WO1986005509A1 - Compositions detergentes desinfectantes et/ou hygienisantes - Google Patents
Compositions detergentes desinfectantes et/ou hygienisantes Download PDFInfo
- Publication number
- WO1986005509A1 WO1986005509A1 PCT/US1986/000486 US8600486W WO8605509A1 WO 1986005509 A1 WO1986005509 A1 WO 1986005509A1 US 8600486 W US8600486 W US 8600486W WO 8605509 A1 WO8605509 A1 WO 8605509A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight percent
- quaternary ammonium
- composition
- weight
- glycoside surfactant
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Definitions
- the present invention pertains to aqueous disinfectant and/or sanitizing cleaning compositions containing a germicidal quaternary ammonium halide compound and a glycoside surfactant material and to the use of such compositions for disinfecting and/or sanitizing surfaces , articles , etc. contaminated with undesired bacterial , fungal and/or viral organisms.
- Alkyl glycoside materials such as , for example , higher alkyl monoglycosides and higher al kyl polyglycosides are known materials; are known , at least in certain circumstances, to function as nonionic surfactants; and have been suggested as being suitable for use in certain specially formulated detergent composi ⁇ tions. See in this regard , for example, Published European Patent Application Numbers 007007 . ; 0070075; 0070076; and 0070077 , all of which published on January 19 , 1983 as well as Published European Patent Applica ⁇ tion Numbers 0075994; 0075995; and 0075996 which pub ⁇ lished on April 6 , 1983.
- Patent 4,493 ,773 (issued January 15 , 1985) which discloses laundry detergent compositions which contain a conventional nonionic detergent surfactant, an alkylpolyglycoside detergent surfactant and a quaternary ammonium cationic fabric softening surfactant and which are said to be capable of including a wide variety of conventional laundry detergent addi ⁇ tives such as relatively small amounts of detergent builders , detergency cosurfactants such as trialkyi amine oxides , solvents such as ethanol , and the like.
- a relatively specialized category of cleaning composition of interest to the art is one which is often referred to as a liquid detergent hard surface cleaning composition and which is specifically designed or for- mulated such that it can be applied to a soiled hard surface of interest (e. g . , glass , painted walls , woodwork , etc. ) and removed therefrom (for example as by wiping with a dry or damp cloth) without a subse ⁇ quent rinsing operation and without leaving a significant or unsightly residual film upon the surface after clean ⁇ ing .
- a hard surface cleaner composition which comprises from 1 -10% of an anionic surfactant (e.g .
- alkyl sulfate or alkyl aryl sulphonate or a nonionic surfactant (e.g . , an ethylene oxide condensate of a fatty alcohol or of an alkyl phenol) and at least 20% of a 1 : 1 to 4: 1 ratio mixture of an alkali metal (or ammonium) borate and sodium carbonate and which , at a 1 % concentration in water , has a pH of at least 9.6.
- a nonionic surfactant e.g , an ethylene oxide condensate of a fatty alcohol or of an alkyl phenol
- Formulations discussed in such article included (a) one which was composed of 1 weight percent of a non ⁇ ionic surfactant (linear alcohol ethoxylate) , 2.5 weight percent of anhydrous tetrapotassium pyrophosphate (builder) , 5 weight percent of ethylene glycol monobutyl ether (solvent) and the balance water and (b) another which was the same as the former except that the indicated nonionic surfactant was replaced with a corre ⁇ sponding amount of a linear alkylbenzenesulfonate anionic surfactant.
- the aforementioned nonionic surfactant-based formulation exhibited slightly more filming (i.e. , being given a "moderate” film rating) than its corresponding anionic surfactant-based counter-part (which obtained a "moderate-good” film rating) .
- cleaner disinfectant compositions such as , for example, those containing quaternary ammonium halide compounds , nonionic detergents and detergent builder ingredients are discussed in an article entitled " Formulating Quaternary Cleaner Disinfectants to Meet EPA Require ⁇ ments" by Donald F. Greene and Alfonso N . Petrocci , SOAP/COSMETI CS/CHEMI CAL SPECIALTI ES , August 1980 , pages 33-35 and 61 .
