WO1992000361A1 - Materiau d'affichage - Google Patents
Materiau d'affichage Download PDFInfo
- Publication number
- WO1992000361A1 WO1992000361A1 PCT/JP1991/000853 JP9100853W WO9200361A1 WO 1992000361 A1 WO1992000361 A1 WO 1992000361A1 JP 9100853 W JP9100853 W JP 9100853W WO 9200361 A1 WO9200361 A1 WO 9200361A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- film
- adhesive
- plastic film
- sheet
- display
- Prior art date
Links
- 239000000463 material Substances 0.000 title abstract description 5
- 239000002985 plastic film Substances 0.000 claims abstract description 33
- 229920006255 plastic film Polymers 0.000 claims abstract description 33
- 239000010410 layer Substances 0.000 claims abstract description 22
- 239000012790 adhesive layer Substances 0.000 claims abstract description 17
- 239000004840 adhesive resin Substances 0.000 claims abstract description 15
- 229920006223 adhesive resin Polymers 0.000 claims abstract description 15
- 239000004014 plasticizer Substances 0.000 claims abstract description 11
- 239000000853 adhesive Substances 0.000 claims description 29
- 239000012769 display material Substances 0.000 claims description 28
- 230000001070 adhesive effect Effects 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 2
- 210000004709 eyebrow Anatomy 0.000 claims description 2
- 239000006260 foam Substances 0.000 abstract description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 10
- 229920000915 polyvinyl chloride Polymers 0.000 description 10
- 239000007787 solid Substances 0.000 description 8
- 230000001681 protective effect Effects 0.000 description 5
- -1 polypropylene Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229920006266 Vinyl film Polymers 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F7/00—Signs, name or number plates, letters, numerals, or symbols; Panels or boards
- G09F7/02—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols
- G09F7/12—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols the elements being secured or adapted to be secured by self-adhesion, moisture, suction, slow-drying adhesive or the like
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F7/00—Signs, name or number plates, letters, numerals, or symbols; Panels or boards
- G09F7/02—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols
- G09F7/12—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols the elements being secured or adapted to be secured by self-adhesion, moisture, suction, slow-drying adhesive or the like
- G09F2007/125—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols the elements being secured or adapted to be secured by self-adhesion, moisture, suction, slow-drying adhesive or the like by electrostatic force
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F7/00—Signs, name or number plates, letters, numerals, or symbols; Panels or boards
- G09F7/02—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols
- G09F7/12—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols the elements being secured or adapted to be secured by self-adhesion, moisture, suction, slow-drying adhesive or the like
- G09F2007/127—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols the elements being secured or adapted to be secured by self-adhesion, moisture, suction, slow-drying adhesive or the like by adhesive
Definitions
- the present invention relates to a display material composed of a display sheet and a backing film.
- a display material is known in which a display sheet is adhered to the surface of a backing film made of a polyvinyl chloride film via an adhesive layer, and a protective backing is adhered to the back surface of the backing film. 5 2 1 1 1 3 8 6 6 Publication).
- the polyvinyl chloride film since the polyvinyl chloride film has an excellent triboelectric property, the polyvinyl chloride film to which the display sheet is adhered is removed from the protective backing, and the polyvinyl chloride film is applied to the polyvinyl chloride film. By causing triboelectric charging, it can be electrostatically adsorbed on a solid surface such as paper or glass.
- the inventor of the present invention has conducted intensive studies on the reason why the electrostatic attraction force of the backing film to which the display sheet is adhered is reduced with the passage of time, and as a result, the plasticizer contained in the adhesive layer and Z or the softening agent are reduced. Agent With the passage of time, the film was transferred to the backing film, and it was found that this caused the electrostatic attraction of the backing film to decrease, and the present invention was completed.
- a display material comprising a display sheet having an electrostatically adsorbable plastic film and an adhesive layer containing no plasticizer and softener on the back surface.
- a display material comprising an electrostatically adsorbable plastic film and a display object sheet having a self-adhesive resin layer on the back surface.
- a display material comprising a display object sheet having an electrostatic attraction plastic film and a self-adhesive foamed resin layer on the back surface.
