WO1995011205A1 - Preparations providing a nutrient source for plants and a process for making such preparations - Google Patents
Preparations providing a nutrient source for plants and a process for making such preparations Download PDFInfo
- Publication number
- WO1995011205A1 WO1995011205A1 PCT/HU1994/000045 HU9400045W WO9511205A1 WO 1995011205 A1 WO1995011205 A1 WO 1995011205A1 HU 9400045 W HU9400045 W HU 9400045W WO 9511205 A1 WO9511205 A1 WO 9511205A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- preparation
- source
- plants
- calcium
- soluble
- Prior art date
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 103
- 235000015097 nutrients Nutrition 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims abstract description 8
- 230000008569 process Effects 0.000 title claims description 7
- 239000011435 rock Substances 0.000 claims abstract description 26
- 238000010521 absorption reaction Methods 0.000 claims abstract description 21
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 15
- 239000004480 active ingredient Substances 0.000 claims abstract description 13
- 230000003115 biocidal effect Effects 0.000 claims abstract description 12
- 239000003139 biocide Substances 0.000 claims abstract description 12
- 239000000575 pesticide Substances 0.000 claims abstract description 10
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- 239000005871 repellent Substances 0.000 claims abstract description 9
- 230000002940 repellent Effects 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 8
- 241000196324 Embryophyta Species 0.000 claims description 64
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 32
- 229910052749 magnesium Inorganic materials 0.000 claims description 25
- 239000011777 magnesium Substances 0.000 claims description 25
- 239000011575 calcium Substances 0.000 claims description 23
- 229910052791 calcium Inorganic materials 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 22
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 20
- 229910052742 iron Inorganic materials 0.000 claims description 20
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 18
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 17
- 229960005069 calcium Drugs 0.000 claims description 17
- 229910052802 copper Inorganic materials 0.000 claims description 17
- 239000010949 copper Substances 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 16
- 239000011572 manganese Substances 0.000 claims description 16
- 229910052698 phosphorus Inorganic materials 0.000 claims description 16
- 235000001465 calcium Nutrition 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 15
- 239000000284 extract Substances 0.000 claims description 15
- 229910052748 manganese Inorganic materials 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 15
- 239000000419 plant extract Substances 0.000 claims description 15
- 229910052700 potassium Inorganic materials 0.000 claims description 15
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 claims description 14
- 229940088594 vitamin Drugs 0.000 claims description 14
- 235000013343 vitamin Nutrition 0.000 claims description 14
- 239000011782 vitamin Substances 0.000 claims description 14
- 229930003231 vitamin Natural products 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- 239000011701 zinc Substances 0.000 claims description 14
- 229910052796 boron Inorganic materials 0.000 claims description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 229910021538 borax Inorganic materials 0.000 claims description 9
- 230000006378 damage Effects 0.000 claims description 9
- 239000011574 phosphorus Substances 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- 239000004328 sodium tetraborate Substances 0.000 claims description 9
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 8
- 150000007522 mineralic acids Chemical class 0.000 claims description 8
- 150000007524 organic acids Chemical class 0.000 claims description 8
- LXNHXLLTXMVWPM-UHFFFAOYSA-N pyridoxine Chemical compound CC1=NC=C(CO)C(CO)=C1O LXNHXLLTXMVWPM-UHFFFAOYSA-N 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 7
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 7
- 244000299790 Rheum rhabarbarum Species 0.000 claims description 7
- 235000009411 Rheum rhabarbarum Nutrition 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 229910052733 gallium Inorganic materials 0.000 claims description 7
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 7
- 229910052744 lithium Inorganic materials 0.000 claims description 7
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 7
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 7
- 239000011702 manganese sulphate Substances 0.000 claims description 7
- 235000007079 manganese sulphate Nutrition 0.000 claims description 7
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 7
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 7
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 7
- 239000001120 potassium sulphate Substances 0.000 claims description 7
- 235000011151 potassium sulphates Nutrition 0.000 claims description 7
- 230000001502 supplementing effect Effects 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 240000002234 Allium sativum Species 0.000 claims description 6
- 235000007232 Matricaria chamomilla Nutrition 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 235000004611 garlic Nutrition 0.000 claims description 6
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 6
- -1 isotite Chemical compound 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000007866 Chamaemelum nobile Nutrition 0.000 claims description 5
- 240000007049 Juglans regia Species 0.000 claims description 5
- 235000009496 Juglans regia Nutrition 0.000 claims description 5
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- XAAHAAMILDNBPS-UHFFFAOYSA-L calcium hydrogenphosphate dihydrate Chemical compound O.O.[Ca+2].OP([O-])([O-])=O XAAHAAMILDNBPS-UHFFFAOYSA-L 0.000 claims description 5
- 229910000514 dolomite Inorganic materials 0.000 claims description 5
- 239000010459 dolomite Substances 0.000 claims description 5
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 claims description 5
- 239000001102 lavandula vera Substances 0.000 claims description 5
- 235000018219 lavender Nutrition 0.000 claims description 5
- 239000004323 potassium nitrate Substances 0.000 claims description 5
- 235000010333 potassium nitrate Nutrition 0.000 claims description 5
- 239000001296 salvia officinalis l. Substances 0.000 claims description 5
- JLIDBLDQVAYHNE-YKALOCIXSA-N (+)-Abscisic acid Chemical compound OC(=O)/C=C(/C)\C=C\[C@@]1(O)C(C)=CC(=O)CC1(C)C JLIDBLDQVAYHNE-YKALOCIXSA-N 0.000 claims description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 4
- 235000005881 Calendula officinalis Nutrition 0.000 claims description 4
- 241000195955 Equisetum hyemale Species 0.000 claims description 4
- 240000000982 Malva neglecta Species 0.000 claims description 4
- 235000000060 Malva neglecta Nutrition 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 235000012550 Pimpinella anisum Nutrition 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 244000274883 Urtica dioica Species 0.000 claims description 4
- 235000009108 Urtica dioica Nutrition 0.000 claims description 4
- LGEGBUUXSZVUJY-UHFFFAOYSA-J calcium manganese(2+) dicarbonate Chemical compound C([O-])([O-])=O.[Mn+2].[Ca+2].C([O-])([O-])=O LGEGBUUXSZVUJY-UHFFFAOYSA-J 0.000 claims description 4
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 claims description 4
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 4
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 4
- 239000001095 magnesium carbonate Substances 0.000 claims description 4
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 4
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 4
- 235000002020 sage Nutrition 0.000 claims description 4
- 229940011671 vitamin b6 Drugs 0.000 claims description 4
- 235000020234 walnut Nutrition 0.000 claims description 4
- 235000011330 Armoracia rusticana Nutrition 0.000 claims description 3
- 240000003291 Armoracia rusticana Species 0.000 claims description 3
- 235000005747 Carum carvi Nutrition 0.000 claims description 3
- 240000000467 Carum carvi Species 0.000 claims description 3
- 235000017788 Cydonia oblonga Nutrition 0.000 claims description 3
- 235000009419 Fagopyrum esculentum Nutrition 0.000 claims description 3
- 240000008620 Fagopyrum esculentum Species 0.000 claims description 3
- 235000017309 Hypericum perforatum Nutrition 0.000 claims description 3
- 244000141009 Hypericum perforatum Species 0.000 claims description 3
- 235000007265 Myrrhis odorata Nutrition 0.000 claims description 3
- 235000003846 Ricinus Nutrition 0.000 claims description 3
- 241000322381 Ricinus <louse> Species 0.000 claims description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 3
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 3
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- 241001116389 Aloe Species 0.000 claims description 2
- 235000003097 Artemisia absinthium Nutrition 0.000 claims description 2
- 241000143476 Bidens Species 0.000 claims description 2
- 241000722877 Borago Species 0.000 claims description 2
- 235000003351 Brassica cretica Nutrition 0.000 claims description 2
- 235000003343 Brassica rupestris Nutrition 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- 240000004160 Capsicum annuum Species 0.000 claims description 2
