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CN103579109B - A kind of manufacture method of integrated optoelectronic circuit - Google Patents

A kind of manufacture method of integrated optoelectronic circuit Download PDF

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CN103579109B
CN103579109B CN201310534726.9A CN201310534726A CN103579109B CN 103579109 B CN103579109 B CN 103579109B CN 201310534726 A CN201310534726 A CN 201310534726A CN 103579109 B CN103579109 B CN 103579109B
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oxide layer
silicon chip
layer
silicon wafer
integrated circuit
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CN103579109A (en
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张有润
董梁
刘影
张飞翔
孙成春
张波
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University of Electronic Science and Technology of China
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/01Manufacture or treatment
    • H10D84/02Manufacture or treatment characterised by using material-based technologies
    • H10D84/03Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
    • H10D84/038Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/76Making of isolation regions between components
    • H01L21/762Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
    • H01L21/76202Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using a local oxidation of silicon, e.g. LOCOS, SWAMI, SILO

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Abstract

本发明涉及半导体技术,具体的说是涉及一种光电集成电路的制造方法。本发明所述的制造方法主要步骤为:对硅片进行处理,使硅片的一部分具备氧化层;将硅片有氧化层的部分和无氧化层的部分进行隔离;在硅片上无氧化层的部分制造光电器件,在氧化层上制造电子器件,所述光电器件为采用纵向结构,电子器件采用SOI工艺。本发明的有益效果为使得光电二极管和集成电路模块集成于同一块芯片上,有效地减少了封装难度和成本,降低了寄生效应,提高了可靠性。本发明尤其适用于光电集成电路的制造。

The invention relates to semiconductor technology, in particular to a method for manufacturing an optoelectronic integrated circuit. The main steps of the manufacturing method of the present invention are: processing the silicon wafer so that a part of the silicon wafer has an oxide layer; isolating the part of the silicon wafer with the oxide layer and the part without the oxide layer; The photoelectric device is manufactured in part, and the electronic device is manufactured on the oxide layer. The photoelectric device adopts a vertical structure, and the electronic device adopts an SOI process. The beneficial effect of the invention is that the photodiode and the integrated circuit module are integrated on the same chip, which effectively reduces packaging difficulty and cost, reduces parasitic effects, and improves reliability. The invention is particularly applicable to the manufacture of optoelectronic integrated circuits.

Description

一种光电集成电路的制造方法A method of manufacturing an optoelectronic integrated circuit

技术领域 technical field

本发明涉及半导体技术,具体的说是涉及一种光电集成电路的制造方法。 The invention relates to semiconductor technology, in particular to a method for manufacturing an optoelectronic integrated circuit.

背景技术 Background technique

光电集成电路(optoelectronicintegratedcircuit,OEIC),是将光电器件和电子器件集成在一起,以实现光通信系统或光信息处理系统中某种特定功能的集成电路。 An optoelectronic integrated circuit (OEIC) is an integrated circuit that integrates optoelectronic devices and electronic devices to achieve a specific function in an optical communication system or an optical information processing system.

以往的普通光电集成电路都是采用与传统标准硅基工艺兼容的制造方法进行单片集成,这样的集成方式减少了混合电路中的组装环节,其可靠性和速度也得到了明显的优化。不过,这种集成方式中的光电器件与电子器件间的电隔离效果较差,光电器件所产生的光生载流子和电子器件中的载流子会相互干扰,此外,常规工艺还需要考虑光电器件和电子器件工艺之间的兼容问题。而本文提出的光电集成电路采用单片集成的局部SOI工艺制作,通过SIMOX或SDB等工艺将芯片隔离成SOI基模块和常规硅衬底区域,其集成电路模块利用标准SOI工艺制作在SOI基模块,而光电器件采用纵向结构制作在常规硅衬底区域,两个模块通过金属进行互联。采用本文集成方式的光电集成电路,能有效地综合光电器件和集成电路模块的各自优势,同时减少了工艺兼容问题,实现性能的最优化。 In the past, ordinary optoelectronic integrated circuits were monolithically integrated using manufacturing methods compatible with traditional standard silicon-based processes. This integration method reduces the assembly steps in hybrid circuits, and its reliability and speed have also been significantly optimized. However, the electrical isolation between the optoelectronic device and the electronic device in this integration method is poor, and the photogenerated carriers generated by the optoelectronic device and the carriers in the electronic device will interfere with each other. In addition, the conventional process also needs to consider the photoelectric Compatibility issues between devices and electronic device processes. However, the optoelectronic integrated circuit proposed in this paper is manufactured by monolithic integrated local SOI process, and the chip is isolated into SOI-based modules and conventional silicon substrate areas by SIMOX or SDB processes. , while optoelectronic devices are fabricated in a conventional silicon substrate area using a vertical structure, and the two modules are interconnected through metal. The optoelectronic integrated circuit adopting the integrated method in this paper can effectively synthesize the respective advantages of optoelectronic devices and integrated circuit modules, reduce the problem of process compatibility, and realize the optimization of performance.