- glycoside surfactants can be suitably employed as the nonionic surfactant component in aqueous disinfectant or sanitizer cleaning compositions of the sort mentioned in the above-identified article by Greene and Petrocci . Additionally, it has also been discovered that glycoside surfactants are particularly effective in such composi ⁇ tions when ethylene diamine tetraacetic acid or alkali metal salts thereof are employed as a detergent builder ingredient. Accordingly , the present invention , in one aspect, is a l iquid disinfectant and/or sanitizer cleaning composition which , on a total composition weight basis , comprises :
- compositions may also optionally include:
- the disinfectant and/or sanitizer cleaning composition of the present invention can , if desired , suitably take the form of a dilutable liquid concentrate for t. e purposes of its convenient and economical initial manufacturing or formulation operations , transport or distribution , and/or marketing and can then be subse ⁇ quently diluted (e. g. , by the final distributor or the ultimate user) with water prior to its ultimate use in cleaner/sanitizer or cleaner/disinfectant end-use applica ⁇ tions.
- compositions of the present invention will typically comprise , on a total concentrate composition weight basis: a. from about 10 to about 50 (preferably from about 10 to about 30) weight percent of the germicidal quaternary ammonium halide compound;
- up to about 50 preferably up to about 30 weight perce ⁇ t of a water soluble detergent builder; up to about 50 (preferably up to about 30) weight per ⁇ cent of a water miscible organic solvent; and/or up to a combined total of about 50
- compositions are diluted to their ready-to-use form (i .e. , for their intended clean ⁇ ing/disinfecting or cleaning/sanitizing purposes) , they will typically contain , on a total composition weight basis : a. from about 0.01 to about 10 (preferably from about 0.01 to about 5 , more pre ⁇ ferably from about 0.02 to about 3 and most preferably from about 0.02 to about 1 .5) weight percent of the germicidal quaternary ammonium halide compound;
- diluted compositions can , if desired , also optionally include , on a total composition weight basis;
- the present invention is also a method for cleaning and disinfecting and/or sanitizing a surface or an article contaminated with undesired bacterial, viral and/or fungal organisms.
- the aforementioned diluted compositions containing at least a sanitizing or disinfecting amount of the germicidal quaternary ammonium halide compound, is contacted with said contaminated surface or article in a fashion so as to suitably sanitize or disinfect same.
- said compositions will contain, on a total composition weight basis, at least about 0.01 weight percent (preferably about 0.02 weight percent or more) of the germicidal quaternary ammonium halide compound for sanitizing purposes and at least about 0.05 (prefer ⁇ ably at least about 0.07) weight percent of sarrt for disinfectant end-use applications.
- the weight ratio of the germicidal quaternary ammonium halide compound to the glycoside surfactant will be at least about 1:1.
- the weight ratio of the germicidal quaternary ammonium halide compound to the glycoside surfactant will general ⁇ ly be within the range of from about 1:1 to about 10:1 (most preferably from about 1:1 to about 2:1).
- Germicidal quaternary ammonium halide com- pounds suitable for use in the present invention include higher (e.g. C g - C--) alkyl trimethyl ammonium halides; higher alkyl dimethyl benzyl ammonium halides; mixed higher alkyl (e.g., mixed C.., C. g , C._ and C.
- Glycoside surfactants suitable for use in the practice of the present invention include those of the formula:
- R is a monovending organic radical (e.g., a monovending saturated aliphatic, unsaturated aliphatic or aromatic radical such as alkyl, hydroxyalkyl, alkenyl, hydroxyalkenyl, aryl, alkylaryl, hydroxyalkylaryl, arylalkyl, alkenylaryl, arylalkenyl, etc.) containing from about 6 to about 30 (preferably from about 8 to about 18 and more preferably from about 9 to about 13) carbon atoms; R 1 is a divalent hydrocarbon radical containing from 2 to about 4 carbon atoms such as ethylene, propylene or butylene (most preferably the unit (R'O) represents repeating units of ethylene oxide, propylene oxide and/or random or block combinations thereof); y is a number having an average value of from 0 to about 12; Z represents a moiety derived from a reducing saccharide containing 5 or 6 carbon
- Glycoside surfactants suitable for use herein also include those of the formula I above in which one or more of the normally free (i . e. , unreacted) hydroxyl groups of the saccharide moiety, Z , have been alkoxylated (preferably , ethoxyiated or propoxylated) so as to attach one or more pendant alkoxy or poly (alkoxy) groups in place thereof.
