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CN110267737B - Device for preparing and treating a gas flow by automatically adjusting the volume of liquid - Google Patents

Device for preparing and treating a gas flow by automatically adjusting the volume of liquid Download PDF

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CN110267737B
CN110267737B CN201880011069.0A CN201880011069A CN110267737B CN 110267737 B CN110267737 B CN 110267737B CN 201880011069 A CN201880011069 A CN 201880011069A CN 110267737 B CN110267737 B CN 110267737B
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liquid
exchange chamber
operating parameter
gas flow
air flow
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CN110267737A (en
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J·詹姆里
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Starklab SAS
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1412Controlling the absorption process
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    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
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    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D53/30Controlling by gas-analysis apparatus
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    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
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    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
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    • B01D53/46Removing components of defined structure
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    • B01D53/50Sulfur oxides
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    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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    • B01J2219/00177Controlling or regulating processes controlling the pH
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    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00186Controlling or regulating processes controlling the composition of the reactive mixture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
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  • Air Conditioning Control Device (AREA)

Abstract

用于气流(F)制备和处理的设备,包括具有至少一个第一气流排出口(2b)的交换室(2)、向交换室供应液体(L)的装置(3;4)、排出交换室(2)中容纳的液体(L)的装置(3;5)及气动装置(6),气动装置在运行时能通过抽吸或吹送产生来自交换室(2)外的进入气流(F),使得进入气流(F)被引入交换室(2)中容纳的液体体积(V)中,及经过与液体体积直接接触获得处理的输出气流(F')在交换室内上升,通过排出口(2b)排出交换室(2)外。设备还包括用于在输出气流(F')中测量的第一操作参数(Xout)的第一测量装置(7)或用于测量交换室(2)中容纳或来自交换室的液体中化合物的浓度(CLout)或测量交换室(2)中容纳或来自交换室的液体的pH值(pHout)的第一操作参数(Xout)的第一测量装置。设备包括电子调节装置(9),其能自动控制交换室供液装置(3;4)和交换室排液装置(3;5),以至少根据第一操作参数(Xout)自动调节交换室内的液体高度(h)。

Figure 201880011069

Apparatus for the preparation and treatment of a gas stream (F), comprising an exchange chamber (2) with at least one first gas flow discharge opening (2b), means (3; 4) for supplying liquid (L) to the exchange chamber, discharging the exchange chamber The device (3; 5) and the pneumatic device (6) of the liquid (L) contained in (2), the pneumatic device can generate the incoming air flow (F) from outside the exchange chamber (2) by suction or blowing during operation, so that the incoming air flow (F) is introduced into the liquid volume (V) contained in the exchange chamber (2), and the output air flow (F') obtained by direct contact with the liquid volume rises in the exchange chamber through the discharge port (2b) out of the exchange chamber (2). The apparatus further comprises first measuring means (7) for measuring the first operating parameter ( Xout ) in the output gas flow (F') or for measuring compounds in the liquid contained in or from the exchange chamber (2) The concentration (CL out ) of the first measuring means (X out ) or the first operating parameter (X out ) of the pH value (pH out ) of the liquid contained in or from the exchange chamber (2). The device comprises electronic regulation means (9) capable of automatically controlling the exchange chamber liquid supply means (3; 4) and the exchange chamber liquid discharge means (3; 5) to automatically regulate the exchange chamber liquid at least according to a first operating parameter (X out ) liquid height (h).

Figure 201880011069

Description

Device for preparing and treating a gas flow by automatically adjusting the volume of liquid
Technical Field
The invention relates to the preparation and treatment of gas streams by means of liquid volumes that undergo automatic adjustment of the liquid volume. The invention applies to various fields, such as, for example, non-exclusively: heat recovery in gas streams, in particular hot air streams or industrial fumes; passing a gas stream through the liquid volume to produce a heated or cooled gas stream; preparing a temperature-controlled gas stream and/or an absolute humidity-controlled gas stream; humidifying or dehumidifying the air flow; purifying or filtering the gas flow; treating the gas stream by chemically reacting the gas stream with a liquid generator; heating or air conditioning of a site or industrial building, commercial building or residential building; site or industrial building, commercial building or residential building air humidity control.
Background
The use of liquids such as water for treating a gas stream, in particular for bringing the gas stream into direct contact with a liquid and for heating or cooling the gas stream by heat exchange between the liquid and the gas stream, is an old-fashioned technique which has the advantage of being environmentally friendly, since it avoids in particular the use of coolant-type heat carriers. The heating or cooling of the air stream, in particular the heating or cooling of the air stream, may for example be aimed at producing an air stream with a controlled temperature and/or at producing an air stream with a controlled absolute humidity.