发明内容 Contents of the invention

本发明所要解决的,就是针对现有的光电集成电路的工艺集成问题,提出了一种光电集成电路中的纵向光电探测器和集成电路模块采用SOI工艺进行单片集成的方法。 What the present invention aims to solve is to propose a method for single-chip integration of longitudinal photodetectors and integrated circuit modules in optoelectronic integrated circuits using SOI technology, aiming at the process integration problem of existing optoelectronic integrated circuits.

本发明解决上述技术问题所采用的技术方案是:一种光电集成电路的制造方法,其特征在于,包括以下步骤: The technical solution adopted by the present invention to solve the above-mentioned technical problems is: a method for manufacturing an optoelectronic integrated circuit, characterized in that it comprises the following steps:

a.对硅片进行处理,使硅片的一部分具备氧化层; a. Treat the silicon wafer so that a part of the silicon wafer has an oxide layer;

b.将硅片有氧化层的部分和无氧化层的部分进行隔离; b. Isolate the part of the silicon wafer with the oxide layer and the part without the oxide layer;

c.在硅片上无氧化层的部分制造光电器件,在氧化层上制造电子器件,所述光电器件为采用纵向结构,电子器件采用SOI工艺。 c. Manufacture optoelectronic devices on the part of the silicon wafer without an oxide layer, and manufacture electronic devices on the oxide layer, the optoelectronic devices adopt a vertical structure, and the electronic devices adopt SOI technology.

具体的,步骤a的具体方法为: Specifically, the specific method of step a is:

a1.将硅片作为半导体衬底301,在半导体衬底301的外延层302上设置掩膜版303,进行氧离子注入,在表面未覆盖掩膜版303的外延层302中形成氧化层304; a1. Using a silicon wafer as a semiconductor substrate 301, a mask plate 303 is set on the epitaxial layer 302 of the semiconductor substrate 301, oxygen ion implantation is performed, and an oxide layer 304 is formed in the epitaxial layer 302 whose surface does not cover the mask plate 303;

a2.通过热处理,将氧化层304形成绝缘层305; a2. Form the oxide layer 304 into an insulating layer 305 by heat treatment;

a3.去除掩膜版303。 a3. Removing the mask plate 303 .

进一步的,步骤b的具体方法为: Further, the specific method of step b is:

采用槽刻蚀,在绝缘层305上刻蚀出多个隔离层306,所述隔离层306将绝缘层305上的外延层302隔离为多个部分。 Using groove etching, a plurality of isolation layers 306 are etched on the insulating layer 305, and the isolation layers 306 isolate the epitaxial layer 302 on the insulating layer 305 into multiple parts.

具体的,步骤a的具体方法为: Specifically, the specific method of step a is:

a1.将有氧化层的硅片401和无氧化层的硅片402经过键合成SOI结构; a1. Bonding a silicon wafer 401 with an oxide layer and a silicon wafer 402 without an oxide layer into an SOI structure;

a2.通过湿法刻蚀去除步骤a1中合成的SOI结构的一部分,具体为去除部分无氧化层的硅片402以及与该部分相连的有氧化层的硅片401,被去除的有氧化层的硅片401的部分包括该部分的氧化层; a2. Remove a part of the SOI structure synthesized in step a1 by wet etching, specifically removing part of the silicon wafer 402 without the oxide layer and the silicon wafer 401 with the oxide layer connected to this part, and the removed oxide layer The portion of silicon wafer 401 includes the oxide layer of the portion;

a3.在步骤a2中得到的结构上生长外延层403; a3. growing an epitaxial layer 403 on the structure obtained in step a2;

a4.将步骤a3中得到的结构采用抛光工艺加工到所需的厚度。 a4. Process the structure obtained in step a3 to a desired thickness by polishing.