- the backing film used in the present invention is made of an electrostatically adsorbing plastic film, and includes a triboelectric plastic film and an electretized plastic film.
- a conventionally known plastic film having a high insulating property is used. Specific examples thereof include a polyvinyl chloride film, a vinylidene chloride resin film, a polystyrene film, Examples include fluorine-containing ethylene, propylene copolymer film, and polypropylene film.
- Electretized plastic film can be obtained by applying a high voltage to a plastic film by corona discharge using a conventional method, and can retain electric charge semipermanently. It is a plastic film that can be used for both.
- Retretted plastic film is a plastic film that has much better charge retention and stability, and is less likely to attenuate the electrostatic attraction force.
- triboelectrically-chargeable plastic film and plastic film for electretization those having high insulating properties which do not contain a plasticizer and an antistatic agent are preferably used.
- the surface resistance of these plastic films is usually at least 10 13 ohms, especially at least 10 15 ohms.
- the display sheet used in the present invention has an adhesive layer, a self-adhesive resin layer, or a self-adhesive foamed resin layer, which can be peelably or non-peelably adhered to the backing film, on the back surface thereof.
- the display sheet can be paper, plastic film, foam sheet, cloth, or the like. If necessary, other films can be laminated and adhered to the surface of the display sheet.For example, when the display sheet is paper, a plastic film or plastic film can be used. In such cases, paper can be attached to the eyebrows.
- the adhesive layer formed on the back surface of the display sheet used in the present invention is an adhesive layer that does not contain a plasticizer and a softener in order to prevent a decrease in the electrostatic attraction force of the backing film. is necessary. In the research of the present inventors, it was generally used as an adhesive.
- a display material sheet formed by applying a plasticizer such as a rubber-based adhesive or a rubber-based solvent-type adhesive to the back surface, and bonding to a backing film via the adhesive layer When left in this state, it was found that after about 10 days had passed, the chargeability of the backing film with electrostatic attraction decreased, and the electrostatic attraction decreased significantly.
- the non-plasticizer-based or non-softening agent-based adhesive used in the present invention includes a pressure-sensitive adhesive in addition to a normal adhesive. It may have or may not have.
- an adhesive include an acrylic adhesive, an aqueous adhesive, a liquid curable adhesive, and a polyurethane adhesive.
- the polyurethane-based adhesive for example, a mixture of 100 parts by weight of a polyol (for example, polyether polyol) and 40 parts by weight of a polyisocyanate (for example, tolylene isocyanate) is mixed. Later, it can be obtained by heating at 100 ° C. for about 15 minutes. Also, the display sheet having the self-adhesive resin layer / self-adhesive foamed resin layer does not suffer from the above-mentioned inconvenience.
- Self-adhesive resin is a removable adhesive that uses the adhesive or tackiness of the resin itself, and does not contain plasticizers or softeners. Therefore, it can be preferably used in the present invention.
- an ethylene-vinyl acetate copolymer-based adhesive sold under the trade name “NK-ONETAK:” by Nippon Kaishi Paper Co., Ltd. is preferably used. be able to.
- the self-adhesive foamed resin is a sheet-shaped foamed resin having a large number of micropores on its surface, and has adhesiveness or adhesion to a smooth surface due to the micropores. This also can be preferably used in the present invention because it does not deteriorate the backing film and does not exhibit the effect of lowering the electrostatic attraction force.
- a resin containing a mixture of a urethane resin and an acrylic resin or a butadiene-based synthetic rubber as a base resin is disclosed in Japanese Patent Application Laid-Open No. 1-259430. It is described in the official gazette, and is sold by Dainichi Ink Chemical Industry Co., Ltd. under the trade name "Papiral B-001 LA".
- the display material of the present invention comprising the display sheet and the electrostatically adhering backing film is allowed to stand naturally for three months in a state where the display sheet and the backing film are adhered, and the backing film is also used. Examination of the change over time of the electrostatic attraction force of the device revealed that the electrostatic attraction force did not significantly decrease.
- the display material of the present invention provides a sheet of display material, a backing film having an adhesive layer, a self-adhesive resin layer or a self-adhesive foamed resin layer on the back surface, and a backing film which provides a backing film.