A first technical solution known for implementing this technique consists in passing the gas stream through a curtain of fine droplets, or passing the gas stream through an exchange surface permeable to the liquid and containing it, for example a water-soaked textile material, or in flowing the gas stream in contact with a wet plate. The main drawbacks of this type of solution are the very low energy efficiency of the heat exchange between the liquid and the air flow, and the low air flow rates that can be obtained.
A second technical solution is known which consists in passing a gas flow, in particular an air flow, directly through the liquid volume contained in the exchange chamber, by injecting the gas flow into said liquid volume below the surface of the latter. Solutions of this type are described, for example, in international patent application WO2006/138287 and in US patent US4697735 (figure 3). Solutions of this type are also described in international patent applications WO2015/086979 and WO 2016/071648. The advantages of this second technical solution are: a higher energy efficiency of the heat exchange between the liquid and the gas flow can be achieved than with the first technical solution.
In this second technical solution, the exchange between the gas flow and the liquid volume depends on the liquid level through which the gas flow passes. The higher the liquid level, the more this exchange. For example, when a liquid is used to heat or cool a gas stream, the higher the level of liquid in the exchange chamber, the greater the amount of heat exchanged between the gas stream and the liquid per unit time. When a liquid is used to capture a compound in a gas stream, the higher the height of the liquid in the exchange chamber, the greater the amount of that compound captured per unit time in the liquid.
In some applications, the pressure in the gas flow at the inlet of the exchange chamber and/or the pressure in the gas flow at the outlet of the exchange chamber may vary in an uncontrolled manner, which automatically leads to a change in the liquid level in the exchange chamber to compensate for such pressure variations. This change in liquid level causes a change in the operating point of the apparatus, the exchange between the gas flow and the liquid volume in the exchange chamber being adversely changed in an uncontrolled manner.
In some applications, even if the pressure in the gas flow at the inlet of the exchange chamber and the pressure of the gas flow at the outlet of the exchange chamber are constant over time, it may prove useful to be able to vary the operating point of the device, and therefore the level of exchange between the gas flow and the liquid volume, for example to bring it to an optimum level.
More generally, there is a need to automatically adjust the operating point of an apparatus for preparing and treating a gas stream by passing the gas stream through the volume of liquid contained in an exchange chamber.
Disclosure of Invention
Object of the Invention
The present invention aims to propose a new technical solution that enables the preparation of a gas flow to be treated by means of a liquid contained in an exchange chamber and the automatic adjustment of the operating point of the plant.
Summary of The Invention
Accordingly, the present invention is directed to an apparatus for preparing and treating a gas stream, the apparatus comprising: an exchange chamber having at least one first gas flow exhaust port; a liquid supply device for supplying liquid to the exchange chamber such that the exchange chamber can contain a volume of liquid and the first gas flow outlet of the exchange chamber is positioned above a surface of the volume of liquid contained within the exchange chamber; a liquid discharge device for discharging the liquid contained in the exchange chamber; and a pneumatic device capable, in operation, of generating an incoming air flow from outside the exchange chamber by suction or blowing, so that the incoming air flow is introduced into the liquid volume contained in the exchange chamber below the surface of said volume, and so that an outgoing air flow, treated by direct contact with said liquid volume, rises inside the exchange chamber and is discharged outside said exchange chamber through a first air flow discharge opening of the exchange chamber.
According to a feature of the invention, the device further comprises a first operating parameter (X) for measurement in the output airflowout) Or for measuring the Concentration (CL) of a compound in or from a liquid contained in or from the exchange chamberout) Or measuring the pH (pH) of the liquid contained in or from the exchange chamberout) First operating parameter (X)out) The first measuring device of (1); and in that the apparatus comprises electronic regulation means able to automatically control, in particular during operation of the apparatus, the liquid supply means of the exchange chamber and the liquid discharge means of the exchange chamber, at least as a function of said first operating parameter (X)out) The liquid level (or in other words the liquid level) in the exchange chamber is automatically adjusted.
More specifically, but optionally according to the invention, the device of the invention may comprise the additional and optional technical features defined in any one of claims 2 to 15, described later, taken alone or in combination.
The invention is also directed to the use of at least one apparatus as described above for preparing at least one gas stream treated by passing through a volume of liquid contained in an exchange chamber of the apparatus.
More specifically, the invention is directed to the use of at least one of the above-described devices for filtering and/or purifying and/or cooling and/or heating an incoming gas stream.