进一步的,步骤b的具体方法为: Further, the specific method of step b is:

在有氧化层的硅片401的氧化层上设置多个隔离层,将氧化层上的硅片隔离为多个部分。 A plurality of isolation layers are provided on the oxide layer of the silicon wafer 401 with an oxide layer to isolate the silicon wafer on the oxide layer into multiple parts.

再进一步的,所述设置多个隔离层为采用通过刻蚀形成沟槽隔离或形成V型槽隔离的方式进行隔离。 Still further, the arranging of the plurality of isolation layers is isolation by means of forming trench isolation or V-shaped groove isolation by etching.

本发明的有益效果为,使得光电二极管和集成电路模块集成于同一块芯片上,有效地减少了封装难度和成本,降低了寄生效应,提高了可靠性。 The beneficial effect of the invention is that the photodiode and the integrated circuit module are integrated on the same chip, which effectively reduces packaging difficulty and cost, reduces parasitic effects, and improves reliability.

附图说明 Description of drawings

图1为实施例1的结构示意图; Fig. 1 is the structural representation of embodiment 1;

图2为实施例1的截面示意图; Fig. 2 is the cross-sectional schematic diagram of embodiment 1;

图3为实施例1的制造工艺流程中覆盖掩膜版303并进行氧离子注入的示意图; 3 is a schematic diagram of covering the mask plate 303 and performing oxygen ion implantation in the manufacturing process flow of embodiment 1;

图4为实施例1的制造工艺流程中形成氧化层304的示意图; 4 is a schematic diagram of forming an oxide layer 304 in the manufacturing process flow of Embodiment 1;

图5为实施例1的制造工艺流程中形成绝缘层305的示意图; 5 is a schematic diagram of forming an insulating layer 305 in the manufacturing process flow of Embodiment 1;

图6为实施例1的制造工艺流程中去除掩膜版303后示意图; 6 is a schematic diagram after removing the mask plate 303 in the manufacturing process flow of embodiment 1;

图7为实施例1的制造工艺流程中刻蚀隔离层306示意图; FIG. 7 is a schematic diagram of etching an isolation layer 306 in the manufacturing process flow of Embodiment 1;

图8为实施例2的制造工艺流程中将有氧化层的硅片401(N+掺杂)与无氧化层的硅片402经过键合成SOI结构的示意图; FIG. 8 is a schematic diagram of bonding a silicon wafer 401 with an oxide layer (N+ doped) and a silicon wafer 402 without an oxide layer into an SOI structure in the manufacturing process flow of Example 2;

图9为实施例2的制造工艺流程中湿法刻蚀去除SOI结构的一部分后的示意图; Fig. 9 is a schematic diagram after removing a part of the SOI structure by wet etching in the manufacturing process flow of embodiment 2;

图10为实施例2的制造工艺流程中生长外延层后示意图; Fig. 10 is a schematic diagram after growing an epitaxial layer in the manufacturing process flow of embodiment 2;

图11为实施例2的制造工艺流程中采用抛光工艺加工到所需的厚度后的示意图; Fig. 11 is the schematic diagram after adopting polishing process to process to required thickness in the manufacturing process flow of embodiment 2;

图12为实施例2的制造工艺流程中通过沟槽隔离后示意图; Fig. 12 is a schematic diagram after trench isolation in the manufacturing process flow of embodiment 2;

图13为实施例2的制造工艺流程中通过V型槽隔离后示意图。 FIG. 13 is a schematic diagram after isolation by V-shaped grooves in the manufacturing process flow of Example 2. FIG.

具体实施方式 detailed description

下面结合附图和实施例,详细描述本发明的技术方案: Below in conjunction with accompanying drawing and embodiment, describe technical solution of the present invention in detail:

本发明在一般的光电集成电路的工艺基础上,改进了制造方法,使得光电二极管和集成电路模块集成于同一块芯片上,有效地减少了封装难度和成本,降低了寄生效应,提高了可靠性。与主流技术相比,本发明具有以下优点:采用的集成光电集成电路,可以有效地减小封装难度和成本,降低寄生效应,并提高可靠性;采用的光电二极管制作成纵向结构,有效地提升了光电二极管的响应速度;采用的集成电路模块为SOI工艺制作,其寄生电容小,无闩锁效应,且能降低电路的功耗;采用的光电集成电路的集成方式,可有效地将光电二极管和集成电路模块的性能实现最优化。 The invention improves the manufacturing method on the basis of the general photoelectric integrated circuit technology, so that the photodiode and the integrated circuit module are integrated on the same chip, which effectively reduces the packaging difficulty and cost, reduces the parasitic effect, and improves the reliability . Compared with the mainstream technology, the present invention has the following advantages: the integrated photoelectric integrated circuit adopted can effectively reduce packaging difficulty and cost, reduce parasitic effects, and improve reliability; the adopted photodiode is made into a vertical structure, which effectively improves The response speed of the photodiode is improved; the integrated circuit module used is made of SOI technology, its parasitic capacitance is small, there is no latch-up effect, and the power consumption of the circuit can be reduced; the integration method of the photoelectric integrated circuit adopted can effectively integrate the photodiode And the performance of the integrated circuit module is optimized.

