (A) in an amount of preferably 15 ppm or more, more preferably 30 ppm or more, and even more preferably 45 ppm or more in terms of cleaning performance, and preferably 300 ppm or less, more preferably 250 ppm or less, and even more preferably 200 ppm or less in terms of rinsing.
  • the cleaning solution of the present invention contains component (B) in an amount of preferably 50 ppm or more, more preferably 100 ppm or more, and even more preferably 150 ppm or more in terms of cleaning performance, and preferably 800 ppm or less, more preferably 700 ppm or less, and even more preferably 600 ppm or less in terms of the residue in cold water.
  • the cleaning solution of the present invention contains component (C) in an amount of preferably 30 ppm or more, more preferably 60 ppm or more, and even more preferably 100 ppm or more in terms of preventing residual dissolution, and preferably 160 ppm or less, more preferably 150 ppm or less, and even more preferably 140 ppm or less in terms of preventing streaking.
  • the cleaning solution of the present invention contains component (D) in an amount of preferably 3 ppm or more, more preferably 5 ppm or more, even more preferably 8 ppm or more, and for example, 50 ppm or less, in terms of antibacterial performance.
  • the cleaning solution of the present invention contains component (E) in an amount of preferably 5 ppm or more, more preferably 10 ppm or more, even more preferably 15 ppm or more, and, for example, 100 ppm or less, in terms of cleaning performance against particulate soiling.
  • the cleaning solution of the present invention contains component (F)
  • the cleaning solution contains component (F) in an amount of preferably 0.5 ppm or more, more preferably 1.0 ppm or more, and even more preferably 1.5 ppm or more in terms of cleaning performance and foaming performance, and preferably 20 ppm or less, more preferably 18 ppm or less, and even more preferably 16 ppm or less in terms of rinsing performance.
  • the cleaning solution of the present invention contains component (G), from the viewpoints of stability and dispersibility of hydrophobic particles, the cleaning solution contains component (G) preferably at 0.5 ppm or more, more preferably at 1 ppm or more, even more preferably at 1.5 ppm or more, and for example, at 50 ppm or less.
  • the amount of component (H) in the cleaning solution is preferably 0.02 ppm or more, more preferably 0.04 ppm or more, and even more preferably 0.06 ppm or more in terms of the cleaning performance, and is preferably 1.2 ppm or less, more preferably 1.0 ppm or less, and even more preferably 0.80 ppm or less in terms of skin irritation.
  • the cleaning solution of the present invention contains component (I), from the viewpoint of cleaning performance, the cleaning solution contains component (I) preferably at 1 ppm or more, more preferably at 2.5 ppm or more, even more preferably at 5 ppm or more, and for example, at 100 ppm or less.
  • the bath ratio which is the ratio of the mass of the textile product (kg) to the amount of water in the cleaning solution (liters), i.e., the amount of water in the cleaning solution (liters) / mass of the textile product (kg) (hereinafter, this ratio may be referred to as the bath ratio).
  • the bath ratio When using a domestic washing machine, if the bath ratio becomes small, the textile products may rub against each other more strongly due to agitation during washing, which may impair the finish of the textile product.
  • the bath ratio is preferably 5 or more, more preferably 10 or more, and even more preferably 20 or more, and from the viewpoint of washing efficiency, it is preferably 100 or less, more preferably 50 or less, and even more preferably 30 or less.
  • the method for washing textile products of the present invention is suitable for a rotary washing method, a method in which the textile products are immersed in a liquid used for scouring while being fed with a roller or the like.
  • the rotary washing method refers to a washing method in which a textile product that is not fixed to a rotating device rotates around a rotating shaft together with the washing liquid.
  • the rotary washing method can be carried out by a rotary washing machine. Therefore, in the present invention, in order to give the textile products a neater finish, it is preferable to wash the textile products using a rotary washing machine.
  • Specific examples of rotary washing machines include drum washing machines, pulsator washing machines, and agitator washing machines. For these rotary washing machines, those commercially available for home use can be used.