More specifically, the invention is directed to the use of at least one of the above-mentioned devices for treating one of the following gas flows: an incoming gas stream resulting from combustion; or an inlet gas stream containing industrial fumes, in particular high-temperature industrial fumes; or a gas stream containing at least one compound selected from the group consisting of: nitrogen oxide NoxVolatile organic compound COV, sulfur oxide SOxPolycyclic aromatic hydrocarbon HAP、CO、CO2、NH3And chloramine.
Drawings
The characteristics and advantages of the invention will emerge from a reading of the following detailed description of some particular embodiments of the invention, described by way of non-limiting and non-exhaustive example with reference to the accompanying schematic drawings in which:
figure 1 is a schematic view of a first device according to the invention;
figure 2 is a schematic view of a second device according to the invention.
Detailed Description
Several embodiments of the apparatus for preparing and treating a gas stream according to the present invention will be described in detail below. These devices can be used in all applications where it is useful to process a gas stream by passing it through a volume of liquid. These devices can therefore also be used in various fields, such as, for example, non-exclusively: heat recovery in gas streams, in particular hot air streams or industrial fumes; passing a gas stream through the liquid volume to produce a heated or cooled gas stream; preparing a temperature-controlled and/or absolute humidity-controlled gas stream; humidifying or dehumidifying the air flow; purifying or filtering the gas flow; performing gas flow treatment by passing gas flow through liquid to perform chemical reaction; heating or air conditioning of a site or industrial building, commercial building or residential building; site or industrial building, commercial building or residential building air humidity control. The prepared gas stream can also be used for cooling, heating, humidifying or dehumidifying any type of object or surface.
With reference to the particular embodiment of fig. 1, the apparatus 1A for gas stream preparation and treatment comprises an exchange chamber 2 and a liquid reservoir in the form of a tank 3, which contains a liquid bath L, for example water.
The invention is not limited to the use of water as the liquid L but extends to any other type of liquid. As non-limiting and non-exhaustive examples, it may be beneficial in certain applications to use a liquid L having a curing temperature below 0 ℃ at atmospheric pressure, such as water containing additives of salts, sugars, glycols, alcohols. It may also be beneficial to use oil as the liquid L.
More specifically, in the embodiment of fig. 1, the bath 3 is hermetically closed, so that the liquid bath L contained in the bath 3 is isolated from the pressure outside the exchange chamber 2, for example from the atmospheric pressure when the apparatus 1A is in the open air.
In another variant, the bath 3 may be open, so that the liquid volume outside the exchange chamber 2 is, for example, at atmospheric pressure.
The lower surface of the lower part 20 of each exchange chamber 2 is open, thus forming a liquid inlet 2 a. The lower part 20 of each exchange chamber 2 is positioned in the bath 3 such that by filling the bath 3 with a sufficient level, the lower part 20 of each exchange chamber 2 is immersed in the bath of liquid contained in the bath 3, the immersed portion of each exchange chamber 2 containing a volume V of liquid.
The exchange chamber 2 comprises at least one gas flow discharge opening 2b in its upper part, which discharge opening 2b is positioned above the liquid volume V contained in the exchange chamber 2.
In order to supply new liquid to the bath 3, the apparatus 1A further comprises a supply device 4 for supplying new liquid, which supply device comprises a supply pipe 40 leading to the bath 3 above the liquid bath, which supply pipe is provided with a supply valve 41 for controlled supply of new liquid to the bath 3. In this embodiment, the bath 3 and the liquid supply means 4 for supplying liquid to the bath 3 form liquid supply means for supplying liquid to the exchange chamber 2.
The apparatus 1A further comprises a drain 5 comprising a drain pipe 50 whose base communicates with the interior of the basin 3 below the surface of the bath of liquid contained in the basin 3, the drain pipe being provided with a drain valve 51 for the controlled discharge of liquid out of the basin 3. In this embodiment, the basin 3 and said drainage means 5 form drainage means for discharging the liquid contained in the exchange chamber 2.
In another embodiment, not shown, the exchange chamber cannot be immersed in the bath 3 at the lower part, as described in international patent application WO2015/086979, but is closed at the lower part and the liquid supply is obtained directly through a pipe without using the bath 3.
The apparatus 1A further comprises pneumatic means 6 able, in operation, to generate an inlet flow F coming from outside the exchange chamber 2, so that the inlet flow F is introduced into the liquid volume V contained in the exchange chamber 2 below the surface S of said liquid volume, and an outlet flow F', treated by direct contact with said liquid volume, rises inside the exchange chamber 2, being discharged outside said exchange chamber 2 through the discharge opening 2b of the exchange chamber 2.
In the particular embodiment of fig. 1, the pneumatic means 6 are able to generate, in operation, an incoming airflow F from outside the exchange chamber 2 by suction. In a further variant, the pneumatic device 6 can generate the inlet air flow F by blowing in operation.