实施例1: Example 1:

如图1所示,本例为光电集成电路,包括两个部分:光电二极管和后续的CMOS放大电路。其中光电二极管为一个纵向的PIN管,由与SOI兼容的CMOS工艺制作,后续的CMOS放大电路由若干个NMOS管、PMOS管、电阻和电容经过特定的连接组成,由SOI工艺制作形成。 As shown in Figure 1, this example is an optoelectronic integrated circuit, including two parts: a photodiode and a subsequent CMOS amplifier circuit. The photodiode is a vertical PIN tube, which is made by SOI-compatible CMOS technology. The subsequent CMOS amplifier circuit is composed of several NMOS tubes, PMOS tubes, resistors and capacitors through specific connections, and is made by SOI technology.

其中,光电二极管101,包括PIN管的阳极102,用于接收光照,金属连线103为接阳极的金属连线,在阳极102上面覆盖有一层抗反射层104,用于提升二极管的量子效率,阴极做在背面,图1中未予显示;图1中CMOS放大电路仅显示两种基本的器件结构,其中NMOS管105包括源级108、栅极109和漏极110,PMOS管106包括源级111、栅极112和漏极113,所有的MOS管都由SiO2107隔开,并做在一层SiO2绝缘层之上。 Wherein, the photodiode 101 includes the anode 102 of the PIN tube for receiving light, the metal wire 103 is a metal wire connected to the anode, and the anode 102 is covered with an anti-reflection layer 104 for improving the quantum efficiency of the diode, The cathode is made on the back side, which is not shown in Figure 1; the CMOS amplifier circuit in Figure 1 only shows two basic device structures, wherein the NMOS transistor 105 includes a source 108, a gate 109 and a drain 110, and the PMOS transistor 106 includes a source 111, gate 112 and drain 113, all MOS transistors are separated by SiO2107, and are made on one layer of SiO2 insulating layer.

如图2所示,为本例的部分器件的截面说明图,其中A-A’段为图1中光电二极管沿A-A’的横截面图,N+衬底201作为PIN管的阴极,N-外延层202为PIN管中的I层,P+掺杂层204作为PIN管的阳极,金属电极203和206分别接在正面和背面;B-B’段为图1中沿CMOS放大电路B-B’段的横截面图,整个电路做在SiO2绝缘层214之上,每个器件均由一层SiO2浅槽207进行隔离,NMOS管包括栅极209、源极208和漏极207,PMOS管包括栅极212、源211和漏极213。 As shown in Figure 2, it is a cross-sectional explanatory diagram of some devices of this example, wherein A-A' section is a cross-sectional view of the photodiode in Figure 1 along A-A', N+ substrate 201 is used as the cathode of the PIN tube, and N -The epitaxial layer 202 is the I layer in the PIN tube, the P+ doped layer 204 is used as the anode of the PIN tube, and the metal electrodes 203 and 206 are respectively connected to the front and the back; BB' section is along the CMOS amplifier circuit B- in Fig. 1 The cross-sectional view of section B', the entire circuit is made on the SiO2 insulating layer 214, each device is isolated by a layer of SiO2 shallow grooves 207, the NMOS transistor includes a gate 209, a source electrode 208 and a drain electrode 207, and a PMOS transistor It includes a gate 212 , a source 211 and a drain 213 .

