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DE69222317D1 - Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung - Google Patents

Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung

Info

Publication number
DE69222317D1
DE69222317D1 DE69222317T DE69222317T DE69222317D1 DE 69222317 D1 DE69222317 D1 DE 69222317D1 DE 69222317 T DE69222317 T DE 69222317T DE 69222317 T DE69222317 T DE 69222317T DE 69222317 D1 DE69222317 D1 DE 69222317D1
Authority
DE
Germany
Prior art keywords
polyionic
transition metal
metal container
container composition
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69222317T
Other languages
English (en)
Other versions
DE69222317T2 (de
Inventor
Howard Turner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25168914&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69222317(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of DE69222317D1 publication Critical patent/DE69222317D1/de
Publication of DE69222317T2 publication Critical patent/DE69222317T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyethers (AREA)
DE69222317T 1991-11-25 1992-11-25 Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung Expired - Lifetime DE69222317T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US79672991A 1991-11-25 1991-11-25
PCT/US1992/010296 WO1993011172A1 (en) 1991-11-25 1992-11-25 Polyonic transition metal catalyst composition

Publications (2)

Publication Number Publication Date
DE69222317D1 true DE69222317D1 (de) 1997-10-23
DE69222317T2 DE69222317T2 (de) 1998-02-12

Family

ID=25168914

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69222317T Expired - Lifetime DE69222317T2 (de) 1991-11-25 1992-11-25 Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung

Country Status (7)

Country Link
US (1) US5427991A (de)
EP (1) EP0614468B1 (de)
JP (1) JP3273944B2 (de)
CA (1) CA2124187C (de)
DE (1) DE69222317T2 (de)
ES (1) ES2108861T3 (de)
WO (1) WO1993011172A1 (de)

