[go: up one dir, main page]

WO1995011205A1 - Preparations providing a nutrient source for plants and a process for making such preparations - Google Patents

Preparations providing a nutrient source for plants and a process for making such preparations Download PDF

Info

Publication number
WO1995011205A1
WO1995011205A1 PCT/HU1994/000045 HU9400045W WO9511205A1 WO 1995011205 A1 WO1995011205 A1 WO 1995011205A1 HU 9400045 W HU9400045 W HU 9400045W WO 9511205 A1 WO9511205 A1 WO 9511205A1
Authority
WO
WIPO (PCT)
Prior art keywords
preparation
source
plants
calcium
soluble
Prior art date
Application number
PCT/HU1994/000045
Other languages
French (fr)
Inventor
Ferenc KÖRÖSI
Elzbieta JEZIERSKA-SZABÓ
Béla ILLÉS
Zoltán Tóth
Original Assignee
Ponton Kft.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10984076&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1995011205(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ponton Kft. filed Critical Ponton Kft.
Priority to AU10746/95A priority Critical patent/AU1074695A/en
Publication of WO1995011205A1 publication Critical patent/WO1995011205A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G1/00Mixtures of fertilisers belonging individually to different subclasses of C05
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

Definitions

  • the invention relates to preparations serving as a nutrient source of plants and for reducing heavy metal and isotope absorption and tolerating injuries brought about by them as well as for reducing the pesticide requirement and a process for the preparation thereof.
  • pollutants such as heavy metals and acid rain generating gases are introduced into the environment, polluting the lithosphere, the hydrosphere and the atmosphere.
  • the pollutants are introduced through the feeding chain into the human and animal bodies, possibly leading to poisoning and related diseases.
  • radio nuclides are introduced into the biosphere.
  • the ones with a long half-period, such as Sr-90 and Cs-137 could cause radiation diseases for many thousands of years.
  • the basis for the invention is the recognition that if the soluble salts and/or complexes of macro and/or micro elements important from a physiologic aspect are applied to the plants or their environment together with the extract of plants containing biocide and/or repellent ingredient, the disadvantages mentioned above can be avoided or mitigated.
  • Macro-elements important for physiological processes are the chemical elements such as C, 0, N, H, P, K, Ca, Mg, S, Si, Na, Cl, Fe and Al occurring in a relatively large quantity in the organic structures of all living creatures.
  • Physiologically important micro-elements are the chemical elements existing in a very low quantity in the organizations of living creatures, the lack of which, however, causes functional troubles, or toxicity if they are present in a volume higher than required, such as B, Zn, Cu, Mn, Ti, Li, F, Br, Ni, Rb, Sn, Sr, Ba.
  • Macro and micro elements may also be applied partly or fully in the form of rocks containing such elements.
  • the subject of the invention covers the preparations serving as a nutrient source for plants, in addition to reducing and helping to tolerate the heavy metal and isotope absorption while decreasing the pesticide volume needed.
  • the active ingredients of these preparations are the soluble salts and/or complexes of physiologically important macro and/or micro elements and/or the rocks containing such materials and the extract of plants containing biocide and/or repellent active ingredient.
  • We have also found that the impact of preparations can be improved in a target-oriented way, by adding inorganic or organic acids, phytohormons and/or vitamins.
  • the macro and micro elements of the preparation embodied by the invention are selected according to the requirements of the plants to be treated, as well as taking into consideration the demand of animals and human beings.
  • the various elements can be applied in the form of their soluble salts and/or complexes.
  • As a complex especially favourable use can be made of chelates.
  • ammonium nitrate or ammonium sulphate can be used as a nitrogen source.
  • a percentage by weight of 0.01 to 40 is adjusted.
  • mono-ammonium-phosphate or super ⁇ phosphate (the mixture of calcium phosphate and calcium phosphate) may be applied, when converting the total phosphorus concentration of the preparation to elementary phosphorus, a per cent by weight of 0.01 to 40 is adjusted.
  • potassium source potassium sulphate, potassium nitrate, potassium acetate, potassium ammonium nitrate or potassium chloride can be used, when converting the total potassium concentrate of the prepration to elementary potassium, a per cent by weight of 0.01 to 40 is adjusted.
  • calcium source calcium nitrate, calcium hydrogen phosphate, calcium pyro-phosphate, calcium magnesium carbonate, calcium glyconate, calcium citrate and calcium lactate are identified, when converting the total calcium concentration of the preparation to elementary calcium, the per cent by weight is 0.01 to 20.
  • magnesium sulphate, magnesium carbonate or calcium-magnesium carbonate may be used, when the total magnesium concentration of the preparation converted to elementary magnesium is a percentage by weight of 0.01 to 20.
  • a suitable manganese source is manganese sulphate, manganese metaborate, manganese-nitrate, manganese-chelates, when converting the total manganese concentration of the preparation to elementary manganese, the percentage by weight is 0.005-30.0.
  • a molibdenum source ammonium molibdenate can be applied, when converting the total molibdenum concentration of the preparation to elementary molibdenum, the percent by weight is 0.001 to 10.
  • a suitable copper source is copper ( II ) sulphate , copper (II) nitrate, copper (II) acetate or copper-amine complexes, copper (II) amine-sulphate, and when converting the total copper concentration of the preparation to elementary copper, the per cent by weight is 0.001 to 10.
  • zinc sulphate and zinc-amine complexes are described, when converting the total zinc concentration of the preparation to elementary zinc, the per cent by weight is 0.05 to 20.
  • boric acid or borax may be used, when converting the total boron concentration of the preparation to elementary boron, the per cent by weight is 0.05-10.
  • a suitable gallium source is gallium chloride and when converting the total gallium concentration to elementary gallium, the per cent by weight is 0.01 to 10.
  • a lithium source lithium nitrate can be used, when the total lithium concentration of the preparation converted to elementary lithium is a percentage by weight of 0.005 to 4.
  • cobalt carbonate and cobalt chlorite can be used, when the total cobalt concentration of the preparation converted to elementary cobalt is a per cent by weight of 0.05 to 4.
  • a suitable titanium source is titanium dioxide, which is taken into solution in the form of colloide, or titanium sulphate, when the total titanium concentration of the preparation converted to elementary titanium is a per cent by weight of 0.001 to 10.
  • iron(III)sulphate or iron-chelates can be used, when the total iron concentration of the preparation converted to elementary iron is a percentage by weight of 0.005 to 30.
  • Certain salts and complexes may serve simultaneously as the source of several macro and micro elements.
  • superphosphate is simultaneously a calcium, magnesium and phosphorus source
  • ammonium molibdenate is a nitrogen and molibdenum source
  • certain nitrates are not only metal but also nitrogen sources.
  • nitro calcite or strewite as a phosphorus source, fluor apatite, isokite, brushite, kutnohorite, or phosphorit, as a potassium source, potassium nitrate, kanelite, cryptomelane, langbeinit, kainite or polyhalite can be used.
  • a calcium source the following are appropriate: dolomite, akermanite, andradite, brushite, monetite, alstonite, aragonite, rezaite, herderite, huntite, kalcite.
  • laitarite monticellite, oldhamite, perovskite, polyhalite, powellite, scholzite, or fairfieldite
  • magnesium source dolomite, ankerite, epsomite, magnesite, pentahydrite, armalcolite, bischofite, faheyite, geikielite, kieserite, kutnahorite, polyhalite, todorokite or strewite
  • the following can be applied: mallardite, ludlamite, graphtonite, jakobsite, kutnahorite, pyrophanite, smikite, or crednerite.
  • Suitable molibdenum sources are molibdenite, powellite, or drysdallite, a copper source is kalkantite, crednerite, delafossite and pisanite, and zinc source is zincite, franklinite, hetaerolite, matraite. scholzite, willemite, and gaslarite.
  • borax As a boron source, borax, boracite, colemanite, inyoite, priceite, warwikite and sassoline, as a gallium source gallite, as a lithium source trifiline, as a cobalt source sphero cobaltite and as a titanium source ilmenite, armalcolite or geikielite may be used.
  • iron source As an iron source, ilmenite, trifiline, cubanite, heterosite, melonteritote, rosenitote, strengite, somolnokite, vivanite or pisanite may be applied.
  • a sitable stroncium source is celestite and stroncianite.
  • Plants containing biocide and/or repellent active ingredient are plants which contain pesticide, such as bactericide, viricide, insecticide, fungicide, miticide or vermicide or repellent materials.