如图3-图7所示,为本例的制造流程: As shown in Figure 3-Figure 7, it is the manufacturing process of this example:

本例采用SIMOX工艺进行制作,具体步骤如下: In this example, the SIMOX process is used for production, and the specific steps are as follows:

1,在半导体衬底301的外延层302用掩模版303将需要制作光电二极管的区域遮住,并进行氧离子注入,如图3所示; 1. In the epitaxial layer 302 of the semiconductor substrate 301, use a mask plate 303 to cover the area where the photodiode needs to be fabricated, and perform oxygen ion implantation, as shown in FIG. 3 ;

2,经过氧离子注入后,形成了初始的氧化层304,如图4所示; 2. After oxygen ion implantation, an initial oxide layer 304 is formed, as shown in FIG. 4 ;

3,经过热处理后,形成所需要的绝缘层305,如图5所示; 3. After heat treatment, the required insulating layer 305 is formed, as shown in FIG. 5 ;

4,将掩模版303去除掉,如图6所示; 4. Remove the mask plate 303, as shown in FIG. 6;

5,利用槽刻蚀,制作出一层隔离层306将CMOS电路部分与光电二极管部分完全隔离开,同时也将CMOS电路中的器件隔离开来,如图7所示。 5. Using trench etching, a layer of isolation layer 306 is formed to completely isolate the CMOS circuit part from the photodiode part, and at the same time isolate the devices in the CMOS circuit, as shown in FIG. 7 .

局部SOI工艺流程完成后,就可以进行常规的纵向光电二极管制作和CMOS电路的制作。具体的纵向光电二极管制作,在公开号为CN101069288A的中国专利中有所提及。 After the local SOI process is completed, conventional vertical photodiode fabrication and CMOS circuit fabrication can be performed. The specific fabrication of vertical photodiodes is mentioned in the Chinese patent with publication number CN101069288A.

实施例2: Example 2:

如图8-图13所示,本例采用直接键合(SDB)技术制作硅片衬底,具体步骤为: As shown in Figure 8-Figure 13, in this example, the direct bonding (SDB) technology is used to fabricate the silicon wafer substrate, and the specific steps are as follows:

1.将一面有氧化层的硅片401(N+掺杂)与无氧化层的硅片402经过键合成SOI结构,如图8所示; 1. Bond a silicon wafer 401 with an oxide layer on one side (N+ doped) and a silicon wafer 402 without an oxide layer to form an SOI structure, as shown in Figure 8;

2.通过湿法刻蚀去除需要制作光电二极管的区域的硅层和氧化层,如图9所示; 2. Remove the silicon layer and oxide layer in the area where the photodiode needs to be fabricated by wet etching, as shown in Figure 9;

3.生长外延层403,如图10所示; 3. growing an epitaxial layer 403, as shown in FIG. 10;

4.将外延层采用抛光工艺至所需的厚度,如图11所示; 4. Polish the epitaxial layer to the desired thickness, as shown in Figure 11;

5.采用横向隔离的方式,将光电器件区域和集成电路区域隔离开,可以采用的方式有沟槽隔离(如图12所示)和V型槽隔离(如图13所示)。 5. Use lateral isolation to isolate the photoelectric device area from the integrated circuit area. The methods that can be used include trench isolation (as shown in Figure 12) and V-groove isolation (as shown in Figure 13).

以上的制作工艺和材料应根据实际工艺环境而决定。 The above manufacturing process and materials should be determined according to the actual process environment.

Claims (2)

1. the manufacture method of an integrated optoelectronic circuit, it is characterised in that comprise the following steps:
A. silicon chip is processed, make a part for silicon chip possess oxide layer; Particularly as follows:
A1. the silicon chip (402) of the silicon chip (401) and non-oxidation layer that have oxide layer through and being bonded to soi structure;
A2. by a part for the soi structure of synthesis in wet etching removal step a1, being specially the silicon chip (402) removing part non-oxidation layer and the silicon chip (401) having oxide layer being connected with this part, the part of the removed silicon chip (401) having oxide layer includes the oxide layer of this part;
A3. the structure growing epitaxial layers (403) obtained in step a2;
A4. glossing is adopted to be worked into required thickness the structure obtained in step a3;
B., silicon chip have the part of oxide layer and the part of non-oxidation layer isolate; It is specially and multiple sealing coat is set in the oxide layer of the silicon chip (401) having oxide layer, the silicon chip in oxide layer is isolated into multiple part;
C. on silicon chip, the part of non-oxidation layer manufactures photoelectric device, manufactures electronic device in oxide layer; Described photoelectric device adopts vertical structure, and for longitudinal P IN photodiode, electronic device adopts SOI technology.
2. the manufacture method of a kind of integrated optoelectronic circuit according to claim 1, it is characterised in that described arrange multiple sealing coat be adopt by etch formed V-groove isolation mode isolate.
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