WO1999040575A1 - Magnetic recording medium with patterned substrate - Google Patents
Magnetic recording medium with patterned substrate Download PDFInfo
- Publication number
- WO1999040575A1 WO1999040575A1 PCT/US1999/002670 US9902670W WO9940575A1 WO 1999040575 A1 WO1999040575 A1 WO 1999040575A1 US 9902670 W US9902670 W US 9902670W WO 9940575 A1 WO9940575 A1 WO 9940575A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- magnetic
- layer
- alloy
- recording medium
- magnetic recording
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 53
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 29
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 25
- 238000000151 deposition Methods 0.000 claims abstract description 12
- 238000007743 anodising Methods 0.000 claims abstract description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000004544 sputter deposition Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 23
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- HBXWYZMULLEJSG-UHFFFAOYSA-N chromium vanadium Chemical compound [V][Cr][V][Cr] HBXWYZMULLEJSG-UHFFFAOYSA-N 0.000 claims description 8
- 238000002048 anodisation reaction Methods 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 3
- QXWGVGIOMAUVTC-UHFFFAOYSA-N chromium cobalt platinum tantalum Chemical compound [Cr][Pt][Co][Ta] QXWGVGIOMAUVTC-UHFFFAOYSA-N 0.000 claims description 3
- OFNHPGDEEMZPFG-UHFFFAOYSA-N phosphanylidynenickel Chemical compound [P].[Ni] OFNHPGDEEMZPFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000006112 glass ceramic composition Substances 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 229910001362 Ta alloys Inorganic materials 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 230000003993 interaction Effects 0.000 abstract description 9
- 230000001747 exhibiting effect Effects 0.000 abstract description 6
- 239000011651 chromium Substances 0.000 description 12
- 239000010408 film Substances 0.000 description 12
- 230000001681 protective effect Effects 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 239000010409 thin film Substances 0.000 description 6
- 230000002463 transducing effect Effects 0.000 description 6
- 239000002585 base Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000013500 data storage Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000002241 glass-ceramic Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 229910001004 magnetic alloy Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- SYQQWGGBOQFINV-FBWHQHKGSA-N 4-[2-[(2s,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-3-oxo-1,2,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-2-yl]ethoxy]-4-oxobutanoic acid Chemical compound C1CC2=CC(=O)[C@H](CCOC(=O)CCC(O)=O)C[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 SYQQWGGBOQFINV-FBWHQHKGSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- KCZFLPPCFOHPNI-UHFFFAOYSA-N alumane;iron Chemical compound [AlH3].[Fe] KCZFLPPCFOHPNI-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000000089 atomic force micrograph Methods 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000010076 replication Effects 0.000 description 1
- 230000003362 replicative effect Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/84—Processes or apparatus specially adapted for manufacturing record carriers
- G11B5/855—Coating only part of a support with a magnetic layer
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
- G11B5/736—Non-magnetic layer under a soft magnetic layer, e.g. between a substrate and a soft magnetic underlayer [SUL] or a keeper layer
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
- G11B5/7368—Non-polymeric layer under the lowermost magnetic recording layer
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
- G11B5/7368—Non-polymeric layer under the lowermost magnetic recording layer
- G11B5/7369—Two or more non-magnetic underlayers, e.g. seed layers or barrier layers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
- G11B5/7368—Non-polymeric layer under the lowermost magnetic recording layer
- G11B5/7379—Seed layer, e.g. at least one non-magnetic layer is specifically adapted as a seed or seeding layer
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
- G11B5/739—Magnetic recording media substrates
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
- G11B5/739—Magnetic recording media substrates
- G11B5/73911—Inorganic substrates
- G11B5/73913—Composites or coated substrates
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
- G11B5/739—Magnetic recording media substrates
- G11B5/73911—Inorganic substrates
- G11B5/73917—Metallic substrates, i.e. elemental metal or metal alloy substrates
- G11B5/73919—Aluminium or titanium elemental or alloy substrates
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
- G11B5/739—Magnetic recording media substrates
- G11B5/73911—Inorganic substrates
- G11B5/73921—Glass or ceramic substrates
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/84—Processes or apparatus specially adapted for manufacturing record carriers
- G11B5/8404—Processes or apparatus specially adapted for manufacturing record carriers manufacturing base layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/90—Magnetic feature
Definitions
- the present invention relates to the recording, storage and reading of magnetic data, particularly rotatable magnetic recording media, such as thin film magnetic disks having textured surfaces for contact with cooperating magnetic transducing heads.