  • Plant extracts applicable as components of the preparations embodied by the invention are available from trade or they can be produced by extraction, vapour distillation and/or pressing of the plant organs containing the active ingredient, for example the flower, leaves, root, berries or seed.
  • the plant extracts available from trade include the active ingredients of one or more plants.
  • Such abstracts are for example the products marketed under the names Aromex and Fresta.
  • Extraction may be carried out by an organic extracting agent, for example by alcohol, some kind of an oil or acid or by the mixtures of these.
  • an organic extracting agent for example by alcohol, some kind of an oil or acid or by the mixtures of these.
  • the effect of the preparations embodied by the invention may be enhanced by adding inorganic or organic acids, phytohormons and/or vitamins.
  • Such inorganic or organic acids can be used which do not harm the plants in the concentration applied.
  • a further advantage of using inorganic or organic acids is that they shift the pH rate of the preparation to the acid range, and as a result the nutrient absorption of plants to be treated is enhanced.
  • An inorganic acid that can be applied beneficially is phosphoric acid, while as an organic acid, lactic acid, citric acid, malic acid, butanedioic acid, acetic acid etc. can be applied.
  • phytohormons and vitamins are also boosting agents.
  • phytohormons it is advantageous to use auxins, gibberellines, cytokinins, abscisic acid and ethylene.
  • vitamins advantageous use can be made of thiamine- hydrochloride, aneurin, pyridoxine and nicotine acid. The quantity of these materials amounts to between 1 ⁇ g and 50 g per one litre of the preparation.
  • suspending agent such as bentonite, alginite or vinace is added.
  • the latter materials partly improve the viscosity of the preparation and partly increase the active colloide surface of the preparation.
  • the retarded effect of the preparation is ensured by the absorbed cations on the surface of the colloides.
  • the accurate composition of the preparation embodied by the invention is selected according to the objective to be accomplished. If the preparation is used as a plant nutrient, through their application the mineral content of plants can be increased in a target-oriented way, meaning the iron, calcium, magnesium, copper, selenium or zinc content. In this way, in addition to increasing the plant yield, it better corresponds to the mineral requirement of the person or the animal species to be fed.
  • vegetables and fruit with a high iron content can be produced. This can be achieved by spraying the vegetables and fruit with a high iron content preparation.
  • Lucern intended to feed high milking capacity cattle for example is sprayed with a high calcium and magnesium preparation and so the fodder will also have a higher calcium and magnesium content.
  • the preparation embodied by the invention is intended for reducing and tolerating the heavy metal absorption of plants
  • first soil and plant analysis is carried out, i.e. it is determined what heavy metals are present, and in which concentration and form. In the knowledge of these factors is the composition selected and such a preparation is produced which has a high calcium and magnesium content and a significant micro-element content.
  • the plant organs above the soil are saturated with calcium, magnesium and micro elements, thereby antagonizing (reducing) the absorption of heavy metals and facilitating the toleration of the plant.
  • the micro elements phytohormons and/or vitamins in the preparation boost the enzyme activities of the plants, thereby contributing to tolerating heavy metal pollution.
  • the preparation embodied by the invention is designed to reduce and tolerate isotope absorption by the plants, again soil and plant analysis precedes the selection of composition.
  • the concentration of the stable forms of polluting isotope(s) or that of the antagonist isotopes we increase in the preparation the concentration of the stable forms of polluting isotope(s) or that of the antagonist isotopes.
  • concentration of calcium and magnesium and also that of stable stroncium in the case of Cs-137 the concentration of potassium, calcium and magnesium and in the case of J-131 that of stable iodine is increased.
  • the salts and/or complexes of macro and micro elements selected according to the purpose to be achieved are added, and then the mixture is supplemented as required by one or more phytohormon and/or vitamin and/or inorganic or organic acid and if necessary also by a suspending agent.
  • the macro and micro elements are used in the form of rocks, one or more rocks selected on the basis of its nutrient content are crushed to 1 nm - 10 mm size, and this is added to the plant extract(s) of biocide effect. If only a part of the macro and micro elements is applied in the form of rocks, the lacking nutrients are supplied by their salts or complexes.
  • Producing foliar fertilizer serving as a nutrient source The water, alcohol or oil based extracts of the following plants are mixed:
  • Thyme oil (oleum thymi) 0.50 litres nettle 3.00 litres pyretrum extract 1.50 litres nicotine 0.50 litres quassia chips 0.50 litres vinace 2.00 litres
  • the mixture is diluted to 100 litres by water, and then the following components are added into a 20-litre volume of the compound, while performing agitation:
  • the volume of the mixture is made up to 100 litres, by means of the compound consisting of plant extracts.
  • the foliar fertilizer concentrate so obtained can be used for supplementing the N, P, . K, Ca, Mg, Fe, Cu , Mn and B nutrients of plants.
  • the mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound while agitating:
  • the volume of the mixture is made up to 100 litres, with the compound consisting of plant extracts.
  • the so obtained foliar fertilizer concentrate By diluting to 0.01 to 30 per cent by volume the so obtained foliar fertilizer concentrate, it can be used for supplementing the N, P, K. Ca, Mg, Fe, Mn and B nutrients of plants and for reducing the zinc absorption and tolerate the excess zink taken up.
  • Example 3 Producing a foliar fertilizer aimed at reducing the absorption of Sr-85 and Sr-90 isotopes and for rehabilitating damage caused by radiation.
  • the mixture is diluted to 100 litres of water and then the following components are added to a volume of 20 litres of this compound, while agitating:
  • the volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
  • the foliar fertilizer concentrate so obtained, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of Sr isotopes.
  • the mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound, while agitating:
  • volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
  • the foliar fertilizer concentrate so obtained By diluting the foliar fertilizer concentrate so obtained, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of Cs isotopes.
  • the mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound, while agitating: superphosphate 20.00 kg potassium sulphate 15.00 kg calcium nitrate 25.00 kg copper tetramine complex 1.00 kg magnesium sulphate 15.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg potassium iodide 1.50 kg iodine 0.75 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
  • volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
  • the foliar fertilizer concentrate so obtained By diluting the foliar fertilizer concentrate so obtained to 0.01 to 10 per cent by volume, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of iodine isotope.
  • Vitamin B2 1.0 g
  • Vitamin B6 2.0 g
  • the plants make better use of the nutrients in the preparation so obtained, and through the application of this mixture, the repairing and recovery processes of poisoning by heavy metal absorption and radiation damage are accelerated in plants.
  • the nutrients of the preparation so obtained are better utilized by the plants, and through its application the reparation processes of plants as a result of poisoning by heavy metal absorption and radiation damage are accelerated.
  • Vitamin Bl 0.5 g
  • Vitamin B2 1.0 g
  • Vitamin B6 2.0 g ⁇ -indolil-acetic acid 5.0 g gibberelline (GA 10 ) 20.0 g nicotine acid 1.0 g kinetine 3.0 g
  • the nutrients of the preparation so obtained are better utilized by the plants, and through its application the repairing processes of plants as a result of poisoning by heavy metal absorption and radiation damage are accelerated.
  • This mixture is diluted to 100 litres by water, and then the following crushed rocks are added to a 20-litre volume of the compound, while agitating:
  • the preparation so produced is diluted to 0.1 to 50 per cent by volume, it can be used for supplementing the N, P,
  • the wheat variety Mv 16 was treated in 2-3 leaf condition with the preparation as per example 1, diluted to 1 %, 5 % and 10 % concentration (A, B, C) .
  • untreated plants were used.
  • the wheat variety Mv 15, was treated in 2-3 leaf condition with a preparation as per example 10, diluted 1%, 5% and 10% concentration (A, B, C) .
  • a preparation as per example 10 diluted 1%, 5% and 10% concentration (A, B, C) .
  • A, B, C diluted 1%, 5% and 10% concentration
  • Tomato berries in green phenological state were treated with preparation A as per example 7, diluted to 10 %, and then in ripe phenological condition we have also determined the nutrient content of the berries.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Agronomy & Crop Science (AREA)
  • Fertilizers (AREA)