- alkoxylated preferably , ethoxyiated or propoxylated
- the amount of alkylene oxide (e.g . ethylene oxide, propylene oxide , etc. ) employed will general ly correspond to from about 1 to about 20 ( preferably from about 3 to about 10) moles thereof per mole of saccharide moiety.
- the RO (R'O) group is generally bonded or attached to the number 1 carbon atom of the saccharide moiety , Z .
- the free hydroxyls available for alkoxylation are typically those in the number 2 , 3 , 4 and 6 positions in 6-carbon atom saccharides and those in the number 2 , 3 and 4 positions in 5-carbon atom saccharide species.
- the number 2 position hydroxyl in 5-carbon saccharides , and the number 2 and 6 position hydroxyls in 6-carbon saccharides are substantially more reactive or susceptable to alkoxylation than those in the number 3 and 4 positions. Accordingly , alkoxylation will usually occur in the former locations in preference to the latter.
- Glycoside surfactants of particular interest for use in the practice of the present invention preferably have a hydrophilic-lipophilic balance ( HLB ) in the range of from about 10 to about 18 and most preferably in the range of from about 12 to about 1 .
- HLB hydrophilic-lipophilic balance
- Water soluble detergent bui lders suitable for use herein include the various water soluble alkal i metal, ammonium or substituted ammonium phosphates , polyphosphates , phosphonates , polyphosphonates , carbonates , silicates , borates , polyhydroxysulfonates, polyacetates , carboxylates , and polycarboxyiates.
- Preferred are the alkali metal , especially sodium , salts of the above.
- suitable water soluble inorganic phosphate builders are sodium and potassium tripolyphosphate, pyrophosphate , polymeric metaphos- phate having a degree of polymerization of from about 6 to 21 , and orthophosphate.
- polyphosphonate builders are the sodium and potassium salts of ethylene-1 , 1 -diphosphonic acid , the sodium and potassium salts of ethane-1 , 1 ,2-triphosphonic acid .
- Suitable water soluble nonphospho- rus , inorganic builders for use herein include sodium and potassium carbonate , bicarbonate, sesquicarbonate, tetraborate decahydrate, and silicate having a molar ratio of SiO_ to alkali metal oxide of from about 0.5 to about 4.0 , preferably from about 1 .0 to about 2.4.
- Water soluble, nonphosphorus organic builders useful herein also include the various alkali metal , ammonium and substituted ammonium polyacetates , carboxylates , polycarboxylates and polyhydroxy- sulfonates.
- polyacetate and polycarboxylate builders include the sodium , potassium , lithium, ammonium and substituted ammonium salts of ethylenediamine tetraacetic acid , nitri lotriacetic acid, oxydisuccinic acid , mellitic acid , benzene polycarboxylic acids , and citric acid.
- Polycarboxylate builders suitable for use herein also include those set forth in U . S . Patent No. 3 , 308 , 067 , Diehl , issued March 7, 1967 incorporated herein by reference.
- Such materials include the water- soluble salts of homo- and copolymers of aliphatic carboxylic acids such as maleic acid , itaconic acid , mesaconic acid , fumaric acid , aconitic acid , citraconic acid and methylenemalonic acid .
- Other builders include the carboxylated carbo ⁇ hydrates of U . S. Patent 3 ,723 ,322 Diehl incorporated herein by reference.
- Other useful builders herein include sodium and potassium carboxymethyloxymalonate, carboxymethy- loxysuccinate, cis-cyclohexanehexacarboxylate, cis-cyclo- pentanetetracarboxylate , phloroglucinol trisulfonate , water-soluble polyacrylates (having molecular weights of from about 2 , 000 to about 200 ,000 for example) , and the copolymers of maleic anhydride with vinyl methyl ether or ethylene.
- polycarboxylates for use herein include the polyacetal carboxylates described in U . S . Patent 4 ,144,226, issued March 13 , 1979 to Crutchfield et al and U . S. Patent 4, 146 , 495 , issued March 27 , 1979 to Crutchfield et al both incorporated herein by reference.
- Preferred water soluble detergent builders for use herein include ethylene diamine tetraacetic acid or the alkal i metal salts thereof, tetrapotassium pyrophos- phate and sodium carbonate. Of these ethylene diamine tetraacetic acid and its alkali metal salts are especially preferred .
