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CN114852948B - MEMS sensor integrated device based on through silicon via and manufacturing method thereof - Google Patents

MEMS sensor integrated device based on through silicon via and manufacturing method thereof Download PDF

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CN114852948B
CN114852948B CN202210474084.7A CN202210474084A CN114852948B CN 114852948 B CN114852948 B CN 114852948B CN 202210474084 A CN202210474084 A CN 202210474084A CN 114852948 B CN114852948 B CN 114852948B
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CN114852948A (en
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王琛
张思勉
武逸飞
邓晓楠
柯声贤
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Tsinghua University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B7/00Microstructural systems; Auxiliary parts of microstructural devices or systems
    • B81B7/0006Interconnects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B7/00Microstructural systems; Auxiliary parts of microstructural devices or systems
    • B81B7/02Microstructural systems; Auxiliary parts of microstructural devices or systems containing distinct electrical or optical devices of particular relevance for their function, e.g. microelectro-mechanical systems [MEMS]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00015Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
    • B81C1/00261Processes for packaging MEMS devices
    • B81C1/00301Connecting electric signal lines from the MEMS device with external electrical signal lines, e.g. through vias
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2201/00Specific applications of microelectromechanical systems
    • B81B2201/02Sensors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C2203/00Forming microstructural systems
    • B81C2203/01Packaging MEMS

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  • Manufacturing & Machinery (AREA)
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Abstract

本公开涉及一种基于硅通孔的MEMS传感器集成装置及其制造方法。装置包括:垂直堆叠的多个传感器和传感器之间的互连层,各传感器包括传感器主体和承载传感器主体且设置有多个硅通孔的基体;传感器主体的测试电极位于基体的上方并连接到对应的各硅通孔、敏感材料层覆盖在测试电极上;各互连层的敏感层孔用于容纳下方传感器的敏感材料层;各互连层的多个线通孔中分别设置的互连线的两端分别连接到下方传感器的测试电极和上方传感器的硅通孔,各传感器中的各硅通孔分别属于不同的硅通孔组,各硅通孔组中的硅通孔通过互连线串联,至少一个硅通孔组中的各硅通孔的对称轴重合。装置集成密度更高、封装尺寸更小、功耗和成本更低,适用范围广。

The present disclosure relates to a through-silicon via-based MEMS sensor integrated device and a manufacturing method thereof. The device includes: a plurality of vertically stacked sensors and an interconnection layer between the sensors; each sensor includes a sensor body and a base body carrying the sensor body and provided with a plurality of through silicon holes; the test electrode of the sensor body is located above the base body and connected to The corresponding through silicon holes and sensitive material layers cover the test electrodes; the sensitive layer holes of each interconnection layer are used to accommodate the sensitive material layer of the sensor below; the interconnections are respectively provided in the multiple line through holes of each interconnection layer Both ends of the line are connected to the test electrode of the lower sensor and the through silicon via of the upper sensor respectively. Each through silicon via in each sensor belongs to a different through silicon via group, and the through silicon vias in each through silicon via group are interconnected. The lines are connected in series, and the symmetry axes of each through silicon hole in at least one through silicon hole group are coincident. The device integration density is higher, the package size is smaller, the power consumption and cost are lower, and the application range is wide.

Description

基于硅通孔的MEMS传感器集成装置及其制造方法MEMS sensor integrated device based on through silicon vias and manufacturing method thereof

技术领域Technical Field

本公开涉及集成电路封装技术领域,尤其涉及一种基于硅通孔的MEMS传感器集成装置及其制造方法。The present disclosure relates to the technical field of integrated circuit packaging, and in particular to a through-silicon via-based MEMS sensor integrated device and a manufacturing method thereof.

背景技术Background technique

随着制造水平的提高,微机电系统(Micro Electro Mechanical System,MEMS)技术被逐渐应用于传感器领域。相比于传统传感器,MEMS传感器体积更小、重量更轻、功耗更低、成本更低,更加适用于在智能设备与可穿戴设备上的集成。因此,MEMS传感器逐渐成为该领域的重要方向之一。With the improvement of manufacturing level, Micro Electro Mechanical System (MEMS) technology is gradually being applied to the field of sensors. Compared with traditional sensors, MEMS sensors are smaller in size, lighter in weight, lower in power consumption, and lower in cost, making them more suitable for integration in smart devices and wearable devices. Therefore, MEMS sensors are gradually becoming one of the important directions in this field.

在推动传感器走向小型化的同时,相关技术中的传感器芯片的设计受到了挑战。例如,器件小型化要求更高可靠性与更小体积的三维封装;敏感膜涂覆工艺需要与晶圆级制备工艺更好兼容;更高效率的流片过程要求晶圆级的植球工艺与封装工艺设计。另外,传感器走向小型化的需求,也对工业进行微型传感器的批量制备提出了更高的要求。复杂且微小的器件结构要求生产过程整体更严格的失效分析与应力控制,批量化与低成本的目标要求器件采取晶圆级封装,敏感薄膜的制备要求与微纳加工技术与晶圆级的衬底相兼容。While pushing sensors towards miniaturization, the design of sensor chips in related technologies has been challenged. For example, device miniaturization requires higher reliability and smaller three-dimensional packaging; the sensitive film coating process needs to be better compatible with the wafer-level preparation process; and a more efficient tape-out process requires wafer-level ball implantation and packaging process design. In addition, the demand for miniaturization of sensors has also put forward higher requirements for the mass production of micro-sensors in the industry. The complex and tiny device structure requires stricter failure analysis and stress control in the entire production process. The goals of mass production and low cost require the device to adopt wafer-level packaging, and the preparation of sensitive films requires compatibility with micro-nano processing technology and wafer-level substrates.

因此,如何提高一种能够解决上述问题的薄膜型传感器及其制造方法是亟待解决的问题。Therefore, how to improve a thin film sensor and its manufacturing method that can solve the above problems is an urgent problem to be solved.

传感器是实现电子设备感知空气及环境不可或缺的器件。因此,传感器被广泛应用在环境、能源、石化、医疗、工业及国防等各个领域,成为各国高新技术发展方向之一。随着微电子技术的发展和芯片集成度的提高,传感器的微型化、低功耗和高综合性能成为发展趋势。Sensors are indispensable devices for electronic devices to sense the air and environment. Therefore, sensors are widely used in various fields such as environment, energy, petrochemicals, medical care, industry and national defense, and have become one of the high-tech development directions of various countries. With the development of microelectronics technology and the improvement of chip integration, miniaturization, low power consumption and high comprehensive performance of sensors have become a development trend.

微机电系统(Micro-Electro-Mechanical System,MEMS)技术将传感器件的加热元件和敏感元件集成为一体,相比于传统的陶瓷衬底基传感器,采用MEMS技术的微结构气体传感器由于具有体积小、功耗低、灵敏度高、重复性好、易批量生产等优点而成为研究热点。Micro-Electro-Mechanical System (MEMS) technology integrates the heating element and sensitive element of the sensor device. Compared with traditional ceramic substrate-based sensors, microstructured gas sensors using MEMS technology have small size. , low power consumption, high sensitivity, good repeatability, easy mass production and other advantages, it has become a research hotspot.

为了进一步拓展微型传感器件的功能范围和应用领域,需要推动微系统走向更高集成密度、更小封装尺寸、更低功耗、更低成本结构。但相关技术中MEMS传感器的典型结构仍然需要采用引线键合引出电极的封装方式,无法实现晶圆级封装,导致器件尺寸受限于外部封装而不能实现进一步缩小,不能充分发挥出MEMS加工工艺制造微型化器件的优势,不利于传感器高密度阵列的制备,限制了传感器的应用范围。In order to further expand the functional scope and application fields of micro-sensor devices, it is necessary to promote microsystems towards higher integration density, smaller package size, lower power consumption, and lower cost structures. However, the typical structure of MEMS sensors in related technologies still requires the packaging method of wire-bonding lead-out electrodes, which cannot achieve wafer-level packaging. As a result, the size of the device is limited by external packaging and cannot be further reduced, and the MEMS processing technology cannot be fully utilized. The advantages of miniaturized devices are not conducive to the preparation of high-density arrays of sensors, which limits the application range of sensors.

如何提供一种更高集成密度、更小封装尺寸、更低功耗、更低成本的MEMS传感器集成装置是亟待解决的技术问题。How to provide a MEMS sensor integrated device with higher integration density, smaller package size, lower power consumption, and lower cost is a technical problem that needs to be solved urgently.

发明内容Summary of the invention

有鉴于此,本公开提出了一种基于硅通孔的MEMS传感器集成装置及其制造方法。In view of this, the present disclosure proposes a through-silicon via-based MEMS sensor integrated device and a manufacturing method thereof.

根据本公开的一方面,提供了一种基于硅通孔的MEMS传感器集成装置,所述装置包括:垂直堆叠的多个传感器和上下相邻的两个所述传感器之间的互连层,各所述传感器包括传感器主体和用于承载所述传感器主体的基体;According to an aspect of the present disclosure, a MEMS sensor integrated device based on through silicon vias is provided. The device includes: a plurality of vertically stacked sensors and an interconnection layer between two adjacent sensors, each of which is The sensor includes a sensor body and a base body for carrying the sensor body;

所述基体设置有多个硅通孔;所述传感器主体包括测试电极和敏感材料层;所述测试电极位于所述基体的上方并连接到对应的各所述硅通孔;所述敏感材料层覆盖在所述测试电极的目标区域上;The base body is provided with a plurality of through silicon holes; the sensor body includes a test electrode and a sensitive material layer; the test electrode is located above the base body and connected to the corresponding through silicon hole; the sensitive material layer Cover the target area of the test electrode;

各所述互连层包括敏感层孔和多个线通孔,各所述线通孔中设置有互连线,各所述互连线的两端分别连接到所在互连层下方传感器的测试电极和所在互连层上方传感器的硅通孔,各所述敏感层孔用于容纳所在互连层下方传感器的敏感材料层;Each of the interconnection layers includes a sensitive layer hole and a plurality of line through holes. Each of the line through holes is provided with an interconnection line. Both ends of each of the interconnection lines are respectively connected to the test of the sensor below the interconnection layer. The through silicon holes of the electrodes and sensors above the interconnection layer, and each of the sensitive layer holes is used to accommodate the sensitive material layer of the sensor below the interconnection layer;

其中,每个所述传感器中的多个硅通孔分别属于不同的硅通孔组,各所述硅通孔组中包括各所述传感器的多个硅通孔中通过所述互连线串联的硅通孔,至少一个所述硅通孔组中的各所述硅通孔的对称轴重合。The multiple silicon vias in each of the sensors belong to different silicon via groups, each of the silicon via groups includes silicon vias in the multiple silicon vias of each sensor that are connected in series through the interconnection lines, and the symmetry axes of the silicon vias in at least one of the silicon via groups coincide.

在一种可能的实现方式中,所述基体还包括衬底、介质层和第一绝缘层;In a possible implementation, the base body further includes a substrate, a dielectric layer and a first insulating layer;

所述介质层覆盖在所述衬底的第一面的至少部分区域,各所述硅通孔贯穿于所述衬底和所述介质层;The dielectric layer covers at least a portion of the first surface of the substrate, and each of the through silicon vias penetrates the substrate and the dielectric layer;

所述第一绝缘层覆盖在所述衬底的第二面且至少暴露出对应于各所述硅通孔的通孔区域;The first insulating layer covers the second surface of the substrate and at least exposes a through-hole region corresponding to each of the through-silicon vias;

其中,所述测试电极位于所述介质层上方。Wherein, the test electrode is located above the dielectric layer.

在一种可能的实现方式中,所述传感器主体还包括:加热电极和第二绝缘层,In a possible implementation, the sensor body further includes: a heating electrode and a second insulating layer,

所述加热电极,位于所述介质层上方且与对应的各所述硅通孔连接;The heating electrode is located above the dielectric layer and connected to the corresponding through silicon holes;

所述第二绝缘层,位于所述介质层上方且覆盖在所述加热电极的除第一连接区的表面,所述第二绝缘层设置有至少两个电极通孔,各所述电极通孔暴露所述测试电极所连接的硅通孔;The second insulating layer is located above the dielectric layer and covers the surface of the heating electrode except the first connection area. The second insulating layer is provided with at least two electrode through holes, each of the electrode through holes Exposing the through silicon via connected to the test electrode;

其中,所述测试电极位于所述第二绝缘层上方且所述目标区域与所述加热电极重叠,并通过所述电极通孔连接到对应的各所述硅通孔。Wherein, the test electrode is located above the second insulating layer and the target area overlaps the heating electrode and is connected to the corresponding through silicon via through the electrode through hole.