- the invention has particular applicability to high density magnetic recording media exhibiting low noise, reduced flying heights and high coercivity.
- Magnetic disks and disk drives are conventionally employed for storing data in magnetizable form.
- one or more disks are rotated on a central axis in combination with data transducing heads positioned in close proximity to the recording surfaces of the disks and moved generally radially with respect thereto.
- Magnetic disks are usually housed in a magnetic disk unit in a stationary state with a magnetic head having a specific load elastically in contact with and pressed against the surface of the disk.
- a magnetic recording medium for ultra-high density recording having suitable magnetic properties, such as high coercivity, e.g., greater than 2500 Oersteads, and a high overwrite, e.g., about 40dB, while at the same time exhibiting suitable mechanical properties for read-write performance, such as a small glide height avalanche, e.g., about 0.75 to about 0.85 ⁇ inch.
- the magnetic disk is normally driven by the contact start stop (CSS) method, wherein the head begins to slide against the surface of the disk as the disk begins to rotate. Upon reaching a predetermined high rotational speed, the head floats in air at a predetermined distance from the surface of the disk due to dynamic pressure effects caused by the air flow generated between the sliding surface of the head and the disk.
- the transducing head is maintained at a controlled distance from the recording surface, supported on a bearing of air as the disk rotates.
- the magnetic head unit is arranged such that the head can be freely moved in both the circumferential and radial directions of the disk in this floating state allowing data to be recorded on and retrieved from the surface of the disk at a desired position.
- the rotational speed of the disk decreases and the head begins to slide against the surface of the disk again and eventually stops in contact with and pressing against the disk.
- the transducing head contacts the recording surface whenever the disk is stationary, accelerated from a stop and during deceleration just prior to completely stopping.
- the sliding surface of the head repeats the cyclic operation consisting of stopping, sliding against the surface of the disk, floating in the air, sliding against the surface of the disk and stopping. It is considered desirable during reading and recording operations to maintain each transducing head as close to its associated recording surface as possible, i.e., to minimize the flying height of the head. This objective becomes particularly significant as the areal recording density increases.
- the areal density (Mbits/in 2 ) is the recording density per unit area and is equal to the track density (TPI) in terms of tracks per inch times (x) the linear density (BPI) in terms of bits per inch.
- TPI track density
- BPI linear density
- head surface and recording surface are too flat, the precision match of these surfaces gives rise to excessive stiction and friction during the start up and stopping phases, thereby causing wear to the head and recording surfaces eventually leading to what is referred to as a "head crash.”
- head crash there are competing goals of reduced head/disk friction and minimum transducer flying height .
- the recording surfaces of magnetic disks are conventionally provided with a roughened surface to reduce the head/disk friction by techniques referred to as "texturing.”
- texturing techniques involve polishing the surface of a disk substrate to provide a texture thereon prior to subsequent deposition of coatings, such as an underlayer, magnetic layer, carbon overcoat and lubricant topcoat, wherein the textured surface on the substrate is reproduced on the surface of the magnetic disk.
- coatings such as an underlayer, magnetic layer, carbon overcoat and lubricant topcoat
- Fig. 1 and comprises a substrate 10, typically aluminum (Al) or an Al alloy, such as an aluminum-magnesium (Al-Mg) -alloy, plated with a layer of amorphous nickel -phosphorus (NiP) .
- Alternative substrates include glass, ceramic, glass-ceramic materials and graphite.
- Substrate 10 typically contains sequentially deposited on each side thereof a chromium (Cr) or Cr-alloy underlayer 11, U N a cobalt (Co) base alloy magnetic layer 12, 12', a protective overcoat 13, 13', typically containing carbon, and a lubricant topcoat 14, 14' .
