JP2002507325A - pn接合を有するSiC半導体装置 - Google Patents
pn接合を有するSiC半導体装置Info
- Publication number
- JP2002507325A JP2002507325A JP50549399A JP50549399A JP2002507325A JP 2002507325 A JP2002507325 A JP 2002507325A JP 50549399 A JP50549399 A JP 50549399A JP 50549399 A JP50549399 A JP 50549399A JP 2002507325 A JP2002507325 A JP 2002507325A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- jte
- junction
- semiconductor device
- region
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004065 semiconductor Substances 0.000 title claims abstract description 27
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 230000007423 decrease Effects 0.000 claims abstract description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 18
- 238000002161 passivation Methods 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 230000005684 electric field Effects 0.000 description 23
- 238000005468 ion implantation Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 239000004020 conductor Substances 0.000 description 4
- 230000000873 masking effect Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/80—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
- H10D62/83—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge
- H10D62/832—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge being Group IV materials comprising two or more elements, e.g. SiGe
- H10D62/8325—Silicon carbide
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/28—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
- H01L23/31—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the arrangement or shape
- H01L23/3157—Partial encapsulation or coating
- H01L23/3178—Coating or filling in grooves made in the semiconductor body
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D48/00—Individual devices not covered by groups H10D1/00 - H10D44/00
- H10D48/30—Devices controlled by electric currents or voltages
- H10D48/32—Devices controlled by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H10D48/36—Unipolar devices
- H10D48/362—Unipolar transistors having ohmic electrodes on emitter-like, base-like, and collector-like regions, e.g. hot electron transistors [HET], metal base transistors [MBT], resonant tunnelling transistors [RTT], bulk barrier transistors [BBT], planar doped barrier transistors [PDBT] or charge injection transistors [CHINT]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/102—Constructional design considerations for preventing surface leakage or controlling electric field concentration
- H10D62/103—Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices
- H10D62/105—Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices by having particular doping profiles, shapes or arrangements of PN junctions; by having supplementary regions, e.g. junction termination extension [JTE]
- H10D62/106—Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices by having particular doping profiles, shapes or arrangements of PN junctions; by having supplementary regions, e.g. junction termination extension [JTE] having supplementary regions doped oppositely to or in rectifying contact with regions of the semiconductor bodies, e.g. guard rings with PN or Schottky junctions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/117—Shapes of semiconductor bodies
Landscapes
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Electrodes Of Semiconductors (AREA)
- Junction Field-Effect Transistors (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