  • the present invention discloses the following aspects.
  • the composition contains the following component (A) in an amount of 5% by mass or more and 40% by mass or less, the following component (B) in an amount of 20% by mass or more and 80% by mass or less, the following component (C) in an amount of 5% by mass or more and 40% by mass or less, the following component (D) in an amount of 0.1% by mass or more and 5.0% by mass or less, and the following component (E) in an amount of 0.1% by mass or more and 10% by mass or less, a mass ratio (a2)/[(a1)+(a2)] of the content of the (a2) component to the total content of the (a1) component and the (a2) component is 0 or more and 0.5 or less; a mass ratio (b2)/[(b1)+(b2)] of the content of the (b2) component to the total content of the (b1) component and the (b2) component is 0.2 or more and 0.8 or less; a mass ratio (C)/[(B)+(C)] of the content of the (C)
  • R 1a is an aliphatic hydrocarbon group having 8 or more carbon atoms, preferably 10 or more, more preferably 12 or more, and 18 or less, preferably 16 or less, more preferably 14 or less, preferably a group selected from an alkyl group and an alkenyl group
  • R 2a is a hydrogen atom or a methyl group, preferably a hydrogen atom.
  • CO is a carbonyl group
  • m is a number of 0 or 1, preferably 0.
  • a 1a O group is one or more selected from alkyleneoxy groups having 2 to 4 carbon atoms, preferably one or more selected from alkyleneoxy groups having 2 to 3 carbon atoms, more preferably an ethyleneoxy group.
  • n is the average number of moles added of A 1a O group, and is a number of 1 or more, preferably 6 or more, more preferably 8 or more, and 30 or less, preferably 25 or less, more preferably 20 or less, and even more preferably 15 or less.
  • the component (a2) is one or more compounds selected from a compound represented by the following general formula (a2-1) (hereinafter referred to as the component (a2-1)), a compound represented by general formula (a2-2) (hereinafter referred to as the component (a2-2)), a compound represented by general formula (a2-3) (hereinafter referred to as the component (a2-3)), and a compound represented by general formula (a2-4) (hereinafter referred to as the component (a2-4)), preferably one or more compounds selected from the component (a2-1), the component (a2-2), and the component (a2-3), and more preferably one or more compounds selected from the component (a2-1) and the component (a2-2).
  • a2-1 compound represented by the following general formula (a2-1)
  • a compound represented by general formula (a2-2) hereinafter referred to as the component (a2-2)
  • a compound represented by general formula (a2-3) hereinafter referred to as the component (a2-3)
  • a compound represented by general formula (a2-4) hereinafter
  • R 3a -B-SO 3 M (a2-1) [In formula (a2-1), R 3a represents an alkyl group having 9 or more, preferably 10 or more, and preferably 14 or less, more preferably 13 or less carbon atoms; B represents a benzene ring; the carbon atom of R 3a bonded to the carbon atom of B is a secondary carbon atom; M represents a cation, preferably an alkali metal ion such as a sodium ion or a potassium ion, or an alkanol ammonium ion such as a monoethanol ammonium ion or a diethanol ammonium ion, more preferably a sodium ion.
  • R 3a represents an alkyl group having 9 or more, preferably 10 or more, and preferably 14 or less, more preferably 13 or less carbon atoms
  • B represents a benzene ring
  • the carbon atom of R 3a bonded to the carbon atom of B is a secondary carbon atom
  • R 4a represents an alkyl or alkenyl group having 10 or more, preferably 11 or more, and 18 or less, preferably 16 or less, more preferably 14 or less, and even more preferably 13 or less carbon atoms, preferably one or more groups selected from a linear alkyl group, a branched alkyl group, a linear alkenyl group, and a branched alkenyl group, more preferably a linear alkyl group
  • M represents a cation, preferably an alkali metal ion such as a sodium ion or a potassium ion, or an alkanol ammonium ion such as a monoethanol ammonium ion or a diethanol ammonium ion, more preferably a sodium ion.