- Cr underlayer 11, 11' can be applied as a composite comprising a plurality of sub-underlayers 11A, 11A' .
- Cr underlayer 11, 11', Co base magnetic alloy layer 12, 12' and protective overcoat 13, 13' are typically sputter deposited in an apparatus containing sequential deposition chambers.
- a conventional Al-alloy substrate is provided with a ⁇ iP plating, primarily to increase the hardness of the Al substrate, serving as a suitable surface to provide a texture, which is substantially reproduced on the disk surface to serve as a landing zone.
- Increasingly high density and large-capacity magnetic disks require smaller flying heights, i.e., the distance by which the head floats above the surface of the disk in the CSS drive.
- the requirement to further reduce the flying height of the head imposed by increasingly higher recording density and capacity render it particularly difficult to accurately control texturing to avoid head crash.
- Conventional techniques for providing a disk substrate with a textured surface comprise a mechanical operation, such as polishing. See, for example, Nakamura et al . , U.S. Patent No. 5,202,810.
- Conventional mechanical texturing techniques are attendant with numerous disadvantages. For example, it is extremely difficult to provide a clean textured surface due to debris formed by mechanical abrasions.
- a magnetic recording medium which has a textured surface formed by sputtering a metallic layer, such as titanium or a titanium alloy, on a non-magnetic substrate, inclusive of a glass, glass-ceramics materials and NiP chemically plated Al-Mg alloy substrates. It has, however, been found difficult to produce a magnetic recording medium having a suitably high coercivity greater than 2500 Oersteads, such as greater than 3000 Oersteads, particularly greater than 3300 Oersteads, with a sputter textured layer.
- process parameters must be optimized for each different type of underlying material , thereby decreasing production throughput . Without such optimization of process parameters, consistently reproducible results are difficult to achieve.
- the requirements for high areal recording density impose increasingly greater requirements on thin film magnetic recording media in terms of coercivity, remanent squareness, low medium noise and narrow track recording performance. It is extremely difficult to produce a magnetic recording medium satisfying such demanding requirements, particularly a high density magnetic rigid disk medium for longitudinal recording.
- the linear recording density can be increased by increasing the coercivity of the magnetic recording medium.
- Hr remanent coercivity
- Mr magnetic remanence
- S* coercive squareness
- Conventional underlayers include Cr, molybdenum (Mo) , tungsten (W) , titanium (Ti) , chromium-vanadium (CrV) as well as Cr alloyed with various substitutional elements. It is recognized that underlayers having a fine grain structure are highly desirable, particularly for growing fine grains of hexagonal close packed (HCP) magnetic Co or Co alloy layers deposited thereon.
- HCP hexagonal close packed
- Co-pending application Serial No. 08/699,759 filed on August 20, 1996, discloses that Cr films deposited on surface oxidized NiP layers experience smaller grains than Cr films deposited on non-oxidized NiP layers.
- Co-pending application Serial No. 08/586,529 filed on January 16, 1996, discloses a method of depositing Cr films on surface oxidized NiP films, wherein the deposited Cr films exhibit a (200) -dominant crystallographic orientation.
- Co-pending Application Serial No. 08/945,084 filed on October 17, 1997 (Our Docket No.
- a magnetic recording medium having high coercivity which magnetic recording medium comprises a seedlayer having an oxidized surface formed on a non-magnetic substrate, a chromium-containing sub-underlayer on the oxidized surface of the seedlayer, a nickel -aluminum or iron-aluminum underlayer, a chromium-containing intermediate layer on the underlayer and a magnetic layer on the intermediate layer.
- U.S. Patent No. 5,470,636 issued to Wakui et al . on November 28, 1995, discloses the formation of a landing zone by anodizing an Al substrate or Al layer on a substrate, filing the resulting pores with a non-magnetic material extending above the anodized surface and treating the anodized layer with a fluorine reagent, acid or base.
- magnetic recording media suitable for high areal recording density exhibiting high Hr, high SNR and high S* and improved flying characteristics.