- mount film A backing film which provides a protective film made of paper or plastic film, is adhered to the back side of the backing film using the electrostatic attraction force of the backing sheet, which provides the backing film. In this state, punching can be performed together with the raw film that provides the protective film. In this way, a display material is obtained in which the display material sheet is laminated on the backing film and the protective film is laminated on the backing film.
- FIG. 1 shows a cross-sectional view of the display material of the present invention.
- 1 is a backing film
- 2 is a display sheet
- an adhesive layer, a self-adhesive resin layer or a self-adhesive foam resin layer is provided between the backing film 1 and the display sheet 2.
- the display material sheet 2 can be preliminarily printed with characters, pictures, designs, etc. on its surface, and can be left blank without printing on the front side, and appropriate characters, pictures, designs, etc. can be made by the user side. May be described.
- the display material of the present invention can be electrostatically adsorbed on a solid surface such as glass, plastic, or paper through the mount film 1 because the mount film 1 has an electrostatic attraction property.
- the display sheet 2 is peeled from the backing film 1 as necessary, and the adhesive layer, the self-adhesive resin layer or the self-adhesive resin formed on the back surface of the display sheet 2 is used. It can be adhered to various solid surfaces via layer 3 and, if necessary, its solid surface
- the display material using the display sheet having the adhesive layer of the present invention can be peeled off from the surface and adhered again to the backing film 1.
- the surface can be coated with a release agent such as silicone to facilitate the release of the display sheet from the backing film.
- the release agent described above is used. It is possible to easily peel off the display sheet from the backing film without applying it on the backing film.
- the display material of the present invention can be adhered (electrostatically adsorbed) to various smooth solid surfaces such as paper, plastic, and glass by utilizing the electrostatic adsorbing property of the backing film.
- the display material can be freely moved and peeled on the solid surface, and Does not cause any contamination or damage to the surface.
- the display object sheet is formed on the back surface thereof by using an adhesive layer, a self-adhesive resin layer, or a self-adhesive foamed resin layer. It can be firmly adhered to solid surfaces.
- the display sheet is left for a long time in a state where the display sheet is adhered to the backing film via the adhesive layer, the self-adhesive resin layer or the self-adhesive foamed resin layer.
- the electrostatic attraction force of the backing film does not suddenly decrease.
- the display material according to the present invention is provided with the necessary characters and It prints paintings, figures, and symbols, and is used for advertising media and learning materials.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Theoretical Computer Science (AREA)
- Laminated Bodies (AREA)
Abstract
Matériau support d'affichage composé d'un film plastique d'attraction électrostatique et d'une feuille d'affichage ayant une couche adhésive exempte de plastifiant et d'assouplissant, d'une couche de résine autocollante ou d'une couche de mousse de résine autocollante, sur sa face arrière. Le matériau ne subit pas une très forte diminution de la force d'attraction électrostatique du film plastique même lorsque la feuille et le film sont liés par laminage puis laissés ainsi pendant longtemps. Ledit matériau peut être utilisé comme support publicitaire éducatif sur lequel on applique des lettres ou des dessins utiles, sur la surface de la feuille d'affichage.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3510772A JP2987934B2 (ja) | 1990-06-25 | 1991-06-25 | 表示用材料 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2/66997U | 1990-06-25 | ||