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 claims description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 235000007849 Lepidium sativum Nutrition 0.000 claims description 2
- 244000211187 Lepidium sativum Species 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 241000220317 Rosa Species 0.000 claims description 2
- 235000007303 Thymus vulgaris Nutrition 0.000 claims description 2
- 240000002657 Thymus vulgaris Species 0.000 claims description 2
- 239000000642 acaricide Substances 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 235000011399 aloe vera Nutrition 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 239000001166 ammonium sulphate Substances 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 229910052836 andradite Inorganic materials 0.000 claims description 2
- 229910000512 ankerite Inorganic materials 0.000 claims description 2
- 239000000921 anthelmintic agent Substances 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000003899 bactericide agent Substances 0.000 claims description 2
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 claims description 2
- 239000001354 calcium citrate Substances 0.000 claims description 2
- JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 claims description 2
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 claims description 2
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 claims description 2
- 239000001527 calcium lactate Substances 0.000 claims description 2
- 235000011086 calcium lactate Nutrition 0.000 claims description 2
- 229960002401 calcium lactate Drugs 0.000 claims description 2
- 229940043256 calcium pyrophosphate Drugs 0.000 claims description 2
- CXUJOBCFZQGUGO-UHFFFAOYSA-F calcium trimagnesium tetracarbonate Chemical compound [Mg++].[Mg++].[Mg++].[Ca++].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O CXUJOBCFZQGUGO-UHFFFAOYSA-F 0.000 claims description 2
- 239000001511 capsicum annuum Substances 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 229910021446 cobalt carbonate Inorganic materials 0.000 claims description 2
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 claims description 2
- 229910021540 colemanite Inorganic materials 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- 239000004062 cytokinin Substances 0.000 claims description 2
- UQHKFADEQIVWID-UHFFFAOYSA-N cytokinin Natural products C1=NC=2C(NCC=C(CO)C)=NC=NC=2N1C1CC(O)C(CO)O1 UQHKFADEQIVWID-UHFFFAOYSA-N 0.000 claims description 2
- FCRACOPGPMPSHN-UHFFFAOYSA-N desoxyabscisic acid Natural products OC(=O)C=C(C)C=CC1C(C)=CC(=O)CC1(C)C FCRACOPGPMPSHN-UHFFFAOYSA-N 0.000 claims description 2
- 235000019821 dicalcium diphosphate Nutrition 0.000 claims description 2
- 235000019700 dicalcium phosphate Nutrition 0.000 claims description 2
- 229910052564 epsomite Inorganic materials 0.000 claims description 2
- 229910052587 fluorapatite Inorganic materials 0.000 claims description 2
- 229940077441 fluorapatite Drugs 0.000 claims description 2
- 230000000855 fungicidal effect Effects 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims description 2
- UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 claims description 2
- 229910000515 huntite Inorganic materials 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims description 2
- 229910052928 kieserite Inorganic materials 0.000 claims description 2
- 229910000516 kutnohorite Inorganic materials 0.000 claims description 2
- 229910001552 magnesium chloroborate Inorganic materials 0.000 claims description 2
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 claims description 2
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 claims description 2
- BMQVDVJKPMGHDO-UHFFFAOYSA-K magnesium;potassium;chloride;sulfate;trihydrate Chemical compound O.O.O.[Mg+2].[Cl-].[K+].[O-]S([O-])(=O)=O BMQVDVJKPMGHDO-UHFFFAOYSA-K 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims description 2
- RZTUFFQPZSXZEM-UHFFFAOYSA-N manganese(2+);oxido(oxo)borane Chemical compound [Mn+2].[O-]B=O.[O-]B=O RZTUFFQPZSXZEM-UHFFFAOYSA-N 0.000 claims description 2
- 239000006012 monoammonium phosphate Substances 0.000 claims description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 2
- 235000010460 mustard Nutrition 0.000 claims description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Chemical compound CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 claims description 2
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- 235000011056 potassium acetate Nutrition 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- 235000008160 pyridoxine Nutrition 0.000 claims description 2
- 239000011677 pyridoxine Substances 0.000 claims description 2
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- 229910052801 chlorine Inorganic materials 0.000 description 1
- SMFIECVAWXJWNE-UHFFFAOYSA-L cobalt(2+) dichlorite Chemical compound [Co+2].[O-]Cl=O.[O-]Cl=O SMFIECVAWXJWNE-UHFFFAOYSA-L 0.000 description 1
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- 230000000979 retarding effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical group [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
Definitions
- the invention relates to preparations serving as a nutrient source of plants and for reducing heavy metal and isotope absorption and tolerating injuries brought about by them as well as for reducing the pesticide requirement and a process for the preparation thereof.
- pollutants such as heavy metals and acid rain generating gases are introduced into the environment, polluting the lithosphere, the hydrosphere and the atmosphere.
- the pollutants are introduced through the feeding chain into the human and animal bodies, possibly leading to poisoning and related diseases.
- radio nuclides are introduced into the biosphere.
- the ones with a long half-period, such as Sr-90 and Cs-137 could cause radiation diseases for many thousands of years.
- the basis for the invention is the recognition that if the soluble salts and/or complexes of macro and/or micro elements important from a physiologic aspect are applied to the plants or their environment together with the extract of plants containing biocide and/or repellent ingredient, the disadvantages mentioned above can be avoided or mitigated.
- Macro-elements important for physiological processes are the chemical elements such as C, 0, N, H, P, K, Ca, Mg, S, Si, Na, Cl, Fe and Al occurring in a relatively large quantity in the organic structures of all living creatures.
- Physiologically important micro-elements are the chemical elements existing in a very low quantity in the organizations of living creatures, the lack of which, however, causes functional troubles, or toxicity if they are present in a volume higher than required, such as B, Zn, Cu, Mn, Ti, Li, F, Br, Ni, Rb, Sn, Sr, Ba.
- Macro and micro elements may also be applied partly or fully in the form of rocks containing such elements.
- the subject of the invention covers the preparations serving as a nutrient source for plants, in addition to reducing and helping to tolerate the heavy metal and isotope absorption while decreasing the pesticide volume needed.
- the active ingredients of these preparations are the soluble salts and/or complexes of physiologically important macro and/or micro elements and/or the rocks containing such materials and the extract of plants containing biocide and/or repellent active ingredient.
- We have also found that the impact of preparations can be improved in a target-oriented way, by adding inorganic or organic acids, phytohormons and/or vitamins.
- the macro and micro elements of the preparation embodied by the invention are selected according to the requirements of the plants to be treated, as well as taking into consideration the demand of animals and human beings.
- the various elements can be applied in the form of their soluble salts and/or complexes.
- As a complex especially favourable use can be made of chelates.
- ammonium nitrate or ammonium sulphate can be used as a nitrogen source.
- a percentage by weight of 0.01 to 40 is adjusted.
- mono-ammonium-phosphate or super ⁇ phosphate (the mixture of calcium phosphate and calcium phosphate) may be applied, when converting the total phosphorus concentration of the preparation to elementary phosphorus, a per cent by weight of 0.01 to 40 is adjusted.
- potassium source potassium sulphate, potassium nitrate, potassium acetate, potassium ammonium nitrate or potassium chloride can be used, when converting the total potassium concentrate of the prepration to elementary potassium, a per cent by weight of 0.01 to 40 is adjusted.
- calcium source calcium nitrate, calcium hydrogen phosphate, calcium pyro-phosphate, calcium magnesium carbonate, calcium glyconate, calcium citrate and calcium lactate are identified, when converting the total calcium concentration of the preparation to elementary calcium, the per cent by weight is 0.01 to 20.
- magnesium sulphate, magnesium carbonate or calcium-magnesium carbonate may be used, when the total magnesium concentration of the preparation converted to elementary magnesium is a percentage by weight of 0.01 to 20.
- a suitable manganese source is manganese sulphate, manganese metaborate, manganese-nitrate, manganese-chelates, when converting the total manganese concentration of the preparation to elementary manganese, the percentage by weight is 0.005-30.0.
- a molibdenum source ammonium molibdenate can be applied, when converting the total molibdenum concentration of the preparation to elementary molibdenum, the percent by weight is 0.001 to 10.