Abstract

The invention covers preparations serving as nutrient source of plants and for reducing and tolerating their heavy metal and isotope absorption, as well as for reducing the pesticide volume and also the procedure of turning out such products. As active ingredient, the preparations contain the soluble salts and/or complexes of physiologically important macro and/or micro elements and/or the rocks containing such materials and the abstract of plants containing biocide and/or repellent active ingredient.

Description

Preparations providing a nutrient source for plants and a process for making such preparations
TECHNICAL FIELD
The invention relates to preparations serving as a nutrient source of plants and for reducing heavy metal and isotope absorption and tolerating injuries brought about by them as well as for reducing the pesticide requirement and a process for the preparation thereof.
BACKGROUND ART
It is well known that in agriculture some preparations containing nutrients to improve the yield are used, such as organic manure, fertilizers, foliar fertilizers as well as large quantities of pesticides which are applied to the plants or their environment, in order to eradicate pests and parasites. Of these preparations, those containing synthetic active ingredients have numerous side-effects in addition to the desired impact. For example the application of large quantities of fertilizers containing nitrogen, phosphorus and potassium may lead to deficiency symptoms reflecting the lack of micro-elements in plants (S. Kiss: Magnesium fertilizers, magnesium in biology. Agricultural Publishing House, Budapest 1983. W. Bergmann: Occurrence and recognizing of nutrition disturbances in cultivated plants, Agricultural Publishing House, Budapest 1979) . This - in addition to retarding the development and growth of plants - also results in the plant generating less growth and development factors (amino-acid, vitamins and enzimes) so important for the human and animal body. Besides, residuals of pesticides may cause different grades and manifestations of poisoning in humans and animals, and they are also the cause of polluting the soil and natural waters.
One of the detrimental side-effects of industrial production is that various pollutants such as heavy metals and acid rain generating gases are introduced into the environment, polluting the lithosphere, the hydrosphere and the atmosphere. The pollutants are introduced through the feeding chain into the human and animal bodies, possibly leading to poisoning and related diseases.
In the operational breakdowns of nuclear power stations or upon experimental nuclear explosions, radio nuclides are introduced into the biosphere. Of these, the ones with a long half-period, such as Sr-90 and Cs-137 could cause radiation diseases for many thousands of years.
Consequently, approaches and preparations are required by which the nutrient demand of plants, animals and people can be met without detrimental side-effects, while reducing the quantity of pesticides applied, along with the heavy metal and isotope absorption of plants, and facilitating repairing and recovery possesses.
The basis for the invention is the recognition that if the soluble salts and/or complexes of macro and/or micro elements important from a physiologic aspect are applied to the plants or their environment together with the extract of plants containing biocide and/or repellent ingredient, the disadvantages mentioned above can be avoided or mitigated.
Macro-elements important for physiological processes are the chemical elements such as C, 0, N, H, P, K, Ca, Mg, S, Si, Na, Cl, Fe and Al occurring in a relatively large quantity in the organic structures of all living creatures.
Physiologically important micro-elements are the chemical elements existing in a very low quantity in the organizations of living creatures, the lack of which, however, causes functional troubles, or toxicity if they are present in a volume higher than required, such as B, Zn, Cu, Mn, Ti, Li, F, Br, Ni, Rb, Sn, Sr, Ba.
Macro and micro elements may also be applied partly or fully in the form of rocks containing such elements.
DISCLOSURE OF THE INVENTION
The subject of the invention covers the preparations serving as a nutrient source for plants, in addition to reducing and helping to tolerate the heavy metal and isotope absorption while decreasing the pesticide volume needed. The active ingredients of these preparations are the soluble salts and/or complexes of physiologically important macro and/or micro elements and/or the rocks containing such materials and the extract of plants containing biocide and/or repellent active ingredient. We have also found that the impact of preparations can be improved in a target-oriented way, by adding inorganic or organic acids, phytohormons and/or vitamins.
The macro and micro elements of the preparation embodied by the invention are selected according to the requirements of the plants to be treated, as well as taking into consideration the demand of animals and human beings.
The various elements can be applied in the form of their soluble salts and/or complexes. As a complex, especially favourable use can be made of chelates.
As the source of macro and micro elements, the following compounds are listed as examples.
As a nitrogen source, ammonium nitrate or ammonium sulphate can be used. In relation to elementary nitrogen, a percentage by weight of 0.01 to 40 is adjusted.
As a phosphorus source, mono-ammonium-phosphate or super¬ phosphate (the mixture of calcium phosphate and calcium phosphate) may be applied, when converting the total phosphorus concentration of the preparation to elementary phosphorus, a per cent by weight of 0.01 to 40 is adjusted.
As a potassium source, potassium sulphate, potassium nitrate, potassium acetate, potassium ammonium nitrate or potassium chloride can be used, when converting the total potassium concentrate of the prepration to elementary potassium, a per cent by weight of 0.01 to 40 is adjusted. As a calcium source, calcium nitrate, calcium hydrogen phosphate, calcium pyro-phosphate, calcium magnesium carbonate, calcium glyconate, calcium citrate and calcium lactate are identified, when converting the total calcium concentration of the preparation to elementary calcium, the per cent by weight is 0.01 to 20.
As a magnesium source, magnesium sulphate, magnesium carbonate or calcium-magnesium carbonate may be used, when the total magnesium concentration of the preparation converted to elementary magnesium is a percentage by weight of 0.01 to 20.
A suitable manganese source is manganese sulphate, manganese metaborate, manganese-nitrate, manganese-chelates, when converting the total manganese concentration of the preparation to elementary manganese, the percentage by weight is 0.005-30.0. As a molibdenum source, ammonium molibdenate can be applied, when converting the total molibdenum concentration of the preparation to elementary molibdenum, the percent by weight is 0.001 to 10.
A suitable copper source is copper ( II ) sulphate , copper (II) nitrate, copper (II) acetate or copper-amine complexes, copper (II) amine-sulphate, and when converting the total copper concentration of the preparation to elementary copper, the per cent by weight is 0.001 to 10.
As a zinc source, zinc sulphate and zinc-amine complexes are described, when converting the total zinc concentration of the preparation to elementary zinc, the per cent by weight is 0.05 to 20.
As a boron source, boric acid or borax may be used, when converting the total boron concentration of the preparation to elementary boron, the per cent by weight is 0.05-10.
A suitable gallium source is gallium chloride and when converting the total gallium concentration to elementary gallium, the per cent by weight is 0.01 to 10. As a lithium source, lithium nitrate can be used, when the total lithium concentration of the preparation converted to elementary lithium is a percentage by weight of 0.005 to 4.
As a cobalt source, cobalt carbonate and cobalt chlorite can be used, when the total cobalt concentration of the preparation converted to elementary cobalt is a per cent by weight of 0.05 to 4.
A suitable titanium source is titanium dioxide, which is taken into solution in the form of colloide, or titanium sulphate, when the total titanium concentration of the preparation converted to elementary titanium is a per cent by weight of 0.001 to 10.
As an iron source, iron(III)sulphate or iron-chelates can be used, when the total iron concentration of the preparation converted to elementary iron is a percentage by weight of 0.005 to 30.
Certain salts and complexes may serve simultaneously as the source of several macro and micro elements. Thus for example superphosphate is simultaneously a calcium, magnesium and phosphorus source, ammonium molibdenate is a nitrogen and molibdenum source, and certain nitrates are not only metal but also nitrogen sources.
If the necessary elements are used in the form of rocks, as examples the following are listed.