  • ⁇ 4> The cleaning composition according to any one of the above ⁇ 1> to ⁇ 3>, wherein the component (b1) is preferably one or more selected from alkali metal carbonates, more preferably one or more selected from sodium carbonate and potassium carbonate, and even more preferably sodium carbonate.
  • the component (b2) is one or more compounds selected from inorganic sulfates, inorganic halogen compounds, and alkali metal bicarbonates, and is preferably a water-soluble inorganic salt containing one or more compounds selected from inorganic sulfates and alkali metal bicarbonates.
  • ⁇ 6> The cleaning composition according to any one of ⁇ 1> to ⁇ 4> above, wherein the component (b2) is one or more compounds selected from sodium sulfate, magnesium sulfate, aluminum sulfate, potassium sulfate, sodium chloride, potassium chloride, calcium chloride, magnesium chloride, sodium hydrogen carbonate, and potassium hydrogen carbonate.
  • the component (b2) is one or more compounds selected from sodium sulfate, magnesium sulfate, aluminum sulfate, potassium sulfate, sodium chloride, potassium chloride, calcium chloride, magnesium chloride, sodium hydrogen carbonate, and potassium hydrogen carbonate.
  • ⁇ 7> The cleaning composition according to any one of the above ⁇ 1> to ⁇ 6>, wherein the component (C) is one or more selected from amorphous silica, calcium silicate, clay minerals, crystalline aluminosilicates, and amorphous aluminosilicates, preferably one or more selected from clay minerals, and crystalline aluminosilicates.
  • the component (C) is one or more selected from amorphous silica, calcium silicate, clay minerals, crystalline aluminosilicates, and amorphous aluminosilicates, preferably one or more selected from clay minerals, and crystalline aluminosilicates.
  • R 1d is an aliphatic hydrocarbon group having 8 or more, preferably 9 or more, more preferably 10 or more, even more preferably 12 or more, and 18 or less, preferably 16 or less, preferably an alkyl or alkenyl group, more preferably an alkyl group;
  • R 2d is a group selected from an aliphatic hydrocarbon group having 8 to 18 carbon atoms, an alkyl group having 1 to 3 carbon atoms, and a hydroxyalkyl group having 1 to 3 carbon atoms;
  • R 3d and R 4d are each independently a group selected from an alkyl group having 1 to 3 carbon atoms and a hydroxyalkyl group having 1 to 3 carbon atoms, preferably a group selected from an alkyl group having 1 to 3 carbon atoms;
  • X ⁇ is an anion, preferably one or more anions selected from a halogen ion and an alkyl sulfate ion having 1 to 3 carbon atoms.
  • R 5d is an aliphatic hydrocarbon group having 8 or more, preferably 10 or more, more preferably 12 or more, and 18 or less, preferably 16 or less, preferably an alkyl or alkenyl group, more preferably an alkyl group
  • R 6d and R 7d are each independently a group selected from an alkyl group having 1 to 3 carbon atoms and a hydroxyalkyl group having 1 to 3 carbon atoms, preferably a group selected from an alkyl group having 1 to 3 carbon atoms
  • X ⁇ is an anion, preferably one or more anions selected from a halogen ion and an alkyl sulfate ion having 1 to 3 carbon atoms.
  • ⁇ 9> The cleaning composition according to any one of ⁇ 1> to ⁇ 8> above, wherein the component (D) is at least one selected from the group consisting of benzalkonium chloride and alkyltrimethylammonium chloride.