- a suitable copper source is copper ( II ) sulphate , copper (II) nitrate, copper (II) acetate or copper-amine complexes, copper (II) amine-sulphate, and when converting the total copper concentration of the preparation to elementary copper, the per cent by weight is 0.001 to 10.
- zinc sulphate and zinc-amine complexes are described, when converting the total zinc concentration of the preparation to elementary zinc, the per cent by weight is 0.05 to 20.
- boric acid or borax may be used, when converting the total boron concentration of the preparation to elementary boron, the per cent by weight is 0.05-10.
- a suitable gallium source is gallium chloride and when converting the total gallium concentration to elementary gallium, the per cent by weight is 0.01 to 10.
- a lithium source lithium nitrate can be used, when the total lithium concentration of the preparation converted to elementary lithium is a percentage by weight of 0.005 to 4.
- cobalt carbonate and cobalt chlorite can be used, when the total cobalt concentration of the preparation converted to elementary cobalt is a per cent by weight of 0.05 to 4.
- a suitable titanium source is titanium dioxide, which is taken into solution in the form of colloide, or titanium sulphate, when the total titanium concentration of the preparation converted to elementary titanium is a per cent by weight of 0.001 to 10.
- iron(III)sulphate or iron-chelates can be used, when the total iron concentration of the preparation converted to elementary iron is a percentage by weight of 0.005 to 30.
- Certain salts and complexes may serve simultaneously as the source of several macro and micro elements.
- superphosphate is simultaneously a calcium, magnesium and phosphorus source
- ammonium molibdenate is a nitrogen and molibdenum source
- certain nitrates are not only metal but also nitrogen sources.
- nitro calcite or strewite as a phosphorus source, fluor apatite, isokite, brushite, kutnohorite, or phosphorit, as a potassium source, potassium nitrate, kanelite, cryptomelane, langbeinit, kainite or polyhalite can be used.
- a calcium source the following are appropriate: dolomite, akermanite, andradite, brushite, monetite, alstonite, aragonite, rezaite, herderite, huntite, kalcite.
- laitarite monticellite, oldhamite, perovskite, polyhalite, powellite, scholzite, or fairfieldite
- magnesium source dolomite, ankerite, epsomite, magnesite, pentahydrite, armalcolite, bischofite, faheyite, geikielite, kieserite, kutnahorite, polyhalite, todorokite or strewite
- the following can be applied: mallardite, ludlamite, graphtonite, jakobsite, kutnahorite, pyrophanite, smikite, or crednerite.
- Suitable molibdenum sources are molibdenite, powellite, or drysdallite, a copper source is kalkantite, crednerite, delafossite and pisanite, and zinc source is zincite, franklinite, hetaerolite, matraite. scholzite, willemite, and gaslarite.
- borax As a boron source, borax, boracite, colemanite, inyoite, priceite, warwikite and sassoline, as a gallium source gallite, as a lithium source trifiline, as a cobalt source sphero cobaltite and as a titanium source ilmenite, armalcolite or geikielite may be used.
- iron source As an iron source, ilmenite, trifiline, cubanite, heterosite, melonteritote, rosenitote, strengite, somolnokite, vivanite or pisanite may be applied.
- a sitable stroncium source is celestite and stroncianite.
- Plants containing biocide and/or repellent active ingredient are plants which contain pesticide, such as bactericide, viricide, insecticide, fungicide, miticide or vermicide or repellent materials.
- Plant extracts applicable as components of the preparations embodied by the invention are available from trade or they can be produced by extraction, vapour distillation and/or pressing of the plant organs containing the active ingredient, for example the flower, leaves, root, berries or seed.
- the plant extracts available from trade include the active ingredients of one or more plants.
- Such abstracts are for example the products marketed under the names Aromex and Fresta.
- Extraction may be carried out by an organic extracting agent, for example by alcohol, some kind of an oil or acid or by the mixtures of these.
- an organic extracting agent for example by alcohol, some kind of an oil or acid or by the mixtures of these.
- the effect of the preparations embodied by the invention may be enhanced by adding inorganic or organic acids, phytohormons and/or vitamins.
- Such inorganic or organic acids can be used which do not harm the plants in the concentration applied.
- a further advantage of using inorganic or organic acids is that they shift the pH rate of the preparation to the acid range, and as a result the nutrient absorption of plants to be treated is enhanced.
- An inorganic acid that can be applied beneficially is phosphoric acid, while as an organic acid, lactic acid, citric acid, malic acid, butanedioic acid, acetic acid etc. can be applied.
- phytohormons and vitamins are also boosting agents.
- phytohormons it is advantageous to use auxins, gibberellines, cytokinins, abscisic acid and ethylene.
- vitamins advantageous use can be made of thiamine- hydrochloride, aneurin, pyridoxine and nicotine acid. The quantity of these materials amounts to between 1 ⁇ g and 50 g per one litre of the preparation.
- suspending agent such as bentonite, alginite or vinace is added.
- the latter materials partly improve the viscosity of the preparation and partly increase the active colloide surface of the preparation.
- the retarded effect of the preparation is ensured by the absorbed cations on the surface of the colloides.
- the accurate composition of the preparation embodied by the invention is selected according to the objective to be accomplished. If the preparation is used as a plant nutrient, through their application the mineral content of plants can be increased in a target-oriented way, meaning the iron, calcium, magnesium, copper, selenium or zinc content. In this way, in addition to increasing the plant yield, it better corresponds to the mineral requirement of the person or the animal species to be fed.
- vegetables and fruit with a high iron content can be produced. This can be achieved by spraying the vegetables and fruit with a high iron content preparation.
- Lucern intended to feed high milking capacity cattle for example is sprayed with a high calcium and magnesium preparation and so the fodder will also have a higher calcium and magnesium content.
- the preparation embodied by the invention is intended for reducing and tolerating the heavy metal absorption of plants
- first soil and plant analysis is carried out, i.e. it is determined what heavy metals are present, and in which concentration and form. In the knowledge of these factors is the composition selected and such a preparation is produced which has a high calcium and magnesium content and a significant micro-element content.
- the plant organs above the soil are saturated with calcium, magnesium and micro elements, thereby antagonizing (reducing) the absorption of heavy metals and facilitating the toleration of the plant.
- the micro elements phytohormons and/or vitamins in the preparation boost the enzyme activities of the plants, thereby contributing to tolerating heavy metal pollution.
- the preparation embodied by the invention is designed to reduce and tolerate isotope absorption by the plants, again soil and plant analysis precedes the selection of composition.
- the concentration of the stable forms of polluting isotope(s) or that of the antagonist isotopes we increase in the preparation the concentration of the stable forms of polluting isotope(s) or that of the antagonist isotopes.
- concentration of calcium and magnesium and also that of stable stroncium in the case of Cs-137 the concentration of potassium, calcium and magnesium and in the case of J-131 that of stable iodine is increased.
- the salts and/or complexes of macro and micro elements selected according to the purpose to be achieved are added, and then the mixture is supplemented as required by one or more phytohormon and/or vitamin and/or inorganic or organic acid and if necessary also by a suspending agent.
- the macro and micro elements are used in the form of rocks, one or more rocks selected on the basis of its nutrient content are crushed to 1 nm - 10 mm size, and this is added to the plant extract(s) of biocide effect. If only a part of the macro and micro elements is applied in the form of rocks, the lacking nutrients are supplied by their salts or complexes.
- Producing foliar fertilizer serving as a nutrient source The water, alcohol or oil based extracts of the following plants are mixed:
- Thyme oil (oleum thymi) 0.50 litres nettle 3.00 litres pyretrum extract 1.50 litres nicotine 0.50 litres quassia chips 0.50 litres vinace 2.00 litres
- the mixture is diluted to 100 litres by water, and then the following components are added into a 20-litre volume of the compound, while performing agitation:
- the volume of the mixture is made up to 100 litres, by means of the compound consisting of plant extracts.
- the foliar fertilizer concentrate so obtained can be used for supplementing the N, P, . K, Ca, Mg, Fe, Cu , Mn and B nutrients of plants.
- the mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound while agitating:
- the volume of the mixture is made up to 100 litres, with the compound consisting of plant extracts.