In the particular embodiment of fig. 1, the pneumatic means 6 comprise a fan 60, the inlet 60a of which is connected to the outlet 2b of the exchange chamber 2.
The fan 60 may be, for example, a centrifugal fan or any known type of gas compressor, such as an axial fan, a pump, etc.
The pneumatic means 6 also comprise injection means 61 which can introduce the incoming gas flow F into the liquid volume V contained in the exchange chamber 2 below the surface S of said volume.
In the particular embodiment of fig. 1, the injection means 61 comprise a vertical injection duct 610 positioned inside the exchange chamber 2, which comprises, at the upper part, an air inlet 610a for the entry of an air flow and, at the lower part, an air discharge 610b for the discharge of an air flow. The intake port 610a communicates with an intake duct 611 for intake of an air flow, which is positioned outside the exchange chamber 2. The intake duct includes an intake port 611a for intake of an air flow.
Depending on the application, this air inlet 611a may, for example, open to the open air, or may be connected to any equipment or any facility in which the air flow F is captured.
When the fan 60 is operated, the inside of the exchange chamber 2 is depressurized. When the fan 60 is operating, the pressure in the bath 3 outside the exchange chamber 2 and above the liquid bath L is equal to the pressure P in the incoming air flow F at the inlet of the injection duct 610, since the bath 3 is closedin. The pressure PinGreater than the pressure P above the liquid volume in the exchange chamber 2out
Pressure difference Δ P (Δ P ═ P)in-Pout) In the exchange chamber 2 (FIG. 1) is represented by a liquid level (FIG. 1/height h) liter in the exchange chamber 2High and the liquid level (figure 1/height H) drops in the tank 3 outside the exchange chamber 2.
The liquid level h and the liquid volume V in the exchange chamber 2 depend on this pressure difference ap.
When the fan 60 is operated, it draws an intake air flow F which enters the injection duct 610 of the exchange chamber 2 through the intake port 610a of the injection duct 610. This (untreated) incoming gas flow F is introduced into the non-immersed portion of the injection pipe 610, through the discharge outlet 610b of the immersed lower portion of the injection pipe 610, below the surface S of the liquid volume V contained in the immersed lower portion of the exchange chamber 2. The exhaust flow F' treated by direct contact with said volume of liquid contained in the exchange chamber 2 rises inside the exchange chamber 2 outside the injection duct 610 and is discharged outside said exchange chamber through the discharge opening 2b thereof. This exhaust air flow F' is drawn by the fan 60 and is exhausted in the form of an air flow F "(fig. 1).
Depending on the application, the air outlet 60b of the fan 60 may, for example, open to the open air, or may be connected to a duct (not shown) for conveying the air flow F "to another device or to another installation without being directly discharged to the free air.
Sensible and latent heat exchange between the gas and the liquid takes place when the temperature of the liquid volume V in the exchange chamber 2 differs from the temperature of the gas flow F before it is introduced into the liquid volume V.
Temperature T of liquid volumeliquideBelow the initial temperature T of the gas flow F before it is introduced into the liquid volumeinitialeWhile the gas flow F' is cooled. More specifically, the temperature of the outgoing air flow F' has been reduced, and may for example be substantially equal to the temperature T of the liquid volumeliquideAnd (5) the consistency is achieved. This at the same time results in the output air flow F 'from the device 1A being dehumidified compared to the incoming air flow F, the absolute humidity (weight of water per unit volume of air) in the output air flow F' being lower than that of the incoming air flow F.
On the contrary, when the temperature T of the liquid volumeliquideAbove the initial temperature TinitialeThe output air flow F 'is heated, the temperature of the output air flow F' can be, for example, substantially equal to the temperature T of the liquid volumeliquideAnd (5) the consistency is achieved. This at the same time results in the output air flow F 'from the device 1A being humidified compared to the incoming air flow F, the absolute humidity (weight of water per unit volume of air) in the output air flow F' being higher than that of the incoming air flow F.
In some applications, the apparatus 1A may be used to filter or purify an incoming gas stream F by passing the incoming gas stream through a volume of liquid V. The apparatus 1A may also be used to condense or evaporate one or more compounds carried in the incoming gas stream F by passing the incoming gas stream F through a volume of liquid V. Depending on the application, the temperature of the liquid volume may be higher or lower than the temperature of the incoming gas stream F, or substantially equal to the temperature of the incoming gas stream F. When the temperature of the liquid volume is substantially equal to the temperature of the incoming gas flow F, an outgoing gas flow F' is generated at the outlet of the device 1A, neither heated nor cooled, having substantially the same temperature as the incoming gas flow F.