  • the component (E) is a polymer having a carboxylic acid group or a salt thereof and having a weight-average molecular weight of 3,000 or more, preferably one or more polymers selected from polyacrylic acid and salts thereof, copolymers of acrylic acid and maleic acid and salts thereof, and polymaleic acid and salts thereof, and has a weight-average molecular weight of preferably 3,000 or more, more preferably 3,500 or more, even more preferably 4,000 or more, still more preferably 5,000 or more, still more preferably 6,000 or more, still more preferably 7,000 or more, still more preferably 8,000 or more, still more preferably 9,000 or more, still more preferably 10,000 or more, and preferably 100,000 or less, more preferably 50,000 or less, still more preferably 25,000 or less, and still more preferably 15,000 or less.
  • the cleaning composition contains the component (A) in an amount of 5 mass% or more, preferably 7 mass% or more, more preferably 9 mass% or more, even more preferably 11 mass% or more, and 40 mass% or less, preferably 30 mass% or less, more preferably 25 mass% or less, even more preferably 20 mass% or less.
  • a mass ratio (a2)/[(a1)+(a2)] of the content of the component (a2) to the total content of the components (a1) and (a2) in the cleaning composition is 0 or more, preferably 0.05 or more, more preferably 0.10 or more, even more preferably 0.15 or more, and is 0.5 or less, preferably 0.45 or less, more preferably 0.40 or less, even more preferably 0.35 or less.
  • the cleaning agent composition according to any one of ⁇ 1> to ⁇ 12> above, wherein the cleaning agent composition contains the component (B) in an amount of 20 mass% or more, preferably 25 mass% or more, more preferably 30 mass% or more, even more preferably 40 mass% or more, and 80 mass% or less, preferably 70 mass% or less, more preferably 65 mass% or less, even more preferably 60 mass% or less, and still more preferably 55 mass% or less.
  • a mass ratio (b2)/[(b1)+(b2)] of the content of the component (b2) to the total content of the component (b1) and the component (b2) in the cleaning composition is 0.2 or more, preferably 0.30 or more, more preferably 0.35 or more, even more preferably 0.40 or more, and is 0.8 or less, preferably 0.7 or less, more preferably 0.65 or less, even more preferably 0.60 or less, still more preferably 0.55 or less, and still more preferably 0.50 or less.
  • the cleaning agent composition according to any one of ⁇ 1> to ⁇ 14> above, wherein the cleaning agent composition contains the component (C) in an amount of 5 mass% or more, preferably 10 mass% or more, more preferably 15 mass% or more, even more preferably 20 mass% or more, still more preferably 25 mass% or more, and 40 mass% or less, preferably 35 mass% or less, more preferably 32.5 mass% or less, and even more preferably 30 mass% or less.
  • a mass ratio (C)/[(B)+(C)] of the content of the component (C) to the total content of the component (B) and the component (C) in the cleaning composition exceeds 0, and is preferably 0.05 or more, more preferably 0.1 or more, even more preferably 0.15 or more, still more preferably 0.20 or more, still more preferably 0.25 or more, still more preferably 0.30 or more, and is 0.50 or less, preferably 0.45 or less, more preferably 0.40 or less, and even more preferably 0.38 or less.
  • the cleaning agent composition according to any one of ⁇ 1> to ⁇ 16>, wherein the cleaning agent composition contains the component (D) in an amount of 0.1 mass% or more, preferably 0.5 mass% or more, more preferably 0.7 mass% or more, even more preferably 1.0 mass% or more, still more preferably 2.0 mass% or more, and 5.0 mass% or less, further 4.0 mass% or less, further 3.5 mass% or less, and further 3.0 mass% or less.
  • the cleaning agent composition contains the component (E) in an amount of 0.1 mass% or more, preferably 1.0 mass% or more, more preferably 2.0 mass% or more, even more preferably 3.0 mass% or more, still more preferably 4.0 mass% or more, and 10 mass% or less, preferably 8.0 mass% or less, more preferably 6.0 mass% or less, and even more preferably 5.0 mass% or less.
  • a ratio of the content of the component (A) to the total content of surfactants contained in the cleaning agent composition, (A)/(total content of surfactants), is preferably 50 mass% or more, more preferably 60 mass% or more, even more preferably 70 mass% or more, still more preferably 80 mass% or more, and is preferably 98 mass% or less, more preferably 96 mass% or less, and even more preferably 94 mass% or less.