As a nitrogen source, nitro calcite or strewite, as a phosphorus source, fluor apatite, isokite, brushite, kutnohorite, or phosphorit, as a potassium source, potassium nitrate, kanelite, cryptomelane, langbeinit, kainite or polyhalite can be used. As a calcium source, the following are appropriate: dolomite, akermanite, andradite, brushite, monetite, alstonite, aragonite, fassaite, herderite, huntite, kalcite. laitarite, monticellite, oldhamite, perovskite, polyhalite, powellite, scholzite, or fairfieldite, as a magnesium source dolomite, ankerite, epsomite, magnesite, pentahydrite, armalcolite, bischofite, faheyite, geikielite, kieserite, kutnahorite, polyhalite, todorokite or strewite, while as a manganese source, the following can be applied: mallardite, ludlamite, graphtonite, jakobsite, kutnahorite, pyrophanite, smikite, or crednerite.
Suitable molibdenum sources are molibdenite, powellite, or drysdallite, a copper source is kalkantite, crednerite, delafossite and pisanite, and zinc source is zincite, franklinite, hetaerolite, matraite. scholzite, willemite, and gaslarite.
As a boron source, borax, boracite, colemanite, inyoite, priceite, warwikite and sassoline, as a gallium source gallite, as a lithium source trifiline, as a cobalt source sphero cobaltite and as a titanium source ilmenite, armalcolite or geikielite may be used.
As an iron source, ilmenite, trifiline, cubanite, heterosite, melonteritote, rosenitote, strengite, somolnokite, vivanite or pisanite may be applied.
A sitable stroncium source is celestite and stroncianite.
Plants containing biocide and/or repellent active ingredient are plants which contain pesticide, such as bactericide, viricide, insecticide, fungicide, miticide or vermicide or repellent materials.
As examples for such plants, the following are mentioned: mustard (Brassica juncea Czern.) absinth (Artemisia absinthium L.) , chamomile (Matricaria chamomilla L.) , calendula (Calendula officinalis L.), thyme (Thy us vulgaris L.), horsetail (Ephedra equisetine Bge.), borago (Borago officinalis L.), caraway (Caru carvi L.), black radish (Raphanus sativum) , quince (Cydonia oblonga Mill.), rose (Rosa L.), sage (Lepidium sativum L.), walnut (Juglans regia L.), ricinus (Ricinus communis L.) paprika (Capsicum annua L.), mallow (Althaea officinalis L.) , hyppophae (Hyppophae rhamnoides L.), celery (Apium gravedens L.), normal sage (Salvia officinalis L.), bidens (Bidens tripartitus L.), abutilon (Abutilon Adans) , chrysanthenum (Chrysenthenum vulgare L. , Phyrethrum Bois. ) , lavender (Lavendula officinalis L.), buckwheat (Fagopyrum Geartu.), St.John's wort (Hypericum perforatum) , horse radish (Verbascum thapsiforme) , plantain (Plantago major L.) , anise (Pimpinella anisum L.), aloe (Aloe arborescens Mill.), rhubarb (Rhenum officinale) , garlic (Alliu sativum L.), nettle (Urtica dioica L.).
Plant extracts applicable as components of the preparations embodied by the invention are available from trade or they can be produced by extraction, vapour distillation and/or pressing of the plant organs containing the active ingredient, for example the flower, leaves, root, berries or seed.
The plant extracts available from trade include the active ingredients of one or more plants. Such abstracts are for example the products marketed under the names Aromex and Fresta.
Extraction may be carried out by an organic extracting agent, for example by alcohol, some kind of an oil or acid or by the mixtures of these. As mentioned above, the effect of the preparations embodied by the invention may be enhanced by adding inorganic or organic acids, phytohormons and/or vitamins.
Such inorganic or organic acids can be used which do not harm the plants in the concentration applied.
A further advantage of using inorganic or organic acids is that they shift the pH rate of the preparation to the acid range, and as a result the nutrient absorption of plants to be treated is enhanced.
An inorganic acid that can be applied beneficially is phosphoric acid, while as an organic acid, lactic acid, citric acid, malic acid, butanedioic acid, acetic acid etc. can be applied.
Phytohormons and vitamins are also boosting agents. As phytohormons, it is advantageous to use auxins, gibberellines, cytokinins, abscisic acid and ethylene. As vitamins, advantageous use can be made of thiamine- hydrochloride, aneurin, pyridoxine and nicotine acid. The quantity of these materials amounts to between 1 μg and 50 g per one litre of the preparation.
For the preparations embodied by the invention, if necessary suspending agent such as bentonite, alginite or vinace is added. The latter materials partly improve the viscosity of the preparation and partly increase the active colloide surface of the preparation. The retarded effect of the preparation is ensured by the absorbed cations on the surface of the colloides.
The accurate composition of the preparation embodied by the invention is selected according to the objective to be accomplished. If the preparation is used as a plant nutrient, through their application the mineral content of plants can be increased in a target-oriented way, meaning the iron, calcium, magnesium, copper, selenium or zinc content. In this way, in addition to increasing the plant yield, it better corresponds to the mineral requirement of the person or the animal species to be fed.
To supply pregnant women and small children, for example, vegetables and fruit with a high iron content can be produced. This can be achieved by spraying the vegetables and fruit with a high iron content preparation.
Lucern intended to feed high milking capacity cattle for example is sprayed with a high calcium and magnesium preparation and so the fodder will also have a higher calcium and magnesium content.
If the preparation embodied by the invention is intended for reducing and tolerating the heavy metal absorption of plants, first soil and plant analysis is carried out, i.e. it is determined what heavy metals are present, and in which concentration and form. In the knowledge of these factors is the composition selected and such a preparation is produced which has a high calcium and magnesium content and a significant micro-element content. When plants are sprayed with such a preparation, the plant organs above the soil are saturated with calcium, magnesium and micro elements, thereby antagonizing (reducing) the absorption of heavy metals and facilitating the toleration of the plant. The micro elements phytohormons and/or vitamins in the preparation boost the enzyme activities of the plants, thereby contributing to tolerating heavy metal pollution.
If the preparation embodied by the invention is designed to reduce and tolerate isotope absorption by the plants, again soil and plant analysis precedes the selection of composition. Once this information is gathered, we can increase in the preparation the concentration of the stable forms of polluting isotope(s) or that of the antagonist isotopes. Thus, for example in the case of Sr-90, we increase the concentration of calcium and magnesium and also that of stable stroncium, in the case of Cs-137 the concentration of potassium, calcium and magnesium and in the case of J-131 that of stable iodine is increased. At the same time, we also enhance the concentration of elements able to change their valence (e.g. copper, manganese, iron) and B-vitamins and phytohormons to encourage the processes of rerairing and recovering the damage caused by radiation.
The plant extracts applied in the preparations embodied by the invention - in addition to exerting a biocide effect themselves, thus reducing the necessary quantity of other pesticides, also assist the nutrient uptake of plants.
The preparations embodied by the invention are produced in the following way.
To the biocide effect plant extract or to the mixture of multi biocide effect plant extracts, the salts and/or complexes of macro and micro elements selected according to the purpose to be achieved are added, and then the mixture is supplemented as required by one or more phytohormon and/or vitamin and/or inorganic or organic acid and if necessary also by a suspending agent.
If the macro and micro elements are used in the form of rocks, one or more rocks selected on the basis of its nutrient content are crushed to 1 nm - 10 mm size, and this is added to the plant extract(s) of biocide effect. If only a part of the macro and micro elements is applied in the form of rocks, the lacking nutrients are supplied by their salts or complexes.
DETAILED DESCRIPTION OF EXAMPLES
The invention is demonstrated by way of the following examples.
Example 1
Producing foliar fertilizer serving as a nutrient source. The water, alcohol or oil based extracts of the following plants are mixed:
marigold 2.00 litres horsetail 5.00 litres sage 10.00 litres
Fresta 1000 2.00 litres
Aromex 0.50 litres
Thyme oil (oleum thymi) 0.50 litres nettle 3.00 litres pyretrum extract 1.50 litres nicotine 0.50 litres quassia chips 0.50 litres vinace 2.00 litres
The mixture is diluted to 100 litres by water, and then the following components are added into a 20-litre volume of the compound, while performing agitation:
ammonium nitrate 20.00 kg superphosphate 10.00 kg potassium sulphate 20.00 kg calcium nitrate 10.00 kg copper-tetramine-complex 5.00 kg magnesium sulphate 5.00 kg iron (III) sulphate 2.00 kg manganese-sulphate 0.50 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
Finally, the volume of the mixture is made up to 100 litres, by means of the compound consisting of plant extracts.
By diluting to 0.01 to 30 per cent by volume, the foliar fertilizer concentrate so obtained can be used for supplementing the N, P, . K, Ca, Mg, Fe, Cu , Mn and B nutrients of plants.