- the so obtained foliar fertilizer concentrate By diluting to 0.01 to 30 per cent by volume the so obtained foliar fertilizer concentrate, it can be used for supplementing the N, P, K. Ca, Mg, Fe, Mn and B nutrients of plants and for reducing the zinc absorption and tolerate the excess zink taken up.
- Example 3 Producing a foliar fertilizer aimed at reducing the absorption of Sr-85 and Sr-90 isotopes and for rehabilitating damage caused by radiation.
- the mixture is diluted to 100 litres of water and then the following components are added to a volume of 20 litres of this compound, while agitating:
- the volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
- the foliar fertilizer concentrate so obtained, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of Sr isotopes.
- the mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound, while agitating:
- volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
- the foliar fertilizer concentrate so obtained By diluting the foliar fertilizer concentrate so obtained, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of Cs isotopes.
- the mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound, while agitating: superphosphate 20.00 kg potassium sulphate 15.00 kg calcium nitrate 25.00 kg copper tetramine complex 1.00 kg magnesium sulphate 15.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg potassium iodide 1.50 kg iodine 0.75 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
- volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
- the foliar fertilizer concentrate so obtained By diluting the foliar fertilizer concentrate so obtained to 0.01 to 10 per cent by volume, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of iodine isotope.
- Vitamin B2 1.0 g
- Vitamin B6 2.0 g
- the plants make better use of the nutrients in the preparation so obtained, and through the application of this mixture, the repairing and recovery processes of poisoning by heavy metal absorption and radiation damage are accelerated in plants.
- the nutrients of the preparation so obtained are better utilized by the plants, and through its application the reparation processes of plants as a result of poisoning by heavy metal absorption and radiation damage are accelerated.
- Vitamin Bl 0.5 g
- Vitamin B2 1.0 g
- Vitamin B6 2.0 g ⁇ -indolil-acetic acid 5.0 g gibberelline (GA 10 ) 20.0 g nicotine acid 1.0 g kinetine 3.0 g
- the nutrients of the preparation so obtained are better utilized by the plants, and through its application the repairing processes of plants as a result of poisoning by heavy metal absorption and radiation damage are accelerated.
- This mixture is diluted to 100 litres by water, and then the following crushed rocks are added to a 20-litre volume of the compound, while agitating:
- the preparation so produced is diluted to 0.1 to 50 per cent by volume, it can be used for supplementing the N, P,
- the wheat variety Mv 16 was treated in 2-3 leaf condition with the preparation as per example 1, diluted to 1 %, 5 % and 10 % concentration (A, B, C) .
- untreated plants were used.
- the wheat variety Mv 15, was treated in 2-3 leaf condition with a preparation as per example 10, diluted 1%, 5% and 10% concentration (A, B, C) .
- a preparation as per example 10 diluted 1%, 5% and 10% concentration (A, B, C) .
- A, B, C diluted 1%, 5% and 10% concentration
- Tomato berries in green phenological state were treated with preparation A as per example 7, diluted to 10 %, and then in ripe phenological condition we have also determined the nutrient content of the berries.
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Abstract
The invention covers preparations serving as nutrient source of plants and for reducing and tolerating their heavy metal and isotope absorption, as well as for reducing the pesticide volume and also the procedure of turning out such products. As active ingredient, the preparations contain the soluble salts and/or complexes of physiologically important macro and/or micro elements and/or the rocks containing such materials and the abstract of plants containing biocide and/or repellent active ingredient.
Description
Preparations providing a nutrient source for plants and a process for making such preparations
TECHNICAL FIELD
The invention relates to preparations serving as a nutrient source of plants and for reducing heavy metal and isotope absorption and tolerating injuries brought about by them as well as for reducing the pesticide requirement and a process for the preparation thereof.
BACKGROUND ART
It is well known that in agriculture some preparations containing nutrients to improve the yield are used, such as organic manure, fertilizers, foliar fertilizers as well as large quantities of pesticides which are applied to the plants or their environment, in order to eradicate pests and parasites.
Of these preparations, those containing synthetic active ingredients have numerous side-effects in addition to the desired impact. For example the application of large quantities of fertilizers containing nitrogen, phosphorus and potassium may lead to deficiency symptoms reflecting the lack of micro-elements in plants (S. Kiss: Magnesium fertilizers, magnesium in biology. Agricultural Publishing House, Budapest 1983. W. Bergmann: Occurrence and recognizing of nutrition disturbances in cultivated plants, Agricultural Publishing House, Budapest 1979) . This - in addition to retarding the development and growth of plants - also results in the plant generating less growth and development factors (amino-acid, vitamins and enzimes) so important for the human and animal body. Besides, residuals of pesticides may cause different grades and manifestations of poisoning in humans and animals, and they are also the cause of polluting the soil and natural waters.
One of the detrimental side-effects of industrial production is that various pollutants such as heavy metals and acid rain generating gases are introduced into the environment, polluting the lithosphere, the hydrosphere and the atmosphere. The pollutants are introduced through the feeding chain into the human and animal bodies, possibly leading to poisoning and related diseases.
In the operational breakdowns of nuclear power stations or upon experimental nuclear explosions, radio nuclides are introduced into the biosphere. Of these, the ones with a long half-period, such as Sr-90 and Cs-137 could cause radiation diseases for many thousands of years.
Consequently, approaches and preparations are required by which the nutrient demand of plants, animals and people can be met without detrimental side-effects, while reducing the quantity of pesticides applied, along with the heavy metal
and isotope absorption of plants, and facilitating repairing and recovery possesses.
The basis for the invention is the recognition that if the soluble salts and/or complexes of macro and/or micro elements important from a physiologic aspect are applied to the plants or their environment together with the extract of plants containing biocide and/or repellent ingredient, the disadvantages mentioned above can be avoided or mitigated.
Macro-elements important for physiological processes are the chemical elements such as C, 0, N, H, P, K, Ca, Mg, S, Si, Na, Cl, Fe and Al occurring in a relatively large quantity in the organic structures of all living creatures.
Physiologically important micro-elements are the chemical elements existing in a very low quantity in the organizations of living creatures, the lack of which, however, causes functional troubles, or toxicity if they are present in a volume higher than required, such as B, Zn, Cu, Mn, Ti, Li, F, Br, Ni, Rb, Sn, Sr, Ba.
Macro and micro elements may also be applied partly or fully in the form of rocks containing such elements.
DISCLOSURE OF THE INVENTION
The subject of the invention covers the preparations serving as a nutrient source for plants, in addition to reducing and helping to tolerate the heavy metal and isotope absorption while decreasing the pesticide volume needed. The active ingredients of these preparations are the soluble salts and/or complexes of physiologically important macro and/or micro elements and/or the rocks containing such materials and the extract of plants containing biocide and/or repellent active ingredient.
We have also found that the impact of preparations can be improved in a target-oriented way, by adding inorganic or organic acids, phytohormons and/or vitamins.
The macro and micro elements of the preparation embodied by the invention are selected according to the requirements of the plants to be treated, as well as taking into consideration the demand of animals and human beings.
The various elements can be applied in the form of their soluble salts and/or complexes. As a complex, especially favourable use can be made of chelates.
As the source of macro and micro elements, the following compounds are listed as examples.
As a nitrogen source, ammonium nitrate or ammonium sulphate can be used. In relation to elementary nitrogen, a percentage by weight of 0.01 to 40 is adjusted.
As a phosphorus source, mono-ammonium-phosphate or super¬ phosphate (the mixture of calcium phosphate and calcium phosphate) may be applied, when converting the total phosphorus concentration of the preparation to elementary phosphorus, a per cent by weight of 0.01 to 40 is adjusted.
As a potassium source, potassium sulphate, potassium nitrate, potassium acetate, potassium ammonium nitrate or potassium chloride can be used, when converting the total potassium concentrate of the prepration to elementary potassium, a per cent by weight of 0.01 to 40 is adjusted. As a calcium source, calcium nitrate, calcium hydrogen phosphate, calcium pyro-phosphate, calcium magnesium carbonate, calcium glyconate, calcium citrate and calcium lactate are identified, when converting the total calcium concentration of the preparation to elementary calcium, the
per cent by weight is 0.01 to 20.
