CN104278953A - Polycrystalline diamond composite tooth, preparation method and down-hole drill bit - Google Patents
Polycrystalline diamond composite tooth, preparation method and down-hole drill bit Download PDFInfo
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- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B10/00—Drill bits
- E21B10/46—Drill bits characterised by wear resisting parts, e.g. diamond inserts
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- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
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Abstract
本发明公开了一种聚晶金刚石复合齿、制备方法及潜孔钻头,所述聚晶金刚石复合齿包括硬质合金基体和聚晶金刚石层,所述硬质合金基体与聚晶金刚石层之间设有耐冲击层,所述耐冲击层由以下质量百分比的组分组成:金刚石75%~80%、WC10%~15%,余量为粘合剂。本发明的聚晶金刚石复合齿,在硬质合金基体与聚晶金刚石层之间设有耐冲击层,所述耐冲击层由金刚石、WC和粘合剂组成,耐冲击层提高了硬质合金基体和聚晶金刚石层之间的结合力,有效减少了拉应力集中,提高了聚晶金刚石复合齿的抗冲击韧性,进而提高了聚晶金刚石复合齿的质量,延长了使用寿命。
The invention discloses a polycrystalline diamond composite tooth, a preparation method and a down-the-hole drill bit. The polycrystalline diamond composite tooth includes a cemented carbide substrate and a polycrystalline diamond layer. An impact-resistant layer is provided, and the impact-resistant layer is composed of the following components in mass percentage: 75%-80% of diamond, 10%-15% of WC, and the balance is adhesive. The polycrystalline diamond composite tooth of the present invention is provided with an impact-resistant layer between the cemented carbide substrate and the polycrystalline diamond layer, and the impact-resistant layer is composed of diamond, WC and adhesive, and the impact-resistant layer improves The bonding force between the matrix and the polycrystalline diamond layer effectively reduces the concentration of tensile stress, improves the impact toughness of the polycrystalline diamond composite tooth, and thus improves the quality of the polycrystalline diamond composite tooth and prolongs the service life.
Description
技术领域technical field
本发明属于钻探设备技术领域,具体涉及一种聚晶金刚石复合齿及其制备方法,同时还涉及一种使用该聚晶金刚石复合齿的潜孔钻头。The invention belongs to the technical field of drilling equipment, specifically relates to a polycrystalline diamond composite tooth and a preparation method thereof, and also relates to a down-the-hole drill using the polycrystalline diamond composite tooth.
背景技术Background technique
潜孔钻头是潜孔凿岩工程中的关键部件,在露天和地下矿山、采石场、水电工程、水井钻进、矿物勘探、岩体钢索锚固孔钻凿、地热开凿、地铁工程开挖、边桩支护等施工场地大量使用;同时也是主要消耗件之一,据统计,在凿岩成本中,钻头费用占20%以上。目前,市场上主要为镶嵌硬质合金柱齿头的潜孔钻头,多用硬质合金的圆球齿、圆锥齿、抛物线齿等镶嵌在钢制基体前部制造而成。这种潜孔钻头在中等硬度及偏软的岩层中可以满足工程需要,但是遇到岩层坚硬的地层(如花岗岩)时,硬质合金磨损严重,钻头使用寿命短,需经常更换,效率低下,不仅影响工程的进度,也造成人力、物力及原材料的大量浪费。针对上述问题,聚晶金刚石复合齿潜孔钻头得到了发展。The down-the-hole bit is the key component in the down-the-hole rock drilling project. It is used in open-pit and underground mines, quarries, hydropower projects, well drilling, mineral exploration, rock mass cable anchor hole drilling, geothermal excavation, and subway engineering excavation. , Side pile support and other construction sites are widely used; at the same time, it is also one of the main consumable parts. According to statistics, in the cost of rock drilling, the cost of drill bits accounts for more than 20%. At present, the main products on the market are down-the-hole drills inlaid with cemented carbide column teeth, which are mostly made of cemented carbide ball teeth, conical teeth, parabolic teeth, etc. embedded in the front part of the steel substrate. This kind of down-the-hole drill bit can meet the engineering needs in medium hardness and soft rock formations, but when encountering hard rock formations (such as granite), the cemented carbide wears seriously, the service life of the drill bit is short, and it needs to be replaced frequently, which is inefficient. It not only affects the progress of the project, but also causes a lot of waste of manpower, material resources and raw materials. In response to the above problems, the polycrystalline diamond composite tooth down-the-hole bit has been developed.
聚晶金刚石复合齿潜孔钻头是采用聚晶金刚石复合齿代替了传统的硬质合金柱齿头。聚晶金刚石复合齿是在高温高压下由人造金刚石微粉与硬质合金基体(圆锥形、球形、楔形、抛物线形等)一次烧结而成的,在硬质合金基体的齿头表面形成一层聚晶金刚石层。与硬质合金柱齿头相比,聚晶金刚石复合齿具有高强度、高耐磨性等优异的机械力学性能,在钻探开采等各个领域得到了广泛的应用。但是,由于硬质合金基体和金刚石层的热膨胀系数、弹性模量等性能参数的不同,烧结而成的聚晶金刚石复合齿内部残余应力较大,削弱了硬质合金基体与金刚石层的结合力,导致其抗冲击韧性差,容易出现崩裂、分层等非正常破坏的现象,严重影响了聚晶金刚石复合齿的质量,从而影响了聚晶金刚石复合齿潜孔钻头的使用性能。The polycrystalline diamond composite tooth down-the-hole drill adopts polycrystalline diamond composite tooth instead of the traditional carbide column tooth head. Polycrystalline diamond composite teeth are sintered by artificial diamond powder and cemented carbide substrate (conical, spherical, wedge-shaped, parabolic, etc.) crystal diamond layer. Compared with the cemented carbide column tooth head, the polycrystalline diamond composite tooth has excellent mechanical properties such as high strength and high wear resistance, and has been widely used in various fields such as drilling and mining. However, due to the difference in performance parameters such as thermal expansion coefficient and elastic modulus between the cemented carbide substrate and the diamond layer, the internal residual stress of the sintered polycrystalline diamond composite tooth is relatively large, which weakens the bonding force between the cemented carbide substrate and the diamond layer. , resulting in poor impact toughness, prone to abnormal damage such as cracking and delamination, which seriously affects the quality of polycrystalline diamond composite teeth, thereby affecting the performance of polycrystalline diamond composite teeth down-the-hole drill bits.