Families Citing this family (141)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
CA2141814A1 (en) * 1992-08-05 1994-02-17 David Jonathan Upton Supported ionic transition metal catalysts for olefin polymerization
US5455214A (en) * 1993-09-09 1995-10-03 Mobil Oil Corporation Metallocenes supported on ion exchange resins
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
AU687231B2 (en) * 1994-08-03 1998-02-19 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
EP0710663A1 (de) * 1994-11-01 1996-05-08 Japan Polyolefins Co., Ltd. Borenthaltende Verbindung, sein Polymer, diese Polymer und ein Metallocen enthaltender Katalysator und ein Verfahren zur Herstellung eines Polyolefins
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US5939347A (en) * 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
EP0727443B1 (de) * 1995-02-20 2001-01-17 Tosoh Corporation Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
KR100420432B1 (ko) * 1995-03-10 2004-07-23 다우 글로벌 테크놀로지스 인크. 지지된촉매및이를이용한중합방법
US5885924A (en) 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
EP0775707B1 (de) * 1995-06-08 2001-11-28 Showa Denko Kabushiki Kaisha Ionische Verbindungen und Katalysator für die Olefinpolymerisation, der die Verbindungen verwendet
US5674613A (en) 1995-06-14 1997-10-07 Exxon Chemical Patents Inc. Electrical devices including ethylene, a-olefin, vinyl norbornene elastomeric polymers
US5766713A (en) * 1995-06-14 1998-06-16 Exxon Chemical Patents Inc. Elastomeric vehicle hoses
JP3514344B2 (ja) 1995-09-27 2004-03-31 昭和電工株式会社 イオン性化合物
KR19990071655A (ko) * 1995-11-27 1999-09-27 그레이스 스티븐 에스. 구속된 양이온 형성 활성화제를 함유하는지지된 촉매
AU1991297A (en) * 1996-03-27 1997-10-17 Dow Chemical Company, The Solution polymerization process with dispersed catalyst activator
ES2129323B1 (es) 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
JPH09309926A (ja) 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
DE19622207A1 (de) 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
ES2158567T3 (es) 1996-06-17 2001-09-01 Exxonmobil Chem Patents Inc Sistemas cataliticos de metales de transicion mixtos para la polimerizacion de olefinas.
US6812184B1 (en) * 1996-06-17 2004-11-02 Exxonmobil Chemical Patents Inc. Supported late transition metal catalyst systems
GB9613814D0 (en) * 1996-07-02 1996-09-04 Bp Chem Int Ltd Supported polymerisation catalysts
US6759499B1 (en) * 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
ATE202365T1 (de) * 1996-08-13 2001-07-15 Basell Polyolefine Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
EP0824112B1 (de) 1996-08-13 2006-05-10 Basell Polyolefine GmbH Geträgerte chemische Verbindung
US5952427A (en) * 1996-12-10 1999-09-14 Exxon Chemical Patents Inc. Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers
US5763533A (en) * 1996-12-10 1998-06-09 Exxon Chemical Patents Inc. Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
US6184319B1 (en) * 1996-12-20 2001-02-06 Sumitomo Chemical Company, Limited Olefin polymer, films or sheets made therefrom, and process for the production of olefin polymer
US5889128A (en) 1997-04-11 1999-03-30 Massachusetts Institute Of Technology Living olefin polymerization processes
KR100532265B1 (ko) * 1997-06-05 2005-11-29 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 중합체 지지 촉매
US6228795B1 (en) * 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
US6426313B2 (en) 1997-06-05 2002-07-30 Exxon Mobil Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
EP1312618A3 (de) * 1997-06-05 2003-12-10 ExxonMobil Chemical Patents Inc. Katalysator auf Polymerträger zur Polymerisation von Olefinen
WO2002083754A1 (en) 2001-04-12 2002-10-24 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
CN1143867C (zh) 1997-12-01 2004-03-31 旭化成株式会社 烯烃聚合催化剂和使用该催化剂来聚合烯烃的方法
US6177375B1 (en) * 1998-03-09 2001-01-23 Pq Corporation High activity olefin polymerization catalysts
DE19812881A1 (de) 1998-03-24 1999-10-07 Bayer Ag Neue dendrimere Verbindungen, ein Verfahren zu deren Herstellung sowie deren Verwendung als Katalysatoren
BR9908171A (pt) * 1998-03-27 2000-10-31 Exxon Chemical Patents Inc Catalizadores poliméricos suportados para polimerização de olefinas
US6977283B1 (en) 1998-04-07 2005-12-20 Exxonmobil Chemical Patents Inc. Polymerization process
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
ES2216586T3 (es) 1998-06-12 2004-10-16 Univation Technologies Llc Procedimiento de polimerizacion de olefinas que usa complejos activados de acido-base de lewis.
EP1522553B1 (de) 1998-07-01 2007-04-11 ExxonMobil Chemical Patents Inc. Elastische Mischung mit Kristallpolymeren und kristallisierbaren Polymeren des Propens
US7354880B2 (en) * 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
CA2330775A1 (en) 1998-07-16 2000-01-27 Univation Technologies Llc Aluminum-based lewis acid cocatalysts for olefin polymerization
AU6045399A (en) 1998-09-16 2000-04-03 Dow Chemical Company, The Slurry polymerization process and polymer compositions
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
US6184171B1 (en) 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
US6486088B1 (en) 1998-10-23 2002-11-26 Exxonmobil Chemical Patents Inc. High activity carbenium-activated polymerization catalysts
DE69922534T2 (de) 1998-10-29 2005-11-03 Exxonmobil Chemical Patents Inc., Baytown Ethylen/alpha-olefin elastomerische zusammensetzungen mit verbesserter extrusionsverarbeitbarkeit
US6147173A (en) * 1998-11-13 2000-11-14 Univation Technologies, Llc Nitrogen-containing group 13 anionic complexes for olefin polymerization
US6197714B1 (en) * 1999-03-23 2001-03-06 Cryovac, Inc. Supported catalysts and olefin polymerization processes utilizing same
US6197715B1 (en) * 1999-03-23 2001-03-06 Cryovac, Inc. Supported catalysts and olefin polymerization processes utilizing same
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6346586B1 (en) * 1999-10-22 2002-02-12 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6399535B1 (en) 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6395847B2 (en) 1999-11-19 2002-05-28 Exxonmobil Chemical Patents Inc. Supported organometallic catalysts and their use in olefin polymerization
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
JP2003518169A (ja) 1999-12-20 2003-06-03 エクソンモービル・ケミカル・パテンツ・インク 担持イオン性触媒を使用するポリオレフィン樹脂の製造方法
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
TW548283B (en) * 2000-01-11 2003-08-21 Dow Chemical Co Chemically-modified supports and supported catalyst systems prepared therefrom
US20030212222A1 (en) * 2001-01-09 2003-11-13 Carnahan Edmund M. Chemically -modified supports and supported catalyst systems prepared therefrom
CA2416197A1 (en) * 2000-07-17 2002-01-24 David E. Gindelberger A catalyst system and its use in a polymerization process
US6858767B1 (en) 2000-08-11 2005-02-22 Uniroyal Chemical Company, Inc. Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
CA2425212A1 (en) * 2000-08-23 2002-02-28 Phairson Medical, Inc. Novel polymer compounds