In the embodiment of fig. 1, fan 60 may generate airflows F and F' by suction. In another variant, the fan 60 can be connected to the air inlet 610a of the injection duct 610 so as to generate these air flows F and F' by blowing and not by suction.
With reference to fig. 1, the apparatus 1A comprises a first operating parameter X for measurement in the output airflow FoutIn this case above the volume of the liquid L in the exchange chamber 2.
The apparatus 1A further comprises a second operating parameter X for measurement in the incoming gas flow FinIn this case in the inlet duct 611 and close to the inlet 610a of the injection pipe 610.
The apparatus 1A also comprises electronic regulation means 9 able to automatically control the liquid supply means 4 and the liquid discharge means 5 during operation of the apparatus, so as to normally depend at least on the first operating parameter XoutFor example at least one set value XCThe height h (or in other words the level) of the liquid in the exchange chamber 2 is automatically adjusted.
More specifically, the electronic regulation means 9 are able to automatically control the liquid supply means 4 and the liquid discharge means 5 so as to also be dependent on the second operating parameter XinPreferably according to the difference Xout-Xin(absolute value orAlgebraic value) automatically adjusts the height h of the liquid in the exchange chamber 2.
For example, when XoutGreater than XCWhen, or when the difference X isout-Xin(absolute value) greater than XCThe electronic regulating device 9 automatically controls the liquid supply device 4 so as to increase the level h of the liquid in the exchange chamber 2. On the contrary, when XoutLess than XCWhen, or when the difference X isout-Xin(absolute value) less than XCThe electronic regulating means 9 automatically controls the draining means 5 so as to lower the level h of the liquid in the exchange chamber 2.
In many applications, the pressure P in the gas flow F at the inlet of the exchange chamber 2inAnd/or the pressure P in the gas flow F' at the outlet of the exchange chamber 2outUncontrolled changes can occur because of the absence of the adjusting means 9, which automatically result in a change in the liquid level h in the exchange chamber 2 to compensate for the pressure change. This variation in the liquid level causes a variation in the operating point of the apparatus, the exchange between the liquid volume and the gas flow in the exchange chamber being detrimentally altered uncontrollably. Also in some applications, even the pressure P in the gas flow at the inlet of the exchange chamber 2inAnd the pressure P of the gas flow at the outlet of the exchange chamber 2outAlways constant, but it may prove useful to be able to vary the operating point of the plant and therefore the level of exchange between the gas flow and the liquid volume, for example in order to make it optimal.
Thus, in the first embodiment, the first operating parameter XoutMay be the pressure P in the treated gas flow Fout(Xout=Pout) And a second operating parameter XinMay be the pressure P in the incoming gas flow Fin(Xin=Pin) The first and second measuring devices 7 and 8 are, for example, pitot probes.
By acting on the pressure PoutMore specifically according to the pressure difference Pout-PinAutomatically adjusting the height h of the liquid in the exchange chamber 2, ensuring that the quality of the exchange between the operating point of the installation, and therefore the incoming gas flow F, and the liquid in the chamber 2 is always correct, independent of the pressure PinAnd PoutInfluence.
In the second embodimentIn (1), a first operating parameter XoutMay be the temperature T measured in the treated gas flow Fout(Xout=Tout) And a second operating parameter XinMay be the temperature T measured in the incoming gas flow Fin(Xin=Tin) In this case the first and second measuring means 7 and 8 are temperature probes.
In a third embodiment, the first operating parameter XoutMay be the concentration C of the (chemical or particulate) component measured in the treated gas stream Fout(Xout=Cout) And a second operating parameter XinMay be the concentration C of the component measured in the incoming gas stream Fin(Xin=Cin) In this case the first and second measuring means 7 and 8 are detectors of the component.
By way of non-limiting and non-exhaustive example, in the treatment of a gas stream consisting of combustion fumes, in particular industrial fumes, the chemical component may be Nitrogen Oxides (NO)x) The liquid volume is used in the exchange chamber to capture these nitrogen oxides. In other applications, the compounds captured in the liquid may be selected from the following table, without limitation and without exhaustive: COV (volatile organic Compounds), SOxHAP (polycyclic aromatic hydrocarbons), CO2、NH3And chloramine.
Another apparatus 1B of the invention is shown in fig. 2, which differs from the apparatus 1A of fig. 1 in that:
a first operating parameter (X) for measurement in the liquid contained in the exchange chamber 2out) Is measured by the first measuring device 7',
a second operating parameter (X) for measurement in the liquid contained in the tank 3 outside the exchange chamber 2in) And a second measuring device 8'.