发明内容Contents of the invention
本发明的目的是提供一种聚晶金刚石复合齿,解决现有聚晶金刚石复合齿的硬质合金基体与金刚石层结合力差、聚晶金刚石复合齿抗冲击韧性差的问题。The purpose of the present invention is to provide a polycrystalline diamond composite tooth, which solves the problems of poor bonding force between the cemented carbide matrix and the diamond layer of the existing polycrystalline diamond composite tooth and poor impact toughness of the polycrystalline diamond composite tooth.
本发明的第二个目的是提供一种聚晶金刚石复合齿的制备方法。The second object of the present invention is to provide a method for preparing polycrystalline diamond composite teeth.
本发明的第三个目的是提供一种使用上述聚晶金刚石复合齿的潜孔钻头。The third object of the present invention is to provide a down-the-hole drill using the polycrystalline diamond composite teeth.
为了实现以上目的,本发明所采用的技术方案是:一种聚晶金刚石复合齿,包括硬质合金基体和聚晶金刚石层,所述硬质合金基体与聚晶金刚石层之间设有耐冲击层,所述耐冲击层由以下质量百分比的组分组成:金刚石75%~80%、WC10%~15%,余量为粘合剂。In order to achieve the above objectives, the technical solution adopted in the present invention is: a polycrystalline diamond composite tooth, including a cemented carbide substrate and a polycrystalline diamond layer, and an impact-resistant tooth is provided between the cemented carbide substrate and the polycrystalline diamond layer. The impact-resistant layer is composed of the following components in mass percentage: 75%-80% of diamond, 10%-15% of WC, and the balance is adhesive.
所述粘合剂为Co、Ni和TiC。The binders are Co, Ni and TiC.
所述耐冲击层由以下质量百分比的组分组成:金刚石75%~80%、WC10%~15%、Co3%~10%、Ni1%~4%、TiC1%~3%。The impact-resistant layer is composed of the following components in mass percentage: 75%-80% of diamond, 10%-15% of WC, 3%-10% of Co, 1%-4% of Ni, and 1%-3% of TiC.
所述耐冲击层与聚晶金刚石层的质量比为1:2~5。The mass ratio of the impact-resistant layer to the polycrystalline diamond layer is 1:2-5.
所述硬质合金基体为WC-Co合金。The cemented carbide substrate is WC-Co alloy.
所述硬质合金基体由以下质量百分比的组分组成:Co6%~10%、WC90%~94%。The cemented carbide matrix is composed of the following components in mass percentage: Co 6%-10%, WC 90%-94%.
所述WC的晶粒度为2.5~5.0μm。The grain size of the WC is 2.5-5.0 μm.
所述聚晶金刚石层由以下质量百分比的组分组成:粒度为50~60μm的金刚石40%~50%、粒度为30~40μm的金刚石30%~40%、粒度为10~20μm的金刚石5%~20%、Co4%~10%。The polycrystalline diamond layer is composed of the following components by mass percentage: 40% to 50% of diamonds with a particle size of 50 to 60 μm, 30% to 40% of diamonds with a particle size of 30 to 40 μm, and 5% of diamonds with a particle size of 10 to 20 μm ~20%, Co4%~10%.
所述硬质合金基体为圆锥形、圆球形、楔形或抛物线形结构。The cemented carbide substrate has a conical, spherical, wedge or parabolic structure.
所述硬质合金基体表面设有凹球面。所述凹球面的个数为偶数。所述凹球面在硬质合金基体表面呈对称分布。所述凹球面的中心轴线与硬质合金基体表面的切线方向垂直。The surface of the cemented carbide substrate is provided with a concave spherical surface. The number of the concave spherical surfaces is an even number. The concave spherical surfaces are symmetrically distributed on the surface of the cemented carbide substrate. The central axis of the concave spherical surface is perpendicular to the tangent direction of the surface of the cemented carbide substrate.
一种上述的聚晶金刚石复合齿的制备方法,包括下列步骤:A method for preparing the above-mentioned polycrystalline diamond composite tooth, comprising the following steps:
1)取金刚石微粉、WC粉和粘合剂制成耐冲击层粉料,备用;1) Take diamond micropowder, WC powder and adhesive to make impact-resistant layer powder, set aside;
2)将硬质合金基体、耐冲击层粉料、聚晶金刚石层粉料依次组装并压实,得组装件;2) Assemble and compact the cemented carbide substrate, impact-resistant layer powder, and polycrystalline diamond layer powder in sequence to obtain an assembly;
3)将步骤2)所得组装件置于叶腊石合成块中,放入导电钢圈,组成合成模;3) Place the assembly obtained in step 2) in the pyrophyllite synthetic block, and put in the conductive steel ring to form a synthetic mold;
4)将步骤3)所得合成模置于六面顶压机中合成后冷却,卸压取出,即得。4) Place the synthetic mold obtained in step 3) in a six-sided top press for synthesis, cool down, release the pressure, and take it out.