US7220804B1 (en) * 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
US6943133B2 (en) * 2000-10-20 2005-09-13 Univation Technologies, Llc Diene functionalized catalyst supports and supported catalyst compositions
US6593267B2 (en) 2000-12-18 2003-07-15 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
WO2002050134A1 (fr) * 2000-12-19 2002-06-27 Sunallomer Ltd. Catalyseur de polymerisation d'olefines, composant de catalyseur pour la polymerisation d'olefines, procede de stockage de ces derniers et processus de production de polymere olefinique
US6933258B2 (en) 2000-12-19 2005-08-23 Univation Technologies, L.L.C. Catalyst composition and methods for its preparation and use in a polymerization process
US6632770B2 (en) 2000-12-22 2003-10-14 Univation Technologies, Llc Catalyst system and its use in a polymerization process
EP1401887A1 (de) 2001-04-30 2004-03-31 W.R. Grace & Co.-Conn. Heterogene chromkatalysatoren und verfahren zur polymerisation von olefinen mit diesen katalysatoren
WO2002088198A1 (en) 2001-04-30 2002-11-07 W.R. Grace & Co.-Conn. Method of making supported transition metal polymerization catalysts and compositions formed therefrom
KR100893971B1 (ko) 2001-04-30 2009-04-20 더블유.알. 그레이스 앤드 캄파니-콘. 지지된 이중 전이금속 촉매 시스템
US6946420B2 (en) 2001-04-30 2005-09-20 W. R. Grace & Co.-Conn Coordination catalyst systems employing chromium support-agglomerate and method of their preparation
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
EP1401570B1 (de) 2001-06-13 2007-08-15 BETA Technologie AG Massenpolymerisation-reaktoren und verfahren zur polymerisation
JP2003128720A (ja) * 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
US6943215B2 (en) * 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
WO2003040201A1 (en) 2001-11-06 2003-05-15 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6927256B2 (en) 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
US6906160B2 (en) * 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
JP4031656B2 (ja) 2002-03-14 2008-01-09 バセル ポリオレフィン イタリア エス．アール．エル． ポリプロピレン系樹脂組成物およびそのフィルム
JP4728643B2 (ja) * 2002-10-02 2011-07-20 ダウ グローバル テクノロジーズ エルエルシー 液状およびゲル状の低分子量エチレンポリマー類
DE60322410D1 (de) * 2002-10-17 2008-09-04 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7579407B2 (en) 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
DE602004027473D1 (de) * 2003-03-21 2010-07-15 Dow Global Technologies Inc Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
CN1852959B (zh) 2003-08-19 2010-06-16 陶氏环球技术公司 适用于热熔粘合剂的共聚体及其制备方法
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
GB0411742D0 (en) 2004-05-26 2004-06-30 Exxonmobil Chem Patents Inc Transition metal compounds for olefin polymerization and oligomerization
US8093341B2 (en) 2004-10-28 2012-01-10 Dow Global Technologies Llc Method of controlling a polymerization reactor
EP1963347B1 (de) 2005-12-14 2011-10-19 ExxonMobil Chemical Patents Inc. Halogensubstituierte metallocenverbindungen für die olefinpolymerisation
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
US7585991B2 (en) * 2007-01-18 2009-09-08 Lewis Stewart P (Pentafluorophenyl) group 11 and 12 metal compounds, processes for preparing (pentafluorophenyl) group 11 and 12 metal compounds, and uses thereof
CN101711258B (zh) * 2007-03-07 2012-07-04 陶氏环球技术有限责任公司 系连负载型过渡金属络合物
ES2401040T3 (es) * 2007-08-16 2013-04-16 Univation Technologies, Llc Aditivos de continuidad y su uso en procesos de polimerización
EP2050755A1 (de) * 2007-10-19 2009-04-22 Total Petrochemicals Research Feluy Gestützte ionische Flüssigkeiten oder activierende Träger
EP2070953A1 (de) 2007-12-11 2009-06-17 Total Petrochemicals Research Feluy Träger zur Aktivierung auf der Basis von Phosphoniumkomplexen
WO2009082546A2 (en) 2007-12-18 2009-07-02 Exxonmobil Chemical Patents Inc. Polyethylene films and process for production thereof
EP2112173A1 (de) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Katalysatorverbindungen und ihre Verwendung
WO2009088428A1 (en) 2008-01-07 2009-07-16 Univation Technologies, Llc Catalyst feed systems and methods for using the same
JP2009269570A (ja) 2008-05-09 2009-11-19 Fujitsu Ten Ltd 電子機器
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
US20110256632A1 (en) 2009-01-08 2011-10-20 Univation Technologies, Llc Additive for Polyolefin Polymerization Processes
WO2010144130A1 (en) 2009-06-11 2010-12-16 W.R. Grace & Co. -Conn. Process of making aluminoxane and catalysts comprising thus prepared aluminoxane
RU2011152483A (ru) 2009-07-23 2013-06-27 Юнивейшн Текнолоджиз, Ллк Реакционная система для полимеризации
US8957167B2 (en) 2009-07-28 2015-02-17 Univation Technologies, Llc Polymerization process using a supported constrained geometry catalyst
US8067652B2 (en) 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
CN105061644B (zh) 2009-12-24 2017-10-27 埃克森美孚化学专利公司 用于生产新型合成基础油料的方法
EP2630168A4 (de) 2010-10-21 2014-10-29 Exxonmobil Chem Patents Inc Polyethylen und herstellungsverfahren dafür
ES2640318T3 (es) 2010-12-22 2017-11-02 Univation Technologies, Llc Aditivo para procedimientos de polimerización de olefinas
US9045569B2 (en) 2011-01-14 2015-06-02 W. R. Grace & Co.-Conn. Process of making modified metallocene catalyst, catalyst produced and use thereof
EP2610269A1 (de) 2011-12-28 2013-07-03 Saudi Basic Industries Corporation Katalysatorzusammensetzung und Herstellungsverfahren dafür
CA2933157C (en) 2013-12-09 2021-11-16 Univation Technologies, Llc Feeding polymerization additives to polymerization processes
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
TWI642675B (zh) 2016-11-25 2018-12-01 南韓商Ｌｇ化學股份有限公司 塗佈組成物以及有機發光裝置
CN111902467B (zh) 2018-02-05 2022-11-11 埃克森美孚化学专利公司 通过添加超高分子量高密度聚乙烯增强的lldpe的加工性
WO2019156968A1 (en) 2018-02-07 2019-08-15 Exxonmobil Chemical Patents Inc. Supported catalysts systems and polymerization processes for using the same
JP7059700B2 (ja) * 2018-03-08 2022-04-26 日本ポリエチレン株式会社 オレフィン重合触媒及びオレフィン重合体の製造方法
EP3768734A1 (de) 2018-03-19 2021-01-27 ExxonMobil Chemical Patents Inc. Elastomere propylen-alpha-olefin-dien-terpolymer-zusammensetzungen
BR112021021366A2 (pt) * 2019-04-30 2022-03-15 Dow Global Technologies Llc Processo de polimerização
US12281221B2 (en) 2019-07-17 2025-04-22 ExxonMobil Engineering & Technology Company Tires comprising rubber compounds that comprise propylene-α-olefin-diene polymers
EP4010421B1 (de) 2019-08-05 2025-05-21 ExxonMobil Chemical Patents Inc. Propylen-alpha-olefin-dien-terpolymer-additiv zur verbesserung der klebrigkeit von gummi
WO2021188361A1 (en) 2020-03-20 2021-09-23 Exxonmobil Chemical Patents Inc. Linear alpha-olefin copolymers and impact copolymers thereof
KR102513518B1 (ko) 2020-12-23 2023-03-22 디엘케미칼 주식회사 메탈로센 올레핀 중합 공정용 대전방지제를 이용한 올레핀 중합 방법
US12195563B2 (en) 2020-12-29 2025-01-14 Exxonmobil Chemical Patents Inc. Polyolefin-based ionomers and production thereof
WO2023081010A1 (en) 2021-11-05 2023-05-11 Exxonmobil Chemical Patents Inc. Polypropylene viscosity modifiers and lubricating oils thereof