- Recrystallisation Techniques (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. ドーピングされた炭化珪素(SiC)を具備し、第1の導電形式の層と、 その上の第2の導電形式の層とから構成されたpn接合を有し、該第2の導電形 式の層のエッジに、エッジターミネーション(JTE)が設けられ、該ターミネ ーションの外側境界に向かって徐々にまたは連続的に有効シート電荷密度が減少 する、平坦構造の半導体装置であって、 前記pn接合およびそのJTEが、第3の層によって被覆されていることを特 徴とする半導体装置。 2. 前記第3の層が、第1の導電形式のものであることを特徴とする請求項1 記載の半導体装置。 3. 前記第3の層が、第2の導電形式のものであることを特徴とする請求項1 記載の半導体装置。 4. 前記第3の層が、前記pn接合の中心から、半径方向外側の方向に向かっ て、前記第2の層におけるJTEの外延を超えて延び、該第3の層自体が、JT Eの最外領域として機能することを特徴とする請求項1から請求項3のいずれか に記載の半導体装置。 5. 前記第3の層が、前記pn接合の中心から、半径方向外側の方向に向かっ て、前記第2の層におけるJTEの外延を超えて延び、前記JTEの最後の領域 が、前記第3の層内に注入されていることを特徴とする請求項1から請求項3の いずれかに記載の半導体装置。 6. 前記装置の表面が不動態層(5)により被覆されていることを特徴とする 請求項1から請求項5のいずれかに記載の半導体装置。 7. 前記pn接合およびそのJTEが、MISFET、IGBT、JFETま たはFCTのいずれかに埋め込まれたグリッドの一部であり、前記第3の層が、 前記構成部材のドリフト領域の一部を構成することを特徴とする請求項1から請 求項5のいずれかに記載の半導体装置。 8. 前記pn接合およびそのJTEが、JFETまたはFCTのいずれかに埋 め込まれたグリッドの一部であり、前記第3の層が、前記構成部材のチャネル領 域の一部を構成することを特徴とする請求項1から請求項5のいずれかに記載の 半導体装置。 9. 前記pn接合およびそのJTEが、MISFETまたはIGBTのいずれ かに埋め込まれたグリッドの一部であり、前記第3の層が前記構成部材のベース 領域の一部を構成することを特徴とする請求項1から請求項5のいずれかに記載 の半導体装置。 10. 前記第3の層(4)が、エピタキシャル成長した層であることを特徴と する請求項1から請求項9のいずれかに記載の半導体装置。 11. pn接合を構成する、低濃度にドーピングされた第1の導電形式の炭化 珪素層(2)と高濃度にドーピングされた第2の導電形式の炭化珪素層(3)と を相互の上に有し、前記高濃度にドーピングされた層のエッジに、エッジターミ ネーションが設けられた物体から開始して、平坦構造のpn接合を具備する半導 体装置を製造する方法であって、SiCからなる第3の層がJTEの上に形成さ れることを特徴とする方法。 12. 前記第3の層が、前記JTEの上および前記pn接合の中心から半径方 向外側に前記第2の層のJTEを超える前記第2の層の外延の上に形成されるこ とを特徴とする請求項11記載の方法。 13. 前記第3の層が、前記JTEの上にエピタキシャル成長されることを特 徴とする請求項11または請求項12記載の方法。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/883,106 | 1997-06-26 | ||
| US08/883,106 US5932894A (en) | 1997-06-26 | 1997-06-26 | SiC semiconductor device comprising a pn junction |
| PCT/SE1998/001255 WO1999000849A2 (en) | 1997-06-26 | 1998-06-26 | SiC SEMICONDUCTOR DEVICE COMPRISING A PN-JUNCTION AND A JUNCTION TERMINATION EXTENTION |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002507325A true JP2002507325A (ja) | 2002-03-05 |
| JP4531142B2 JP4531142B2 (ja) | 2010-08-25 |
Family
ID=25381999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50549399A Expired - Lifetime JP4531142B2 (ja) | 1997-06-26 | 1998-06-26 | SiC半導体装置 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5932894A (ja) |
| EP (1) | EP1016142B9 (ja) |
| JP (1) | JP4531142B2 (ja) |
| DE (1) | DE69841272D1 (ja) |
| WO (1) | WO1999000849A2 (ja) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007029375A1 (ja) * | 2005-09-08 | 2007-03-15 | Mitsubishi Denki Kabushiki Kaisha | 半導体装置および半導体装置の製造方法 |
| JP2007096245A (ja) * | 2005-09-05 | 2007-04-12 | Fujitsu Ltd | 半導体装置及びその半導体装置の製造方法 |
| WO2012131878A1 (ja) * | 2011-03-28 | 2012-10-04 | トヨタ自動車株式会社 | 縦型半導体装置 |
| WO2014155565A1 (ja) * | 2013-03-27 | 2014-10-02 | トヨタ自動車株式会社 | 縦型半導体装置 |
| US8866158B2 (en) | 2011-04-04 | 2014-10-21 | Mitsubishi Electric Corporation | Semiconductor device and method for manufacturing same |
| JP2015115373A (ja) * | 2013-12-09 | 2015-06-22 | 富士電機株式会社 | 半導体装置および半導体装置の製造方法 |
| JP2015142080A (ja) * | 2014-01-30 | 2015-08-03 | 富士電機株式会社 | 半導体装置および半導体装置の製造方法 |
| JP2017118139A (ja) * | 2017-02-27 | 2017-06-29 | 富士電機株式会社 | 半導体装置および半導体装置の製造方法 |
| JP2017199926A (ja) * | 2017-07-03 | 2017-11-02 | 富士電機株式会社 | 半導体装置および半導体装置の製造方法 |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE512259C2 (sv) * | 1998-03-23 | 2000-02-21 | Abb Research Ltd | Halvledaranordning bestående av dopad kiselkarbid vilken innefattar en pn-övergång som uppvisar åtminstone en ihålig defekt och förfarande för dess framställning |
| SE9904710L (sv) * | 1999-12-22 | 2001-06-23 | Abb Ab | Halvledaranordning |
| US6642558B1 (en) * | 2000-03-20 | 2003-11-04 | Koninklijke Philips Electronics N.V. | Method and apparatus of terminating a high voltage solid state device |