在一种可能的实现方式中,每个所述硅通孔组中的各所述硅通孔的对称轴重合,且不同所述硅通孔组中的各所述硅通孔的对称轴所处直线不相同。In a possible implementation, the symmetry axes of the through silicon holes in each of the through silicon via groups coincide with each other, and are located at different locations from the symmetry axes of the through silicon holes in the through silicon via group. The straight lines are different.

在一种可能的实现方式中,多个所述硅通孔组中存在至少一个不重合硅通孔组,所述不重合硅通孔组的多个硅通孔中至少两个硅通孔的对称轴不重合,In a possible implementation, there is at least one non-overlapping through silicon via group among the plurality of through silicon via groups, and at least two through silicon holes among the plurality of through silicon holes in the non-overlapping through silicon via group are The axes of symmetry do not coincide,

其中,所述互连层中还设置有金属布线,所述金属布线用于连接所在互连层下方传感器的测试电极和所在互连层上方传感器的硅通孔,和/或,所述金属布线用于连接所在互连层下方传感器的加热电极和所在互连层上方传感器的硅通孔。Wherein, the interconnection layer is also provided with metal wiring, the metal wiring is used to connect the test electrode of the sensor below the interconnection layer and the through silicon via of the sensor above the interconnection layer, and/or, the metal wiring Used to connect the heating electrode of the sensor below the interconnect layer to the through silicon via of the sensor above the interconnect layer.

在一种可能的实现方式中,所述多个传感器包括气体传感器、温度传感器和加速度传感器,所述装置中所述气体传感器位于所述温度传感器的上方,所述加速度传感器位于所述温度传感器的下方。In a possible implementation, the multiple sensors include a gas sensor, a temperature sensor, and an acceleration sensor. In the device, the gas sensor is located above the temperature sensor, and the acceleration sensor is located below the temperature sensor.

在一种可能的实现方式中,所述装置还包括:基板和报警模块,所述多个传感器中处于最下层的传感器和所述报警模块,固定在所述基板上并通过所述基板电连接,In a possible implementation, the device further includes: a substrate and an alarm module. The lowest sensor among the plurality of sensors and the alarm module are fixed on the substrate and electrically connected through the substrate. ,

所述报警模块,用于在根据各所述传感器的检测结果确定满足报警条件的情况下,发出告警提示。The alarm module is configured to issue an alarm prompt when it is determined that the alarm conditions are met based on the detection results of each of the sensors.

在一种可能的实现方式中,各所述硅通孔的直径为20μm~50μm,各所述硅通孔的深宽比为5:1~10:1。In a possible implementation manner, the diameter of each through silicon hole is 20 μm to 50 μm, and the aspect ratio of each through silicon hole is 5:1 to 10:1.

在一种可能的实现方式中,所述加热电极的形状包括可延展形状,所述可延展形状包括蛇形、S形中的任意一种;并且/或者In a possible implementation, the shape of the heating electrode includes an extensible shape, and the extensible shape includes any one of a serpentine shape and an S-shape; and/or

所述测试电极包括叉指电极,所述目标区域为所述叉指电极的周期性图案区域,所述加热电极的可延展形状区域和所述目标区域的尺寸匹配且位置重叠。The test electrode includes an interdigital electrode, the target area is a periodic pattern area of the interdigital electrode, and the extensible shape area of the heating electrode matches the size of the target area and overlaps in position.

根据本公开的另一方面,提供了一种基于硅通孔的MEMS传感器集成装置的制造方法,其特征在于,用于制造上述基于硅通孔的MEMS传感器集成装置,所述方法包括:传感器制造步骤和传感器堆叠步骤,According to another aspect of the present disclosure, a method for manufacturing a through-silicon via-based MEMS sensor integrated device is provided, which is characterized in that it is used to manufacture the above-mentioned through-silicon via-based MEMS sensor integrated device, and the method includes: sensor manufacturing steps and sensor stacking steps,

所述传感器制造步骤包括:在衬底的第一面制备介质层;制造贯穿所述衬底和所述介质层的多个硅通孔;在所述衬底的第二面制备第一绝缘层,并对所述第一绝缘层进行刻蚀以至少暴露出各所述硅通孔对应的通孔区域,得到所述传感器的基体;在所述介质层的上方制造测试电极;在所述测试电极的目标区域的上方制造敏感材料层,得到传感器主体,完成传感器制备;The sensor manufacturing steps include: preparing a dielectric layer on the first surface of the substrate; manufacturing a plurality of silicon through holes penetrating the substrate and the dielectric layer; preparing a first insulating layer on the second surface of the substrate, and etching the first insulating layer to at least expose the through hole area corresponding to each silicon through hole, so as to obtain the base of the sensor; manufacturing a test electrode above the dielectric layer; manufacturing a sensitive material layer above the target area of the test electrode, so as to obtain the sensor body, and complete the sensor manufacturing;

所述传感器堆叠步骤包括:基于装置中多个传感器的堆叠顺序,在最下层传感器的上方制备互连层;对所述互连层进行刻蚀形成敏感层孔和多个线通孔,以通过所述敏感层孔暴露出所述敏感材料层、通过各所述线通孔暴露出所述测试电极;在所述线通孔中填充金属形成互连线;将所述最下层传感器上方与所述最下层传感器相邻的上层传感器固定到所述互连层;将所述上层传感器作为最下层传感器继续进行下一传感器的固定,直至全部传感器均完成堆叠。The sensor stacking step includes: preparing an interconnection layer above the lowest sensor based on the stacking sequence of multiple sensors in the device; etching the interconnection layer to form sensitive layer holes and multiple line through holes to pass through The sensitive layer holes expose the sensitive material layer, and the test electrodes are exposed through each of the line through holes; fill the line through holes with metal to form interconnection lines; connect the uppermost layer of the sensor to the The upper sensor adjacent to the lowermost sensor is fixed to the interconnection layer; the upper sensor is used as the lowermost sensor to continue fixing the next sensor until all the sensors are stacked.

根据下面参考附图对示例性实施例的详细说明,本公开的其它特征及方面将变得清楚。Other features and aspects of the present disclosure will become apparent from the following detailed description of exemplary embodiments with reference to the accompanying drawings.

本公开实施例所提供了的基于硅通孔的MEMS传感器集成装置及其制造方法,所制造的装置具有更高的集成密度、更小的封装尺寸、更低的功耗和更低的成本,且适用范围广。The MEMS sensor integrated device based on through silicon vias and its manufacturing method provided by the embodiments of the present disclosure have higher integration density, smaller package size, lower power consumption and lower cost. And has a wide range of applications.

附图说明Description of drawings

包含在说明书中并且构成说明书的一部分的附图与说明书一起示出了本公开的示例性实施例、特征和方面,并且用于解释本公开的原理。The accompanying drawings, which are incorporated in and constitute a part of the specification, illustrate exemplary embodiments, features, and aspects of the disclosure and together with the description serve to explain the principles of the disclosure.

图1、图2示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的结构示意图。1 and 2 show a schematic structural diagram of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

图3A、图3B示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置中传感器的结构示意图。3A and 3B show a schematic structural diagram of a sensor in a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

图4示出根据本公开一实施例的加热电极的结构示意图。Figure 4 shows a schematic structural diagram of a heating electrode according to an embodiment of the present disclosure.

图5示出根据本公开一实施例的测试电极的结构示意图。Figure 5 shows a schematic structural diagram of a test electrode according to an embodiment of the present disclosure.

图6示出根据本公开一实施例的敏感材料层的结构示意图。Figure 6 shows a schematic structural diagram of a sensitive material layer according to an embodiment of the present disclosure.

图7示出根据本公开一实施例的加热电极、测试电极和敏感材料层的相对位置示意图。FIG. 7 is a schematic diagram showing the relative positions of a heating electrode, a testing electrode, and a sensitive material layer according to an embodiment of the present disclosure.

图8示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的结构示意图。FIG. 8 shows a schematic structural diagram of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

图9示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的结构示意图。FIG. 9 shows a schematic structural diagram of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

图10示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置中盖帽层的结构示意图。FIG. 10 shows a schematic structural diagram of a capping layer in a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

图11示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的结构示意图。FIG. 11 shows a schematic structural diagram of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

图12示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的制造方法的流程图。FIG. 12 shows a flow chart of a manufacturing method of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

图13示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的制造方法中制造传感器的过程示意图。FIG. 13 shows a schematic diagram of a process of manufacturing a sensor in a method of manufacturing a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

图14示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的制造方法中传感器堆叠的过程示意图。14 shows a schematic diagram of a process of sensor stacking in a manufacturing method of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

图15示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的制造方法中硅通孔的制造过程示意图。FIG. 15 shows a schematic diagram of the manufacturing process of the through silicon via in the manufacturing method of the through silicon via based MEMS sensor integrated device according to an embodiment of the present disclosure.

具体实施方式Detailed ways

以下将参考附图详细说明本公开的各种示例性实施例、特征和方面。附图中相同的附图标记表示功能相同或相似的元件。尽管在附图中示出了实施例的各种方面,但是除非特别指出,不必按比例绘制附图。Various exemplary embodiments, features, and aspects of the present disclosure will be described in detail below with reference to the accompanying drawings. The same reference numbers in the drawings identify functionally identical or similar elements. Although various aspects of the embodiments are illustrated in the drawings, the drawings are not necessarily drawn to scale unless otherwise indicated.

在这里专用的词“示例性”意为“用作例子、实施例或说明性”。这里作为“示例性”所说明的任何实施例不必解释为优于或好于其它实施例。The word "exemplary" as used herein means "serving as an example, example, or illustrative." Any embodiment described herein as "exemplary" is not necessarily to be construed as superior or superior to other embodiments.

另外,为了更好的说明本公开,在下文的具体实施方式中给出了众多的具体细节。本领域技术人员应当理解,没有某些具体细节,本公开同样可以实施。在一些实例中,对于本领域技术人员熟知的方法、手段、元件和电路未作详细描述,以便于凸显本公开的主旨。In addition, in order to better illustrate the present disclosure, numerous specific details are given in the following specific embodiments. It should be understood by those skilled in the art that the present disclosure can also be implemented without certain specific details. In some examples, methods, means, components and circuits well known to those skilled in the art are not described in detail in order to highlight the main purpose of the present disclosure.

为解决上述技术问题,本公开提供了一种基于硅通孔的MEMS传感器集成装置及其制造方法,所制造的装置具有更高的集成密度、更小的封装尺寸、更低的功耗和更低的成本,且适用范围广。In order to solve the above technical problems, the present disclosure provides a through-silicon via-based MEMS sensor integrated device and a manufacturing method thereof. The manufactured device has higher integration density, smaller package size, lower power consumption and more Low cost and wide application range.

图1、图2示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的结构示意图。如图1、图2所示,该装置包括垂直堆叠的多个传感器和上下相邻的两个所述传感器之间的互连层51,各所述传感器包括传感器主体和用于承载所述传感器主体的基体1。1 and 2 show a schematic structural diagram of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure. As shown in Figures 1 and 2, the device includes a plurality of vertically stacked sensors and an interconnection layer 51 between two adjacent sensors. Each sensor includes a sensor body and a sensor for carrying the sensor. The main body of the body 1.

如图1、图2所示,所述基体1设置有多个硅通孔15。所述传感器主体包括测试电极20和敏感材料层21。所述测试电极20位于所述基体1的上方并连接到对应的各所述硅通孔15。所述敏感材料层21覆盖在所述测试电极20的目标区域上。As shown in Fig. 1 and Fig. 2, the substrate 1 is provided with a plurality of through silicon vias 15. The sensor body comprises a test electrode 20 and a sensitive material layer 21. The test electrode 20 is located above the substrate 1 and connected to the corresponding through silicon vias 15. The sensitive material layer 21 covers the target area of the test electrode 20.

如图1、图2所示,各所述互连层51包括敏感层孔511和多个线通孔512,各所述线通孔512中设置有互连线513,各所述互连线513的两端分别连接到所在互连层51下方传感器的测试电极20和所在互连层51上方传感器的硅通孔15,各所述敏感层孔511用于容纳所在互连层51下方传感器的敏感材料层21。其中,敏感层孔511可以为图1、图2所示的通孔。或者,若敏感材料层21工作过程中不受上方是否覆盖膜层影响,互连层51中可以不设置敏感层孔511,此时,互连层51直接覆盖在敏感材料层21表面。As shown in Figures 1 and 2, each of the interconnection layers 51 includes a sensitive layer hole 511 and a plurality of line through holes 512. Each of the line through holes 512 is provided with an interconnection line 513. Each of the interconnection lines The two ends of 513 are respectively connected to the test electrode 20 of the sensor below the interconnection layer 51 and the through silicon hole 15 of the sensor above the interconnection layer 51. Each of the sensitive layer holes 511 is used to accommodate the sensor below the interconnection layer 51. Sensitive material layer 21. The sensitive layer hole 511 may be a through hole as shown in FIG. 1 and FIG. 2 . Alternatively, if the working process of the sensitive material layer 21 is not affected by whether it is covered with a film layer, the sensitive layer holes 511 may not be provided in the interconnection layer 51 . In this case, the interconnection layer 51 directly covers the surface of the sensitive material layer 21 .