JP6699790 | 1990-06-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992000361A1 true WO1992000361A1 (fr) | 1992-01-09 |
Family
ID=13332158
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1991/000853 WO1992000361A1 (fr) | 1990-06-25 | 1991-06-25 | Materiau d'affichage |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO1992000361A1 (fr) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002055624A1 (fr) * | 2001-01-09 | 2002-07-18 | 3M Innovative Properties Company | Feuilles electrostatiques adhesives |
US7008680B2 (en) | 2003-07-03 | 2006-03-07 | 3M Innovative Properties Company | Heat-activatable adhesive |
WO2009154177A1 (fr) * | 2008-06-16 | 2009-12-23 | 株式会社ユポ・コーポレーション | Feuille à attraction électrostatique |
JP2010023502A (ja) * | 2008-06-16 | 2010-02-04 | Yupo Corp | 積層フィルム |
JP2010266474A (ja) * | 2009-05-12 | 2010-11-25 | Yupo Corp | 静電吸着シート |
WO2013191289A1 (fr) * | 2012-06-22 | 2013-12-27 | 株式会社ユポ・コーポレーション | Feuille électrostatiquement adsorbante et dispositif d'affichage l'utilisant |
JP2014024327A (ja) * | 2012-06-22 | 2014-02-06 | Yupo Corp | 掲示シート、その製造方法、並びに該掲示シートを用いた表示物 |
JP2014024326A (ja) * | 2012-06-22 | 2014-02-06 | Yupo Corp | 静電吸着シート、その製造方法、並びに該静電吸着シートを用いた表示物 |
WO2015034019A1 (fr) * | 2013-09-04 | 2015-03-12 | 株式会社ユポ・コーポレーション | Feuilles fixables électrostatiquement et objet d'affichage les incluant |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5721648U (fr) * | 1980-07-10 | 1982-02-04 | ||
JPS5721472A (en) * | 1980-07-16 | 1982-02-04 | Mitsui Petrochem Ind Ltd | Simple sticking material |
JPS57172045U (fr) * | 1981-04-24 | 1982-10-29 | ||
JPS5988434U (ja) * | 1982-05-24 | 1984-06-15 | 長谷井 妙子 | 高帯電性の高分子フイルム並びに同シ−トよりなる接着片 |
JPS62264950A (ja) * | 1986-05-13 | 1987-11-17 | 米良 總一 | 印刷面を有する静電気吸着シ−ト、フイルム類 |
-
1991
- 1991-06-25 WO PCT/JP1991/000853 patent/WO1992000361A1/fr unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5721648U (fr) * | 1980-07-10 | 1982-02-04 | ||
JPS5721472A (en) * | 1980-07-16 | 1982-02-04 | Mitsui Petrochem Ind Ltd | Simple sticking material |
JPS57172045U (fr) * | 1981-04-24 | 1982-10-29 | ||
JPS5988434U (ja) * | 1982-05-24 | 1984-06-15 | 長谷井 妙子 | 高帯電性の高分子フイルム並びに同シ−トよりなる接着片 |
JPS62264950A (ja) * | 1986-05-13 | 1987-11-17 | 米良 總一 | 印刷面を有する静電気吸着シ−ト、フイルム類 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002055624A1 (fr) * | 2001-01-09 | 2002-07-18 | 3M Innovative Properties Company | Feuilles electrostatiques adhesives |
US6660352B2 (en) | 2001-01-09 | 2003-12-09 | 3M Innovative Properties Company | Adhesive electrostatic sheets |
US7008680B2 (en) | 2003-07-03 | 2006-03-07 | 3M Innovative Properties Company | Heat-activatable adhesive |
WO2009154177A1 (fr) * | 2008-06-16 | 2009-12-23 | 株式会社ユポ・コーポレーション | Feuille à attraction électrostatique |
JP2010023502A (ja) * | 2008-06-16 | 2010-02-04 | Yupo Corp | 積層フィルム |
US9044916B2 (en) | 2008-06-16 | 2015-06-02 | Yupo Corporation | Electrostatic adsorbable sheet |
JP2010266474A (ja) * | 2009-05-12 | 2010-11-25 | Yupo Corp | 静電吸着シート |
WO2013191289A1 (fr) * | 2012-06-22 | 2013-12-27 | 株式会社ユポ・コーポレーション | Feuille électrostatiquement adsorbante et dispositif d'affichage l'utilisant |
JP2014024327A (ja) * | 2012-06-22 | 2014-02-06 | Yupo Corp | 掲示シート、その製造方法、並びに該掲示シートを用いた表示物 |
JP2014024326A (ja) * | 2012-06-22 | 2014-02-06 | Yupo Corp | 静電吸着シート、その製造方法、並びに該静電吸着シートを用いた表示物 |
WO2015034019A1 (fr) * | 2013-09-04 | 2015-03-12 | 株式会社ユポ・コーポレーション | Feuilles fixables électrostatiquement et objet d'affichage les incluant |
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