- Water miscible organic solvents suitable for use in the compositions of the present invention include alkylene glycols and/or ethers thereof (e .g . , mono-lower alkyl , C. to C g , ethers thereof) such as , for example , ethylene glycol mono-n-butyl ether , ethylene glycol monomethyl ether , ethylene glycol monoethyl ether , ethylene glycol mono-n-hexyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, isopropylene glycol monoethyl or monopropyl or monobutyl ether , etc; polyalkylene glycols and/or ethers thereof (e.g .
- compositions of the present invention can also, if desired in a given instance, suitably include one or more of the various known types of supplemental or auxiliary ingredients or additives such as , for example, hydrotropes (e. g .
- water soluble salts of low molecular weight organic acids such as the sodium or potassium salts of toluene-, benzene-, xylene-, or cumene sulfonic acid , sodium or potassium sulfosuccinate, etc.
- perfumes dyes or colorants
- thickeners and /or soil suspensing agents e.g . , carboxymethyl cel lulose , sodium polyacrylate, polyethylene glycols having molecular weights of from about 400 to about 100 ,000
- deodorizers ammonia
- antioxidants antioxidants
- aerosol propellants and the l ike.
- Typical ⁇ ly such supplemental or auxiliary ingredients wil l be employed in relatively minor proportions.
- aqueous disinfectant and/or sanitizing cleaner compositions hereof there is typically no particular criticality associated with the order of ingredient addition or the technique employed in manufacturing or formulating same and such can there ⁇ fore be accomplished in any fashion that may be con ⁇ venient or expedient under the circumstances to provide the subject composition of interest in the form of a stable, homogeneous aqueous solution thereof.
- compositions of the present invention can suitably be in ⁇ itial ly formulated , transported , distributed and/or marketed in the form of a dilutable aqueous concentrate composition and , in such event, can be diluted to the ultimately desired , end-use active ingredient strength by the eventual end-user or by a distributor at the retail or wholesale level .
- the compositions hereof can also suitably be initial ly and directly manu ⁇ factured or formulated , transported , and marketed in their diluted , ready-to-use form as previously described in accordance with the present invention.
- Rw Reflectance of the washed tile or panel
- Rs Reflectance of the soiled tile or panel
- Ro Reflectance of the clean, unsoiled tile or panel
- compositions of the present invention can be conveniently determined in accordance with the Association of Official Analytical Chemists (AOAC) Use
- Example 1 and 2 each employ a glycoside surfactant and are within the scope of the present invention .
- Controls 1 and 2 employ a commercial ly available ethoxyiated nonlyphenol nonionic surfactant (9.5 mole ethylene oxide per mole of nonylphenol) in place of the glycoside surfactant and are presented and evaluated for comparative purposes.
- Nonionic Surfactant Ethoxyiated nonylphenol (9.5 moles ethylene oxide per mole of nonylphenol).
- EDTA Tetrasodium salt of ethylene diamine tetraacetic acid.
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- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
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Abstract
Compositions liquides détergentes désinfectantes et/ou hygiénisantes sous forme de solutions aqueuses homogènes comprenant de l'eau, un composé germicide à base d'halogénure d'ammonium quaternaire et un agent tensio-actif glycoside, dans lesquelles le rapport pondéral entre le composé à base d'halogénure d'ammonium quaternaire et l'agent tensio-actif glycoside est au moins égal à 0,65:1. De telles compositions peuvent également comprendre éventuellement des ingrédients supplémentaires tels que des formeurs de détergents solubles dans l'eau, des solvants organiques miscibles dans l'eau, des hydrotropes, des parfums, des colorants, des épaississants, des agents de suspension de saletés, des désodorisants, de l'ammoniaque, des agents propulseurs aérosol et analogues.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/709,965 USH269H (en) | 1985-03-11 | 1985-03-11 | Disinfectant and/or sanitizing cleaner compositions |