In another variant, the first operating parameter (X) can be measured in the liquid coming from the exchange chamber 2out)。
In another variant, said second operating parameter (X)in) Can be measured in the new liquid before it is introduced into the bath 3 and thus into the exchange chamber 2,for example measured in the supply pipe 40 upstream or downstream of the valve 41.
Within the framework of the invention, the first operating parameter (X)out) May be the concentration of the Compound (CL) in the liquid contained in the exchange chamber 2out) And the second operating parameter may be the concentration of the compound in the liquid outside the exchange chamber 2 (CL)in)。
Within the framework of the invention, the first operating parameter (X)out) May be the pH value (pH) of the liquid contained in the exchange chamber 2out) And the second operating parameter may be the pH value (pH) of the liquid outside the exchange chamber 2in) In this case, the first and second measuring devices 7 'and 8' are pH measuring probes.
In a modified variant of the invention, in addition to adjusting the liquid level h in the exchange chamber 2, the electronic adjusting means 9 can also be designed, for example programmed, to automatically control the valves 41 and 51 so as to be able to continuously or intermittently update the liquid in the exchange chamber 2, preferably during operation of the apparatus, on the basis of parameters measured in the liquid in the exchange chamber 2 or in the liquid from the exchange chamber 2 and/or in a new liquid before introduction into the exchange chamber 2, such as the pH value of the liquid and/or the concentration of compounds in the liquid and/or the liquid temperature, and/or on the basis of parameters measured in the incoming gas flow F and/or parameters measured in the outgoing gas flow F', such as in particular the gas flow temperature or the concentration of components in the gas flow.

Claims (21)

1.一种用于制备和处理气流(F)的设备,所述设备包括:交换室(2),交换室具有至少一个第一气流排出口(2b);供液装置(3;4),用于向交换室供应液体(L),使得交换室(2)能够容纳液体体积(V),并且所述交换室的第一气流排出口(2b)定位于交换室内容纳的液体体积(V)的表面(S)上方;排液装置(3;5),用于排出容纳在交换室(2)中的液体(L);以及气动装置(6),气动装置在运行时能够通过抽吸或吹送产生来自交换室(2)外部的进入气流(F),使得进入气流(F)在交换室(2)中容纳的液体体积(V)的表面(S)的下方被引入到所述液体体积中,以及使得经过与所述液体体积直接接触获得处理的输出气流(F')在交换室内上升,并通过交换室(2)的第一气流排出口(2b)被排出到所述交换室(2)之外,其特征在于,所述设备还包括用于在输出气流(F')中测量的第一操作参数(Xout)的第一测量装置(7)、或者用于测量交换室(2)中容纳的液体中或来自交换室(2)的液体中化合物的浓度(CLout)或测量交换室(2)中容纳的液体或来自交换室(2)的液体的pH值(pHout)的第一操作参数(Xout)的第一测量装置(7');并且,所述设备包括电子调节装置(9),电子调节装置能够自动控制交换室的供液装置(3;4)和交换室的排液装置(3;5),以至少根据所述第一操作参数(Xout)自动调节交换室内的液体高度(h)。1. An apparatus for preparing and processing gas flow (F), the apparatus comprising: an exchange chamber (2) having at least one first gas flow outlet (2b); a liquid supply device (3; 4), for supplying liquid (L) to the exchange chamber so that the exchange chamber (2) can accommodate the liquid volume (V), and the first gas flow discharge port (2b) of the exchange chamber is positioned at the liquid volume (V) contained in the exchange chamber above the surface (S) of the device; drain means (3; 5) for draining the liquid (L) contained in the exchange chamber (2); and pneumatic means (6) which can be operated by suction or The blowing creates an incoming air flow (F) from outside the exchange chamber (2) so that the incoming air flow (F) is introduced into the liquid volume below the surface (S) of the liquid volume (V) contained in the exchange chamber (2) and the output air flow (F') obtained by direct contact with the liquid volume rises in the exchange chamber and is discharged into the exchange chamber (2) through the first air flow discharge port (2b) of the exchange chamber (2). 