Example 2
Producing foliar fertilizer for reducing heavy metal absorption.
When producing foliar fertilizer for reducing zinc absorption, the zinc salts and complexes are left out of the nutrients and the calcium, magnesium and micro-element content of the product is increased.
The extracts of the following plants are mixed:
celery 2.00 litres rhubarb 5.00 litres black radish 5.00 litres garlic 5.00 litres lavender 10.00 litres
Fresta 1000 2.00 litres caraway seed 1.50 litres ricinus 1.50 litres vinace 2.00 litres
The mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound while agitating:
ammonium nitrate 20.00 kg superphosphate 10.00 kg potassium sulphate 20.00 kg calcium nitrate 15.00 kg magnesium sulphate 10.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
And finally the volume of the mixture is made up to 100 litres, with the compound consisting of plant extracts.
By diluting to 0.01 to 30 per cent by volume the so obtained foliar fertilizer concentrate, it can be used for supplementing the N, P, K. Ca, Mg, Fe, Mn and B nutrients of plants and for reducing the zinc absorption and tolerate the excess zink taken up.
Example 3 Producing a foliar fertilizer aimed at reducing the absorption of Sr-85 and Sr-90 isotopes and for rehabilitating damage caused by radiation.
The extracts of the following plants are mixed:
chamomile 2.00 litres rhubarb 5.00 litres garlic 10.00 litres
Fresta 1000 2.00 litres
Aromex 1.50 litres horsetail 2.00 litres mustard seed 3.00 litres vinace 5.00 litres
The mixture is diluted to 100 litres of water and then the following components are added to a volume of 20 litres of this compound, while agitating:
superphosphate 20.00 kg potassium sulphate 15.00 kg calcium nitrate 25.00 kg copper tetramine complex 1.00 kg magnesium sulphate 15.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
Finally, the volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts. By diluting the foliar fertilizer concentrate so obtained, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of Sr isotopes.
Example 4
Producing a foliar fertilizer for reducing the absorption of Cs-134 and Cs-137 isotopes.
The extracts of the following plants are mixed:
chamomile 2.00 litres rhubarb 5.00 litres garlic 10.00 litres horse radish 3.00 litres anise 1.00 litres
St John's wort 1.50 litres
Fresta 1000 2.00 litres
Aromex 1.50 litres vinace 5.00 litres
The mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound, while agitating:
superphosphate 20.00 kg potassium sulphate 30.00 kg calcium nitrate 15.00 kg copper tetramine complex 1.50 kg magnesium sulphate 20.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
Finally, the volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
By diluting the foliar fertilizer concentrate so obtained, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of Cs isotopes.
Example 5
Producing a foliar fertilizer for reducing the absorption of J-131 isotope.
The extracts of the following plants are mixed:
chamomile 2.00 litres walnut shell 4.00 litres mallow 2.50 litres black radish 5.00 litres lavender 0.50 litres rhubarb 5.00 litres garlic 10.00 litres
Fresta 1000 2.00 litres
Aromex 1.50 litres vinace 5.00 litres
The mixture is diluted to 100 litres by water, and then the following components are added to a 20-litre volume of the compound, while agitating: superphosphate 20.00 kg potassium sulphate 15.00 kg calcium nitrate 25.00 kg copper tetramine complex 1.00 kg magnesium sulphate 15.00 kg iron(III)sulphate 2.00 kg manganese-sulphate 0.50 kg potassium iodide 1.50 kg iodine 0.75 kg zinc-hexamine complex 0.50 kg ammonium molibdenite 0.01 kg lithium nitrate 0.01 kg borax 1.00 kg bentonite 1.00 kg
Finally, the volume of the mixture is supplemented to 100 litres by the compound consisting of plant extracts.
By diluting the foliar fertilizer concentrate so obtained to 0.01 to 10 per cent by volume, it can be used for supplementing the N, P, K, Ca, Mg, Fe, Cu, Mn and B nutrients of plants and for reducing the absorption of iodine isotope.
Example 6
Producing a foliar fertilizer supplemented with acid.
To 100 litres of the preparation as per example 1, lactic acid of 5 per cent by volume is added.
The preparation so produced facilitates the nutrient absorption of plants, and the active ingredients of plant extracts are activated. Example 7
Producing of foliar fertilizer supplemented with vitamins.
To 100 litres of the preparation as per Example 1, the following vitamins are added:
Vitamin B 10.5 g
Vitamin B2 1.0 g
Vitamin B6 2.0 g
The plants make better use of the nutrients in the preparation so obtained, and through the application of this mixture, the repairing and recovery processes of poisoning by heavy metal absorption and radiation damage are accelerated in plants.
Example 8
Producing of foliar fertilizer supplemented with phytohormons .
To 100 litres of the preparation as per Example 2, the following phytohormons are added:
naphthil-acetic acid 5.0 g gibberelline (GA3) 20.0 g nicotine acid 1.0 g kinetine 3.0 g
The nutrients of the preparation so obtained are better utilized by the plants, and through its application the reparation processes of plants as a result of poisoning by heavy metal absorption and radiation damage are accelerated.
Example 9
Producing foliar fertilizer supplemented with vitamins and phytohormons.
To 100 litres of the preparation as per Example 1, the following vitamins and phytohormons are added:
Vitamin Bl 0.5 g
Vitamin B2 1.0 g
Vitamin B6 2.0 g α-indolil-acetic acid 5.0 g gibberelline (GA10) 20.0 g nicotine acid 1.0 g kinetine 3.0 g
The nutrients of the preparation so obtained are better utilized by the plants, and through its application the repairing processes of plants as a result of poisoning by heavy metal absorption and radiation damage are accelerated.
Example 10
Producing foliar fertilizer serving as the nutrient of plants, through the use of rocks.
chamomile extract 2.00 litres rhubarb extract 5.00 litres marigold extract 1.50 litres walnut extract 0.50 litres garlic extract 10.00 litres
Figure imgf000023_0001
This mixture is diluted to 100 litres by water, and then the following crushed rocks are added to a 20-litre volume of the compound, while agitating:
nitrocalcite 15.00 kg strewite 10.00 kg brushite 15.00 kg isokite 12.00 kg potassium nitrate 20.00 kg dolomite 18.00 kg mallardite 1.00 kg powellite 1.50 kg pisanite 2.50 kg zincite 2.50 kg gallite 0.50 kg trifiline 0.50 kg spherocobaltite 0.25 kg ilmenite 0.25 kg bentonite 1.00 kg
Let the mixture stand for seven days.
When the preparation so produced is diluted to 0.1 to 50 per cent by volume, it can be used for supplementing the N, P,
K, Ca, Mg, Fe, Cu, Mn nutrients of plants.
The efficiency of preparations embodied by the invention is demonstrated by the following experiments:
Experiment A
Testing of nutrient content in wheat
The wheat variety Mv 16, was treated in 2-3 leaf condition with the preparation as per example 1, diluted to 1 %, 5 % and 10 % concentration (A, B, C) . As a reference, untreated plants were used.
In 3-4 leaf condition we have determined the nutrient content of the leaves. The results are given in the following Table I.
Experiment B
Testing of nutrient content in wheat.
The wheat variety Mv 15, was treated in 2-3 leaf condition with a preparation as per example 10, diluted 1%, 5% and 10% concentration (A, B, C) . As a reference, untreated plants were used.
In 3-4 leaf condition we have determined the nutrient content of the leaves. The results are given in the following Table II. Table I
Figure imgf000025_0001
Figure imgf000025_0002
Table II
Figure imgf000025_0003
Experiment C
Testing the reduction of SR-85 activity on bean plants. Two-week old bean plants which absorbed SR-85 isotope from the soil were treated with a preparation as per example 3, diluted to 5 % concentration.
When the age reached 4-weeks, we have re-measured the Ns-85 activity of the plants. The results obtained are summarized in the following Table III.
Table III
Sr-85 activity In a percentage of (Bq/g) the reference
Before treatment (reference) 8.12 ± 0.59 100.0 After treatment 7.21 ± 1.06 88.79
Experiment D
Testing of nutrient content on tomatoes.
Tomato berries in green phenological state were treated with preparation A as per example 7, diluted to 10 %, and then in ripe phenological condition we have also determined the nutrient content of the berries.
The results achieved are given in Table IV. Experiment E
Testing of nutrient content on grapes .
At the time of the bursting of the buds we have determined the nutrient content of the leaves of Ezerj ό ( Thousand goodies) grape variety and the plants were treated with the preparation as per example 9 , diluted to 1% , 5% and 10% concentration (A, B and C) .
At the t ime when the berr i es were r ipe , we have re- determined the nutrient content of leaves . The results obtained are given in Table V.
Experiment F
Treatment of sugar-beet.
In 3 -5 leaf state we have determined the Fe , Zn , and Mn content of the leaves of Beta-poly 1 sugar beet hybride , and then the plants were treated with the preparation as per
Example 2 .
In 5-7 leaf state we have re-measured the Fe- Zn and Mn content of the leaves. The results obtained are indicated in the following Table VI.
Table IV
Figure imgf000028_0001
Table V
Figure imgf000028_0002
Table VI
Figure imgf000028_0003