US709,965 | 1985-03-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1986005509A1 true WO1986005509A1 (fr) | 1986-09-25 |
Family
ID=24852054
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1986/000486 WO1986005509A1 (fr) | 1985-03-11 | 1986-03-10 | Compositions detergentes desinfectantes et/ou hygienisantes |
Country Status (4)
Country | Link |
---|---|
US (1) | USH269H (fr) |
EP (1) | EP0214285A1 (fr) |
CA (1) | CA1332687C (fr) |
WO (1) | WO1986005509A1 (fr) |
Cited By (17)
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EP0275987A3 (fr) * | 1987-01-20 | 1989-07-26 | The Dow Chemical Company | Composition et procédé de nettoyage de compresseurs de turbine à gaz |
FR2662174A1 (fr) * | 1990-05-15 | 1991-11-22 | Eparco Sa | Compositions de nettoyage et de desinfection a usage menager a proprietes hypoallergeniques et a capacites aracides. |
EP0538762A1 (fr) * | 1991-10-22 | 1993-04-28 | Kao Corporation | Composition cosmétique pour cheveux |
WO1994006899A1 (fr) * | 1992-09-11 | 1994-03-31 | Henkel Kommanditgesellschaft Auf Aktien | Melanges de detergents |
WO1994012602A1 (fr) * | 1992-11-26 | 1994-06-09 | Henkel Kommanditgesellschaft Auf Aktien | Preparations tensio-actives visqueuses aqueuses |
EP0639636A3 (fr) * | 1993-08-19 | 1996-03-20 | Kao Corp | Composition détergente germicide et dèsinfectante. |
WO1996010069A1 (fr) * | 1994-09-26 | 1996-04-04 | Henkel Kommanditgesellschaft Auf Aktien | Detergents desinfectants pour surfaces dures |
WO1996023050A1 (fr) * | 1995-01-24 | 1996-08-01 | Jeyes Group Plc | Compositions detersives |
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WO1998000599A1 (fr) * | 1996-06-28 | 1998-01-08 | Henkel-Ecolab Gmbh & Co. Ohg | Concentre d'amidon de lessive liquide |
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US5503754A (en) * | 1993-11-10 | 1996-04-02 | Henkel Corporation | Wet treatment of leather hides |
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JP2008533005A (ja) * | 2005-03-11 | 2008-08-21 | ヴァーダ コンサルティング リミテッド | 生物学的活性物質の皮内的、経皮的又は経粘膜的送達のための方法 |
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AU2017210203B2 (en) | 2016-01-20 | 2021-07-08 | Rockline Industries | Wet wipes containing hydroxy acetophenone and cocamidopropyl PG-dimonium chloride phosphate |
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US4259217A (en) * | 1978-03-07 | 1981-03-31 | The Procter & Gamble Company | Laundry detergent compositions having enhanced greasy and oily soil removal performance |
US4264479A (en) * | 1978-12-18 | 1981-04-28 | Flanagan John J | Surfactant system |
US4336152A (en) * | 1981-07-06 | 1982-06-22 | American Cyanamid Company | Disinfectant/cleanser compositions exhibiting reduced eye irritancy potential |
US4443363A (en) * | 1980-12-23 | 1984-04-17 | Hoechst Aktiengesellschaft | Detergent composition for cleaning hard surfaces and method of using the same |
US4443364A (en) * | 1980-12-23 | 1984-04-17 | Hoechst Aktiengesellschaft | Detergent composition containing an antifoaming agent for cleaning hard surfaces and method of using the same |
EP0106692A1 (fr) * | 1982-10-18 | 1984-04-25 | THE PROCTER & GAMBLE COMPANY | Détergent liquide contenant du polyéthylène glycol |
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1985
- 1985-03-11 US US06/709,965 patent/USH269H/en not_active Abandoned
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1986
- 1986-03-05 CA CA000503335A patent/CA1332687C/fr not_active Expired - Fee Related
- 1986-03-10 EP EP86902143A patent/EP0214285A1/fr not_active Withdrawn
- 1986-03-10 WO PCT/US1986/000486 patent/WO1986005509A1/fr unknown