步骤1)中,所述粘合剂为Co、Ni和TiC。In step 1), the binder is Co, Ni and TiC.
步骤1)中,所述金刚石微粉的粒度为20~50μm,WC粉的晶粒度为2.5~5.0μm,Co粉的粒度为5~20μm,Ni粉的粒度为1.0~10μm,TiC粉的粒度为1.0~10μm。In step 1), the particle size of the diamond powder is 20-50 μm, the grain size of the WC powder is 2.5-5.0 μm, the particle size of the Co powder is 5-20 μm, the particle size of the Ni powder is 1.0-10 μm, and the particle size of the TiC powder is 1.0 to 10 μm.
所述耐冲击层粉料的制备方法是:将金刚石微粉、WC粉和粘合剂球磨8~10h后,置于真空干燥箱中于100~150℃下保存备用。The preparation method of the impact-resistant layer powder is as follows: after ball milling diamond micropowder, WC powder and binder for 8-10 hours, it is stored in a vacuum drying oven at 100-150° C. for later use.
所述聚晶金刚石层粉料由以下质量百分比的组分组成:粒度为50~60μm的金刚石微粉40%~50%、粒度为30~40μm的金刚石微粉30%~40%、粒度为10~20μm的金刚石微粉5%~20%、粒度为5~20μm的Co粉4%~10%。The polycrystalline diamond layer powder is composed of the following components by mass percentage: 40%-50% of diamond powder with a particle size of 50-60 μm, 30%-40% of diamond powder with a particle size of 30-40 μm, and 10-20 μm 5% to 20% of diamond fine powder, 4% to 10% of Co powder with a particle size of 5 to 20 μm.
所述聚晶金刚石层粉料的制备方法是将金刚石微粉和Co粉球磨10~15h后,置于真空干燥箱中于100~120℃下保存备用。The preparation method of the polycrystalline diamond layer powder is as follows: after ball milling the diamond micropowder and Co powder for 10-15 hours, the powder is placed in a vacuum drying oven and stored at 100-120° C. for later use.
步骤4)中,所述合成的压力为5.2~6.0GPa,温度为1450~1550℃,合成时间为2~5min。In step 4), the synthesis pressure is 5.2-6.0 GPa, the temperature is 1450-1550° C., and the synthesis time is 2-5 minutes.
步骤4)中,所述冷却时间为5~10min。In step 4), the cooling time is 5-10 minutes.
一种使用上述的聚晶金刚石复合齿的潜孔钻头,包括潜孔钻头基体,所述潜孔钻头基体上设有至少一个齿孔,所述齿孔中镶嵌有所述的聚晶金刚石复合齿。A down-the-hole drill bit using the above-mentioned polycrystalline diamond composite tooth, comprising a down-the-hole drill bit base body, the down-the-hole drill bit base body is provided with at least one tooth hole, and the polycrystalline diamond composite tooth is embedded in the tooth hole .
所述潜孔钻头基体是依次通过基体锻造、基体正火、基体机械加工、基体二次热处理、基体齿孔加工工艺制备得到。The base body of the down-the-hole drill bit is prepared sequentially through base forging, base normalizing, base machining, base secondary heat treatment, and base gear hole processing.
本发明的聚晶金刚石复合齿,在硬质合金基体与聚晶金刚石层之间设有耐冲击层,所述耐冲击层由金刚石、WC和粘合剂组成,耐冲击层提高了硬质合金基体和聚晶金刚石层之间的结合力,有效减少了拉应力集中,提高了聚晶金刚石复合齿的抗冲击韧性,进而提高了聚晶金刚石复合齿的质量,延长了使用寿命。The polycrystalline diamond composite tooth of the present invention is provided with an impact-resistant layer between the cemented carbide substrate and the polycrystalline diamond layer, and the impact-resistant layer is composed of diamond, WC and adhesive, and the impact-resistant layer improves the The bonding force between the matrix and the polycrystalline diamond layer effectively reduces the concentration of tensile stress, improves the impact toughness of the polycrystalline diamond composite tooth, and thus improves the quality of the polycrystalline diamond composite tooth and prolongs the service life.
本发明的聚晶金刚石复合齿中,耐冲击层采用Co、Ni、TiC混合粉料做粘合剂,粘合力强,不仅使硬质合金基体与聚晶金刚石层之间具有较强的粘合力,同时提高了聚晶金刚石复合齿的抗冲击韧性。聚晶金刚石层采用不同粒度的金刚石混合粉料,提高了聚晶金刚石层的整体硬度、耐磨性,进一步提高了聚晶金刚石复合齿的抗冲击韧性。In the polycrystalline diamond composite tooth of the present invention, the impact-resistant layer uses Co, Ni, TiC mixed powder as the adhesive, which has strong adhesive force, not only makes the cemented carbide substrate and the polycrystalline diamond layer have stronger adhesion At the same time, the impact toughness of polycrystalline diamond composite teeth is improved. The polycrystalline diamond layer adopts diamond mixed powder with different particle sizes, which improves the overall hardness and wear resistance of the polycrystalline diamond layer, and further improves the impact toughness of the polycrystalline diamond composite tooth.