| US6573128B1 (en) | 2000-11-28 | 2003-06-03 | Cree, Inc. | Epitaxial edge termination for silicon carbide Schottky devices and methods of fabricating silicon carbide devices incorporating same |
| SE0004377D0 (sv) | 2000-11-29 | 2000-11-29 | Abb Research Ltd | A semiconductor device and a method for production thereof |
| US6734462B1 (en) | 2001-12-07 | 2004-05-11 | The United States Of America As Represented By The Secretary Of The Army | Silicon carbide power devices having increased voltage blocking capabilities |
| CA2381128A1 (en) * | 2002-04-09 | 2003-10-09 | Quantiscript Inc. | Plasma polymerized electron beam resist |
| US7026650B2 (en) | 2003-01-15 | 2006-04-11 | Cree, Inc. | Multiple floating guard ring edge termination for silicon carbide devices |
| US9515135B2 (en) * | 2003-01-15 | 2016-12-06 | Cree, Inc. | Edge termination structures for silicon carbide devices |
| WO2004100225A2 (en) * | 2003-05-01 | 2004-11-18 | The University Of South Carolina | A system and method for fabricating diodes |
| US20050259368A1 (en) * | 2003-11-12 | 2005-11-24 | Ted Letavic | Method and apparatus of terminating a high voltage solid state device |
| WO2005119793A2 (en) * | 2004-05-28 | 2005-12-15 | Caracal, Inc. | Silicon carbide schottky diodes and fabrication method |
| US7812441B2 (en) | 2004-10-21 | 2010-10-12 | Siliconix Technology C.V. | Schottky diode with improved surge capability |
| US7394158B2 (en) * | 2004-10-21 | 2008-07-01 | Siliconix Technology C.V. | Solderable top metal for SiC device |
| US7834376B2 (en) * | 2005-03-04 | 2010-11-16 | Siliconix Technology C. V. | Power semiconductor switch |
| US9419092B2 (en) * | 2005-03-04 | 2016-08-16 | Vishay-Siliconix | Termination for SiC trench devices |
| US8901699B2 (en) | 2005-05-11 | 2014-12-02 | Cree, Inc. | Silicon carbide junction barrier Schottky diodes with suppressed minority carrier injection |
| US7768092B2 (en) * | 2005-07-20 | 2010-08-03 | Cree Sweden Ab | Semiconductor device comprising a junction having a plurality of rings |
| US8368165B2 (en) * | 2005-10-20 | 2013-02-05 | Siliconix Technology C. V. | Silicon carbide Schottky diode |
| JP2009545885A (ja) * | 2006-07-31 | 2009-12-24 | ヴィシェイ−シリコニックス | SiCショットキーダイオード用モリブデンバリア金属および製造方法 |
| US8106487B2 (en) | 2008-12-23 | 2012-01-31 | Pratt & Whitney Rocketdyne, Inc. | Semiconductor device having an inorganic coating layer applied over a junction termination extension |
| US8637386B2 (en) * | 2009-05-12 | 2014-01-28 | Cree, Inc. | Diffused junction termination structures for silicon carbide devices and methods of fabricating silicon carbide devices incorporating same |
| US8933643B2 (en) | 2012-04-20 | 2015-01-13 | Apple Inc. | Display backlight driver IC configuration |
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| JPH01138759A (ja) * | 1986-12-26 | 1989-05-31 | Toshiba Corp | 高耐圧プレーナ素子 |
| JPH02186675A (ja) * | 1989-01-13 | 1990-07-20 | Toshiba Corp | 高耐圧プレーナ型半導体素子およびその製造方法 |
| WO1996003774A1 (de) * | 1994-07-27 | 1996-02-08 | Siemens Aktiengesellschaft | Halbleiterbauelement mit hochsperrendem randabschluss |
| WO1996021246A1 (en) * | 1995-01-03 | 1996-07-11 | Abb Research Ltd. | Semiconductor device having a passivation layer |
| JPH08186246A (ja) * | 1994-12-28 | 1996-07-16 | Yazaki Corp | 埋込ゲート型半導体装置 |
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| JP3471823B2 (ja) * | 1992-01-16 | 2003-12-02 | 富士電機株式会社 | 絶縁ゲート型半導体装置およびその製造方法 |
| US5378642A (en) * | 1993-04-19 | 1995-01-03 | General Electric Company | Method of making a silicon carbide junction field effect transistor device for high temperature applications |