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1221307A (en) * 1982-12-02 1987-05-05 Nobutaka Tani Adsorbent and process for preparing the same
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
CA1248679A (en) * 1984-05-21 1989-01-10 Peter C. Gaa Aqueous dispersion, internally silylated and dispersed polyurethane resins, and process for producing same and surfaces containing same
CA1244349A (en) * 1985-06-26 1988-11-08 Jen-Chang Hsia Purification of hemoglobin and modified hemoglobin by affinity chromatography
EP0230247A3 (de) * 1986-01-14 1988-02-17 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Adsorbiermittel zur Entfernung einer komplementären Komponente
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
DE3718888A1 (de) * 1987-06-05 1988-12-22 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
JPH05502906A (ja) * 1990-01-02 1993-05-20 エクソン・ケミカル・パテンツ・インク オレフィン重合用の担持イオン性メタロセン触媒
PL166690B1 (pl) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
DE69124255T3 (de) * 1990-06-22 2005-10-06 Exxon Chemical Patents Inc. Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation
US5079205A (en) * 1990-07-13 1992-01-07 Exxon Chemical Patents Inc. Group ivb, vb and vib metal hydrocarbyloxides, with alumoxane for olefin polymerization
ES2085000T3 (es) * 1990-12-27 1996-05-16 Exxon Chemical Patents Inc Un compuesto de amido-metal de transicion y un sistema catalitico para la produccion de polipropileno isotactico.
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids

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DE69222317T2 (de) 1998-02-12
WO1993011172A1 (en) 1993-06-10
EP0614468B1 (de) 1997-09-17
EP0614468A1 (de) 1994-09-14
US5427991A (en) 1995-06-27
JP3273944B2 (ja) 2002-04-15
CA2124187A1 (en) 1993-06-10
CA2124187C (en) 2001-08-07
JPH07501573A (ja) 1995-02-16

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