在一种可能的实现方式中,如图1、图2所示,每个所述传感器中的多个硅通孔15分别属于不同的硅通孔组,各所述硅通孔组中包括各所述传感器的多个硅通孔15中通过所述互连线串联的硅通孔15,至少一个所述硅通孔组中的各所述硅通孔15的对称轴重合。例如,如图1、图2所示的虚线框80中的多个硅通孔15即属于同一硅通孔组,各个硅通孔15的对称轴重合。In a possible implementation, as shown in FIG. 1 and FIG. 2 , the plurality of TSVs 15 in each of the sensors belong to different TSV groups, each TSV group includes TSVs 15 connected in series through the interconnection lines among the plurality of TSVs 15 in each of the sensors, and the symmetry axes of the TSVs 15 in at least one TSV group coincide. For example, the plurality of TSVs 15 in the dashed box 80 shown in FIG. 1 and FIG. 2 belong to the same TSV group, and the symmetry axes of the TSVs 15 coincide.

在一种可能的实现方式中,如图2所示,多个所述硅通孔组中可以存在至少一个不重合硅通孔组,所述不重合硅通孔组的多个硅通孔15中至少两个硅通孔15的对称轴不重合。则互连层51中还设置有金属布线514,所述金属布线514,用于连接所在互连层下方传感器的测试电极和所在互连层上方传感器的硅通孔,和/或,所述金属布线514用于连接所在互连层下方传感器的加热电极和所在互连层上方传感器的硅通孔。其中,多个所述硅通孔组中每一个可以均为不重合硅通孔组。In a possible implementation, as shown in FIG. 2 , there may be at least one non-overlapping through silicon via group among the plurality of through silicon via groups, and the plurality of through silicon vias 15 of the non-overlapping through silicon via group The symmetry axes of at least two through silicon holes 15 do not coincide. Then the interconnection layer 51 is also provided with a metal wiring 514. The metal wiring 514 is used to connect the test electrode of the sensor below the interconnection layer and the through silicon via of the sensor above the interconnection layer, and/or the metal wiring 514. The wiring 514 is used to connect the heating electrode of the sensor below the interconnection layer and the through silicon via of the sensor above the interconnection layer. Each of the plurality of through silicon via groups may be a non-overlapping through silicon via group.

在本实施例中,衬底11可以为硅衬底。敏感材料层的材料可以为氧化物、金属、高分子聚合物等,根据实际需要切换不同的材料。敏感材料层可以用自组装、整晶圆涂覆、溅射等成膜工艺形成,并通过光刻实现图案化,从而与晶圆级制造技术更好兼容。其中,传感器主体工作过程中可以在测试电极两端施加一定电压,当敏感材料层在传感过程中发生特异性变化时,测试电极两端电信号会发生改变,通过读取该信号变化可实现相应检测。In this embodiment, the substrate 11 may be a silicon substrate. The material of the sensitive material layer can be oxide, metal, polymer, etc., and different materials can be switched according to actual needs. The sensitive material layer can be formed using film-forming processes such as self-assembly, whole-wafer coating, and sputtering, and can be patterned through photolithography to be better compatible with wafer-level manufacturing technology. Among them, a certain voltage can be applied to both ends of the test electrode during the working process of the sensor body. When the sensitive material layer undergoes specific changes during the sensing process, the electrical signal at both ends of the test electrode will change. This can be achieved by reading the signal change. Test accordingly.

图3A、图3B示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置中传感器的结构示意图。3A and 3B show a schematic structural diagram of a sensor in a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure.

在一种可能的实现方式中,如图3A、图3B所示,所述基体1还包括衬底11、介质层12和第一绝缘层16。所述介质层12覆盖在所述衬底11的第一面的至少部分区域,各所述硅通孔15贯穿于所述衬底11和所述介质层12。所述第一绝缘层16覆盖在所述衬底11的第二面且至少暴露出对应于各所述硅通孔15的通孔区域17。其中,所述测试电极20位于所述介质层12上方。In a possible implementation, as shown in FIG. 3A and FIG. 3B , the base 1 further includes a substrate 11 , a dielectric layer 12 and a first insulating layer 16 . The dielectric layer 12 covers at least part of the first surface of the substrate 11 , and each of the through silicon holes 15 penetrates the substrate 11 and the dielectric layer 12 . The first insulating layer 16 covers the second surface of the substrate 11 and exposes at least the through hole area 17 corresponding to each of the through silicon holes 15 . Wherein, the test electrode 20 is located above the dielectric layer 12 .

在该实现方式中,介质层用于将衬底与传感器主体中的测试电极以及下文描述的加热电极隔离。介质层可以为ONO介质层,ONO介质层可以为氧化硅(SiO2)/氮化硅(SiNx)/氧化硅层,可以采用等离子体增强化学气相沉积法(Plasma Enhanced ChemicalVaporDeposition,PECVD)等工艺制备。由于氮化硅与氧化硅有相反的热膨胀特性,因此可在高温工艺中减少热膨胀带来的附加应力,所以可以将介质层设置为ONO介质层。例如,如图3B所示,介质层12可以包括氧化硅层121、氮化硅层122和氧化硅层123。In this implementation, a dielectric layer is used to isolate the substrate from the test electrode in the sensor body and the heating electrode described below. The dielectric layer can be an ONO dielectric layer. The ONO dielectric layer can be a silicon oxide (SiO 2 )/silicon nitride (SiN x )/silicon oxide layer. Plasma Enhanced Chemical Vapor Deposition (PECVD) and other processes can be used. preparation. Since silicon nitride and silicon oxide have opposite thermal expansion characteristics, the additional stress caused by thermal expansion can be reduced in high-temperature processes, so the dielectric layer can be set as an ONO dielectric layer. For example, as shown in FIG. 3B , the dielectric layer 12 may include a silicon oxide layer 121 , a silicon nitride layer 122 and a silicon oxide layer 123 .

在该实现方式中,第一绝缘层的材料可以是氧化硅等绝缘材料,第一绝缘层的厚度可以为300nm~1000nm。本领域技术人员可以根据实际需要对介质层、第一绝缘层的材料、尺寸进行设置,本公开对此不作限制。In this implementation manner, the material of the first insulating layer may be an insulating material such as silicon oxide, and the thickness of the first insulating layer may be 300 nm to 1000 nm. Those skilled in the art can set the materials and sizes of the dielectric layer and the first insulating layer according to actual needs, and this disclosure does not limit this.

在一种可能的实现方式中,如图3B所示,在所制造的传感器中敏感材料层21需要加热到一定温度后才能正常工作的情况下,所述传感器主体还包括:加热电极18和第二绝缘层19。所述加热电极18,位于所述介质层12上方且与对应的各所述硅通孔15连接。所述第二绝缘层19,位于所述介质层12上方且覆盖在所述加热电极18的除第一连接区181(如图4所示)的表面。所述第二绝缘层19设置有至少两个电极通孔191,各所述电极通孔191暴露所述测试电极20所连接的硅通孔15。其中,所述测试电极20位于所述第二绝缘层19上方且所述目标区域与所述加热电极18重叠,并通过所述电极通孔191连接到对应的各所述硅通孔15。In a possible implementation, as shown in FIG3B , in the case where the sensitive material layer 21 in the manufactured sensor needs to be heated to a certain temperature before it can work normally, the sensor body further includes: a heating electrode 18 and a second insulating layer 19. The heating electrode 18 is located above the dielectric layer 12 and connected to the corresponding through-silicon vias 15. The second insulating layer 19 is located above the dielectric layer 12 and covers the surface of the heating electrode 18 except the first connection area 181 (as shown in FIG4 ). The second insulating layer 19 is provided with at least two electrode through holes 191, each of which exposes the through-silicon via 15 to which the test electrode 20 is connected. The test electrode 20 is located above the second insulating layer 19 and the target area overlaps with the heating electrode 18, and is connected to the corresponding through-silicon vias 15 through the electrode through holes 191.

在该实现方式中,加热电极18用于在通电时产生热量,这些热量能够对传感器主体中敏感材料层21进行加热,对敏感材料层21的温度进行调节,使得敏感材料层21在传感器工作过程中处于工作温度,保证传感器主体可以进行相应的检测。其中,若传感器为气体传感器(也即用于对外界环境中的气体种类和/或浓度进行检测的传感器),则传感器主体还可以包括加热电极18、第二绝缘层19,敏感材料层21的材料可以是气敏材料,气敏材料被加热后可以与气体分子进行特异性结合。第二绝缘层19用于隔绝测试电极20和加热电极18,使得测试电极20和加热电极18互不联通。其中,第二绝缘层19的材料可以为氧化硅、氮化硅等绝缘材料,本公开对此不作限制。In this implementation, the heating electrode 18 is used to generate heat when energized. This heat can heat the sensitive material layer 21 in the sensor body and adjust the temperature of the sensitive material layer 21 so that the sensitive material layer 21 can be used during the working process of the sensor. at the working temperature to ensure that the sensor body can perform corresponding detection. Wherein, if the sensor is a gas sensor (that is, a sensor used to detect gas types and/or concentrations in the external environment), the sensor body may also include a heating electrode 18, a second insulating layer 19, and a sensitive material layer 21. The material can be a gas-sensitive material, and the gas-sensitive material can specifically bind to gas molecules after being heated. The second insulating layer 19 is used to isolate the test electrode 20 and the heating electrode 18 so that the test electrode 20 and the heating electrode 18 are not connected to each other. The material of the second insulating layer 19 may be silicon oxide, silicon nitride or other insulating materials, which is not limited in this disclosure.

图4示出根据本公开一实施例的加热电极的结构示意图。图5示出根据本公开一实施例的测试电极的结构示意图。图6示出根据本公开一实施例的敏感材料层的结构示意图。图7示出根据本公开一实施例的加热电极、测试电极和敏感材料层的相对位置示意图。其中,为更清晰的示意加热电极18、测试电极20和敏感材料层21在空间中的相对位置关系,图7并未示出第二绝缘层19。Figure 4 shows a schematic structural diagram of a heating electrode according to an embodiment of the present disclosure. Figure 5 shows a schematic structural diagram of a test electrode according to an embodiment of the present disclosure. Figure 6 shows a schematic structural diagram of a sensitive material layer according to an embodiment of the present disclosure. Figure 7 shows a schematic diagram of the relative positions of the heating electrode, the test electrode and the sensitive material layer according to an embodiment of the present disclosure. Among them, in order to more clearly illustrate the relative positional relationship between the heating electrode 18, the test electrode 20 and the sensitive material layer 21 in space, the second insulating layer 19 is not shown in FIG. 7 .

在一种可能的实现方式中,所述加热电极18的形状可以包括可延展形状,所述可延展形状可以包括如图4、图7所示的蛇形、S形等具有延展性的形状。这样,可以增加加热电极的长度。加热电极18可以包括可延展形状区域M1、用于连接硅通孔15的第一连接区181、用于实现可延展形状区域M1与第一连接区181之间连接的第一导线区182。In one possible implementation, the shape of the heating electrode 18 may include an extensible shape, and the extensible shape may include a serpentine shape, an S shape, or other malleable shapes as shown in FIG. 4 and FIG. 7 . In this way, the length of the heating electrode can be increased. The heating electrode 18 may include a ductile shape region M1, a first connection region 181 for connecting the through silicon via 15, and a first wire region 182 for realizing connection between the ductile shape region M1 and the first connection region 181.

在一种可能的实现方式中,如图5所示,测试电极20可以为叉指电极。叉指电极中互不联通的叉指之间可以通过其上方覆盖的敏感材料层21实现联通。测试电极20可以包括周期性图案区域M2、用于连接硅通孔15的第二连接区201、用于实现周期性图案区域M2与第二连接区201之间连接的第二导线区202。目标区域可以为周期性图案区域M2。In a possible implementation, as shown in FIG. 5 , the test electrode 20 may be an interdigital electrode. Interdigital interdigital electrodes that are not connected to each other can be connected through the sensitive material layer 21 covering them. The test electrode 20 may include a periodic pattern area M2, a second connection area 201 for connecting the through silicon via 15, and a second wire area 202 for realizing connection between the periodic pattern area M2 and the second connection area 201. The target area may be the periodic pattern area M2.