  • the cleaning agent composition according to any one of ⁇ 1> to ⁇ 20> above which is for textile products, for hard surfaces, or for automatic dishwashing machines, preferably for textile products.
  • a cleaning agent article comprising the cleaning agent composition according to any one of ⁇ 1> to ⁇ 21> above and a water-soluble film, wherein the cleaning agent composition is packaged in the water-soluble film.
  • a method for cleaning textile products comprising washing the textile products with a cleaning liquid obtained by mixing the detergent composition according to any one of ⁇ 1> to ⁇ 21> above with water.
  • a method for cleaning textile products comprising cleaning the textile products with a cleaning liquid obtained by mixing the detergent article according to ⁇ 22> with water.
  • Component (B)> [Component (b1)] Sodium carbonate: light ash, bulk density 600 g/L, average particle size 100 ⁇ m, manufactured by Central Glass Co., Ltd. [component (b2)] Sodium sulfate: anhydrous neutral Glauber's salt, manufactured by Shikoku Kasei Co., Ltd. Sodium chloride: Nacl N, manufactured by Nankai Salt Industry Co., Ltd.
  • the cleaning compositions shown in Table 1 were prepared by the following method. Sodium sulfate, 110 kg of sodium carbonate, 40% sodium polyacrylate, sodium chloride, and 93 kg of zeolite were mixed in a mixing tank to prepare a slurry. The slurry was pumped into a spray-drying tower (countercurrent type), and the slurry was sprayed from a pressure spray nozzle installed near the top of the tower to obtain spray-dried particles.
  • Example 1-3 dry neutralization using component (a2) was not carried out, and alkyl sulfate granules were finally mixed with the enzyme and flavor in a blend.
  • the mass% of the blended components other than component (H) are all values based on the active ingredient, and the blended amount (mass%) of component (H) is shown as a solid form.
  • the blended amount (mass%) of component (a2) in the table is shown after dry neutralization, i.e., as a sodium salt.
  • A Model sebum soil (used in amounts such that the mass percentages in the artificial soil were 0.44 mass% lauric acid, 3.15 mass% myristic acid, 2.35 mass% pentadecanoic acid, 6.31 mass% palmitic acid, 0.44 mass% heptadecanoic acid, 1.60 mass% stearic acid, 7.91 mass% oleic acid, 2.22 mass% n-hexadecyl palmitate, and 6.66 mass% squalene)
  • B Hard water obtained by weighing out 105 mg of calcium chloride dihydrate and dissolving it in distilled water to make 1,000 mL.
  • E Egg white lecithin liquid crystals 1.98% by mass (egg white lecithin liquid crystals obtained by dissolving 11.37 g of arginine hydrochloride, 4.20 g of histidine, and 2.44 g of serine in 80 mL of distilled water, adjusting the pH to 5.0 with concentrated hydrochloric acid, and then thoroughly mixing this solution with egg white lecithin in a mixer).
  • D Kanuma red soil 8.11% by mass
  • E 0.025% by mass of carbon black
  • the specific washing conditions were as follows: four pieces of artificially soiled cloth and 0.30 g of each detergent composition shown in Table 1 were placed in the tergotometer, 600 mL of water was poured in, and a washing solution was prepared while dissolving the detergent composition in water, and at the same time, the artificially soiled cloth was washed at 100 rpm for 10 minutes.
  • the water temperature of each washing solution was 20° C.
  • the stained cloth was rinsed with city water (20° C.) for 1 minute, and then dehydrated for 3 minutes using a two-layer washing machine, and then left to dry for 5 hours under conditions of 20° C. and 50% RH.
  • the cleaning rate (%) was calculated based on the following formula (1) and the average value of the four pieces was calculated.
  • a detergent composition rated as "0" in the evaluation of foam remaining is a cleaning composition with excellent rinsing properties.