- cost effective, efficient methodology for manufacturing high areal density magnetic recording media exhibiting high Hr, SNR and S* and improved flying characteristics.
- An advantage of the present invention is a magnetic recording medium suitable for high areal density longitudinal magnetic recording which exhibits low medium noise, high Hr, high S* and improved flying characteristics.
- Another advantage of the present invention is a cost effective, efficient method of manufacturing a magnetic recording medium suitable for high areal density longitudinal magnetic recording which exhibits low medium noise, high Hr, high S* and improved flying characteristics.
- a magnetic recording medium comprising: a non-magnetic substrate; a layer comprising Al or an Al alloy on the substrate, the Al or Al alloy having a substantially uniform pattern thereon; and a magnetic layer; wherein, the pattern is substantially replicated on the magnetic layer to form a data zone.
- Another aspect of the present invention is a method of manufacturing a magnetic recording medium, the method comprising: forming a layer of Al or an Al alloy on a nonmagnetic substrate; forming a substantially uniform pattern on the Al or Al alloy layer; and forming a magnetic layer; wherein, the pattern is substantially replicated on the magnetic layer to form a data zone.
- Embodiments of the present invention comprise anodizing the Al or Al alloy layer to form a substantially uniform honeycomb pattern comprising substantially hexagonal cells of Al oxide.
- Embodiments of the present invention further comprise texturing the surface of the substrate to form a textured area which is substantially replicated on subsequently deposited layers, including the magnetic layer, to form a recording data zone.
- FIG. 1 schematically depicts a conventional magnetic recording medium structure .
- Fig. 2 schematically depicts a magnetic recording medium structure in accordance with the present invention.
- Fig. 3 is an atomic force microscope (AFM) image of a NiP/Al substrate before and after anodizing in accordance with an embodiment of the present invention.
- AFM atomic force microscope
- Figs. 4A and 4B show the Hr and SNR, respectively, of an embodiment of the present invention vis-a-vis a conventional magnetic recording medium.
- the present invention addresses the problem of increasing the data storage capacity of magnetic recording media by increasing the Hr and lowering media noise.
- the increased Hr narrows the pulse width and enables a reduction of the bit length for increased recording density.
- Lower media noise generates a higher SNR.
- Embodiments of the present invention achieve the foregoing objectives by a physically segregating the magnetic grains of the magnetic layer. Such physical segregation of magnetic grains is achieved by forming a pattern on the substrate which initiates magnetic film growth in patterns. Such patterns minimize the irregularity of grain growth and narrow the magnetic grain unit's distribution, thereby reducing the origins of zigzag transitions, consequently suppressing magnetic grain interactions and improving SNR. 10
- Embodiments of the present invention comprise forming a continuous film on any of various conventional non-magnetic substrates.
- the continuous film is patterned to provide a substantially uniform matrix for thin film growth, which matrix is substantially replicated in subsequently deposited layers, including the magnetic layer, to form a data zone.
- the uniform pattern formed on the substrate in accordance with embodiments of the present invention serves as a template for films subsequently deposited thereon, e.g. the underlayer and magnetic layer.
- magnetic unit clusters are replicated in accordance with the substrate pattern and, hence, magnetic grain clusters are separated by the pattern boundaries. In this way, grain interactions are minimized and SNR increased.
- an Al or Al alloy is sputter deposited on a nonmagnetic substrate, such as a NiP plated Al or Al alloy substrate, or a glass, ceramic, or glass-ceramic substrate.
- the Al or Al alloy film can be sputter deposited to a thickness of about 50A to about 5000A, e.g., about 500A to about 1500A.
- a substantially uniform pattern is formed on the sputter deposited Al or Al alloy film to serve as a template such that the magnetic grain clusters of the subsequently deposited magnetic layer are separated by the pattern boundaries.
- the sputter deposited Al or Al alloy film is anodized to form a pattern comprising aluminum oxide, such as a substantially honeycomb pattern.
- Anodization can be effected in any conventional manner, as by treatment with a solution of hydrogen phosphate (H 3 P0 4 ) of about 1% to about
- the resulting substantially honeycomb pattern comprises substantially hexagonal cells of aluminum oxide.