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EP0275987A3 (fr) * | 1987-01-20 | 1989-07-26 | The Dow Chemical Company | Composition et procédé de nettoyage de compresseurs de turbine à gaz |
FR2662174A1 (fr) * | 1990-05-15 | 1991-11-22 | Eparco Sa | Compositions de nettoyage et de desinfection a usage menager a proprietes hypoallergeniques et a capacites aracides. |
US5714136A (en) * | 1991-10-22 | 1998-02-03 | Kao Corporation | Hair cosmetic containing a cationic surfactant, fat and oil and an alkyl saccharide surfactant |
EP0538762A1 (fr) * | 1991-10-22 | 1993-04-28 | Kao Corporation | Composition cosmétique pour cheveux |
WO1994006899A1 (fr) * | 1992-09-11 | 1994-03-31 | Henkel Kommanditgesellschaft Auf Aktien | Melanges de detergents |
EP0838518A3 (fr) * | 1992-09-11 | 1998-11-25 | Henkel Kommanditgesellschaft auf Aktien | Mélanges de détergents |
US5627144A (en) * | 1992-09-11 | 1997-05-06 | Henkel Kommanditgesellschaft Auf Aktien | Composition for enhanced crude oil recovery operations containing hydrochloric acid or hydrofluoric acid, or mixtures thereof with ester quaternary ammonium compounds or/and alkyl quaternary ammonium compounds |
WO1994012602A1 (fr) * | 1992-11-26 | 1994-06-09 | Henkel Kommanditgesellschaft Auf Aktien | Preparations tensio-actives visqueuses aqueuses |
EP0639636A3 (fr) * | 1993-08-19 | 1996-03-20 | Kao Corp | Composition détergente germicide et dèsinfectante. |
CN1074897C (zh) * | 1993-08-19 | 2001-11-21 | 花王株式会社 | 杀菌-消毒的去污组合物 |
US5739168A (en) * | 1993-08-19 | 1998-04-14 | Kao Corporation | Germicidal-disinfectant detergent composition |
WO1996010069A1 (fr) * | 1994-09-26 | 1996-04-04 | Henkel Kommanditgesellschaft Auf Aktien | Detergents desinfectants pour surfaces dures |
EP1018542A1 (fr) * | 1994-09-26 | 2000-07-12 | Henkel KGaA | Détergents désinfectants pour surfaces dures |
US5576284A (en) * | 1994-09-26 | 1996-11-19 | Henkel Kommanditgesellschaft Auf Aktien | Disinfecting cleanser for hard surfaces |
US5856290A (en) * | 1994-09-26 | 1999-01-05 | Henkel Kommanditgesellschaft Auf Aktien | Disinfecting cleanser for hard surfaces based on mixtures of APG and C8 -C18 alkyl ether |
WO1996023050A1 (fr) * | 1995-01-24 | 1996-08-01 | Jeyes Group Plc | Compositions detersives |
DE19508654B4 (de) * | 1995-03-13 | 2006-08-10 | Stepan Co., Northfield | Tuberkulozides Desinfekionsmittel und dessen Verwendung |
FR2731585A1 (fr) * | 1995-03-13 | 1996-09-20 | Stepan Co | Procedes et compositions pour la desinfection des surfaces comportant des bacteries responsables de la tuberculose |
US6555515B1 (en) | 1995-12-06 | 2003-04-29 | Henkel Kommanitgesellschaft Auf Aktien | Formulations for cleaning hard surfaces based on at least partly branched-chain alkyl oligoglucosides |
WO1998000599A1 (fr) * | 1996-06-28 | 1998-01-08 | Henkel-Ecolab Gmbh & Co. Ohg | Concentre d'amidon de lessive liquide |
AU727813B2 (en) * | 1996-06-28 | 2000-12-21 | Henkel-Ecolab Gmbh & Co. Ohg | A liquid laundry starch concentrate |
US6444023B1 (en) | 1996-06-28 | 2002-09-03 | Henkel Ecolab Gmbh & Co, Ohg | Liquid laundry starch concentrate |
EP0959122A1 (fr) * | 1998-05-18 | 1999-11-24 | Bayer Corporation | Solution de nettoyage pour les surfaces optiques des appareils d'analyse d'urine |
WO2004009754A1 (fr) * | 2002-07-24 | 2004-01-29 | Reckitt Benckiser Inc | Nettoyants pour surfaces dures |
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US8859481B2 (en) | 2005-12-15 | 2014-10-14 | Kimberly-Clark Worldwide, Inc. | Wiper for use with disinfectants |
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CN109997849A (zh) * | 2019-04-28 | 2019-07-12 | 河北瑞鸿生物科技有限公司 | 一种消毒液及其制备方法 |
US20220268538A1 (en) * | 2021-02-24 | 2022-08-25 | Valvoline Licensing And Intellectual Property Llc | Foaming evaporator coil cleaner |
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Also Published As
Publication number | Publication date |
---|---|
USH269H (en) | 1987-05-05 |
EP0214285A1 (fr) | 1987-03-18 |
CA1332687C (fr) | 1994-10-25 |
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