Claims

1. A preparation serving the purposes of providing a nutrient source for plants and of reducing and tolerating the heavy metal and isotope absorption of and injuries caused by them to plants, characterized in that as active ingredients the preparation contains soluble salts of physiologically important macro and/or micro elements and/or complexes and/or rocks including the same, and said preparation further containing extracts of plants containing biocide and/or repellent active ingredient.
2. The preparation as claimed in claim 1, characterized in that as a nitrogen source it contains some kind of a soluble ammonium compound or nitrate, preferably ammonium nitrate or ammonium sulphate.
3. The preparation as claimed in claim 1, characterized in that as a phosphorus source it contains some kind of a soluble phosphate, preferably mono-ammonium phosphate or superphospate.
4. The preparation as claimed in claim 1, characterized in that as a potassium source it contains some kind of a soluble potassium salt, preferably potassium sulphate, potassium nitrate, potassium acetate or potassium chloride.
5. The preparation as claimed in claim 1, characterized in that as a calcium source it contains some kind of a soluble calcium salt, preferably calcium nitrate, calcium hydrogen phosphate, calcium pyrophosphate, calcium citrate, calcium glyconate, calcium lactate or calcium magnesium carbonate.
6. The preparation as claimed in claim 1, characterized in that as a magnesium source it contains some kind of a soluble magnesium salt, preferably magnesium sulphate, magnesium carbonate or calcium magnesium carbonate.
7. The preparation as claimed in claim 1, characterized in that as a manganese source it contains some kind of a soluble manganese salt, preferably manganese sulphate, manganese metaborate, manganese nitrate or manganese chelate.
8. The preparation as claimed in claim 1, characterized in that as a molibdenum source it contains some kind of a soluble molibdenum salt, preferably ammonium-molibdenate.
9. The preparation as claimed in claim 1, characterized in that as a copper source some kind of a copper salt, preferably copper sulphate, copper-nitrate, copper-acetate or copper-amine complex is included.
10. The preparation as claimed in claim 1, characterized in that as a zinc source it includes some kind of a soluble zinc salt, preferably zinc sulphate or zinc hexamine complex.
11. The preparation as claimed in claim 1, characterized in that as a boron source it includes some kind of a boric acid or soluble boron salt, preferably borax.
12. The preparation as claimed in claim 1, characterized in that it includes as a gallium source some kind of a soluble gallium salt preferably gallium chloride.
13. The preparation as claimed in claim 1, characterized in that as a lithium source, some kind of a soluble lithium salt, preferably lithium nitrate is included.
14. The preparation as claimed in claim 1, characterized in that as a cobalt source, it includes some kind of a soluble cobalt salt, preferably cobalt carbonate or cobalt chloride.
15. The preparation as claimed in claim 1, characterized in that as a titanium source, it includes titanium dioxide.
16. The preparation as claimed in claim 1, characterized in that as an iron source, it includes some kind of a soluble iron (III) salt, preferably iron (III) sulphate or iron kelates.
17. The preparation as claimed in claim 1, characterized in that as a nitrogen source it includes some kind of nitrogen-containing rocks, preferably nitro-calcite or strewite.
18. The preparation as claimed in claim 1, characterized in that as a phosphorus source, it includes some kind of phosphorus containing rocks, preferably fluor apatite, isotite, brushite, kutnohorite or phosphorite.
19. The preparation as claimed in claim 1, characterized in that as a potassium source it includes some kind of potassium containing rocks, preferably potassium nitrate, karnallite, cryptomelane, langbeinite or kainite.
20. The preparation as claimed in claim 1, characterized in that as a calcium source it includes some kind of calcium- containing rocks, preferably dolomite, akermanite, andradite, brushite, monetite, alstonite, aragonite, fassaite, herderite, huntite, calcite, lautarite, monticellite, oldhamite, perovskite, polyhalite, powellite, scholzite or fairfieldite.
21. The preparation as claimed in claim 1, characterized in that as a magnesium source it includes some kind of magnesium containing rocks, preferably dolomite, ankerite, epsomite, magnesite, pentahydrite, armalcolite, bischofite, fajheyite, geikielite, kieserite, kutnahorite, polyhalite, strevite, todorokite, or strewite.
22. The preparation as claimed in claim 1, characterized in that as a manganese source it includes some kind of manganese containing rocks, preferably mallardite, ludlamite, graphtonite, jakobsite, kutnahorite, pyrofanite, smikite or crednerite.
23. The preparation as claimed in claim 1, characterized in that as a molibdenum source it includes some kind of molibdenum containing rocks, preferably molibdenite, drysdallite, or powellite.
24. The preparation as claimed in claim 1, characterized in that as a copper source it includes some kind of copper containing rocks, preferably calcantite, credrenite, delafossite, or pysanite.
25. The preparation as claimed in claim 1, characterized in that as a zinc source it includes some kind of zinc containing rocks, preferably zincite, franklinite, hataerolite, matraite, scholzite, willemite or gaslarite.
26. The preparation as claimed in claim 1, characterized in that as a boron source some kind of boron containing rocks preferably borax, boracite, colemanite, inyotite, priceite, warwicite or sassoline is included.
27. The preparation as claimed in claim 1, characterized in that as a gallium source some kind of gallium containing rocks is included, preferably gallite.
28. The preparation as claimed in claim 1, characterized in that as a lithium source some kind of lithium containing rocks are included, preferably trifiline.
29. The preparation as claimed in claim 1 , characterized in that as a cobalt source some kind of cobalt containing rocks, preferably spherocobaltite is included.