本发明的聚晶金刚石复合齿的制备方法,是将硬质合金基体、耐冲击层粉料、聚晶金刚石层粉料依次组装后高温高压合成,该方法实现了在硬质合金基体与聚晶金刚石层之间设置耐冲击层,体高了硬质合金基体和聚晶金刚石层之间的结合力,有效减少了拉应力集中,提高了聚晶金刚石复合齿的抗冲击韧性,进而提高了聚晶金刚石复合齿的质量,延长了使用寿命;该方法一步合成,工艺简单,操作方便,适合大规模工业化生产。The preparation method of the polycrystalline diamond composite tooth of the present invention is to assemble the cemented carbide substrate, the impact-resistant layer powder, and the polycrystalline diamond layer powder sequentially and then synthesize them at high temperature and high pressure. An impact-resistant layer is set between the diamond layers, which increases the bonding force between the cemented carbide substrate and the polycrystalline diamond layer, effectively reduces the concentration of tensile stress, improves the impact toughness of the polycrystalline diamond composite tooth, and further improves the polycrystalline diamond. The quality of the diamond composite tooth prolongs the service life; the method is one-step synthesis, the process is simple, the operation is convenient, and it is suitable for large-scale industrial production.
本发明的潜孔钻头,是将上述的聚晶金刚石复合齿镶嵌在潜孔钻头基体的齿孔中所得,聚晶金刚石复合齿具有良好的耐冲击韧性和硬度,使得潜孔钻头具有较高的耐磨性及抗冲击性,提高了潜孔钻头的质量,延长了使用寿命,提高了潜孔凿岩的工作效率,降低了生产成本。The down-the-hole drill bit of the present invention is obtained by inlaying the above-mentioned polycrystalline diamond composite tooth in the tooth hole of the down-the-hole drill bit matrix. The polycrystalline diamond composite tooth has good impact resistance toughness and hardness, so that the down-the-hole drill bit has a higher The wear resistance and impact resistance improve the quality of the down-the-hole bit, prolong the service life, improve the working efficiency of down-the-hole rock drilling, and reduce the production cost.
附图说明Description of drawings
图1为实施例1的聚晶金刚石复合齿的结构示意图;Fig. 1 is the structural representation of the polycrystalline diamond composite tooth of embodiment 1;
图2为实施例2的聚晶金刚石复合齿的结构示意图;Fig. 2 is the structural representation of the polycrystalline diamond composite tooth of embodiment 2;
图3为图2中硬质合金基体的俯视图;Fig. 3 is the top view of cemented carbide substrate in Fig. 2;
图4为实施例2的潜孔钻头的结构示意图。Fig. 4 is a structural schematic diagram of the down-the-hole drill bit of embodiment 2.
具体实施方式Detailed ways
下面结合具体实施方式对本发明作进一步的说明。The present invention will be further described below in combination with specific embodiments.
实施例1Example 1
本实施例的聚晶金刚石复合齿,包括硬质合金基体和聚晶金刚石层,所述硬质合金基体与聚晶金刚石层之间设有耐冲击层,所述耐冲击层由以下质量百分比的组分组成:金刚石75%、WC15%、Co6%、Ni2%、TiC2%。所述硬质合金基体由以下质量百分比的组分组成:Co10%、WC90%;其中WC晶粒度大小为2.5~5.0μm。所述耐冲击层与聚晶金刚石层的质量比为1:2。所述聚晶金刚石层由以下质量百分比的组分组成:粒度为50~60μm的金刚石50%、粒度为30~40μm的金刚石30%、粒度为10~20μm的金刚石10%、Co10%。The polycrystalline diamond composite tooth of this embodiment comprises a cemented carbide substrate and a polycrystalline diamond layer, and an impact-resistant layer is arranged between the cemented carbide substrate and the polycrystalline diamond layer, and the impact-resistant layer consists of the following mass percentage Component composition: Diamond 75%, WC15%, Co6%, Ni2%, TiC2%. The cemented carbide matrix is composed of the following components in mass percentage: 10% Co, 90% WC; wherein the grain size of WC is 2.5-5.0 μm. The mass ratio of the impact-resistant layer to the polycrystalline diamond layer is 1:2. The polycrystalline diamond layer is composed of the following components in mass percentage: 50% of diamond with a particle size of 50-60 μm, 30% of diamond with a particle size of 30-40 μm, 10% of diamond with a particle size of 10-20 μm, and 10% of Co.
本实施例的聚晶金刚石复合齿的结构如图1所示,包括硬质合金基体3和聚晶金刚石层2,所述硬质合金基体3与聚晶金刚石层2之间设有耐冲击层1;所述硬质合金基体3一端为圆柱体,另一端为半球状的齿头4,齿头4的外表面为半球面,耐冲击层1位于齿头4的半球面上,耐冲击层1上面为聚晶金刚石层2。The structure of the polycrystalline diamond composite tooth of this embodiment is shown in Figure 1, including a cemented carbide substrate 3 and a polycrystalline diamond layer 2, and an impact-resistant layer is arranged between the cemented carbide substrate 3 and the polycrystalline diamond layer 2 1. One end of the cemented carbide substrate 3 is a cylinder, and the other end is a hemispherical tooth head 4. The outer surface of the tooth head 4 is a hemispherical surface. The impact-resistant layer 1 is located on the hemispherical surface of the tooth head 4. The impact-resistant layer 1 above is polycrystalline diamond layer 2.