其中,加热电极18中可延展形状区域M1和第一导线区182的宽度w1与叉指电极的宽度(也即周期性图案区域M2和第二连接区201的宽度)w2相等,也即w1=w2。可延展形状区域M1条状金属之间的距离s1与叉指电极中叉指之间的距离(也即周期性图案区域M2中条状金属之间的距离)s2相同,也即s1=s2。并且,w1与s1可以相等。可延展形状区域M1与周期性图案区域M2的尺寸相同。可延展形状区域M1、周期性图案区域M2的周期数也可以相同,其中,如图4、图7所示的可延展形状区域M1的周期数为4,图5、图7所示的周期性图案区域M2的周期数为4。加热电极18的厚度和测试电极20的厚度可以相同,该厚度可以为80nm~150nm,例如加热电极18和测试电极20的厚度设置为110nm。Wherein, the width w1 of the ductile shape area M1 and the first wire area 182 in the heating electrode 18 is equal to the width w2 of the interdigital electrode (that is, the width of the periodic pattern area M2 and the second connection area 201), that is, w1= w2. The distance s1 between the strip metals in the ductile shape area M1 is the same as the distance s2 between the interdigitated electrodes (that is, the distance between the strip metals in the periodic pattern area M2), that is, s1=s2. Moreover, w1 and s1 can be equal. The extensible shape area M1 and the periodic pattern area M2 have the same size. The number of periods of the stretchable shape region M1 and the periodic pattern region M2 can also be the same. The number of periods of the stretchable shape region M1 shown in Figures 4 and 7 is 4, and the number of periods of the stretchable shape region M1 shown in Figures 5 and 7 is 4. The number of cycles of the pattern area M2 is four. The thickness of the heating electrode 18 and the thickness of the test electrode 20 may be the same, and the thickness may be 80 nm to 150 nm. For example, the thickness of the heating electrode 18 and the test electrode 20 is set to 110 nm.

在该实现方式中,加热电极18和测试电极20的材料可以是钛(Ti)、铂(Pt)等金属,本公开对此不作限制。In this implementation, the materials of the heating electrode 18 and the test electrode 20 may be metals such as titanium (Ti), platinum (Pt), etc., which are not limited in this disclosure.

在一种可能的实现方式中,如图6、图7所示,敏感材料层21可以是球状敏感材料211的自组装团簇。敏感材料层21的尺寸可以略小于或等于周期性图案区域M2的尺寸,以使得敏感材料层21可以完全覆盖周期性图案区域M2,保证传感器的电路导通。In a possible implementation, as shown in FIGS. 6 and 7 , the sensitive material layer 21 may be a self-assembled cluster of spherical sensitive materials 211 . The size of the sensitive material layer 21 may be slightly smaller than or equal to the size of the periodic pattern area M2, so that the sensitive material layer 21 can completely cover the periodic pattern area M2 to ensure circuit conduction of the sensor.

在本实施例中,可以根据传感器的尺寸设置需要对敏感材料层21、测试电极20、加热电极18的尺寸进行设置。假定根据传感器的尺寸设置确定敏感材料层21的尺寸为100μm×100μm~300μm×300μm,则s1、s2、w1、w2可以为5μm~20μm,测试电极20、加热电极18的长度可以为35μm~380μm。可以理解的是,本领域技术人员可以根据实际需要对传感器主体中各部分的尺寸、材料等进行设置,本公开对此不作限制。In this embodiment, the sizes of the sensitive material layer 21, the test electrode 20, and the heating electrode 18 can be set according to the size setting requirements of the sensor. Assume that the size of the sensitive material layer 21 is determined to be 100μm×100μm~300μm×300μm according to the size setting of the sensor, then s1, s2, w1, w2 can be 5μm~20μm, and the length of the test electrode 20 and the heating electrode 18 can be 35μm~380μm. . It can be understood that those skilled in the art can set the size, material, etc. of each part of the sensor body according to actual needs, and this disclosure does not limit this.

图8示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的结构示意图。在一种可能的实现方式中,如图8所示,该装置可以包括基板71和报警模块61。所述多个传感器中处于最下层的传感器和所述报警模块61,固定在所述基板71上并通过所述基板71电连。所述报警模块61,用于在根据各所述传感器的检测结果确定满足报警条件的情况下,发出告警提示。其中,最下层的传感器和所述报警模块61可以通过基板71内部的导线层711实现电连接。FIG. 8 shows a schematic structural diagram of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure. In a possible implementation, as shown in FIG. 8 , the device may include a base plate 71 and an alarm module 61 . The lowest sensor among the plurality of sensors and the alarm module 61 are fixed on the base plate 71 and are electrically connected through the base plate 71 . The alarm module 61 is configured to issue an alarm prompt when it is determined that the alarm conditions are met according to the detection results of each of the sensors. The lowest layer sensor and the alarm module 61 can be electrically connected through the wire layer 711 inside the substrate 71 .

在该实现方式中,报警模块可以通过声音、震动、灯光等方式中的一种或几种发出告警提示,本公开对此不作限制。In this implementation, the alarm module may issue an alarm prompt through one or more of the following methods: sound, vibration, light, etc., and the present disclosure does not limit this.

在本实施例中,可以根据实际需要对装置中传感器的数量进行设置。还可以根据装置中各传感器的功能对垂直堆叠的顺序进行设置,本公开对此不作限制。举例来说,假定装置中包括三个传感器,分别为气体传感器、温度传感器和加速度传感器,则所述装置中所述气体传感器位于所述温度传感器的上方,所述加速度传感器位于所述温度传感器的下方。这样,气体传感器位于顶层可以保证其可以精准地对环境中的特定气体进行检测。中间层的温度传感器可以对环境中的温度进行检测。而将加速度传感器设置在底层,可以保证整个装置能够对装置安装位置的震动进行检测。这使得包括气体传感器、温度传感器和加速度传感器的装置可以可实现高集成度、微型化的多功能工业生产环境监测与报警系统,检测工厂内有毒气体泄漏、火情与异常振动,并在发现异常的时候通过报警模块发出告警提示。其中,告警模块还可以在根据各所述传感器的检测结果确定满足报警条件的情况下,向上上报,如向工厂的控制中心、监控中心等上报,以使得相关人员可以及时响应处理。In this embodiment, the number of sensors in the device can be set according to actual needs. The order of vertical stacking can also be set according to the functions of each sensor in the device, and this disclosure does not limit this. For example, assuming that the device includes three sensors, namely a gas sensor, a temperature sensor and an acceleration sensor, the gas sensor in the device is located above the temperature sensor, and the acceleration sensor is located above the temperature sensor. below. In this way, the gas sensor is located on the top layer to ensure that it can accurately detect specific gases in the environment. The temperature sensor in the middle layer can detect the temperature in the environment. Setting the acceleration sensor on the bottom layer can ensure that the entire device can detect vibrations at the installation location of the device. This allows devices including gas sensors, temperature sensors and acceleration sensors to implement highly integrated, miniaturized, multi-functional industrial production environment monitoring and alarm systems, which can detect toxic gas leaks, fires and abnormal vibrations in factories, and detect abnormalities when abnormalities are found. When the alarm occurs, an alarm prompt is issued through the alarm module. Among them, the alarm module can also report upwards, such as to the factory's control center, monitoring center, etc., when it is determined that the alarm conditions are met based on the detection results of each sensor, so that relevant personnel can respond in a timely manner.

图9示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的结构示意图。在一种可能的实现方式中,如图9所示,为保证装置顶层传感器的安全,提高装置的可靠性和稳定性,该装置可以包括盖帽层。对于顶层传感器为不需要与外界环境接触的加速度传感器、压力传感器等传感器时,该盖帽层可以包括如图9所示的盖帽衬底31和键合环32。所述盖帽衬底31的第一面设置有容置槽312,顶层传感器的至少部分处于所述容置槽312中。所述键合环32设置于所述盖帽衬底31的第一面且闭合环绕所述容置槽312,用于将所述顶层传感器和所述盖帽层固定连接在一起。FIG9 shows a schematic diagram of the structure of a MEMS sensor integration device based on silicon through vias according to an embodiment of the present disclosure. In a possible implementation, as shown in FIG9 , in order to ensure the safety of the top-layer sensor of the device and improve the reliability and stability of the device, the device may include a cap layer. When the top-layer sensor is an acceleration sensor, a pressure sensor or other sensor that does not need to contact the external environment, the cap layer may include a cap substrate 31 and a bonding ring 32 as shown in FIG9 . A receiving groove 312 is provided on the first surface of the cap substrate 31, and at least a portion of the top-layer sensor is located in the receiving groove 312. The bonding ring 32 is provided on the first surface of the cap substrate 31 and is closed around the receiving groove 312, and is used to fix the top-layer sensor and the cap layer together.

图10示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置中盖帽层的结构示意图。在一种可能的实现方式中,如图10所示,若装置中顶层传感器为气体传感器,则盖帽层还可以包括透气膜层33和防尘网层34。盖帽衬底31的第二面可以设置有与所述容置槽312连接的、位置对应于顶层传感器中测试电极的目标区域的通气孔311。透气膜层33位于所述盖帽衬底31的第二面的上方且至少覆盖所述通气孔311。防尘网层34,位于所述盖帽衬底31的第二面且至少覆盖在所述透气膜层33的与所述通气孔311对应的区域,所述防尘网层34的对应于通气孔311的部分设置有多个通孔341。FIG. 10 shows a schematic structural diagram of a capping layer in a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure. In a possible implementation, as shown in Figure 10, if the top sensor in the device is a gas sensor, the cap layer may also include a breathable film layer 33 and a dustproof mesh layer 34. The second surface of the cap substrate 31 may be provided with a vent 311 connected to the accommodating groove 312 and located corresponding to the target area of the test electrode in the top sensor. The breathable film layer 33 is located above the second surface of the cap substrate 31 and at least covers the vent hole 311 . The dust-proof mesh layer 34 is located on the second surface of the cap substrate 31 and covers at least the area of the breathable film layer 33 corresponding to the ventilation holes 311. The dust-proof mesh layer 34 corresponds to the ventilation holes. The portion 311 is provided with a plurality of through holes 341 .

在该实现方式中,透气膜层33可以覆盖在盖帽衬底31的第二面的全部区域(如图11所示),也可以仅覆盖在盖帽衬底31的第二面对应于所述通气孔311的区域。该透气膜层33具有选择通过性,可以使气体进入通气孔311中,阻挡十微米级的污染物进入通气孔311中。例如,透气膜层33的材料可以为聚合物。这样,可以避免污染物对传感器中敏感材料层造成污染和损伤。本领域技术人员可以根据实际需要对透气膜层的材料、厚度进行设置,本公开对此不作限制。In this implementation, the breathable film layer 33 can cover the entire area of the second side of the cap substrate 31 (as shown in FIG. 11 ), or can only cover the second side of the cap substrate 31 corresponding to the above-mentioned area. The area of the vent 311. The breathable film layer 33 has selective permeability, allowing gas to enter the vent hole 311 and blocking ten micron-level contaminants from entering the vent hole 311 . For example, the material of the breathable film layer 33 may be polymer. In this way, contamination and damage caused by pollutants to the sensitive material layer in the sensor can be avoided. Those skilled in the art can set the material and thickness of the breathable film layer according to actual needs, and this disclosure does not limit this.

在该实现方式中,防尘网层34可以覆盖在透气膜层33的全部区域(如图10所示),也可以仅覆盖在透气膜层33的对应于所述通气孔311的区域。防尘网层34与透气膜层33的尺寸可以相同也可以不同,本公开对此不作限制。防尘网层34用于阻挡灰尘等大颗粒污物通过通气孔311落入顶层的气体传感器内部,避免大颗粒污物对气体传感器中敏感材料层造成污染和机械损伤。防尘网层34的材料可以是金属等能够抵抗腐蚀性气体的腐蚀的材料,以提高传感器的可靠性。例如,防尘网层34的材料可以是Pt。防尘网层34的厚度可以是100nm~300nm。本领域技术人员可以根据实际需要对防尘网层的材料、厚度进行设置,本公开对此不作限制。In this implementation manner, the dustproof mesh layer 34 can cover the entire area of the breathable film layer 33 (as shown in FIG. 10 ), or can only cover the area of the breathable film layer 33 corresponding to the ventilation holes 311 . The sizes of the dust-proof mesh layer 34 and the breathable film layer 33 may be the same or different, and this disclosure does not limit this. The dust-proof mesh layer 34 is used to prevent dust and other large particles of dirt from falling into the gas sensor on the top layer through the ventilation hole 311, so as to prevent large particles of dirt from causing contamination and mechanical damage to the sensitive material layer in the gas sensor. The material of the dust-proof mesh layer 34 may be metal or other materials that can resist corrosion by corrosive gases to improve the reliability of the sensor. For example, the material of the dust-proof mesh layer 34 may be Pt. The thickness of the dust-proof mesh layer 34 may be 100 nm to 300 nm. Those skilled in the art can set the material and thickness of the dust-proof mesh layer according to actual needs, and this disclosure does not limit this.