2), characterized in that the device further comprises a first measuring device (7) for measuring a first operating parameter ( Xout ) in the output air flow (F'), or a first measuring device (7) for measuring the exchange chamber ( 2) Concentration of the compound in the liquid contained in or from the exchange chamber (2) (CL out ) or measure the pH of the liquid contained in the exchange chamber (2) or from the exchange chamber (2) (pH out ) ) of a first measuring device (7') of a first operating parameter (X out ); and, the device comprises electronic regulation means (9) capable of automatically controlling the liquid supply means (3; 4) of the exchange chamber and liquid discharge means (3; 5) for the exchange chamber to automatically adjust the liquid height (h) in the exchange chamber according to at least said first operating parameter (X out ). 2.根据权利要求1所述的设备,其特征在于,第一操作参数(Xout)是交换室(2)中在液体体积上方测得的压力(Pout)。2. Device according to claim 1, characterized in that the first operating parameter (X out ) is the pressure (P out ) measured above the liquid volume in the exchange chamber (2). 3.根据权利要求1所述的设备,其特征在于,第一操作参数(Xout)是输出气流(F')的温度(Tout)。3. Device according to claim 1, characterized in that the first operating parameter (X out ) is the temperature (T out ) of the output air flow (F'). 4.根据权利要求1所述的设备,其特征在于,第一操作参数(Xout)是输出气流(F')中组分的浓度(Cout)。4. Apparatus according to claim 1, characterized in that the first operating parameter (X out ) is the concentration (C out ) of the component in the output gas stream (F'). 5.根据前述权利要求中任一项所述的设备,其特征在于,所述设备还包括用于在输出气流(F')外部测量第二操作参数(Xin)的第二测量装置(8;8'),其特征在于,电子调节装置(9)能够自动控制交换室(2)的供液装置(3;4)和交换室(2)的排液装置(3;5),以还根据所述第二操作参数(Xin)自动调节交换室(2)内的液体高度(h)。5. Device according to any of the preceding claims, characterized in that it further comprises second measuring means (8) for measuring the second operating parameter (X in ) outside the output air flow (F') 8'), characterized in that the electronic regulating device (9) can automatically control the liquid supply device (3; 4) of the exchange chamber (2) and the liquid discharge device (3; 5) of the exchange chamber (2), so as to also The liquid height (h) in the exchange chamber (2) is automatically adjusted according to said second operating parameter (X in ). 6.根据权利要求5所述的设备,其特征在于,第二测量装置(8)能够在进入气流(F)中测量所述第二操作参数(Xin)。6. Device according to claim 5, characterized in that second measuring means (8) are capable of measuring the second operating parameter (X in ) in the incoming air flow (F). 7.根据权利要求6所述的设备,其特征在于,第二操作参数(Xin)是在进入气流(F)中测得的压力(Pin)。7. Device according to claim 6, characterized in that the second operating parameter (X in ) is the pressure (P in ) measured in the incoming gas flow (F). 8.根据权利要求6所述的设备,其特征在于,第二操作参数(Xin)是进入气流(F)的温度(Tin)。8. Device according to claim 6, characterized in that the second operating parameter (X in ) is the temperature (T in ) of the incoming gas flow (F). 9.根据权利要求6所述的设备,其特征在于,第二操作参数(Xin)是进入气流(F)中组分的浓度(Cin)。9. Apparatus according to claim 6, characterized in that the second operating parameter (X in ) is the concentration (C in ) of the component in the incoming gas stream (F). 10.根据权利要求5所述的设备,其特征在于,第二操作参数(Xin)是在交换室(2)外部的液体中的化合物的浓度(CLin)。10. Device according to claim 5, characterized in that the second operating parameter (X in ) is the concentration (CL in ) of the compound in the liquid outside the exchange chamber (2). 11.根据权利要求5所述的设备,其特征在于,第二操作参数(Xin)是在交换室(2)外部的液体的pH值(pHin)。11. Device according to claim 5, characterized in that the second operating parameter (Xin) is the pH value ( pHin ) of the liquid outside the exchange chamber (2). 12.根据权利要求5所述的设备,其特征在于,电子调节装置(9)能够根据第一操作参数(Xout)和第二操作参数(Xin)之差值自动控制交换室(2)的供液装置(3;4)和交换室(2)的排液装置(3;5)。12. The device according to claim 5, characterized in that the electronic regulating means (9) are capable of automatically controlling the exchange chamber (2) according to the difference between the first operating parameter (X out ) and the second operating parameter (X in ) The liquid supply device (3; 4) and the liquid discharge device (3; 5) of the exchange chamber (2). 13.根据权利要求1至4中任一项所述的设备,其特征在于,用于向交换室(2)供应液体的供液装置(3;4)包括液体(L)储存器(3),交换室(2)的下部包括至少一个液体入口(2a)并浸入在液体储存器(3)中。13. Apparatus according to any one of claims 1 to 4, characterized in that the liquid supply means (3; 4) for supplying liquid to the exchange chamber (2) comprise a liquid (L) reservoir (3) , the lower part of the exchange chamber (2) comprises at least one liquid inlet (2a) and is immersed in a liquid reservoir (3). 