本实施例的聚晶金刚石复合齿的制备方法,包括下列步骤:The preparation method of the polycrystalline diamond composite tooth of the present embodiment comprises the following steps:
1)取粒度为20~50μm的金刚石微粉、晶粒度为2.5~5.0μm的WC粉、粒度为5~20μm的Co粉、粒度为1.0~10μm的Ni粉、粒度为1.0~10μm的TiC粉,加入行星式球磨机,行星式球磨机的参数:公转40转/分,自转80转/分,球磨10h混合均匀后,置于真空干燥箱中于150℃条件下保存备用;1) Take diamond powder with a particle size of 20-50 μm, WC powder with a particle size of 2.5-5.0 μm, Co powder with a particle size of 5-20 μm, Ni powder with a particle size of 1.0-10 μm, and TiC powder with a particle size of 1.0-10 μm , add a planetary ball mill, the parameters of the planetary ball mill: revolution 40 rpm, rotation 80 rpm, ball mill 10h after mixing evenly, put it in a vacuum drying oven at 150 ℃ and save it for later use;
2)取粒度为50~60μm的金刚石微粉、粒度为30~40μm的金刚石微粉、粒度为10~20μm的金刚石微粉、粒度为5~20μm的Co粉,加入行星式球磨机,球磨10h混合均匀后,置于真空干燥箱中于120℃条件下保存备用;2) Take diamond powder with a particle size of 50-60 μm, diamond powder with a particle size of 30-40 μm, diamond powder with a particle size of 10-20 μm, and Co powder with a particle size of 5-20 μm, add it to a planetary ball mill, and mix it evenly after ball milling for 10 hours. Store in a vacuum oven at 120°C for later use;
3)将硬质合金基体、耐冲击层粉料、聚晶金刚石层粉料依次组装并用5吨的压力机压实,得组装件;3) Assemble the cemented carbide substrate, impact-resistant layer powder, and polycrystalline diamond layer powder sequentially and compact them with a 5-ton press to obtain an assembly;
4)将步骤3)所得组装件置于叶腊石合成块中,放入导电钢圈,组成合成模;4) Place the assembly obtained in step 3) in the synthetic block of pyrophyllite, and put in the conductive steel ring to form a synthetic mold;
5)将步骤4)所得合成模置于六面顶金刚石压机中,在压力5.8GPa、温度1500℃条件下合成5min后,冷却5min,卸压取出样品,喷砂处理后,机械加工使其直径公差为±0.01mm,高度公差为±0.05mm,即得。5) Place the synthetic mold obtained in step 4) in a six-sided top diamond press, synthesize it at a pressure of 5.8GPa and a temperature of 1500°C for 5 minutes, cool for 5 minutes, release the pressure and take out the sample, and after sandblasting, mechanically process it to make it The diameter tolerance is ±0.01mm, and the height tolerance is ±0.05mm.
本实施例的潜孔钻头,包括潜孔钻头基体,所述潜孔钻头基体上设有14个齿孔,所述齿孔中镶嵌有所述的聚晶金刚石复合齿。The down-the-hole bit of this embodiment includes a down-the-hole bit base body, and 14 tooth holes are arranged on the down-the-hole bit base body, and the polycrystalline diamond composite teeth are embedded in the tooth holes.
该潜孔钻头的制备方法,包括依次通过基体锻造、基体正火、基体机械加工、基体二次热处理、基体齿孔加工工艺制备得到潜孔钻头基体,再将所述的聚晶金刚石复合齿镶嵌到潜孔钻头基体的齿孔中,后经质量检验。喷漆包装,即得。The preparation method of the down-the-hole drill comprises sequentially preparing the down-the-hole drill base by forging the base, normalizing the base, machining the base, secondary heat treatment of the base, and processing the tooth holes of the base, and then inlaying the polycrystalline diamond composite teeth Into the tooth hole of the DTH bit base, after the quality inspection. Spray paint packaging, that is.
实施例2Example 2
本实施例的聚晶金刚石复合齿,包括硬质合金基体和聚晶金刚石层,所述硬质合金基体与聚晶金刚石层之间设有耐冲击层,所述耐冲击层由以下质量百分比的组分组成:金刚石80%、WC10%、Co3%、Ni4%、TiC3%。所述硬质合金基体由以下质量百分比的组分组成:Co8%、WC92%;其中WC晶粒度大小为2.5~5.0μm。所述耐冲击层与聚晶金刚石层的质量比为1:3。所述聚晶金刚石层由以下质量百分比的组分组成:粒度为50~60μm的金刚石40%、粒度为30~40μm的金刚石40%、粒度为10~20μm的金刚石16%、Co4%。The polycrystalline diamond composite tooth of this embodiment comprises a cemented carbide substrate and a polycrystalline diamond layer, and an impact-resistant layer is arranged between the cemented carbide substrate and the polycrystalline diamond layer, and the impact-resistant layer consists of the following mass percentage Composition: Diamond 80%, WC10%, Co3%, Ni4%, TiC3%. The cemented carbide matrix is composed of the following components in mass percentage: Co8%, WC92%, wherein the grain size of WC is 2.5-5.0 μm. The mass ratio of the impact-resistant layer to the polycrystalline diamond layer is 1:3. The polycrystalline diamond layer is composed of the following components in mass percentage: 40% diamond with a particle size of 50-60 μm, 40% diamond with a particle size of 30-40 μm, 16% diamond with a particle size of 10-20 μm, and 4% Co.