As a magnesium source, magnesium sulphate, magnesium carbonate or calcium-magnesium carbonate may be used, when the total magnesium concentration of the preparation converted to elementary magnesium is a percentage by weight of 0.01 to 20.
A suitable manganese source is manganese sulphate, manganese metaborate, manganese-nitrate, manganese-chelates, when converting the total manganese concentration of the preparation to elementary manganese, the percentage by weight is 0.005-30.0. As a molibdenum source, ammonium molibdenate can be applied, when converting the total molibdenum concentration of the preparation to elementary molibdenum, the percent by weight is 0.001 to 10.
A suitable copper source is copper ( II ) sulphate , copper (II) nitrate, copper (II) acetate or copper-amine complexes, copper (II) amine-sulphate, and when converting the total copper concentration of the preparation to elementary copper, the per cent by weight is 0.001 to 10.
As a zinc source, zinc sulphate and zinc-amine complexes are described, when converting the total zinc concentration of the preparation to elementary zinc, the per cent by weight is 0.05 to 20.
As a boron source, boric acid or borax may be used, when converting the total boron concentration of the preparation to elementary boron, the per cent by weight is 0.05-10.
A suitable gallium source is gallium chloride and when converting the total gallium concentration to elementary gallium, the per cent by weight is 0.01 to 10.
As a lithium source, lithium nitrate can be used, when the total lithium concentration of the preparation converted to elementary lithium is a percentage by weight of 0.005 to 4.
As a cobalt source, cobalt carbonate and cobalt chlorite can be used, when the total cobalt concentration of the preparation converted to elementary cobalt is a per cent by weight of 0.05 to 4.
A suitable titanium source is titanium dioxide, which is taken into solution in the form of colloide, or titanium sulphate, when the total titanium concentration of the preparation converted to elementary titanium is a per cent by weight of 0.001 to 10.
As an iron source, iron(III)sulphate or iron-chelates can be used, when the total iron concentration of the preparation converted to elementary iron is a percentage by weight of 0.005 to 30.
Certain salts and complexes may serve simultaneously as the source of several macro and micro elements. Thus for example superphosphate is simultaneously a calcium, magnesium and phosphorus source, ammonium molibdenate is a nitrogen and molibdenum source, and certain nitrates are not only metal but also nitrogen sources.
If the necessary elements are used in the form of rocks, as examples the following are listed.
As a nitrogen source, nitro calcite or strewite, as a phosphorus source, fluor apatite, isokite, brushite, kutnohorite, or phosphorit, as a potassium source, potassium nitrate, kanelite, cryptomelane, langbeinit, kainite or polyhalite can be used.
As a calcium source, the following are appropriate: dolomite, akermanite, andradite, brushite, monetite, alstonite, aragonite, fassaite, herderite, huntite, kalcite. laitarite, monticellite, oldhamite, perovskite, polyhalite, powellite, scholzite, or fairfieldite, as a magnesium source dolomite, ankerite, epsomite, magnesite, pentahydrite, armalcolite, bischofite, faheyite, geikielite, kieserite, kutnahorite, polyhalite, todorokite or strewite, while as a manganese source, the following can be applied: mallardite, ludlamite, graphtonite, jakobsite, kutnahorite, pyrophanite, smikite, or crednerite.
Suitable molibdenum sources are molibdenite, powellite, or drysdallite, a copper source is kalkantite, crednerite, delafossite and pisanite, and zinc source is zincite, franklinite, hetaerolite, matraite. scholzite, willemite, and gaslarite.
As a boron source, borax, boracite, colemanite, inyoite, priceite, warwikite and sassoline, as a gallium source gallite, as a lithium source trifiline, as a cobalt source sphero cobaltite and as a titanium source ilmenite, armalcolite or geikielite may be used.
As an iron source, ilmenite, trifiline, cubanite, heterosite, melonteritote, rosenitote, strengite, somolnokite, vivanite or pisanite may be applied.
A sitable stroncium source is celestite and stroncianite.
Plants containing biocide and/or repellent active ingredient are plants which contain pesticide, such as bactericide, viricide, insecticide, fungicide, miticide or vermicide or repellent materials.
As examples for such plants, the following are mentioned:
mustard (Brassica juncea Czern.) absinth (Artemisia absinthium L.) , chamomile (Matricaria chamomilla L.) , calendula (Calendula officinalis L.), thyme (Thy us vulgaris L.), horsetail (Ephedra equisetine Bge.), borago (Borago officinalis L.), caraway (Caru carvi L.), black radish (Raphanus sativum) , quince (Cydonia oblonga Mill.), rose (Rosa L.), sage (Lepidium sativum L.), walnut (Juglans regia L.), ricinus (Ricinus communis L.) paprika (Capsicum annua L.), mallow (Althaea officinalis L.) , hyppophae (Hyppophae rhamnoides L.), celery (Apium gravedens L.), normal sage (Salvia officinalis L.), bidens (Bidens tripartitus L.), abutilon (Abutilon Adans) , chrysanthenum (Chrysenthenum vulgare L. , Phyrethrum Bois. ) , lavender (Lavendula officinalis L.), buckwheat (Fagopyrum Geartu.), St.John's wort (Hypericum perforatum) , horse radish (Verbascum thapsiforme) , plantain (Plantago major L.) , anise (Pimpinella anisum L.), aloe (Aloe arborescens Mill.), rhubarb (Rhenum officinale) , garlic (Alliu sativum L.), nettle (Urtica dioica L.).
Plant extracts applicable as components of the preparations embodied by the invention are available from trade or they can be produced by extraction, vapour distillation and/or pressing of the plant organs containing the active ingredient, for example the flower, leaves, root, berries or seed.
The plant extracts available from trade include the active ingredients of one or more plants. Such abstracts are for example the products marketed under the names Aromex and Fresta.
Extraction may be carried out by an organic extracting agent, for example by alcohol, some kind of an oil or acid or by the mixtures of these.
As mentioned above, the effect of the preparations embodied by the invention may be enhanced by adding inorganic or organic acids, phytohormons and/or vitamins.
Such inorganic or organic acids can be used which do not harm the plants in the concentration applied.
A further advantage of using inorganic or organic acids is that they shift the pH rate of the preparation to the acid range, and as a result the nutrient absorption of plants to be treated is enhanced.
An inorganic acid that can be applied beneficially is phosphoric acid, while as an organic acid, lactic acid, citric acid, malic acid, butanedioic acid, acetic acid etc. can be applied.
Phytohormons and vitamins are also boosting agents. As phytohormons, it is advantageous to use auxins, gibberellines, cytokinins, abscisic acid and ethylene. As vitamins, advantageous use can be made of thiamine- hydrochloride, aneurin, pyridoxine and nicotine acid. The quantity of these materials amounts to between 1 μg and 50 g per one litre of the preparation.
For the preparations embodied by the invention, if necessary suspending agent such as bentonite, alginite or vinace is added. The latter materials partly improve the viscosity of the preparation and partly increase the active colloide surface of the preparation. The retarded effect of the preparation is ensured by the absorbed cations on the surface of the colloides.
The accurate composition of the preparation embodied by the invention is selected according to the objective to be accomplished.
If the preparation is used as a plant nutrient, through their application the mineral content of plants can be increased in a target-oriented way, meaning the iron, calcium, magnesium, copper, selenium or zinc content. In this way, in addition to increasing the plant yield, it better corresponds to the mineral requirement of the person or the animal species to be fed.
To supply pregnant women and small children, for example, vegetables and fruit with a high iron content can be produced. This can be achieved by spraying the vegetables and fruit with a high iron content preparation.
Lucern intended to feed high milking capacity cattle for example is sprayed with a high calcium and magnesium preparation and so the fodder will also have a higher calcium and magnesium content.