- Such substantially hexagonal cells serve as a suitable template for the subsequently deposited magnetic layer such that epitaxial growth is effective to produce a desired 11 hexagonal close packed (HCP) crystal structure.
- the boundaries of the substantially hexagonal cells due to substantial replication in the magnetic layer, serve to separate the magnetic grain clusters thereby minimizing grain interactions and improving SNR.
- the magnetic recording medium is completed by depositing an underlayer and magnetic layer on the anodized surface, replicating the patterns on the substrate.
- a seedlayer such as nickel aluminum (NiAl) is deposited on the anodized Al or Al alloy layer. It is believed that the cells are not completely filled.
- An underlayer, such as CrV, is sputter deposited on the NiAl seedlayer, and a magnetic layer, such as a cobalt-chromium- platinum-tantalum (CoCrPtTa) alloy layer is sputter deposited on the underlayer.
- CoCrPtTa cobalt-chromium- platinum-tantalum
- a protective overcoat such as a carbon- containing protective overcoat, is sputter deposited on the magnetic layer and a lubricant topcoat is formed on the protective overcoat.
- the layers can be sputter deposited in order to optimize magnetic properties, as by employing a base pressure of 2 x 10 "7 Torr with a substrate temperature of about 200°C to 300°C and a substrate bias at about -250 volts, employing a sputtering power density of between 2W/cm 2 to
- FIG. 2 An embodiment of the present invention is schematically illustrated in Fig. 2 and comprises a non-magnetic substrate
- anodized sputter deposited Al layer 21, 21' comprising a substantially uniform honeycomb pattern of substantially hexagonal cells of aluminum oxide.
- Seedlayer 22, 22' such as NiAl
- An underlayer 23, 23' such as CrV
- a magnetic layer 24, 24' such as CoCrPtTa
- an HCP pattern is formed substantially following the template of the patterned layer
- a conventional protective overcoat 25, 25' such as a carbon-containing protective overcoat, is sputter deposited on the magnetic layer 24, 24' and a conventional lubricant topcoat 26, 26' formed thereon.
- a magnetic recording medium in accordance with the present invention was made by sputter depositing an Al layer on an NiP/Al substrate and anodizing the Al layer to form a substantially honeycomb Al oxide pattern comprising substantially hexagonal cells having a depth of about 500A and a diameter of about 500A, suitable for magnetic recording bit size scales.
- a NiAl seedlayer was deposited on the anodized Al layer
- a CrV underlayer was deposited on the NiAl seedlayer
- a CoCrPtTa magnetic layer was deposited on the CrV underlayer.
- a carbon-containing protective overcoat was deposited on the CoCrPtTa layer.
- the Al layer was anodized in a 4% H 3 P0 4 solution and the results of anodization are shown in Fig. 3, the left hand portion of Fig. 3 illustrating the Al layer before anodization and right hand portion comprising the honeycomb structure subsequent to anodization.
- a comparison (regular) magnetic recording medium was made employing substantially the same layers and substantially the same deposition conditions as in forming the magnetic recording medium representative of the present invention, except that an Al layer was not sputter deposited on the substrate and anodized.
- the magnetic properties of both media were tested employing a non-destructive rotating disk magnetometer. Recording characteristics and media noise was measured at a linear density of 240kfci (kiloflux changes per inch) employing a Guzik 1601 tester with a magnetorestive (MR) head having a 0.35 ⁇ in gap length and flying at a nominal height of 2.1 ⁇ in.
- MR magnetorestive
- Fig. 4A shows the magnetic properties of the comparison (regular) medium and the medium in accordance with the present invention
- Fig. 4B illustrates that the magnetic recording medium in accordance with the present invention exhibits an improvement in SNR of about 0.5 to about ldB vis-a-vis the comparison (regular) magnetic recording medium.
- a patterned anodized Al oxide layer is formed on a non-magnetic substrate for increased areal recording density.
- the anodized pattern can be formed on any non-magnetic substrate, and typically exhibits a substantially hexagonal honeycomb structure comprising a single hexagonal unit cell ranging from about 50A to about 5000A in diameter and about 50A to about 10,OOOA in depth.