本实施例的聚晶金刚石复合齿的结构如图2所示,与实施例1不同之处在于:齿头4的半球面上设有24个凹球面5,围绕齿头4表面的中心(半球面的中心)呈三层环状对称均布(如图3所示),每层8个;凹球面5的中心轴线与硬质合金基体3的齿头4的外表面的切线方向垂直;耐冲击层1位于硬质合金基体3的齿头4与聚晶金刚石层2之间,并填满由凹球面5形成的半球体的凹槽。The structure of the polycrystalline diamond composite tooth of the present embodiment is as shown in Figure 2, differs from embodiment 1 in that: the hemispherical surface of tooth head 4 is provided with 24 concave spherical surfaces 5, surrounds the center of tooth head 4 surfaces (hemispherical The center of the surface) is three-layer annular symmetrically distributed (as shown in Figure 3), and each layer is 8; the central axis of the concave spherical surface 5 is perpendicular to the tangential direction of the outer surface of the tooth head 4 of the cemented carbide substrate 3; The impact layer 1 is located between the tooth head 4 of the cemented carbide substrate 3 and the polycrystalline diamond layer 2 , and fills the groove of the hemisphere formed by the concave spherical surface 5 .
本实施例的聚晶金刚石复合齿的制备方法,包括下列步骤:The preparation method of the polycrystalline diamond composite tooth of the present embodiment comprises the following steps:
1)取粒度为20~50μm的金刚石微粉、晶粒度为2.5~5.0μm的WC粉、粒度为5~20μm的Co粉、粒度为1.0~10μm的Ni粉、粒度为1.0~10μm的TiC粉,加入行星式球磨机,行星式球磨机的参数:公转40转/分,自转80转/分,球磨8h混合均匀后,置于真空干燥箱中于140℃条件下保存备用;1) Take diamond powder with a particle size of 20-50 μm, WC powder with a particle size of 2.5-5.0 μm, Co powder with a particle size of 5-20 μm, Ni powder with a particle size of 1.0-10 μm, and TiC powder with a particle size of 1.0-10 μm , adding a planetary ball mill, the parameters of the planetary ball mill: 40 revolutions per minute, 80 revolutions per minute, ball milled for 8 hours and mixed evenly, then placed in a vacuum drying oven at 140 ° C for future use;
2)取粒度为50~60μm的金刚石微粉、粒度为30~40μm的金刚石微粉、粒度为10~20μm的金刚石微粉、粒度为5~20μm的Co粉,加入行星式球磨机,球磨12h混合均匀后,置于真空干燥箱中于110℃条件下保存备用;2) Take diamond powder with a particle size of 50-60 μm, diamond powder with a particle size of 30-40 μm, diamond powder with a particle size of 10-20 μm, and Co powder with a particle size of 5-20 μm, add it to a planetary ball mill, and mix it evenly after ball milling for 12 hours. Store in a vacuum oven at 110°C for later use;
3)将硬质合金基体、耐冲击层粉料、聚晶金刚石层粉料依次组装并用5吨的压力机压实,得组装件;3) Assemble the cemented carbide substrate, impact-resistant layer powder, and polycrystalline diamond layer powder sequentially and compact them with a 5-ton press to obtain an assembly;
4)将步骤3)所得组装件置于叶腊石合成块中,放入导电钢圈,组成合成模;4) Place the assembly obtained in step 3) in the synthetic block of pyrophyllite, and put in the conductive steel ring to form a synthetic mold;
5)将步骤4)所得合成模置于六面顶金刚石压机中,在压力5.2GPa、温度1550℃条件下合成2min后,冷却10min,卸压取出样品,喷砂处理后,机械加工使其直径公差为±0.01mm,高度公差为±0.05mm,即得。5) Place the synthetic mold obtained in step 4) in a six-sided top diamond press, synthesize it at a pressure of 5.2GPa and a temperature of 1550°C for 2 minutes, cool for 10 minutes, release the pressure and take out the sample, and after sandblasting, machine it to make it The diameter tolerance is ±0.01mm, and the height tolerance is ±0.05mm.
本实施例的潜孔钻头,如图4所示,包括潜孔钻头基体6,所述潜孔钻头基体6上设有12个齿孔8,所述齿孔8中镶嵌有所述的聚晶金刚石复合齿7。所述聚晶金刚石复合齿7即为图1所示的聚晶金刚石复合齿。The down-the-hole bit of the present embodiment, as shown in Figure 4, comprises the down-the-hole bit base body 6, and the described down-the-hole bit base body 6 is provided with 12 toothed holes 8, and described polycrystalline Diamond composite teeth7. The polycrystalline diamond composite tooth 7 is the polycrystalline diamond composite tooth shown in FIG. 1 .
该潜孔钻头的制备方法,包括依次通过基体锻造、基体正火、基体机械加工、基体二次热处理、基体齿孔加工工艺制备得到潜孔钻头基体,再将所述的聚晶金刚石复合齿镶嵌到潜孔钻头基体的齿孔中,后经质量检验。喷漆包装,即得。The preparation method of the down-the-hole drill comprises sequentially preparing the down-the-hole drill base by forging the base, normalizing the base, machining the base, secondary heat treatment of the base, and processing the tooth holes of the base, and then inlaying the polycrystalline diamond composite teeth Into the tooth hole of the DTH bit base, after the quality inspection. Spray paint packaging, that is.