14.根据权利要求13所述的设备,其特征在于,其特征在于,液体储存器(3)密闭,使得液体储存器(3)中在液体上方的压力(Pin)等于进入气流(F)中的压力。14. Apparatus according to claim 13, characterized in that the liquid reservoir (3) is sealed such that the pressure (Pin) above the liquid in the liquid reservoir (3) is equal to the incoming gas flow (F) pressure in. 15.根据权利要求1至4中任一项所述的设备,其特征在于,电子调节装置(9)能够自动控制交换室的供液装置(3;4)以及交换室的排液装置(3;5),以便根据在交换室(2)的液体中或来自交换室(2)的液体中测得的参数和/或在引入交换室(2)之前的新液体中测得的参数、和/或根据在进入气流(F)中测得的参数和/或在输出气流(F')中测得的参数,能连续或断续地更新交换室(2)中的液体。15. The device according to any one of claims 1 to 4, characterized in that the electronic regulating device (9) can automatically control the liquid supply device (3; 4) of the exchange chamber and the liquid discharge device (3) of the exchange chamber 5), so as to be based on the parameters measured in the liquid of the exchange chamber (2) or from the liquid from the exchange chamber (2) and/or the parameters measured in the new liquid before introduction into the exchange chamber (2), and The liquid in the exchange chamber (2) can be updated continuously or intermittently according to parameters measured in the incoming gas flow (F) and/or parameters measured in the outgoing gas flow (F'). 16.根据权利要求11所述的设备,其特征在于,第二操作参数(Xin)是在引入交换室(2)之前的新液体中的pH值(pHin)。16. Device according to claim 11, characterized in that the second operating parameter (Xin) is the pH value ( pHin) in the new liquid before introduction into the exchange chamber (2). 17.根据前述权利要求15所述的设备,其特征在于,电子调节装置(9)能够自动控制交换室的供液装置(3;4)以及交换室的排液装置(3;5),以便根据在交换室(2)的液体中或来自交换室(2)的液体中测得的和/或在引入交换室(2)之前的新液体中测得的液体的pH值和/或液体中化合物的浓度和/或液体温度、和/或根据在进入气流(F)中测得的和/或在输出气流(F')中测得的气流温度或气流中组分的浓度,能连续或断续地更新交换室(2)中的液体。17. The device according to the preceding claim 15, characterized in that the electronic regulation means (9) are able to automatically control the liquid supply means (3; 4) of the exchange chamber and the liquid discharge means (3; 5) of the exchange chamber in order to According to the pH of the liquid and/or in the liquid measured in the liquid in the exchange chamber (2) or in the liquid from the exchange chamber (2) and/or in the new liquid before introduction into the exchange chamber (2) The concentration of the compound and/or the liquid temperature, and/or the gas stream temperature measured in the incoming gas stream (F) and/or the gas stream temperature or the concentration of the components in the gas stream measured in the outgoing gas stream (F'), can be continuously or The liquid in the exchange chamber (2) is refreshed intermittently. 18.至少一个根据前述权利要求中任一项所述的设备的用途,其特征在于,所述设备用于制备至少一种气流(F'),所述至少一种气流通过使进入气流(F)经过设备的交换室(2)中容纳的液体体积而获得处理。18. Use of at least one device according to any one of the preceding claims, characterized in that it is used to prepare at least one gas flow (F') by making the incoming gas flow (F') ) is processed through the volume of liquid contained in the exchange chamber (2) of the device. 19.根据权利要求18所述的用途,其特征在于,所述设备用于过滤和/或净化和/或冷却和/或加热进入气流(F)。19. Use according to claim 18, characterised in that the device is used for filtering and/or purifying and/or cooling and/or heating the incoming gas stream (F). 20.根据权利要求18或19所述的用途,其特征在于,所述设备用于处理以下气流中的一种气流:源于燃烧的进入气流(F);或含有工业烟气的进入气流(F);或含有选自下列化合物中的至少一种化合物的气流:氮氧化物NO x、挥发性有机化合物VOC、硫氧化物SOx、多环芳烃HAP、CO、CO2、NH3、氯胺。20. Use according to claim 18 or 19, characterised in that the device is used to treat one of the following gas streams: an incoming air stream (F) originating from combustion; or an incoming air stream (F) containing industrial fumes ( F); or a gas stream containing at least one compound selected from the group consisting of nitrogen oxides NO x , volatile organic compounds VOC, sulfur oxides SO x , polycyclic aromatic hydrocarbons HAP, CO, CO 2 , NH 3 , chlorine amine. 21.根据权利要求20所述的用途,其特征在于,工业烟气是高温工业烟气。21. The use according to claim 20, wherein the industrial flue gas is high temperature industrial flue gas.
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