30. The preparation as claimed in claim 1, characterized in that as a titanium source some kind of titanium containing rocks, preferably armalcolite, geikielite or ilmenite is included.
31. The preparation as claimed in claim 1, characterized in that as an iron source some kind of iron containing rocks, preferably ilmenite, trifiline, cubanite, heterosite, melonterite, rosenite, strengite, somolnokite, vivianite or pisanite is included.
32. The preparation as claimed in claim 1, characterized in that as a plant extract containing biocide and/or repellent active ingredient, the extract of plants containing pesticide such as bactericide, viricide, insecticide, fungicide, miticide or vermicide or repellent materials are included.
33. The preparation as claimed in claim 1, characterized in that as a plant extract containing biolcide and/or repellent active ingredient, the extract of the following plants is included: mustard, wormwood, chamomile, marigold, thyme, horsetail, sage, lavender, nettle, rhubarb, cselery borago, walnut, paprika, cress, quince, mallow, ricinus, hippophae, rose, black radish, tansy, lavender, caraway, buckwheat, St. John's wort, horse radish, plaintain, anise, aloe, normal mallow, bidens and/or garlic.
34. The preparation as claimed in claim 1, characterized in that it includes some kind of an inorganic or organic acid not harming the plants.
35. The preparation as claimed in claim 34, characterized in that as an acid it includes phosphoric acid, lactic acid, citric acid, malic acid, tartaric acid or acetic acid.
36. The preparation as claimed in claim 1, characterized in that it includes one or more vitamins and/or plant hormons.
37. The preparation as claimed in claim 36, characterized in that as a vitamins it includes thyamine-hydrochloride, aneurine, pyridoxine and/or nicotin acid and as phytohormons auxines, giberrelines, cytokinins, abscisic acid and/or ethylene.
38. A process to produce preparations serving as nutrient source for plants and capable of reducing and tolerating the heavy metal and isotope absorption of plants and repairing the injuries caused by them, as well as for reducing the pesticide volume, characterized in that to the biocide effect plant extract or to the mixture of extracts of many biocide effects plants, the salts and/or complexes of macro and micro elements selected according to the purpose to be achieved and/or the rock(s) crushed as necessary and containing these materials, followed by the supplementing of the mixture in the desired case by one or more phytohormon and/or vitamin and/or inorganic or organic acid and if necessary by a suspending material.
PCT/HU1994/000045 1993-10-21 1994-10-21 Preparations providing a nutrient source for plants and a process for making such preparations WO1995011205A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU10746/95A AU1074695A (en) 1993-10-21 1994-10-21 Preparations providing a nutrient source for plants and a process for making such preparations

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
HU9302976A HU9302976D0 (en) 1993-10-21 1993-10-21 Plains foodelementsource and heavy-metal and isotope-intake using produces and process for producing it
HUP9302976 1993-10-21

Publications (1)

Publication Number Publication Date
WO1995011205A1 true WO1995011205A1 (en) 1995-04-27

Family

ID=10984076

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/HU1994/000045 WO1995011205A1 (en) 1993-10-21 1994-10-21 Preparations providing a nutrient source for plants and a process for making such preparations

Country Status (3)

Country Link
AU (1) AU1074695A (en)
HU (1) HU9302976D0 (en)
WO (1) WO1995011205A1 (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0795526A3 (en) * 1996-03-14 1998-11-11 Brill, Holger, Dr. rer. nat. Fertiliser
EP1103535A3 (en) * 1999-11-24 2001-11-21 Iwao Takeda Fertilizer containing polyphosphate-metal chelates
ES2165749A1 (en) * 1998-02-03 2002-03-16 Outspan Int Ltd Fruit fly-controlling composition and its production and method for controlling fruit fly and device therefor
EP1634500A3 (en) * 1998-07-28 2006-08-09 Ecosmart Technologies Inc. Synergistic and residual pesticidal compositions containing plant essentials oils
US7250175B2 (en) 1998-07-28 2007-07-31 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
EP1779728A3 (en) * 1998-07-28 2007-09-05 EcoSmart Technologies Inc. Synergistic and residual pesticidal compositions containing plant essential oils
WO2009078691A1 (en) * 2007-12-19 2009-06-25 Mezclas Y Fertilizantes, S.A. De C.V. Liquid fertiliser composition
EP2048956A4 (en) * 2006-07-27 2012-09-05 Vegano Aps Organic herbicide and method for manufacturing
CN104250174A (en) * 2014-09-04 2014-12-31 李晓枫 Composite organic fertilizer and preparation method thereof
WO2018192591A1 (en) * 2017-04-21 2018-10-25 Corporacion Universidad De La Costa Cuc Natural, organic insecticide formed by extracts of chilli pepper and nettle plant and method for obtaining same
WO2019215724A1 (en) * 2018-05-08 2019-11-14 Dead Sea Works Ltd. Polyhalite enriched animal feed
US10743535B2 (en) 2017-08-18 2020-08-18 H&K Solutions Llc Insecticide for flight-capable pests
WO2021163809A1 (en) 2020-02-21 2021-08-26 Ostara Nutrient Recovery Technologies Inc. Slow-release potassium and sulfur fertilizer and methods for making same
RU2799017C1 (en) * 2022-06-23 2023-06-30 Евгений Григорьевич НИКОЛАЕВ Means for increasing the yield and quality of agricultural crops
CN116473073A (en) * 2023-05-08 2023-07-25 广东方中高新材料有限公司 Pyraclostrobin synergistic suspension preparation containing gallium complex and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE934104C (en) * 1953-05-28 1955-10-13 Andreas Raedler Liquid spray for the treatment of plants and to improve, activate and keep soil healthy
FR2124075A1 (en) * 1971-02-03 1972-09-22 Mouilleau Clovis
WO1979000261A1 (en) * 1977-11-04 1979-05-17 Mallinckrodt Inc Composition and process for a granular plant nutrient
DD210449A1 (en) * 1981-09-12 1984-06-13 Huels Chemische Werke Ag SOLID, WATER-SOLID MASSAGE MIXTURES, THEIR PREPARATION AND USE
AT377972B (en) * 1980-12-29 1985-05-28 Kerteszeti Egyetem TITANIUM-BASED AGENT FOR FOLIAGE FERTILIZATION AND SEED SEEDING