实施例3Example 3
本实施例的聚晶金刚石复合齿,包括硬质合金基体和聚晶金刚石层,所述硬质合金基体与聚晶金刚石层之间设有耐冲击层,所述耐冲击层由以下质量百分比的组分组成:金刚石78%、WC12%、Co7%、Ni2%、TiC1%。所述硬质合金基体由以下质量百分比的组分组成:Co6%、WC94%;其中WC晶粒度大小为2.5~5.0μm。所述耐冲击层与聚晶金刚石层的质量比为1:4。所述聚晶金刚石层由以下质量百分比的组分组成:粒度为50~60μm的金刚石40%、粒度为30~40μm的金刚石33%、粒度为10~20μm的金刚石20%、Co7%。The polycrystalline diamond composite tooth of this embodiment comprises a cemented carbide substrate and a polycrystalline diamond layer, and an impact-resistant layer is arranged between the cemented carbide substrate and the polycrystalline diamond layer, and the impact-resistant layer consists of the following mass percentage Component composition: Diamond 78%, WC12%, Co7%, Ni2%, TiC1%. The cemented carbide matrix is composed of the following components in mass percentage: Co6%, WC94%, wherein the grain size of WC is 2.5-5.0 μm. The mass ratio of the impact-resistant layer to the polycrystalline diamond layer is 1:4. The polycrystalline diamond layer is composed of the following components in mass percentage: 40% diamond with a particle size of 50-60 μm, 33% diamond with a particle size of 30-40 μm, 20% diamond with a particle size of 10-20 μm, and 7% Co.
本实施例的聚晶金刚石复合齿的制备方法,包括下列步骤:The preparation method of the polycrystalline diamond composite tooth of the present embodiment comprises the following steps:
1)取粒度为20~50μm的金刚石微粉、晶粒度为2.5~5.0μm的WC粉、粒度为5~20μm的Co粉、粒度为1.0~10μm的Ni粉、粒度为1.0~10μm的TiC粉,加入行星式球磨机,行星式球磨机的参数:公转40转/分,自转80转/分,球磨9h混合均匀后,置于真空干燥箱中于130℃条件下保存备用;1) Take diamond powder with a particle size of 20-50 μm, WC powder with a particle size of 2.5-5.0 μm, Co powder with a particle size of 5-20 μm, Ni powder with a particle size of 1.0-10 μm, and TiC powder with a particle size of 1.0-10 μm , adding a planetary ball mill, the parameters of the planetary ball mill: 40 revolutions per minute, 80 revolutions per minute, ball milled for 9 hours and mixed evenly, then placed in a vacuum drying oven at 130 ° C for future use;
2)取粒度为50~60μm的金刚石微粉、粒度为30~40μm的金刚石微粉、粒度为10~20μm的金刚石微粉、粒度为5~20μm的Co粉,加入行星式球磨机,球磨14h混合均匀后,置于真空干燥箱中于105℃条件下保存备用;2) Take diamond powder with a particle size of 50-60 μm, diamond powder with a particle size of 30-40 μm, diamond powder with a particle size of 10-20 μm, and Co powder with a particle size of 5-20 μm, add it to a planetary ball mill, and mix it evenly after ball milling for 14 hours. Store in a vacuum oven at 105°C for later use;
3)将硬质合金基体、耐冲击层粉料、聚晶金刚石层粉料依次组装并用5吨的压力机压实,得组装件;3) Assemble the cemented carbide substrate, impact-resistant layer powder, and polycrystalline diamond layer powder sequentially and compact them with a 5-ton press to obtain an assembly;
4)将步骤3)所得组装件置于叶腊石合成块中,放入导电钢圈,组成合成模;4) Place the assembly obtained in step 3) in the synthetic block of pyrophyllite, and put in the conductive steel ring to form a synthetic mold;
5)将步骤4)所得合成模置于六面顶金刚石压机中,在压力5.5GPa、温度1500℃条件下合成3min后,冷却8min,卸压取出样品,喷砂处理后,机械加工使其直径公差为±0.01mm,高度公差为±0.05mm,即得。5) Place the synthetic mold obtained in step 4) in a six-sided top diamond press, synthesize it at a pressure of 5.5GPa and a temperature of 1500°C for 3 minutes, cool for 8 minutes, release the pressure and take out the sample, and after sandblasting, mechanically process it to make it The diameter tolerance is ±0.01mm, and the height tolerance is ±0.05mm.
本实施例的潜孔钻头,包括潜孔钻头基体,所述潜孔钻头基体上设有13个齿孔,所述齿孔中镶嵌有所述的聚晶金刚石复合齿。The down-the-hole bit of this embodiment includes a down-the-hole bit base body, and 13 tooth holes are arranged on the down-the-hole bit base body, and the polycrystalline diamond composite teeth are embedded in the tooth holes.
该潜孔钻头的制备方法,包括依次通过基体锻造、基体正火、基体机械加工、基体二次热处理、基体齿孔加工工艺制备得到潜孔钻头基体,再将所述的聚晶金刚石复合齿镶嵌到潜孔钻头基体的齿孔中,后经质量检验。喷漆包装,即得。The preparation method of the down-the-hole drill comprises sequentially preparing the down-the-hole drill base by forging the base, normalizing the base, machining the base, secondary heat treatment of the base, and processing the tooth holes of the base, and then inlaying the polycrystalline diamond composite teeth Into the tooth hole of the DTH bit base, after the quality inspection. Spray paint packaging, that is.