在一种可能的实现方式中,若装置中顶层传感器为气体传感器,则盖帽层还可以仅包括防尘网层(也即不包括透气膜层),该和防尘网层位于所述盖帽衬底31的第二面且至少覆盖在所述通气孔311对应的区域,所述防尘网层的至少覆盖通气孔311的区域设置有多个通孔341。In a possible implementation, if the top sensor in the device is a gas sensor, the cap layer may also only include a dust-proof mesh layer (that is, not including a breathable film layer), and the dust-proof mesh layer and the dust-proof mesh layer are located on the cap lining. The second surface of the bottom 31 covers at least the area corresponding to the ventilation hole 311 , and a plurality of through holes 341 is provided in at least the area of the dustproof mesh layer covering the ventilation hole 311 .

在本实施例中,盖帽层的厚度可以为200微米~400微米,衬底11和盖帽衬底31可以为硅等材料,以使得二者与器件层制造工艺具有较高的兼容性,保证基体与键合环之间接触强度的匹配。盖帽层的材料还可以是玻璃等材料,本公开对此不作限制。In this embodiment, the thickness of the capping layer can be 200 microns to 400 microns, and the substrate 11 and the capping substrate 31 can be made of silicon or other materials, so that they have high compatibility with the device layer manufacturing process and ensure that the substrate Matching of contact strength with bonded rings. The material of the capping layer may also be glass or other materials, which is not limited in this disclosure.

在本实施例中,盖帽层和顶层传感器中基体可以是尺寸相同、厚度相近或相同结构。这样,可以确保顶层传感器中基体和盖帽层之间有相当的力学性能,在键合及后续操作中不会因膨胀系数、抗压强度等不匹配而产生问题。键合环32的材料可以是易于与顶层传感器中基体键合的材料,例如,键合环32的材料可以是金(Au)等金属。为保证盖帽层和顶层传感器中基体之间固定连接的可靠性,可以对键合环的宽度w3和厚度h进行设置,例如,w3可以为100μm~150μm,h可以为150nm。键合环32可以环绕容置槽且位于盖帽衬底31的第一面的边缘。In this embodiment, the cap layer and the substrate in the top sensor may have the same size, similar thickness, or the same structure. In this way, it can be ensured that the base and cap layers in the top sensor have comparable mechanical properties, and no problems will arise due to mismatch in expansion coefficient, compressive strength, etc. during bonding and subsequent operations. The material of the bonding ring 32 may be a material that is easy to bond with the substrate in the top sensor. For example, the material of the bonding ring 32 may be a metal such as gold (Au). In order to ensure the reliability of the fixed connection between the capping layer and the substrate in the top-level sensor, the width w3 and thickness h of the bonding ring can be set. For example, w3 can be 100 μm to 150 μm, and h can be 150 nm. The bonding ring 32 may surround the receiving groove and be located at an edge of the first side of the cap substrate 31 .

在本实施例中,可以通过键合的方式将键合环32固定到顶层传感器的基体上,以将所述盖帽层与顶层传感器的基体固定连接在一起。而由于顶层传感器的基体和传感器主体结构上的差异,与键合环32键合连接的结构存在差异,以下通过键合方式一、二、三、四、五进行示意性说明。In this embodiment, the bonding ring 32 can be fixed to the substrate of the top sensor by bonding, so as to fix the cap layer and the substrate of the top sensor together. However, due to the difference in the structure of the substrate of the top sensor and the sensor body, the structure bonded to the bonding ring 32 is different, and the bonding methods 1, 2, 3, 4, and 5 are schematically described below.

键合方式一:Bonding method one:

若顶层传感器主体还包括第二绝缘层和加热电极,且所述介质层12覆盖所述衬底11的第一面的对应于所述容置槽312的区域且所述第二绝缘层19还至多覆盖裸露的所述介质层12,则通过键合的方式将所述键合环32与所述衬底11的第一面固定连接,以使所述基体和所述盖帽层固定连接在一起、所述传感器主体和所述介质层12位于所述容置槽312内。If the top sensor body further includes a second insulating layer and a heating electrode, and the dielectric layer 12 covers the area corresponding to the accommodating groove 312 on the first surface of the substrate 11 and the second insulating layer 19 also At most, the exposed dielectric layer 12 is covered, and the bonding ring 32 is fixedly connected to the first surface of the substrate 11 by bonding, so that the base body and the capping layer are fixedly connected together. , the sensor body and the dielectric layer 12 are located in the accommodating groove 312 .

键合方式二:Bonding method two:

若顶层传感器主体还包括第二绝缘层和加热电极,且所述介质层12覆盖所述衬底11的第一面的全部区域、且所述第二绝缘层19还至多覆盖裸露的所述介质层12的对应于所述容置槽312的区域,则通过键合的方式将所述键合环32与所述介质层12固定连接,以使所述基体和所述盖帽层固定连接在一起、所述传感器主体位于所述容置槽312内。If the top sensor body also includes a second insulating layer and a heating electrode, and the dielectric layer 12 covers the entire area of the first surface of the substrate 11, and the second insulating layer 19 also covers at most the exposed dielectric In the area of the layer 12 corresponding to the accommodation groove 312, the bonding ring 32 is fixedly connected to the dielectric layer 12 by bonding, so that the base and the capping layer are fixedly connected together. , the sensor body is located in the accommodating groove 312 .

键合方式三:Bonding method three:

若顶层传感器主体还包括第二绝缘层和加热电极,且所述介质层12覆盖所述衬底11的第一面的全部区域且所述第二绝缘层还覆盖裸露的所述介质层12的全部区域,则通过键合的方式将所述键合环32与所述第二绝缘层19固定连接,以使所述基体和所述盖帽层固定连接在一起、至少所述敏感材料层21位于所述容置槽312内。If the top sensor body also includes a second insulating layer and a heating electrode, and the dielectric layer 12 covers the entire area of the first surface of the substrate 11 and the second insulating layer also covers the exposed dielectric layer 12 In all areas, the bonding ring 32 is fixedly connected to the second insulating layer 19 by bonding, so that the base body and the capping layer are fixedly connected together, and at least the sensitive material layer 21 is located inside the accommodating groove 312 .

键合方式四:Bonding method four:

若顶层传感器主体仅包括测试电极和敏感材料层,且所述介质层12覆盖所述衬底11的第一面的对应于所述容置槽312的区域,则通过键合的方式将所述键合环32与所述衬底11的第一面固定连接,以使所述基体和所述盖帽层固定连接在一起、所述传感器主体和所述介质层12位于所述容置槽312内。If the top sensor body only includes a test electrode and a sensitive material layer, and the dielectric layer 12 covers the area corresponding to the accommodation groove 312 on the first surface of the substrate 11 , then the sensor can be bonded by bonding. The bonding ring 32 is fixedly connected to the first surface of the substrate 11 so that the base body and the cap layer are fixedly connected together, and the sensor body and the dielectric layer 12 are located in the accommodating groove 312 .

键合方式五:Bonding method five:

若顶层传感器主体仅包括测试电极和敏感材料层,且所述介质层12覆盖所述衬底11的第一面的全部区域,则通过键合的方式将所述键合环32与所述介质层12固定连接,以使所述基体和所述盖帽层固定连接在一起、所述传感器主体中至少所述敏感材料层21位于所述容置槽312内。If the top sensor body only includes a test electrode and a sensitive material layer, and the dielectric layer 12 covers the entire area of the first surface of the substrate 11, the bonding ring 32 and the dielectric layer are bonded together. The layer 12 is fixedly connected, so that the base body and the cap layer are fixedly connected together, and at least the sensitive material layer 21 in the sensor body is located in the accommodating groove 312.

在一种可能的实现方式中,该传感器还可以包括处理模块,该处理模块用于对装置中各传感器中的加热电极的通电进行控制,以使得装置工作过程中,设置有加热电极的传感器的加热电极能通电以将敏感材料层加热至工作温度。在装置工作过程中,处理模块还用于对各传感器中的测试电极的通电进行控制,处理模块本身或者控制对应的检测模块对流经各传感器中的测试电极的电流进行监测,并根据监测结果确定各传感器所检测到的针对与对象的相关数据,将其作为检测结果。其中,检测对象可以是气体、温度、湿度、加速度、速度等,本公开对此不作限制。In a possible implementation, the sensor may also include a processing module, which is used to control the energization of the heating electrodes in each sensor in the device, so that during operation of the device, the sensor equipped with the heating electrode The heating electrode can be energized to heat the sensitive material layer to operating temperature. During the operation of the device, the processing module is also used to control the energization of the test electrodes in each sensor. The processing module itself or controls the corresponding detection module to monitor the current flowing through the test electrodes in each sensor, and determine based on the monitoring results. The data related to the object detected by each sensor is used as the detection result. The detection object may be gas, temperature, humidity, acceleration, speed, etc., which is not limited by this disclosure.

在本实施例中,容置槽312的位置、尺寸和形状可以根据传感器主体的位置、尺寸和形状进行设置,以使得顶层传感器至少敏感材料层21处于容置槽312中。容置槽312的深度可以为100微米~300微米。In this embodiment, the position, size and shape of the accommodating groove 312 can be set according to the position, size and shape of the sensor body, so that at least the sensitive material layer 21 of the top sensor is located in the accommodating groove 312 . The depth of the accommodating groove 312 may be 100 microns to 300 microns.

举例来说,若敏感材料层21的尺寸为100μm×100μm~300μm×300μm,则容置槽312可以为长方体结构,其尺寸为500μm×500μm×100μm(100μm为深度)。For example, if the size of the sensitive material layer 21 is 100 μm×100 μm to 300 μm×300 μm, the receiving groove 312 may be a rectangular parallelepiped structure with a size of 500 μm×500 μm×100 μm (100 μm is the depth).

图11示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的结构示意图。在一种可能的实现方式中,如图11所示,该装置还可以包括装置电极41。装置电极41设置于对应的所述通孔区域17且与对应的所述硅通孔15电连接。这样,通过硅通孔15下方连接装置电极41,可减少平面金属布线,将测试区域与电气区域有效隔离,从而提高装置可靠性,并实现装置小型化。FIG. 11 shows a schematic structural diagram of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure. In a possible implementation, as shown in FIG. 11 , the device may also include device electrodes 41 . The device electrode 41 is disposed in the corresponding through-hole region 17 and is electrically connected to the corresponding through-silicon via 15 . In this way, by connecting the device electrode 41 under the through silicon via 15, the planar metal wiring can be reduced, and the test area and the electrical area can be effectively isolated, thereby improving the reliability of the device and miniaturizing the device.

其中,装置中底层传感器的通孔区域17可以大于对应的硅通孔15的截面面积,该通孔区域17中设置有金属电极沉积层40。该金属电极沉积层40位于各通孔区域17且覆盖各通孔区域17。金属电极沉积层40的材料可以是钛(Ti)、铂(Pt)、金(Au)等金属。金属电极沉积层40的厚度可以是550nm。通过金属电极沉积层40可以便于后续通过植球方式制备装置电极41,保证植球的顺利进行。本领域技术人员可以根据实际需要对金属电极沉积层、装置电极的材料、尺寸进行设置,本公开对此不作限制。装置电极41可以为通过激光植球等植球方式制造的金属球,金属球的材料可以是铅锡合金(PbSn)等。Wherein, the through hole area 17 of the underlying sensor in the device may be larger than the cross-sectional area of the corresponding through silicon hole 15, and the metal electrode deposition layer 40 is disposed in the through hole area 17. The metal electrode deposition layer 40 is located in each through hole area 17 and covers each through hole area 17 . The material of the metal electrode deposition layer 40 may be titanium (Ti), platinum (Pt), gold (Au) and other metals. The thickness of the metal electrode deposition layer 40 may be 550 nm. The metal electrode deposition layer 40 can facilitate the subsequent preparation of the device electrode 41 through ball planting, ensuring the smooth progress of ball planting. Those skilled in the art can set the materials and sizes of the metal electrode deposition layer and the device electrode according to actual needs, and this disclosure does not limit this. The device electrode 41 may be a metal ball manufactured by a ball planting method such as laser ball planting, and the material of the metal ball may be lead-tin alloy (PbSn) or the like.