If the preparation embodied by the invention is intended for reducing and tolerating the heavy metal absorption of plants, first soil and plant analysis is carried out, i.e. it is determined what heavy metals are present, and in which concentration and form. In the knowledge of these factors is the composition selected and such a preparation is produced which has a high calcium and magnesium content and a significant micro-element content. When plants are sprayed with such a preparation, the plant organs above the soil are saturated with calcium, magnesium and micro elements, thereby antagonizing (reducing) the absorption of heavy metals and facilitating the toleration of the plant. The micro elements phytohormons and/or vitamins in the preparation boost the enzyme activities of the plants, thereby contributing to tolerating heavy metal pollution.
If the preparation embodied by the invention is designed to
reduce and tolerate isotope absorption by the plants, again soil and plant analysis precedes the selection of composition. Once this information is gathered, we can increase in the preparation the concentration of the stable forms of polluting isotope(s) or that of the antagonist isotopes. Thus, for example in the case of Sr-90, we increase the concentration of calcium and magnesium and also that of stable stroncium, in the case of Cs-137 the concentration of potassium, calcium and magnesium and in the case of J-131 that of stable iodine is increased. At the same time, we also enhance the concentration of elements able to change their valence (e.g. copper, manganese, iron) and B-vitamins and phytohormons to encourage the processes of rerairing and recovering the damage caused by radiation.
The plant extracts applied in the preparations embodied by the invention - in addition to exerting a biocide effect themselves, thus reducing the necessary quantity of other pesticides, also assist the nutrient uptake of plants.
The preparations embodied by the invention are produced in the following way.
To the biocide effect plant extract or to the mixture of multi biocide effect plant extracts, the salts and/or complexes of macro and micro elements selected according to the purpose to be achieved are added, and then the mixture is supplemented as required by one or more phytohormon and/or vitamin and/or inorganic or organic acid and if necessary also by a suspending agent.
If the macro and micro elements are used in the form of rocks, one or more rocks selected on the basis of its nutrient content are crushed to 1 nm - 10 mm size, and this is added to the plant extract(s) of biocide effect.
If only a part of the macro and micro elements is applied in the form of rocks, the lacking nutrients are supplied by their salts or complexes.
DETAILED DESCRIPTION OF EXAMPLES
The invention is demonstrated by way of the following examples.
Example 1
Producing foliar fertilizer serving as a nutrient source. The water, alcohol or oil based extracts of the following plants are mixed:
marigold 2.00 litres horsetail 5.00 litres sage 10.00 litres
Fresta 1000 2.00 litres
Aromex 0.50 litres
Thyme oil (oleum thymi) 0.50 litres nettle 3.00 litres pyretrum extract 1.50 litres nicotine 0.50 litres quassia chips 0.50 litres vinace 2.00 litres
The mixture is diluted to 100 litres by water, and then the following components are added into a 20-litre volume of the compound, while performing agitation:
ammonium nitrate 20.00 kg
superphosphate 10.00 kg potassium sulphate 20.00 kg calcium nitrate 10.00 kg copper-tetramine-complex 5.00 kg magnesium sulphate 5.00 kg iron (III) sulphate 2.00 kg manganese-sulphate 0.50 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
Finally, the volume of the mixture is made up to 100 litres, by means of the compound consisting of plant extracts.
By diluting to 0.01 to 30 per cent by volume, the foliar fertilizer concentrate so obtained can be used for supplementing the N, P, . K, Ca, Mg, Fe, Cu , Mn and B nutrients of plants.
Example 2
Producing foliar fertilizer for reducing heavy metal absorption.
When producing foliar fertilizer for reducing zinc absorption, the zinc salts and complexes are left out of the nutrients and the calcium, magnesium and micro-element content of the product is increased.
The extracts of the following plants are mixed:
celery 2.00 litres rhubarb 5.00 litres
black radish 5.00 litres garlic 5.00 litres lavender 10.00 litres
Fresta 1000 2.00 litres caraway seed 1.50 litres ricinus 1.50 litres vinace 2.00 litres
The mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound while agitating:
ammonium nitrate 20.00 kg superphosphate 10.00 kg potassium sulphate 20.00 kg calcium nitrate 15.00 kg magnesium sulphate 10.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
And finally the volume of the mixture is made up to 100 litres, with the compound consisting of plant extracts.
By diluting to 0.01 to 30 per cent by volume the so obtained foliar fertilizer concentrate, it can be used for supplementing the N, P, K. Ca, Mg, Fe, Mn and B nutrients of plants and for reducing the zinc absorption and tolerate the excess zink taken up.
Example 3
Producing a foliar fertilizer aimed at reducing the absorption of Sr-85 and Sr-90 isotopes and for rehabilitating damage caused by radiation.
The extracts of the following plants are mixed:
chamomile 2.00 litres rhubarb 5.00 litres garlic 10.00 litres
Fresta 1000 2.00 litres
Aromex 1.50 litres horsetail 2.00 litres mustard seed 3.00 litres vinace 5.00 litres
The mixture is diluted to 100 litres of water and then the following components are added to a volume of 20 litres of this compound, while agitating:
superphosphate 20.00 kg potassium sulphate 15.00 kg calcium nitrate 25.00 kg copper tetramine complex 1.00 kg magnesium sulphate 15.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
Finally, the volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
By diluting the foliar fertilizer concentrate so obtained, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of Sr isotopes.
Example 4
Producing a foliar fertilizer for reducing the absorption of Cs-134 and Cs-137 isotopes.
The extracts of the following plants are mixed:
chamomile 2.00 litres rhubarb 5.00 litres garlic 10.00 litres horse radish 3.00 litres anise 1.00 litres
St John's wort 1.50 litres
Fresta 1000 2.00 litres
Aromex 1.50 litres vinace 5.00 litres
The mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound, while agitating:
superphosphate 20.00 kg potassium sulphate 30.00 kg calcium nitrate 15.00 kg copper tetramine complex 1.50 kg magnesium sulphate 20.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg zinc-hexamine complex 0.50 kg
ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
Finally, the volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
By diluting the foliar fertilizer concentrate so obtained, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of Cs isotopes.
Example 5
Producing a foliar fertilizer for reducing the absorption of J-131 isotope.
The extracts of the following plants are mixed:
chamomile 2.00 litres walnut shell 4.00 litres mallow 2.50 litres black radish 5.00 litres lavender 0.50 litres rhubarb 5.00 litres garlic 10.00 litres
Fresta 1000 2.00 litres
Aromex 1.50 litres vinace 5.00 litres
The mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound, while agitating:
superphosphate 20.00 kg potassium sulphate 15.00 kg calcium nitrate 25.00 kg copper tetramine complex 1.00 kg magnesium sulphate 15.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg potassium iodide 1.50 kg iodine 0.75 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
Finally, the volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
By diluting the foliar fertilizer concentrate so obtained to 0.01 to 10 per cent by volume, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of iodine isotope.
Example 6
Producing a foliar fertilizer supplemented with acid.
To 100 litres of the preparation as per example 1, lactic acid of 5 per cent by volume is added.
The preparation so produced facilitates the nutrient absorption of plants, and the active ingredients of plant extracts are activated.
Example 7
Producing of foliar fertilizer supplemented with vitamins.
To 100 litres of the preparation as per Example 1, the following vitamins are added:
Vitamin B 10.5 g
Vitamin B2 1.0 g
Vitamin B6 2.0 g
The plants make better use of the nutrients in the preparation so obtained, and through the application of this mixture, the repairing and recovery processes of poisoning by heavy metal absorption and radiation damage are accelerated in plants.
Example 8
Producing of foliar fertilizer supplemented with phytohormons .
To 100 litres of the preparation as per Example 2, the following phytohormons are added:
naphthil-acetic acid 5.0 g gibberelline (GA3) 20.0 g nicotine acid 1.0 g kinetine 3.0 g
The nutrients of the preparation so obtained are better
utilized by the plants, and through its application the reparation processes of plants as a result of poisoning by heavy metal absorption and radiation damage are accelerated.
Example 9
Producing foliar fertilizer supplemented with vitamins and phytohormons.
To 100 litres of the preparation as per Example 1, the following vitamins and phytohormons are added:
Vitamin Bl 0.5 g
Vitamin B2 1.0 g
Vitamin B6 2.0 g α-indolil-acetic acid 5.0 g gibberelline (GA10) 20.0 g nicotine acid 1.0 g kinetine 3.0 g
The nutrients of the preparation so obtained are better utilized by the plants, and through its application the repairing processes of plants as a result of poisoning by heavy metal absorption and radiation damage are accelerated.