  • Evaluation index of remaining foam 0 The remaining amount of foam is less than 1/4 of the washing tub 1: The remaining amount of foam is 1/4 or more of the washing tub
  • Turbidity evaluation index 0 The letters attached to the bottom of the tub were recognizable. 1: The letters attached to the bottom of the tub could not be recognized.
  • Antibacterial Test Method Preparation of Fabric for Antibacterial Test 30 g of cotton fabric (cotton #2003, Tanigashira Shoten Co., Ltd.) and 600 mL of cleaning solution containing 0.3 g of each detergent composition listed in Table 1 were placed in a tergotometer, and the fabric was washed at 85 rpm for 10 minutes and rinsed for 3 minutes for a total of five cycles to prepare a test fabric. Boiled and sterilized tap water was used for all water.
  • Antibacterial Test Using Moraxella osloensis isolated from worn clothing, an antibacterial test was carried out in accordance with JIS L 1902. Specifically, the test was carried out as follows.
  • test cloth prepared by the method in (1) above was cut into test pieces of 2 cm square (each piece had a mass of approximately 0.4 g) to be used as specimens.
  • Moraxella osloensis isolated from worn clothing was streaked on a plate with SCD-LP agar medium, and the resulting cultured specimen was scraped off with a platinum loop and placed in 10 mL of nutrient (NT) medium and pre-cultured for 24 hours at 37°C and 110 rpm.
  • the concentration of the pre-cultured culture solution was estimated by spectrophotometry, and the bacterial concentration was adjusted to about 1 x 10 8 cells/mL.
  • test bacteria liquid was taken with a pipette, and each specimen or untreated standard cloth (JIS L 1902 standard cloth) was contacted with the liquid at several points, placed in a vial, and cultured at 37° C. for 18 hours with the lid closed. Inoculation with the test bacteria liquid and culture were performed multiple times for each of the specimens and standard cloth.
  • Bacteriostatic activity value Log B - Log C A: The average number of bacteria recovered from the control cloth immediately after inoculation. B: The average number of bacteria recovered from the control cloth after 18 hours of culture. C: The average number of bacteria recovered from the specimen after 18 hours of culture. However, this must satisfy the test validity condition, that is, Log B - Log A must exceed 1.5.
  • the residual dissolution property of each of the cleaning compositions of the Examples and Comparative Examples in Table 1 was evaluated based on the presence or absence of streaks on the cleaned object and the diameter of the residual dissolution property of the cleaning composition that remained after cleaning.
  • the residual dissolution property was evaluated by the following method. 40 g of each detergent composition in Table 1 was placed on a black cotton cloth (black dyed cotton broadcloth 40, purchased from Tanigashira Shoten) cut to 15 cm x 15 cm, and the detergent composition was wrapped around the cloth and woven.
  • the following is an example of a detergent article including the detergent composition of the present invention and a water-soluble film for packaging the detergent composition.
  • the detergent article can have a burst strength of 300 N or more in the burst strength measurement shown below, and can suppress a decrease in detergency even when the detergent composition is packaged in a water-soluble film in the cleaning performance evaluation shown below.
  • ⁇ Preparation of cleaning article> For each reference example, two sheets of 76 ⁇ m water-soluble film (M8685, manufactured by Kuraray Co., Ltd.) cut to a predetermined rectangular size were stacked, and a heat sealer (manufactured by Fuji Impulse Co., Ltd.) was used to set the sealing conditions of the heat sealer to 8, and three sides of the water-soluble film were fused by the heat sealer at a width of 2 mm from the edge of each side to prepare a bag with only one side open. 15 g of the detergent composition of Examples 1-4 in Table 1 was placed in this bag for each reference example.
  • a heat sealer manufactured by Fuji Impulse Co., Ltd.
  • each cylindrical detergent article in which the detergent composition was encapsulated in the water-soluble film was fused and closed with a heat sealer to obtain each cylindrical detergent article in which the detergent composition was encapsulated in the water-soluble film.