- Conventional magnetron sputtering techniques can be employed to produce magnetic recording media in accordance with the present invention. Accordingly, the present invention can be easily integrated into existing production facilities.
- the present invention enables the formation of magnetic recording media suitable for high areal density recording having improved Hr, improved SNR and S*.
- the present invention also achieves a significant increase in SNR by effecting separation of magnetic grain cells by the pattern boundaries, thereby suppressing magnetic interaction.
- the present invention enables production of any of various types of magnetic recording media, particularly magnetic recording media, such as thin film disks having improved flying heights. Only certain embodiments of the present invention and but a few examples of its versatility are shown and described in the present disclosure. It is to be understood that the present invention is capable of use in various other combinations and environments and is capable of changes and modifications within the scope of the inventive concept as expressed herein.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Metallurgy (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Magnetic Record Carriers (AREA)
- Manufacturing Of Magnetic Record Carriers (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000530905A JP2002503009A (en) | 1998-02-10 | 1999-02-10 | Magnetic recording medium having pattern substrate |
GB0019477A GB2350471B (en) | 1998-02-10 | 1999-02-10 | Magnetic recording medium with patterned substrate |
DE19982817T DE19982817T1 (en) | 1998-02-10 | 1999-02-10 | Magnetic recording medium with patterned substrate |
US09/242,226 US6764738B1 (en) | 1998-02-10 | 1999-02-10 | Magnetic recording medium with patterned substrate |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US7425398P | 1998-02-10 | 1998-02-10 | |
US60/074,253 | 1998-02-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999040575A1 true WO1999040575A1 (en) | 1999-08-12 |
Family
ID=22118583
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1999/002670 WO1999040575A1 (en) | 1998-02-10 | 1999-02-10 | Magnetic recording medium with patterned substrate |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP2002503009A (en) |
KR (1) | KR100629034B1 (en) |
DE (1) | DE19982817T1 (en) |
GB (1) | GB2350471B (en) |
WO (1) | WO1999040575A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000068941A1 (en) * | 1999-05-11 | 2000-11-16 | Hitachi Maxell, Ltd. | Magnetic recording medium and its production method, and magnetic recorder |
US6999279B2 (en) | 2002-10-29 | 2006-02-14 | Imation Corp. | Perpendicular patterned magnetic media |
US7050251B2 (en) | 2003-06-25 | 2006-05-23 | Imation Corp. | Encoding techniques for patterned magnetic media |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5062021A (en) * | 1990-03-12 | 1991-10-29 | Magnetic Peripherals Inc. | Selectively textured magnetic recording media |
US5718811A (en) * | 1996-02-28 | 1998-02-17 | Seagate Technology, Inc. | Sputter textured magnetic recording medium |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5470636A (en) * | 1991-03-15 | 1995-11-28 | Yamaha Corporation | Magnetic recording medium and method of producing it |
JPH056539A (en) * | 1991-06-28 | 1993-01-14 | Mitsubishi Plastics Ind Ltd | Production of stamper for information recording medium |
US5693426A (en) * | 1994-09-29 | 1997-12-02 | Carnegie Mellon University | Magnetic recording medium with B2 structured underlayer and a cobalt-based magnetic layer |
GB2334134B (en) * | 1996-10-17 | 2000-10-25 | Seagate Technology | Magnetic recording medium comprising a nickel aluminum or iron aluminum underlayer |
-
1999
- 1999-02-10 DE DE19982817T patent/DE19982817T1/en not_active Withdrawn
- 1999-02-10 KR KR1020007008738A patent/KR100629034B1/en not_active Expired - Fee Related
- 1999-02-10 JP JP2000530905A patent/JP2002503009A/en active Pending
- 1999-02-10 WO PCT/US1999/002670 patent/WO1999040575A1/en active IP Right Grant
- 1999-02-10 GB GB0019477A patent/GB2350471B/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5062021A (en) * | 1990-03-12 | 1991-10-29 | Magnetic Peripherals Inc. | Selectively textured magnetic recording media |