在一些实施例中,如图1所示,每个所述硅通孔组中的各所述硅通孔15的对称轴重合,且不同所述硅通孔组中的各所述硅通孔15的对称轴所处直线不相同。这样,可以借助硅通孔实现多个传感器之间的串联,提高装置的集成度,降低装置的厚度。In some embodiments, as shown in FIG1 , the symmetry axes of the through silicon vias 15 in each through silicon via group coincide, and the symmetry axes of the through silicon vias 15 in different through silicon via groups are located on different straight lines. In this way, multiple sensors can be connected in series by means of through silicon vias, thereby improving the integration of the device and reducing the thickness of the device.

在本实施例中,各硅通孔15设置于加热电极18的第一连接区181或测试电极20的第二连接区201下方,各硅通孔15中的填充金属在衬底11的第一面与加热电极18或测试电极20相接触。硅通孔15中的填充金属下层传感器的测试电极或加热电极相连。最下层传感器中的硅通孔15可连接至外部使得检测到的信号输入处理电路。这样,硅通孔15用作互联线路,实现晶圆三维封装,将互联线路与电路区域与测试区域在空间上隔离,从而实现装置中MEMS传感器的纵向集成,且能够降低装置的厚度。采用硅通孔互连技术能够实现装置中多个传感器的上下电学导通,有利于实现传感器与IC的多层堆叠,使得装置具备高性能、高密度和低功耗等特点。In this embodiment, each through silicon via 15 is arranged below the first connection area 181 of the heating electrode 18 or the second connection area 201 of the test electrode 20, and the filling metal in each through silicon via 15 contacts the heating electrode 18 or the test electrode 20 on the first surface of the substrate 11. The filling metal in the through silicon via 15 is connected to the test electrode or the heating electrode of the lower sensor. The through silicon via 15 in the bottom sensor can be connected to the outside so that the detected signal is input to the processing circuit. In this way, the through silicon via 15 is used as an interconnection line to realize the three-dimensional packaging of the wafer, and the interconnection line is spatially isolated from the circuit area and the test area, thereby realizing the vertical integration of the MEMS sensor in the device and reducing the thickness of the device. The use of through silicon via interconnection technology can realize the upper and lower electrical conduction of multiple sensors in the device, which is conducive to the realization of multi-layer stacking of sensors and ICs, so that the device has the characteristics of high performance, high density and low power consumption.

在一种可能的实现方式中,硅通孔15可以为大孔径、高深宽比的硅通孔,硅通孔15的直径可以为20μm~50μm、深宽比可以为5:1~10:1。这样,可实现针对大电流大功率MEMS传感器及其横纵向集成结构的互联线路制备。In a possible implementation, the through silicon via 15 can be a through silicon via with a large aperture and a high aspect ratio. The diameter of the through silicon via 15 can be 20 μm to 50 μm, and the aspect ratio can be 5:1 to 10:1. . In this way, the preparation of interconnection lines for high-current and high-power MEMS sensors and their horizontal and vertical integration structures can be achieved.

图12示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的制造方法的流程图。图13示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的制造方法中制造传感器的过程示意图。图14示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的制造方法中传感器堆叠的过程示意图。图15示出根据本公开一实施例的基于硅通孔的MEMS传感器集成装置的制造方法中硅通孔的制造过程示意图。FIG. 12 shows a flow chart of a manufacturing method of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure. FIG. 13 shows a schematic diagram of a process of manufacturing a sensor in a method of manufacturing a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure. 14 shows a schematic diagram of a process of sensor stacking in a manufacturing method of a through-silicon via-based MEMS sensor integrated device according to an embodiment of the present disclosure. FIG. 15 shows a schematic diagram of the manufacturing process of the through silicon via in the manufacturing method of the through silicon via based MEMS sensor integrated device according to an embodiment of the present disclosure.

如图12-图15所示,该方法包括:传感器制造步骤、传感器堆叠步骤。其中,图13中示意性的以制造图3B所示的传感器为例、图14中示意性的以基于图13制造的3个传感器为例、图15为简明仅示意了多个硅通孔中的某一个硅通孔的制造过程为例,示出了装置的制造方法的流程。传感器制造步骤在传感器堆叠步骤之前执行。As shown in Figures 12 to 15, the method includes: a sensor manufacturing step and a sensor stacking step. Figure 13 schematically takes the manufacturing of the sensor shown in Figure 3B as an example, Figure 14 schematically takes the manufacturing of three sensors based on Figure 13 as an example, and Figure 15 simply illustrates the manufacturing process of one of the multiple silicon through vias as an example, showing the flow of the device manufacturing method. The sensor manufacturing step is performed before the sensor stacking step.

如图12所示,传感器制造步骤可以包括:基体制造步骤和传感器主体制造步骤。基体制造步骤包括步骤S501至步骤S503。传感器主体制造步骤包括步骤S504至步骤S505。As shown in FIG. 12 , the sensor manufacturing steps may include: a substrate manufacturing step and a sensor body manufacturing step. The substrate manufacturing step includes step S501 to step S503. The sensor body manufacturing steps include steps S504 to S505.

在步骤S501中,在衬底11的第一面制备出介质层12,介质层12可以为由氧化硅层121、氮化硅层122和氧化硅层123。可以采用PECVD工艺制备该介质层12。In step S501 , a dielectric layer 12 is prepared on the first surface of the substrate 11 . The dielectric layer 12 may be composed of a silicon oxide layer 121 , a silicon nitride layer 122 and a silicon oxide layer 123 . The dielectric layer 12 can be prepared using a PECVD process.

在步骤S502中,对衬底11和介质层12进行刻蚀、并对所述衬底11进行减薄,形成多个硅通孔15。In step S502 , the substrate 11 and the dielectric layer 12 are etched, and the substrate 11 is thinned to form a plurality of through silicon holes 15 .

其中,如图15所示,步骤S502可以包括:As shown in Figure 15, step S502 may include:

采用BOSCH工艺对衬底11和介质层12进行刻蚀,形成制备该传感器所需的多个高深宽比盲孔13;通过热氧化、PECVD、低压力化学气相沉积法(Low Pressure ChemicalVaporDeposition,LPCVD)等方法在盲孔13表面制备氧化硅绝缘层131,其中,热氧化方法制造绝缘层可以避免后续高温损坏绝缘层。而后在绝缘层131表面采用原子层沉积(Atomiclayer deposition,ALD)工艺或物理气相沉积(Physical Vapor Deposition,PVD)等工艺制备TiN、Ti/W等材料的阻挡层132,阻挡层132的厚度可以为50nm~150nm。采用物理气相沉积、原子层沉积、化学镀等方式在阻挡层的表面制备Cu等材料的种子层133,种子层133的厚度可以是500nm~1μm。可以采用电镀等工艺在盲孔13中填充铜等导电金属形成如图13所示的金属结构14,而后可以退火以部分释放填充金属带来的应力。由于介质层12上也电镀上了金属结构14,因而可以继续采用化学机械抛光(Chemical MechanicalPolishing,CMP)等工艺对介质层12上的金属结构14进行抛光。抛光后对衬底11的第二面进行减薄直至暴露出盲孔13,得到硅通孔15。其中,为简明图13中并未示出硅通孔中的绝缘层131、阻挡层132和种子层133。绝缘层用于在硅通孔15中的金属柱与衬底11之间实现电绝缘。阻挡层用于防止硅通孔15中的金属柱中电极金属扩散进入绝缘层及衬底11。The substrate 11 and the dielectric layer 12 are etched using the BOSCH process to form multiple high aspect ratio blind holes 13 required to prepare the sensor; through thermal oxidation, PECVD, and low pressure chemical vapor deposition (Low Pressure Chemical Vapor Deposition, LPCVD) The silicon oxide insulating layer 131 is prepared on the surface of the blind hole 13 by other methods. The thermal oxidation method to manufacture the insulating layer can avoid subsequent high temperature damage to the insulating layer. Then, a barrier layer 132 of materials such as TiN and Ti/W is prepared on the surface of the insulating layer 131 using an atomic layer deposition (ALD) process or a physical vapor deposition (PVD) process. The thickness of the barrier layer 132 can be 50nm~150nm. A seed layer 133 of Cu or other materials is prepared on the surface of the barrier layer by means of physical vapor deposition, atomic layer deposition, electroless plating, etc. The thickness of the seed layer 133 may be 500 nm to 1 μm. Electroplating and other processes can be used to fill the blind hole 13 with conductive metal such as copper to form a metal structure 14 as shown in FIG. 13 , and then can be annealed to partially release the stress caused by the filling metal. Since the metal structure 14 is also electroplated on the dielectric layer 12, processes such as chemical mechanical polishing (CMP) can continue to be used to polish the metal structure 14 on the dielectric layer 12. After polishing, the second surface of the substrate 11 is thinned until the blind hole 13 is exposed to obtain the through silicon via 15 . For simplicity, the insulating layer 131, the barrier layer 132 and the seed layer 133 in the through silicon hole are not shown in FIG. 13 . The insulating layer is used to achieve electrical insulation between the metal pillars in the through silicon via 15 and the substrate 11 . The barrier layer is used to prevent the electrode metal in the metal pillar in the through silicon via 15 from diffusing into the insulating layer and the substrate 11 .

其中,可以采用电感耦合等离子体(Inductively Coupled Plasma,ICP)等刻蚀技术对介质层12进行刻蚀,采用Bosch工艺对衬底11进行刻蚀,最终形成多个盲孔13。The dielectric layer 12 may be etched using an etching technique such as inductively coupled plasma (ICP), and the substrate 11 may be etched using a Bosch process, so as to finally form a plurality of blind holes 13 .

在步骤S503中,在所述衬底11的第二面制备第一绝缘层16,并对所述第一绝缘层16进行刻蚀以至少暴露出各所述硅通孔15对应的通孔区域17,完成基体的制造。In step S503, a first insulating layer 16 is prepared on the second side of the substrate 11, and the first insulating layer 16 is etched to expose at least the through hole area corresponding to each of the through silicon holes 15. 17. Complete the manufacturing of the matrix.

其中,可以采用PECVD制备第一绝缘层16,可以避免高温下硅通孔中的金属扩散。而后可以采用光刻工艺对通孔区域进行图案化,而后利用ICP工艺等干法刻蚀工艺刻蚀第一绝缘层16直至暴露出各通孔区域17。而后可以通过磁控溅射或蒸发镀膜等金属沉积方式在通孔区域14中沉积金属电极沉积层40,作为后续植球的接触区(接触区的制造步骤为可选步骤)。通过制备硅通孔过程中的抛光和步骤S503中的减薄,可以消除薄膜应力导致的晶圆翘曲,保障后续工艺的顺利实施。Among them, PECVD can be used to prepare the first insulating layer 16, which can avoid metal diffusion in the through silicon holes at high temperatures. Then, a photolithography process may be used to pattern the through-hole areas, and then a dry etching process such as an ICP process may be used to etch the first insulating layer 16 until each through-hole area 17 is exposed. Then, a metal electrode deposition layer 40 can be deposited in the through hole area 14 by a metal deposition method such as magnetron sputtering or evaporation coating, as a contact area for subsequent ball planting (the manufacturing step of the contact area is an optional step). Through polishing in the process of preparing through silicon holes and thinning in step S503, wafer warpage caused by film stress can be eliminated and the smooth implementation of subsequent processes can be ensured.

传感器主体制造步骤:包括步骤S504至步骤S505。Sensor body manufacturing steps: including steps S504 to S505.

在步骤S504中,在介质层12的表面制备测试电极20。In step S504, the test electrode 20 is prepared on the surface of the dielectric layer 12.

其中,可以在介质层12表面涂覆光刻胶,基于测试电极20的结构和尺寸对光刻胶进行图案化后,暴露出介质层12表面需要制备测试电极20的区域,通过磁控溅射或蒸发镀膜等金属沉积方式进行金属沉积形成测试电极20,而后去掉介质层12表面的多余光刻胶。Among them, photoresist can be coated on the surface of the dielectric layer 12. After the photoresist is patterned based on the structure and size of the test electrode 20, the area on the surface of the dielectric layer 12 where the test electrode 20 needs to be prepared is exposed, and metal deposition is performed by metal deposition methods such as magnetron sputtering or evaporation coating to form the test electrode 20, and then the excess photoresist on the surface of the dielectric layer 12 is removed.

在步骤S505中,在所述测试电极20的目标区域的上方制造敏感材料层21,完成传感器主体的制造。In step S505, the sensitive material layer 21 is manufactured above the target area of the test electrode 20 to complete the manufacturing of the sensor body.