| JPH09501018A (ja) * | 1993-07-29 | 1997-01-28 | シーメンス コンポーネンツ インコーポレイテッド | リバースフィールドプレート、接合終端構造 |
| US5486718A (en) * | 1994-07-05 | 1996-01-23 | Motorola, Inc. | High voltage planar edge termination structure and method of making same |
| US5455432A (en) * | 1994-10-11 | 1995-10-03 | Kobe Steel Usa | Diamond semiconductor device with carbide interlayer |
| US5543637A (en) * | 1994-11-14 | 1996-08-06 | North Carolina State University | Silicon carbide semiconductor devices having buried silicon carbide conduction barrier layers therein |
| SE9601176D0 (sv) * | 1996-03-27 | 1996-03-27 | Abb Research Ltd | A method for producing a semiconductor device having semiconductor layers of SiC by the use of an implanting step and a device produced thereby |
| US5763905A (en) * | 1996-07-09 | 1998-06-09 | Abb Research Ltd. | Semiconductor device having a passivation layer |
-
1997
- 1997-06-26 US US08/883,106 patent/US5932894A/en not_active Expired - Lifetime
-
1998
- 1998-06-26 DE DE69841272T patent/DE69841272D1/de not_active Expired - Lifetime
- 1998-06-26 EP EP98931179A patent/EP1016142B9/en not_active Expired - Lifetime
- 1998-06-26 JP JP50549399A patent/JP4531142B2/ja not_active Expired - Lifetime
- 1998-06-26 WO PCT/SE1998/001255 patent/WO1999000849A2/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01138759A (ja) * | 1986-12-26 | 1989-05-31 | Toshiba Corp | 高耐圧プレーナ素子 |
| JPH02186675A (ja) * | 1989-01-13 | 1990-07-20 | Toshiba Corp | 高耐圧プレーナ型半導体素子およびその製造方法 |
| WO1996003774A1 (de) * | 1994-07-27 | 1996-02-08 | Siemens Aktiengesellschaft | Halbleiterbauelement mit hochsperrendem randabschluss |
| JPH08186246A (ja) * | 1994-12-28 | 1996-07-16 | Yazaki Corp | 埋込ゲート型半導体装置 |
| WO1996021246A1 (en) * | 1995-01-03 | 1996-07-11 | Abb Research Ltd. | Semiconductor device having a passivation layer |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007096245A (ja) * | 2005-09-05 | 2007-04-12 | Fujitsu Ltd | 半導体装置及びその半導体装置の製造方法 |
| WO2007029375A1 (ja) * | 2005-09-08 | 2007-03-15 | Mitsubishi Denki Kabushiki Kaisha | 半導体装置および半導体装置の製造方法 |
| DE112006002377T5 (de) | 2005-09-08 | 2008-07-03 | Mitsubishi Denki K.K. | Halbleitervorrichtung und Verfahren zum Herstellen einer Halbleitervorrichtung |
| US8026160B2 (en) | 2005-09-08 | 2011-09-27 | Mitsubishi Electric Corporation | Semiconductor device and semiconductor device manufacturing method |
| JP4889645B2 (ja) * | 2005-09-08 | 2012-03-07 | 三菱電機株式会社 | 半導体装置の製造方法 |
| JP5459403B2 (ja) * | 2011-03-28 | 2014-04-02 | トヨタ自動車株式会社 | 縦型半導体装置 |
| WO2012131878A1 (ja) * | 2011-03-28 | 2012-10-04 | トヨタ自動車株式会社 | 縦型半導体装置 |
| US9035415B2 (en) | 2011-03-28 | 2015-05-19 | Toyota Jidosha Kabushiki Kaisha | Vertical semiconductor device comprising a resurf structure |
| US8866158B2 (en) | 2011-04-04 | 2014-10-21 | Mitsubishi Electric Corporation | Semiconductor device and method for manufacturing same |
| WO2014155565A1 (ja) * | 2013-03-27 | 2014-10-02 | トヨタ自動車株式会社 | 縦型半導体装置 |
| JP2015115373A (ja) * | 2013-12-09 | 2015-06-22 | 富士電機株式会社 | 半導体装置および半導体装置の製造方法 |
| JP2015142080A (ja) * | 2014-01-30 | 2015-08-03 | 富士電機株式会社 | 半導体装置および半導体装置の製造方法 |
| JP2017118139A (ja) * | 2017-02-27 | 2017-06-29 | 富士電機株式会社 | 半導体装置および半導体装置の製造方法 |
| JP2017199926A (ja) * | 2017-07-03 | 2017-11-02 | 富士電機株式会社 | 半導体装置および半導体装置の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69841272D1 (de) | 2009-12-17 |
| EP1016142B9 (en) | 2010-02-24 |
| JP4531142B2 (ja) | 2010-08-25 |
| EP1016142B1 (en) | 2009-11-04 |
| US5932894A (en) | 1999-08-03 |
| WO1999000849A3 (en) | 1999-03-25 |
| EP1016142A2 (en) | 2000-07-05 |
| WO1999000849A2 (en) | 1999-01-07 |
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