  • the maximum projected area of each of the obtained detergent articles was rectangular, and the major axis diameter of the maximum projected area and the aspect ratio (major axis diameter/minor axis diameter) between the major axis diameter and the minor axis diameter perpendicular to the major axis diameter were as shown in Table 2.
  • the total area of the water-soluble film in contact with the detergent composition was 48 cm 2 .
  • the area of the sealed portion of the water-soluble film is included in the maximum projected area.
  • the total area of the water-soluble film in contact with the detergent composition is calculated as twice the product of the length of the major axis diameter of the detergent article excluding the sealed portion (4 mm) and the length of the minor axis diameter of the detergent article excluding the sealed portion (4 mm), and is 30.4 cm 2 , 34.2 cm 2 , 35.6 cm 2 , 37.1 cm 2 , and 38.6 cm 2 for Reference Examples 1 to 5, respectively.
  • Burst strength is measured for each of the detergent articles in Table 2. Under the conditions of room temperature (20°C)/relative humidity of about 50%, a compression tester (AUTOGRAPH AG-X, Shimadzu Science Co., Ltd.) is used to place each detergent article so that the surface with the maximum projected area is in contact with a fixed platen (not a spherical type, and having an area larger than the maximum projected area of each detergent article) of the compression tester, and a compressive force of 300N is applied at a speed of 200mm/min to perform evaluation. This measurement shows that none of the detergent articles of each reference example bursts at a compressive force of 300N, indicating that the burst strength is 300N or more.
  • a compression tester AUTOGRAPH AG-X, Shimadzu Science Co., Ltd.
  • Model Sebum soil having the following composition is prepared and used to prepare an artificial soiled cloth containing the model sebum soil.
  • Model sebum stain composition 0.44% by mass of lauric acid, 3.15% by mass of myristic acid, 2.35% by mass of pentadecanoic acid, 6.31% by mass of palmitic acid, 0.44% by mass of heptadecanoic acid, 1.6% by mass of stearic acid, 7.91% by mass of oleic acid, 13.33% by mass of triolein, 2.22% by mass of n-hexadecyl palmitate, 6.66% by mass of squalene, and the balance being water (total 100% by mass)
  • washing method Four artificially soiled cloths were sewn onto the chest of a cotton T-shirt (Gunze Co., Ltd.). A vertical washing machine (NA-F70PB1, Panasonic Co., Ltd.) was used. The detergent article of each Reference Example in Table 2 was placed at the bottom of the washing tub, and then the cotton T-shirt (Gunze Co., Ltd.) was added so that the total weight was 2 kg. In each of the reference examples, water was added so that the concentration of the detergent composition contained in the detergent article in the washing tub was 0.5 g/L, and the washing was performed for 9 minutes, 1 rinse, and 7 minutes spin-dry time. The temperature of the water used for washing and rinsing was 20° C. In addition, instead of each detergent article, the detergent composition of Example 1-4 in Table 1 that is not packaged in a water-soluble film is put into the washing tub, and the same washing method as above is carried out. This is used as a reference example.
  • the four pieces of artificially soiled cloth sewn onto the cotton T-shirt were removed, and the cleaning rate was measured by the following method, and the average value of the four pieces was calculated.
  • the reflectance at 550 nm of the unsoiled raw cloth and the artificially soiled cloth before and after washing was measured using a spectrophotometer (SE-2000, manufactured by Nippon Denshoku Co., Ltd.).
  • the cleaning rate (%) was calculated using the following formula, and the average value of the four pieces was calculated.
  • Cleaning rate (%) 100 x [(reflectance after cleaning - reflectance before cleaning) / (reflectance of original fabric - reflectance before cleaning)]
  • the cleaning rate of each Reference Example is calculated by taking the cleaning rate of a Reference Example using a cleaning composition not packaged in a water-soluble film as 100%, and calculating the relative cleaning rate (%) to the Reference Example.