Example 10
Producing foliar fertilizer serving as the nutrient of plants, through the use of rocks.
chamomile extract 2.00 litres rhubarb extract 5.00 litres marigold extract 1.50 litres walnut extract 0.50 litres garlic extract 10.00 litres
This mixture is diluted to 100 litres by water, and then the following crushed rocks are added to a 20-litre volume of the compound, while agitating:
nitrocalcite 15.00 kg strewite 10.00 kg brushite 15.00 kg isokite 12.00 kg potassium nitrate 20.00 kg dolomite 18.00 kg mallardite 1.00 kg powellite 1.50 kg pisanite 2.50 kg zincite 2.50 kg gallite 0.50 kg trifiline 0.50 kg
spherocobaltite 0.25 kg ilmenite 0.25 kg bentonite 1.00 kg
Let the mixture stand for seven days.
When the preparation so produced is diluted to 0.1 to 50 per cent by volume, it can be used for supplementing the N, P,
K, Ca, Mg, Fe, Cu, Mn nutrients of plants.
The efficiency of preparations embodied by the invention is demonstrated by the following experiments:
Experiment A
Testing of nutrient content in wheat
The wheat variety Mv 16, was treated in 2-3 leaf condition with the preparation as per example 1, diluted to 1 %, 5 % and 10 % concentration (A, B, C) . As a reference, untreated plants were used.
In 3-4 leaf condition we have determined the nutrient content of the leaves. The results are given in the following Table I.
Experiment B
Testing of nutrient content in wheat.
The wheat variety Mv 15, was treated in 2-3 leaf condition with a preparation as per example 10, diluted 1%, 5% and 10% concentration (A, B, C) . As a reference, untreated plants were used.
In 3-4 leaf condition we have determined the nutrient content of the leaves. The results are given in the following Table II.
Table I
Table II
Experiment C
Testing the reduction of SR-85 activity on bean plants. Two-week old bean plants which absorbed SR-85 isotope from the soil were treated with a preparation as per example 3, diluted to 5 % concentration.
When the age reached 4-weeks, we have re-measured the Ns-85 activity of the plants. The results obtained are summarized in the following Table III.
Table III
Sr-85 activity In a percentage of (Bq/g) the reference
Before treatment (reference) 8.12 ± 0.59 100.0 After treatment 7.21 ± 1.06 88.79
Experiment D
Testing of nutrient content on tomatoes.
Tomato berries in green phenological state were treated with preparation A as per example 7, diluted to 10 %, and then in ripe phenological condition we have also determined the nutrient content of the berries.
The results achieved are given in Table IV.
Experiment E
Testing of nutrient content on grapes .
At the time of the bursting of the buds we have determined the nutrient content of the leaves of Ezerj ό ( Thousand goodies) grape variety and the plants were treated with the preparation as per example 9 , diluted to 1% , 5% and 10% concentration (A, B and C) .
At the t ime when the berr i es were r ipe , we have re- determined the nutrient content of leaves . The results obtained are given in Table V.
Experiment F
Treatment of sugar-beet.
In 3 -5 leaf state we have determined the Fe , Zn , and Mn content of the leaves of Beta-poly 1 sugar beet hybride , and then the plants were treated with the preparation as per
Example 2 .
In 5-7 leaf state we have re-measured the Fe- Zn and Mn content of the leaves. The results obtained are indicated in the following Table VI.
Table IV
Table V
Table VI
Claims
1. A preparation serving the purposes of providing a nutrient source for plants and of reducing and tolerating the heavy metal and isotope absorption of and injuries caused by them to plants, characterized in that as active ingredients the preparation contains soluble salts of physiologically important macro and/or micro elements and/or complexes and/or rocks including the same, and said preparation further containing extracts of plants containing biocide and/or repellent active ingredient.
2. The preparation as claimed in claim 1, characterized in that as a nitrogen source it contains some kind of a soluble ammonium compound or nitrate, preferably ammonium nitrate or ammonium sulphate.
3. The preparation as claimed in claim 1, characterized in that as a phosphorus source it contains some kind of a soluble phosphate, preferably mono-ammonium phosphate or superphospate.
4. The preparation as claimed in claim 1, characterized in that as a potassium source it contains some kind of a soluble potassium salt, preferably potassium sulphate, potassium nitrate, potassium acetate or potassium chloride.
5. The preparation as claimed in claim 1, characterized in that as a calcium source it contains some kind of a soluble calcium salt, preferably calcium nitrate, calcium hydrogen phosphate, calcium pyrophosphate, calcium citrate, calcium glyconate, calcium lactate or calcium magnesium carbonate.
6. The preparation as claimed in claim 1, characterized in that as a magnesium source it contains some kind of a soluble magnesium salt, preferably magnesium sulphate, magnesium carbonate or calcium magnesium carbonate.
7. The preparation as claimed in claim 1, characterized in that as a manganese source it contains some kind of a soluble manganese salt, preferably manganese sulphate, manganese metaborate, manganese nitrate or manganese chelate.
8. The preparation as claimed in claim 1, characterized in that as a molibdenum source it contains some kind of a soluble molibdenum salt, preferably ammonium-molibdenate.
9. The preparation as claimed in claim 1, characterized in that as a copper source some kind of a copper salt, preferably copper sulphate, copper-nitrate, copper-acetate or copper-amine complex is included.
10. The preparation as claimed in claim 1, characterized in that as a zinc source it includes some kind of a soluble zinc salt, preferably zinc sulphate or zinc hexamine complex.
11. The preparation as claimed in claim 1, characterized in that as a boron source it includes some kind of a boric acid or soluble boron salt, preferably borax.
12. The preparation as claimed in claim 1, characterized in that it includes as a gallium source some kind of a soluble gallium salt preferably gallium chloride.
13. The preparation as claimed in claim 1, characterized in that as a lithium source, some kind of a soluble lithium salt, preferably lithium nitrate is included.
14. The preparation as claimed in claim 1, characterized in that as a cobalt source, it includes some kind of a soluble cobalt salt, preferably cobalt carbonate or cobalt chloride.
15. The preparation as claimed in claim 1, characterized in that as a titanium source, it includes titanium dioxide.
16. The preparation as claimed in claim 1, characterized in that as an iron source, it includes some kind of a soluble iron (III) salt, preferably iron (III) sulphate or iron kelates.
17. The preparation as claimed in claim 1, characterized in that as a nitrogen source it includes some kind of nitrogen-containing rocks, preferably nitro-calcite or strewite.
18. The preparation as claimed in claim 1, characterized in that as a phosphorus source, it includes some kind of phosphorus containing rocks, preferably fluor apatite, isotite, brushite, kutnohorite or phosphorite.
19. The preparation as claimed in claim 1, characterized in that as a potassium source it includes some kind of potassium containing rocks, preferably potassium nitrate, karnallite, cryptomelane, langbeinite or kainite.
20. The preparation as claimed in claim 1, characterized in that as a calcium source it includes some kind of calcium- containing rocks, preferably dolomite, akermanite, andradite, brushite, monetite, alstonite, aragonite, fassaite, herderite, huntite, calcite, lautarite, monticellite, oldhamite, perovskite, polyhalite, powellite, scholzite or fairfieldite.
21. The preparation as claimed in claim 1, characterized in that as a magnesium source it includes some kind of magnesium containing rocks, preferably dolomite, ankerite, epsomite, magnesite, pentahydrite, armalcolite, bischofite, fajheyite, geikielite, kieserite, kutnahorite, polyhalite, strevite, todorokite, or strewite.
22. The preparation as claimed in claim 1, characterized in that as a manganese source it includes some kind of manganese containing rocks, preferably mallardite, ludlamite, graphtonite, jakobsite, kutnahorite, pyrofanite, smikite or crednerite.
23. The preparation as claimed in claim 1, characterized in that as a molibdenum source it includes some kind of molibdenum containing rocks, preferably molibdenite, drysdallite, or powellite.