US5718811A (en) * | 1996-02-28 | 1998-02-17 | Seagate Technology, Inc. | Sputter textured magnetic recording medium |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000068941A1 (en) * | 1999-05-11 | 2000-11-16 | Hitachi Maxell, Ltd. | Magnetic recording medium and its production method, and magnetic recorder |
US6730421B1 (en) | 1999-05-11 | 2004-05-04 | Hitachi, Maxell, Ltd. | Magnetic recording medium and its production method, and magnetic recorder |
US6999279B2 (en) | 2002-10-29 | 2006-02-14 | Imation Corp. | Perpendicular patterned magnetic media |
US7050251B2 (en) | 2003-06-25 | 2006-05-23 | Imation Corp. | Encoding techniques for patterned magnetic media |
Also Published As
Publication number | Publication date |
---|---|
JP2002503009A (en) | 2002-01-29 |
DE19982817T1 (en) | 2001-03-22 |
KR20010040843A (en) | 2001-05-15 |
KR100629034B1 (en) | 2006-09-26 |
GB2350471B (en) | 2002-04-17 |
GB2350471A (en) | 2000-11-29 |
GB0019477D0 (en) | 2000-09-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6673474B2 (en) | Medium substrate, production method thereof and magnetic disk device | |
US7169487B2 (en) | Magnetic recording medium | |
US6057021A (en) | Magnetic recording media and magnetic recording system using the same | |
KR970005351B1 (en) | Magnetic recording disk for contact recovring | |
US6607842B2 (en) | Containing an AITa or AITi pre-seed layer, a CoCr onset layer and a CoCrPtB magnetic layer | |
CN114446327A (en) | Heat Assisted Magnetic Recording (HAMR) media with multi-layer underlayer for recording layer | |
US6509083B2 (en) | High coercivity magnetic recording medium comprising a sputter textured layer | |
US6572989B2 (en) | Thin film magnetic recording disk with a chromium-nickel pre-seed layer | |
US6403241B1 (en) | CoCrPtB medium with a 1010 crystallographic orientation | |
US5989674A (en) | Thin film disk with acicular magnetic grains | |
EP0703573A1 (en) | Magnetic recording disk with texturing layer | |
US6238780B1 (en) | Magnetic recording medium comprising multilayered carbon-containing protective overcoats | |
WO1997032055A1 (en) | Sputter textured magnetic recording medium | |
US6740397B1 (en) | Subseedlayers for magnetic recording media | |
US6764738B1 (en) | Magnetic recording medium with patterned substrate | |
KR100629034B1 (en) | Magnetic recording medium with patterned substrate | |
JP2005078796A (en) | Thin film magnetic medium having a two-layer structure made of CrTi / NiP | |
US6517956B1 (en) | Magneto-resistance recording media comprising aluminum nitride corrosion barrier layer and a c-overcoat | |
US6497925B1 (en) | Surface treatment on solgel coated substrate to improve glide height performance | |
JP3657196B2 (en) | Magnetic recording medium and magnetic disk device | |
EP0897576B1 (en) | Laser texturing of magnetic recording medium using multiple lens focusing | |
JP2005092970A (en) | Magnetic recording medium and magnetic storage device | |
US5945197A (en) | Laser texturing of magnetic recording medium using multiple lens focusing | |
JP2003109213A (en) | Magnetic recording medium | |
JP2006155863A (en) | Perpendicular magnetic recording medium, its manufacturing method, and magnetic recording and reproducing apparatus |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 09242226 Country of ref document: US |
|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): DE GB JP KR SG US |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
ENP | Entry into the national phase |
Ref document number: 200019477 Country of ref document: GB Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2000 530905 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020007008738 Country of ref document: KR |
|
RET | De translation (de og part 6b) |
Ref document number: 19982817 Country of ref document: DE Date of ref document: 20010322 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 19982817 Country of ref document: DE |
|
WWP | Wipo information: published in national office |
Ref document number: 1020007008738 Country of ref document: KR |
|
WWG | Wipo information: grant in national office |
Ref document number: 1020007008738 Country of ref document: KR |