其中,采用光刻的方式对测试电极20的目标区域上方进行图案化,暴露出测试电极20表面需要制备敏感材料层21的区域,而后采用涂覆的方式在进行敏感材料涂覆,剥离光刻胶之后得到敏感材料层21,得到传感器主体。Among them, photolithography is used to pattern the target area of the test electrode 20 to expose the area on the surface of the test electrode 20 where the sensitive material layer 21 needs to be prepared, and then the sensitive material is coated by coating, and the photolithography is peeled off. After gluing, the sensitive material layer 21 is obtained, and the sensor body is obtained.

在一种可能的实现方式中,若传感器主体还包括加热电极和第二绝缘层(如图3B所示),则传感器主体的制造步骤可以包括:在介质层12的表面制备加热电极18。在加热电极18以及裸露的介质层12表面制造第二绝缘层19;对第二绝缘层19进行刻蚀,形成电极通孔191,以通过电极通孔191暴露出多个硅通孔15中用于与测试电极20连接的硅通孔;在所述第二绝缘层19上制造出目标区域与所述加热电极18重叠的测试电极20,并使所述测试电极20通过电极通孔191与对应的硅通孔15连接;在所述目标区域的上方制造敏感材料层21,完成传感器主体的制造。In a possible implementation, if the sensor body further includes a heating electrode and a second insulating layer (as shown in FIG. 3B ), the manufacturing step of the sensor body may include: preparing the heating electrode 18 on the surface of the dielectric layer 12 . A second insulating layer 19 is formed on the surface of the heating electrode 18 and the exposed dielectric layer 12; the second insulating layer 19 is etched to form electrode through holes 191, so as to expose a plurality of through silicon holes 15 through the electrode through holes 191. For the through silicon hole connected to the test electrode 20; on the second insulating layer 19, a test electrode 20 with a target area overlapping the heating electrode 18 is manufactured, and the test electrode 20 is passed through the electrode through hole 191 and the corresponding The through silicon via 15 is connected; a sensitive material layer 21 is manufactured above the target area to complete the manufacturing of the sensor body.

在该实现方式中,可以在介质层12表面涂覆光刻胶,基于加热电极18的结构和尺寸对光刻胶进行图案化后,暴露出介质层12表面需要制造加热电极18的区域,通过磁控溅射或蒸发镀膜等金属沉积方式进行金属沉积形成加热电极,而后去掉介质层12表面的多余光刻胶。可以采用PECVD工艺沉积第二绝缘层。可以在第二绝缘层19表面涂覆光刻胶,基于测试电极20连接的硅通孔15的位置和尺寸对光刻胶进行图案化后,通过干法刻蚀工艺对第二绝缘层19进行刻蚀,暴露出多个硅通孔15中用于与测试电极20连接的硅通孔而后去掉第二绝缘层19表面的多余光刻胶。可以在第二绝缘层19表面涂覆光刻胶,基于测试电极20的结构和尺寸对光刻胶进行图案化后,暴露出第二绝缘层19表面需要制备测试电极20的区域,通过磁控溅射或蒸发镀膜等金属沉积方式进行金属沉积形成测试电极20,而后去掉第二绝缘层19表面的多余光刻胶。采用光刻的方式对测试电极20的目标区域上方进行图案化,暴露出第二绝缘层19和测试电极20表面需要制备敏感材料层21的区域,而后采用涂覆的方式在进行敏感材料涂覆,剥离光刻胶之后得到敏感材料层21,得到传感器主体。In this implementation, photoresist can be coated on the surface of the dielectric layer 12. After patterning the photoresist based on the structure and size of the heating electrode 18, the area on the surface of the dielectric layer 12 where the heating electrode 18 needs to be manufactured is exposed. Metal deposition is performed by magnetron sputtering or evaporation coating to form a heating electrode, and then excess photoresist on the surface of the dielectric layer 12 is removed. The second insulating layer can be deposited using a PECVD process. Photoresist can be coated on the surface of the second insulating layer 19, and after patterning the photoresist based on the position and size of the through silicon hole 15 connected to the test electrode 20, the second insulating layer 19 can be etched through a dry etching process. Etching is performed to expose the through silicon holes used to connect to the test electrodes 20 among the plurality of through silicon holes 15 and then the excess photoresist on the surface of the second insulating layer 19 is removed. Photoresist can be coated on the surface of the second insulating layer 19. After patterning the photoresist based on the structure and size of the test electrode 20, the area on the surface of the second insulating layer 19 where the test electrode 20 needs to be prepared is exposed. The test electrode 20 is formed by metal deposition using a metal deposition method such as sputtering or evaporation coating, and then the excess photoresist on the surface of the second insulating layer 19 is removed. Use photolithography to pattern the top of the target area of the test electrode 20 to expose the second insulating layer 19 and the area on the surface of the test electrode 20 where the sensitive material layer 21 needs to be prepared, and then use coating to coat the sensitive material. , after peeling off the photoresist, the sensitive material layer 21 is obtained, and the sensor body is obtained.

在装置还包括盖帽层的情况下,该装置的制造方法还包括盖帽层制造步骤,盖帽层制造步骤(也即制造如图9所示的盖帽层)可以包括:在盖帽衬底31的第一面制备键合环32。对所述盖帽衬底31的第一面进行刻蚀,形成容置槽312。In the case where the device further includes a capping layer, the manufacturing method of the device further includes a capping layer manufacturing step. The capping layer manufacturing step (ie, manufacturing the capping layer as shown in FIG. 9 ) may include: first forming the capping substrate 31 The bonding ring 32 is prepared. The first surface of the cap substrate 31 is etched to form an accommodating groove 312 .

其中,可以采用光刻的方式对键合环区域进行图案化,而后可以使用磁控溅射或蒸发镀膜等金属沉积方式进行沉积,而后对多余的胶层进行剥离获得键合环32。可以通过光刻对盖帽衬底31的第一面对应于容置槽的区域进行图案化,并采用BOSCH工艺刻蚀图案化区域内的盖帽衬底31,形成容置槽312。Among them, photolithography can be used to pattern the bonding ring area, and then metal deposition such as magnetron sputtering or evaporation coating can be used to deposit, and then the excess adhesive layer is peeled off to obtain the bonding ring 32 . The area of the first side of the cap substrate 31 corresponding to the accommodating groove can be patterned by photolithography, and the cap substrate 31 in the patterned area can be etched using a BOSCH process to form the accommodating groove 312 .

在一种可能的实现方式中,若传感器为气体传感器,则盖帽层制造步骤(也即制造图10所示的盖帽层)可以包括:对所述盖帽衬底31进行刻蚀,形成贯穿所述盖帽衬底31且对应于所述目标区域的通气孔311。其中,可以采用BOSCH工艺对盖帽衬底31进行刻蚀,以形成通气孔311。对所述盖帽衬底31的第一面进行刻蚀,形成与所述通气孔311连接的容置槽312。其中,可以通过光刻对盖帽衬底31的第一面对应于容置槽的区域进行图案化,并采用BOSCH工艺刻蚀图案化区域内的盖帽衬底31,形成容置槽312。将预先制备的透气膜贴合在所述盖帽衬底31的第二面并至少覆盖所述通气孔311,形成透气膜层33。在所述透气膜层33上方进行防尘网层制备,形成至少覆盖所述透气膜层33的部分带有多个通孔341的防尘网层34。其中,可以采用光刻的方式对防尘网层进行图案化,暴露出透气膜层33上方和盖帽衬底的第二面上方需要制备防尘网层的区域,通过磁控溅射或蒸发镀膜等金属沉积方式进行金属沉积形成防尘网层,而后去掉多余光刻胶,完成防尘网层34的制备。In a possible implementation, if the sensor is a gas sensor, the capping layer manufacturing step (that is, manufacturing the capping layer shown in FIG. 10 ) may include: etching the capping substrate 31 to form a layer through the capping layer 31 . The vent 311 caps the substrate 31 and corresponds to the target area. Among them, the cap substrate 31 can be etched using a BOSCH process to form the vent hole 311 . The first surface of the cap substrate 31 is etched to form an accommodating groove 312 connected to the ventilation hole 311 . Wherein, the area of the first side of the cap substrate 31 corresponding to the accommodating groove can be patterned by photolithography, and the BOSCH process is used to etch the cap substrate 31 in the patterned area to form the accommodating groove 312 . The pre-prepared breathable film is attached to the second surface of the cap substrate 31 and at least covers the ventilation holes 311 to form the breathable film layer 33 . A dust-proof mesh layer is prepared above the breathable film layer 33 to form a dust-proof mesh layer 34 with a plurality of through holes 341 that covers at least a portion of the breathable film layer 33 . Among them, the dust-proof mesh layer can be patterned by photolithography to expose the area where the dust-proof mesh layer needs to be prepared above the breathable film layer 33 and above the second side of the cap substrate, and the film can be coated by magnetron sputtering or evaporation. Metal deposition is performed using a metal deposition method to form a dust-proof mesh layer, and then excess photoresist is removed to complete the preparation of the dust-proof mesh layer 34 .

在一种可能的实现方式中,若传感器为气体传感器,且盖帽层包括防尘网层但不包括透气膜层,则盖帽层制造步骤可以包括:对所述盖帽衬底进行刻蚀,形成贯穿所述盖帽衬底且对应于所述目标区域的通气孔。对所述盖帽衬底的第一面进行刻蚀,形成与所述通气孔连接的容置槽。可以采用光刻的方式对防尘网层进行图案化,暴露出盖帽衬底的第二面上方需要制备防尘网层的区域,通过磁控溅射或蒸发镀膜等金属沉积方式进行金属沉积形成防尘网层,而后去掉多余光刻胶,完成防尘网层的制备,得到至少覆盖所述通气孔的部分带有多个通孔的防尘网层。In a possible implementation, if the sensor is a gas sensor and the cap layer includes a dust-proof mesh layer but does not include a breathable film layer, the cap layer manufacturing step may include: etching the cap substrate to form a through-hole The cap substrate and the vent corresponding to the target area. The first surface of the cap substrate is etched to form an accommodating groove connected to the vent hole. The dust-proof mesh layer can be patterned by photolithography to expose the area where the dust-proof mesh layer needs to be prepared above the second side of the cap substrate, and metal deposition can be performed by metal deposition methods such as magnetron sputtering or evaporation coating. The dust-proof mesh layer is then removed, and the excess photoresist is removed to complete the preparation of the dust-proof mesh layer, thereby obtaining a dust-proof mesh layer with multiple through holes that at least covers the vent hole.

在一种可能的实现方式中,若装置包括盖帽层,则顶层传感器的制造步骤或者传感器堆叠步骤还可以包括固定连接步骤。固定连接步骤包括通过键合的方式将所述键合环32与所述基体固定连接在一起,以使顶层传感器中至少敏感材料层21处于所述容置槽312中。In a possible implementation, if the device includes a cap layer, the manufacturing step of the top sensor or the sensor stacking step may further include a fixing and connecting step. The fixing and connecting step includes fixing the bonding ring 32 and the substrate together by bonding, so that at least the sensitive material layer 21 in the top sensor is in the receiving groove 312.

其中,在键合过程中可以对顶层传感器或者已堆叠的多个传感器件施加反向压应力,进一步减轻翘曲。In the bonding process, reverse compressive stress can be applied to the top layer sensor or multiple stacked sensor devices to further reduce the warping.

其中,根据基体和传感器主体结构的差异,固定连接步骤可以包括以下任意一种实现方式:Among them, according to the difference in structure between the base body and the sensor body, the fixed connection step can include any of the following implementation methods:

若顶层传感器的传感器主体不包括加热电极和第二绝缘层,且所述介质层12覆盖所述衬底11的第一面的对应于所述容置槽312的区域,则通过键合的方式将所述键合环32与所述衬底11的第一面固定连接,以使所述基体和所述盖帽层固定连接在一起、所述传感器主体和所述介质层12位于所述容置槽312内.If the sensor body of the top sensor does not include a heating electrode and a second insulating layer, and the dielectric layer 12 covers the area of the first surface of the substrate 11 corresponding to the receiving groove 312, the bonding ring 32 is fixedly connected to the first surface of the substrate 11 by bonding, so that the base and the cap layer are fixedly connected together, and the sensor body and the dielectric layer 12 are located in the receiving groove 312.

若顶层传感器的传感器主体不包括加热电极和第二绝缘层,且所述介质层12覆盖所述衬底11的第一面的全部区域,则通过键合的方式将所述键合环32与所述介质层12固定连接,以使所述基体和所述盖帽层固定连接在一起、所述传感器主体中至少所述敏感材料层21位于所述容置槽312内。If the sensor body of the top-level sensor does not include a heating electrode and a second insulating layer, and the dielectric layer 12 covers the entire area of the first surface of the substrate 11, the bonding ring 32 is fixedly connected to the dielectric layer 12 by bonding, so that the base and the cap layer are fixedly connected together and at least the sensitive material layer 21 in the sensor body is located in the accommodating groove 312.