24. The preparation as claimed in claim 1, characterized in that as a copper source it includes some kind of copper containing rocks, preferably calcantite, credrenite, delafossite, or pysanite.
25. The preparation as claimed in claim 1, characterized in that as a zinc source it includes some kind of zinc containing rocks, preferably zincite, franklinite, hataerolite, matraite, scholzite, willemite or gaslarite.
26. The preparation as claimed in claim 1, characterized in that as a boron source some kind of boron containing rocks preferably borax, boracite, colemanite, inyotite, priceite, warwicite or sassoline is included.
27. The preparation as claimed in claim 1, characterized in that as a gallium source some kind of gallium containing rocks is included, preferably gallite.
28. The preparation as claimed in claim 1, characterized in that as a lithium source some kind of lithium containing rocks are included, preferably trifiline.
29. The preparation as claimed in claim 1 , characterized in that as a cobalt source some kind of cobalt containing rocks, preferably spherocobaltite is included.
30. The preparation as claimed in claim 1, characterized in that as a titanium source some kind of titanium containing rocks, preferably armalcolite, geikielite or ilmenite is included.
31. The preparation as claimed in claim 1, characterized in that as an iron source some kind of iron containing rocks, preferably ilmenite, trifiline, cubanite, heterosite, melonterite, rosenite, strengite, somolnokite, vivianite or pisanite is included.
32. The preparation as claimed in claim 1, characterized in that as a plant extract containing biocide and/or repellent active ingredient, the extract of plants containing pesticide such as bactericide, viricide, insecticide, fungicide, miticide or vermicide or repellent materials are included.
33. The preparation as claimed in claim 1, characterized in that as a plant extract containing biolcide and/or repellent active ingredient, the extract of the following plants is included: mustard, wormwood, chamomile, marigold, thyme, horsetail, sage, lavender, nettle, rhubarb, cselery borago, walnut, paprika, cress, quince, mallow, ricinus, hippophae, rose, black radish, tansy, lavender, caraway, buckwheat, St. John's wort, horse radish, plaintain, anise, aloe, normal mallow, bidens and/or garlic.
34. The preparation as claimed in claim 1, characterized in that it includes some kind of an inorganic or organic acid not harming the plants.
35. The preparation as claimed in claim 34, characterized in that as an acid it includes phosphoric acid, lactic acid, citric acid, malic acid, tartaric acid or acetic acid.
36. The preparation as claimed in claim 1, characterized in that it includes one or more vitamins and/or plant hormons.
37. The preparation as claimed in claim 36, characterized in that as a vitamins it includes thyamine-hydrochloride, aneurine, pyridoxine and/or nicotin acid and as phytohormons auxines, giberrelines, cytokinins, abscisic acid and/or ethylene.
38. A process to produce preparations serving as nutrient source for plants and capable of reducing and tolerating the heavy metal and isotope absorption of plants and repairing the injuries caused by them, as well as for reducing the pesticide volume, characterized in that to the biocide effect plant extract or to the mixture of extracts of many biocide effects plants, the salts and/or complexes of macro and micro elements selected according to the purpose to be achieved and/or the rock(s) crushed as necessary and containing these materials, followed by the supplementing of the mixture in the desired case by one or more phytohormon and/or vitamin and/or inorganic or organic acid and if necessary by a suspending material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU10746/95A AU1074695A (en) | 1993-10-21 | 1994-10-21 | Preparations providing a nutrient source for plants and a process for making such preparations |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HU9302976A HU9302976D0 (en) | 1993-10-21 | 1993-10-21 | Plains foodelementsource and heavy-metal and isotope-intake using produces and process for producing it |
HUP9302976 | 1993-10-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995011205A1 true WO1995011205A1 (en) | 1995-04-27 |
Family
ID=10984076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/HU1994/000045 WO1995011205A1 (en) | 1993-10-21 | 1994-10-21 | Preparations providing a nutrient source for plants and a process for making such preparations |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU1074695A (en) |
HU (1) | HU9302976D0 (en) |
WO (1) | WO1995011205A1 (en) |
Cited By (15)
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EP0795526A3 (en) * | 1996-03-14 | 1998-11-11 | Brill, Holger, Dr. rer. nat. | Fertiliser |
EP1103535A3 (en) * | 1999-11-24 | 2001-11-21 | Iwao Takeda | Fertilizer containing polyphosphate-metal chelates |
ES2165749A1 (en) * | 1998-02-03 | 2002-03-16 | Outspan Int Ltd | Fruit fly-controlling composition and its production and method for controlling fruit fly and device therefor |
EP1634500A3 (en) * | 1998-07-28 | 2006-08-09 | Ecosmart Technologies Inc. | Synergistic and residual pesticidal compositions containing plant essentials oils |
US7250175B2 (en) | 1998-07-28 | 2007-07-31 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
EP1779728A3 (en) * | 1998-07-28 | 2007-09-05 | EcoSmart Technologies Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
WO2009078691A1 (en) * | 2007-12-19 | 2009-06-25 | Mezclas Y Fertilizantes, S.A. De C.V. | Liquid fertiliser composition |
EP2048956A4 (en) * | 2006-07-27 | 2012-09-05 | Vegano Aps | Organic herbicide and method for manufacturing |
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EP0795526A3 (en) * | 1996-03-14 | 1998-11-11 | Brill, Holger, Dr. rer. nat. | Fertiliser |
ES2165749A1 (en) * | 1998-02-03 | 2002-03-16 | Outspan Int Ltd | Fruit fly-controlling composition and its production and method for controlling fruit fly and device therefor |
US7537777B2 (en) | 1998-07-28 | 2009-05-26 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
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EP1779730A3 (en) * | 1998-07-28 | 2007-09-05 | EcoSmart Technologies Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
EP1779729A3 (en) * | 1998-07-28 | 2007-09-05 | EcoSmart Technologies Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
US7320966B2 (en) | 1998-07-28 | 2008-01-22 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
US7351420B2 (en) | 1998-07-28 | 2008-04-01 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
US7361366B2 (en) | 1998-07-28 | 2008-04-22 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
US7618645B2 (en) | 1998-07-28 | 2009-11-17 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
US7531189B2 (en) | 1998-07-28 | 2009-05-12 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
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EP1103535A3 (en) * | 1999-11-24 | 2001-11-21 | Iwao Takeda | Fertilizer containing polyphosphate-metal chelates |
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WO2009078691A1 (en) * | 2007-12-19 | 2009-06-25 | Mezclas Y Fertilizantes, S.A. De C.V. | Liquid fertiliser composition |
CN104250174A (en) * | 2014-09-04 | 2014-12-31 | 李晓枫 | Composite organic fertilizer and preparation method thereof |
WO2018192591A1 (en) * | 2017-04-21 | 2018-10-25 | Corporacion Universidad De La Costa Cuc | Natural, organic insecticide formed by extracts of chilli pepper and nettle plant and method for obtaining same |
US10743535B2 (en) | 2017-08-18 | 2020-08-18 | H&K Solutions Llc | Insecticide for flight-capable pests |
US11589599B2 (en) | 2018-05-08 | 2023-02-28 | Icl Europe Cooperatief U.A. | Polyhalite enriched animal feed |
WO2019215724A1 (en) * | 2018-05-08 | 2019-11-14 | Dead Sea Works Ltd. | Polyhalite enriched animal feed |
US11864568B2 (en) | 2018-05-08 | 2024-01-09 | Icl Europe Cooperatief U.A. | Polyhalite enriched animal feed |
WO2021163809A1 (en) | 2020-02-21 | 2021-08-26 | Ostara Nutrient Recovery Technologies Inc. | Slow-release potassium and sulfur fertilizer and methods for making same |
RU2799017C1 (en) * | 2022-06-23 | 2023-06-30 | Евгений Григорьевич НИКОЛАЕВ | Means for increasing the yield and quality of agricultural crops |
CN116473073A (en) * | 2023-05-08 | 2023-07-25 | 广东方中高新材料有限公司 | Pyraclostrobin synergistic suspension preparation containing gallium complex and preparation method thereof |
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HU9302976D0 (en) | 1994-01-28 |
AU1074695A (en) | 1995-05-08 |
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