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE934104C (en) * 1953-05-28 1955-10-13 Andreas Raedler Liquid spray for the treatment of plants and to improve, activate and keep soil healthy
FR2124075A1 (en) * 1971-02-03 1972-09-22 Mouilleau Clovis
WO1979000261A1 (en) * 1977-11-04 1979-05-17 Mallinckrodt Inc Composition and process for a granular plant nutrient
AT377972B (en) * 1980-12-29 1985-05-28 Kerteszeti Egyetem TITANIUM-BASED AGENT FOR FOLIAGE FERTILIZATION AND SEED SEEDING
DD210449A1 (en) * 1981-09-12 1984-06-13 Huels Chemische Werke Ag SOLID, WATER-SOLID MASSAGE MIXTURES, THEIR PREPARATION AND USE

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0795526A3 (en) * 1996-03-14 1998-11-11 Brill, Holger, Dr. rer. nat. Fertiliser
ES2165749A1 (en) * 1998-02-03 2002-03-16 Outspan Int Ltd Fruit fly-controlling composition and its production and method for controlling fruit fly and device therefor
US7537777B2 (en) 1998-07-28 2009-05-26 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
US7476397B2 (en) 1998-07-28 2009-01-13 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
US7250175B2 (en) 1998-07-28 2007-07-31 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
EP1779728A3 (en) * 1998-07-28 2007-09-05 EcoSmart Technologies Inc. Synergistic and residual pesticidal compositions containing plant essential oils
EP1779730A3 (en) * 1998-07-28 2007-09-05 EcoSmart Technologies Inc. Synergistic and residual pesticidal compositions containing plant essential oils
EP1779729A3 (en) * 1998-07-28 2007-09-05 EcoSmart Technologies Inc. Synergistic and residual pesticidal compositions containing plant essential oils
US7320966B2 (en) 1998-07-28 2008-01-22 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
US7351420B2 (en) 1998-07-28 2008-04-01 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
US7361366B2 (en) 1998-07-28 2008-04-22 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
US7618645B2 (en) 1998-07-28 2009-11-17 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
US7531189B2 (en) 1998-07-28 2009-05-12 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
US7534447B2 (en) 1998-07-28 2009-05-19 Ecosmart Technologies, Inc. Synergistic and residual pesticidal compositions containing plant essential oils
EP1634500A3 (en) * 1998-07-28 2006-08-09 Ecosmart Technologies Inc. Synergistic and residual pesticidal compositions containing plant essentials oils
EP1103535A3 (en) * 1999-11-24 2001-11-21 Iwao Takeda Fertilizer containing polyphosphate-metal chelates
EP2048956A4 (en) * 2006-07-27 2012-09-05 Vegano Aps Organic herbicide and method for manufacturing
US8048190B2 (en) 2007-12-19 2011-11-01 Jose Luis Miranda Valencia Composition of liquid fertilizer
WO2009078691A1 (en) * 2007-12-19 2009-06-25 Mezclas Y Fertilizantes, S.A. De C.V. Liquid fertiliser composition
CN104250174A (en) * 2014-09-04 2014-12-31 李晓枫 Composite organic fertilizer and preparation method thereof
WO2018192591A1 (en) * 2017-04-21 2018-10-25 Corporacion Universidad De La Costa Cuc Natural, organic insecticide formed by extracts of chilli pepper and nettle plant and method for obtaining same
US10743535B2 (en) 2017-08-18 2020-08-18 H&K Solutions Llc Insecticide for flight-capable pests
US11589599B2 (en) 2018-05-08 2023-02-28 Icl Europe Cooperatief U.A. Polyhalite enriched animal feed
WO2019215724A1 (en) * 2018-05-08 2019-11-14 Dead Sea Works Ltd. Polyhalite enriched animal feed
US11864568B2 (en) 2018-05-08 2024-01-09 Icl Europe Cooperatief U.A. Polyhalite enriched animal feed
WO2021163809A1 (en) 2020-02-21 2021-08-26 Ostara Nutrient Recovery Technologies Inc. Slow-release potassium and sulfur fertilizer and methods for making same
RU2799017C1 (en) * 2022-06-23 2023-06-30 Евгений Григорьевич НИКОЛАЕВ Means for increasing the yield and quality of agricultural crops
CN116473073A (en) * 2023-05-08 2023-07-25 广东方中高新材料有限公司 Pyraclostrobin synergistic suspension preparation containing gallium complex and preparation method thereof

Also Published As

Publication number Publication date
HU9302976D0 (en) 1994-01-28
AU1074695A (en) 1995-05-08

Similar Documents

Publication Publication Date Title
Rehakova et al. Agricultural and agrochemical uses of natural zeolite of the clinoptilolite type
WO1995011205A1 (en) Preparations providing a nutrient source for plants and a process for making such preparations
AU2017210504A1 (en) Fertilizer compositions comprising a cellulose nutrient component and methods for using same
Dewdar et al. Effect of nano micronutrients and nitrogen foliar applications on sugar beet (Beta vulgaris L.) of quantity and quality traits in marginal soils in Egypt
Sabry Synthetic fertilizers; role and hazards
Parra-Torrejón et al. Multifunctional nanomaterials for biofortification and protection of tomato plants
CN108586100A (en) A kind of foliar fertilizer and preparation method thereof
CN102633576A (en) Soil nutrient protective agent for preventing harm of acid rain
CN104003780A (en) Nitrogen-sulfur phosphate fertilizer and preparation method thereof
Samoraj et al. Biomass-based micronutrient fertilizers and biofortification of raspberries fruits
Nakano et al. Effects of different kinds of fertilizer and application methods on δ15N values of tomato
KR20090049966A (en) Composition for nourishment and growth of crops and prevention of pests
Jat et al. A review on use of micronutrients in tropical and subtropical fruit crops
Ataya et al. Improving of hayany date palm production by using k-humate as soil application and magnetic water irrigation at south Sinai governorate Egypt
KR20110136520A (en) Soil improver
Elsayed et al. The efficiency of using vermicompost and some bio-safe stimulants in recovering yield and quality of flame seedless cv. in degraded vineyard
Gulz Arsenic uptake of common crop plants from contaminated soils and interaction with phosphate
Michalak et al. Trace elements as fertilizer micronutrients
Murgueitio-Herrera et al. Synthesis of Iron, Zinc, and Manganese Nanofertilizers, using Andean Blueberry Extract, and their effect in the growth of Cabbage and Lupin plants. Nanomaterials. 2022; 12 (11)
Ferreira et al. Kamafugite from the Alto Paranaíba province as a multi-nutrient fertilizer
Naz et al. Recent Developments to Mitigate Selenium Deficiency in Agricultural Eco-Systems.
Mogwasi et al. Effect of farm additives on the potential bioavailability of some nutritional elements from Kenyan wild plants
CN111704502A (en) Special synergistic selenium-rich fertilizer for acid soil and preparation method thereof
US20250282690A1 (en) Nano-chelated complexes
El-Sayed Yield and quality of sugar beet as affected by zinc foliar application under different nitrogen fertilization levels

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AT AU BB BG BR BY CA CH CN CZ DE DK ES FI GB JP KP KR KZ LK LU LV MG MN MW NL NO NZ PL PT RO RU SD SE SK UA US UZ VN

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA