WO1994007984A1 - Composition de detergent contenant un dispersant de savon de chaux et des lipases - Google Patents
Composition de detergent contenant un dispersant de savon de chaux et des lipases Download PDFInfo
- Publication number
- WO1994007984A1 WO1994007984A1 PCT/US1993/008875 US9308875W WO9407984A1 WO 1994007984 A1 WO1994007984 A1 WO 1994007984A1 US 9308875 W US9308875 W US 9308875W WO 9407984 A1 WO9407984 A1 WO 9407984A1
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- WO
- WIPO (PCT)
- Prior art keywords
- weight
- alkyl
- detergent composition
- composition according
- detergent
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 176
- 235000008733 Citrus aurantifolia Nutrition 0.000 title claims abstract description 40
- 235000011941 Tilia x europaea Nutrition 0.000 title claims abstract description 40
- 239000004571 lime Substances 0.000 title claims abstract description 40
- 239000000344 soap Substances 0.000 title claims abstract description 40
- 239000002270 dispersing agent Substances 0.000 title claims abstract description 32
- 108090001060 Lipase Proteins 0.000 title claims abstract description 21
- 102000004882 Lipase Human genes 0.000 title claims abstract description 21
- 239000003599 detergent Substances 0.000 title claims description 80
- 238000004851 dishwashing Methods 0.000 claims abstract description 45
- 102000004190 Enzymes Human genes 0.000 claims abstract description 33
- 108090000790 Enzymes Proteins 0.000 claims abstract description 33
- 239000004367 Lipase Substances 0.000 claims abstract description 18
- 235000019421 lipase Nutrition 0.000 claims abstract description 18
- 230000002366 lipolytic effect Effects 0.000 claims abstract description 14
- 241000589630 Pseudomonas pseudoalcaligenes Species 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims description 93
- 239000004094 surface-active agent Substances 0.000 claims description 59
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- 239000002518 antifoaming agent Substances 0.000 claims description 44
- 229940088598 enzyme Drugs 0.000 claims description 32
- 229920001296 polysiloxane Polymers 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 23
- 239000007844 bleaching agent Substances 0.000 claims description 21
- 239000000460 chlorine Substances 0.000 claims description 17
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 16
- 229910052801 chlorine Inorganic materials 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 16
- 229910019142 PO4 Inorganic materials 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 11
- 150000004965 peroxy acids Chemical class 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 10
- 239000010452 phosphate Substances 0.000 claims description 10
- 239000002243 precursor Substances 0.000 claims description 10
- 239000003752 hydrotrope Substances 0.000 claims description 7
- 108010065511 Amylases Proteins 0.000 claims description 6
- 102000013142 Amylases Human genes 0.000 claims description 6
- 235000019418 amylase Nutrition 0.000 claims description 5
- 229940025131 amylases Drugs 0.000 claims description 5
- 150000004967 organic peroxy acids Chemical class 0.000 claims description 4
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 3
- 108091005658 Basic proteases Proteins 0.000 claims description 2
- 108091005507 Neutral proteases Proteins 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
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- 125000000217 alkyl group Chemical group 0.000 description 72
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- 125000004432 carbon atom Chemical group C* 0.000 description 38
- 239000002253 acid Substances 0.000 description 33
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 16
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- 229910052700 potassium Inorganic materials 0.000 description 14
- 239000011591 potassium Substances 0.000 description 14
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- 150000002430 hydrocarbons Chemical class 0.000 description 8
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- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 7
- 125000002947 alkylene group Chemical group 0.000 description 7
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- 230000000694 effects Effects 0.000 description 7
- 229910001385 heavy metal Inorganic materials 0.000 description 7
- 239000001257 hydrogen Chemical group 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 6
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- 230000015572 biosynthetic process Effects 0.000 description 6
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
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- 150000004760 silicates Chemical class 0.000 description 6
- VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 description 5
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- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 5
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- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 4
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 125000004665 trialkylsilyl group Chemical group 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 210000001364 upper extremity Anatomy 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
Definitions
- machine dishwashing or rinsing detergent products are free from chlorine bleaches or phosphate builder compounds.
- spotting and filming effects are known to be a particular problem for machine dishwashing and rinsing products containing no chlorine bleach and/or no phosphate builder compound.
- the machine dishwashing or rinsing detergent compositions of the present invention are of particular value when formulated as compositions containing no chlorine bleach and no phosphate builder compound since they provide the abovementioned mitigation of spotting and filming effects for these formulations where spotting and filming is known to be a particular problem.
- the aluminosilicate ion exchange materials can be naturally occurring materials, but are preferably synthetically derived. A method for producing aluminosilicate ion exchange materials is discussed in US Patent No. 3,985,669. Synthetic crystalline aluminosilicate ion exchange materials are available under the designations Zeolite A, Zeolite B, Zeolite P, Zeolite X, Zeolite HS and mixtures thereof. Zeolite A has the formula
- a lipase unit is defined as the amound of lipase which produces l umol of titratable butyric acid per minute in a pH stat, where pH is 7.0, temperature is 30°C, and substrate is an emulsion of ributyrin and gum arabic in the presence of Ca ++ and NaCl in phosphate buffer.
- Anionic sulfonate surfactants suitable for use herein include essentially any sulfonate surfactants including, for example, the salts (eg : alkali metal salts) of C5-C2 0 linear alkylbenzene sulfonates, C -C22 primary or secondary alkane sulfonates, C 6 -C 24 olefin sulfonates, sulfonated polycarboxylic acids, alkyl glycerol sulfonates, fatty acyl glycerol sulfonates, fatty oleyl glycerol sulfonates, paraffin sulfonates, and any mixtures thereof.
- the salts eg : alkali metal salts
- C5-C2 0 linear alkylbenzene sulfonates C -C22 primary or secondary alkane sulfonates
- Anionic alkyl ethoxy carboxylate surfactant Anionic alkyl ethoxy carboxylate surfactant
- the mixed ethoxylated/propoxylated fatty alcohols have an alkyl chain length of from 10 to 18 carbon atoms, a degree of ethoxylation of from 3 to 30 and a degree of propoxylation of from 1 to 10.
- a pholytic surfactants can be incorporated into the detergent compositions herein. These surfactants can be broadly described as aliphatic derivatives of secondary or tertiary amines, or aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical can be straight chain or branched.
- One of the aliphatic substituents contains at least about 8 carbon atoms, typically from about 8 to about 18 carbon atoms, and at least one contains an anionic water-solubilizing group, e.g., carboxy, sulfonate, sulfate. See U.S. Patent No. 3,929,678 to Laughlin et al., issued December 30, 1975 at column 19, lines 18-35 for examples of ampholytic surfactants.
- the complex betaines for use herein have the formula R - (A) n - [N - (CHR ⁇ ) x ] y - N - Q (I)
- x can be O or an integer between 1 & 6.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Enzymes And Modification Thereof (AREA)
Abstract
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE69330230T DE69330230T2 (de) | 1992-09-25 | 1993-09-20 | Verwendung einer kalkseifendispergator und lipasehaltige waschmittelzusammensetzung |
| EP93922706A EP0662118B1 (fr) | 1992-09-25 | 1993-09-20 | Utilisation d'une composition de detergent contenant un dispersant de savon de chaux et des lipases |
| AT93922706T ATE201228T1 (de) | 1992-09-25 | 1993-09-20 | Verwendung einer kalkseifendispergator und lipasehaltige waschmittelzusammensetzung |
| CA002145176A CA2145176C (fr) | 1992-09-25 | 1993-09-20 | Composition detergente renfermant un dispersant a base de savon de chaux et de la lipase |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9220343.9 | 1992-09-25 | ||
| GB929220343A GB9220343D0 (en) | 1992-09-25 | 1992-09-25 | Detergent compositions |
| EP93870170.3 | 1993-08-13 | ||
| EP93870170 | 1993-08-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1994007984A1 true WO1994007984A1 (fr) | 1994-04-14 |
Family
ID=26134995
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1993/008875 WO1994007984A1 (fr) | 1992-09-25 | 1993-09-20 | Composition de detergent contenant un dispersant de savon de chaux et des lipases |
Country Status (5)
| Country | Link |
|---|---|
| AT (1) | ATE201228T1 (fr) |
| CA (1) | CA2145176C (fr) |
| DE (1) | DE69330230T2 (fr) |
| ES (1) | ES2156586T3 (fr) |
| WO (1) | WO1994007984A1 (fr) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995004806A1 (fr) * | 1993-08-10 | 1995-02-16 | The Procter & Gamble Company | Composition pour la vaisselle a la main comprenant des lipases et un dispersant des savons de chaux |
| WO1997043379A1 (fr) * | 1996-05-15 | 1997-11-20 | The Procter & Gamble Company | Compositions detergentes comprenant une enzyme lipolytique specifique et un dispersant a base de savon de chaux |
| US5772786A (en) * | 1993-08-13 | 1998-06-30 | The Procter & Gamble Company | Detergent composition comprising lime soap dispersant and lipase enzymes |
| EP0835925A3 (fr) * | 1996-09-09 | 1999-01-27 | Unilever N.V. | Compositions pour lave-vaisselle contenant des polymères amphotères |
| US5963658A (en) * | 1997-01-27 | 1999-10-05 | University Of North Carolina | Method and apparatus for detecting an abnormality within a host medium |
| EP1090978A1 (fr) * | 1999-10-09 | 2001-04-11 | Cognis Deutschland GmbH, Dep. Intellectual Properties | Agent de lavage, de rinçage et nettoyage solide contenant des granulats antimousse |
| WO2007087258A3 (fr) * | 2006-01-23 | 2008-12-04 | Procter & Gamble | Composition comprenant une lipase et un catalyseur de blanchiment |
| RU2395565C2 (ru) * | 2006-01-23 | 2010-07-27 | Дзе Проктер Энд Гэмбл Компани | Композиция, содержащая липазу и катализатор отбеливания |
| US7786067B2 (en) | 2006-01-23 | 2010-08-31 | The Procter & Gamble Company | Composition comprising a lipase and a bleach catalyst |
| US9138393B2 (en) | 2013-02-08 | 2015-09-22 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for improving the appearance of aging skin |
| US9144538B2 (en) | 2013-02-08 | 2015-09-29 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for alleviating the signs of photoaged skin |
| WO2017220422A1 (fr) * | 2016-06-23 | 2017-12-28 | Novozymes A/S | Utilisation d'enzymes, composition et procédé d'élimination de salissures |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987000859A1 (fr) * | 1985-08-09 | 1987-02-12 | Gist-Brocades N.V. | Nouveaux enzymes lipolytiques et leur utilisation dans des compositions de detergents |
| EP0271153A2 (fr) * | 1986-12-10 | 1988-06-15 | Unilever N.V. | Composition détergente à base d'enzymes |
| US4797223A (en) * | 1988-01-11 | 1989-01-10 | Rohm And Haas Company | Water soluble polymers for detergent compositions |
| EP0373850A1 (fr) * | 1988-12-12 | 1990-06-20 | Unilever Plc | Compositions détergentes contenant des enzymes et leur utilisation |
| US4959179A (en) * | 1989-01-30 | 1990-09-25 | Lever Brothers Company | Stabilized enzymes liquid detergent composition containing lipase and protease |
| US5069809A (en) * | 1988-05-09 | 1991-12-03 | Lever Brothers Company, Division Of Conopco, Inc. | Enzymatic detergent and bleaching composition containing a specific rdna technique cloned lipase |
| US5078898A (en) * | 1987-11-02 | 1992-01-07 | Novo Nordisk A/S | Detergent compositions comprising pseudomonas lipase and a specific protease |
-
1993
- 1993-09-20 CA CA002145176A patent/CA2145176C/fr not_active Expired - Fee Related
- 1993-09-20 DE DE69330230T patent/DE69330230T2/de not_active Expired - Fee Related
- 1993-09-20 ES ES93922706T patent/ES2156586T3/es not_active Expired - Lifetime
- 1993-09-20 AT AT93922706T patent/ATE201228T1/de not_active IP Right Cessation