  • Each of the cleaning articles in Table 2 can increase the relative cleaning rate, and can suppress a decrease in cleaning power even when the cleaning composition is packaged in a water-soluble film.

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Abstract

La présente invention concerne une composition de produit de nettoyage qui présente d'excellentes performances de nettoyage, de rinçage et de finition sur des produits textiles et qui confère également des propriétés antibactériennes à des produits textiles.　La composition de produit de nettoyage contient, dans des quantités prescrites, le composant (A) décrit ci-dessous, le composant (B) décrit ci-dessous, (C) un composant inorganique insoluble dans l'eau, (D) un tensioactif cationique, et (E) un polymère anionique et le rapport de masse de la teneur (B) à la teneur totale (B) et (C) est supérieur à 0 et inférieur ou égal à 0,50. Composant (A) : tensioactif contenant un rapport prédéfini (a1) d'un tensioactif non ionique et éventuellement (a2) d'un tensioactif anionique. Composant (B) : sel inorganique soluble dans l'eau contenant un rapport prédéfini des composant (b1) et composant (b2) suivants. Composant (b1) : sel inorganique soluble dans l'eau, le pH d'une solution aqueuse à 0,1 g/l dudit sel étant supérieur ou égal à 9,0. Composant (b2) : sel inorganique soluble dans l'eau, le pH d'une solution aqueuse à 0,1 g/l dudit sel étant inférieur à 9,0.
PCT/JP2024/003614 2023-02-06 2024-02-05 Composition de produit de nettoyage Pending WO2024166840A1 (fr)

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CN202480010949.1A CN120641545A (zh) 2023-02-06 2024-02-05 清洁剂组合物
AU2024218057A AU2024218057A1 (en) 2023-02-06 2024-02-05 Cleaning agent composition

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JP2023015856 2023-02-06
JP2023-015856 2023-02-06

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WO2024166840A1 true WO2024166840A1 (fr) 2024-08-15

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JP (1) JP2024111828A (fr)
CN (1) CN120641545A (fr)
AU (1) AU2024218057A1 (fr)
TW (1) TW202449128A (fr)
WO (1) WO2024166840A1 (fr)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0987691A (ja) * 1995-09-27 1997-03-31 Lion Corp 粒状ノニオン洗剤組成物及びその製造方法
JP2002241799A (ja) * 2001-02-20 2002-08-28 Kao Corp 洗濯用物品
WO2006016700A1 (fr) * 2004-08-13 2006-02-16 Lion Corporation Particule contenant un agent tensioactif non ionique et procédé de production correspondant
JP2008156565A (ja) * 2006-12-26 2008-07-10 Lion Corp 洗濯用添加剤粒子とその製造方法および、これを含む衣料用洗剤
JP2008163253A (ja) * 2006-12-28 2008-07-17 Kao Corp 洗剤組成物
JP2010065116A (ja) * 2008-09-10 2010-03-25 Kao Corp 洗剤組成物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0987691A (ja) * 1995-09-27 1997-03-31 Lion Corp 粒状ノニオン洗剤組成物及びその製造方法
JP2002241799A (ja) * 2001-02-20 2002-08-28 Kao Corp 洗濯用物品
WO2006016700A1 (fr) * 2004-08-13 2006-02-16 Lion Corporation Particule contenant un agent tensioactif non ionique et procédé de production correspondant
JP2008156565A (ja) * 2006-12-26 2008-07-10 Lion Corp 洗濯用添加剤粒子とその製造方法および、これを含む衣料用洗剤
JP2008163253A (ja) * 2006-12-28 2008-07-17 Kao Corp 洗剤組成物
JP2010065116A (ja) * 2008-09-10 2010-03-25 Kao Corp 洗剤組成物

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AU2024218057A1 (en) 2025-07-24
CN120641545A (zh) 2025-09-12
JP2024111828A (ja) 2024-08-19
TW202449128A (zh) 2024-12-16

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