若顶层传感器的传感器主体包括加热电极18和第二绝缘层19,且所述介质层12覆盖所述衬底11的第一面的对应于所述容置槽312的区域且所述第二绝缘层19还至多覆盖裸露的所述介质层12,则通过键合的方式将所述键合环32与所述衬底11的第一面固定连接,以使所述基体和所述盖帽层固定连接在一起、所述传感器主体和所述介质层12位于所述容置槽312内。If the sensor body of the top sensor includes a heating electrode 18 and a second insulating layer 19, and the dielectric layer 12 covers the area corresponding to the accommodating groove 312 on the first surface of the substrate 11 and the second insulating The layer 19 can cover at most the exposed dielectric layer 12, and the bonding ring 32 is fixedly connected to the first surface of the substrate 11 by bonding, so that the base and the capping layer are fixed. Connected together, the sensor body and the dielectric layer 12 are located in the accommodating groove 312 .

若顶层传感器的传感器主体包括加热电极18和第二绝缘层19,且所述介质层12覆盖所述衬底11的第一面的全部区域、且所述第二绝缘层19还至多覆盖裸露的所述介质层12的对应于所述容置槽312的区域,则通过键合的方式将所述键合环32与所述介质层12固定连接,以使所述基体和所述盖帽层固定连接在一起、所述传感器主体位于所述容置槽312内。If the sensor body of the top sensor includes a heating electrode 18 and a second insulating layer 19, and the dielectric layer 12 covers the entire area of the first surface of the substrate 11, and the second insulating layer 19 also covers at most the exposed In the area of the dielectric layer 12 corresponding to the accommodating groove 312, the bonding ring 32 is fixedly connected to the dielectric layer 12 by bonding, so that the base body and the cap layer are fixed. Connected together, the sensor body is located in the receiving groove 312 .

若顶层传感器的传感器主体包括加热电极18和第二绝缘层19,且所述介质层12覆盖所述衬底11的第一面的全部区域且所述第二绝缘层19还覆盖裸露的所述介质层12的全部区域,则通过键合的方式将所述键合环32与所述第二绝缘层19固定连接,以使所述基体和所述盖帽层固定连接在一起、至少所述敏感材料层21位于所述容置槽312内。If the sensor body of the top sensor includes a heating electrode 18 and a second insulating layer 19, and the dielectric layer 12 covers the entire area of the first surface of the substrate 11, and the second insulating layer 19 also covers the exposed In the entire area of the dielectric layer 12, the bonding ring 32 is fixedly connected to the second insulating layer 19 by bonding, so that the base body and the capping layer are fixedly connected together, at least the sensitive The material layer 21 is located in the receiving groove 312 .

所述传感器堆叠步骤包括:步骤S506-步骤S508。The sensor stacking step includes: step S506-step S508.

在步骤S506中,基于装置中多个传感器的堆叠顺序,在最下层传感器的上方制备互连层51。对所述互连层51进行刻蚀形成敏感层孔511和多个线通孔512,以通过所述敏感层孔511暴露出所述敏感材料层21、通过各所述线通孔512暴露出所述测试电极20。In step S506, based on the stacking order of multiple sensors in the device, an interconnection layer 51 is prepared above the bottommost sensor. The interconnection layer 51 is etched to form a sensitive layer hole 511 and a plurality of line through holes 512, so as to expose the sensitive material layer 21 through the sensitive layer hole 511 and expose the test electrode 20 through each of the line through holes 512.

其中,可以采用CVD等方法直接在最下层传感器的上方生长互连层51。互连层51可以为介质层(Interposer),互连层的材料可以为SiGI、Si等。可以光刻等方式对互连层进行刻蚀,以形成敏感层孔511和多个线通孔512。Among them, methods such as CVD can be used to grow the interconnection layer 51 directly above the lowermost sensor. The interconnection layer 51 may be an interposer, and the material of the interconnection layer may be SiGI, Si, etc. The interconnection layer can be etched by photolithography or other methods to form sensitive layer holes 511 and a plurality of line via holes 512 .

在步骤S507中,在所述线通孔512中填充金属形成互连线513。可以采用PVD等方式在线通孔512中进行金属填充,以形成互连线513。In step S507, metal is filled in the line via 512 to form an interconnection line 513. The metal can be filled in the line via 512 by PVD or other methods to form the interconnection line 513.

在步骤S508中,将所述最下层传感器上方与所述最下层传感器相邻的上层传感器固定到所述互连层51。而后将所述上层传感器作为最下层传感器继续进行下一传感器的固定,直至全部传感器均完成堆叠。In step S508, an upper layer sensor adjacent to the lowermost layer sensor above the lowermost layer sensor is fixed to the interconnection layer 51. Then, the upper sensor is used as the lowest sensor and the next sensor is fixed until all the sensors are stacked.

在一种可能的实现方式中,若多个所述硅通孔组中存在至少一个不重合硅通孔组,所述不重合硅通孔组的多个硅通孔中至少两个硅通孔的对称轴不重合,则传感器堆叠步骤还可以包括:在制造互连层51的过程中进行金属布线的制备,以使得该金属布线可以连接所在互连层下方传感器的测试电极和所在互连层上方传感器的硅通孔,和/或,所述金属布线用于连接所在互连层下方传感器的加热电极和所在互连层上方传感器的硅通孔。In a possible implementation, if there is at least one non-overlapping through silicon via group among the plurality of through silicon via groups, at least two through silicon holes among the plurality of through silicon holes in the non-overlapping through silicon via group symmetry axes do not coincide, the sensor stacking step may also include: preparing metal wiring in the process of manufacturing the interconnection layer 51, so that the metal wiring can connect the test electrode of the sensor below the interconnection layer and the interconnection layer where it is located. The through silicon via of the upper sensor, and/or the metal wiring is used to connect the heating electrode of the sensor below the interconnection layer and the through silicon via of the sensor above the interconnection layer.

在一种可能的实现方式中,若装置包括装置电极,则该方法还可以包括电极制造步骤:在最下层传感器的通孔区域植球,形成装置电极41,完成所述装置的制备。其中,可以采用激光植球的方式进行植球。In a possible implementation, if the device includes a device electrode, the method may further include an electrode manufacturing step: implanting a ball in the through-hole region of the bottom sensor to form a device electrode 41, thereby completing the preparation of the device. The implantation may be performed by laser implantation.

需要说明的是,尽管以上述实施例作为示例介绍了一种基于硅通孔的MEMS传感器集成装置及其制造方法如上,但本领域技术人员能够理解,本公开应不限于此。事实上,用户完全可根据个人喜好和/或实际应用场景灵活设定各步骤和装置的各部分,只要符合本公开的技术方案即可。It should be noted that, although the above embodiment is used as an example to introduce a MEMS sensor integrated device based on silicon through vias and a manufacturing method thereof, those skilled in the art will understand that the present disclosure should not be limited thereto. In fact, the user can flexibly set each step and each part of the device according to personal preferences and/or actual application scenarios, as long as it complies with the technical solution of the present disclosure.

以上已经描述了本公开的各实施例,上述说明是示例性的,并非穷尽性的,并且也不限于所披露的各实施例。在不偏离所说明的各实施例的范围和精神的情况下,对于本技术领域的普通技术人员来说许多修改和变更都是显而易见的。本文中所用术语的选择,旨在最好地解释各实施例的原理、实际应用或对市场中的技术改进,或者使本技术领域的其它普通技术人员能理解本文披露的各实施例。The embodiments of the present disclosure have been described above, and the above description is exemplary, not exhaustive, and is not limited to the disclosed embodiments. Many modifications and changes will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The selection of terms used herein is intended to best explain the principles of the embodiments, practical applications, or technical improvements in the market, or to enable other persons of ordinary skill in the art to understand the embodiments disclosed herein.

Claims (10)

1. A through silicon via based MEMS sensor integrated device, the device comprising: a plurality of sensors vertically stacked and an interconnection layer between two adjacent sensors, each of the sensors including a sensor body and a base body for carrying the sensor body;
the substrate is provided with a plurality of through silicon vias; the sensor body includes a test electrode and a layer of sensitive material; the test electrode is positioned above the matrix and connected to each corresponding through silicon via; the sensitive material layer covers a target area of the test electrode;
each interconnection layer comprises a sensitive layer hole and a plurality of wire through holes, wherein each wire through hole is provided with an interconnection wire, two ends of each interconnection wire are respectively connected to a test electrode of a sensor below the interconnection layer and a silicon through hole of a sensor above the interconnection layer, and each sensitive layer hole is used for accommodating a sensitive material layer of the sensor below the interconnection layer;
the plurality of through silicon vias in each sensor respectively belong to different through silicon via groups, each through silicon via group comprises through silicon vias which are connected in series through the interconnection lines in the plurality of through silicon vias in each sensor, and symmetry axes of the through silicon vias in at least one through silicon via group coincide.
2. The apparatus of claim 1, wherein the base further comprises a substrate, a dielectric layer, and a first insulating layer;
the dielectric layer covers at least part of the area of the first surface of the substrate, and each silicon through hole penetrates through the substrate and the dielectric layer;
the first insulating layer covers the second surface of the substrate and at least exposes a through hole area corresponding to each through silicon hole;
wherein the test electrode is located above the dielectric layer.
3. The apparatus of claim 2, wherein the sensor body further comprises: the electrode and the second insulating layer are heated,
the heating electrode is positioned above the dielectric layer and connected with each corresponding silicon through hole;
the second insulating layer is positioned above the dielectric layer and covers the surface of the heating electrode except the first connecting region, and is provided with at least two electrode through holes, and each electrode through hole exposes a silicon through hole connected with the test electrode;
the test electrode is located above the second insulating layer, the target area is overlapped with the heating electrode, and the test electrode is connected to each corresponding through silicon via through the electrode via.
4. The apparatus of claim 1, wherein axes of symmetry of the through-silicon vias in each of the through-silicon via groups coincide and the lines of symmetry of the through-silicon vias in different ones of the through-silicon via groups are not identical.
5. The apparatus of claim 1 or 3, wherein at least one misaligned through-silicon via group is present in a plurality of said through-silicon via groups, the symmetry axes of at least two through-silicon vias in the plurality of through-silicon vias of said misaligned through-silicon via group being misaligned,
and the metal wiring is used for connecting the heating electrode of the sensor below the interconnection layer and the through silicon hole of the sensor above the interconnection layer.
6. The device of claim 1, wherein the plurality of sensors includes a gas sensor, a temperature sensor, and an acceleration sensor, the gas sensor being located above the temperature sensor and the acceleration sensor being located below the temperature sensor in the device.
7. The apparatus of claim 1, wherein the apparatus further comprises: the sensor at the lowest layer of the plurality of sensors and the alarm module are fixed on the substrate and are electrically connected through the substrate,
the alarm module is used for sending out alarm prompts under the condition that the alarm conditions are met according to the detection results of the sensors.
8. The apparatus of claim 1, wherein each of the through-silicon vias has a diameter of 20 μm to 50 μm and an aspect ratio of 5:1 to 10:1.
9. The apparatus of claim 3, wherein the device comprises a plurality of sensors,
the shape of the heating electrode comprises a malleable shape, and the malleable shape comprises any one of a snake shape and an S shape; and/or
The test electrode comprises an interdigital electrode, the target area is a periodic pattern area of the interdigital electrode, and the ductile-shaped area of the heating electrode and the target area are matched in size and overlapped in position.
10. A method of manufacturing a through-silicon via based MEMS sensor integrated device according to any one of claims 1-9, the method comprising: a sensor manufacturing step and a sensor stacking step,
The sensor manufacturing steps include: preparing a dielectric layer on a first surface of a substrate; manufacturing a plurality of through silicon vias penetrating through the substrate and the dielectric layer; preparing a first insulating layer on the second surface of the substrate, and etching the first insulating layer to at least expose a through hole area corresponding to each silicon through hole to obtain a matrix of the sensor; manufacturing a test electrode above the dielectric layer; manufacturing a sensitive material layer above a target area of the test electrode to obtain a sensor main body, and finishing the preparation of the sensor;
the sensor stacking step includes: preparing an interconnect layer over a lowermost sensor based on a stacking order of a plurality of sensors in the device; etching the interconnection layer to form a sensitive layer hole and a plurality of line through holes so as to expose the sensitive material layer through the sensitive layer hole and expose the test electrode through each line through hole; filling metal in the wire through hole to form an interconnection wire; fixing an upper sensor adjacent to the lowermost sensor above the lowermost sensor to the interconnect layer; and taking the upper layer sensor as the lowest layer sensor to continuously fix the next sensor until all the sensors are stacked.
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