- 1993-09-20 WO PCT/US1993/008875 patent/WO1994007984A1/fr active IP Right Grant
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987000859A1 (fr) * | 1985-08-09 | 1987-02-12 | Gist-Brocades N.V. | Nouveaux enzymes lipolytiques et leur utilisation dans des compositions de detergents |
| EP0271153A2 (fr) * | 1986-12-10 | 1988-06-15 | Unilever N.V. | Composition détergente à base d'enzymes |
| US5078898A (en) * | 1987-11-02 | 1992-01-07 | Novo Nordisk A/S | Detergent compositions comprising pseudomonas lipase and a specific protease |
| US4797223A (en) * | 1988-01-11 | 1989-01-10 | Rohm And Haas Company | Water soluble polymers for detergent compositions |
| US5069809A (en) * | 1988-05-09 | 1991-12-03 | Lever Brothers Company, Division Of Conopco, Inc. | Enzymatic detergent and bleaching composition containing a specific rdna technique cloned lipase |
| EP0373850A1 (fr) * | 1988-12-12 | 1990-06-20 | Unilever Plc | Compositions détergentes contenant des enzymes et leur utilisation |
| US4959179A (en) * | 1989-01-30 | 1990-09-25 | Lever Brothers Company | Stabilized enzymes liquid detergent composition containing lipase and protease |
Non-Patent Citations (2)
| Title |
|---|
| LINFIELD, Tenside Sust. Det., Volume 27, pages 159-161 (1990). * |
| NAGARAJAN and MASLER, Polymeric Lime Soap Dispersants, Cosmetic and Toiletries, Volume 104, pages 71-73 (1989). * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995004806A1 (fr) * | 1993-08-10 | 1995-02-16 | The Procter & Gamble Company | Composition pour la vaisselle a la main comprenant des lipases et un dispersant des savons de chaux |
| US5772786A (en) * | 1993-08-13 | 1998-06-30 | The Procter & Gamble Company | Detergent composition comprising lime soap dispersant and lipase enzymes |
| WO1997043379A1 (fr) * | 1996-05-15 | 1997-11-20 | The Procter & Gamble Company | Compositions detergentes comprenant une enzyme lipolytique specifique et un dispersant a base de savon de chaux |
| EP0835925A3 (fr) * | 1996-09-09 | 1999-01-27 | Unilever N.V. | Compositions pour lave-vaisselle contenant des polymères amphotères |
| US5963658A (en) * | 1997-01-27 | 1999-10-05 | University Of North Carolina | Method and apparatus for detecting an abnormality within a host medium |
| EP1090978A1 (fr) * | 1999-10-09 | 2001-04-11 | Cognis Deutschland GmbH, Dep. Intellectual Properties | Agent de lavage, de rinçage et nettoyage solide contenant des granulats antimousse |
| WO2007087258A3 (fr) * | 2006-01-23 | 2008-12-04 | Procter & Gamble | Composition comprenant une lipase et un catalyseur de blanchiment |
| RU2395565C2 (ru) * | 2006-01-23 | 2010-07-27 | Дзе Проктер Энд Гэмбл Компани | Композиция, содержащая липазу и катализатор отбеливания |
| US7786067B2 (en) | 2006-01-23 | 2010-08-31 | The Procter & Gamble Company | Composition comprising a lipase and a bleach catalyst |
| US8022027B2 (en) | 2006-01-23 | 2011-09-20 | The Procter & Gamble Company | Composition comprising a lipase and a bleach catalyst |
| US9138393B2 (en) | 2013-02-08 | 2015-09-22 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for improving the appearance of aging skin |
| US9144538B2 (en) | 2013-02-08 | 2015-09-29 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for alleviating the signs of photoaged skin |
| WO2017220422A1 (fr) * | 2016-06-23 | 2017-12-28 | Novozymes A/S | Utilisation d'enzymes, composition et procédé d'élimination de salissures |
| US11001787B2 (en) | 2016-06-23 | 2021-05-11 | Novozymes A/S | Use of enzymes, composition and method for removing soil |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2145176A1 (fr) | 1994-04-14 |
| DE69330230D1 (de) | 2001-06-21 |
| DE69330230T2 (de) | 2002-02-28 |
| ATE201228T1 (de) | 2001-06-15 |
| CA2145176C (fr) | 1999-07-13 |
| ES2156586T3 (es) | 2001-07-01 |
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