实施例4Example 4
本实施例的聚晶金刚石复合齿,包括硬质合金基体和聚晶金刚石层,所述硬质合金基体与聚晶金刚石层之间设有耐冲击层,所述耐冲击层由以下质量百分比的组分组成:金刚石76%、WC12%、Co10%、Ni1%、TiC1%。所述硬质合金基体由以下质量百分比的组分组成:Co7%、WC93%;其中WC晶粒度大小为2.5~5.0μm。所述耐冲击层与聚晶金刚石层的质量比为1:5。所述聚晶金刚石层由以下质量百分比的组分组成:粒度为50~60μm的金刚石45%、粒度为30~40μm的金刚石40%、粒度为10~20μm的金刚石5%、Co10%。The polycrystalline diamond composite tooth of this embodiment comprises a cemented carbide substrate and a polycrystalline diamond layer, and an impact-resistant layer is arranged between the cemented carbide substrate and the polycrystalline diamond layer, and the impact-resistant layer consists of the following mass percentage Composition: 76% diamond, 12% WC, 10% Co, 1% Ni, 1% TiC. The cemented carbide matrix is composed of the following components in mass percentage: Co7%, WC93%, wherein the grain size of WC is 2.5-5.0 μm. The mass ratio of the impact-resistant layer to the polycrystalline diamond layer is 1:5. The polycrystalline diamond layer is composed of the following components in mass percentage: 45% diamond with a particle size of 50-60 μm, 40% diamond with a particle size of 30-40 μm, 5% diamond with a particle size of 10-20 μm, and 10% Co.
本实施例的聚晶金刚石复合齿的制备方法,包括下列步骤:The preparation method of the polycrystalline diamond composite tooth of the present embodiment comprises the following steps:
1)取粒度为20~50μm的金刚石微粉、晶粒度为2.5~5.0μm的WC粉、粒度为5~20μm的Co粉、粒度为1.0~10μm的Ni粉、粒度为1.0~10μm的TiC粉,加入行星式球磨机,行星式球磨机的参数:公转40转/分,自转80转/分,球磨10h混合均匀后,置于真空干燥箱中于120℃条件下保存备用;1) Take diamond powder with a particle size of 20-50 μm, WC powder with a particle size of 2.5-5.0 μm, Co powder with a particle size of 5-20 μm, Ni powder with a particle size of 1.0-10 μm, and TiC powder with a particle size of 1.0-10 μm , adding a planetary ball mill, the parameters of the planetary ball mill: 40 revolutions per minute, 80 revolutions per minute, ball milled for 10 hours and mixed evenly, then placed in a vacuum drying oven at 120 ° C for future use;
2)取粒度为50~60μm的金刚石微粉、粒度为30~40μm的金刚石微粉、粒度为10~20μm的金刚石微粉、粒度为5~20μm的Co粉,加入行星式球磨机,球磨15h混合均匀后,置于真空干燥箱中于100℃条件下保存备用;2) Take diamond powder with a particle size of 50-60 μm, diamond powder with a particle size of 30-40 μm, diamond powder with a particle size of 10-20 μm, and Co powder with a particle size of 5-20 μm, add it to a planetary ball mill, and mix it evenly after ball milling for 15 hours. Store in a vacuum oven at 100°C for later use;
3)将硬质合金基体、耐冲击层粉料、聚晶金刚石层粉料依次组装并用5吨的压力机压实,得组装件;3) Assemble the cemented carbide substrate, impact-resistant layer powder, and polycrystalline diamond layer powder sequentially and compact them with a 5-ton press to obtain an assembly;
4)将步骤3)所得组装件置于叶腊石合成块中,放入导电钢圈,组成合成模;4) Place the assembly obtained in step 3) in the synthetic block of pyrophyllite, and put in the conductive steel ring to form a synthetic mold;
5)将步骤4)所得合成模置于六面顶金刚石压机中,在压力6.0GPa、温度1450℃条件下合成4min后,冷却7min,卸压取出样品,喷砂处理后,机械加工使其直径公差为±0.01mm,高度公差为±0.05mm,即得。5) Place the synthetic mold obtained in step 4) in a six-sided top diamond press, synthesize it at a pressure of 6.0GPa and a temperature of 1450°C for 4 minutes, cool for 7 minutes, release the pressure and take out the sample, and after sandblasting, mechanically process it to make it The diameter tolerance is ±0.01mm, and the height tolerance is ±0.05mm.
本实施例的潜孔钻头,包括潜孔钻头基体,所述潜孔钻头基体上设有16个齿孔,所述齿孔中镶嵌有所述的聚晶金刚石复合齿。The down-the-hole bit of this embodiment includes a down-the-hole bit base body, and 16 tooth holes are arranged on the down-the-hole bit base body, and the polycrystalline diamond composite teeth are embedded in the tooth holes.
该潜孔钻头的制备方法,包括依次通过基体锻造、基体正火、基体机械加工、基体二次热处理、基体齿孔加工工艺制备得到潜孔钻头基体,再将所述的聚晶金刚石复合齿镶嵌到潜孔钻头基体的齿孔中,后经质量检验。喷漆包装,即得。The preparation method of the down-the-hole drill comprises sequentially preparing the down-the-hole drill base by forging the base, normalizing the base, machining the base, secondary heat treatment of the base, and processing the tooth holes of the base, and then inlaying the polycrystalline diamond composite teeth Into the tooth hole of the DTH bit base, after the quality inspection. Spray paint packaging, that is.
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